AR085417A1 - Composiciones de oxido mixto y proceso para preparar isoolefinas - Google Patents
Composiciones de oxido mixto y proceso para preparar isoolefinasInfo
- Publication number
- AR085417A1 AR085417A1 ARP120100864A ARP120100864A AR085417A1 AR 085417 A1 AR085417 A1 AR 085417A1 AR P120100864 A ARP120100864 A AR P120100864A AR P120100864 A ARP120100864 A AR P120100864A AR 085417 A1 AR085417 A1 AR 085417A1
- Authority
- AR
- Argentina
- Prior art keywords
- isoolefins
- mixed
- mixed oxide
- sio2
- prepare
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 239000011164 primary particle Substances 0.000 abstract 3
- -1 alkyl ether butyl tertiary alcohols Chemical class 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000003776 cleavage reaction Methods 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000007017 scission Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/28—Phosphorising
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
- C07C1/213—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by splitting of esters
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/06—Propene
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
La presente se refiere a la composición de óxidos mixtos, a su uso como un catalizador para la escisión de éteres alquilterbutílicos o alcoholes terciarios, y a un proceso para escindir éteres alquilterbutílicos o alcoholes terciarios a isoolefinas y alcohol o agua.Reivindicación 1: Composición de óxido mixto que comprende un polvo de óxido mixto de silicio y aluminio que está presente en forma predominante o completa en la forma de partículas agregadas primarias y en que a) la relación de peso (AI2O3/SiO2)ttl en la partícula primaria total es 0,002 a 0,05, con preferencia 0,003 a 0,015, con más preferencia 0,005 a 0,01, b) la relación de peso (Al2O3/SiO2)superficie de las partículas primarias en una capa cerca de la superficie que tiene un espesor de aproximadamente 5 nm es menor que en la partícula primaria total y c) el área de superficie BET es 50 a 250 m2/g, con preferencia 100 a 200 m2/g; y óxidos de metal alcalino o metal alcalinotérreo.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011005608A DE102011005608A1 (de) | 2011-03-16 | 2011-03-16 | Mischoxidzusammensetzungen und Verfahren zur Herstellung von Isoolefinen |
Publications (1)
Publication Number | Publication Date |
---|---|
AR085417A1 true AR085417A1 (es) | 2013-10-02 |
Family
ID=45819208
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP120100864A AR085417A1 (es) | 2011-03-16 | 2012-03-16 | Composiciones de oxido mixto y proceso para preparar isoolefinas |
Country Status (16)
Country | Link |
---|---|
US (1) | US9371255B2 (es) |
EP (1) | EP2686289B1 (es) |
JP (1) | JP5877853B2 (es) |
KR (1) | KR101900984B1 (es) |
CN (1) | CN103608318A (es) |
AR (1) | AR085417A1 (es) |
BR (1) | BR112013023454B8 (es) |
DE (1) | DE102011005608A1 (es) |
ES (1) | ES2735278T3 (es) |
MX (1) | MX342213B (es) |
MY (1) | MY173388A (es) |
PL (1) | PL2686289T3 (es) |
RU (1) | RU2596822C2 (es) |
SG (1) | SG193475A1 (es) |
TW (1) | TWI556866B (es) |
WO (1) | WO2012123292A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010042774A1 (de) | 2010-10-21 | 2012-04-26 | Evonik Oxeno Gmbh | Verfahren zur Aufreinigung von MTBE-haltigen Gemischen sowie zur Herstellung von Isobuten durch Spaltung von MTBE-haltigen Gemischen |
DE102012215956A1 (de) | 2012-09-10 | 2014-03-13 | Evonik Industries Ag | Methanolbehandlung von Alumosilicat-haltigen ATAE-Spaltkatalysatoren |
EP3822244A1 (de) | 2019-11-14 | 2021-05-19 | Evonik Operations GmbH | Verfahren zur isomerisierung von olefinen |
US20220380276A1 (en) | 2019-11-14 | 2022-12-01 | Evonik Operations Gmbh | Process for Heterogeneous Isomerization of alpha-Olefins |
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DE102005062700A1 (de) | 2005-12-28 | 2007-07-05 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Buten aus technischen Mischungen von C4-Kohlenwasserstoffen |
DE102006003492A1 (de) | 2006-01-25 | 2007-07-26 | Oxeno Olefinchemie Gmbh | Verfahren zur Entwässerung von Ethanol |
DE102006040430B4 (de) | 2006-08-29 | 2022-06-15 | Evonik Operations Gmbh | Verfahren zur Spaltung von MTBE |
DE102006040432A1 (de) | 2006-08-29 | 2008-03-20 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Herstellung von Isoolefinen |
DE102006040433A1 (de) | 2006-08-29 | 2008-03-13 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Isoolefinen |
DE102006040431A1 (de) * | 2006-08-29 | 2008-03-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Spaltung von MTBE |
DE102006040434A1 (de) | 2006-08-29 | 2008-03-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Spaltung von MTBE |
EP1982764A1 (en) | 2007-04-17 | 2008-10-22 | Evonik Degussa GmbH | Catalyst for the preparation of methyl mercaptan |
DE102007041380A1 (de) | 2007-08-31 | 2009-03-05 | Evonik Oxeno Gmbh | Hydrierkatalysator und Verfahren zur Herstellung von Alkoholen durch Hydrierung von Carbonylverbindungen |
DE102008040511A1 (de) | 2008-07-17 | 2010-01-21 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von Isobuten durch Spaltung von MTBE-haltigen Gemischen |
WO2010069690A1 (en) | 2008-12-17 | 2010-06-24 | Evonik Degussa Gmbh | Process for preparing an aluminium oxide powder having a high alpha-al2o3 content |
DE102009027405A1 (de) | 2009-07-01 | 2011-01-05 | Evonik Oxeno Gmbh | Verfahren zur Regeneration eines Katalysators |
DE102009027404A1 (de) | 2009-07-01 | 2011-01-05 | Evonik Oxeno Gmbh | Herstellung von Isobuten durch Spaltung von MTBE |
-
2011
- 2011-03-16 DE DE102011005608A patent/DE102011005608A1/de not_active Withdrawn
-
2012
- 2012-03-07 PL PL12708534T patent/PL2686289T3/pl unknown
- 2012-03-07 SG SG2013069356A patent/SG193475A1/en unknown
- 2012-03-07 ES ES12708534T patent/ES2735278T3/es active Active
- 2012-03-07 KR KR1020137026828A patent/KR101900984B1/ko active IP Right Grant
- 2012-03-07 MY MYPI2013003360A patent/MY173388A/en unknown
- 2012-03-07 MX MX2013010519A patent/MX342213B/es active IP Right Grant
- 2012-03-07 JP JP2013558364A patent/JP5877853B2/ja not_active Expired - Fee Related
- 2012-03-07 CN CN201280023181.9A patent/CN103608318A/zh active Pending
- 2012-03-07 US US14/005,479 patent/US9371255B2/en active Active
- 2012-03-07 WO PCT/EP2012/053835 patent/WO2012123292A1/de active Application Filing
- 2012-03-07 EP EP12708534.8A patent/EP2686289B1/de active Active
- 2012-03-07 BR BR112013023454A patent/BR112013023454B8/pt not_active IP Right Cessation
- 2012-03-07 RU RU2013145966/04A patent/RU2596822C2/ru not_active IP Right Cessation
- 2012-03-13 TW TW101108464A patent/TWI556866B/zh not_active IP Right Cessation
- 2012-03-16 AR ARP120100864A patent/AR085417A1/es active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
KR20140011378A (ko) | 2014-01-28 |
TW201300166A (zh) | 2013-01-01 |
RU2596822C2 (ru) | 2016-09-10 |
ES2735278T3 (es) | 2019-12-17 |
CN103608318A (zh) | 2014-02-26 |
US9371255B2 (en) | 2016-06-21 |
BR112013023454A2 (pt) | 2016-12-06 |
TWI556866B (zh) | 2016-11-11 |
JP2014514996A (ja) | 2014-06-26 |
RU2013145966A (ru) | 2015-04-27 |
MY173388A (en) | 2020-01-22 |
EP2686289B1 (de) | 2019-05-08 |
BR112013023454B8 (pt) | 2019-11-05 |
JP5877853B2 (ja) | 2016-03-08 |
BR112013023454B1 (pt) | 2019-10-22 |
DE102011005608A1 (de) | 2012-09-20 |
SG193475A1 (en) | 2013-10-30 |
EP2686289A1 (de) | 2014-01-22 |
US20140087940A1 (en) | 2014-03-27 |
MX2013010519A (es) | 2013-12-06 |
PL2686289T3 (pl) | 2019-10-31 |
MX342213B (es) | 2016-09-20 |
WO2012123292A1 (de) | 2012-09-20 |
KR101900984B1 (ko) | 2018-09-20 |
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