BR112018076043A2 - processo de epoxidação de alqueno tetrassubstituído e uso de agente oxidante - Google Patents

processo de epoxidação de alqueno tetrassubstituído e uso de agente oxidante

Info

Publication number
BR112018076043A2
BR112018076043A2 BR112018076043-9A BR112018076043A BR112018076043A2 BR 112018076043 A2 BR112018076043 A2 BR 112018076043A2 BR 112018076043 A BR112018076043 A BR 112018076043A BR 112018076043 A2 BR112018076043 A2 BR 112018076043A2
Authority
BR
Brazil
Prior art keywords
oxidizing agent
tetrasubstituted alkene
epoxidation process
alkene epoxidation
tetrasubstituted
Prior art date
Application number
BR112018076043-9A
Other languages
English (en)
Other versions
BR112018076043B1 (pt
Inventor
Gebhardt Joachim
Rack Michael
Wolf Bernd
BENSON Stefan
Goetz Roland
Kraus Helmut
Original Assignee
BASF Agro B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Agro B.V. filed Critical BASF Agro B.V.
Publication of BR112018076043A2 publication Critical patent/BR112018076043A2/pt
Publication of BR112018076043B1 publication Critical patent/BR112018076043B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • C07D301/16—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof formed in situ, e.g. from carboxylic acids and hydrogen peroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0086—Processes carried out with a view to control or to change the pH-value; Applications of buffer salts; Neutralisation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

a presente invenção refere-se a um processo de epoxidação de alqueno tetrassubstituído, tal como terpinoleno, no epóxido correspondente, tal como epóxido de terpinoleno, por meio de reação do alqueno tetrassubstituído com ácido perfórmico preparado in situ a partir de ácido fórmico e peróxido de hidrogênio na presença de pelo menos um agente tampão. além disso, a presente invenção refere-se ao uso de agente oxidante que compreende peróxido de hidrogênio e ácido fórmico para epoxidação in situ de alqueno tetrassubstituído.
BR112018076043-9A 2016-06-15 2017-06-01 Processo de epoxidação de alqueno tetrassubstituído e uso de agente oxidante BR112018076043B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16174601 2016-06-15
EP16174601.1 2016-06-15
PCT/EP2017/063276 WO2017215928A1 (en) 2016-06-15 2017-06-01 Process for the epoxidation of a tetrasubstituted alkene

Publications (2)

Publication Number Publication Date
BR112018076043A2 true BR112018076043A2 (pt) 2019-03-26
BR112018076043B1 BR112018076043B1 (pt) 2023-09-26

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018076043-9A BR112018076043B1 (pt) 2016-06-15 2017-06-01 Processo de epoxidação de alqueno tetrassubstituído e uso de agente oxidante

Country Status (12)

Country Link
US (1) US11072593B2 (pt)
EP (1) EP3472138B1 (pt)
KR (1) KR20190017924A (pt)
CN (1) CN109311835A (pt)
AR (1) AR108740A1 (pt)
AU (1) AU2017286055B2 (pt)
BR (1) BR112018076043B1 (pt)
DK (1) DK3472138T3 (pt)
ES (1) ES2833202T3 (pt)
IL (1) IL263518B (pt)
MX (1) MX2018015764A (pt)
WO (1) WO2017215928A1 (pt)

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CN107846891B (zh) 2015-07-10 2024-02-20 巴斯夫农业公司 包含环庚草醚和特异性色素合成抑制剂的除草组合物
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KR102642072B1 (ko) 2015-12-18 2024-02-28 바스프 아그로 비.브이. 2-[4-(4-클로로페녹시)-2-(트리플루오로메틸)페닐]-1-(1,2,4-트리아졸-1-일)프로판-2-올의 제조 방법
MX2018009453A (es) 2016-02-02 2018-09-21 Basf Se Proceso de hidrogenacion catalitico para preparar pirazoles.
MX2018010305A (es) 2016-02-26 2019-05-20 Basf Agro Bv Proceso para preparar terpinen-4-ol.
ES2787895T3 (es) 2016-02-26 2020-10-19 Basf Agro Bv Procedimiento para la preparación de una mezcla de alcoholes de terpeno
KR20190017926A (ko) 2016-06-15 2019-02-20 바스프 아그로 비.브이. 사치환된 알켄의 에폭시화 방법
ES2833202T3 (es) 2016-06-15 2021-06-14 Basf Agro Bv Procedimiento para la epoxidación de un alqueno tetrasustituido

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AU2017286055B2 (en) 2021-07-01
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DK3472138T3 (da) 2020-11-23
EP3472138B1 (en) 2020-08-26
IL263518A (en) 2019-01-31
IL263518B (en) 2021-03-25
ES2833202T3 (es) 2021-06-14
EP3472138A1 (en) 2019-04-24
MX2018015764A (es) 2019-08-29
US20200308125A1 (en) 2020-10-01
AU2017286055A1 (en) 2019-01-03
KR20190017924A (ko) 2019-02-20
AR108740A1 (es) 2018-09-19
CN109311835A (zh) 2019-02-05

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