AU2003245926B2 - Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency - Google Patents
Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency Download PDFInfo
- Publication number
- AU2003245926B2 AU2003245926B2 AU2003245926A AU2003245926A AU2003245926B2 AU 2003245926 B2 AU2003245926 B2 AU 2003245926B2 AU 2003245926 A AU2003245926 A AU 2003245926A AU 2003245926 A AU2003245926 A AU 2003245926A AU 2003245926 B2 AU2003245926 B2 AU 2003245926B2
- Authority
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- Australia
- Prior art keywords
- propylene copolymer
- propylene
- copolymer composition
- copolymer compositions
- temperature
- Prior art date
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- Ceased
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims description 175
- 229920001577 copolymer Polymers 0.000 title claims description 164
- 239000000203 mixture Substances 0.000 title claims description 108
- 238000000034 method Methods 0.000 claims description 29
- 238000006116 polymerization reaction Methods 0.000 claims description 25
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 23
- 229920001384 propylene homopolymer Polymers 0.000 claims description 22
- 230000002087 whitening effect Effects 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 19
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 17
- 239000005977 Ethylene Substances 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
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- 239000000835 fiber Substances 0.000 claims description 12
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- 238000000465 moulding Methods 0.000 claims description 12
- 239000011159 matrix material Substances 0.000 claims description 11
- 238000009826 distribution Methods 0.000 claims description 10
- 230000000052 comparative effect Effects 0.000 claims description 7
- 239000002667 nucleating agent Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 238000002076 thermal analysis method Methods 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 2
- 238000012360 testing method Methods 0.000 description 40
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
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- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
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- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
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- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
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- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
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- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
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- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
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- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
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- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
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- 238000002156 mixing Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 230000010363 phase shift Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 125000003906 silylidene group Chemical group [H][Si]([H])=* 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- XBFJAVXCNXDMBH-UHFFFAOYSA-N tetracyclo[6.2.1.1(3,6).0(2,7)]dodec-4-ene Chemical compound C1C(C23)C=CC1C3C1CC2CC1 XBFJAVXCNXDMBH-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Chemical group 0.000 description 1
- 239000010936 titanium Chemical group 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/22—Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10226184.9 | 2002-06-12 | ||
| DE10226184 | 2002-06-12 | ||
| US39461502P | 2002-07-09 | 2002-07-09 | |
| US60/394,615 | 2002-07-09 | ||
| PCT/EP2003/006043 WO2003106553A1 (en) | 2002-06-01 | 2003-06-10 | Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2003245926A1 AU2003245926A1 (en) | 2003-12-31 |
| AU2003245926B2 true AU2003245926B2 (en) | 2007-11-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2003245926A Ceased AU2003245926B2 (en) | 2002-06-12 | 2003-06-10 | Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20060167185A1 (enExample) |
| EP (1) | EP1511803B1 (enExample) |
| JP (1) | JP2005529227A (enExample) |
| CN (1) | CN1290917C (enExample) |
| AR (1) | AR040187A1 (enExample) |
| AT (1) | ATE373692T1 (enExample) |
| AU (1) | AU2003245926B2 (enExample) |
| BR (1) | BR0311863B1 (enExample) |
| CA (1) | CA2483206A1 (enExample) |
| DE (1) | DE60316437T2 (enExample) |
| ES (1) | ES2291651T3 (enExample) |
| RU (1) | RU2337114C2 (enExample) |
| WO (1) | WO2003106553A1 (enExample) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1511783B1 (en) * | 2002-06-12 | 2013-07-31 | Basell Polyolefine GmbH | Flexible propylene copolymer compositions having a high transparency |
| ES2393782T3 (es) * | 2003-05-08 | 2012-12-28 | Lummus Novolen Technology Gmbh | Composición de resinas de polipropileno |
| ATE416233T1 (de) | 2004-07-30 | 2008-12-15 | Saudi Basic Ind Corp | Hochtransparente propylencopolymerzusammensetzungen |
| JP5116210B2 (ja) * | 2004-11-26 | 2013-01-09 | 三井化学株式会社 | レトルトフィルム用シーラントフィルム |
| JP2008523231A (ja) * | 2004-12-13 | 2008-07-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィン繊維 |
| EP1844099B1 (en) | 2005-02-03 | 2011-03-16 | Basell Polyolefine GmbH | Process for producing thermoformed articles |
| EP1861435B1 (en) * | 2005-03-23 | 2016-01-13 | Basell Polyolefine GmbH | Process for the polymerization of olefins |
| EP1871832B1 (en) * | 2005-04-21 | 2012-06-13 | Basell Poliolefine Italia S.r.l. | Biaxially oriented propylene polymer films |
| CN101163727B (zh) * | 2005-04-28 | 2012-11-28 | 巴塞尔聚烯烃意大利有限责任公司 | 热成形用的丙烯聚合物组合物 |
| KR101183747B1 (ko) * | 2005-05-10 | 2012-09-17 | 에스케이종합화학 주식회사 | 우수한 내충격성, 굴곡탄성율 및 투명성을 갖는폴리프로필렌 조성물 및 이의 제품 |
| CN101242945B (zh) * | 2005-08-19 | 2010-08-04 | 索维公司 | 用于制造塑料基的蜂窝状结构的工艺和用于实现所述工艺的设备 |
| EP2006314B2 (en) | 2006-03-29 | 2019-07-31 | Mitsui Chemicals, Inc. | Propylene random block copolymer, resin compositions containing the copolymer, and moldings of both |
| JP5277175B2 (ja) * | 2007-01-12 | 2013-08-28 | ダウ グローバル テクノロジーズ エルエルシー | 薄肉射出成形品に好適な組成物 |
| JP5309129B2 (ja) * | 2007-04-09 | 2013-10-09 | エクソンモービル・ケミカル・パテンツ・インク | 柔軟な不均一のアイソタクチックポリプロピレン組成物 |
| ATE552300T1 (de) | 2008-10-29 | 2012-04-15 | Borealis Ag | Feste zusammensetzung für lebensmittelanwendungen |
| US8076429B2 (en) | 2009-03-11 | 2011-12-13 | Lummus Novolen Technology Gmbh | Supertransparent high impact strength random block copolymer |
| DE102009049122B4 (de) | 2009-10-12 | 2023-10-19 | Sihl Gmbh | Kratzfeste Polypropylenfolie |
| KR100977665B1 (ko) * | 2009-12-18 | 2010-08-24 | 에스케이에너지 주식회사 | 충격강도, 표면특성 및 유동성이 우수한 에틸렌-프로필렌 블록공중합체계 폴리프로필렌 수지 조성물 |
| WO2011102946A1 (en) * | 2010-02-19 | 2011-08-25 | Exxonmobil Chemical Parents Inc. | Elastomeric polymer blends and processes for their production |
| US8907019B2 (en) | 2010-12-21 | 2014-12-09 | Basell Polyolefine Gmbh | Polypropylene composition with high elasticity and transparency |
| CN102757614A (zh) * | 2011-04-28 | 2012-10-31 | 北京化工大学 | 一种化妆品用耐低温高抗冲透明聚丙烯材料及其制备方法 |
| KR101966085B1 (ko) * | 2011-07-08 | 2019-04-05 | 보레알리스 아게 | 촉매 |
| EP2824142B1 (en) | 2013-07-12 | 2016-04-13 | Borealis AG | Heterophasic copolymer |
| KR101501835B1 (ko) * | 2013-08-13 | 2015-03-12 | 삼성토탈 주식회사 | 내백화성 및 내충격성이 우수한 폴리프로필렌 수지 조성물 |
| CN104558811A (zh) * | 2013-10-10 | 2015-04-29 | 中国石油化工股份有限公司 | 一种聚丙烯组合物及其制备方法和应用 |
| US10696829B2 (en) | 2013-12-20 | 2020-06-30 | Saudi Basic Industries Corporation | Heterophasic propylene copolymer |
| MX2016008034A (es) | 2013-12-20 | 2017-03-03 | Saudi Basic Ind Corp | Composicion de poliolefina. |
| PL2891667T3 (pl) | 2014-01-07 | 2017-07-31 | Borealis Ag | Heterofazowy polimer polipropylenu |
| CN103923392A (zh) * | 2014-04-29 | 2014-07-16 | 广东溢达纺织有限公司 | 耐低温聚丙烯服装包装薄膜及其制备方法 |
| CN106795239A (zh) | 2014-09-12 | 2017-05-31 | 博里利斯股份公司 | 制备丙烯共聚物的方法 |
| EP2995629B1 (en) | 2014-09-12 | 2018-03-07 | Borealis AG | Process for producing propylene copolymers in gas phase |
| EP3015504A1 (en) | 2014-10-27 | 2016-05-04 | Borealis AG | Heterophasic polypropylene with improved puncture respectively impact strength/stiffness balance |
| EP3015503A1 (en) | 2014-10-27 | 2016-05-04 | Borealis AG | Heterophasic polypropylene with improved stiffness/impact balance |
| ES2713165T5 (es) * | 2014-10-27 | 2022-09-07 | Borealis Ag | Polipropileno heterofásico con equilibrio mejorado de resistencia a impacto/tenacidad, fluidez de polvo mejorada, menores emisiones y baja contracción |
| EP3476888B1 (en) | 2017-10-25 | 2024-02-14 | Borealis AG | Filled polypropylene composition with improved thermo-mechanical properties |
| CN107903499A (zh) * | 2017-12-04 | 2018-04-13 | 天津科技大学 | 一种透明增韧改性聚丙烯塑料及其制备 |
| EP3781604B1 (en) * | 2018-04-18 | 2024-12-11 | W. R. Grace & Co.-Conn | Transparent polypropylene copolymer composition having impact resistance |
| JP7153464B2 (ja) | 2018-04-27 | 2022-10-14 | サンアロマー株式会社 | ポリプロピレン組成物および成形体 |
| WO2020106172A1 (en) * | 2018-11-21 | 2020-05-28 | Public Joint Stock Company "Sibur Holding" | Transparent, tasily flow able high-impact polypropylene composition |
| JP2021066825A (ja) | 2019-10-24 | 2021-04-30 | サンアロマー株式会社 | ポリプロピレン組成物および成形体 |
| KR20230128376A (ko) * | 2021-01-22 | 2023-09-04 | 보레알리스 아게 | 섬유 강화 폴리프로필렌 조성물 |
| US20250179280A1 (en) * | 2022-03-21 | 2025-06-05 | Borealis Ag | Glass fiber reinforced polypropylene composition |
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| DE19983451B4 (de) * | 1998-08-21 | 2009-09-24 | Chisso Corp. | Polypropylen-Folie und deren Verwendung |
| JP4346182B2 (ja) * | 1999-12-14 | 2009-10-21 | 株式会社プライムポリマー | 二軸延伸フィルム |
| EP1252202B1 (de) * | 1999-12-21 | 2006-02-22 | Basell Polyolefine GmbH | Teilkristalline propylenpolymerisat-zusammensetzung zur herstellung von biaxial gereckten polypropylenfolien |
| DE19962130A1 (de) * | 1999-12-21 | 2001-07-05 | Basell Polypropylen Gmbh | Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien |
| WO2001048034A2 (de) * | 1999-12-23 | 2001-07-05 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, ligandensystem, katalysatorsystem und seine verwendung zur polymerisation und copolymerisation von olefinen |
| US6586528B1 (en) * | 2000-11-15 | 2003-07-01 | Polypropylene Belgium (Naamlose Vennootshap) | Composition based on propylene polymers and process for obtaining same |
| EP1511783B1 (en) * | 2002-06-12 | 2013-07-31 | Basell Polyolefine GmbH | Flexible propylene copolymer compositions having a high transparency |
-
2003
- 2003-06-10 US US10/517,580 patent/US20060167185A1/en not_active Abandoned
- 2003-06-10 CN CN03813426.8A patent/CN1290917C/zh not_active Expired - Lifetime
- 2003-06-10 JP JP2004513375A patent/JP2005529227A/ja active Pending
- 2003-06-10 AT AT03738009T patent/ATE373692T1/de not_active IP Right Cessation
- 2003-06-10 RU RU2005100045/04A patent/RU2337114C2/ru not_active IP Right Cessation
- 2003-06-10 DE DE60316437T patent/DE60316437T2/de not_active Expired - Lifetime
- 2003-06-10 ES ES03738009T patent/ES2291651T3/es not_active Expired - Lifetime
- 2003-06-10 AU AU2003245926A patent/AU2003245926B2/en not_active Ceased
- 2003-06-10 CA CA002483206A patent/CA2483206A1/en not_active Abandoned
- 2003-06-10 BR BRPI0311863-0B1A patent/BR0311863B1/pt active IP Right Grant
- 2003-06-10 WO PCT/EP2003/006043 patent/WO2003106553A1/en not_active Ceased
- 2003-06-10 EP EP03738009A patent/EP1511803B1/en not_active Revoked
- 2003-06-11 AR ARP030102077A patent/AR040187A1/es unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5773516A (en) * | 1995-12-06 | 1998-06-30 | Basf Aktiengesellschaft | Propylene polymers |
| EP0885926A2 (en) * | 1997-05-22 | 1998-12-23 | Chisso Corporation | Propylene polymer blends, processes of producing the same, and polypropylene resin compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| BR0311863B1 (pt) | 2013-11-26 |
| DE60316437T2 (de) | 2008-06-26 |
| CN1290917C (zh) | 2006-12-20 |
| RU2337114C2 (ru) | 2008-10-27 |
| CA2483206A1 (en) | 2003-12-24 |
| RU2005100045A (ru) | 2005-06-27 |
| ES2291651T3 (es) | 2008-03-01 |
| WO2003106553A1 (en) | 2003-12-24 |
| CN1659224A (zh) | 2005-08-24 |
| BR0311863A (pt) | 2005-03-15 |
| EP1511803A1 (en) | 2005-03-09 |
| EP1511803B1 (en) | 2007-09-19 |
| AR040187A1 (es) | 2005-03-16 |
| AU2003245926A1 (en) | 2003-12-31 |
| JP2005529227A (ja) | 2005-09-29 |
| US20060167185A1 (en) | 2006-07-27 |
| ATE373692T1 (de) | 2007-10-15 |
| DE60316437D1 (de) | 2007-10-31 |
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