BR0012774A - Processo para preparação de poliamida, e, poliamida. - Google Patents

Processo para preparação de poliamida, e, poliamida.

Info

Publication number
BR0012774A
BR0012774A BR0012774-4A BR0012774A BR0012774A BR 0012774 A BR0012774 A BR 0012774A BR 0012774 A BR0012774 A BR 0012774A BR 0012774 A BR0012774 A BR 0012774A
Authority
BR
Brazil
Prior art keywords
polyamide
dinitrile
diamine
oxides
preparing
Prior art date
Application number
BR0012774-4A
Other languages
English (en)
Other versions
BR0012774B1 (pt
Inventor
Frank Ohlbach
Hermann Luyken
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BR0012774A publication Critical patent/BR0012774A/pt
Publication of BR0012774B1 publication Critical patent/BR0012774B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/04Preparatory processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/28Preparatory processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/38Polyamides prepared from aldehydes and polynitriles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyamides (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO PARA PREPARAçãO DE POLIAMIDA, E, POLIAMIDA". Processo para produzir poliamidas a partir de dinitrilas e diaminas pela reação de pelo menos uma dinitrila e pelo menos uma diamina com água a uma temperatura de 90 - 400<198> C e uma pressão de 0,1 - 50* 10^ 6^ Pa em uma relação molar de água para o soma total da dinitrila e da diamina de pelo menos 1:1 e na presença de um catalisador heterogêneo selecionado do grupo que consiste de óxido de alumínio, óxido de zinco, óxido de silício, óxidos do segundo ao sétimo subgrupos da tabela periódica, óxidos dos lantanídeos e actinídeos, filossilicatos e zeólitos; A invenção está relacionada também a poliamidas obtidas de acordo com o mencionado processo.
BRPI0012774-4A 1999-07-30 2000-07-11 processo para preparação de poliamida. BR0012774B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19935398A DE19935398A1 (de) 1999-07-30 1999-07-30 Verfahren zur Herstellung von Polyamiden aus Dinitrilen und Diaminen
PCT/EP2000/006566 WO2001009224A1 (de) 1999-07-30 2000-07-11 Verfahren zur herstellung von polyamiden aus dinitrilen und diaminen

Publications (2)

Publication Number Publication Date
BR0012774A true BR0012774A (pt) 2002-12-17
BR0012774B1 BR0012774B1 (pt) 2011-03-22

Family

ID=7916325

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0012774-4A BR0012774B1 (pt) 1999-07-30 2000-07-11 processo para preparação de poliamida.

Country Status (22)

Country Link
US (1) US6699960B1 (pt)
EP (1) EP1198491B1 (pt)
JP (1) JP3462868B2 (pt)
KR (1) KR100610728B1 (pt)
CN (1) CN1175029C (pt)
AR (1) AR024799A1 (pt)
AT (1) ATE251194T1 (pt)
AU (1) AU6691700A (pt)
BG (1) BG106341A (pt)
BR (1) BR0012774B1 (pt)
CA (1) CA2386888C (pt)
CZ (1) CZ2002188A3 (pt)
DE (2) DE19935398A1 (pt)
ES (1) ES2209950T3 (pt)
HU (1) HUP0202105A3 (pt)
IL (1) IL147297A0 (pt)
MX (1) MXPA02001054A (pt)
PL (1) PL353271A1 (pt)
SK (1) SK1492002A3 (pt)
TW (1) TW593433B (pt)
WO (1) WO2001009224A1 (pt)
ZA (1) ZA200201638B (pt)

Families Citing this family (91)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7068724B1 (en) 1999-10-20 2006-06-27 Prime Research Alliance E., Inc. Method and apparatus for inserting digital media advertisements into statistical multiplexed streams
DE10021191A1 (de) * 2000-05-03 2001-11-08 Basf Ag Verfahren zur Herstellung eines Polymers unter Verwendung von Caprolactam
DE10058292A1 (de) * 2000-11-23 2002-05-29 Basf Ag Polyamide
DE10217439A1 (de) 2002-04-18 2003-10-30 Basf Ag Verfahren zur Herstellung von Polyamiden
MY146531A (en) 2006-12-13 2012-08-15 Basf Se Polyamides with acrylate rubbers
DE102008038411A1 (de) 2007-09-11 2009-03-12 Basf Se Flammgeschützte Polyamide
US8309221B2 (en) * 2007-10-01 2012-11-13 Jay Plaehn Reinforced foam panel
EP2227507B1 (de) 2007-12-18 2011-08-31 Basf Se Thermoplastische polyamide mit polyetheraminen
DE102009011668A1 (de) 2008-03-05 2009-09-10 Basf Se Polyamid und hyperverzweigte Polyesster enthaltende Formmasse
WO2009156342A1 (de) 2008-06-27 2009-12-30 Basf Se Wärmeleitfähige polyamide mit diatomeenerde
KR20110028533A (ko) * 2008-07-02 2011-03-18 바스프 에스이 발포성 폴리아미드
DE102008058246A1 (de) 2008-11-19 2010-05-20 Basf Se Hochmolekulare Polyamide
BRPI0922909B1 (pt) 2008-12-16 2019-06-25 Basf Se Material de moldagem termoplástico, uso de materiais de moldagem termoplásticos, e, fibras, folhas ou corpo moldado de qualquer tipo
EP2264093A1 (de) 2009-06-16 2010-12-22 THOR GmbH Flammgeschützte Polyamidformmassen
WO2011000772A1 (de) 2009-06-30 2011-01-06 Basf Se Polyamidfasern mit anfärbbaren partikeln und verfahren zu deren herstellung
WO2011000816A1 (de) 2009-07-03 2011-01-06 Basf Se Nanokompositblends enthaltend polyamide und polyolefine
EP2456816A1 (de) 2009-07-21 2012-05-30 Basf Se Nanokompositblends auf basis von polyamiden und polyarylenethersulfonen
WO2011009877A1 (de) 2009-07-24 2011-01-27 Basf Se Flammgeschützte polyamidformmassen
KR101863376B1 (ko) 2009-10-27 2018-05-31 바스프 에스이 열 노화에 내성인 폴리아미드
JP5496351B2 (ja) 2009-10-27 2014-05-21 ビーエーエスエフ ソシエタス・ヨーロピア 難燃剤を有する耐熱老化性ポリアミド
WO2011069942A1 (de) 2009-12-08 2011-06-16 Basf Se Teilaromatische copolyamidformmassen auf der basis von octamethylendiamin
CN102803387B (zh) 2009-12-09 2014-06-25 巴斯夫欧洲公司 半芳族、半结晶共聚酰胺
DE102010062886A1 (de) 2009-12-16 2011-06-22 Basf Se, 67063 Polyarylenethersulfone als Schlagzähmodifier
AU2011226220B2 (en) 2010-03-09 2015-02-19 Basf Se Polyamides resistant to hot ageing
US8466221B2 (en) 2010-03-09 2013-06-18 Basf Se Polyamides that resist heat-aging
WO2011134930A1 (de) 2010-04-30 2011-11-03 Basf Se Langfaserverstärkte polyamide mit polyolefinen
DE102010023770A1 (de) 2010-06-15 2011-12-15 Basf Se Glühdrahtbeständige Formmassen
US8563680B2 (en) 2010-06-15 2013-10-22 Basf Se Heat-aging-resistant polyamides
BR112012031898B1 (pt) 2010-06-15 2019-12-24 Basf Se composição de moldagem termoplástica, uso das composições de moldagem, e, fibra, folha metálica ou peça moldada
WO2012013564A1 (de) 2010-07-30 2012-02-02 Basf Se Flammgeschützte formmassen
EP2415827A1 (de) 2010-08-04 2012-02-08 Basf Se Flammgeschützte Polyamide mit Schichtsilikaten
WO2012062594A1 (de) 2010-11-11 2012-05-18 Basf Se Wärmealterungsbeständige polyamide
EP2640784B1 (de) 2010-11-18 2015-10-07 Styrolution Europe GmbH Thermoplastische formmassen auf basis von styrolcopolymeren und polyamiden; verfahren zu deren herstellung und deren verwendung
US8575295B2 (en) 2010-12-16 2013-11-05 Basf Se Glow-wire resistant polyamides
KR101950360B1 (ko) 2010-12-16 2019-02-21 바스프 에스이 글로우 와이어 내성 폴리아미드
WO2012084785A1 (de) 2010-12-20 2012-06-28 Basf Se Thermoplastische formmassen auf basis von styrol-copolymeren und polyamiden mit verbesserter tieftemperaturzähigkeit
US8629220B2 (en) 2011-01-18 2014-01-14 Basf Se Hydrolysis-resistant polyamides
EP2665777B1 (de) 2011-01-18 2014-11-19 Basf Se Hydrolysestabile polyamide
US8629206B2 (en) 2011-01-20 2014-01-14 Basf Se Flame-retardant thermoplastic molding composition
CN103492778A (zh) 2011-04-21 2014-01-01 巴斯夫欧洲公司 用于将传热介质管固定至容器的装置
EP2702102A1 (de) 2011-04-28 2014-03-05 Basf Se Flammgeschütze formmassen
US8653168B2 (en) 2011-05-10 2014-02-18 Basf Se Flame-retardant thermoplastic molding composition
EP2527402A1 (de) 2011-05-27 2012-11-28 Basf Se Thermoplastische Formmasse
US8987357B2 (en) 2011-05-27 2015-03-24 Basf Se Thermoplastic molding composition
DE102011104303A1 (de) 2011-06-03 2012-12-06 Basf Se Photovoltaik-System zur Installation auf Dächern mit Kunststoffträger und Photovoltaik-Modul
US8883904B2 (en) 2011-09-15 2014-11-11 Basf Se Mixtures of silver and zinc oxide as stabilizer for flame-retardant polyamides
JP6049730B2 (ja) 2011-09-15 2016-12-21 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 赤リン含有難燃性ポリアミド用の安定剤としての銀/酸化亜鉛混合物
EP2573138A1 (de) 2011-09-21 2013-03-27 Basf Se Polyamid-Formmassen
WO2013075982A1 (de) 2011-11-25 2013-05-30 Basf Se Blasformbare polyamidformmassen
WO2013083508A1 (de) 2011-12-07 2013-06-13 Basf Se Flammgeschützte polyamide mit flüssigkristallinen polyestern
RU2014137951A (ru) 2012-02-20 2016-04-10 Басф Се СМЕСИ CuO/ZnO В КАЧЕСТВЕ СТАБИЛИЗАТОРОВ ОГНЕСТОЙКИХ ПОЛИАМИДОВ
EP2641939A1 (de) 2012-03-21 2013-09-25 Basf Se Hellgefärbte flammgeschützte Polyamide
EP2650331A1 (de) 2012-04-11 2013-10-16 Basf Se Polyamide für Trinkwasseranwendungen
WO2013189676A1 (de) 2012-06-18 2013-12-27 Basf Se Flammgeschützte polyamide mit polyacrylnitrilhomopolymerisaten
PT2898009T (pt) 2012-09-19 2017-01-23 Basf Schweiz Ag Poliamidas à prova de chama com cor clara
JP6509195B2 (ja) 2013-04-15 2019-05-08 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 耐グローワイヤ性ポリアミド
DE102014215370A1 (de) 2013-09-05 2015-03-05 Basf Se Langfaserverstärkte flammgeschützte Polyamide
EP3060597A4 (en) 2013-10-22 2017-06-14 Empire Technology Development LLC Compounds and methods for producing nylon 6
US9988491B2 (en) 2013-10-22 2018-06-05 Empire Technology Development Llc Methods and compounds for producing nylon 6,6
CN105658616A (zh) 2013-10-25 2016-06-08 英派尔科技开发有限公司 产生二羰基化合物的方法
WO2016087324A1 (de) 2014-12-01 2016-06-09 Basf Se Flammgeschützte polyamide mit sulfonsäuresalzen
KR102466147B1 (ko) 2014-12-01 2022-11-10 바스프 에스이 열가소성 폴리아미드 입자
GB201421293D0 (en) 2014-12-01 2015-01-14 Xeros Ltd New cleaning method, apparatus and use
US11674015B2 (en) 2015-04-16 2023-06-13 Basf Se Polyamides with improved optical properties
CN107810239A (zh) 2015-06-19 2018-03-16 巴斯夫欧洲公司 具有高的熔体流动和良好的机械性能的聚酰胺组合物
EP3118247A1 (de) 2015-07-15 2017-01-18 Basf Se Polyamide mit besseren optischen eigenschaften
EP3130633A1 (de) 2015-08-13 2017-02-15 Basf Se Polyamide mit guter mechanik und schwindung
EP3135730A1 (de) 2015-08-27 2017-03-01 Basf Se Polyamide mit niedrigem kristallisationspunkt und geringer schwindung
BR112018071480B1 (pt) 2016-04-26 2023-02-28 Basf Se Partículas de poliamida termoplástica, método para produzir partículas de poliamida termoplástica e uso das partículas de poliamida termoplástica
HUE052380T2 (hu) 2016-06-15 2021-04-28 Basf Se Poliamid-diszperzió poliolban és elõállítása
JP2019522083A (ja) 2016-06-15 2019-08-08 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se ポリイソブテンを基礎とするポリアミド耐衝撃性改良剤
KR102491411B1 (ko) 2016-10-13 2023-01-20 바스프 에스이 난연성 폴리아미드
CN110198967B (zh) 2017-02-01 2022-04-05 巴斯夫欧洲公司 含有萘二甲酸酐端基的聚亚芳基醚砜
CN110446756B (zh) 2017-03-01 2023-04-04 巴斯夫欧洲公司 含pvp的阻燃聚酰胺
JP7196107B2 (ja) 2017-06-22 2022-12-26 ビーエーエスエフ ソシエタス・ヨーロピア リン及びAl-ホスホネートを有するポリアミド
WO2019197511A1 (en) 2018-04-13 2019-10-17 Basf Se Flame-retardant thermoplastic molding composition
US11939469B2 (en) 2018-08-16 2024-03-26 Basf Se Thermoplastic molding material
JP2022522415A (ja) 2019-02-20 2022-04-19 ビーエーエスエフ ソシエタス・ヨーロピア 熱可塑性成形化合物
JP7500592B2 (ja) 2019-02-25 2024-06-17 ビーエーエスエフ ソシエタス・ヨーロピア 熱可塑性成形組成物
KR20220059511A (ko) 2019-09-05 2022-05-10 바스프 에스이 열에 내성인 열가소성 성형 조성물
EP3808810B1 (de) 2019-10-16 2023-03-29 INEOS Styrolution Group GmbH Thermoplastische formmassen für rotomolding-verfahren
US20230102597A1 (en) 2020-01-27 2023-03-30 Basf Se Thermoplastic polyamide molding compositions that resist heat
CA3169428A1 (en) 2020-02-26 2021-09-02 Basf Se Heat-aging resistant polyamide molding compositions
CA3175749A1 (en) 2020-03-20 2021-09-23 Basf Se Plasticized polyamide molding compositions
US20230129664A1 (en) 2020-03-25 2023-04-27 Basf Se Heat-aging resistant polyamide molding compositions
WO2022180221A1 (en) 2021-02-25 2022-09-01 Basf Se Polymers having improved thermal conductivity
CN117320869A (zh) 2021-05-11 2023-12-29 巴斯夫欧洲公司 经激光打标和激光焊接的模制体及其制造
CN117413020A (zh) 2021-06-04 2024-01-16 巴斯夫欧洲公司 保持高光泽的热塑性模塑组合物
WO2023237603A1 (en) 2022-06-08 2023-12-14 Basf Se Recycling method for producing a polyamide compound
WO2024068509A1 (en) 2022-09-27 2024-04-04 Basf Se Thermoplastic moulding compositions having an improved colour stability-1
WO2024104965A1 (en) 2022-11-17 2024-05-23 Basf Se Mixed metal-oxide compositions as stabilizer for flame retardant polyamides

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3429095B2 (ja) * 1994-05-27 2003-07-22 ツイマー・アクチェンゲゼルシャフト α,ω−ジニトリルに基づくポリアミドの製造方法
DE4430480A1 (de) * 1994-08-27 1996-02-29 Basf Ag Hochmolekulare Polyamide aus Nitrilen
WO1998008889A2 (de) * 1996-08-30 1998-03-05 Basf Aktiengesellschaft Verfahren zur herstellung von polyamiden aus aminonitrilen
DE19804020A1 (de) * 1998-02-02 1999-08-05 Basf Ag Verfahren zur Herstellung von Polyamiden aus Aminonitrilen
DE19804014A1 (de) * 1998-02-02 1999-08-05 Basf Ag Diskontinuierliches Verfahren zur Herstellung von Polyamiden aus Aminonitrilen
DE19804023A1 (de) * 1998-02-02 1999-08-05 Basf Ag Kontinuierliches Verfahren zur Herstellung von Polyamiden aus Aminonitrilen
US6509439B1 (en) * 2000-04-14 2003-01-21 E. I. Du Pont De Nemours And Company Process for the production of polyamides from dinitriles and diamines

Also Published As

Publication number Publication date
IL147297A0 (en) 2002-08-14
WO2001009224A1 (de) 2001-02-08
AR024799A1 (es) 2002-10-23
ZA200201638B (en) 2003-04-30
CZ2002188A3 (cs) 2002-05-15
PL353271A1 (en) 2003-11-03
KR20020016927A (ko) 2002-03-06
DE19935398A1 (de) 2001-02-01
CN1175029C (zh) 2004-11-10
KR100610728B1 (ko) 2006-08-09
JP3462868B2 (ja) 2003-11-05
EP1198491B1 (de) 2003-10-01
HUP0202105A2 (en) 2002-10-28
SK1492002A3 (en) 2002-10-08
ATE251194T1 (de) 2003-10-15
ES2209950T3 (es) 2004-07-01
CN1364178A (zh) 2002-08-14
MXPA02001054A (es) 2002-08-20
AU6691700A (en) 2001-02-19
TW593433B (en) 2004-06-21
JP2003506509A (ja) 2003-02-18
HUP0202105A3 (en) 2003-10-28
CA2386888C (en) 2009-03-03
DE50003919D1 (de) 2003-11-06
CA2386888A1 (en) 2001-02-08
US6699960B1 (en) 2004-03-02
BG106341A (en) 2002-11-29
BR0012774B1 (pt) 2011-03-22
EP1198491A1 (de) 2002-04-24

Similar Documents

Publication Publication Date Title
BR0012774A (pt) Processo para preparação de poliamida, e, poliamida.
BR0114522A (pt) Processo de fabricação de poliamida
AR039962A1 (es) Materiales de moldeo de poliamida transparente, que presentan una mejor transparencia, resistencia a quimicos y alta resistencia a la fatiga permanente
BR9903420A (pt) Processos de preparação de microcápsulas por policondensação de uma mistura de resina de melamina/formaldeìdo e de uso de microcápsulas, microcápsula, mistura de resina de melamina/formaldeìdo, e, uso de uma mistura de resina de melamina/formaldeìdo
KR920002663A (ko) 신규한 코폴리아미드와 그의 제조방법
DE50108614D1 (de) Verfahren zur herstellung von diaminodiphenylmethanen
ES2152747T3 (es) Un procedimiento para preparar 5-(acetil(2,3-dihidroxipropil)amino)-n,n&#39;-bis(2,3-dihidroxipropil)-2,4,6-triyodo-1,3-bencenodicarboxamida.
KR970706333A (ko) 잉크-제트 인쇄 조성물(ink-jet printing compositions)
BR0210082A (pt) Processos de conversão de dinitrilas em diaminas e/ou aminonitrilas
BR9908397A (pt) Agente de cura para resina epóxi, composição, sistema de resina epóxi curável aquoso, composição curada, e, processo para a preparação de um agente de cura para resinas epóxi
BR0112229A (pt) Processo para tratamento de materiais de fibra têxtil ou couro
BR9811235A (pt) Processo para a produção de uma amina aromática
RU2000122972A (ru) Непрерывный способ получения полиамидов из аминонитрилов
BR0109261A (pt) Processo de hidrogenação de funções nitrilas em funções aminas
RU2000122969A (ru) Непрерывный способ получения полиамидов из аминонитрилов
BR9917023A (pt) Processo para a produção de poliamida
KR840004447A (ko) 폴리아미드의 제조방법
WO2008039162A1 (fr) Procédé de fabrication de polyguanidines
CN108129657A (zh) 一种生物质基聚酰胺树脂的合成方法
JPH0841196A (ja) α,ω−ジニトリルに基づくポリアミドの製造方法
FR2823994B1 (fr) Procede de fabrication de microcapsules par polycondensation interfaciale avec de la polyoxyalkyneamine et des chlorures d&#39;acide
BR0209842A (pt) Processo para a preparação de imipenem
RU2000122970A (ru) Периодический способ получения полиамидов из аминонитрилов
BR0109937A (pt) Processo para a preparação de heterociclos benzo-fundidos
BR0017003A (pt) Processo de preparação de poliamida modificada, produto e filamento

Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 22/03/2011, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)