ATE497983T1 - Verfahren zur herstellung von polyurethanweichschaumstoffen - Google Patents
Verfahren zur herstellung von polyurethanweichschaumstoffenInfo
- Publication number
- ATE497983T1 ATE497983T1 AT02794917T AT02794917T ATE497983T1 AT E497983 T1 ATE497983 T1 AT E497983T1 AT 02794917 T AT02794917 T AT 02794917T AT 02794917 T AT02794917 T AT 02794917T AT E497983 T1 ATE497983 T1 AT E497983T1
- Authority
- AT
- Austria
- Prior art keywords
- polyurethane foam
- soft polyurethane
- producing soft
- polyol
- autocatalytic
- Prior art date
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000011496 polyurethane foam Substances 0.000 title abstract 2
- 229920005862 polyol Polymers 0.000 abstract 3
- 150000003077 polyols Chemical class 0.000 abstract 3
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 230000009257 reactivity Effects 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31257601P | 2001-08-15 | 2001-08-15 | |
| PCT/US2002/026222 WO2003016372A1 (en) | 2001-08-15 | 2002-08-15 | Process to manufacture flexible polyurethane foams |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE497983T1 true ATE497983T1 (de) | 2011-02-15 |
Family
ID=23212098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT02794917T ATE497983T1 (de) | 2001-08-15 | 2002-08-15 | Verfahren zur herstellung von polyurethanweichschaumstoffen |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7361695B2 (de) |
| EP (1) | EP1419189B1 (de) |
| JP (1) | JP4220384B2 (de) |
| KR (1) | KR100909946B1 (de) |
| CN (1) | CN1262569C (de) |
| AT (1) | ATE497983T1 (de) |
| BR (1) | BRPI0211861B1 (de) |
| CA (1) | CA2455503C (de) |
| DE (1) | DE60239136D1 (de) |
| ES (1) | ES2357642T3 (de) |
| HU (1) | HU229193B1 (de) |
| MX (1) | MXPA04001427A (de) |
| TW (1) | TW592813B (de) |
| WO (1) | WO2003016372A1 (de) |
| ZA (1) | ZA200400647B (de) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE530588T1 (de) * | 2000-09-13 | 2011-11-15 | Dow Global Technologies Llc | Polyole mit autokatalytischen eigenschaften und polyurethanprodukte |
| US20060281893A1 (en) * | 2003-06-13 | 2006-12-14 | Dow Global Technologies Inc. | Catalyst composition to get polyurethane product with good hydrolysis resitstance |
| DE10337319A1 (de) | 2003-08-12 | 2005-03-17 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| US7078443B2 (en) * | 2003-10-22 | 2006-07-18 | Intellectual Property Holdings, Llc | Viscoelastic foam layer and composition |
| KR100745094B1 (ko) | 2003-10-28 | 2007-08-01 | 미쓰이 가가쿠 폴리우레탄 가부시키가이샤 | 연질 폴리우레탄 폼 및 그 용도 |
| CN1898289B (zh) * | 2003-12-23 | 2010-05-05 | 陶氏环球技术公司 | 使用叔胺封端的聚醚多元醇自动催化产生聚氨酯产品的方法 |
| EP1699840B1 (de) * | 2003-12-23 | 2014-01-22 | Dow Global Technologies LLC | Nichtflüchtige katalysatoren mit iminbindungen und tertiären aminen und daraus hergestellte polyurethanprodukte |
| CA2553728C (en) * | 2004-03-31 | 2012-11-27 | Dow Global Technologies Inc. | A urethane-modified isocyanate composition and polyurethane product therefrom |
| CA2584294A1 (en) * | 2004-11-17 | 2006-05-26 | Francois M. Casati | Acid blocked, amine based, autocatalytic polyols and polyurethane foams made therefrom |
| BRPI0618405B1 (pt) * | 2005-10-14 | 2018-01-02 | Dow Global Technologies Inc. | Artigo compósito, processo para fabricar um artigo compósito, artigo laminado, e tapete |
| MX2009003214A (es) * | 2006-09-25 | 2009-04-06 | Dow Global Technologies Inc | Espumas de poliuretano hechas de polioles de poliester que contienen hidroximetilo y polioles que contienen amina terciaria. |
| US8552078B2 (en) | 2006-10-17 | 2013-10-08 | Air Products And Chemicals, Inc. | Crosslinkers for improving stability of polyurethane foams |
| US8367870B2 (en) | 2007-09-19 | 2013-02-05 | Air Products And Chemicals, Inc. | Autocatalytic polyols |
| EP2072556A1 (de) * | 2007-12-17 | 2009-06-24 | Sika Technology AG | Verfahren zur Herstellung von hydroxyfunktionellen Polymeren, die hieraus gewinnbaren Isocyanatgruppen-endständigen Polyadditionsprodukte sowie deren Verwendung |
| JP5596040B2 (ja) * | 2008-10-24 | 2014-09-24 | ビーエーエスエフ ソシエタス・ヨーロピア | 粘弾性ポリウレタン軟質フォームの製造方法 |
| CN102414234A (zh) * | 2009-03-05 | 2012-04-11 | 陶氏环球技术有限责任公司 | 源自hppo的多元醇以及由该多元醇制备的聚氨酯产品 |
| US20130296449A1 (en) * | 2010-02-26 | 2013-11-07 | Peterson Chemical Technology, Inc. | Polyurethane Gel-Like Polymers, Methods and Use in Flexible Foams |
| US10113043B2 (en) * | 2010-02-26 | 2018-10-30 | Twin Brook Capital Partners, Llc | Polyurethane gel particles, methods and use in flexible foams |
| ES2727720T3 (es) | 2010-06-15 | 2019-10-18 | Dow Global Technologies Llc | Método para la fabricación de productos de recubrimiento de suelo de espuma de poliuretano con fibras de alfombra posteriores al consumo |
| WO2012006539A1 (en) | 2010-07-09 | 2012-01-12 | Air Products And Chemicals, Inc. | Process for producing flexible polyurethane foam |
| MX338585B (es) | 2010-07-09 | 2016-04-22 | Air Prod & Chem | Aditivos para mejorar el desempeño de la espuma de poliuretano. |
| JP5905892B2 (ja) * | 2010-10-01 | 2016-04-20 | ダウ グローバル テクノロジーズ エルエルシー | 低密度高弾性軟質ポリウレタンフォームの製造方法 |
| US9968919B2 (en) | 2011-06-29 | 2018-05-15 | Evonik Degussa Gmbh | Reducing emissions in polyurethane foam |
| US9447223B2 (en) | 2011-07-07 | 2016-09-20 | Air Products And Chemicals, Inc. | Additives for improving natural oil based polyurethane foam performance |
| US9145466B2 (en) | 2011-07-07 | 2015-09-29 | Air Products And Chemicals, Inc. | Process for producing flexible polyurethane foam using natural oil polyols |
| US10106638B2 (en) | 2011-07-29 | 2018-10-23 | Evonik Degussa Gmbh | Reduced emissions low density spray polyurethane foam |
| US9273175B2 (en) | 2011-10-03 | 2016-03-01 | Air Products And Chemicals, Inc. | Tertiary amine composition and method for making the composition |
| CN103946260B (zh) | 2011-11-17 | 2016-09-21 | 气体产品与化学公司 | 具有芳族羧酸的四烷基胍盐的方法、产物、和组合物 |
| WO2013102097A2 (en) | 2011-12-29 | 2013-07-04 | Dow Global Technologies Llc | Cyclic amine compounds, compositions, and polyurethane foams made therefrom |
| MX359155B (es) | 2012-03-30 | 2018-09-17 | Evonik Degussa Gmbh | Proceso de producción de espuma de poliuretano, pre-mezcla, formulación y producto. |
| US10023681B2 (en) | 2012-10-24 | 2018-07-17 | Evonik Degussa Gmbh | Delay action catalyst for improving the stability of polyurethane systems having halogen containing blowing agents |
| JP6191244B2 (ja) * | 2013-05-30 | 2017-09-06 | 旭硝子株式会社 | ポリマー分散ポリオール組成物の製造方法および引火点を上昇させる方法 |
| MX2016007379A (es) | 2013-12-19 | 2016-08-19 | Air Prod & Chem | Nueva composicion de amina no emisiva para la estabilidad de vida en anaquel del sistema mejorada. |
| BR112016022662B1 (pt) | 2014-04-01 | 2021-12-07 | Dow Global Technologies Llc | Composição de iniciador poliol, iniciador de poliol,primeira composição de poliol polimérico e processo para preparar um polímero de poliuretano por reação de uma mistura |
| BR112017005021B1 (pt) | 2014-09-12 | 2021-12-21 | Evonik Operations Gmbh | Espuma de poliuretano de baixas emissões produzida com catalisadores de amina reativos a isocianato |
| ES2919876T3 (es) | 2014-10-13 | 2022-07-28 | Evonik Operations Gmbh | Espuma de poliuretano |
| CA2983681C (en) | 2015-05-05 | 2023-09-05 | Evonik Degussa Gmbh | Delayed action gelling catalyst compositions and methods for making polyurethane polymers |
| JP6843772B2 (ja) | 2015-06-01 | 2021-03-17 | エボニック オペレーションズ ゲーエムベーハー | ポリウレタン用途のための反応性アミン触媒 |
| KR20180018758A (ko) | 2015-06-16 | 2018-02-21 | 에보닉 데구사 게엠베하 | 폴리우레탄 발포체용 알데하이드 스캐빈저 |
| US10696777B2 (en) | 2015-06-16 | 2020-06-30 | Evonik Operations Gmbh | Aldehyde scavengers mixtures for polyurethane foams |
| JP2018519381A (ja) | 2015-06-19 | 2018-07-19 | ダウ グローバル テクノロジーズ エルエルシー | ポリウレタンフォーム製造に有用な自己触媒ポリオール |
| ES2819879T3 (es) | 2016-04-12 | 2021-04-19 | Evonik Operations Gmbh | Composiciones de tensioactivos de copolímeros de siloxano-oxialquileno |
| EP3469012B9 (de) | 2016-06-13 | 2022-04-06 | Dow Global Technologies LLC | Autokatalytische polyole |
| BR112019000637A2 (pt) | 2016-07-11 | 2019-04-24 | Evonik Degussa Gmbh | catalisador, composição catalisadora para produzir espuma de poliuretano, composição de poliuretano, produto de espuma de poliuretano e método para preparar uma espuma de poliuretano |
| US10767008B2 (en) | 2017-01-16 | 2020-09-08 | Covestro Llc | Polymer polyols comprising amine based polyether polyols and a process for preparing these polymer polyols |
| KR102543009B1 (ko) * | 2017-01-23 | 2023-06-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 가요성 폴리우레탄 포움 및 제조 방법 |
| CN107189028B (zh) * | 2017-06-23 | 2020-02-28 | 黎明化工研究设计院有限责任公司 | 一种环保高性能快速脱模聚氨酯反应注射成型组合物及其自催化扩链剂的制备方法 |
| EP3707185A1 (de) | 2017-11-10 | 2020-09-16 | Dow Global Technologies LLC | Polyurethanschaumsystem |
| US20210017324A1 (en) | 2017-11-10 | 2021-01-21 | Dow Global Technologies Llc | Polyurethane foam system |
| US10479862B2 (en) | 2017-12-07 | 2019-11-19 | Covestro Llc | Amine based polymer polyol stabilizers |
| US10526484B2 (en) | 2017-12-20 | 2020-01-07 | Covestro Llc | Dithiocarbonate containing polyols as polymer polyol stabilizers |
| EP3584726A1 (de) * | 2018-06-18 | 2019-12-25 | Covestro Deutschland AG | Verfahren und computersystem zur bestimmung von polymerprodukteigenschaften |
| CN109971007B (zh) * | 2019-04-01 | 2021-05-28 | 江南大学 | 一种常温固化聚氨酯类防雾薄膜及其制备方法 |
| EP3760659A1 (de) * | 2019-07-01 | 2021-01-06 | Covestro Deutschland AG | Amingestartete polyole als einbaubare katalysatoren im hr-schaum |
| US11814566B2 (en) | 2020-07-13 | 2023-11-14 | L&P Property Management Company | Thermally conductive nanomaterials in flexible foam |
| EP3954722A1 (de) | 2020-07-30 | 2022-02-16 | Evonik Operations GmbH | Verfahren und zusammensetzung zur herstellung von polyurethanweichschaum |
| US11738487B2 (en) * | 2021-01-22 | 2023-08-29 | Covestro Llc | Processes for making molded flexible foams and flexible foams produced thereby |
| US20220235168A1 (en) * | 2021-01-22 | 2022-07-28 | Covestro Llc | Processes for making molded flexible foams and flexible foams produced thereby |
| US11597862B2 (en) | 2021-03-10 | 2023-03-07 | L&P Property Management Company | Thermally conductive nanomaterial coatings on flexible foam or fabrics |
| WO2024175628A1 (en) | 2023-02-24 | 2024-08-29 | Evonik Operations Gmbh | Inhibiting solids formation in co2 polyurethane production |
| WO2024245991A1 (en) | 2023-06-01 | 2024-12-05 | Evonik Operations Gmbh | Amine catalysts for polyurethane applications |
| WO2025040451A1 (en) | 2023-08-18 | 2025-02-27 | Evonik Operations Gmbh | Hydrolysis resistance of polyurethane foams |
| WO2025045680A1 (en) | 2023-08-25 | 2025-03-06 | Evonik Operations Gmbh | Method to make bicyclic guanidines |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE235878C (de) | ||||
| US3838076A (en) | 1973-03-12 | 1974-09-24 | Jefferson Chem Co Inc | Polyurethane foams from partially aminated polyether polyols |
| US4049931A (en) | 1975-05-29 | 1977-09-20 | Union Carbide Corporation | Catalyst systems containing dimethylamino ether mono-ols for polyurethane foam formation |
| US4383070A (en) * | 1982-05-27 | 1983-05-10 | Mobay Chemical Corporation | Storage stable polyurethane compositions |
| US4530941A (en) * | 1983-01-26 | 1985-07-23 | The Dow Chemical Company | Reaction injection molded polyurethanes employing high molecular weight polyols |
| US4517313A (en) | 1984-04-11 | 1985-05-14 | Abbott Laboratories | Method of making polyurethane foam |
| DE3435070A1 (de) | 1984-09-25 | 1986-04-03 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von gegebenenfalls geschaeumten polyurethanen, die mit einem anderen werkstoff verbunden oder konfektioniert worden sind |
| DD235878B5 (de) * | 1985-04-02 | 1994-04-28 | Basf Schwarzheide Gmbh | Verfahren zur Herstellung autokatalytisch wirkender Polyetheralkohole |
| GB2199504A (en) * | 1987-01-06 | 1988-07-13 | Peter Egan | Directional dice |
| US4963399A (en) | 1987-03-31 | 1990-10-16 | Union Carbide Chemicals And Plastics Company, Inc. | Polyurethane foam with low vinyl-staining tendencies |
| US5223547A (en) | 1990-11-27 | 1993-06-29 | Kao Corporation | Polyurethane, process for producing the same, and process for producing polyurethane foam |
| DE4135588A1 (de) | 1991-10-29 | 1993-05-06 | Basf Ag, 6700 Ludwigshafen, De | Hochreaktive, tertiaere aminogruppen gebunden enthaltende polyoxyalkylenpolyole, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyisocyanat-polyadditionsprodukten |
| GB9215488D0 (en) | 1992-07-21 | 1992-09-02 | Polyol Int Bv | Isocyanate modified amines as catalysts useful for the preparation of polyurethane materials |
| US5508340A (en) * | 1993-03-10 | 1996-04-16 | R. E. Hart Labs, Inc. | Water-based, solvent-free or low voc, two-component polyurethane coatings |
| IT1270979B (it) | 1993-09-30 | 1997-05-26 | Afros Spa | Procedimento e apparecchiatura per la produzione in continuo di schiume poliuretaniche in blocchi |
| DE4437878A1 (de) | 1994-10-22 | 1996-04-25 | Basf Ag | Verfahren zur Herstellung von fogging-armen Polyurethan-Schaumstoffen und hierfür verwendbare spezielle Polyoxyalkylen-polyole |
| EP0747407B1 (de) | 1995-06-05 | 1999-01-13 | Air Products And Chemicals, Inc. | Hydroxymethylchinuclidin-Katalysatorzusammensetzungen zur Herstellung von Polyurethanschäumen |
| DE19744747A1 (de) | 1997-10-10 | 1999-04-15 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen |
| US5874485A (en) * | 1997-11-10 | 1999-02-23 | Bayer Corporation | Flexible foams and flexible molded foams based on allophanate-modified diphenylmethane diisocyanates and processes for the production of these foams |
| US6762274B2 (en) * | 2000-02-10 | 2004-07-13 | Dow Global Technologies Inc. | Low emission polyurethane polymers made with autocatalytic polyols |
| BR0108384B1 (pt) * | 2000-02-10 | 2011-02-08 | processo para a produção de um produto de poliuretano, composição de poliol autocatalìtica, pré-polìmero e processo. | |
| US6924321B2 (en) * | 2001-08-16 | 2005-08-02 | Dow Global Technologies Inc. | Polyols with autocatalytic characteristics and polyurethane products made therefrom |
-
2002
- 2002-08-14 TW TW091118315A patent/TW592813B/zh not_active IP Right Cessation
- 2002-08-15 JP JP2003521695A patent/JP4220384B2/ja not_active Expired - Fee Related
- 2002-08-15 EP EP02794917A patent/EP1419189B1/de not_active Expired - Lifetime
- 2002-08-15 KR KR1020047002193A patent/KR100909946B1/ko not_active Expired - Fee Related
- 2002-08-15 CN CNB028158555A patent/CN1262569C/zh not_active Expired - Fee Related
- 2002-08-15 WO PCT/US2002/026222 patent/WO2003016372A1/en not_active Ceased
- 2002-08-15 US US10/486,776 patent/US7361695B2/en not_active Expired - Lifetime
- 2002-08-15 AT AT02794917T patent/ATE497983T1/de not_active IP Right Cessation
- 2002-08-15 ES ES02794917T patent/ES2357642T3/es not_active Expired - Lifetime
- 2002-08-15 HU HU0401049A patent/HU229193B1/hu not_active IP Right Cessation
- 2002-08-15 MX MXPA04001427A patent/MXPA04001427A/es active IP Right Grant
- 2002-08-15 BR BRPI0211861A patent/BRPI0211861B1/pt not_active IP Right Cessation
- 2002-08-15 CA CA2455503A patent/CA2455503C/en not_active Expired - Fee Related
- 2002-08-15 DE DE60239136T patent/DE60239136D1/de not_active Expired - Lifetime
-
2004
- 2004-01-27 ZA ZA2004/00647A patent/ZA200400647B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HU229193B1 (hu) | 2013-09-30 |
| EP1419189A1 (de) | 2004-05-19 |
| US7361695B2 (en) | 2008-04-22 |
| BRPI0211861B1 (pt) | 2015-09-08 |
| MXPA04001427A (es) | 2004-06-03 |
| TW592813B (en) | 2004-06-21 |
| ES2357642T3 (es) | 2011-04-28 |
| US20040242718A1 (en) | 2004-12-02 |
| CA2455503A1 (en) | 2003-02-27 |
| DE60239136D1 (de) | 2011-03-24 |
| HUP0401049A3 (en) | 2008-04-28 |
| CA2455503C (en) | 2011-03-22 |
| CN1262569C (zh) | 2006-07-05 |
| KR100909946B1 (ko) | 2009-07-30 |
| JP4220384B2 (ja) | 2009-02-04 |
| CN1541234A (zh) | 2004-10-27 |
| KR20040030084A (ko) | 2004-04-08 |
| WO2003016372A1 (en) | 2003-02-27 |
| HUP0401049A2 (hu) | 2004-08-30 |
| JP2005500416A (ja) | 2005-01-06 |
| BR0211861A (pt) | 2004-09-21 |
| EP1419189B1 (de) | 2011-02-09 |
| ZA200400647B (en) | 2005-03-30 |
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