BRPI0514759A - processo de oxidação em fase lìquida, e, aparelho para oxidação em fase lìquida - Google Patents

processo de oxidação em fase lìquida, e, aparelho para oxidação em fase lìquida

Info

Publication number
BRPI0514759A
BRPI0514759A BRPI0514759-0A BRPI0514759A BRPI0514759A BR PI0514759 A BRPI0514759 A BR PI0514759A BR PI0514759 A BRPI0514759 A BR PI0514759A BR PI0514759 A BRPI0514759 A BR PI0514759A
Authority
BR
Brazil
Prior art keywords
liquid phase
phase oxidation
cta
oxidation
oxidation process
Prior art date
Application number
BRPI0514759-0A
Other languages
English (en)
Inventor
Alan George Wonders
Marcel De Vreede
Lee Reynolds Partin
Wayne Scott Strasser
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Publication of BRPI0514759A publication Critical patent/BRPI0514759A/pt
Publication of BRPI0514759B1 publication Critical patent/BRPI0514759B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/003—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/222—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid in the presence of a rotating device only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/14—Monocyclic dicarboxylic acids
    • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
    • C07C63/26—1,4 - Benzenedicarboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

PROCESSO DE OXIDAçãO EM FASE LìQUIDA, E, APARELHO PARA OXIDAçãO EM FASE LìQUIDA São revelados um processo e aparelho otimizados para realizar de forma mais eficiente e económica a oxidação em fase líquida de um composto oxidável. Tal oxidação em fase líquida é realizada em um reator de coluna de bolhas que permite uma reação altamente eficiente a temperaturas relativamente baixas. Quando o composto oxidado é para-xileno e o produto da reação de oxidação é ácido tereftálico bruto (CTA), tal produto CTA pode ser purificado e separado por técnicas mais económicas do que as que poderiam ser empregadas se o CTA fosse formado por um processo convencional de oxidação a alta temperatura.
BRPI0514759A 2004-09-02 2005-08-29 processo de oxidação em fase líquida, e, aparelho para oxidação em fase líquida BRPI0514759B1 (pt)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US60668904P 2004-09-02 2004-09-02
US63132704P 2004-11-29 2004-11-29
US11/154,139 US7371894B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
PCT/US2005/030660 WO2006028772A2 (en) 2004-09-02 2005-08-29 Optimized liquid-phase oxidation

Publications (2)

Publication Number Publication Date
BRPI0514759A true BRPI0514759A (pt) 2008-06-24
BRPI0514759B1 BRPI0514759B1 (pt) 2016-03-29

Family

ID=35781259

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0514759A BRPI0514759B1 (pt) 2004-09-02 2005-08-29 processo de oxidação em fase líquida, e, aparelho para oxidação em fase líquida

Country Status (13)

Country Link
US (1) US7371894B2 (pt)
EP (1) EP1786551B1 (pt)
JP (1) JP2008511650A (pt)
KR (1) KR101169490B1 (pt)
CN (1) CN101010132B (pt)
BR (1) BRPI0514759B1 (pt)
CA (2) CA2577062A1 (pt)
ES (1) ES2611152T3 (pt)
LT (1) LT1786551T (pt)
MX (1) MX2007002501A (pt)
PL (1) PL1786551T3 (pt)
PT (1) PT1786551T (pt)
WO (1) WO2006028772A2 (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070155987A1 (en) * 2006-01-04 2007-07-05 O'meadhra Ruairi S Oxidative digestion with optimized agitation
US20070208194A1 (en) * 2006-03-01 2007-09-06 Woodruff Thomas E Oxidation system with sidedraw secondary reactor
US7393973B2 (en) * 2006-03-01 2008-07-01 Eastman Chemical Company Polycarboxylic acid production system with enhanced residence time distribution for oxidative digestion
US7501537B2 (en) * 2006-03-01 2009-03-10 Eastman Chemical Company Polycarboxylic acid production system employing oxidative digestion with reduced or eliminated upstream liquor exchange
US7420082B2 (en) * 2006-03-01 2008-09-02 Eastman Chemical Company Polycarboxylic acid production system employing hot liquor removal downstream of oxidative digestion
US7816556B2 (en) * 2006-03-01 2010-10-19 Eastman Chemical Company Polycarboxylic acid production system employing enhanced multistage oxidative digestion
US7326808B2 (en) * 2006-03-01 2008-02-05 Eastman Chemical Company Polycarboxylic acid production system employing cooled mother liquor from oxidative digestion as feed to impurity purge system
US7326807B2 (en) * 2006-03-01 2008-02-05 Eastman Chemical Company Polycarboxylic acid production system with enhanced heating for oxidative digestion
US7772424B2 (en) * 2006-03-01 2010-08-10 Eastman Chemical Company Polycarboxylic acid production system employing enhanced evaporative concentration downstream of oxidative digestion
EP2440515B1 (en) 2009-06-13 2018-08-15 Archer-Daniels-Midland Company Production of adipic acid and derivatives from carbohydrate-containing materials
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
CA2763177C (en) 2009-06-13 2017-08-01 Thomas R. Boussie Production of glutaric acid and derivatives from carbohydrate-containing materials
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
KR101390661B1 (ko) * 2013-01-24 2014-04-30 한국에너지기술연구원 동적 기체분배기 및 그를 적용한 기포탑 반응기
US10537865B2 (en) 2016-09-05 2020-01-21 Sabic Global Technologies B.V. Method for producing dihydroxy compounds
US10000435B1 (en) 2017-02-28 2018-06-19 Grupo Petrotemex, S.A. De C.V. Energy and environmentally integrated method for production of aromatic dicarboxylic acids by oxidation
CN112844283A (zh) * 2020-12-29 2021-05-28 河北英科石化工程有限公司 一种用于氯化聚氯乙烯制备的氯化反应设备
CN118454405A (zh) * 2024-07-10 2024-08-09 杭州千岛湖啤酒有限公司 一种用于啤酒工业生产的气体分离装置及其使用方法

Family Cites Families (153)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1902550A (en) * 1930-01-31 1933-03-21 Nat Synthetic Corp Process of oxidizing cyclic organic compounds
US1936427A (en) 1930-01-31 1933-11-21 Nat Synthetic Corp Process of oxidizing naphthalene and related condensed aromatic ring compounds
US2572710A (en) 1949-09-23 1951-10-23 Monsanto Chemicals Preparation of terephthalic acid
US2572575A (en) 1949-09-23 1951-10-23 Monsanto Chemicals Preparation of terephthalic acid
US3064044A (en) 1957-08-15 1962-11-13 Standard Oil Co Multistage oxidation system for preparing dicarboxylic acid
US3082250A (en) * 1958-05-05 1963-03-19 Standard Oil Co Recovery of phthalic acid products
US3071447A (en) * 1958-09-09 1963-01-01 Whiting Corp Hydraulic classifier
US3029278A (en) * 1958-12-11 1962-04-10 Standard Oil Co Process for separation of phthalic acids
GB1007570A (en) * 1961-07-24 1965-10-13 Socaty Process for the catalytic oxidation of xylenes or industrial mixtures of xylenes
NL282031A (pt) * 1961-08-14
US3216481A (en) 1962-04-17 1965-11-09 Badger Co Recovery of phthalic and maleic acid from solutions
US3244744A (en) * 1963-02-27 1966-04-05 Standard Oil Co Separation process for isophthalic acid and terephthalic acid
DE1276628C2 (de) * 1963-05-20 1975-01-16 Rudzki, Henryk Stanislaw, Dr., Los Angeles, Calif. (V.St.A.) Verfahren zur herstellung von isophtalsaeure und/oder terephthalsaeure
US3410897A (en) 1963-10-10 1968-11-12 Maruzen Oil Company Ltd Purification of terephthalic acid
US3388157A (en) * 1965-02-10 1968-06-11 Ethyl Corp Process for the production of dicarboxylic acids
NL6606774A (pt) 1965-05-17 1966-11-18
GB1142864A (en) 1965-11-15 1969-02-12 Ici Ltd Crystallisation process
US3497552A (en) * 1966-07-18 1970-02-24 Standard Oil Co Continuous crystallization in a plurality of cooling stages using dilutions by cooled solvent of feed to each stage
US3549695A (en) 1966-09-01 1970-12-22 Mobil Oil Corp Method for downflow leaching
US3534090A (en) 1966-11-04 1970-10-13 Mobil Oil Corp Hydrocarbon oxidation
US3584039A (en) * 1967-08-30 1971-06-08 Standard Oil Co Fiber-grade terephthalic acid by catalytic hydrogen treatment of dissolved impure terephthalic acid
US3556733A (en) * 1968-04-05 1971-01-19 Struthers Scientific Int Corp Fines dissolver for crystallizers
US3626001A (en) 1968-05-09 1971-12-07 Atlantic Richfield Co Method for the production of high-purity isophthalic or terephthalic acid
AT282466B (de) 1968-07-25 1970-06-25 Oemv Ag Bitumenblasverfahren und Einrichtung zur Durchführung desselben
DE1792402A1 (de) 1968-08-29 1971-11-11 Dynamit Nobel Ag Verfahren zur Durchfuehrung exothermer chemischer Reaktionen in heterogenen Gas-Fluessigkeits-Gemischen
CA849014A (en) 1968-10-25 1970-08-11 Ichikawa Yataro Apparatus for continuous gas-liquid contact and process for refining crude terephthalic acid
GB1250222A (pt) * 1968-10-25 1971-10-20
US3660476A (en) 1968-10-30 1972-05-02 Teijin Ltd Method for the preparation of terephthalic acid
US3708532A (en) 1968-11-04 1973-01-02 Teijin Ltd Process for the continuous purification of crude terephthalic acid
US3700731A (en) 1969-02-28 1972-10-24 Du Pont Process for oxidizing xylenes to phthalic acids
US3839436A (en) 1969-05-26 1974-10-01 Standard Oil Co Integration of para-or meta-xylene oxidation to terephthalic acid or isophthalic acid and its purification by hydrogen treatment of aqueous solution
US3629321A (en) 1969-05-26 1971-12-21 Standard Oil Co Integration of para-xylene oxidation to terephthalic acid and its esterification to dimethyl terephthalate
US3683018A (en) 1969-05-26 1972-08-08 Standard Oil Co Integrated oxidation of isomeric xylene mixture to isomeric phthalic acid mixture and separation of mixture of isomeric phthalic acids into individual isomer products
US3873275A (en) 1969-09-29 1975-03-25 Whiting Corp Crystallization apparatus and method
BE759284A (fr) 1969-11-24 1971-05-24 Shell Int Research Procede et appareil pour la mise en contact d'un liquide avec des particules solides
US3686293A (en) 1970-07-13 1972-08-22 Giorgio Gualdi Process for the preparation of aromatic carboxylic acids
JPS5328419B1 (pt) * 1971-04-26 1978-08-15
US3785779A (en) * 1971-08-02 1974-01-15 Exxon Research Engineering Co Gas liquid inlet distributor
JPS5544644B2 (pt) * 1971-09-23 1980-11-13
JPS5234590B2 (pt) * 1971-12-28 1977-09-03
NL169993C (nl) * 1972-01-13 1982-09-16 Maruzen Oil Co Ltd Werkwijze ter bereiding van tereftaalzuur.
US3845117A (en) 1972-12-14 1974-10-29 Halcon International Inc Process for preparation of phthalic acids
JPS5328421B2 (pt) 1973-05-15 1978-08-15
US3931305A (en) * 1973-08-20 1976-01-06 Standard Oil Company Terephthalic acid recovery by continuous flash crystallization
JPS5328902B2 (pt) 1973-09-14 1978-08-17
US4053506A (en) 1975-05-02 1977-10-11 Standard Oil Company (Indiana) Production of fiber-grade terephthalic acid
US3997620A (en) 1975-10-28 1976-12-14 Uop Inc. Process for separating para-xylene
JPS5912096B2 (ja) * 1975-10-31 1984-03-21 三菱化学株式会社 ホウコウゾクポリカルボンサンノセイゾウホウ
JPS5278846A (en) * 1975-12-25 1977-07-02 Matsuyama Sekyu Kagaku Kk Continuous production of high purity telephthalic acid
NL170133C (nl) * 1976-02-24 1982-10-01 Matsuyama Petrochemicals Inc Werkwijze voor de bereiding van een aromatisch dicarbonzuur.
SU1126202A3 (ru) * 1976-05-28 1984-11-23 Институт Фор Атомэнерги (Фирма) Способ непрерывной многостадийной кристаллизации из раствора
US4185073A (en) * 1976-07-26 1980-01-22 Standard Oil Company (Indiana) Apparatus for iso- or terephthalic acid production in and recovery from benzoic acid-water solvent system
US4081464A (en) * 1976-07-26 1978-03-28 Standard Oil Company Iso- or terephthalic acid production in and recovery from benzoic acid-water solvent system
GB1542320A (en) * 1976-10-26 1979-03-14 Labofina Sa Process for the preparation of aromatic dicarboxylic acids
US4158738A (en) * 1977-05-26 1979-06-19 E. I. Du Pont De Nemours And Company Process for the production of fiber-grade terephthalic acid
US4482524A (en) 1978-01-31 1984-11-13 Ari Technologies, Inc. Autocirculation apparatus
DE2805915C3 (de) * 1978-02-13 1981-11-05 Dynamit Nobel Ag, 5210 Troisdorf Reaktor zur Oxidation von Gemischen aus p-Xylol und p-Toluylsäuremethylester mit sauerstoffhaltigen Gasen in flüssiger Phase
US4233269A (en) 1978-11-09 1980-11-11 Exxon Research & Engineering Co. Gas liquid distributor
US4263448A (en) * 1979-03-30 1981-04-21 Halcon Research And Development Corp. Process for oxidation of hydrocarbons
US4255590A (en) * 1979-11-08 1981-03-10 Standard Oil Company (Indiana) Combination of pyrolysis and incineration of solid mixture of oxygen-containing aromatic compounds obtained as residue of manufacture of benzene di- and tricarboxylic acids
IT1129759B (it) 1980-01-23 1986-06-11 Montedison Spa Metodo per ricuperare in forma attiva i componenti del sistema catalitico della sintesi dell'acido tereftalico
GB2072162B (en) 1980-03-21 1984-03-21 Labofina Sa Process for the production and the recovery of terephthalic acid
DE3047101A1 (de) 1980-12-13 1982-07-22 Hoechst Ag, 6000 Frankfurt Verfahren zum verbessern der gasverteilung in mammut-schlaufenreaktoren
US4342876A (en) * 1980-12-22 1982-08-03 Bechtel International Corporation Method for oxidation of p-xylene and method for preparing dimethylterephthalate
US4334086A (en) * 1981-03-16 1982-06-08 Labofina S.A. Production of terephthalic acid
US4391985A (en) * 1981-11-16 1983-07-05 Eastman Kodak Company Process for the separation of isophthalic acid from terephthalic acid
DE3363127D1 (en) * 1982-02-09 1986-05-28 Bbc Brown Boveri & Cie Method and apparatus for treating a liquid with a gas
JPS59104345A (ja) * 1982-12-03 1984-06-16 Kuraray Yuka Kk 直接重合用に適したテレフタル酸の製造方法
JPS59106435A (ja) * 1982-12-10 1984-06-20 Mitsubishi Chem Ind Ltd 高純度テレフタル酸の製法
JPS6036439A (ja) * 1983-08-09 1985-02-25 Mitsubishi Chem Ind Ltd テレフタル酸の製法
US4500732A (en) * 1983-09-15 1985-02-19 Standard Oil Company (Indiana) Process for removal and recycle of p-toluic acid from terephthalic acid crystallizer solvent
US4769487A (en) * 1984-08-20 1988-09-06 Amoco Corporation Multistage oxidation in a single reactor
US4605763A (en) * 1984-08-31 1986-08-12 Eastman Kodak Company Process for the purification of terephthalic acid
US4777287A (en) 1984-10-29 1988-10-11 Amoco Corporation Recycle of vaporized solvent in liquid phase oxidation of an alkyl aromatic
US4835307A (en) * 1984-12-13 1989-05-30 Amoco Corporation Method and apparatus for controlling the manufacture of terephthalic acid to control the level and variability of the contaminant content and the optical density
US4648999A (en) * 1985-07-22 1987-03-10 M. W. Kellogg Company Apparatus for contacting fluid with solid
US4892970A (en) * 1985-12-30 1990-01-09 Amoco Corporation Staged aromatics oxidation in aqueous systems
US5099064A (en) * 1985-12-30 1992-03-24 Amoco Corporation Method for increasing conversion efficiency for oxidation of an alkyl aromatic compound to an aromatic carboxylic acid
DE3625261A1 (de) 1986-07-25 1988-02-04 Basf Ag Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen
US4914230A (en) * 1986-07-28 1990-04-03 Amoco Corporation Catalyst recovery method
US4769489A (en) * 1986-07-28 1988-09-06 Amoco Corporation Catalyst recovery method
JPH078821B2 (ja) * 1986-09-26 1995-02-01 三井石油化学工業株式会社 芳香族カルボン酸の製造方法
US5166420A (en) 1986-10-20 1992-11-24 Mitsui Petrochemical Industries, Ltd. Process for the production of high purity terephthalic acid
US4900480A (en) * 1986-10-21 1990-02-13 Union Carbide Corporation Gas-liquid mixing
DE3704720A1 (de) * 1987-02-14 1988-08-25 Huels Troisdorf Verfahren und vorrichtung zur herstellung von benzolcarbonsaeuren bzw. benzoldicarbonsaeureestern
JP2504461B2 (ja) 1987-04-24 1996-06-05 三菱化学株式会社 高品質テレフタル酸の製法
DE3839229A1 (de) 1988-11-19 1990-05-23 Krupp Koppers Gmbh Verfahren zur gewinnung von p-xylol mit einer reinheit von mehr als 99,8 gew.-%
JPH01160476A (ja) * 1987-12-16 1989-06-23 Nippon Sharyo Seizo Kaisha Ltd 気泡塔型反応装置
US5211924A (en) * 1988-02-29 1993-05-18 Amoco Corporation Method and apparatus for increasing conversion efficiency and reducing power costs for oxidation of an aromatic alkyl to an aromatic carboxylic acid
US4855491A (en) * 1988-04-25 1989-08-08 Amoco Corporation Method for selectively removing process stream impurities utilizing reverse osmosis
US4863888A (en) 1988-04-29 1989-09-05 Amoco Corporation Catalyst containing cobalt boron and oxygen and optionally aluminum of preparation and process
US4855492A (en) * 1988-05-27 1989-08-08 Amoco Corporation Process for production of aromatic polycarboxylic acids
US4833269A (en) * 1988-08-05 1989-05-23 Amoco Corporation Method for purifying terephthalic acid recycle streams
US5068406A (en) 1989-09-06 1991-11-26 Amoco Corporation Compartmented oxidation method
US5126037A (en) * 1990-05-04 1992-06-30 Union Oil Company Of California Geopreater heating method and apparatus
KR920004602B1 (ko) 1990-06-07 1992-06-11 재단법인 한국화학연구소 1-옥소-1, 2, 3, 4-테트라하이드로나프탈렌의 제조방법
EP0465100B1 (en) * 1990-06-25 1994-09-28 Mitsubishi Gas Chemical Company, Inc. Process for producing high purity isophthalic acid
US5356600A (en) 1990-09-24 1994-10-18 Praxair Technology, Inc. Oxygen enrichment method and system
US5095142A (en) * 1990-11-29 1992-03-10 Amoco Corporation Solvent recovery during production of aromatic polycarboxylic acids
GB9102393D0 (en) * 1991-02-05 1991-03-20 Ici Plc Production of terephthalic acid
GB9104776D0 (en) * 1991-03-07 1991-04-17 Ici Plc Process for the production of terephthalic acid
US5175355A (en) 1991-04-12 1992-12-29 Amoco Corporation Improved process for recovery of purified terephthalic acid
US5227570A (en) * 1991-12-02 1993-07-13 Taiwan Styrene Monomer Corporation Process for separation of ethylbenzene or ethylbenzene/p-xylene from a xylene isomers mixture
US5292934A (en) * 1992-06-18 1994-03-08 Amoco Corporation Method for preparing aromatic carboxylic acids
KR970000136B1 (ko) * 1993-09-28 1997-01-04 브이.피. 유리예프 고순도 벤젠디카르복실산 이성질체의 제조방법
US5523474A (en) * 1994-05-11 1996-06-04 Praxair Technology, Inc. Terephthalic acid production using evaporative cooling
US5712412A (en) * 1994-12-26 1998-01-27 Mitsubishi Gas Chemical Co., Inc. Process for producing highly pure terephthalic acid
SI9500109A (en) * 1995-04-05 1996-10-31 Levec Janez Dipl Ing Prof Dr Apparatus and Process for Thermal Oxidative Treatment of Waste Waters
US6013835A (en) * 1995-06-07 2000-01-11 Hfm International, Inc. Method and apparatus for preparing purified terephthalic acid
US5929274A (en) * 1995-06-07 1999-07-27 Hfm International, Inc. Method to reduce carboxybenzaldehyde isomers in terephthalic acid or isophthalic acid
US5767311A (en) * 1995-06-07 1998-06-16 Glitsch International, Inc. Method and apparatus for preparing purified terephtalic acid
ES2104512B1 (es) * 1995-09-21 1998-07-01 Interquisa Procedimiento industrial para la fabricacion de acidos carboxilicos aromaticos.
FR2739375B1 (fr) * 1995-09-29 1997-12-05 Inst Francais Du Petrole Production de paraxylene a partir d'un effluent de dismutation paraselective du toluene par un procede de cristallisation associe a une adsorption en lit mobile simule
US5693856A (en) * 1996-01-16 1997-12-02 The Boc Group, Inc. Production of terephthalic acid
US6376733B1 (en) * 1996-01-25 2002-04-23 Exxonmobil Chemical Patents Inc. Process for production of paraxylene
US5756833A (en) * 1996-02-01 1998-05-26 Amoco Corporation Catalytic purification and recovery of dicarboxylic aromatic acids
ID15851A (id) * 1996-02-13 1997-08-14 Mitsubishi Chem Corp Proses untuk menghasilkan suatu asam aromatik karboksilik
JPH09278709A (ja) * 1996-02-13 1997-10-28 Mitsubishi Chem Corp 芳香族カルボン酸の製造方法
US6242643B1 (en) * 1996-05-17 2001-06-05 Toray Industries, Inc. Method for preparing aromatic carboxylic acids, aromatic aldehydes, and aromatic alcohols
JP3757995B2 (ja) * 1996-07-12 2006-03-22 三菱瓦斯化学株式会社 高純度イソフタル酸の製造方法
JPH1045667A (ja) * 1996-07-29 1998-02-17 Mitsubishi Gas Chem Co Inc 分散媒置換装置を用いた高純度テレフタル酸の製造方法
EP0928203B1 (en) * 1996-09-24 2006-10-25 Merck & Co., Inc. Compounds for the inhibition of angiogenesis by gene therapy
ID19133A (id) * 1996-12-12 1998-06-18 Praxair Technology Inc Pengisian oksigen langsung kedalam reaktor-reaktor ruang gelembung
GB9701251D0 (en) * 1997-01-22 1997-03-12 Bp Chem Int Ltd Process
US6037491A (en) * 1997-07-25 2000-03-14 Rpc Inc. Methods and devices for controlling hydrocarbon oxidations to respective acids by adjusting the solvent to hydrocarbon ratio
US5939313A (en) * 1997-09-12 1999-08-17 Praxair Technology, Inc. Stationary vortex system for direct injection of supplemental reactor oxygen
BR9907687A (pt) * 1998-02-09 2000-11-14 Rpc Inc Processo para o tratamento de catalisador cobalto em misturas de oxidação de hidrocarbonetos a ácidos dibásicos
DE19837723A1 (de) * 1998-08-20 2000-02-24 Phenolchemie Gmbh & Co Kg Verfahren zur Reinigung von Abwässern aus dem Hock-Verfahren
US6080372A (en) * 1998-09-11 2000-06-27 Air Products And Chemicals, Inc. Two stage reactor for continuous three phase slurry hydrogenation and method of operation
DE19843573A1 (de) * 1998-09-23 2000-03-30 Degussa Blasensäule und deren Verwendung
JP2000128824A (ja) * 1998-10-27 2000-05-09 Mitsui Chemicals Inc 芳香族カルボン酸の製造方法
US6392091B2 (en) * 1998-11-24 2002-05-21 Tsong-Dar Vincent Lin Process of purifying and producing high purity aromatic polycarboxylic acids
IT1311976B1 (it) * 1999-03-25 2002-03-22 Franco Codignola Procedimento per la produzione di acidi aromatici.
US20020091285A1 (en) * 2001-01-10 2002-07-11 Housley Samuel Duncan Method for increasing oxidation reactor production capacity
US20010007910A1 (en) * 2000-01-12 2001-07-12 Housley Samuel D. Process for producing carboxylic acids
JP2003520263A (ja) * 2000-01-21 2003-07-02 ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド 安息香酸・水溶剤中での酸化による高純度芳香族カルボン酸の製造
JP2001247511A (ja) * 2000-03-07 2001-09-11 Mitsubishi Chemicals Corp 芳香族カルボン酸の製造方法
US6765113B2 (en) * 2000-07-19 2004-07-20 E.I. Du Pont De Nemours And Company Production of aromatic carboxylic acids
PL224046B1 (pl) * 2000-12-07 2016-11-30 Eastman Chem Co Sposób wytwarzania polimeru poliestrowego
WO2002055468A1 (en) * 2001-01-10 2002-07-18 E.I. Du Pont De Nemours And Company Improved process for producing carboxylic acids
CN2562866Y (zh) * 2002-02-01 2003-07-30 中国石油天然气股份有限公司 多级环流反应器
US7135596B2 (en) * 2002-04-23 2006-11-14 Bp Corporation North America Inc. Method of removing iron contaminants from liquid streams during the manufacture and/or purification of aromatic acids
EP1568691A4 (en) 2002-12-06 2010-08-25 Kowa Co ACCELERATOR FOR ERYTHROPOETIN PRODUCTION
CA2505976A1 (en) * 2002-12-09 2004-06-24 Eastman Chemical Company Process for the purification of a crude carboxylic acid slurry
US7161027B2 (en) * 2002-12-09 2007-01-09 Eastman Chemical Company Process for the oxidative purification of terephthalic acid
US7074954B2 (en) * 2002-12-09 2006-07-11 Eastman Chemical Company Process for the oxidative purification of terephthalic acid
US7132566B2 (en) * 2003-09-22 2006-11-07 Eastman Chemical Company Process for the purification of a crude carboxylic acid slurry
US20040133057A1 (en) * 2003-01-02 2004-07-08 Conocophillips Company Gaseous hydrocarbon-oxygen bubble tank mixer
US6825278B2 (en) * 2003-01-16 2004-11-30 Resolution Specialty Materials Llc Modified pressure sensitive adhesive
US7494641B2 (en) * 2003-06-05 2009-02-24 Eastman Chemical Company Extraction process for removal of impurities from an oxidizer purge stream in the synthesis of carboxylic acid
US7485746B2 (en) * 2003-11-14 2009-02-03 Bp Corporation North America Inc. Staged countercurrent oxidation
US7504535B2 (en) * 2004-09-02 2009-03-17 Eastman Chemical Company Optimized liquid-phase oxidation
US7615663B2 (en) * 2004-09-02 2009-11-10 Eastman Chemical Company Optimized production of aromatic dicarboxylic acids

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US20060047144A1 (en) 2006-03-02
WO2006028772A3 (en) 2006-07-27
LT1786551T (lt) 2017-04-10
CN101010132A (zh) 2007-08-01
BRPI0514759B1 (pt) 2016-03-29
US7371894B2 (en) 2008-05-13
PL1786551T3 (pl) 2017-08-31
KR20070057217A (ko) 2007-06-04
JP2008511650A (ja) 2008-04-17
CA2681849A1 (en) 2006-03-16
WO2006028772A2 (en) 2006-03-16
CA2577062A1 (en) 2006-03-16
PT1786551T (pt) 2017-01-26
KR101169490B1 (ko) 2012-07-27
ES2611152T3 (es) 2017-05-05
EP1786551B1 (en) 2016-10-19
EP1786551A2 (en) 2007-05-23
MX2007002501A (es) 2007-05-04

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