AU711973B2 - Epoxidation catalyst and process - Google Patents

Epoxidation catalyst and process Download PDF

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Publication number
AU711973B2
AU711973B2 AU27760/97A AU2776097A AU711973B2 AU 711973 B2 AU711973 B2 AU 711973B2 AU 27760/97 A AU27760/97 A AU 27760/97A AU 2776097 A AU2776097 A AU 2776097A AU 711973 B2 AU711973 B2 AU 711973B2
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AU
Australia
Prior art keywords
catalyst
carrier
weight
percent
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU27760/97A
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English (en)
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AU2776097A (en
Inventor
Ruth Mary Kowaleski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
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Publication of AU2776097A publication Critical patent/AU2776097A/en
Application granted granted Critical
Publication of AU711973B2 publication Critical patent/AU711973B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
AU27760/97A 1996-04-30 1997-04-25 Epoxidation catalyst and process Ceased AU711973B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/643,158 US5801259A (en) 1996-04-30 1996-04-30 Ethylene oxide catalyst and process
US08/643158 1996-04-30
PCT/EP1997/002236 WO1997040933A1 (en) 1996-04-30 1997-04-25 Epoxidation catalyst and process

Publications (2)

Publication Number Publication Date
AU2776097A AU2776097A (en) 1997-11-19
AU711973B2 true AU711973B2 (en) 1999-10-28

Family

ID=24579602

Family Applications (1)

Application Number Title Priority Date Filing Date
AU27760/97A Ceased AU711973B2 (en) 1996-04-30 1997-04-25 Epoxidation catalyst and process

Country Status (12)

Country Link
US (1) US5801259A (h)
EP (1) EP0900128B1 (h)
JP (1) JP4052673B2 (h)
CN (1) CN1093002C (h)
AU (1) AU711973B2 (h)
CA (1) CA2252780C (h)
DE (1) DE69705309T2 (h)
ES (1) ES2158559T3 (h)
IN (2) IN2004DE02379A (h)
MX (1) MX217137B (h)
TW (1) TW344675B (h)
WO (1) WO1997040933A1 (h)

Families Citing this family (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5939569A (en) * 1998-03-10 1999-08-17 Jones; C. Andrew Epoxidation process
EP1086743B1 (en) 1999-09-21 2006-08-16 Nippon Shokubai Co., Ltd. Catalyst for production of epoxides and methods for production thereof and epoxides
JP4050041B2 (ja) * 2001-11-06 2008-02-20 株式会社日本触媒 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法
US7193094B2 (en) 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
EP1354626B1 (en) * 2002-04-04 2005-07-13 Nippon Shokubai Co., Ltd. Alumina-silica supported silver catalyst and use thereof in the production of epoxide
US6750173B2 (en) * 2002-04-08 2004-06-15 Scientific Design Company, Inc. Ethylene oxide catalyst
RU2314156C2 (ru) 2002-06-28 2008-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ улучшения селективности катализатора и способ эпоксидирования олефина
WO2004002972A2 (en) 2002-06-28 2004-01-08 Shell Internationale Research Maatschappij B.V. A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin
DE10300526A1 (de) * 2003-01-09 2004-07-22 Hte Ag The High Throughput Experimentation Company Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen
US7319156B2 (en) * 2003-03-25 2008-01-15 Sumitomo Chemical Company, Limited Process for producing olefin oxide
TWI346574B (en) 2003-03-31 2011-08-11 Shell Int Research A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition
IN2005DN04374A (h) * 2003-04-01 2010-01-15 Shell Int Research
US7348444B2 (en) * 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
WO2004101144A1 (en) 2003-05-07 2004-11-25 Shell Internationale Research Maatschappij B.V., Silver-containing catalysts, the manufacture of such silver­ containing catalysts, and the use thereof
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
EP1658136A1 (en) * 2003-08-22 2006-05-24 Union Carbide Chemicals & Plastics Technology Corporation Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
WO2005039757A1 (en) 2003-10-16 2005-05-06 Union Carbide Chemicals & Plastics Technology Corporation Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
CN1301791C (zh) * 2003-12-31 2007-02-28 中国石油化工股份有限公司北京燕山分公司研究院 用于环氧乙烷生产用银催化剂的载体、其制备方法及其应用
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
WO2006020709A1 (en) * 2004-08-12 2006-02-23 Velocys Inc. Process for converting ethylene to ethylene oxide using microchannel process technology
CN101072631B (zh) * 2004-09-24 2013-02-13 国际壳牌研究有限公司 用来选择成形颗粒的过程、用来安装系统的过程、用来在这样一种系统中使气体原料反应的过程、计算机程序产品、及计算机系统
CN101146604A (zh) * 2005-03-22 2008-03-19 国际壳牌研究有限公司 制备环氧乙烷的反应器系统和方法
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
BRPI0611817A2 (pt) * 2005-06-07 2011-12-20 Saint Gobain Ceramics veìculo catalisador e um processo para preparação do veìculo catalisador
CA2611093C (en) 2005-06-07 2014-08-26 Shell Internationale Research Maatschappij B.V. A catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US20070197808A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070213545A1 (en) * 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203348A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
NL2000386C2 (nl) * 2005-12-22 2007-10-24 Shell Int Research Methode ter bereiding van een epoxideringskatalysator, epoxideringskatalysator, werkwijze ter bereiding van een olefineoxide of een chemisch product dat van een olefineoxide kan worden afgeleid en reactor die voor een dergelijke werkwijze geschikt is.
US20070203352A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7459589B2 (en) * 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
US20070151451A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the cooling, concentration or purification of ethylene oxide
US20070203349A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203350A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7704908B2 (en) * 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
US20070154377A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the removal of combustible volatile contaminant materials from a process stream
US20070197801A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
CN100577289C (zh) * 2006-01-28 2010-01-06 中国石油化工股份有限公司 环氧乙烷生产用银催化剂的载体、其制备方法及其应用
TW200738332A (en) * 2006-02-03 2007-10-16 Shell Int Research A process for treating a catalyst, the catalyst, and use of the catalyst
KR101066082B1 (ko) * 2006-02-10 2011-09-20 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 다공성 세라믹 물질의 제조방법
US10159961B2 (en) 2006-04-18 2018-12-25 Dow Global Technologies Llc Alkylene oxide catalyst and use thereof
RU2008145498A (ru) * 2006-04-18 2010-05-27 Дау Глобал Текнолоджиз Инк. (Us) Катализатор оксида алкилена и его применение
US8097557B2 (en) 2006-08-08 2012-01-17 Sd Lizenverwertungsgesellschaft Mbh & Co. Kg Two-stage calcination for catalyst production
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
CA2669585A1 (en) * 2006-11-20 2008-05-29 Shell Internationale Research Maatschappij B.V. A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
US20080154051A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
TWI446964B (zh) 2007-05-09 2014-08-01 Shell Int Research 環氧化催化劑,製備該催化劑之方法及製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法
CA2686825C (en) * 2007-05-09 2016-09-13 Shell Internationale Research Maatschappij B.V. An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
KR101505216B1 (ko) * 2007-05-09 2015-03-23 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산 방법
CA2687593C (en) * 2007-05-18 2018-11-13 Shell Internationale Research Maatschappij B.V. A reactor system, and a process for preparing an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate and an alkanolamine
JP2010527758A (ja) 2007-05-18 2010-08-19 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 反応器系、吸収剤および供給材料を反応させるための方法
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
US7803957B2 (en) * 2007-09-11 2010-09-28 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Ethylene oxide production using fixed moderator concentration
US7553980B2 (en) * 2007-09-26 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for initiating a highly selective ethylene oxide catalyst
WO2009088040A1 (ja) * 2008-01-11 2009-07-16 Nippon Shokubai Co., Ltd. エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
CN102015095B (zh) * 2008-04-30 2013-05-08 陶氏技术投资有限公司 多孔体前体,成形多孔体,它们的制备方法和基于它们的终端产品
CA2723160A1 (en) * 2008-04-30 2009-11-05 Dow Technology Investments Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
CN102015101B (zh) 2008-04-30 2013-11-06 陶氏技术投资有限公司 多孔体前体,成形多孔体,它们的制备方法和基于它们的终端产品
US7763096B2 (en) 2008-05-06 2010-07-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Recovery of rhenium
PL2297125T3 (pl) 2008-05-07 2013-12-31 Shell Int Research Sposób wytwarzania tlenku olefiny, 1,2-diolu, eteru 1,2-diolu, 1,2-węglanu albo alkanoloaminy
CN102056909B (zh) 2008-05-07 2014-03-05 国际壳牌研究有限公司 环氧化工艺的开车方法及环氧乙烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法
BRPI0912718B1 (pt) 2008-05-15 2017-12-26 Shell Internationale Research Maataschappij B.V Method for producing an alkylene carbonate and / or an alkylene glycol
WO2009140318A1 (en) * 2008-05-15 2009-11-19 Shell Oil Company Process for the preparation of an alkylene carbonate and an alkylene glycol
CA2759560C (en) 2009-04-21 2017-05-30 Dow Technology Investments Llc Rhenium-promoted epoxidation catalysts and methods of making and using them
SG175770A1 (en) * 2009-04-21 2011-12-29 Dow Technology Investments Llc Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages
JP5756087B2 (ja) * 2009-04-21 2015-07-29 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法
TWI462912B (zh) * 2009-04-21 2014-12-01 Dow Technology Investments Llc 環氧化反應及其操作條件
JP2012522061A (ja) * 2009-12-28 2012-09-20 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー アルキレンオキサイドの製造における銀触媒上への塩化銀の生成の制御方法
US8937031B2 (en) 2010-03-01 2015-01-20 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US9018126B2 (en) 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
ES2653712T3 (es) 2010-09-29 2018-02-08 Shell Internationale Research Maatschappij B.V. Control mejorado del proceso EO
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742146B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
CA2832552C (en) 2011-04-11 2020-09-01 Dow Technology Investments Llc Process for conditioning a high efficiency ethylene oxide catalyst
US9174928B2 (en) 2011-04-29 2015-11-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
CN103357436B (zh) * 2012-03-28 2016-02-24 中国石油化工股份有限公司 氧化铝载体碱处理改性、其负载的银催化剂的制备及应用
CN103357440B (zh) * 2012-03-28 2015-03-11 中国石油化工股份有限公司 氧化铝载体的改性、及其负载的银催化剂的制备及其应用
CN103357442B (zh) * 2012-03-28 2016-03-30 中国石油化工股份有限公司 烯烃环氧化用银催化剂的载体、其制备方法及其应用
CN103566980B (zh) * 2012-07-23 2015-08-19 中国石油化工股份有限公司 氧化铝载体及其负载的银催化剂的制备方法及应用
CN103816940B (zh) * 2012-11-19 2019-03-26 中国石油化工股份有限公司 一种氧化铝载体及其制备方法
EP2938435A4 (en) * 2012-12-31 2016-10-05 Scient Design Co CALCINATION PROCESS FOR PREPARING AN IMPROVED ETHYLENE OXIDE CATALYST
CN104069893B (zh) * 2013-03-27 2016-05-25 中国石油化工股份有限公司 生产环氧乙烷用银催化剂载体、制备方法及其应用
CN104549546B (zh) * 2013-10-29 2017-08-22 中国石油化工股份有限公司 氧化铝载体、制备方法及银催化剂
RU2017144428A (ru) 2015-06-02 2019-07-09 Сайентифик Дизайн Компани, Инк. Способ изготовления пористых тел с улучшенными свойствами
CN106311230B (zh) * 2015-06-30 2019-05-31 中国石油化工股份有限公司 用于烯烃环氧化的银催化剂的制备方法、催化剂及应用
CN106311231A (zh) * 2015-06-30 2017-01-11 中国石油化工股份有限公司 用于烯烃环氧化的银催化剂的制备方法、银催化剂及应用
EP3548471B1 (en) 2016-12-02 2021-05-19 Shell Internationale Research Maatschappij B.V. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
US11331652B2 (en) 2017-05-15 2022-05-17 Scientific Design Company, Inc. Porous bodies with enhanced pore architecture prepared without a high-temperature burnout material
TWI808125B (zh) 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
US10676401B2 (en) 2018-04-23 2020-06-09 Scientific Design Company, Inc. Porous bodies with enhanced pore architecture prepared with oxalic acid

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
US4621071A (en) * 1983-12-09 1986-11-04 Pro-Catalyse Composite catalyst for treatment of vehicular exhaust gases and process for the preparation of the catalyst
WO1996023585A1 (en) * 1995-02-01 1996-08-08 Shell Internationale Research Maatschappij B.V. Alkylene oxide catalyst and process

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3172866A (en) * 1965-03-09 Method of preparing alumina catalyst carriers and the product thereof
US3316279A (en) * 1964-06-09 1967-04-25 Union Oil Co Preparation of olefin oxides
US3844981A (en) * 1969-12-23 1974-10-29 Exxon Research Engineering Co Method for preparation of olefin oxidation catalyst
GB1325715A (en) * 1969-12-23 1973-08-08 Exxon Research Engineering Co Bimetallic catalyst manufacture and use in ethylene oxidation
US3702259A (en) * 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4012425A (en) * 1972-01-07 1977-03-15 Shell Oil Company Ethylene oxide process
US4010115A (en) * 1972-01-07 1977-03-01 Shell Oil Company Catalyst for the oxidation of ethylene to ethylene oxide
US4356312A (en) * 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
US3962285A (en) * 1972-06-05 1976-06-08 Exxon Research And Engineering Company Olefin oxidation process
US3972829A (en) * 1974-11-07 1976-08-03 Universal Oil Products Company Method of depositing a catalytically active metallic component on a carrier material
US4005049A (en) * 1975-05-23 1977-01-25 Standard Oil Company (Indiana) Silver catalysts
US4212772A (en) * 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
EP0002045B1 (de) * 1977-11-19 1981-09-02 BASF Aktiengesellschaft Verfahren zur Herstellung eines Äthylenoxydkatalysators
DE2844402A1 (de) * 1978-10-12 1980-04-30 Basf Ag Silber enthaltende traegerkatalysatoren, verfahren zu ihrer herstellung und verfahren zur herstellung von aethylenoxid mittels dieser katalysatoren
DE2904919A1 (de) * 1979-02-09 1980-08-21 Basf Ag Verfahren zur herstellung und regenerierung von traegerkatalysatoren sowie deren verwendung fuer die herstellung von aethylenoxid
JPS56108533A (en) * 1980-01-30 1981-08-28 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for preparing ethylene oxide
JPS56149320A (en) * 1980-04-21 1981-11-19 Sumitomo Alum Smelt Co Ltd Manufacture of activated alumina molding with low density
NL8201396A (nl) * 1982-04-01 1983-11-01 Dow Chemical Nederland Zilver katalysator en een werkwijze voor de bereiding daarvan.
US4459372A (en) * 1982-08-25 1984-07-10 Uop Inc. Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides
GB8304749D0 (en) * 1983-02-21 1983-03-23 Ici Plc Catalysts
EP0172280B1 (en) * 1983-03-14 1988-03-09 E.I. Du Pont De Nemours And Company Catalyst composition
US4579728A (en) * 1985-04-24 1986-04-01 Shell Oil Company Wide pore alumina supports
EP0211521B1 (en) * 1985-07-31 1990-03-21 Imperial Chemical Industries Plc Process of promoting catalysts for the production of alkylene oxides
EP0211448B1 (en) * 1985-08-16 1990-11-14 Sumitomo Chemical Company, Limited Process for preparing solid base
GB8611121D0 (en) * 1986-05-07 1986-06-11 Shell Int Research Silver catalyst
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) * 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
US4897498A (en) * 1988-01-28 1990-01-30 Eastman Kodak Company Selective monoepoxidation of olefins
CN1009437B (zh) * 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
US5072886A (en) * 1988-09-09 1991-12-17 Simon Fraser University Method of preparing a new ultra-fine particle transition alumina
US5130286A (en) * 1989-01-11 1992-07-14 Amoco Corporation Catalyst for lower alkane conversion
US5028577A (en) * 1989-01-11 1991-07-02 Amoco Corporation Lower alkane conversion catalysts
US4992409A (en) * 1989-01-11 1991-02-12 Amoco Corporation Catalyst and method of preparing the catalyst for lower alkane conversion
US5081324A (en) * 1989-01-11 1992-01-14 Amoco Corporation Lower alkane conversion
US5055442A (en) * 1989-02-17 1991-10-08 Nippon Shokubai Kagaku Kogyo Co., Ltd. Carrier for catalyst and method for production thereof
DE3905578A1 (de) * 1989-02-23 1990-08-30 Basf Ag Verfahren zur herstellung eines silberkatalysators
US5071815A (en) * 1989-09-01 1991-12-10 British Columbia Research Corporation Method for producing catalysts
US5037794A (en) * 1989-09-12 1991-08-06 The B. F. Goodrich Company Attrition resistant catalyst support
US5081096A (en) * 1990-07-25 1992-01-14 Eastman Kodak Company Epoxidation catalyst
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
DE4106508A1 (de) * 1991-03-01 1992-09-03 Basf Ag Silberkatalysator
US5153165A (en) * 1991-05-09 1992-10-06 Phillips Petroleum Company Preparation of alkaline earth oxide catalysts
JP3312916B2 (ja) * 1991-06-06 2002-08-12 三菱化学株式会社 酸化エチレン製造用銀触媒
CA2089510C (en) * 1992-02-27 1998-09-01 Shinichi Nagase Silver catalyst for production of ethylene oxide and method for production of the catalyst
US5384302A (en) * 1993-09-08 1995-01-24 Norton Chemical Process Products Corp. Catalyst carrier
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
US4621071A (en) * 1983-12-09 1986-11-04 Pro-Catalyse Composite catalyst for treatment of vehicular exhaust gases and process for the preparation of the catalyst
WO1996023585A1 (en) * 1995-02-01 1996-08-08 Shell Internationale Research Maatschappij B.V. Alkylene oxide catalyst and process

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