ZA200205215B - Redox material for cathodes in non-aqueous batteries. - Google Patents
Redox material for cathodes in non-aqueous batteries. Download PDFInfo
- Publication number
- ZA200205215B ZA200205215B ZA200205215A ZA200205215A ZA200205215B ZA 200205215 B ZA200205215 B ZA 200205215B ZA 200205215 A ZA200205215 A ZA 200205215A ZA 200205215 A ZA200205215 A ZA 200205215A ZA 200205215 B ZA200205215 B ZA 200205215B
- Authority
- ZA
- South Africa
- Prior art keywords
- pvm
- cathode material
- electrochemical cell
- group
- electrolyte
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims description 12
- 239000010406 cathode material Substances 0.000 claims description 46
- 239000003792 electrolyte Substances 0.000 claims description 40
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 15
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 15
- 229910052744 lithium Inorganic materials 0.000 claims description 15
- 239000011777 magnesium Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 239000010405 anode material Substances 0.000 claims description 12
- -1 methyl formate Chemical compound 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
- 239000011244 liquid electrolyte Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 8
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims description 8
- 150000001450 anions Chemical class 0.000 claims description 7
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- 125000005207 tetraalkylammonium group Chemical group 0.000 claims description 6
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 159000000003 magnesium salts Chemical class 0.000 claims description 5
- 125000005910 alkyl carbonate group Chemical group 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- 239000006230 acetylene black Substances 0.000 claims description 3
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 38
- 239000000243 solution Substances 0.000 description 10
- 238000002484 cyclic voltammetry Methods 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 229920001940 conductive polymer Polymers 0.000 description 6
- 238000007599 discharging Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000007784 solid electrolyte Substances 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 5
- 229920006037 cross link polymer Polymers 0.000 description 5
- 230000001351 cycling effect Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 230000005012 migration Effects 0.000 description 5
- 238000013508 migration Methods 0.000 description 5
- 229910013075 LiBF Inorganic materials 0.000 description 4
- 229910013872 LiPF Inorganic materials 0.000 description 4
- 101150058243 Lipf gene Proteins 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 238000010504 bond cleavage reaction Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 231100000053 low toxicity Toxicity 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 125000001741 organic sulfur group Chemical group 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 230000007017 scission Effects 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 150000007944 thiolates Chemical class 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- SXWUDUINABFBMK-UHFFFAOYSA-L dilithium;fluoro-dioxido-oxo-$l^{5}-phosphane Chemical compound [Li+].[Li+].[O-]P([O-])(F)=O SXWUDUINABFBMK-UHFFFAOYSA-L 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 125000004354 sulfur functional group Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000006276 transfer reaction Methods 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- KSJBMDCFYZKAFH-UHFFFAOYSA-N 2-(2-sulfanylethylsulfanyl)ethanethiol Chemical compound SCCSCCS KSJBMDCFYZKAFH-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 229910019445 Mg(ClO4) Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002873 Polyethylenimine Chemical class 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000008364 bulk solution Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 229910001914 chlorine tetroxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000002228 disulfide group Chemical group 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- QDXBVEACAWKSFL-UHFFFAOYSA-N ethenethiol Chemical compound SC=C QDXBVEACAWKSFL-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007717 redox polymerization reaction Methods 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000010405 reoxidation reaction Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Conductive Materials (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/459,478 US6403255B1 (en) | 1999-12-13 | 1999-12-13 | Polyvinyl mercaptan redox material for cathodes in non-aqueous batteries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200205215B true ZA200205215B (en) | 2003-09-11 |
Family
ID=23824950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200205215A ZA200205215B (en) | 1999-12-13 | 2002-06-28 | Redox material for cathodes in non-aqueous batteries. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6403255B1 (fr) |
| EP (1) | EP1332529A2 (fr) |
| JP (1) | JP2003531455A (fr) |
| KR (1) | KR20030014347A (fr) |
| CN (1) | CN1460301A (fr) |
| AU (1) | AU3041601A (fr) |
| BR (1) | BR0016764A (fr) |
| CA (1) | CA2394226A1 (fr) |
| CZ (1) | CZ20022440A3 (fr) |
| HU (1) | HUP0302724A2 (fr) |
| MX (1) | MXPA02005897A (fr) |
| OA (1) | OA12208A (fr) |
| RU (1) | RU2002118688A (fr) |
| WO (1) | WO2001043209A2 (fr) |
| ZA (1) | ZA200205215B (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6403255B1 (en) * | 1999-12-13 | 2002-06-11 | Bar Ilan University | Polyvinyl mercaptan redox material for cathodes in non-aqueous batteries |
| US7241535B2 (en) * | 2001-10-15 | 2007-07-10 | Samsung Sdi Co., Ltd. | Electrolyte for lithium-sulfur batteries and lithium-sulfur batteries comprising the same |
| KR100436712B1 (ko) * | 2001-12-19 | 2004-06-22 | 삼성에스디아이 주식회사 | 캐소드 전극, 그 제조방법 및 이를 채용한 리튬 전지 |
| US8211578B2 (en) * | 2009-06-09 | 2012-07-03 | The Gillette Company | Magnesium cell with improved electrolyte |
| US8877383B2 (en) | 2010-06-21 | 2014-11-04 | Toyota Motor Engineering & Manufacturing North America, Inc. | Magnesium-based battery |
| WO2012168862A1 (fr) | 2011-06-09 | 2012-12-13 | Basf Se | Matériaux d'électrode pour cellules électriques |
| US9093709B2 (en) | 2011-06-09 | 2015-07-28 | Basf Se | Electrode materials for electrical cells |
| JP6528310B2 (ja) * | 2015-02-27 | 2019-06-12 | 国立大学法人山口大学 | ロタキサンネットワークポリマーを含有するポリマー電解質、及びそれを用いたマグネシウム二次電池 |
| JP7304032B2 (ja) * | 2019-06-12 | 2023-07-06 | Ｅｎｅｏｓ株式会社 | 正極材および蓄電デバイス |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60254515A (ja) * | 1984-05-31 | 1985-12-16 | 旭化成株式会社 | 導電性高分子材料 |
| FR2570882B1 (fr) * | 1984-09-21 | 1986-12-05 | Comp Generale Electricite | Matiere active positive a base d'un polymere conducteur electronique pour generateur electrochimique |
| US4833048A (en) * | 1988-03-31 | 1989-05-23 | The United States Of America As Represented By The United States Department Of Energy | Metal-sulfur type cell having improved positive electrode |
| US5162175A (en) * | 1989-10-13 | 1992-11-10 | Visco Steven J | Cell for making secondary batteries |
| US5324599A (en) * | 1991-01-29 | 1994-06-28 | Matsushita Electric Industrial Co., Ltd. | Reversible electrode material |
| JP2936097B2 (ja) * | 1997-04-22 | 1999-08-23 | 錦湖石油化學 株式會▲社▼ | 複合電極およびそれから得られる二次電池 |
| US6090504A (en) * | 1997-09-24 | 2000-07-18 | Korea Kumho Petrochemical Co., Ltd. | High capacity composite electrode and secondary cell therefrom |
| US6403255B1 (en) * | 1999-12-13 | 2002-06-11 | Bar Ilan University | Polyvinyl mercaptan redox material for cathodes in non-aqueous batteries |
-
1999
- 1999-12-13 US US09/459,478 patent/US6403255B1/en not_active Expired - Fee Related
-
2000
- 2000-12-12 JP JP2001543794A patent/JP2003531455A/ja active Pending
- 2000-12-12 RU RU2002118688/09A patent/RU2002118688A/ru not_active Application Discontinuation
- 2000-12-12 KR KR1020027007495A patent/KR20030014347A/ko not_active Application Discontinuation
- 2000-12-12 OA OA1200200182A patent/OA12208A/en unknown
- 2000-12-12 EP EP00990865A patent/EP1332529A2/fr not_active Withdrawn
- 2000-12-12 WO PCT/IB2000/001994 patent/WO2001043209A2/fr not_active Application Discontinuation
- 2000-12-12 CZ CZ20022440A patent/CZ20022440A3/cs unknown
- 2000-12-12 CA CA002394226A patent/CA2394226A1/fr not_active Abandoned
- 2000-12-12 HU HU0302724A patent/HUP0302724A2/hu unknown
- 2000-12-12 CN CN00819639A patent/CN1460301A/zh active Pending
- 2000-12-12 MX MXPA02005897A patent/MXPA02005897A/es unknown
- 2000-12-12 AU AU30416/01A patent/AU3041601A/en not_active Abandoned
- 2000-12-12 BR BR0016764-9A patent/BR0016764A/pt not_active IP Right Cessation
-
2002
- 2002-06-28 ZA ZA200205215A patent/ZA200205215B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CZ20022440A3 (cs) | 2003-03-12 |
| CN1460301A (zh) | 2003-12-03 |
| JP2003531455A (ja) | 2003-10-21 |
| HUP0302724A2 (hu) | 2004-01-28 |
| RU2002118688A (ru) | 2004-03-10 |
| EP1332529A4 (fr) | 2003-08-06 |
| BR0016764A (pt) | 2003-11-18 |
| CA2394226A1 (fr) | 2001-06-14 |
| US6403255B1 (en) | 2002-06-11 |
| OA12208A (en) | 2006-05-09 |
| EP1332529A2 (fr) | 2003-08-06 |
| WO2001043209A2 (fr) | 2001-06-14 |
| WO2001043209A3 (fr) | 2003-04-17 |
| AU3041601A (en) | 2001-06-18 |
| MXPA02005897A (es) | 2003-10-14 |
| KR20030014347A (ko) | 2003-02-17 |
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