ATE313573T1 - Katalysatorsystem und verfahren zur herstellung von polybutadien - Google Patents

Katalysatorsystem und verfahren zur herstellung von polybutadien

Info

Publication number
ATE313573T1
ATE313573T1 AT03727363T AT03727363T ATE313573T1 AT E313573 T1 ATE313573 T1 AT E313573T1 AT 03727363 T AT03727363 T AT 03727363T AT 03727363 T AT03727363 T AT 03727363T AT E313573 T1 ATE313573 T1 AT E313573T1
Authority
AT
Austria
Prior art keywords
catalytic system
sub
preparation
rare earth
alkylaluminium
Prior art date
Application number
AT03727363T
Other languages
English (en)
Inventor
Philippe Laubry
Fanny Barbotin
Original Assignee
Michelin Soc Tech
Michelin Rech Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michelin Soc Tech, Michelin Rech Tech filed Critical Michelin Soc Tech
Application granted granted Critical
Publication of ATE313573T1 publication Critical patent/ATE313573T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT03727363T 2002-05-16 2003-04-25 Katalysatorsystem und verfahren zur herstellung von polybutadien ATE313573T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0206244 2002-05-16
PCT/EP2003/004314 WO2003097708A1 (fr) 2002-05-16 2003-04-25 Systeme catalytique pour preparer des polybutadienes et procede de preparation

Publications (1)

Publication Number Publication Date
ATE313573T1 true ATE313573T1 (de) 2006-01-15

Family

ID=29433295

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03727363T ATE313573T1 (de) 2002-05-16 2003-04-25 Katalysatorsystem und verfahren zur herstellung von polybutadien

Country Status (15)

Country Link
US (1) US7056998B2 (de)
EP (1) EP1509557B1 (de)
JP (1) JP4685442B2 (de)
KR (1) KR101010865B1 (de)
CN (1) CN100386352C (de)
AT (1) ATE313573T1 (de)
AU (1) AU2003233065A1 (de)
BR (1) BR0309644B8 (de)
DE (1) DE60302891T2 (de)
ES (1) ES2254934T3 (de)
MX (1) MXPA04011261A (de)
RU (1) RU2301811C2 (de)
TW (1) TWI273107B (de)
WO (1) WO2003097708A1 (de)
ZA (1) ZA200407894B (de)

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EP1332162B1 (de) 2000-11-10 2013-05-01 Bridgestone Corporation Funktionalisiertes polybutadien mit hohem cis-1,4 anteil hergestellt mit neuen funktionellen verbindungen
AU2003292037A1 (en) * 2002-11-18 2004-06-15 Michelin Recherche Et Technique S.A. Method for obtaining a butadiene hompolymer in the presence of mono-olefin(s) with 4 carbon atoms
JP4467258B2 (ja) 2003-06-25 2010-05-26 株式会社ブリヂストン ブタジエン系重合体及びその製造方法、並びにそれを用いたゴム組成物及びタイヤ
FR2886937B1 (fr) * 2005-06-14 2007-08-10 Michelin Soc Tech Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene
FR2892121B1 (fr) * 2005-10-19 2008-01-04 Michelin Soc Tech Procede de preparation en continu d'un systeme catalytique pour polymeriser un diene conjugue, et installation pour sa mise en oeuvre.
FR2899903B1 (fr) 2006-04-14 2012-01-06 Michelin Soc Tech Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene.
US20080006833A1 (en) * 2006-06-02 2008-01-10 Semiconductor Energy Laboratory Co., Ltd. Lighting device and liquid crystal display device
FR2919871B1 (fr) * 2007-08-08 2010-04-23 Rhodia Operations Procede de preparation d'une solution d'un organophosphate de terre rare dans un solvant organique
JP5345835B2 (ja) 2007-12-31 2013-11-20 株式会社ブリヂストン ポリジエンの製造のためのバルク重合法
US7906592B2 (en) * 2008-07-03 2011-03-15 Bridgestone Corporation Polymers functionalized with imide compounds containing a protected amino group
FR2939800B1 (fr) 2008-12-15 2011-06-17 Michelin Soc Tech Procede de preparation d'un elastomere dienique fonctionnalise, tel qu'un polybutadiene.
US8188195B2 (en) 2008-12-31 2012-05-29 Bridgestone Corporation Polymers functionalized with nitroso compounds
CN102361887B (zh) 2009-01-23 2013-06-26 株式会社普利司通 用包含被保护氨基的腈化合物官能化的聚合物
EP2382241B1 (de) 2009-01-23 2016-11-23 Bridgestone Corporation Mit polycyan-verbindungen funktionalisierte polymere
FR2945803B1 (fr) * 2009-05-19 2011-07-29 Michelin Soc Tech Procede de synthese d'un organophosphate de terre rare et son utilisation pour la preparation d'un systeme calalytique "preforme"
FR2946048B1 (fr) 2009-06-02 2012-12-28 Michelin Soc Tech Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu
FR2946047B1 (fr) 2009-06-02 2011-07-29 Michelin Soc Tech Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation
US8338544B2 (en) * 2009-12-21 2012-12-25 Bridgestone Corporation Polymers functionalized with polyoxime compounds and methods for their manufacture
EP2363303A1 (de) * 2010-02-19 2011-09-07 LANXESS Deutschland GmbH Bimodales NdBR
US8748531B2 (en) 2010-12-10 2014-06-10 Bridgestone Corporation Polymers functionalized with oxime compounds containing an acyl group
US8962766B2 (en) 2011-09-15 2015-02-24 Bridgestone Corporation Polymers functionalized with polyhydrazone compounds
FR2984890B1 (fr) * 2011-12-22 2014-06-13 Michelin Soc Tech Activation de systemes catalytiques pour la polymerisation stereospecifique des dienes
FR2992649B1 (fr) 2012-07-02 2015-06-19 Michelin & Cie Procede de synthese en continu d'un elastomere dienique
US9399689B2 (en) 2012-07-04 2016-07-26 Bridgestone Corporation Method for producing polybutadiene, polybutadiene, rubber composition and tire
CN103665197B (zh) * 2012-09-18 2015-12-02 中国石油天然气股份有限公司 一种均相稀土催化剂及其在共轭二烯烃聚合中的应用
CN103224517B (zh) * 2013-04-17 2016-05-11 中国石油天然气股份有限公司 一种合成溶液型磷酸钕配合物的方法
CN103694386B (zh) * 2013-12-19 2017-03-08 华宇橡胶有限责任公司 一种有机磷酸钕催化剂体系的制备方法
CN103694378B (zh) * 2013-12-19 2016-08-31 华宇橡胶有限责任公司 一种合成溶液型稀土橡胶催化剂的方法
FR3015980B1 (fr) 2014-01-02 2016-02-05 Michelin & Cie Procede de synthese en continu d'un elastomere dienique fonctionnalise.
CN103951776B (zh) * 2014-04-14 2016-08-17 华宇橡胶有限责任公司 钕系聚丁二烯橡胶聚合过程中催化剂进料方法
WO2016027401A1 (ja) 2014-08-20 2016-02-25 株式会社ブリヂストン 末端変性共役ジエン重合体の製造方法、末端変性共役ジエン重合体、ゴム組成物及びタイヤ
KR101853048B1 (ko) * 2016-11-11 2018-04-27 금호석유화학 주식회사 희토류 알킬인산 용액의 제조방법
CN108219046A (zh) * 2016-12-15 2018-06-29 中国石油天然气股份有限公司 一种稀土催化剂及其制备方法和应用
KR101897136B1 (ko) * 2017-03-14 2018-09-12 금호석유화학 주식회사 희토류 알킬인산 용액의 제조방법
FR3069550A1 (fr) 2017-07-28 2019-02-01 Compagnie Generale Des Etablissements Michelin Elastomere etendu a la resine
EP3720889A1 (de) 2017-12-05 2020-10-14 Compagnie Générale des Etablissements Michelin Kontinuierliches verfahren zur herstellung eines dienelastomers
FR3081462B1 (fr) * 2018-05-25 2020-05-29 Compagnie Generale Des Etablissements Michelin Procede de synthese d'un polybutadiene fonctionnalise
FR3096052B1 (fr) 2019-05-14 2021-04-23 Michelin & Cie Pneumatique pourvu de flancs externes
FR3098518A1 (fr) 2019-07-09 2021-01-15 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc de bande de roulement de pneumatique
US20230089837A1 (en) * 2019-12-23 2023-03-23 Steven M. Baldwin Polymerization processes for the production of cis-1,4-polydienes
CN116023533A (zh) * 2021-10-25 2023-04-28 中国石油化工股份有限公司 膦酸酯钕溶液及其制备方法和应用
CN117209638B (zh) * 2023-11-08 2024-02-13 传化智联股份有限公司 一种两性离子稀土元素烷基催化剂及其制备方法和应用

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Publication number Priority date Publication date Assignee Title
JPS6023406A (ja) * 1983-07-18 1985-02-06 Asahi Chem Ind Co Ltd ポリブタジエンの製造方法
JP2595539B2 (ja) * 1987-05-29 1997-04-02 日本合成ゴム株式会社 新規な共役ジエン系重合体の製造方法
DE3877859T2 (de) * 1987-08-19 1993-09-02 Asahi Chemical Ind Praepolymerisationsverfahren zur herstellung einer loesung einer konjugierten dienverbindung.
JPH0822881B2 (ja) * 1987-08-19 1996-03-06 旭化成工業株式会社 共役ジエン系重合体類の製造方法
JP4067592B2 (ja) * 1996-12-04 2008-03-26 Ｊｓｒ株式会社 共役ジエン系重合体の製造方法
WO2000069928A2 (en) * 1999-05-19 2000-11-23 Bridgestone Corporation Low molecular weight high-cis polybutadienes
CN100558767C (zh) * 2000-11-09 2009-11-11 米其林技术公司 催化体系与使用此体系制备弹性体的方法

Also Published As

Publication number Publication date
MXPA04011261A (es) 2005-02-17
TWI273107B (en) 2007-02-11
TW200406431A (en) 2004-05-01
CN1649919A (zh) 2005-08-03
RU2004136857A (ru) 2005-05-27
EP1509557A1 (de) 2005-03-02
KR20050000550A (ko) 2005-01-05
KR101010865B1 (ko) 2011-01-26
RU2301811C2 (ru) 2007-06-27
BR0309644B1 (pt) 2013-01-08
US20050130835A1 (en) 2005-06-16
DE60302891T2 (de) 2006-08-03
AU2003233065A1 (en) 2003-12-02
EP1509557B1 (de) 2005-12-21
BR0309644A (pt) 2005-03-01
BR0309644B8 (pt) 2013-02-19
WO2003097708A1 (fr) 2003-11-27
JP2005530872A (ja) 2005-10-13
ZA200407894B (en) 2009-07-29
JP4685442B2 (ja) 2011-05-18
ES2254934T3 (es) 2006-06-16
CN100386352C (zh) 2008-05-07
US7056998B2 (en) 2006-06-06
DE60302891D1 (de) 2006-01-26

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