BR112012031330B1 - catalisador armazenador de óxido de nitrogênio, sistema de tratamento para uma corrente de gás de escape de automóvel, e, método para o tratamento de gás de escape de motor de automóvel - Google Patents
catalisador armazenador de óxido de nitrogênio, sistema de tratamento para uma corrente de gás de escape de automóvel, e, método para o tratamento de gás de escape de motor de automóvel Download PDFInfo
- Publication number
- BR112012031330B1 BR112012031330B1 BR112012031330-4A BR112012031330A BR112012031330B1 BR 112012031330 B1 BR112012031330 B1 BR 112012031330B1 BR 112012031330 A BR112012031330 A BR 112012031330A BR 112012031330 B1 BR112012031330 B1 BR 112012031330B1
- Authority
- BR
- Brazil
- Prior art keywords
- nitrogen oxide
- reactive coating
- storage catalyst
- exhaust gas
- oxide storage
- Prior art date
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- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims abstract description 303
- 239000003054 catalyst Substances 0.000 title claims abstract description 112
- 239000007789 gas Substances 0.000 title claims abstract description 70
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 93
- 239000011247 coating layer Substances 0.000 claims abstract description 69
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 68
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 68
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 59
- 238000006243 chemical reaction Methods 0.000 claims abstract description 59
- 239000000758 substrate Substances 0.000 claims abstract description 57
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- 239000011232 storage material Substances 0.000 claims abstract description 16
- 238000010531 catalytic reduction reaction Methods 0.000 claims abstract description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 89
- 239000010410 layer Substances 0.000 claims description 89
- 238000000576 coating method Methods 0.000 claims description 80
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 80
- 239000011248 coating agent Substances 0.000 claims description 79
- 229910044991 metal oxide Inorganic materials 0.000 claims description 45
- 150000004706 metal oxides Chemical class 0.000 claims description 45
- 229910052751 metal Inorganic materials 0.000 claims description 44
- 239000002184 metal Substances 0.000 claims description 44
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 39
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 39
- 239000002245 particle Substances 0.000 claims description 39
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 27
- 239000010457 zeolite Substances 0.000 claims description 23
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 20
- 229910021536 Zeolite Inorganic materials 0.000 claims description 19
- 229910052697 platinum Inorganic materials 0.000 claims description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 238000002485 combustion reaction Methods 0.000 claims description 14
- 230000000052 comparative effect Effects 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 229910052788 barium Inorganic materials 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229910052763 palladium Inorganic materials 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 8
- 229910052703 rhodium Inorganic materials 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052741 iridium Inorganic materials 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 150000002909 rare earth metal compounds Chemical class 0.000 claims description 4
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 238000004891 communication Methods 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 2
- 150000001339 alkali metal compounds Chemical class 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 229910052792 caesium Inorganic materials 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 150000002736 metal compounds Chemical class 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 229910052701 rubidium Inorganic materials 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 32
- 239000010948 rhodium Substances 0.000 description 27
- 238000011068 loading method Methods 0.000 description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 18
- 230000003197 catalytic effect Effects 0.000 description 16
- 150000002739 metals Chemical class 0.000 description 15
- 239000000377 silicon dioxide Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 239000004071 soot Substances 0.000 description 9
- 229910002091 carbon monoxide Inorganic materials 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 7
- 230000001771 impaired effect Effects 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 239000000395 magnesium oxide Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- -1 preferably Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
- 239000003870 refractory metal Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- 229910052845 zircon Inorganic materials 0.000 description 3
- 229910000505 Al2TiO5 Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000003832 Lantana Species 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052878 cordierite Inorganic materials 0.000 description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 239000010944 silver (metal) Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 241000269350 Anura Species 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
- HEHRHMRHPUNLIR-UHFFFAOYSA-N aluminum;hydroxy-[hydroxy(oxo)silyl]oxy-oxosilane;lithium Chemical compound [Li].[Al].O[Si](=O)O[Si](O)=O.O[Si](=O)O[Si](O)=O HEHRHMRHPUNLIR-UHFFFAOYSA-N 0.000 description 1
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 1
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 229910052676 chabazite Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910001603 clinoptilolite Inorganic materials 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 230000018537 nitric oxide storage Effects 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229910052670 petalite Inorganic materials 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9422—Processes characterised by a specific catalyst for removing nitrogen oxides by NOx storage or reduction by cyclic switching between lean and rich exhaust gases (LNT, NSC, NSR)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D2255/10—Noble metals or compounds thereof
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- B01D2255/1021—Platinum
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2255/2042—Barium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2255/20—Metals or compounds thereof
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- B01D2255/2065—Cerium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D2255/20—Metals or compounds thereof
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- B01D2255/20715—Zirconium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D2255/209—Other metals
- B01D2255/2092—Aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
- B01D2255/502—Beta zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/902—Multilayered catalyst
- B01D2255/9022—Two layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/902—Multilayered catalyst
- B01D2255/9025—Three layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/908—O2-storage component incorporated in the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/91—NOx-storage component incorporated in the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/912—HC-storage component incorporated in the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
- B01D2258/012—Diesel engines and lean burn gasoline engines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7415—Zeolite Beta
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- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10165484 | 2010-06-10 | ||
| EP10165484.6 | 2010-06-10 | ||
| PCT/IB2011/052512 WO2011154913A1 (en) | 2010-06-10 | 2011-06-09 | Nox storage catalyst with improved hydrocarbon conversion activity |
Publications (2)
| Publication Number | Publication Date |
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| BR112012031330A2 BR112012031330A2 (pt) | 2016-10-25 |
| BR112012031330B1 true BR112012031330B1 (pt) | 2018-12-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| BR112012031330-4A BR112012031330B1 (pt) | 2010-06-10 | 2011-06-09 | catalisador armazenador de óxido de nitrogênio, sistema de tratamento para uma corrente de gás de escape de automóvel, e, método para o tratamento de gás de escape de motor de automóvel |
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| Country | Link |
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| JP (1) | JP5937579B2 (https=) |
| KR (1) | KR101846593B1 (https=) |
| CN (1) | CN103052444B (https=) |
| BR (1) | BR112012031330B1 (https=) |
| WO (1) | WO2011154913A1 (https=) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201021649D0 (en) * | 2010-12-21 | 2011-02-02 | Johnson Matthey Plc | NOx Absorber catalyst |
| CN104203404B (zh) * | 2012-04-06 | 2017-05-31 | 巴斯夫公司 | 具有碳氢化合物储存功能的稀燃NOx捕集器柴油机氧化催化剂 |
| GB201220912D0 (en) * | 2012-11-21 | 2013-01-02 | Johnson Matthey Plc | Oxidation catalyst for treating the exhaust gas of a compression ignition engine |
| EP2769760A1 (de) * | 2013-02-21 | 2014-08-27 | Umicore AG & Co. KG | Katalysator zur Reduktion von Stickoxiden |
| WO2014164732A1 (en) * | 2013-03-12 | 2014-10-09 | Basf Corporation | Catalyst materials for no oxidation |
| US9034287B2 (en) * | 2013-03-13 | 2015-05-19 | Basf Corporation | Catalyst compositions, articles, methods and systems |
| GB2514177A (en) * | 2013-05-17 | 2014-11-19 | Johnson Matthey Plc | Oxidation catalyst for a compression ignition engine |
| JP5994730B2 (ja) * | 2013-05-27 | 2016-09-21 | マツダ株式会社 | 排気ガス浄化用触媒の製造方法 |
| JP5949662B2 (ja) * | 2013-05-27 | 2016-07-13 | マツダ株式会社 | 排気ガス浄化用触媒及びその製造方法 |
| JP6236995B2 (ja) * | 2013-08-28 | 2017-11-29 | マツダ株式会社 | 排気ガス浄化用触媒及びその製造方法並びにそれを用いた排気ガス浄化方法 |
| CN105683518B (zh) * | 2013-09-16 | 2019-10-18 | 庄信万丰股份有限公司 | 具有改性贫燃NOx阱的排气系统和方法 |
| CN104667914A (zh) * | 2013-11-29 | 2015-06-03 | 陈社云 | 一种柴油机尾气脱硝催化剂及其制备方法 |
| EP3485964B1 (en) * | 2013-12-06 | 2022-09-21 | Johnson Matthey Public Limited Company | Cold start catalyst and its use in exhaust systems |
| EP2985068A1 (de) * | 2014-08-13 | 2016-02-17 | Umicore AG & Co. KG | Katalysator-System zur Reduktion von Stickoxiden |
| WO2016130456A1 (en) | 2015-02-09 | 2016-08-18 | Basf Corporation | Diesel oxidation catalyst |
| US10226754B2 (en) | 2015-03-03 | 2019-03-12 | Basf Corporation | Lean NOx trap with enhanced high and low temperature performance |
| WO2017003981A1 (en) | 2015-06-29 | 2017-01-05 | Corning Incorporated | Porous ceramic body to reduce emissions |
| GB2546164A (en) * | 2015-09-30 | 2017-07-12 | Johnson Matthey Plc | Gasoline particulate filter |
| KR102429131B1 (ko) | 2016-06-10 | 2022-08-05 | 존슨 맛쎄이 퍼블릭 리미티드 컴파니 | NOx 흡착제 촉매 |
| JP6912468B2 (ja) * | 2016-06-23 | 2021-08-04 | エヌ・イーケムキャット株式会社 | リーンバーン用触媒 |
| GB2557673A (en) * | 2016-12-15 | 2018-06-27 | Johnson Matthey Plc | NOx adsorber catalyst |
| GB2560941A (en) * | 2017-03-29 | 2018-10-03 | Johnson Matthey Plc | NOx Adsorber catalyst |
| GB2560939A (en) * | 2017-03-29 | 2018-10-03 | Johnson Matthey Plc | NOx Adsorber catalyst |
| GB2560944A (en) * | 2017-03-29 | 2018-10-03 | Johnson Matthey Plc | NOx adsorber catalyst |
| GB2560940A (en) * | 2017-03-29 | 2018-10-03 | Johnson Matthey Plc | Three layer NOx Adsorber catalyst |
| GB2560942A (en) * | 2017-03-29 | 2018-10-03 | Johnson Matthey Plc | NOx Adsorber catalyst |
| WO2019116268A1 (en) * | 2017-12-13 | 2019-06-20 | Johnson Matthey Public Limited Company | Improved nh3 abatement with greater selectivity to n2 |
| US10850264B2 (en) * | 2018-05-18 | 2020-12-01 | Umicore Ag & Co. Kg | Hydrocarbon trap catalyst |
| JP7777727B2 (ja) * | 2018-06-12 | 2025-12-01 | ビーエーエスエフ コーポレーション | 燃料カットＮＯｘ制御用ＴＷＣシステム |
| EP3623047B1 (de) | 2018-09-17 | 2021-02-24 | Umicore Ag & Co. Kg | Katalysator zur reduktion von stickoxiden |
| JPWO2020149313A1 (ja) * | 2019-01-15 | 2021-12-02 | 日立造船株式会社 | 排ガス浄化用触媒 |
| EP3695902B1 (de) | 2019-02-18 | 2021-09-01 | Umicore Ag & Co. Kg | Katalysator zur reduktion von stickoxiden |
| EP3824988B1 (en) * | 2019-11-20 | 2025-03-05 | Umicore AG & Co. KG | Catalyst for reducing nitrogen oxides |
| EP4302862A1 (en) * | 2022-07-06 | 2024-01-10 | Johnson Matthey Public Limited Company | Lean nox trap |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2577258A (en) * | 1946-06-13 | 1951-12-04 | Ohio Commw Eng Co | Alternating-current welder |
| US5024981A (en) | 1989-04-20 | 1991-06-18 | Engelhard Corporation | Staged metal-promoted zeolite catalysts and method for catalytic reduction of nitrogen oxides using the same |
| US4961917A (en) | 1989-04-20 | 1990-10-09 | Engelhard Corporation | Method for reduction of nitrogen oxides with ammonia using promoted zeolite catalysts |
| JPH0910594A (ja) * | 1995-04-28 | 1997-01-14 | Mazda Motor Corp | 排気ガス浄化用触媒 |
| JP3799651B2 (ja) * | 1995-04-28 | 2006-07-19 | マツダ株式会社 | 排気ガス浄化用触媒 |
| JPH10165819A (ja) * | 1996-12-12 | 1998-06-23 | Nissan Motor Co Ltd | 排気ガス浄化用触媒及びその使用方法 |
| GB9713428D0 (en) * | 1997-06-26 | 1997-08-27 | Johnson Matthey Plc | Improvements in emissions control |
| EP0935055B1 (en) | 1998-02-05 | 2006-01-11 | Nissan Motor Company, Limited | Method for purifying oxygen rich exhaust gas |
| JPH11226415A (ja) | 1998-02-19 | 1999-08-24 | Nissan Motor Co Ltd | 排気ガス浄化用触媒及び排気ガス浄化方法 |
| JPH11300211A (ja) | 1998-04-24 | 1999-11-02 | Nissan Motor Co Ltd | 排気ガス浄化用触媒及び排気ガス浄化方法 |
| DE19854794A1 (de) * | 1998-11-27 | 2000-05-31 | Degussa | Katalysator für die Reinigung der Abgase eines Dieselmotors |
| US7022646B2 (en) * | 2003-01-31 | 2006-04-04 | Engelhard Corporation | Layered catalyst composite |
| JP2005169203A (ja) | 2003-12-09 | 2005-06-30 | Nissan Motor Co Ltd | 排気ガス浄化触媒及びその製造方法 |
| JP2005205302A (ja) * | 2004-01-22 | 2005-08-04 | Hitachi Ltd | 内燃機関用排ガス浄化触媒および排ガス浄化装置 |
| US7795172B2 (en) * | 2004-06-22 | 2010-09-14 | Basf Corporation | Layered exhaust treatment catalyst |
| JP2008100152A (ja) * | 2006-10-18 | 2008-05-01 | Cataler Corp | 排ガス浄化用触媒 |
| EP2307122B1 (en) * | 2008-07-31 | 2014-09-17 | Basf Se | Nox storage materials and traps resistant to thermal aging |
| GB2479807B (en) * | 2010-02-01 | 2012-12-05 | Johnson Matthey Plc | Three way catalyst comprising extruded solid body |
-
2011
- 2011-06-09 EP EP18176505.8A patent/EP3403722A1/en active Pending
- 2011-06-09 KR KR1020137000558A patent/KR101846593B1/ko active Active
- 2011-06-09 WO PCT/IB2011/052512 patent/WO2011154913A1/en not_active Ceased
- 2011-06-09 JP JP2013513802A patent/JP5937579B2/ja active Active
- 2011-06-09 CN CN201180038737.7A patent/CN103052444B/zh active Active
- 2011-06-09 EP EP11792037.1A patent/EP2579985A4/en not_active Ceased
- 2011-06-09 BR BR112012031330-4A patent/BR112012031330B1/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130109093A (ko) | 2013-10-07 |
| JP2013528119A (ja) | 2013-07-08 |
| KR101846593B1 (ko) | 2018-04-06 |
| EP2579985A1 (en) | 2013-04-17 |
| JP5937579B2 (ja) | 2016-06-22 |
| EP3403722A1 (en) | 2018-11-21 |
| CN103052444A (zh) | 2013-04-17 |
| BR112012031330A2 (pt) | 2016-10-25 |
| WO2011154913A1 (en) | 2011-12-15 |
| EP2579985A4 (en) | 2015-01-21 |
| CN103052444B (zh) | 2016-05-11 |
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