AR040547A1 - Alquilacion de parafina - Google Patents

Alquilacion de parafina

Info

Publication number
AR040547A1
AR040547A1 AR20030102510A ARP030102510A AR040547A1 AR 040547 A1 AR040547 A1 AR 040547A1 AR 20030102510 A AR20030102510 A AR 20030102510A AR P030102510 A ARP030102510 A AR P030102510A AR 040547 A1 AR040547 A1 AR 040547A1
Authority
AR
Argentina
Prior art keywords
olefin
isobutene
isoparaffin
oligomers
produced
Prior art date
Application number
AR20030102510A
Other languages
English (en)
Original Assignee
Catalytic Distillation Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Catalytic Distillation Tech filed Critical Catalytic Distillation Tech
Publication of AR040547A1 publication Critical patent/AR040547A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1081—Alkanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Un procedimiento para la alquilación de alcano con olefina o con un precursor de olefina tal como un oligómero de olefina terciaria que comprende poner en contacto un sistema líquido que comprende un catalizador ácido, isoparafina y olefina en flujo descendente concurrente en contacto en una zona de reacción con una malla dispersadora bajo condiciones de temperatura y presión para que reaccionen dicha isoparafina y dicha olefina para producir un producto alquilado. Preferiblemente el sistema líquido se mantiene aproximadamente en su punto de ebullición en la zona de reacción. Los oligómeros de olefina han demostrado que funcionan como precursores de olefina y no como olefinas en la reacción. Por lo tanto, por ejemplo, una alquilación de ácido frío usando un oligómero de isobuteno (principalmente dímero y trímero) con isobuteno produce isooctano, donde el isobutano reacciona con las unidades de isobuteno constituyentes de los oligómeros en su base molar. El isooctano producido es esencialmente el mismo que se produce con un procedimiento de ácido frío convencional.
AR20030102510A 2002-08-15 2003-07-11 Alquilacion de parafina AR040547A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/219,877 US6858770B2 (en) 2001-08-21 2002-08-15 Paraffin alkylation

Publications (1)

Publication Number Publication Date
AR040547A1 true AR040547A1 (es) 2005-04-13

Family

ID=31886603

Family Applications (1)

Application Number Title Priority Date Filing Date
AR20030102510A AR040547A1 (es) 2002-08-15 2003-07-11 Alquilacion de parafina

Country Status (17)

Country Link
US (4) US6858770B2 (es)
EP (2) EP2258673A1 (es)
JP (3) JP4542427B2 (es)
KR (1) KR100970799B1 (es)
CN (2) CN101186551B (es)
AR (1) AR040547A1 (es)
AU (1) AU2003238019B2 (es)
BR (2) BR122013007356B1 (es)
CA (2) CA2493862C (es)
EG (1) EG23453A (es)
IN (1) IN2012DN00643A (es)
MX (1) MXPA05001556A (es)
RO (4) RO125602B1 (es)
RU (1) RU2303024C2 (es)
TW (2) TWI327993B (es)
WO (1) WO2004016573A1 (es)
ZA (1) ZA200410027B (es)

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US6774275B2 (en) * 2001-08-21 2004-08-10 Catalytic Distillation Technologies Pulse flow reaction
US20040052703A1 (en) * 2001-08-21 2004-03-18 Catalytic Distillation Technologies Contact structures
RU2366642C2 (ru) 2003-07-15 2009-09-10 Джи Ар Ти, Инк. Синтез углеводородов
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7550643B2 (en) * 2004-04-28 2009-06-23 Precision Combustion, Inc. Isobutane alkylation
US7550644B2 (en) * 2004-05-10 2009-06-23 Precision Combustion, Inc. Isobutane alkylation
US7119244B2 (en) * 2005-01-13 2006-10-10 Catalytic Distillation Technologies Method of removing organic sulfur compounds from alkylate
US7446238B2 (en) * 2005-01-31 2008-11-04 Uop Llc Alkylation process with recontacting in settler
US7408090B2 (en) * 2005-04-07 2008-08-05 Catalytic Distillation Technologies Method of operating downflow boiling point reactors in the selective hydrogenation of acetylenes and dienes
EA020442B1 (ru) 2006-02-03 2014-11-28 ДжиАрТи, ИНК. Способ превращения углеводородного сырья (варианты) и система для его осуществления
CN101395088B (zh) 2006-02-03 2012-04-04 Grt公司 轻气体与卤素的分离方法
US7449612B2 (en) * 2006-04-11 2008-11-11 Catalytic Distillation Technologies Paraffin alkylation process
US7906700B2 (en) * 2006-06-01 2011-03-15 Uop Llc Alkylation of isobutene feeds
US20070299292A1 (en) * 2006-06-23 2007-12-27 Catalytic Distillation Technologies Paraffin alkylation
US7601879B2 (en) * 2006-08-16 2009-10-13 Catalytic Distillation Technologies Paraffin alkylation
US7781634B2 (en) * 2007-01-08 2010-08-24 Catalytic Distillation Technologies Treatment of olefin feed to paraffin alkylation
JP2010528054A (ja) 2007-05-24 2010-08-19 ジーアールティー インコーポレイテッド 可逆的なハロゲン化水素の捕捉及び放出を組み込んだ領域反応器
US7491856B2 (en) 2007-06-27 2009-02-17 H R D Corporation Method of making alkylene glycols
US8304584B2 (en) 2007-06-27 2012-11-06 H R D Corporation Method of making alkylene glycols
US8278494B2 (en) * 2007-06-27 2012-10-02 H R D Corporation Method of making linear alkylbenzenes
US7977525B2 (en) * 2008-01-31 2011-07-12 Catalytic Distillation Technologies H2SO4 alkylation by conversion of olefin feed to oligomers and sulfate esters
US20090200205A1 (en) * 2008-02-11 2009-08-13 Catalytic Distillation Technologies Sulfur extraction from straight run gasoline
US20090275791A1 (en) * 2008-05-05 2009-11-05 Saudi Arabian Oil Company Ceramic foam catalyst support for gasoline alkylation
US8153854B2 (en) * 2008-06-06 2012-04-10 Catalytic Distillation Technologies Gasoline alkylate RVP control
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8415517B2 (en) 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US8119848B2 (en) 2008-10-01 2012-02-21 Catalytic Distillation Technologies Preparation of alkylation feed
US8492603B2 (en) * 2009-01-12 2013-07-23 Catalytic Distillation Technologies Selectivated isoolefin dimerization using metalized resins
US20100204964A1 (en) * 2009-02-09 2010-08-12 Utah State University Lidar-assisted multi-image matching for 3-d model and sensor pose refinement
US7785921B1 (en) * 2009-04-13 2010-08-31 Miasole Barrier for doped molybdenum targets
US8258362B2 (en) * 2009-05-04 2012-09-04 Isp Investments Inc. Method for the production of α, ω-olefins by using the copper catalyzed coupling reaction of a Grignard reagent with an allylic substrate
US20100331599A1 (en) * 2009-06-09 2010-12-30 Bala Subramaniam Alkylation catalyzed by binary mixtures of acid and ionic liquid
US8502006B2 (en) * 2009-09-11 2013-08-06 Catalytic Distillation Technologies Dimerization process
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
WO2011143215A2 (en) 2010-05-10 2011-11-17 Catalytic Distillation Technologies Production of jet and other heavy fuels from isobutanol
RU2445164C1 (ru) * 2010-09-09 2012-03-20 Учреждение Российской Академии Наук Ордена Трудового Красного Знамени Институт Нефтехимического Синтеза Им. А.В. Топчиева Ран (Инхс Ран) Катализатор, способ его получения (варианты) и способ жидкофазного алкилирования изобутана олефинами c2-c4 в его присутствии
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CN103865570B (zh) * 2012-12-11 2016-05-11 中国石油化工集团公司 一种烷基化反应器及方法
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US9522859B2 (en) 2014-12-11 2016-12-20 Uop Llc Methods for recovering ionic liquid fines from a process stream
CN106032472B (zh) * 2015-03-20 2019-04-16 中国石油化工股份有限公司 一种液体酸催化的异构烷烃与烯烃的烷基化反应方法和装置
CN106032349A (zh) * 2015-03-20 2016-10-19 中国石油化工股份有限公司 一种液体酸催化的异构烷烃与烯烃的烷基化反应方法
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CN105032329B (zh) * 2015-08-04 2017-12-29 惠州宇新化工有限责任公司 一种烷基化反应方法及脉冲流反应器
RU2622294C2 (ru) * 2015-09-01 2017-06-14 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный технологический институт (технический университет)" (СПбГТИ(ТУ)) Устройство для алкилирования изобутана олефинами на твердом катализаторе
CN107974280B (zh) * 2016-10-25 2020-05-19 中国石油化工股份有限公司 一种液体酸烷基化反应方法
WO2020242961A1 (en) * 2019-05-24 2020-12-03 Lummus Technology Llc Flexible production of gasoline and jet fuel in alkylation reactor
TWI801918B (zh) 2020-06-29 2023-05-11 美商魯瑪斯科技有限責任公司 用於丁烯之經控制寡聚化的方法

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US315574A (en) * 1885-04-14 Stove
US2091917A (en) * 1933-09-06 1937-08-31 Pennsylvania Petroleum Res Cor Apparatus for treating mineral oils
US2472578A (en) * 1946-03-21 1949-06-07 Atlantic Refining Co Method of contacting fluids
US3155742A (en) * 1961-09-11 1964-11-03 Shell Oil Co Alkylation process
US3435092A (en) * 1966-08-24 1969-03-25 Phillips Petroleum Co Alkylation utilizing fine dispersion of reactants in a constant catalyst mass
IL28565A (en) * 1967-08-25 1971-12-29 Hydro Chem & Mineral Corp Apparatus and process for providing direct contact between a liquid and one or more other fluids
US3725499A (en) * 1968-06-27 1973-04-03 Texaco Inc Alkylation of secondary olefins derived from hydrocarbon compositions containing tertiary olefins
US3839487A (en) * 1971-07-09 1974-10-01 Merichem Co Alkylation utilizing fibers in a conduit reactor
US3759318A (en) * 1972-03-15 1973-09-18 Stratford Eng Corp Contactor improvements
US3999889A (en) * 1975-10-23 1976-12-28 Exxon Research And Engineering Company Mixing head
US4100220A (en) * 1977-06-27 1978-07-11 Petro-Tex Chemical Corporation Dimerization of isobutene
US4301315A (en) * 1977-09-22 1981-11-17 Phillips Petroleum Company Method of producing high octane alkylate gasoline
US4139573A (en) * 1978-04-24 1979-02-13 Uop Inc. Isoparaffin-olefin alkylation utilizing vaporization of normal paraffin to control the reaction temperature
US4242530A (en) 1978-07-27 1980-12-30 Chemical Research & Licensing Company Process for separating isobutene from C4 streams
JPS577259A (en) * 1980-06-18 1982-01-14 Japan Organo Co Ltd Catalyst used in organic reaction
US4313016A (en) 1980-10-23 1982-01-26 Petro-Tex Chemical Corporation Isobutene removal from C4 streams
US4375576A (en) 1981-07-27 1983-03-01 Chemical Research & Licensing Co. Enhanced diisobutene production in the presence of methyl tertiary butyl ether
US5003124A (en) 1982-11-17 1991-03-26 Chemical Research & Licensing Company Oligomerization process
US4540839A (en) 1984-03-26 1985-09-10 Petro-Tex Chemical Corporation Process for the production of polymer gasoline
JPS61291017A (ja) * 1985-06-19 1986-12-20 Hitachi Ltd 充填塔
US4891466A (en) * 1987-11-23 1990-01-02 Uop HF alkylation process
US4783567A (en) * 1987-11-23 1988-11-08 Uop Inc. HF alkylation process
DK168520B1 (da) 1989-12-18 1994-04-11 Topsoe Haldor As Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel
US5420093A (en) 1991-10-25 1995-05-30 Institut Francais Du Petrole Catalyst based on silica and sulfuric acid and its use for the alkylation of paraffins
US5196626A (en) * 1991-11-04 1993-03-23 Mobil Oil Corporation Film type alkylation process
ES2090914T3 (es) 1992-08-20 1996-10-16 Inst Francais Du Petrole Procedimiento de alquilacion de parafinas.
US5345027A (en) * 1992-08-21 1994-09-06 Mobile Oil Corp. Alkylation process using co-current downflow reactor with a continuous hydrocarbon phase
US5792428A (en) 1994-07-18 1998-08-11 Chemical Research & Licensing Company Apparatus for conducting exothermic reactions
US5659096A (en) 1995-06-05 1997-08-19 Phillips Petroleum Company Combination of olefin oligomerization and paraffin alkylation
US5730843A (en) 1995-12-29 1998-03-24 Chemical Research & Licensing Company Catalytic distillation structure
US5785933A (en) * 1997-01-21 1998-07-28 Mobil Oil Corporation Sulfuric acid alkylation reactor system with static mixers
US6000685A (en) 1998-06-29 1999-12-14 Catalytic Distillation Technologies Gas/liquid contact structure
EP0987237B1 (en) * 1998-09-14 2003-11-26 Haldor Topsoe A/S Process for the catalytic alkylation of a hydrocarbon feed
US20040052703A1 (en) * 2001-08-21 2004-03-18 Catalytic Distillation Technologies Contact structures
US20040100220A1 (en) * 2002-11-25 2004-05-27 Zhenxing Fu Weighted higher-order proportional-integral current regulator for synchronous machines

Also Published As

Publication number Publication date
BR122013007356B1 (pt) 2015-07-21
TWI327993B (en) 2010-08-01
CA2493862A1 (en) 2004-02-26
US20040171901A1 (en) 2004-09-02
RO125602B1 (ro) 2013-10-30
CN100379710C (zh) 2008-04-09
US7319180B2 (en) 2008-01-15
CN101186551B (zh) 2012-05-30
CN1659118A (zh) 2005-08-24
RO125601A2 (ro) 2010-07-30
EP2258673A1 (en) 2010-12-08
JP2010209348A (ja) 2010-09-24
KR20050051636A (ko) 2005-06-01
US20050113624A1 (en) 2005-05-26
BR0312605B1 (pt) 2013-07-23
US6995296B2 (en) 2006-02-07
US7250542B2 (en) 2007-07-31
RO125602A2 (ro) 2010-07-30
IN2012DN00643A (es) 2015-08-21
RO125600A2 (ro) 2010-07-30
RU2005106995A (ru) 2005-08-10
US6858770B2 (en) 2005-02-22
JP2010100859A (ja) 2010-05-06
RO125600B1 (ro) 2012-11-29
TWI327994B (en) 2010-08-01
CA2688868A1 (en) 2004-02-26
WO2004016573A1 (en) 2004-02-26
EP1546068A1 (en) 2005-06-29
US20030176755A1 (en) 2003-09-18
TW201004897A (en) 2010-02-01
AU2003238019A1 (en) 2004-03-03
ZA200410027B (en) 2006-07-26
RO123094B1 (ro) 2010-10-29
JP4542427B2 (ja) 2010-09-15
EP1546068A4 (en) 2009-11-25
TW200406368A (en) 2004-05-01
AU2003238019B2 (en) 2009-07-16
CA2493862C (en) 2010-08-24
CN101186551A (zh) 2008-05-28
KR100970799B1 (ko) 2010-07-16
RU2303024C2 (ru) 2007-07-20
CA2688868C (en) 2011-11-01
JP2005539106A (ja) 2005-12-22
EG23453A (en) 2005-09-21
US20040260136A1 (en) 2004-12-23
BR0312605A (pt) 2005-04-19
RO125601B1 (ro) 2012-11-29
MXPA05001556A (es) 2005-04-19

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