ATE313573T1 - Katalysatorsystem und verfahren zur herstellung von polybutadien - Google Patents
Katalysatorsystem und verfahren zur herstellung von polybutadienInfo
- Publication number
- ATE313573T1 ATE313573T1 AT03727363T AT03727363T ATE313573T1 AT E313573 T1 ATE313573 T1 AT E313573T1 AT 03727363 T AT03727363 T AT 03727363T AT 03727363 T AT03727363 T AT 03727363T AT E313573 T1 ATE313573 T1 AT E313573T1
- Authority
- AT
- Austria
- Prior art keywords
- catalytic system
- sub
- preparation
- rare earth
- alkylaluminium
- Prior art date
Links
- 229920002857 polybutadiene Polymers 0.000 title abstract 3
- 239000005062 Polybutadiene Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 abstract 5
- -1 alicyclic hydrocarbon Chemical class 0.000 abstract 3
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 3
- 125000005234 alkyl aluminium group Chemical group 0.000 abstract 2
- 229940100198 alkylating agent Drugs 0.000 abstract 2
- 239000002168 alkylating agent Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 150000002910 rare earth metals Chemical class 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000003016 phosphoric acids Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0206244 | 2002-05-16 | ||
| PCT/EP2003/004314 WO2003097708A1 (fr) | 2002-05-16 | 2003-04-25 | Systeme catalytique pour preparer des polybutadienes et procede de preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE313573T1 true ATE313573T1 (de) | 2006-01-15 |
Family
ID=29433295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT03727363T ATE313573T1 (de) | 2002-05-16 | 2003-04-25 | Katalysatorsystem und verfahren zur herstellung von polybutadien |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7056998B2 (de) |
| EP (1) | EP1509557B1 (de) |
| JP (1) | JP4685442B2 (de) |
| KR (1) | KR101010865B1 (de) |
| CN (1) | CN100386352C (de) |
| AT (1) | ATE313573T1 (de) |
| AU (1) | AU2003233065A1 (de) |
| BR (1) | BR0309644B8 (de) |
| DE (1) | DE60302891T2 (de) |
| ES (1) | ES2254934T3 (de) |
| MX (1) | MXPA04011261A (de) |
| RU (1) | RU2301811C2 (de) |
| TW (1) | TWI273107B (de) |
| WO (1) | WO2003097708A1 (de) |
| ZA (1) | ZA200407894B (de) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4965055B2 (ja) | 2000-11-10 | 2012-07-04 | 株式会社ブリヂストン | 新規な官能化剤を用いて製造した官能化高シス−１，４−ポリブタジエン |
| JP5318316B2 (ja) * | 2002-11-18 | 2013-10-16 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 炭素原子４個を有するモノオレフィンの存在下でのブタジエンホモポリマーの製造方法 |
| JP4467258B2 (ja) | 2003-06-25 | 2010-05-26 | 株式会社ブリヂストン | ブタジエン系重合体及びその製造方法、並びにそれを用いたゴム組成物及びタイヤ |
| FR2886937B1 (fr) * | 2005-06-14 | 2007-08-10 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene |
| FR2892121B1 (fr) * | 2005-10-19 | 2008-01-04 | Michelin Soc Tech | Procede de preparation en continu d'un systeme catalytique pour polymeriser un diene conjugue, et installation pour sa mise en oeuvre. |
| FR2899903B1 (fr) | 2006-04-14 | 2012-01-06 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene. |
| US20080006833A1 (en) * | 2006-06-02 | 2008-01-10 | Semiconductor Energy Laboratory Co., Ltd. | Lighting device and liquid crystal display device |
| FR2919871B1 (fr) * | 2007-08-08 | 2010-04-23 | Rhodia Operations | Procede de preparation d'une solution d'un organophosphate de terre rare dans un solvant organique |
| RU2515980C2 (ru) | 2007-12-31 | 2014-05-20 | Бриджстоун Корпорейшн | Способ получения полидиенов полимеризацией в объеме |
| US7906592B2 (en) * | 2008-07-03 | 2011-03-15 | Bridgestone Corporation | Polymers functionalized with imide compounds containing a protected amino group |
| FR2939800B1 (fr) | 2008-12-15 | 2011-06-17 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique fonctionnalise, tel qu'un polybutadiene. |
| US8188195B2 (en) | 2008-12-31 | 2012-05-29 | Bridgestone Corporation | Polymers functionalized with nitroso compounds |
| ES2616272T3 (es) | 2009-01-23 | 2017-06-12 | Bridgestone Corporation | Polímeros funcionalizados con compuestos de policiano |
| BRPI1007255B1 (pt) | 2009-01-23 | 2020-01-21 | Bridgestone Corp | polímeros funcionalizados com compostos nitrila contendo um grupo amino protegido |
| FR2945803B1 (fr) * | 2009-05-19 | 2011-07-29 | Michelin Soc Tech | Procede de synthese d'un organophosphate de terre rare et son utilisation pour la preparation d'un systeme calalytique "preforme" |
| FR2946047B1 (fr) * | 2009-06-02 | 2011-07-29 | Michelin Soc Tech | Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation |
| FR2946048B1 (fr) | 2009-06-02 | 2012-12-28 | Michelin Soc Tech | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
| US8338544B2 (en) * | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
| EP2363303A1 (de) * | 2010-02-19 | 2011-09-07 | LANXESS Deutschland GmbH | Bimodales NdBR |
| RU2442653C2 (ru) * | 2010-05-04 | 2012-02-20 | Открытое акционерное общество "Воронежский синтетический каучук" | Способ получения каталитической системы для полимеризации бутадиена и способ получения цис-1,4-полибутадиена |
| US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
| US8962766B2 (en) | 2011-09-15 | 2015-02-24 | Bridgestone Corporation | Polymers functionalized with polyhydrazone compounds |
| FR2984890B1 (fr) * | 2011-12-22 | 2014-06-13 | Michelin Soc Tech | Activation de systemes catalytiques pour la polymerisation stereospecifique des dienes |
| FR2992649B1 (fr) | 2012-07-02 | 2015-06-19 | Michelin & Cie | Procede de synthese en continu d'un elastomere dienique |
| CN104428323B (zh) | 2012-07-04 | 2016-12-07 | 株式会社普利司通 | 聚丁二烯的制造方法、聚丁二烯、橡胶组合物和轮胎 |
| CN103665197B (zh) * | 2012-09-18 | 2015-12-02 | 中国石油天然气股份有限公司 | 一种均相稀土催化剂及其在共轭二烯烃聚合中的应用 |
| CN103224517B (zh) * | 2013-04-17 | 2016-05-11 | 中国石油天然气股份有限公司 | 一种合成溶液型磷酸钕配合物的方法 |
| CN103694378B (zh) * | 2013-12-19 | 2016-08-31 | 华宇橡胶有限责任公司 | 一种合成溶液型稀土橡胶催化剂的方法 |
| CN103694386B (zh) * | 2013-12-19 | 2017-03-08 | 华宇橡胶有限责任公司 | 一种有机磷酸钕催化剂体系的制备方法 |
| FR3015980B1 (fr) | 2014-01-02 | 2016-02-05 | Michelin & Cie | Procede de synthese en continu d'un elastomere dienique fonctionnalise. |
| CN103951776B (zh) * | 2014-04-14 | 2016-08-17 | 华宇橡胶有限责任公司 | 钕系聚丁二烯橡胶聚合过程中催化剂进料方法 |
| RU2671351C2 (ru) | 2014-08-20 | 2018-10-30 | Бриджстоун Корпорейшн | Способ получения терминально модифицированного полимера сопряженного диена, терминально модифицированный полимер сопряженного диена, резиновая композиция и шина |
| KR101853048B1 (ko) * | 2016-11-11 | 2018-04-27 | 금호석유화학 주식회사 | 희토류 알킬인산 용액의 제조방법 |
| CN108219046A (zh) * | 2016-12-15 | 2018-06-29 | 中国石油天然气股份有限公司 | 一种稀土催化剂及其制备方法和应用 |
| KR101897136B1 (ko) * | 2017-03-14 | 2018-09-12 | 금호석유화학 주식회사 | 희토류 알킬인산 용액의 제조방법 |
| FR3069550A1 (fr) | 2017-07-28 | 2019-02-01 | Compagnie Generale Des Etablissements Michelin | Elastomere etendu a la resine |
| EP3720889B1 (de) | 2017-12-05 | 2025-08-06 | Compagnie Générale des Etablissements Michelin | Kontinuierliches verfahren zur herstellung eines dienelastomers |
| FR3081462B1 (fr) * | 2018-05-25 | 2020-05-29 | Compagnie Generale Des Etablissements Michelin | Procede de synthese d'un polybutadiene fonctionnalise |
| FR3096052B1 (fr) | 2019-05-14 | 2021-04-23 | Michelin & Cie | Pneumatique pourvu de flancs externes |
| FR3098518A1 (fr) | 2019-07-09 | 2021-01-15 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc de bande de roulement de pneumatique |
| US12479935B2 (en) | 2019-12-23 | 2025-11-25 | Bridgestone Corporation | Polymerization processes for the production of cis-1,4-polydienes |
| CN116023533B (zh) * | 2021-10-25 | 2025-02-28 | 中国石油化工股份有限公司 | 膦酸酯钕溶液及其制备方法和应用 |
| CN120457135A (zh) * | 2023-01-04 | 2025-08-08 | 尤米科尔特殊材料布鲁日公司 | 烷基磷酸钕溶液的制备方法 |
| CN117209638B (zh) * | 2023-11-08 | 2024-02-13 | 传化智联股份有限公司 | 一种两性离子稀土元素烷基催化剂及其制备方法和应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6023406A (ja) * | 1983-07-18 | 1985-02-06 | Asahi Chem Ind Co Ltd | ポリブタジエンの製造方法 |
| JP2595539B2 (ja) * | 1987-05-29 | 1997-04-02 | 日本合成ゴム株式会社 | 新規な共役ジエン系重合体の製造方法 |
| JPH0822881B2 (ja) * | 1987-08-19 | 1996-03-06 | 旭化成工業株式会社 | 共役ジエン系重合体類の製造方法 |
| DE3877859T2 (de) * | 1987-08-19 | 1993-09-02 | Asahi Chemical Ind | Praepolymerisationsverfahren zur herstellung einer loesung einer konjugierten dienverbindung. |
| JP4067592B2 (ja) * | 1996-12-04 | 2008-03-26 | Ｊｓｒ株式会社 | 共役ジエン系重合体の製造方法 |
| RU2127281C1 (ru) * | 1997-03-11 | 1999-03-10 | Акционерное общество открытого типа "Ефремовский завод синтетического каучука" | Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена |
| RU2139298C1 (ru) * | 1998-04-07 | 1999-10-10 | Открытое акционерное общество "Ефремовский завод синтетического каучука" | Способ получения цис-1,4-полибутадиена |
| EP2206734A1 (de) * | 1999-05-19 | 2010-07-14 | Bridgestone Corporation | Niedermolekulares Polybutadien mit hohem cis-Gehalt |
| AU2002217006A1 (en) * | 2000-11-09 | 2002-05-21 | Michelin Recherche Et Technique S.A. | Catalytic system and method for preparing elastomers using same |
-
2003
- 2003-04-25 EP EP03727363A patent/EP1509557B1/de not_active Expired - Lifetime
- 2003-04-25 WO PCT/EP2003/004314 patent/WO2003097708A1/fr not_active Ceased
- 2003-04-25 JP JP2004506380A patent/JP4685442B2/ja not_active Expired - Lifetime
- 2003-04-25 CN CNB038095475A patent/CN100386352C/zh not_active Expired - Lifetime
- 2003-04-25 MX MXPA04011261A patent/MXPA04011261A/es active IP Right Grant
- 2003-04-25 BR BRPI0309644-0A patent/BR0309644B8/pt active IP Right Grant
- 2003-04-25 RU RU2004136857/04A patent/RU2301811C2/ru active
- 2003-04-25 AU AU2003233065A patent/AU2003233065A1/en not_active Abandoned
- 2003-04-25 DE DE60302891T patent/DE60302891T2/de not_active Expired - Lifetime
- 2003-04-25 ES ES03727363T patent/ES2254934T3/es not_active Expired - Lifetime
- 2003-04-25 KR KR1020047018497A patent/KR101010865B1/ko not_active Expired - Lifetime
- 2003-04-25 AT AT03727363T patent/ATE313573T1/de not_active IP Right Cessation
- 2003-05-06 TW TW092112357A patent/TWI273107B/zh not_active IP Right Cessation
-
2004
- 2004-09-30 ZA ZA200407894A patent/ZA200407894B/xx unknown
- 2004-11-16 US US10/989,031 patent/US7056998B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| TWI273107B (en) | 2007-02-11 |
| BR0309644B8 (pt) | 2013-02-19 |
| DE60302891T2 (de) | 2006-08-03 |
| CN100386352C (zh) | 2008-05-07 |
| DE60302891D1 (de) | 2006-01-26 |
| BR0309644A (pt) | 2005-03-01 |
| TW200406431A (en) | 2004-05-01 |
| US7056998B2 (en) | 2006-06-06 |
| ES2254934T3 (es) | 2006-06-16 |
| RU2004136857A (ru) | 2005-05-27 |
| JP2005530872A (ja) | 2005-10-13 |
| AU2003233065A1 (en) | 2003-12-02 |
| EP1509557A1 (de) | 2005-03-02 |
| US20050130835A1 (en) | 2005-06-16 |
| MXPA04011261A (es) | 2005-02-17 |
| CN1649919A (zh) | 2005-08-03 |
| KR101010865B1 (ko) | 2011-01-26 |
| BR0309644B1 (pt) | 2013-01-08 |
| JP4685442B2 (ja) | 2011-05-18 |
| EP1509557B1 (de) | 2005-12-21 |
| RU2301811C2 (ru) | 2007-06-27 |
| WO2003097708A1 (fr) | 2003-11-27 |
| KR20050000550A (ko) | 2005-01-05 |
| ZA200407894B (en) | 2009-07-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |