BR112013013010A2 - borracha de cloropreno modificada com enxofre, moldagem, e, método para produzir a borracha de cloropreno modificada com enxofre. - Google Patents

borracha de cloropreno modificada com enxofre, moldagem, e, método para produzir a borracha de cloropreno modificada com enxofre.

Info

Publication number
BR112013013010A2
BR112013013010A2 BR112013013010A BR112013013010A BR112013013010A2 BR 112013013010 A2 BR112013013010 A2 BR 112013013010A2 BR 112013013010 A BR112013013010 A BR 112013013010A BR 112013013010 A BR112013013010 A BR 112013013010A BR 112013013010 A2 BR112013013010 A2 BR 112013013010A2
Authority
BR
Brazil
Prior art keywords
chloroprene rubber
modified chloroprene
sulfur modified
ppm
molding
Prior art date
Application number
BR112013013010A
Other languages
English (en)
Other versions
BR112013013010B1 (pt
Inventor
Motohiro Ose
Naoki Kobayashi
Ryochi Suzuki
Yasushi Abe
Original Assignee
Denki Kagaku Kogyo Kk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denki Kagaku Kogyo Kk filed Critical Denki Kagaku Kogyo Kk
Publication of BR112013013010A2 publication Critical patent/BR112013013010A2/pt
Publication of BR112013013010B1 publication Critical patent/BR112013013010B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/20—Incorporating sulfur atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/08—Depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/22—Incorporating nitrogen atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/26—Incorporating metal atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/14—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen
    • C08F136/16—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen
    • C08F136/18—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen containing chlorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/14—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen
    • C08F236/16—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen
    • C08F236/18—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen containing chlorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16F—SPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
    • F16F1/00—Springs
    • F16F1/36—Springs made of rubber or other material having high internal friction, e.g. thermoplastic elastomers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16F—SPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
    • F16F15/00—Suppression of vibrations in systems; Means or arrangements for avoiding or reducing out-of-balance forces, e.g. due to motion
    • F16F15/02—Suppression of vibrations of non-rotating, e.g. reciprocating systems; Suppression of vibrations of rotating systems by use of members not moving with the rotating systems
    • F16F15/04—Suppression of vibrations of non-rotating, e.g. reciprocating systems; Suppression of vibrations of rotating systems by use of members not moving with the rotating systems using elastic means
    • F16F15/08—Suppression of vibrations of non-rotating, e.g. reciprocating systems; Suppression of vibrations of rotating systems by use of members not moving with the rotating systems using elastic means with rubber springs ; with springs made of rubber and metal
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G1/00—Driving-belts
    • F16G1/06—Driving-belts made of rubber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G5/00—V-belts, i.e. belts of tapered cross-section
    • F16G5/04—V-belts, i.e. belts of tapered cross-section made of rubber

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Aviation & Aerospace Engineering (AREA)
  • Acoustics & Sound (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

borracha de cloropreno modificada com enxofre, moldagem, e, método para produzir a borracha de cloropreno modificada com enxofre. são fornecidos uma borracha de cloropreno modificada com enxofre com propriedades geradoras de calor reduzidas, uma sua moldagem, e um método de produção das mesmas. é obtida uma borracha de cloropreno modificada com enxofre na qual: as extremidades do polímero estão modificadas por pelo menos um tipo de composto selecionado de dissulfeto de tetrametil-tiuram, dissulfetos de tetraaquil-tiuram tendo grupos c~ 2~ - ~ 7~ alquila, e ditiocarbamatos de dialquila tendo grupos c~ 1~ - ~ 7~ alquila; o espectro de ^ 1^h-rmn medido em um solvente clorofórmio deuterado tem topos de pico a 3,55-3,61 ppm e a 3,41 - 3,47 ppm e a razão (a/b) entre a área de pico (a) a 3,55-3,61 ppm e a área de pico (b) a 4,2-6,5 ppm é de 0,05/100-0,50/100; e a quantidade extraída por uma mistura azetrópica de etanol/tolueno conforme fornecida por jis k 6229 é de 3,0-9,0% em massa.
BR112013013010-5A 2010-11-26 2011-10-25 borracha de cloropreno modificada com enxofre, artigo moldado, e, método para produzir a borracha de cloropreno modificada com enxofre BR112013013010B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2010263150 2010-11-26
JP2010263150 2010-11-26
PCT/JP2011/074507 WO2012070347A1 (ja) 2010-11-26 2011-10-25 硫黄変性クロロプレンゴム及びその成形体、並びにその製造方法

Publications (2)

Publication Number Publication Date
BR112013013010A2 true BR112013013010A2 (pt) 2016-08-09
BR112013013010B1 BR112013013010B1 (pt) 2020-10-13

Family

ID=46145704

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013013010-5A BR112013013010B1 (pt) 2010-11-26 2011-10-25 borracha de cloropreno modificada com enxofre, artigo moldado, e, método para produzir a borracha de cloropreno modificada com enxofre

Country Status (10)

Country Link
US (1) US9328175B2 (pt)
EP (1) EP2644625B1 (pt)
JP (1) JP5843266B2 (pt)
KR (1) KR101802169B1 (pt)
CN (1) CN103228679B (pt)
BR (1) BR112013013010B1 (pt)
PL (1) PL2644625T3 (pt)
RU (1) RU2577834C2 (pt)
TW (1) TWI525104B (pt)
WO (1) WO2012070347A1 (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013144748A (ja) * 2012-01-13 2013-07-25 Denki Kagaku Kogyo Kk 硫黄変性クロロプレンゴム及びその製造方法、並びに成形体
JP5485342B2 (ja) * 2012-07-25 2014-05-07 電気化学工業株式会社 クロロプレンゴム、その製造方法及びクロロプレンゴム組成物並びにその加硫物
CN104403039B (zh) * 2014-11-07 2017-11-28 山纳合成橡胶有限责任公司 一种胶乳门尼粘度稳定性高的硫调型氯丁橡胶的制备方法
JP7289266B2 (ja) * 2017-11-24 2023-06-09 デンカ株式会社 硫黄変性クロロプレンゴム組成物及び加硫物、並びに該加硫物を用いた成形品及び硫黄変性クロロプレンゴム組成物の製造方法
US11993671B2 (en) 2018-11-09 2024-05-28 Denka Company Limited Chloroprene/unsaturated nitrile copolymer, chloroprene/unsaturated nitrile copolymer composition and vulcanized molded article
EP3889188B1 (en) * 2019-03-20 2022-08-03 Denka Company Limited Sulfur-modified chloroprene rubber, method for producing same, sulfur-modified chloroprene rubber composition, vulcanized product and molded article
JP7336221B2 (ja) * 2019-03-20 2023-08-31 デンカ株式会社 硫黄変性クロロプレンゴム、加硫物及び該加硫物を用いた成形品並びに硫黄変性クロロプレンゴムの製造方法
WO2022130702A1 (ja) * 2020-12-14 2022-06-23 デンカ株式会社 ゴム材料、ゴム組成物、加硫物、発泡体、及び、ウェットスーツ
WO2023190144A1 (ja) * 2022-03-31 2023-10-05 デンカ株式会社 クロロプレン系重合体及び浸漬成形物

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US3507825A (en) * 1967-08-24 1970-04-21 Du Pont Chloroprene-sulfur copolymers having improved flex resistance through use of organic sulfides
US4124754A (en) * 1976-12-14 1978-11-07 E. I. Du Pont De Nemours And Company Polymerization process with subsequent peptization
RU2075487C1 (ru) * 1989-10-31 1997-03-20 Е.И.Дюпон Де Немур Энд Компани Способ получения эластомера
JP3480003B2 (ja) 1993-08-25 2003-12-15 東ソー株式会社 硫黄変性クロロプレン重合体の製造方法
JP3411127B2 (ja) * 1995-06-22 2003-05-26 電気化学工業株式会社 硫黄変性クロロプレン重合体の製造方法
JP3603473B2 (ja) 1996-01-31 2004-12-22 日本ゼオン株式会社 低発熱性ゴム組成物およびロール
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JPH11116622A (ja) 1997-10-15 1999-04-27 Showa Dde Seizo Kk 硫黄変性クロロプレン重合体の製造方法
JP4485017B2 (ja) * 2000-06-01 2010-06-16 電気化学工業株式会社 クロロプレン系ゴム組成物
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Also Published As

Publication number Publication date
WO2012070347A1 (ja) 2012-05-31
JPWO2012070347A1 (ja) 2014-05-19
KR101802169B1 (ko) 2017-11-28
TWI525104B (zh) 2016-03-11
TW201223966A (en) 2012-06-16
CN103228679B (zh) 2015-09-02
EP2644625B1 (en) 2017-05-31
EP2644625A1 (en) 2013-10-02
PL2644625T3 (pl) 2017-10-31
JP5843266B2 (ja) 2016-01-13
RU2013128965A (ru) 2015-01-10
KR20130133796A (ko) 2013-12-09
RU2577834C2 (ru) 2016-03-20
US9328175B2 (en) 2016-05-03
CN103228679A (zh) 2013-07-31
BR112013013010B1 (pt) 2020-10-13
US20130245202A1 (en) 2013-09-19
EP2644625A4 (en) 2015-02-11

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B25D Requested change of name of applicant approved

Owner name: DENKA COMPANY LIMITED (JP)

B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 25/10/2011, OBSERVADAS AS CONDICOES LEGAIS.