BR112015023277A2 - catalisador e processo para oxicloração de etileno para dicloroetano - Google Patents

catalisador e processo para oxicloração de etileno para dicloroetano

Info

Publication number
BR112015023277A2
BR112015023277A2 BR112015023277A BR112015023277A BR112015023277A2 BR 112015023277 A2 BR112015023277 A2 BR 112015023277A2 BR 112015023277 A BR112015023277 A BR 112015023277A BR 112015023277 A BR112015023277 A BR 112015023277A BR 112015023277 A2 BR112015023277 A2 BR 112015023277A2
Authority
BR
Brazil
Prior art keywords
catalyst
dichloroethane
aqueous solution
ethylene
oxychlorination
Prior art date
Application number
BR112015023277A
Other languages
English (en)
Other versions
BR112015023277B1 (pt
Inventor
Kramer Keith
Original Assignee
Oxy Vinyls Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxy Vinyls Lp filed Critical Oxy Vinyls Lp
Publication of BR112015023277A2 publication Critical patent/BR112015023277A2/pt
Publication of BR112015023277B1 publication Critical patent/BR112015023277B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
    • C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

resumo “catalisador e processo para oxicloração de etileno para dicloroetano” em um processo de oxicloração do tipo em que o etileno é convertido a 1,2-dicloroetano na presença de um catalisador de cobre fixado, a melhoria compreende: o uso de um catalisador de cobre fixado preparado por (i) impregnação, em uma primeira etapa, um suporte de alumina com uma primeira solução aquosa incluindo cobre, um metal alcalino-terroso, e um metal alcalino para deste modo formar, um primeiro componente de catalisador; e (ii) pela impregnação, em uma etapa subsequente, do primeiro componente do catalisador com uma segunda solução aquosa incluindo cobre e metal alcalino-terroso em que a segunda solução aquosa é substancialmente desprovida de metal alcalino, para deste modo, formar o catalisador fixado. 1/ 1
BR112015023277-9A 2013-03-15 2014-03-17 Processo de síntese de um catalisador para oxicloração de etileno BR112015023277B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361798872P 2013-03-15 2013-03-15
US61/798,872 2013-03-15
PCT/US2014/030233 WO2014145463A2 (en) 2013-03-15 2014-03-17 Catalyst and process for oxychlorination of ethylene to dichloroethane

Publications (2)

Publication Number Publication Date
BR112015023277A2 true BR112015023277A2 (pt) 2017-07-18
BR112015023277B1 BR112015023277B1 (pt) 2021-06-01

Family

ID=50686179

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015023277-9A BR112015023277B1 (pt) 2013-03-15 2014-03-17 Processo de síntese de um catalisador para oxicloração de etileno

Country Status (10)

Country Link
US (3) US9073046B2 (pt)
EP (1) EP2969192A2 (pt)
JP (2) JP6509807B2 (pt)
KR (1) KR102183954B1 (pt)
CN (1) CN105073255B (pt)
BR (1) BR112015023277B1 (pt)
MX (1) MX2015009957A (pt)
MY (1) MY187937A (pt)
RU (1) RU2664116C2 (pt)
WO (1) WO2014145463A2 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6509807B2 (ja) * 2013-03-15 2019-05-08 オキシ ヴィニールズ，エルピー ジクロロエタンへのエチレンのオキシ塩素化のための触媒及びプロセス
CN106588559B (zh) * 2016-12-14 2020-06-05 厦门中科易工化学科技有限公司 一种用于制备1,2-二氯乙烷的乙烯氯化剂及其用途和1,2-二氯乙烷的制备方法
EP3721993B1 (en) * 2018-02-23 2022-06-15 Lg Chem, Ltd. Catalyst for processing oxychlorination of hydrocarbon, preparation method therefor, and preparation method of oxychlorinated compound of hydrocarbon using same
WO2023141486A1 (en) 2022-01-19 2023-07-27 Oxy Vinyls, Lp Oxychlorination process

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2125748A5 (pt) * 1971-02-19 1972-09-29 Pechiney Saint Gobain
GB8829706D0 (en) * 1988-12-20 1989-02-15 Ici Plc Oxychlorination catalyst composition
US5260247A (en) * 1991-01-11 1993-11-09 Solvay (Societe Anonyme) Catalytic composition for oxychlorination and process for the oxychlorination of ethylene using such a composition
US5292703A (en) * 1992-07-28 1994-03-08 The Geon Company Catalyst and process for oxychlorination of ethylene to EDC
TWI255736B (en) * 2002-02-05 2006-06-01 Basf Ag A catalyst composition for the oxychlorination of ethylene and its use
ITMI20030630A1 (it) * 2003-03-31 2004-10-01 Sued Chemie Mt Srl Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano.
ITMI20042317A1 (it) 2004-12-02 2005-03-02 Sued Chemie Mt Srl Catalizzatori per l'ossiclorurazione dell'etilene a 1,2-dicloroetano
CN101175567B (zh) * 2005-05-12 2011-06-08 索维公司 氧氯化催化剂和使用这种催化剂的方法
JP5256036B2 (ja) * 2005-08-18 2013-08-07 アルベマール・ネーザーランズ・ベー・ブイ 接触的オキシ塩素化
TWI341218B (en) 2005-11-14 2011-05-01 Oxy Vinyls Lp Catalyst compositions and process for oxychlorination
EP2070898B1 (de) 2007-12-03 2013-02-20 Basf Se Katalysator zur Oxichlorierung
US9248434B2 (en) * 2012-11-06 2016-02-02 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane
JP6509807B2 (ja) * 2013-03-15 2019-05-08 オキシ ヴィニールズ，エルピー ジクロロエタンへのエチレンのオキシ塩素化のための触媒及びプロセス

Also Published As

Publication number Publication date
US10981150B2 (en) 2021-04-20
CN105073255B (zh) 2017-12-12
CN105073255A (zh) 2015-11-18
EP2969192A2 (en) 2016-01-20
RU2664116C2 (ru) 2018-08-15
JP2016518968A (ja) 2016-06-30
BR112015023277B1 (pt) 2021-06-01
US20160023191A1 (en) 2016-01-28
US9073046B2 (en) 2015-07-07
WO2014145463A3 (en) 2014-12-04
KR20150131139A (ko) 2015-11-24
MY187937A (en) 2021-10-29
RU2015140998A (ru) 2017-04-24
US20210237038A1 (en) 2021-08-05
JP6509807B2 (ja) 2019-05-08
US20140275661A1 (en) 2014-09-18
KR102183954B1 (ko) 2020-11-30
JP2019122959A (ja) 2019-07-25
WO2014145463A2 (en) 2014-09-18
MX2015009957A (es) 2015-10-29

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/03/2014, OBSERVADAS AS CONDICOES LEGAIS.