BRPI0411201B1 - processo para preparar um componente catalítico - Google Patents
processo para preparar um componente catalítico Download PDFInfo
- Publication number
- BRPI0411201B1 BRPI0411201B1 BRPI0411201-6A BRPI0411201A BRPI0411201B1 BR PI0411201 B1 BRPI0411201 B1 BR PI0411201B1 BR PI0411201 A BRPI0411201 A BR PI0411201A BR PI0411201 B1 BRPI0411201 B1 BR PI0411201B1
- Authority
- BR
- Brazil
- Prior art keywords
- compound
- solid
- compounds
- fact
- catalytic component
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 68
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 51
- 150000001875 compounds Chemical class 0.000 claims abstract description 75
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 11
- 150000001298 alcohols Chemical class 0.000 claims abstract description 5
- 150000001408 amides Chemical class 0.000 claims abstract description 5
- 150000002576 ketones Chemical class 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims description 44
- 239000010936 titanium Substances 0.000 claims description 29
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 27
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 20
- 150000003609 titanium compounds Chemical class 0.000 claims description 14
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 10
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 10
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 5
- 150000004292 cyclic ethers Chemical class 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 125000005907 alkyl ester group Chemical group 0.000 claims description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 239000013067 intermediate product Substances 0.000 claims description 4
- GJRQTCIYDGXPES-UHFFFAOYSA-N isobutyl acetate Chemical compound CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 4
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 2
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims description 2
- POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 claims description 2
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims description 2
- 229940090181 propyl acetate Drugs 0.000 claims description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- -1 aliphatic ethers Chemical class 0.000 abstract description 20
- 150000002148 esters Chemical class 0.000 abstract description 7
- 150000001412 amines Chemical class 0.000 abstract description 6
- 150000002825 nitriles Chemical class 0.000 abstract description 5
- 150000002334 glycols Chemical class 0.000 abstract description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 51
- 239000003054 catalyst Substances 0.000 description 37
- 239000011777 magnesium Substances 0.000 description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 20
- 239000005977 Ethylene Substances 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 238000007334 copolymerization reaction Methods 0.000 description 18
- 238000011282 treatment Methods 0.000 description 18
- 150000002430 hydrocarbons Chemical group 0.000 description 13
- 239000007788 liquid Substances 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 150000001336 alkenes Chemical class 0.000 description 8
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 239000004711 α-olefin Substances 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 150000003377 silicon compounds Chemical class 0.000 description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical group CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910010165 TiCu Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 229920001038 ethylene copolymer Polymers 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 210000003739 neck Anatomy 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 239000012265 solid product Substances 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000002083 X-ray spectrum Methods 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007792 gaseous phase Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 150000002899 organoaluminium compounds Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- 229920001866 very low density polyethylene Polymers 0.000 description 2
- WZZBNLYBHUDSHF-DHLKQENFSA-N 1-[(3s,4s)-4-[8-(2-chloro-4-pyrimidin-2-yloxyphenyl)-7-fluoro-2-methylimidazo[4,5-c]quinolin-1-yl]-3-fluoropiperidin-1-yl]-2-hydroxyethanone Chemical compound CC1=NC2=CN=C3C=C(F)C(C=4C(=CC(OC=5N=CC=CN=5)=CC=4)Cl)=CC3=C2N1[C@H]1CCN(C(=O)CO)C[C@@H]1F WZZBNLYBHUDSHF-DHLKQENFSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003918 potentiometric titration Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- HZWYYZMKXWSBJL-UHFFFAOYSA-N tert-butyl(methoxy)silane Chemical compound CO[SiH2]C(C)(C)C HZWYYZMKXWSBJL-UHFFFAOYSA-N 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JAYPHJBLPAEMEX-UHFFFAOYSA-N trimethoxy(2-methylpentan-2-yl)silane Chemical compound CCCC(C)(C)[Si](OC)(OC)OC JAYPHJBLPAEMEX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03076697 | 2003-05-29 | ||
| EP03076697.6 | 2003-05-29 | ||
| US48296603P | 2003-06-27 | 2003-06-27 | |
| US60/482,966 | 2003-06-27 | ||
| PCT/EP2004/005186 WO2004106388A2 (en) | 2003-05-29 | 2004-05-07 | Process for the preparation of a catalyst component and components therefrom obtained |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0411201A BRPI0411201A (pt) | 2006-07-18 |
| BRPI0411201B1 true BRPI0411201B1 (pt) | 2021-01-26 |
Family
ID=33492149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0411201-6A BRPI0411201B1 (pt) | 2003-05-29 | 2004-05-07 | processo para preparar um componente catalítico |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7592286B2 (enExample) |
| EP (1) | EP1626996B1 (enExample) |
| JP (1) | JP5073291B2 (enExample) |
| KR (1) | KR101167538B1 (enExample) |
| AR (1) | AR044445A1 (enExample) |
| AU (1) | AU2004242899A1 (enExample) |
| BR (1) | BRPI0411201B1 (enExample) |
| CA (1) | CA2527357A1 (enExample) |
| MX (1) | MXPA05012830A (enExample) |
| RU (1) | RU2380380C2 (enExample) |
| SA (1) | SA04250130B1 (enExample) |
| TW (1) | TW200500386A (enExample) |
| WO (1) | WO2004106388A2 (enExample) |
Families Citing this family (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11523917B2 (en) | 2002-12-20 | 2022-12-13 | Ossur Hf | Suspension liner system with seal |
| US9877851B2 (en) | 2002-12-20 | 2018-01-30 | Ossur Hf | Adjustable seal system, seal component and method for using the same |
| US8034120B2 (en) | 2002-12-20 | 2011-10-11 | Ossur Hf | Suspension liner system with seal |
| US10322016B2 (en) | 2002-12-20 | 2019-06-18 | Ossur Iceland Ehf | Adjustable seal system, seal component and method for using the same |
| US7491781B2 (en) * | 2005-03-08 | 2009-02-17 | Ineos Usa Llc | Propylene polymer catalyst donor component |
| CN101268104B (zh) * | 2005-09-19 | 2010-11-24 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合反应的气相方法 |
| US7674943B2 (en) * | 2006-03-01 | 2010-03-09 | Ineos Usa Llc | Propylene polymer catalyst donor component |
| ATE455801T1 (de) | 2006-08-03 | 2010-02-15 | Basell Polyolefine Gmbh | Verfahren zur endbehandlung von polyolefin |
| CN102164969B (zh) * | 2008-09-26 | 2015-11-25 | 巴塞尔聚烯烃意大利有限责任公司 | 烯烃聚合的催化剂组分 |
| CN102271795A (zh) | 2008-12-29 | 2011-12-07 | 巴塞尔聚烯烃意大利有限责任公司 | 用于将催化剂供给到聚合反应器中的方法 |
| US8372159B2 (en) | 2009-01-21 | 2013-02-12 | Evolution Industries, Inc. | Sealing sheath for prosthetic liner and related methods |
| ES2472668T3 (es) | 2009-08-21 | 2014-07-02 | China Petroleum & Chemical Corporation | Componente de catalizador para la polimerizaci�n de etileno, preparación del mismo y catalizador que comprende el componente de catalizador |
| US9562119B2 (en) | 2010-05-25 | 2017-02-07 | W. R. Grace & Co.-Conn. | Ethylene polymerization catalysts |
| US20110319571A1 (en) * | 2010-06-29 | 2011-12-29 | Botros Maged G | Polyolefin adhesive composition |
| US10138310B2 (en) * | 2010-08-24 | 2018-11-27 | Equistar Chemicals, Lp | Preparation of LLDPE resins and films having low gels |
| EP2609124B1 (en) * | 2010-08-24 | 2017-09-20 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| WO2012041813A1 (en) | 2010-09-28 | 2012-04-05 | Basell Polyolefine Gmbh | Polyethylene extruded articles |
| WO2012139897A1 (en) * | 2011-04-12 | 2012-10-18 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| JP5918486B2 (ja) | 2011-07-06 | 2016-05-18 | サンアロマー株式会社 | α−オレフィン重合方法 |
| JP2014522804A (ja) * | 2011-08-08 | 2014-09-08 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 二塩化マグネシウムエタノール付加物とそれから得られる触媒成分 |
| US8956422B2 (en) | 2011-08-22 | 2015-02-17 | Ossur Hf | Suspension liner with seal component |
| US8765626B2 (en) | 2011-11-30 | 2014-07-01 | Basf Corporation | Internal donor structure for olefin polymerization catalysts and methods of making and using same |
| US8575283B1 (en) * | 2012-06-28 | 2013-11-05 | Formosa Plastics Corporation, U.S.A. | Heterocyclic organic compounds as electron donors for polyolefin catalysts |
| CN104755549B (zh) | 2012-10-22 | 2017-05-24 | 巴塞尔聚烯烃股份有限公司 | 具有高膨胀比的聚乙烯组合物 |
| EP2738211A1 (en) | 2012-11-28 | 2014-06-04 | Basell Polyolefine GmbH | Polyethylene composition having high swell ratio |
| EP2722347A1 (en) | 2012-10-22 | 2014-04-23 | Basell Polyolefine GmbH | Multistage process for the polymerization of olefins |
| EP2909265B1 (en) | 2012-10-22 | 2020-11-25 | Basell Polyolefine GmbH | Polyethylene composition having high swell ratio |
| US9458312B2 (en) * | 2012-10-22 | 2016-10-04 | Basell Polyolefine Gmbh | Polyethylene composition having high mechanical properties |
| EP2738213A1 (en) | 2012-11-28 | 2014-06-04 | Basell Polyolefine GmbH | Polyethylene composition having high swell ratio |
| EP2738212A1 (en) | 2012-11-28 | 2014-06-04 | Basell Polyolefine GmbH | Polyethylene composition having high mechanical properties |
| EP2743279A1 (en) | 2012-12-11 | 2014-06-18 | Basell Polyolefine GmbH | Process for treating polyolefin particles obtained by gas-phase polymerization |
| EP2803676A1 (en) | 2013-05-16 | 2014-11-19 | Basell Polyolefine GmbH | Process for the gas-phase polymerization of ethylene or ethylene mixtures |
| EP2818508A1 (en) * | 2013-06-25 | 2014-12-31 | Basell Polyolefine GmbH | Polyethylene composition having high impact and stress cracking resistance |
| EP2818509A1 (en) | 2013-06-25 | 2014-12-31 | Basell Polyolefine GmbH | Polyethylene composition for blow molding having high stress cracking resistance |
| US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
| US9428598B2 (en) | 2014-02-07 | 2016-08-30 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
| WO2015197453A1 (en) | 2014-06-24 | 2015-12-30 | Basell Polyolefine Gmbh | Polyethylene composition for injection moulding |
| EP3274376B1 (en) | 2015-03-26 | 2018-06-20 | Basell Polyolefine GmbH | Polymerization process in the presence of antistatic agent |
| WO2016206959A1 (en) | 2015-06-26 | 2016-12-29 | Basell Polyolefine Gmbh | Polyethylene composition having high mechanical properties and processability |
| ES2784698T3 (es) | 2015-09-11 | 2020-09-30 | Basell Poliolefine Italia Srl | Proceso para la preparación de componentes catalizadores para la polimerización de olefinas |
| US10420657B2 (en) | 2015-10-15 | 2019-09-24 | Ossur Iceland Ehf | Adjustable seal system |
| RU2729072C2 (ru) | 2015-12-21 | 2020-08-04 | Базелл Полиолефин Италия С.Р.Л. | Способ полимеризации олефина в присутствии состава с антистатическим действием |
| EP3238667B1 (de) | 2016-04-25 | 2018-10-10 | Össur Iceland EHF | Liner zum überziehen über einen gliedmassenstumpf |
| JP7164519B2 (ja) | 2016-09-29 | 2022-11-01 | ダウ グローバル テクノロジーズ エルエルシー | オレフィンを重合する方法 |
| US11155650B2 (en) | 2016-09-29 | 2021-10-26 | Dow Global Technologies Llc | Magnesium halide-supported titanium (pro)catalysts |
| BR112019005532B1 (pt) | 2016-09-29 | 2023-04-11 | Dow Global Technologies Llc | Sistema e (pró)catalisador de ziegler-natta modificado |
| US10556972B2 (en) | 2016-11-04 | 2020-02-11 | Basell Poliolefine Italia S.R.L. | Process for the polymerization of olefins |
| EP3541852B1 (en) * | 2016-11-17 | 2024-04-03 | Basell Polyolefine GmbH | Polyethylene composition having high swell ratio |
| KR102109308B1 (ko) | 2016-11-24 | 2020-05-12 | 바젤 폴리올레핀 게엠베하 | 높은 응력 균열 저항을 갖는 블로우 성형용 폴리에틸렌 조성물 |
| CA3044313C (en) * | 2016-11-24 | 2022-07-12 | Basell Polyolefine Gmbh | Polyethylene composition for blow molding having high stress cracking resistance |
| CN110072896B (zh) * | 2016-12-19 | 2021-10-26 | 巴塞尔聚烯烃意大利有限公司 | 用来聚合烯烃的催化剂组分以及由其获得的催化剂 |
| US11267907B2 (en) | 2017-09-15 | 2022-03-08 | Basell Poliolefine Italia S.R.L. | Process for the preparation of catalyst components for the polymerization of olefins |
| WO2019089876A1 (en) | 2017-11-01 | 2019-05-09 | Ossur Iceland Ehf | Prosthetic socket system |
| EP3716919B1 (en) | 2017-11-28 | 2021-11-03 | Ossur Iceland EHF | Adjustable seal systemand a seal component between a residual limb and a prosthetic socket |
| PL3728456T3 (pl) * | 2017-12-18 | 2022-12-19 | Basell Polyolefine Gmbh | Kompozycja polietylenowa mająca odporność na środowiskowe pękanie naprężeniowe |
| US11447580B2 (en) * | 2017-12-27 | 2022-09-20 | Borealis Ag | Ziegler-Natta catalyst and preparation thereof |
| CN111566131B (zh) | 2017-12-28 | 2024-04-26 | 博里利斯股份公司 | 催化剂及其制备方法 |
| EP3524343A1 (en) | 2018-02-07 | 2019-08-14 | Basell Polyolefine GmbH | Process for polymerizing olefins in the gas-phase |
| BR112021008492A2 (pt) | 2018-12-04 | 2021-08-03 | Basell Poliolefine Italia S.R.L. | processo para a preparação de um componente de catalisador sólido, componente catalisador sólido, e, catalisador sólido. |
| EP4631983A3 (en) * | 2019-10-04 | 2025-12-31 | Borealis GmbH | ZIEGLER-NATTA CATALYSTS FOR OLEFIN POLYMERIZATION |
| US12509533B2 (en) | 2019-11-20 | 2025-12-30 | Basell Poliolefine Italia S.R.L. | Process for the preparation of a catalyst component and components therefrom obtained |
| CN113621098B (zh) | 2020-05-09 | 2022-11-04 | 中国石油天然气股份有限公司 | 丙烯聚合催化剂、丙烯聚合催化剂体系及其制备与应用 |
| CN114262397B (zh) * | 2021-12-03 | 2023-06-16 | 西北师范大学 | 一种聚丙烯催化剂及其制备方法和应用 |
| KR102852527B1 (ko) * | 2022-05-27 | 2025-09-01 | 에스케이이노베이션 주식회사 | 선형 저밀도 폴리에틸렌 중합용 지글러-나타 촉매의 제조방법 |
| JPWO2024204845A1 (enExample) * | 2023-03-30 | 2024-10-03 | ||
| WO2024204844A1 (ja) * | 2023-03-31 | 2024-10-03 | 三井化学株式会社 | 固体状チタン触媒成分、オレフィン重合用触媒、オレフィンの重合方法 |
| EP4720138A1 (en) | 2023-05-31 | 2026-04-08 | Basell Poliolefine Italia S.r.l. | Process for the polymerization of olefins |
| EP4720139A1 (en) | 2023-06-01 | 2026-04-08 | Basell Poliolefine Italia S.r.l. | Process for the polymerization of olefins |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL162661B (nl) | 1968-11-21 | 1980-01-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1. |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| NL160286C (enExample) * | 1971-06-25 | |||
| GB1603724A (en) | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| JPS56149405A (en) * | 1980-04-23 | 1981-11-19 | Showa Denko Kk | Production of ethylene polymer |
| JPS56151707A (en) * | 1980-04-24 | 1981-11-24 | Showa Denko Kk | Preparation of ethylene type polymer |
| US4405495A (en) | 1980-06-30 | 1983-09-20 | Union Carbide Corporation | Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization |
| IT1151627B (it) * | 1982-06-10 | 1986-12-24 | Anic Spa | Procedimento per la preparazione di copolimeri dell'etilene con basso valore delle densita' |
| JPS59215304A (ja) * | 1983-05-24 | 1984-12-05 | Showa Denko Kk | 熱可塑性エラストマ−の製造法 |
| US4468938A (en) | 1983-09-12 | 1984-09-04 | General Electric Company | Tubless washing machine |
| FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
| IT1197320B (it) * | 1986-10-02 | 1988-11-30 | Ausimont Spa | Catalizzatori per la preparazione di copolimeri olefinici elastomerici,saturi ed insaturi,e vopolimeri con essi ottenuti |
| US5278118A (en) * | 1986-10-02 | 1994-01-11 | Ausimont, S.P.A. | Catalysts for the preparation of elastomeric olefinic copolymers |
| JPH0277409A (ja) * | 1988-09-06 | 1990-03-16 | Mitsubishi Petrochem Co Ltd | エチレン共重合体の製造法 |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| JP2879347B2 (ja) | 1989-10-02 | 1999-04-05 | チッソ株式会社 | オレフィン重合用触媒の製法 |
| JP2940684B2 (ja) * | 1989-12-29 | 1999-08-25 | 三井化学株式会社 | オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法 |
| IT1241062B (it) * | 1990-01-10 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| ATE156843T1 (de) | 1990-04-13 | 1997-08-15 | Mitsui Petrochemical Ind | Festes titan enthaltendes katalysatorbestandteil und katalysator für olefinpolymerisation, vorpolymerisierte olefinpolymerisationskatalysator und verfahren für olefinpolymerisation |
| US5726262A (en) * | 1990-04-13 | 1998-03-10 | Mitsui Petrochemical Industries, Ltd. | Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization |
| FI86866C (fi) | 1990-12-19 | 1992-10-26 | Neste Oy | Foerfarande foer modifiering av katalysatorer avsedda foer polymerisation av olefiner |
| US5767215A (en) * | 1991-05-09 | 1998-06-16 | Borealis Holding A/S | Coarse-grained polyolefin, its production method and a catalyst used in the method |
| IT1246614B (it) | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| IT1250731B (it) | 1991-07-31 | 1995-04-21 | Himont Inc | Procedimento per la preparazione di polietilene lineare a bassa densita' |
| FI90985C (fi) * | 1991-10-02 | 1994-04-25 | Neste Oy | Tehokkaan elektronidonorin sisältävä polymerointikatalyytin prokatalyyttikompositio |
| DZ1626A1 (fr) * | 1991-10-09 | 2002-02-17 | Enichem Polimeri | Catalyseurs pour la polymérisation d'oléfines. |
| IT1254279B (it) | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| US20020103302A1 (en) * | 1992-05-29 | 2002-08-01 | Giuliano Cecchin | Crystalline polymer of propylene having improved processability in the molten state and process for their preparation |
| JP3476965B2 (ja) * | 1995-05-31 | 2003-12-10 | 昭和電工株式会社 | エチレン系重合体の製造方法 |
| FI102070B1 (fi) * | 1996-03-29 | 1998-10-15 | Borealis As | Uusi kompleksiyhdiste, sen valmistus ja käyttö |
| IL127230A (en) | 1997-03-29 | 2004-07-25 | Montell Technology Company Bv | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
| KR100528310B1 (ko) * | 1998-03-23 | 2005-11-15 | 바셀 테크놀로지 캄파니 비이브이 | 올레핀 중합용 예비중합된 촉매 성분 |
| JP2002540265A (ja) | 1999-03-30 | 2002-11-26 | イーストマン ケミカル カンパニー | ポリオレフィンの製造方法 |
| JP4177937B2 (ja) * | 1999-08-18 | 2008-11-05 | 日本ポリプロ株式会社 | α−オレフィン重合用触媒および重合方法 |
| DE60232745D1 (de) * | 2001-06-26 | 2009-08-06 | Basell Poliolefine Srl | Verfahren zur Herstellung von Katalysator-Komponenten für die Olefinpolymerisation |
| CA2510679C (en) * | 2002-12-18 | 2013-04-23 | Basell Poliolefine Italia S.P.A. | Polymerization catalysts comprising titanium and magnesium |
-
2004
- 2004-05-07 KR KR1020057022812A patent/KR101167538B1/ko not_active Expired - Lifetime
- 2004-05-07 CA CA002527357A patent/CA2527357A1/en not_active Abandoned
- 2004-05-07 RU RU2005141427/04A patent/RU2380380C2/ru active
- 2004-05-07 MX MXPA05012830A patent/MXPA05012830A/es unknown
- 2004-05-07 JP JP2006529818A patent/JP5073291B2/ja not_active Expired - Lifetime
- 2004-05-07 US US10/557,933 patent/US7592286B2/en not_active Expired - Lifetime
- 2004-05-07 AU AU2004242899A patent/AU2004242899A1/en not_active Abandoned
- 2004-05-07 BR BRPI0411201-6A patent/BRPI0411201B1/pt active IP Right Grant
- 2004-05-07 WO PCT/EP2004/005186 patent/WO2004106388A2/en not_active Ceased
- 2004-05-07 EP EP04731636.9A patent/EP1626996B1/en not_active Expired - Lifetime
- 2004-05-18 TW TW093113898A patent/TW200500386A/zh unknown
- 2004-05-28 AR ARP040101839A patent/AR044445A1/es unknown
- 2004-05-29 SA SA04250130A patent/SA04250130B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR101167538B1 (ko) | 2012-07-20 |
| US7592286B2 (en) | 2009-09-22 |
| WO2004106388A2 (en) | 2004-12-09 |
| JP2006528271A (ja) | 2006-12-14 |
| EP1626996B1 (en) | 2017-04-26 |
| WO2004106388A3 (en) | 2005-05-12 |
| AU2004242899A1 (en) | 2004-12-09 |
| RU2380380C2 (ru) | 2010-01-27 |
| EP1626996A2 (en) | 2006-02-22 |
| CA2527357A1 (en) | 2004-12-09 |
| RU2005141427A (ru) | 2006-06-27 |
| BRPI0411201A (pt) | 2006-07-18 |
| SA04250130B1 (ar) | 2010-01-17 |
| TW200500386A (en) | 2005-01-01 |
| KR20060015322A (ko) | 2006-02-16 |
| AR044445A1 (es) | 2005-09-14 |
| MXPA05012830A (es) | 2006-02-13 |
| US20070021295A1 (en) | 2007-01-25 |
| JP5073291B2 (ja) | 2012-11-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101167538B1 (ko) | 촉매 성분의 제조 방법 및 그로부터 수득된 성분들 | |
| BR0316913B1 (pt) | Componente catalítico sólido para a polimerização de olefinas, catalisador para a polimerização de olefinas e processo para a | |
| JP3297120B2 (ja) | オレフィンの重合用成分及び触媒 | |
| JP3051439B2 (ja) | 多金属触媒、製造方法およびそれにより製造される重合体 | |
| SE449107B (sv) | Katalysator innefattande ett magnesium-aluminiumkomplex, forfarande for dess framstellning samt anvendning derav for olefinpolymerisation | |
| BR112015029828B1 (pt) | componente catalisador pré-polimerizado, processo para sua preparação, sistema catalisador e processo para (co)polimerização de etileno | |
| JP3168341B2 (ja) | オレフィン重合触媒及び方法 | |
| BR112019011717B1 (pt) | Componente catalisador para a polimerização de olefinas, catalisadores obtidos a partir dos mesmos e processo para a (co)polimerização de olefinas | |
| JP2010209362A (ja) | マグネシウムジクロライド−アルコール付加物の製造方法 | |
| BRPI0707016A2 (pt) | componentes catalìticos para a polimerização de olefinas | |
| WO2003106511A1 (en) | Catalyst components for the polymerization of olefins | |
| BRPI0409017B1 (pt) | Adutos de dicloreto de magnésio-álcool, componentes catalíticos obtidos a partir deles, catalisador e processo para a polimerização de olefinas | |
| KR20040095605A (ko) | 마그네슘 디클로라이드-에탄올 첨가생성물 및 그로부터수득된 촉매 성분 | |
| JPH0326706A (ja) | ポリ―１―オレフィンの製造方法 | |
| EP1539839A1 (en) | Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom | |
| JP3355819B2 (ja) | プロピレン・エチレンブロック共重合体の製造方法 | |
| ES2625904T3 (es) | Proceso para la preparación de un componente catalizador y componentes que se obtienen de este | |
| JPS5947207A (ja) | オレフイン重合用触媒 | |
| BR112014002801B1 (pt) | Produtos de adução de dicloreto-etanol magnésio, seu processo de preparação e processo para a polimerização de olefinas utilizando os referidos produtos | |
| WO1996004320A1 (en) | Catalyst system containing a solid titanium component for the stereoregulation of polyolefins | |
| JP2563235B2 (ja) | 多面体構造の塩化マグネシウム粒子と、その製造方法と、この粒子に担持された触媒成分 | |
| CN102459362B (zh) | 用于烯烃聚合的催化剂组分以及由其所获得的催化剂 | |
| ES2379381T3 (es) | Componentes de catalizador para la polimerización de olefinas | |
| CN101326201B (zh) | 用于烯烃聚合的催化剂组分 | |
| BR112015016048B1 (pt) | componentes de catalisador para a polimerização de olefinas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O E 13 DA LPI |
|
| B12B | Appeal against refusal [chapter 12.2 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 26/01/2021, OBSERVADAS AS CONDICOES LEGAIS. |