BRPI0506618B1 - processo para a produção de concentrado de polifenol de cacau - Google Patents
processo para a produção de concentrado de polifenol de cacau Download PDFInfo
- Publication number
- BRPI0506618B1 BRPI0506618B1 BRPI0506618A BRPI0506618A BRPI0506618B1 BR PI0506618 B1 BRPI0506618 B1 BR PI0506618B1 BR PI0506618 A BRPI0506618 A BR PI0506618A BR PI0506618 A BRPI0506618 A BR PI0506618A BR PI0506618 B1 BRPI0506618 B1 BR PI0506618B1
- Authority
- BR
- Brazil
- Prior art keywords
- cocoa
- process according
- polyphenol
- unfermented
- beans
- Prior art date
Links
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/0003—Processes of manufacture not relating to composition or compounding ingredients
- A23G1/002—Processes for preparing or treating cocoa beans or nibs
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/0003—Processes of manufacture not relating to composition or compounding ingredients
- A23G1/0006—Processes specially adapted for manufacture or treatment of cocoa or cocoa products
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P3/00—Drugs for disorders of the metabolism
- A61P3/02—Nutrients, e.g. vitamins, minerals
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- Health & Medical Sciences (AREA)
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Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0411556A GB2414393B (en) | 2004-05-24 | 2004-05-24 | Process for producing cocoa polyphenol concentrate |
| PCT/IB2005/001075 WO2005115160A1 (en) | 2004-05-24 | 2005-04-20 | Process for producing cocoa polyphenol concentrate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0506618A BRPI0506618A (pt) | 2007-05-02 |
| BRPI0506618B1 true BRPI0506618B1 (pt) | 2016-03-29 |
Family
ID=32607868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0506618A BRPI0506618B1 (pt) | 2004-05-24 | 2005-04-20 | processo para a produção de concentrado de polifenol de cacau |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US20070077318A1 (enExample) |
| EP (2) | EP1927288A1 (enExample) |
| JP (1) | JP5091670B2 (enExample) |
| CN (1) | CN1933736A (enExample) |
| AT (1) | ATE385177T1 (enExample) |
| AU (2) | AU2005247155B2 (enExample) |
| BR (1) | BRPI0506618B1 (enExample) |
| DE (1) | DE602005004613T2 (enExample) |
| EC (1) | ECSP066929A (enExample) |
| ES (1) | ES2300999T3 (enExample) |
| GB (1) | GB2414393B (enExample) |
| RU (1) | RU2375907C2 (enExample) |
| WO (1) | WO2005115160A1 (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7968140B2 (en) | 1997-09-08 | 2011-06-28 | Mars, Incorporated | Chocolates and chocolate liquor having an enhanced polyphenol content |
| ES2280141B1 (es) * | 2006-02-27 | 2008-10-01 | Natraceutical, S.A. | "proceso para la obtencion de polvo de cacao rico en polifenoles y bajo contenido en materia grasa y polvo de cacao obtenido". |
| US20110268846A1 (en) | 2006-03-13 | 2011-11-03 | Malathy Nair | Steeped cocoa compositions and functional cocoa beverages made from them |
| EP1998635A4 (en) | 2006-03-13 | 2013-02-06 | Hershey Co | SELECTED COCOA COMPOSITIONS AND FUNCTIONAL COCOA-DRINKS MADE THEREFROM |
| EP2071961B1 (en) * | 2006-05-25 | 2015-11-18 | Naturex | Method for obtaining cocoa extracts with a high content of polyphenols |
| ES2286947B1 (es) * | 2006-05-25 | 2008-11-01 | Natraceutical S.A. | Proceso de obtencion de extractos de cacao con elevado contenido de polifenoles. |
| WO2008000846A1 (es) * | 2006-06-19 | 2008-01-03 | Natraceutical S.A. | Método para la esterilización de materiales de cacao mediante co2 supercrítico |
| US8609174B2 (en) * | 2006-11-17 | 2013-12-17 | Barry Callebaut Ag | Method for producing a soluble cocoa product from cocoa powder |
| US8372456B2 (en) | 2006-11-17 | 2013-02-12 | Barry Callebaut Ag | Method for producing a soluble cocoa product from cocoa powder |
| PL2005835T3 (pl) * | 2007-06-15 | 2011-11-30 | Kraft Foods R & D Inc | Ziarnka kakaowe o zmniejszonej aktywności oksydazy polifenolowej i o dużej zawartości polifenoli |
| US9114114B2 (en) * | 2007-06-21 | 2015-08-25 | Mars, Inc. | Edible products having a high cocoa polyphenol content and improved flavor and the milled cocoa extracts used therein |
| GB2452972A (en) * | 2007-09-21 | 2009-03-25 | Albert Zumbe | Chocolate incorporating cryogenically milled cocoa beans |
| GB0724716D0 (en) * | 2007-12-19 | 2008-01-30 | Barry Callebaut Ag | Process |
| ATE547006T1 (de) * | 2008-03-28 | 2012-03-15 | Barry Callebaut Ag | Kakaozusammensetzung |
| US20090263518A1 (en) | 2008-04-17 | 2009-10-22 | Barry Callebaut Ag | Composition and Uses Thereof |
| DE102009040925A1 (de) | 2009-09-11 | 2011-03-31 | Teutoburger Ölmühle GmbH & Co. KG | Nutzung von geschälten Rapssamen |
| WO2013055875A1 (en) * | 2011-10-12 | 2013-04-18 | Ocean Spray Cranberries, Inc. | Xyloglucan extraction process |
| CN104219972A (zh) * | 2012-02-16 | 2014-12-17 | 株式会社鎌田 | 内置胶囊的滤嘴和具备该滤嘴的香烟及香烟替代品 |
| KR102287681B1 (ko) * | 2013-06-25 | 2021-08-11 | 올람 인터내셔널 리미티드 | 암적색 및 암갈색 천연 코코아의 제조방법 |
| RU2569151C2 (ru) * | 2013-07-30 | 2015-11-20 | Федеральное государственное бюджетное научное учреждение "Всероссийский научно-исследовательский институт сои" | Способ приготовления белковых продуктов на основе сои |
| US9682112B2 (en) | 2013-08-05 | 2017-06-20 | Akay Flavours & Aromatics PVT. LTD | Ultrasound-assisted continuous extraction for complete fragmentation of cocoa beans into fractions |
| MD4299C1 (ro) * | 2013-09-16 | 2015-03-31 | Институт Генетики И Физиологии Растений Академии Наук Молдовы | Procedeu de obţinere a compuşilor antioxidanţi din pieliţă de miez de nucă (Juglans regia L.) |
| DK3308650T3 (da) * | 2015-07-08 | 2020-11-30 | Odc Lizenz Ag | Chokolade, chokoladelignende produkter, chokoladefremstillingskit og fremgangsmåder til fremstilling af samme |
| HUE038260T2 (hu) | 2015-07-08 | 2018-10-29 | Odc Lizenz Ag | Kakaókivonatok, kakaó termékek és eljárások azok elõállítására |
| LT3114942T (lt) * | 2015-07-08 | 2018-04-25 | Odc Lizenz Ag | Kakavos produktai, pagaminti iš nefermentuotų kakavos pupelių, ir jų gavimo būdas |
| CN105341136A (zh) * | 2015-11-03 | 2016-02-24 | 安徽工程大学 | 一种含有植物提取物的天然抗氧剂及其制备方法和应用、一种猪肉糜的加工方法 |
| CN107006854A (zh) * | 2017-02-28 | 2017-08-04 | 浙江大学 | 一种可可多酚提取以及富集制备方法 |
| BR112020003732B1 (pt) * | 2017-08-24 | 2023-12-26 | Cargill, Incorporated | Método para produzir um produto alimentar e composição compreendendo um produto alimentar |
| JP7512259B2 (ja) * | 2018-09-17 | 2024-07-08 | コマス－コストルツィオニ マッチネ スペシアリ－エセ．ピ．ア． | 再構成タバコの製造のための方法およびプラント |
| IT201800020941A1 (it) * | 2018-12-21 | 2020-06-21 | Tessieri Alessio | Nanoparticelle di estratto di cacao e loro uso come antiossidanti |
| MX2022003957A (es) * | 2019-10-01 | 2022-07-21 | Meiji Co Ltd | Composicion y metodo para producir la misma. |
| IT202000005572A1 (it) * | 2020-03-16 | 2021-09-16 | Comas Costruzioni Macch Speciali S P A | Metodo di produzione di fogli omogenei di fibre vegetali prive di nicotina. |
| WO2022215734A1 (ja) * | 2021-04-07 | 2022-10-13 | 株式会社明治 | カカオ組成物を含有するグミ組成物 |
| JP7711175B2 (ja) * | 2021-04-07 | 2025-07-22 | 株式会社明治 | カカオ組成物を含有する冷凍菓子 |
| WO2022215731A1 (ja) * | 2021-04-07 | 2022-10-13 | 株式会社明治 | カカオ組成物を含有する穀粉膨化食品 |
| WO2022215732A1 (ja) * | 2021-04-07 | 2022-10-13 | 株式会社明治 | カカオ組成物を含有する焼成菓子 |
| JPWO2023182483A1 (enExample) * | 2022-03-25 | 2023-09-28 | ||
| EP4442122A1 (en) * | 2023-04-06 | 2024-10-09 | ODC Lizenz AG | Cocoa extraction methods and extracts obtained by the same |
| WO2025070403A1 (ja) * | 2023-09-25 | 2025-04-03 | 株式会社明治 | カカオ豆加工物を含む飲食品組成物およびその製造方法 |
| CO2023017111A1 (es) * | 2023-12-07 | 2024-05-30 | Compania Nac De Chocolates S A S | Composiciones de biocompuestos derivados del cacao y métodos para su producción |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2687959A (en) * | 1952-03-21 | 1954-08-31 | Krim Ko Corp | Processing of cocoa beans |
| US3294549A (en) * | 1965-02-12 | 1966-12-27 | Henry L E Vix | Partially-defatted nut meats and process |
| US4329375A (en) * | 1980-10-21 | 1982-05-11 | Nabisco Brands, Inc. | Low-fat nuts with improved natural flavor |
| JPS61100152A (ja) * | 1984-10-23 | 1986-05-19 | Anan Koryo Sangyo Kk | バナナ果肉食品の製造方法 |
| US4755391A (en) * | 1986-01-22 | 1988-07-05 | Hershey Foods Corporation | Removal of methylxanthines from cacao materials |
| US4938987A (en) * | 1989-08-31 | 1990-07-03 | Nabisco Brands, Inc. | Products and process for preparing low-fat roasted nuts |
| JPH0475569A (ja) * | 1990-05-01 | 1992-03-10 | Kanegafuchi Chem Ind Co Ltd | ヤーコン及びそれを用いた飲食品 |
| US5164217A (en) * | 1991-07-22 | 1992-11-17 | The Procter & Gamble Company | Process of making low fat nuts |
| JP2631805B2 (ja) * | 1992-03-24 | 1997-07-16 | 江崎グリコ株式会社 | 白色カカオニブの製造方法とそれを使用した食品 |
| JP3098652B2 (ja) * | 1993-04-02 | 2000-10-16 | 社団法人長野県農村工業研究所 | 冷凍ブナシメジの製造方法 |
| US5554645A (en) * | 1994-10-03 | 1996-09-10 | Mars, Incorporated | Antineoplastic cocoa extracts and methods for making and using the same |
| JP3663414B2 (ja) * | 1996-02-28 | 2005-06-22 | 秋田県 | 緑色杜仲粉末の製造方法 |
| US6261565B1 (en) * | 1996-03-13 | 2001-07-17 | Archer Daniels Midland Company | Method of preparing and using isoflavones |
| US6696485B1 (en) * | 1996-04-02 | 2004-02-24 | Mars, Incorporated | Procyanidin and cyclo-oxygenase modulator compositions |
| US6297273B1 (en) * | 1996-04-02 | 2001-10-02 | Mars, Inc. | Use of cocoa solids having high cocoa polyphenol content in tabletting compositions and capsule filling compositions |
| US6015913A (en) * | 1996-09-06 | 2000-01-18 | Mars, Incorporated | Method for producing fat and/or solids from cocoa beans |
| US6312753B1 (en) * | 1996-09-06 | 2001-11-06 | Mars, Incorporated | Cocoa components, edible products having enriched polyphenol content, methods of making same and medical uses |
| JPH1132682A (ja) * | 1997-07-17 | 1999-02-09 | Morinaga & Co Ltd | インスタントココア及びその製造法 |
| JPH11169079A (ja) * | 1997-12-15 | 1999-06-29 | Morinaga & Co Ltd | カカオマス、ココアパウダー懸濁液及びそれらの処理方法 |
| EP1061816B2 (en) * | 1998-03-12 | 2012-04-04 | Mars Incorporated | Products containing polyphenol(s) and l-arginine to stimulate nitric oxide production |
| ES2201354T3 (es) * | 1998-03-13 | 2004-03-16 | Westfalia Separator Ag | Procedimiento para la extraccion con disolventes de compuestos hidrofobos. |
| JP3892144B2 (ja) * | 1998-06-11 | 2007-03-14 | 森永製菓株式会社 | ココア組成物 |
| EP1026164A1 (en) * | 1999-02-02 | 2000-08-09 | ADM Cocoa B.V. | Process for extracting polyphenolic antioxidants from purine-containing plants |
| US6576275B1 (en) * | 1999-02-02 | 2003-06-10 | Archer-Daniels-Midland Company | Process for extracting polyphenolic antioxidants from purine-containing plants |
| US6660322B2 (en) * | 1999-12-21 | 2003-12-09 | Loretta Zapp | Method for enhancing post-processing content of beneficial compounds in foodstuffs made with cocoa beans |
| FR2812873B1 (fr) * | 2000-08-11 | 2003-08-01 | Barry Callebaut France | Procede de production de polyphenols a partir de feves de cacao |
| JP2002097187A (ja) * | 2000-09-21 | 2002-04-02 | Usaien Seiyaku Kk | ポリフェノール類の抽出方法および該方法の行程で得られるポリフェノール金属塩 |
-
2004
- 2004-05-24 GB GB0411556A patent/GB2414393B/en not_active Expired - Fee Related
-
2005
- 2005-04-20 WO PCT/IB2005/001075 patent/WO2005115160A1/en not_active Ceased
- 2005-04-20 EP EP08001412A patent/EP1927288A1/en not_active Withdrawn
- 2005-04-20 AU AU2005247155A patent/AU2005247155B2/en not_active Expired
- 2005-04-20 AT AT05718511T patent/ATE385177T1/de not_active IP Right Cessation
- 2005-04-20 CN CNA2005800083357A patent/CN1933736A/zh active Pending
- 2005-04-20 RU RU2006119430/13A patent/RU2375907C2/ru active
- 2005-04-20 US US10/582,492 patent/US20070077318A1/en not_active Abandoned
- 2005-04-20 EP EP05718511A patent/EP1748700B1/en not_active Expired - Lifetime
- 2005-04-20 DE DE602005004613T patent/DE602005004613T2/de not_active Expired - Lifetime
- 2005-04-20 ES ES05718511T patent/ES2300999T3/es not_active Expired - Lifetime
- 2005-04-20 BR BRPI0506618A patent/BRPI0506618B1/pt active IP Right Grant
- 2005-04-20 JP JP2007517474A patent/JP5091670B2/ja not_active Expired - Lifetime
-
2006
- 2006-10-16 EC EC2006006929A patent/ECSP066929A/es unknown
-
2008
- 2008-03-31 US US12/058,849 patent/US20080193629A1/en not_active Abandoned
-
2009
- 2009-12-01 AU AU2009243468A patent/AU2009243468B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB0411556D0 (en) | 2004-06-23 |
| AU2005247155A1 (en) | 2005-12-08 |
| EP1748700A1 (en) | 2007-02-07 |
| DE602005004613D1 (de) | 2008-03-20 |
| ATE385177T1 (de) | 2008-02-15 |
| US20070077318A1 (en) | 2007-04-05 |
| AU2009243468A1 (en) | 2009-12-24 |
| JP2008500380A (ja) | 2008-01-10 |
| AU2005247155B2 (en) | 2009-09-10 |
| CN1933736A (zh) | 2007-03-21 |
| WO2005115160A1 (en) | 2005-12-08 |
| ES2300999T3 (es) | 2008-06-16 |
| AU2009243468B2 (en) | 2011-10-20 |
| US20080193629A1 (en) | 2008-08-14 |
| DE602005004613T2 (de) | 2009-01-08 |
| GB2414393A (en) | 2005-11-30 |
| EP1927288A1 (en) | 2008-06-04 |
| BRPI0506618A (pt) | 2007-05-02 |
| ECSP066929A (es) | 2006-12-20 |
| GB2414393B (en) | 2008-06-11 |
| EP1748700B1 (en) | 2008-01-30 |
| RU2375907C2 (ru) | 2009-12-20 |
| RU2006119430A (ru) | 2008-02-10 |
| JP5091670B2 (ja) | 2012-12-05 |
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