WO2022270380A1 - 有機溶剤回収システム - Google Patents
有機溶剤回収システム Download PDFInfo
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- WO2022270380A1 WO2022270380A1 PCT/JP2022/023971 JP2022023971W WO2022270380A1 WO 2022270380 A1 WO2022270380 A1 WO 2022270380A1 JP 2022023971 W JP2022023971 W JP 2022023971W WO 2022270380 A1 WO2022270380 A1 WO 2022270380A1
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- Prior art keywords
- organic solvent
- gas
- cooling
- recovery system
- adsorption
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- 239000003960 organic solvent Substances 0.000 title claims abstract description 448
- 238000011084 recovery Methods 0.000 title claims abstract description 217
- 238000001816 cooling Methods 0.000 claims abstract description 357
- 238000001179 sorption measurement Methods 0.000 claims description 293
- 238000003795 desorption Methods 0.000 claims description 187
- 238000000034 method Methods 0.000 claims description 165
- 238000004519 manufacturing process Methods 0.000 claims description 39
- 239000003507 refrigerant Substances 0.000 claims description 21
- 230000006835 compression Effects 0.000 abstract 6
- 238000007906 compression Methods 0.000 abstract 6
- 239000007789 gas Substances 0.000 description 617
- 239000003463 adsorbent Substances 0.000 description 68
- 230000002093 peripheral effect Effects 0.000 description 45
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 42
- 238000009833 condensation Methods 0.000 description 40
- 230000005494 condensation Effects 0.000 description 40
- 238000000926 separation method Methods 0.000 description 38
- 230000008929 regeneration Effects 0.000 description 30
- 238000011069 regeneration method Methods 0.000 description 30
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 28
- 238000010586 diagram Methods 0.000 description 28
- 238000010926 purge Methods 0.000 description 25
- 229910021536 Zeolite Inorganic materials 0.000 description 21
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 21
- 239000010457 zeolite Substances 0.000 description 21
- 239000007788 liquid Substances 0.000 description 20
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 18
- 239000012530 fluid Substances 0.000 description 17
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 239000000741 silica gel Substances 0.000 description 10
- 229910002027 silica gel Inorganic materials 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 238000005192 partition Methods 0.000 description 9
- 230000002209 hydrophobic effect Effects 0.000 description 7
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 6
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 6
- 239000012267 brine Substances 0.000 description 6
- 239000000498 cooling water Substances 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000000112 cooling gas Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0027—Condensation of vapours; Recovering volatile solvents by condensation by direct contact between vapours or gases and the cooling medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0003—Condensation of vapours; Recovering volatile solvents by condensation by using heat-exchange surfaces for indirect contact between gases or vapours and the cooling medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0057—Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
Definitions
- This disclosure relates to an organic solvent recovery system.
- a combination of a cooling condensation device and a concentrating device using an adsorption element is known.
- the cooling condensing device condenses and recovers the organic solvent to reduce the concentration of the organic solvent in the exhaust gas.
- Concentrators using adsorption elements contact the exhaust gas with reduced organic solvent concentration discharged from the cooling and condensing device with the adsorption element to absorb the organic solvent and further reduce the organic solvent concentration in the exhaust gas.
- a high-temperature gas is blown onto the adsorbent that has adsorbed the solvent to desorb the organic solvent, and the desorbed gas containing the organic solvent at a high concentration is discharged.
- the desorbed gas is returned to the cooling condenser and reprocessed (see Patent Literatures 1 and 2).
- JP 2016-101553 A Japanese Unexamined Patent Application Publication No. 2017-991
- An object of the present disclosure is to provide an organic solvent recovery system capable of recovering an organic solvent from exhaust gas more efficiently.
- the organic solvent recovery system of the present disclosure is an organic solvent recovery system that recovers the organic solvent from the organic solvent-containing exhaust gas emitted from production equipment.
- the organic solvent recovery system includes a cooling condensation device that liquefies and condenses the organic solvent by cooling the exhaust gas containing the organic solvent and discharges it as a cooled gas in which the concentration of the organic solvent is reduced; a first flow path through which the process gas flows; and a first adsorption element that adsorbs the organic solvent contained in the cooled process gas introduced from the first flow path to further increase the concentration of the organic solvent.
- a first concentrator for discharging as a reduced first treated gas, introducing a high-temperature gas to desorb the organic solvent from the first adsorption element, and discharging as a first desorbed gas; and a second adsorption element adsorbs the organic solvent contained in the first process gas introduced from the second circulation path to further increase the concentration of the organic solvent.
- a second concentrator that discharges as a reduced second process gas, introduces hot gas to desorb the organic solvent from the second adsorption element, and discharges as a second desorbed gas. At least two or more of the first concentrating devices are provided, at least one or more of the second concentrating devices are provided, and the number of the second concentrating devices is less than the number of the first concentrating devices.
- the plurality of first concentrators are arranged in parallel with the production equipment.
- At least two cooling and condensing devices are provided, and the number of the first concentrating devices is the same as the number of the cooling and condensing devices.
- the cooling and condensing device includes a network structure that separates the condensed organic solvent and the cooling process gas by contacting the exhaust gas after cooling, and the network structure. and a chamber in which the cooled processing gas after passing through is stored for a certain period of time.
- the cooling and condensing device further includes a heat exchanger that performs the cooling by heat exchange with a refrigerant.
- a plurality of the first concentrators are arranged in the circumferential direction around the cylinder axis of a hollow columnar rotor in which the first adsorption element rotates around the cylinder axis.
- the second concentrator is arranged on a disk-shaped adsorption rotor in which the second adsorption element rotates around the cylinder axis.
- an organic solvent recovery system capable of recovering the organic solvent from the exhaust gas more efficiently.
- FIG. 1 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 1A;
- FIG. FIG. 4 is an example of another configuration diagram of the organic solvent recovery system in Embodiment 1A.
- FIG. 10 is an example of still another configuration diagram of the organic solvent recovery system in Embodiment 1A.
- 1 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 1B;
- FIG. FIG. 4 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 2B; It is a figure which shows roughly the structure of the organic-solvent recovery system of Embodiment 1C.
- FIG. 4 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 2C; It is a figure which shows roughly the structure of the organic-solvent recovery system of Embodiment 3C.
- FIG. 4 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 4C; 1 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 1D; FIG. FIG. 4 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 2D; It is a figure which shows roughly the structure of the organic-solvent recovery system of Embodiment 3D.
- FIG. 4 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 2C; It is a figure which shows roughly the structure of the organic-solvent recovery system of Embodiment 3D.
- FIG. 4 is a diagram schematically showing the configuration of an organic solvent recovery system according to Embodiment 2C; It is a figure which shows roughly
- FIG. 1 is a diagram schematically showing the configuration of an organic solvent recovery system 1A according to Embodiment 1A.
- the organic solvent recovery system 1A is composed of a cooling condenser 100, a concentrator 300, a first circulation path F1, and a second circulation path F2.
- the cooling-condensing device 100 has a cooling section 110 , a separating section 120 and a chamber 123 .
- the exhaust gas G1 containing the organic solvent is cooled by passing through the cooling section 110, and the organic solvent is liquefied and condensed accordingly.
- the exhaust gas G2 is separated into a liquefied and condensed cooled condensate L1 and a cooled processed gas G3 having a reduced organic solvent concentration by passing through the separation section 120 .
- a portion of the cooled process gas (adsorption inlet gas) G 4 is distributed to feed concentrator 300 and exit cooled condenser 100 .
- cooling means and configuration of the cooling unit 110 are not particularly limited, there is a first heat exchanger 111 that cools the exhaust gas by indirect heat exchange between refrigerant such as cooling water, cold water, and brine. Conditions such as the cooling temperature may also be appropriately determined depending on the organic solvent to be recovered.
- the cooling unit 110 may be provided with a second heat exchanger 112 in front of the first heat exchanger 111 that cools the exhaust gas G1 by heat exchange between the remainder (return gas) G6 of the cooling process gas and the exhaust gas G1. good. This is because the heat transfer area and the amount of refrigerant required for the first heat exchanger 111 are reduced.
- the separation means and configuration of the separation unit 120 are not particularly limited, there are net-like structures 121 such as demisters, filters, and meshes that catch droplets by contact.
- the cooled condensate L1 trapped in the mesh-like structure 121 is collected by gravity into a tank 125 arranged below the mesh-like structure 121 and recovered as a recovered liquid L3.
- the chamber 123 is a structure having a certain amount of space. A part of the cooling process gas (adsorption inlet gas) G4 to be supplied to the concentrator 300 and the rest of the cooling process gas (return gas) G6 are distributed.
- the chamber 123 has a partition part 128 that allows the intake of the first flow path F1 so as to face the exhaust direction of the cooling process gas G3 discharged from the mesh structure 121 .
- the concentrator 300 has an adsorption element 310 containing an adsorbent that adsorbs the contained organic solvent when it comes into contact with the gas and desorbs the adsorbed organic solvent when it comes into contact with the heated gas.
- the adsorption element 310 also includes a desorption section (desorption zone) 311 and an adsorption section (adsorption zone) 312 .
- a part of the cooling process gas (adsorption inlet gas) G4 is introduced, and a part of the cooling process gas (adsorption inlet gas) G4 is brought into contact with the adsorbent.
- the organic solvent contained in the inlet gas) G4 is adsorbed by the adsorbent, whereby part of the cooling process gas (adsorption inlet gas) G4 is cleaned and discharged as clean gas G9.
- the organic solvent is desorbed from the adsorbent by introducing a gas G10 having a higher temperature than a part of the cooling process gas (adsorption inlet gas) G4 into the adsorbent, thereby desorbing the organic solvent. It is discharged as gas G11.
- activated alumina, silica gel, activated carbon material, and zeolite are widely used, and among them, activated carbon and hydrophobic zeolite are particularly preferably used.
- activated carbon and hydrophobic zeolite are excellent in the function of adsorbing and desorbing low-concentration organic compounds, and have been used as adsorbents in various devices for a long time.
- the specific configuration of the concentrator in the embodiment is not particularly limited, as shown in FIG. is known to rotate the adsorption section 312 so that the adsorbent that adsorbs the organic solvent in the part of the cooling process gas (adsorption inlet gas) G4 is continuously moved to the desorption section 311 .
- the desorption section 311 is preferably arranged below the adsorption section 312 as shown in FIG. This is because even when part of the organic solvent contained in the desorption gas G11 is liquefied and condensed to generate the desorption condensate L2, the desorption condensate L2 is less likely to adhere to the adsorption unit 312.
- the desorbed condensate L2 falls downward from the desorbing portion 311 and is collected along the inner surface of the exterior of the desorbing portion. More preferably, as shown in FIG. 1, the attachment/detachment portion 311 is inclined downward. This is because the desorbed condensate L2 falls more easily.
- the concentrating device 300 may have a purge section (not shown) in which the portion of the desorption section 311 that has completed the desorption process is transferred before transfer to the adsorption section 312 .
- a part of the clean gas G9 may be introduced into the purge section, and the purge section outlet gas discharged from the purge section may be introduced into the adsorption section 312 . This is because, by purging the adsorbent that has been completely desorbed with the clean gas G9, the desorbed gas G11 remaining in the adsorbent can be prevented from being mixed with the clean gas G9, and the adsorbent can be cooled.
- the high-temperature gas G10 used for desorption is preferably a part of the clean gas G9 heated to a high temperature using heating means such as the regeneration heater 350. This is because the amount of air to be processed for the organic solvent-containing gas in the adsorption section 312 does not increase.
- the temperature of the exhaust gas G1 is 50 to 200° C., it is more preferable to heat a part of the exhaust gas G1 with the regeneration heater 350 or the like before use. This is because the utility of the regeneration heater 350 can be reduced by using the high-temperature exhaust gas G1 for desorption, and the regeneration heater 350 becomes unnecessary for desorption depending on the temperature of the exhaust gas G1. Further, it is assumed that the exhaust gas G1 and the desorption gas G11 pass through the cooling and condensing device 100 at a ratio of 0% to 50% and 50% to 100%, respectively.
- the first flow path F1 is a part that introduces part of the cooling process gas (adsorption inlet gas) G4 from the chamber 123 to the concentrator 300.
- the connection port of the first flow path F1 to the chamber 123 is preferably the ceiling portion 127 of the chamber 123 . This is to prevent a small amount of liquid droplets that could not be captured by the separation unit 120 from entering the concentrating device 300, thereby preventing deterioration in performance and strength due to wetting of the adsorption element 310 of the concentrating device 300, which will be described later.
- the partition 128 should be provided so as to take out a part of the cooling process gas (adsorption inlet gas) G4 so as to be opposed to the ventilation direction of the cooling process gas G3.
- a liquid droplet penetration prevention member similar to the mesh structure 121 may be provided at the outlet of part of the cooling process gas (adsorption inlet gas) G4, or a heater for vaporizing liquid droplets may be provided. may be provided.
- the second flow path F2 is a part that returns the desorption gas G11 to the exhaust gas G1 introduction part of the cooling/condensing device 100.
- the second flow path F2 is preferably connected so that the desorption section 311 is arranged above the position where the desorption gas G11 and the exhaust gas G1 supplied to the cooling/condensing device 100 join. This is because the desorbed condensate L2 generated from the desorbed gas G11 of the concentrator 300 easily moves to the cooling condensing device 100 . More preferably, it should be configured such that it is ventilated in two places, the exhaust gas G1 introduction part of the cooling and condensing device 100 and the tank 125 . This is because the desorbed condensed liquid L2 generated from the desorbed gas G11 can be easily collected directly into the tank 125 .
- the high-temperature gas G10 used for desorption of the concentrator 300 of the organic solvent recovery system 1A in the embodiment is preferably a part of the clean gas G9 heated to a high temperature using a heating means such as the regeneration heater 350 as described above.
- a heating means such as the regeneration heater 350 as described above.
- the regeneration heater 350 it is more preferable to use the regeneration heater 350 or the like to raise the temperature of a part of the exhaust gas G1. This is because the utility of the regeneration heater 350 can be reduced by using high-temperature exhaust gas for desorption, and the regeneration heater 350 becomes unnecessary for desorption depending on the temperature of the exhaust gas G1.
- the exhaust gas G1 and the desorption gas G11 pass through the cooling and condensing device 100 at a ratio of 0% to 50% and 50% to 100%, respectively.
- the rest of the cooling process gas (return gas) G6 may be returned to the production facility 130.
- a concentrator 600 for processing the clean gas G9 may be additionally introduced.
- the concentrator 500 and the concentrator 600 may have the same configuration as the concentrator 300 or a different configuration. There is no limit to the number of concentrators to be additionally introduced.
- the desorption gas discharged from any concentrator is returned to the exhaust gas G1 introduction part of the cooling condenser 100 via the second flow path F2.
- the organic solvent contained in the exhaust gas G1 includes an organic solvent that can be liquefied and recovered by cooling at 1°C to 50°C.
- organic solvents are N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N,N-dimethylformamide, N,N-dimethylacetamide and n-decane. These are examples and are not limiting.
- the organic solvent contained may be one or more.
- FIG. 4 is a diagram schematically showing the configuration of an organic solvent recovery system 1B according to Embodiment 1B.
- the organic solvent recovery system 1B is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the cooling/condensing device 100 has a cooling section 110 and a separating section 120 .
- An exhaust gas G1 containing an organic solvent is discharged from the production facility 130. As shown in FIG.
- the exhaust gas G1 is cooled by passing through the cooling section 110 .
- the organic solvent is liquefied and condensed.
- the exhaust gas G2 that has passed through the cooling section 110 is separated into a liquefied and condensed cooling condensate L1 and a cooling process gas G3 with a reduced organic solvent concentration by passing through the separation section 120 .
- Cooled process gas G3 is discharged from cooled condenser 100 to first concentrator 200 through chamber 123 as cooled process gas G4.
- the cooling means and configuration of the cooling unit 110 are not particularly limited.
- a first heat exchanger 111 is used that cools exhaust gas by indirect heat exchange between a refrigerant such as cooling water, cold water, and brine.
- the first heat exchanger 111 is positioned so that the exhaust gas G1 flows vertically.
- the cooling unit 110 is provided with a second heat exchanger 112 in front of the first heat exchanger 111 that cools the exhaust gas G1 by heat exchange between the cooling process gas G6 and the exhaust gas G1, which will be described later.
- the second heat exchanger 112 can reduce the heat transfer area and the amount of refrigerant required for the first heat exchanger 111 .
- a part of the exhaust gas G1 and the cooling process gas G6 is returned to the production facility 130 through the fifth flow path F5.
- Conditions such as the cooling temperature in the first heat exchanger 111 and the second heat exchanger 112 may be appropriately determined according to the organic solvent to be recovered.
- Embodiment 1B uses a reticulated structure 121 such as demisters, filters, and meshes that contact and trap droplets.
- the separation unit 120 has a funnel-shaped receiving unit 122 that receives the cooled condensate L1 containing the organic solvent that has been cooled in the cooling unit 110 .
- the cooled condensate L1 cooled in the cooling part 110 and the cooled condensate L1 trapped in the network structure 121 flow to the receiving part 122 by gravity, and then are collected in the tank 125 arranged below the receiving part 122 . It is liquefied and recovered as recovery liquid L3.
- the chamber 123 is a structure having a certain amount of space.
- a weir 124 is provided in the chamber 123 .
- the weir 124 prevents part of the cooling condensate L1 from moving toward the tip of the chamber 123 and flowing into the first flow path F1 as the cooling gas flow path.
- Weir 124 serves to ensure that cooling condensate L1 is recovered.
- the cooled process gas G3 stored in the chamber 123 for a certain period of time flows through the first flow path F1 as the cooled process gas G4 and is supplied to the first concentration device 200 .
- the direction of flow from the mesh structure 121 to the chamber 123 in the separation unit 120 is relative to the direction of flow from the cooling unit 110 to the separation unit 120.
- the exhaust gas G1 exhaust gas G2, cooling process gas G3 flows in the L-shaped direction.
- the organic solvent recovery system 1B Since the organic solvent recovery system 1B has an L-shaped structure where the cooling unit 110 and the separation unit 120 are configured, it suppresses the exposure of the first concentration device 200 and the second concentration device 300 by droplets and splashes. can do.
- the first concentrator 200 and the second concentrator 300 may be weakened or damaged if exposed and the adsorbent gets wet. Since the organic solvent recovery system 1B has an L-shaped structure, it is possible to prevent the first concentrator 200 and the second concentrator 300 from being weakened or damaged.
- the first concentrator 200 has an adsorption rotor 212 that includes an adsorbent that adsorbs the contained organic solvent by contact with gas and desorbs the adsorbed organic solvent by contact with heated gas.
- the adsorption rotor 212 is composed of a plurality of adsorption units 210 partitioned by a plurality of partitions.
- the suction rotor 212 has a hollow cylindrical shape as a whole due to the plurality of suction units 210 .
- the adsorption rotor 212 is installed in the processing chamber and is provided so that the fluid can flow in the radial direction.
- the attraction rotor 212 is rotatable around the cylinder axis by receiving the rotational driving force of the motor.
- a part of the adsorption unit 210 constitutes an adsorption section that adsorbs the organic solvent contained in the cooled processed gas G4 supplied from the outside to the inside of the adsorption unit 210, and the adsorption unit 210 constitutes a desorption section that desorbs the organic solvent adsorbed by the adsorption unit 210 from the adsorption unit 210 by supplying heated air from the inside to the outside of the adsorption unit 210 .
- the cooled processing gas G4 supplied into the processing chamber is introduced from the outer peripheral surface of the adsorption rotor 212 into the adsorption section.
- the cooled processing gas G4 introduced into the adsorption section adsorbs the organic solvent to the plurality of adsorption units 210 positioned in the adsorption section when passing through the adsorption rotor 212 from the outer peripheral surface to the inner peripheral surface along the radial direction. It is purified by letting
- the cooled process gases G5 and G6 as the cleaned fluid to be processed are discharged from the upper part of the adsorption unit 210 as clean gas.
- a part of the discharged clean gas flows through the second flow path F2 as the cooled processed gas G5 and is supplied to the second concentrator 300.
- a part of the discharged clean gas flows through the fourth flow path F4 as the cooled processed gas G6 and is returned to the second heat exchanger 112 .
- the inner peripheral side flow path forming member 211 and the outer peripheral side flow path forming member 213 are arranged facing each other on the inner peripheral side and the outer peripheral side of the adsorption rotor 212 so as to sandwich a part of the adsorption rotor 212 in the circumferential direction. ing.
- a region of the adsorption rotor 212 sandwiched between the inner peripheral side flow path forming member 211 and the outer peripheral side flow path forming member 213 is a detachable portion.
- the hot gas G7 which is a part of the cooling process gas G5 heated by the regeneration heater 250, is introduced from the inner peripheral side passage forming member 211 to the desorption portion.
- the high-temperature gas G7 introduced into the desorption section when passing through the adsorption rotor 212, thermally desorbs the organic solvent adsorbed by the plurality of adsorption units 210 located in the desorption section.
- the desorption gas G8 containing the organic solvent is discharged as a concentrated gas from the desorption section through the outer peripheral side flow path forming member 213 to the outside of the processing chamber and returned to the third flow path F3.
- a part of the organic solvent contained in the desorption gas G8 is liquefied and condensed and collected in the tank 125 as the desorption condensate L2.
- the third flow path F3 is a part for returning the desorption gas G8 and the later-described desorption gas G11 to the exhaust gas G1 introduction part of the cooling and condensing device 100.
- the third flow path F3 is preferably connected so that the desorption section is arranged above the position where the desorption gas and the exhaust gas G1 supplied to the cooling/condensing device 100 join. This is because the desorbed condensate L2 generated from the desorbed gas G8 of the first concentrator 200 and the desorbed gas G11 of the second concentrator 300 easily moves to the cooling condenser 100 .
- the third flow path F3 is configured so as to pass through two points, the inlet of the exhaust gas G1 of the cooling and condensing device 100 and the tank 125 . This is because the desorbed condensed liquid L2 generated from the desorbed gas G8 and the desorbed gas G11 can be easily collected directly into the tank 125 .
- the adsorption unit 210 located in the adsorption section performs adsorption processing of the substance to be processed, and after the adsorption processing, the adsorption unit 210 located in the desorption section performs desorption processing of the substance to be processed. done.
- the adsorption rotor 212 rotates around the cylindrical axis, the adsorption unit 210 alternately moves between the desorption section and the adsorption section, and adsorption and desorption of the substance to be treated are continuously performed.
- Activated alumina, silica gel, activated carbon material, zeolite, and the like can be used as materials for the adsorption elements that constitute the adsorption unit 210 .
- the shape of the adsorption element in the adsorption unit 210 is not particularly limited, and may be, for example, a honeycomb-shaped sheet containing an activated carbon material or zeolite, or a laminate of activated carbon fiber nonwoven fabrics.
- the second concentrator 300 has an adsorption element 310 containing an adsorbent that adsorbs the contained organic solvent by contact with gas and desorbs the adsorbed organic solvent by contact with heated gas.
- the adsorption element 310 includes a desorption section (desorption zone) 311 and an adsorption section (adsorption zone) 312 .
- the cooling process gas G5 is introduced into the adsorbent, and the cooling process gas G5 is brought into contact with the adsorbent. is cleaned and discharged as clean gas G9.
- the high-temperature gas G10 having a higher temperature than the cooling process gas G5 is introduced into the adsorbent, whereby the organic solvent is desorbed from the adsorbent and discharged as the desorbed gas G11 containing the organic solvent.
- activated alumina, silica gel, activated carbon material, and zeolite are widely used, and among them, activated carbon and hydrophobic zeolite are particularly preferably used.
- the second concentrator 300 includes a rotating shaft and an adsorption element 310 provided around the rotating shaft.
- the second concentrating device 300 rotates the adsorption element 310 around the rotation axis, so that the adsorbent that adsorbs the organic solvent in the cooling process gas G5 introduced from the second flow path F2 is continuous in the adsorption section 312. It is configured to move to the detachable portion 311 automatically.
- the desorption section 311 of the second concentrator 300 is arranged below the adsorption section 312 . This is because even when part of the organic solvent contained in the desorption gas G11 is liquefied and condensed to generate the desorption condensate L2, the desorption condensate L2 is less likely to adhere to the adsorption unit 312.
- the desorbed condensate L2 falls downward from the desorption section 311 and is collected along the inner surface of the exterior of the desorption section. More preferably, the desorbing portion 311 is inclined downward so that the desorbed condensate L2 can easily fall downward.
- the second concentrating device 300 may have a cleaning section (purge section) in which the portion where the desorption processing of the desorption section 311 is completed transfers before transferring to the adsorption section 312 .
- a part of the clean gas G9 may be introduced into the purge section, and the purge section outlet gas discharged from the purge section may be introduced into the adsorption section 312 .
- the high-temperature gas G10 used for desorption is preferably a part of the clean gas G9 heated to a high temperature using heating means such as the regeneration heater 350. This is because, in the adsorption section 312, the processing air volume of the organic solvent-containing gas does not increase.
- FIG. 5 is a diagram schematically showing the configuration of an organic solvent recovery system 2B according to Embodiment 2B.
- the organic solvent recovery system 2B is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the organic solvent recovery system 2B is the same as the organic solvent recovery system 1B of Embodiment 1B except that a heater 126 is provided inside the chamber 123 .
- the heater 126 slightly heats the cooled process gas G3 after cooling.
- the cooled process gas G3 can prevent the organic solvent or moisture from condensing by being slightly heated.
- the cooling/condensing device 100 includes a cooling section 110 through which the exhaust gas G1 flows, and a separating section 120 located downstream of the cooling section 110 when viewed along the flow direction of the exhaust gas G1. contains.
- the separation unit 120 separates the cooled condensate L1 and the cooling process gas G3 by bringing the exhaust gas G2 after cooling into contact with the receiving unit 122 that receives the cooled condensate L1 containing the organic solvent cooled in the cooling unit 110. It has a mesh-like structure 121 and a chamber 123 in which the cooled processing gas G3 after passing through the mesh-like structure 121 is stored for a certain period of time.
- the direction of flow from the mesh structure 121 to the chamber 123 in the separation unit 120 intersects with the direction of flow from the cooling unit 110 to the separation unit 120, thereby causing the exhaust gas to flow. It flows in an L-shaped direction.
- the cooled condensate L1 containing the organic solvent can be recovered from the exhaust gas G1 with high efficiency. Since the organic solvent recovery system in the present embodiment has an L-shaped structure where the cooling unit 110 and the separation unit 120 are configured, the first concentration device 200 and the second Exposure of the concentrator 300 can be suppressed.
- a heater 126 for heating the cooling process gas G3 is arranged downstream of the mesh structure 121 in the present embodiment. As a result, it is possible to prevent the organic solvent or moisture from condensing due to the slight heating of the cooling process gas G3.
- a weir 124 is provided in the chamber 123 in the present embodiment. As a result, it is possible to prevent the cooling condensate L1 from flowing into the first circulation path F1 as the cooling gas circulation path.
- the concentrating device in the present embodiment includes a first concentrating device 200 and a second concentrating device 300 located downstream of the first concentrating device.
- the first concentrating device 200 absorbs the organic solvent contained in the cooled processed gas G4 introduced from the first flow path F1 by the adsorption unit 210, and discharges as the cooled processed gas G5 in which the concentration of the organic solvent is further reduced. Then, the high-temperature gas G7 is introduced to desorb the organic solvent from the adsorption unit 210, and the desorbed gas G8 is discharged.
- the organic solvent recovery system in the present embodiment further includes a second flow path F2 that allows a portion of the cooling process gas G5 to flow.
- the organic solvent contained in the processing gas G5 is adsorbed by the adsorption element 310 and discharged as a clean gas G9 in which the concentration of the organic solvent is further reduced. It is discharged as desorption gas G11.
- a plurality of adsorption units 210 are arranged in the circumferential direction around the cylinder axis of a hollow columnar rotor rotating around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- the adsorption element 310 is arranged on a disk-shaped adsorption rotor that rotates around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- two concentrating devices the first concentrating device 200 and the second concentrating device 300
- the concentrator two first concentrators 200 or two second concentrators 300 may be applied depending on the air volume. Also, depending on the removal efficiency, three or more concentrators may be applied.
- Examples of the organic solvent contained in the exhaust gas G1 include organic solvents that can be liquefied and recovered by cooling to 1°C to 50°C.
- Examples of organic solvents are N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N,N-dimethylformamide, N,N-dimethylacetamide and n-decane. These are examples and are not limiting.
- the organic solvent contained may be one or more.
- FIG. 6 is a diagram schematically showing the configuration of an organic solvent recovery system 1C according to Embodiment 1C.
- the organic solvent recovery system 1C is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the cooling/condensing device 100 has a cooling section 110 and a separating section 120 .
- An exhaust gas G1 containing an organic solvent is discharged from the production facility 130. As shown in FIG.
- the exhaust gas G1 is cooled by passing through the cooling section 110 .
- the organic solvent is liquefied and condensed.
- the exhaust gas G2 that has passed through the cooling section 110 is separated into a liquefied and condensed cooling condensate L1 and a cooling process gas G3 with a reduced organic solvent concentration by passing through the separation section 120 .
- Cooled process gas G3 is discharged from cooled condenser 100 to first concentrator 200 through chamber 123 as cooled process gas G4.
- the cooling means and configuration of the cooling unit 110 are not particularly limited.
- the first heat exchanger 111 is used to cool the exhaust gas by indirect heat exchange between a refrigerant such as cooling water, cold water, and brine.
- the first heat exchanger 111 is positioned so that the exhaust gas G1 flows horizontally.
- the cooling unit 110 is provided with a second heat exchanger 112 in front of the first heat exchanger 111 that cools the exhaust gas G1 by heat exchange between the cooling process gas G6 and the exhaust gas G1, which will be described later.
- the second heat exchanger 112 can reduce the heat transfer area and the amount of refrigerant required for the first heat exchanger 111 .
- a part of the exhaust gas G1 and the cooling process gas G6 is returned to the production facility 130 through the fifth flow path F5.
- Conditions such as the cooling temperature in the first heat exchanger 111 and the second heat exchanger 112 may be appropriately determined according to the organic solvent to be recovered.
- Embodiment 1C uses a reticulated structure 121 such as demisters, filters, and meshes that contact and trap droplets.
- the cooled condensate L1 trapped in the mesh-like structure 121 is collected by gravity into a tank 125 arranged below the mesh-like structure 121 and recovered as a recovery liquid L3.
- the chamber 123 is a structure having a certain amount of space.
- the cooled process gas G3 stored in the chamber 123 for a certain period of time flows through the first flow path F1 as the cooled process gas G4 and is supplied to the first concentration device 200 .
- the chamber 123 has a partition part 128 that allows the intake of the first flow path F1 so as to face the exhaust direction of the cooling process gas G3 discharged from the mesh structure 121 .
- the first flow path F1 is a part that introduces the cooled process gas G4 from the chamber 123 to the first concentration device 200.
- the connection port of the first flow path F1 to the chamber 123 is preferably the ceiling portion 127 of the chamber 123 .
- the cooling process gas G4 is taken out so as to be opposed to the ventilation direction of the cooling process gas G3. This makes it possible to further prevent droplets from entering.
- a liquid drop prevention member similar to the mesh structure 121 may be provided at the outlet of the cooling process gas G4, or a heater for vaporizing the liquid drops may be provided.
- the first concentrator 200 has an adsorption rotor 212 that includes an adsorbent that adsorbs the contained organic solvent by contact with gas and desorbs the adsorbed organic solvent by contact with heated gas.
- the adsorption rotor 212 is composed of a plurality of adsorption units 210 partitioned by a plurality of partitions.
- the suction rotor 212 has a hollow cylindrical shape as a whole due to the plurality of suction units 210 .
- the adsorption rotor 212 is installed in the processing chamber and is provided so that the fluid can flow in the radial direction.
- the attraction rotor 212 is rotatable around the cylinder axis by receiving the rotational driving force of the motor.
- a part of the adsorption unit 210 constitutes an adsorption section that adsorbs the organic solvent contained in the cooled processed gas G4 supplied from the outside to the inside of the adsorption unit 210, and the adsorption unit 210 constitutes a desorption section that desorbs the organic solvent adsorbed by the adsorption unit 210 from the adsorption unit 210 by supplying heated air from the inside to the outside of the adsorption unit 210 .
- the cooled processing gas G4 supplied into the processing chamber is introduced from the outer peripheral surface of the adsorption rotor 212 into the adsorption section.
- the cooled processing gas G4 introduced into the adsorption section adsorbs the organic solvent to the plurality of adsorption units 210 positioned in the adsorption section when passing through the adsorption rotor 212 from the outer peripheral surface to the inner peripheral surface along the radial direction. It is purified by letting
- the cooled process gases G5 and G6 as the cleaned fluid to be processed are discharged from the upper part of the adsorption unit 210 as clean gas.
- a part of the discharged clean gas flows through the second flow path F2 as the cooled processed gas G5 and is supplied to the second concentrator 300.
- a part of the discharged clean gas flows through the fourth flow path F4 as the cooled processed gas G6 and is returned to the second heat exchanger 112 .
- the inner peripheral side flow path forming member 211 and the outer peripheral side flow path forming member 213 are arranged facing each other on the inner peripheral side and the outer peripheral side of the adsorption rotor 212 so as to sandwich a part of the adsorption rotor 212 in the circumferential direction. ing.
- a region of the adsorption rotor 212 sandwiched between the inner peripheral side flow path forming member 211 and the outer peripheral side flow path forming member 213 is a detachable portion.
- the hot gas G7 which is a part of the cooling process gas G5 heated by the regeneration heater 250, is introduced from the inner peripheral side passage forming member 211 to the desorption portion.
- the high-temperature gas G7 introduced into the desorption section when passing through the adsorption rotor 212, thermally desorbs the organic solvent adsorbed by the plurality of adsorption units 210 located in the desorption section.
- the desorption gas G8 containing the organic solvent is discharged as a concentrated gas from the desorption section through the outer peripheral side flow path forming member 213 to the outside of the processing chamber and returned to the third flow path F3.
- a part of the organic solvent contained in the desorption gas G8 is liquefied and condensed and collected in the tank 125 as the desorption condensate L2.
- the third flow path F3 is a part that returns the desorption gas G8 to the inlet of the exhaust gas G1 of the cooling and condensing device 100.
- the third flow path F3 is preferably connected such that the desorption section is arranged above the confluence position of the desorption gas G8 and the exhaust gas G1 supplied to the cooling/condensing device 100 . This arrangement makes it easier for the desorbed condensate L2 generated from the desorbed gas G8 of the first concentrator 200 to migrate to the cooling condenser 100 .
- the third flow path F3 is configured so as to pass through two points, the inlet of the exhaust gas G1 of the cooling and condensing device 100 and the tank 125 . This configuration makes it easier for the desorbed condensate L2 generated from the desorbed gas G8 to be collected directly into the tank 125 .
- the adsorption unit 210 located in the adsorption section performs adsorption processing of the substance to be processed, and after the adsorption processing, the adsorption unit 210 located in the desorption section performs desorption processing of the substance to be processed. done.
- the adsorption rotor 212 rotates around the cylindrical axis, the adsorption unit 210 alternately moves between the desorption section and the adsorption section, and adsorption and desorption of the substance to be treated are continuously performed.
- Activated alumina, silica gel, activated carbon material, zeolite, and the like can be used as materials for the adsorption elements that constitute the adsorption unit 210 .
- the shape of the adsorption element in the adsorption unit 210 is not particularly limited, and may be, for example, a honeycomb-shaped sheet containing an activated carbon material or zeolite, or a laminate of activated carbon fiber nonwoven fabrics.
- the second concentrator 300 has an adsorption element 310 containing an adsorbent that adsorbs the contained organic solvent by contact with gas and desorbs the adsorbed organic solvent by contact with heated gas.
- the adsorption element 310 includes a desorption section (desorption zone) 311 and an adsorption section (adsorption zone) 312 .
- the cooling process gas G5 is introduced into the adsorbent, and the cooling process gas G5 is brought into contact with the adsorbent. is cleaned and discharged as clean gas G9.
- the high-temperature gas G10 having a higher temperature than the cooling process gas G5 is introduced into the adsorbent, whereby the organic solvent is desorbed from the adsorbent and discharged as the desorbed gas G11 containing the organic solvent.
- the desorption gas G11 is returned to the first flow path F1 along the sixth flow path F6.
- the organic solvent recovery system 1C Since the organic solvent recovery system 1C returns the desorption gas G11 to the first flow path F1, it is not necessary to process the air volume of the desorption gas G11 in the cooling condensation device 100. Therefore, the organic solvent recovery system 1C can contribute to miniaturization and energy saving of the cooling/condensing device 100 .
- the organic solvent recovery system 1C can suppress condensation of NMP (N-methyl-2-pyrrolidone), moisture, etc. contained in the cooling process gas G4 because the desorption gas G11 is at a high temperature.
- activated alumina, silica gel, activated carbon material, and zeolite are widely used, and among them, activated carbon and hydrophobic zeolite are particularly preferably used.
- the second concentrator 300 includes a rotating shaft and an adsorption element 310 provided around the rotating shaft.
- the second concentrating device 300 rotates the adsorption element 310 around the rotation axis, so that the adsorbent that adsorbs the organic solvent in the cooling process gas G5 introduced from the second flow path F2 is continuous in the adsorption section 312. It is configured to move to the detachable portion 311 automatically.
- the second concentrating device 300 may have a cleaning section (purge section) in which the portion where the desorption processing of the desorption section 311 is completed transfers before transferring to the adsorption section 312 .
- a part of the clean gas G9 may be introduced into the purge section, and the purge section outlet gas discharged from the purge section may be introduced into the adsorption section 312 .
- the high-temperature gas G10 used for desorption is preferably a part of the clean gas G9 heated to a high temperature using heating means such as the regeneration heater 350.
- heating means such as the regeneration heater 350.
- FIG. 7 is a diagram schematically showing the configuration of an organic solvent recovery system 2C according to Embodiment 2C.
- the organic solvent recovery system 2C is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the organic solvent recovery system 2C is the same as the organic solvent recovery system 1C of Embodiment 1C except that the desorption gas G11 of the second concentrator 300 is returned to the regeneration heater 250 through the sixth flow path F6. be.
- the organic solvent recovery system 2C returns the desorbed gas G11 to the regeneration heater 250, it is not necessary to process the air volume of the desorbed gas G11 in the cooling condensation device 100 and the first concentrating device 200. Therefore, the organic solvent recovery system 2C can contribute to miniaturization and energy saving of the cooling condensation device 100 and the first concentrating device 200 . The organic solvent recovery system 2C can contribute to energy saving of the regeneration heater 250 because the desorption gas G11 is at a high temperature.
- FIG. 8 is a diagram schematically showing the configuration of an organic solvent recovery system 3C according to Embodiment 3C.
- the organic solvent recovery system 3C is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the desorption gas G11 of the second concentrator 300 is returned to the fourth flow path F4 through the sixth flow path F6.
- the organic solvent recovery system 3C has the same configuration as the organic solvent recovery system 1C of the embodiment 1C except that the desorption gas G11 of the second concentrator 300 is returned to the fourth flow path F4 through the sixth flow path F6. are the same.
- the desorption gas G11 that has flowed through the sixth flow path F6 flows through the fourth flow path F4 together with the cooled processed gas G6 discharged from the second concentrator 300, and is returned to the second heat exchanger 112.
- the organic solvent recovery system 3 ⁇ /b>C eliminates the need for the air volume of the desorbed gas G ⁇ b>11 to be processed in the cooling condensation device 100 and the first concentration device 200 . Therefore, the organic solvent recovery system 3C can contribute to miniaturization and energy saving of the cooling condensation device 100 and the first concentrating device 200 .
- the organic solvent recovery system 3C can improve the temperature of the fluid flowing through the second heat exchanger 112 because the desorption gas G11 is at a high temperature. It can contribute to energy efficiency and energy saving.
- FIG. 9 is a diagram schematically showing the configuration of an organic solvent recovery system 4C according to Embodiment 4C.
- the organic solvent recovery system 4C is composed of a cooling/condensing device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the desorption gas G11 from the second concentrator 300 is returned to the fifth flow path F5 through the sixth flow path F6.
- the organic solvent recovery system 4C has the same configuration as the organic solvent recovery system 1C of the embodiment 1C except that the desorption gas G11 of the second concentrator 300 is returned to the fifth circulation path F5 through the sixth circulation path F6. are the same.
- the desorption gas G11 that has flowed through the sixth flow path F6 flows through the fifth flow path F5 together with part of the exhaust gas G1 and the cooling process gas G6 discharged from the second heat exchanger 112 and is returned to the production facility 130.
- the organic solvent recovery system 4 ⁇ /b>C eliminates the need to process the air volume of the desorption gas G ⁇ b>11 in the cooling condensation device 100 and the first concentration device 200 . Therefore, the organic solvent recovery system 4C can contribute to miniaturization and energy saving of the cooling condenser 100 and the first concentration device 200 .
- the organic solvent recovery system 4C can increase the temperature of the exhaust gas G1 discharged again from the production facility 130 because the desorption gas G11 is at a high temperature. Therefore, the organic solvent recovery system 4C can improve the temperature of the fluid flowing through the second heat exchanger 112, and contributes to downsizing and energy saving of the second heat exchanger 112 for cooling the exhaust gas G1. can contribute.
- the organic solvent recovery system 1C in the present embodiment cools the exhaust gas G1 containing the organic solvent, liquefies and condenses the organic solvent, and discharges it as a cooled processed gas G4 in which the concentration of the organic solvent is reduced.
- a first flow path F1 for flowing the cooling process gas G4 and an adsorption unit 210 adsorbing the organic solvent contained in the cooling process gas G4 introduced from the first flow path F1 to remove the organic solvent.
- a first concentrator 200 that discharges a cooled processed gas G5 with a further reduced concentration, introduces a high-temperature gas G7, desorbs an organic solvent from the adsorption unit 210, and discharges it as a desorbed gas G8;
- the concentration of the organic solvent was further reduced by adsorbing the organic solvent contained in the cooling process gas G5 introduced from the second circulation path F2 and the adsorption element 310, which was introduced from the second circulation path F2.
- a second concentrator 300 that discharges as clean gas G9, introduces hot gas G10 to desorb the organic solvent from the adsorption element 310, and discharges as desorbed gas G11.
- the desorbed gas G8 is returned to the cooling condenser 100, and the desorbed gas G11 is returned to the first flow path F1. Since the organic solvent recovery system 1C returns the desorbed gas G11 to the first flow path F1, it is not necessary to process the air volume of the desorbed gas G11 in the cooling and condensing device 100. FIG. Therefore, the organic solvent recovery system 1C can contribute to miniaturization and energy saving of the cooling/condensing device 100 .
- the organic solvent recovery system 1C can suppress condensation of NMP (N-methyl-2-pyrrolidone), moisture, etc. contained in the cooling process gas G4 because the desorption gas G11 is at a high temperature.
- the desorption gas G8 is returned to the cooling condenser 100, and the desorption gas G11 is returned to the regeneration heater 250. Since the organic solvent recovery system 2C returns the desorbed gas G11 to the regeneration heater 250, it is not necessary to process the air volume of the desorbed gas G11 in the cooling condensation device 100 and the first concentrating device 200. FIG. Therefore, the organic solvent recovery system 2C can contribute to miniaturization and energy saving of the cooling condensation device 100 and the first concentrating device 200 . The organic solvent recovery system 2C can contribute to energy saving of the regeneration heater 250 because the desorption gas G11 is at a high temperature.
- the desorbed gas G8 is returned to the cooling condenser 100, and the desorbed gas G11 is returned to the fourth flow path F4.
- the desorption gas G11 is returned to the second heat exchanger 112 through the fourth flow path F4 together with the cooling process gas G6.
- the organic solvent recovery system 3 ⁇ /b>C eliminates the need for the air volume of the desorbed gas G ⁇ b>11 to be processed in the cooling condensation device 100 and the first concentration device 200 . Therefore, the organic solvent recovery system 3C can contribute to miniaturization and energy saving of the cooling condensation device 100 and the first concentrating device 200 .
- the organic solvent recovery system 3C can improve the temperature of the fluid flowing through the second heat exchanger 112 because the desorption gas G11 is at a high temperature. It can contribute to energy efficiency and energy saving.
- the desorbed gas G8 is returned to the cooling condenser 100, and the desorbed gas G11 is returned to the fifth flow path F5.
- the desorption gas G11 flows through the fifth flow path F5 together with part of the exhaust gas G1 and the cooling process gas G6 discharged from the second heat exchanger 112 and is returned to the production facility 130.
- the organic solvent recovery system 4 ⁇ /b>C eliminates the need to process the air volume of the desorption gas G ⁇ b>11 in the cooling condensation device 100 and the first concentration device 200 . Therefore, the organic solvent recovery system 4C can contribute to miniaturization and energy saving of the cooling condenser 100 and the first concentration device 200 .
- the organic solvent recovery system 4C can increase the temperature of the exhaust gas G1 discharged again from the production facility 130 because the desorption gas G11 is at a high temperature. Therefore, the organic solvent recovery system 4C can improve the temperature of the fluid flowing through the second heat exchanger 112, and contributes to downsizing and energy saving of the second heat exchanger 112 for cooling the exhaust gas G1. can contribute.
- a plurality of adsorption units 210 are arranged in the circumferential direction around the cylinder axis of a hollow columnar rotor rotating around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- the adsorption element 310 is arranged on a disk-shaped adsorption rotor that rotates around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- two concentrating devices the first concentrating device 200 and the second concentrating device 300
- the concentrator two first concentrators 200 or two second concentrators 300 may be applied depending on the air volume. Also, depending on the removal efficiency, three or more concentrators may be applied.
- Examples of the organic solvent contained in the exhaust gas G1 include organic solvents that can be liquefied and recovered by cooling to 1°C to 50°C.
- Examples of organic solvents are N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N,N-dimethylformamide, N,N-dimethylacetamide and n-decane. These are examples and are not limiting.
- the organic solvent contained may be one or more.
- FIG. 10 is a diagram schematically showing the configuration of an organic solvent recovery system 1D according to Embodiment 1D.
- the organic solvent recovery system 1D is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the cooling/condensing device 100 has a cooling section 110 and a separating section 120 .
- An exhaust gas G1 containing an organic solvent is discharged from the production facility 130. As shown in FIG.
- the exhaust gas G1 is cooled by passing through the cooling section 110 .
- the organic solvent is liquefied and condensed.
- the exhaust gas G2 that has passed through the cooling section 110 is separated into a liquefied and condensed cooling condensate L1 and a cooling process gas G3 with a reduced organic solvent concentration by passing through the separation section 120 .
- a part of the cooled process gas G3 is discharged from the cooling condensing device 100 to the first concentration device 200 as the cooling process gas G4 through the chamber 123, and the remaining part is discharged from the cooling condensing device 100 as the cooling process gas G6 to the second heat exchange to be described later. returned to vessel 112 .
- the cooling means and configuration of the cooling unit 110 are not particularly limited.
- a first heat exchanger 111 that cools the exhaust gas by indirect heat exchange between a refrigerant such as cooling water, cold water, and brine is used.
- the first heat exchanger 111 is positioned so that the exhaust gas G1 flows horizontally.
- the cooling unit 110 is provided with a second heat exchanger 112 in front of the first heat exchanger 111 that cools the exhaust gas G1 by heat exchange between the cooling process gas G6 and the exhaust gas G1.
- the second heat exchanger 112 can reduce the heat transfer area and the amount of refrigerant required for the first heat exchanger 111 .
- a part of the exhaust gas G1 and the cooling process gas G6 is returned to the production facility 130 through the fifth flow path F5.
- Conditions such as the cooling temperature in the first heat exchanger 111 and the second heat exchanger 112 may be appropriately determined according to the organic solvent to be recovered.
- Embodiment 1D uses a reticulated structure 121 such as demisters, filters, and meshes that contact and trap droplets.
- the cooled condensate L1 trapped in the mesh-like structure 121 is collected by gravity into a tank 125 arranged below the mesh-like structure 121 and recovered as a recovery liquid L3.
- the chamber 123 is a structure having a certain amount of space. A portion of the cooled process gas G3 stored in the chamber 123 for a certain period of time flows through the first flow path F1 as the cooled process gas G4 and is supplied to the first concentration device 200 . The cooling process gas G3 is returned to the second heat exchanger 112 after the remaining portion flows through the fourth flow path F4 as the cooling process gas G6.
- the chamber 123 has a partition part 128 that allows the intake of the first flow path F1 so as to face the exhaust direction of the cooling process gas G3 discharged from the mesh structure 121 .
- the first flow path F1 is a part that introduces the cooled process gas G4 from the chamber 123 to the first concentration device 200.
- the connection port of the first flow path F1 to the chamber 123 is preferably the ceiling portion 127 of the chamber 123 .
- the cooling process gas G4 is taken out so as to be opposed to the ventilation direction of the cooling process gas G3. This makes it possible to further prevent droplets from entering.
- a liquid drop prevention member similar to the mesh structure 121 may be provided at the outlet of the cooling process gas G4, or a heater for vaporizing the liquid drops may be provided.
- the first concentrator 200 has an adsorption rotor 212 that includes an adsorbent that adsorbs the contained organic solvent by contact with gas and desorbs the adsorbed organic solvent by contact with heated gas.
- the adsorption rotor 212 is composed of a plurality of adsorption units 210 partitioned by a plurality of partitions.
- the suction rotor 212 has a hollow cylindrical shape as a whole due to the plurality of suction units 210 .
- the adsorption rotor 212 is installed in the processing chamber and is provided so that the fluid can flow in the radial direction.
- the attraction rotor 212 is rotatable around the cylinder axis by receiving the rotational driving force of the motor.
- a part of the adsorption unit 210 constitutes an adsorption section that adsorbs the organic solvent contained in the cooled processed gas G4 supplied from the outside to the inside of the adsorption unit 210, and the adsorption unit 210 constitutes a desorption section that desorbs the organic solvent adsorbed by the adsorption unit 210 from the adsorption unit 210 by supplying heated air from the inside to the outside of the adsorption unit 210 .
- the cooled processing gas G4 supplied into the processing chamber is introduced from the outer peripheral surface of the adsorption rotor 212 into the adsorption section.
- the cooled processing gas G4 introduced into the adsorption section adsorbs the organic solvent to the plurality of adsorption units 210 positioned in the adsorption section when passing through the adsorption rotor 212 from the outer peripheral surface to the inner peripheral surface along the radial direction. It is purified by letting
- the cooled process gas G5 as the cleaned fluid to be processed is discharged from the upper part of the adsorption unit 210 as clean gas.
- the discharged clean gas flows through the second flow path F2 as the cooled processed gas G5 and is supplied to the second concentrator 300.
- the inner peripheral side flow path forming member 211 and the outer peripheral side flow path forming member 213 are arranged facing each other on the inner peripheral side and the outer peripheral side of the adsorption rotor 212 so as to sandwich a part of the adsorption rotor 212 in the circumferential direction. ing.
- a region of the adsorption rotor 212 sandwiched between the inner peripheral side flow path forming member 211 and the outer peripheral side flow path forming member 213 is a detachable portion.
- the hot gas G7 which is a part of the cooling process gas G5 heated by the regeneration heater 250, is introduced from the inner peripheral side passage forming member 211 to the desorption portion.
- the high-temperature gas G7 introduced into the desorption section when passing through the adsorption rotor 212, thermally desorbs the organic solvent adsorbed by the plurality of adsorption units 210 located in the desorption section.
- the desorption gas G8 containing the organic solvent is discharged as a concentrated gas from the desorption section through the outer peripheral side flow path forming member 213 to the outside of the processing chamber and returned to the third flow path F3.
- a part of the organic solvent contained in the desorption gas G8 is liquefied and condensed and collected in the tank 125 as the desorption condensate L2.
- the third flow path F3 is a part that returns the desorption gas G8 to the inlet of the exhaust gas G1 of the cooling and condensing device 100.
- the third flow path F3 is preferably connected such that the desorption section is arranged above the confluence position of the desorption gas G8 and the exhaust gas G1 supplied to the cooling/condensing device 100 . This arrangement makes it easier for the desorbed condensate L2 generated from the desorbed gas G8 of the first concentrator 200 to migrate to the cooling condenser 100 .
- the third flow path F3 is configured so as to pass through two points, the inlet of the exhaust gas G1 of the cooling and condensing device 100 and the tank 125 . This configuration makes it easier for the desorbed condensate L2 generated from the desorbed gas G8 to be collected directly into the tank 125 .
- the adsorption unit 210 located in the adsorption section performs adsorption processing of the substance to be processed, and after the adsorption processing, the adsorption unit 210 located in the desorption section performs desorption processing of the substance to be processed. done.
- the adsorption rotor 212 rotates around the cylindrical axis, the adsorption unit 210 alternately moves between the desorption section and the adsorption section, and adsorption and desorption of the substance to be treated are continuously performed.
- Activated alumina, silica gel, activated carbon material, zeolite, and the like can be used as materials for the adsorption elements that constitute the adsorption unit 210 .
- the shape of the adsorption element in the adsorption unit 210 is not particularly limited, and may be, for example, a honeycomb-shaped sheet containing an activated carbon material or zeolite, or a laminate of activated carbon fiber nonwoven fabrics.
- the second concentrator 300 has an adsorption element 310 containing an adsorbent that adsorbs the contained organic solvent by contact with gas and desorbs the adsorbed organic solvent by contact with heated gas.
- the adsorption element 310 includes a desorption section (desorption zone) 311 and an adsorption section (adsorption zone) 312 .
- the cooling process gas G5 is introduced into the adsorbent, and the cooling process gas G5 is brought into contact with the adsorbent. is cleaned and discharged as clean gas G9.
- the high-temperature gas G10 having a higher temperature than the cooling process gas G5 is introduced into the adsorbent, whereby the organic solvent is desorbed from the adsorbent and discharged as the desorbed gas G11 containing the organic solvent.
- the desorption gas G11 is returned to the first flow path F1 along the sixth flow path F6.
- the organic solvent recovery system 1D Since the organic solvent recovery system 1D returns the desorption gas G11 to the first flow path F1, it is not necessary to process the air volume of the desorption gas G11 in the cooling condensation device 100. Therefore, the organic solvent recovery system 1D can contribute to miniaturization and energy saving of the cooling/condensing device 100 .
- the organic solvent recovery system 1D can suppress condensation of NMP (N-methyl-2-pyrrolidone), moisture, etc. contained in the cooling process gas G4 because the desorption gas G11 is at a high temperature.
- activated alumina, silica gel, activated carbon material, and zeolite are widely used, and among them, activated carbon and hydrophobic zeolite are particularly preferably used.
- the second concentrator 300 includes a rotating shaft and an adsorption element 310 provided around the rotating shaft.
- the second concentrating device 300 rotates the adsorption element 310 around the rotation axis, so that the adsorbent that adsorbs the organic solvent in the cooling process gas G5 introduced from the second flow path F2 is continuous in the adsorption section 312. It is configured to move to the detachable portion 311 automatically.
- the second concentrating device 300 may have a cleaning section (purge section) in which the portion where the desorption processing of the desorption section 311 is completed transfers before transferring to the adsorption section 312 .
- a part of the clean gas G9 may be introduced into the purge section, and the purge section outlet gas discharged from the purge section may be introduced into the adsorption section 312 .
- the high-temperature gas G10 used for desorption is preferably a part of the clean gas G9 heated to a high temperature using heating means such as the regeneration heater 350.
- heating means such as the regeneration heater 350.
- FIG. 11 is a diagram schematically showing the configuration of an organic solvent recovery system 2D according to Embodiment 2D.
- the organic solvent recovery system 2D is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the organic solvent recovery system 2D is the same as the organic solvent recovery system 1D of Embodiment 1D except that the desorption gas G11 of the second concentrator 300 is returned to the regeneration heater 250 through the sixth flow path F6. be.
- the organic solvent recovery system 2D Since the organic solvent recovery system 2D returns the desorbed gas G11 to the regeneration heater 250, it is not necessary to process the air volume of the desorbed gas G11 in the cooling condensation device 100 and the first concentration device 200. Therefore, the organic solvent recovery system 2D can contribute to miniaturization and energy saving of the cooling condensation device 100 and the first concentrating device 200 . The organic solvent recovery system 2D can contribute to energy saving of the regeneration heater 250 because the desorption gas G11 is at a high temperature.
- FIG. 12 is a diagram schematically showing the configuration of an organic solvent recovery system 3D according to Embodiment 3D.
- the organic solvent recovery system 3D is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the desorption gas G11 of the second concentrator 300 is returned to the fourth flow path F4 through the sixth flow path F6.
- the organic solvent recovery system 3D has the same configuration as the organic solvent recovery system 1D of Embodiment 1D except that the desorption gas G11 of the second concentrator 300 is returned to the fourth flow path F4 through the sixth flow path F6. are the same.
- the desorption gas G11 that has flowed through the sixth flow path F6 flows through the fourth flow path F4 together with the cooling process gas G6 discharged from the cooling condenser 100, and is returned to the second heat exchanger 112.
- the organic solvent recovery system 3D eliminates the need for the air volume of the desorption gas G11 to be processed in the cooling condensation device 100 and the first concentrating device 200. FIG. Therefore, the organic solvent recovery system 3D can contribute to miniaturization and energy saving of the cooling condensation device 100 and the first concentrating device 200 .
- the organic solvent recovery system 3D can improve the temperature of the fluid flowing through the second heat exchanger 112 because the desorption gas G11 is at a high temperature, and the small size of the second heat exchanger 112 for cooling the exhaust gas G1. It can contribute to energy efficiency and energy saving.
- FIG. 13 is a diagram schematically showing the configuration of an organic solvent recovery system 4D according to Embodiment 4D.
- the organic solvent recovery system 4D is composed of a cooling condensation device 100, a first concentrating device 200, a second concentrating device 300, and various flow paths.
- the desorption gas G11 of the second concentration device 300 is returned to the fifth flow path F5 through the sixth flow path F6.
- the organic solvent recovery system 4D has the same configuration as the organic solvent recovery system 1D of Embodiment 1D except that the desorption gas G11 of the second concentrator 300 is returned to the fifth circulation path F5 through the sixth circulation path F6. are the same.
- the desorption gas G11 that has flowed through the sixth flow path F6 flows through the fifth flow path F5 together with part of the exhaust gas G1 and the cooling process gas G6 discharged from the second heat exchanger 112 and is returned to the production facility 130.
- the organic solvent recovery system 4D eliminates the need for the air volume of the desorbed gas G11 to be processed in the cooling condensation device 100 and the first concentrating device 200. FIG. Therefore, the organic solvent recovery system 4D can contribute to miniaturization and energy saving of the cooling condenser 100 and the first concentration device 200 .
- the organic solvent recovery system 4D can increase the temperature of the exhaust gas G1 discharged again from the production facility 130 because the desorption gas G11 is at a high temperature. Therefore, the organic solvent recovery system 4D can improve the temperature of the fluid flowing through the second heat exchanger 112, and contributes to downsizing and energy saving of the second heat exchanger 112 for cooling the exhaust gas G1. can contribute.
- the organic solvent recovery system 1D in the present embodiment is a cooling condensation device that liquefies and condenses the organic solvent by cooling the exhaust gas G1 containing the organic solvent and discharges it as a cooled processed gas G4 in which the concentration of the organic solvent is reduced.
- a cooling condensation device that liquefies and condenses the organic solvent by cooling the exhaust gas G1 containing the organic solvent and discharges it as a cooled processed gas G4 in which the concentration of the organic solvent is reduced.
- 100 a first circulation path F1 through which a part of the cooling process gas G4 flows, and an adsorption unit 210 adsorbing the organic solvent contained in the cooling process gas G4 introduced from the first circulation path F1.
- a first concentrator 200 that discharges a cooled processed gas G5 in which the concentration of the organic solvent is further reduced, introduces a high-temperature gas G7, desorbs the organic solvent from the adsorption unit 210, and discharges it as a desorbed gas G8, and a cooled processed gas.
- the concentration of the organic solvent was further reduced by adsorbing the organic solvent contained in the second flow path F2 for flowing G5 and the cooling process gas G5 introduced from the second flow path F2 by the adsorption element 310.
- a second concentrator 300 that discharges as clean gas G9, introduces hot gas G10 to desorb the organic solvent from the adsorption element 310, and discharges as desorbed gas G11.
- the cooling/condensing device 100 includes a second heat exchanger 112 that cools the exhaust gas G1 by heat exchange with the refrigerant.
- the organic solvent recovery system 1D further includes a fourth flow path F4 for returning the cooling process gas G6, which is the remainder of the cooling process gas other than a part of the cooling process gas G4, to the second heat exchanger 112.
- the desorbed gas G8 is returned to the cooling condenser 100, and the desorbed gas G11 is returned to the first flow path F1. Since the organic solvent recovery system 1D returns the desorbed gas G11 to the first flow path F1, it is not necessary to process the air volume of the desorbed gas G11 in the cooling and condensing device 100.
- the organic solvent recovery system 1D can contribute to miniaturization and energy saving of the cooling/condensing device 100 .
- the organic solvent recovery system 1D can suppress condensation of NMP (N-methyl-2-pyrrolidone), moisture, etc. contained in the cooling process gas G4 because the desorption gas G11 is at a high temperature.
- the desorption gas G8 is returned to the cooling condenser 100, and the desorption gas G11 is returned to the regeneration heater 250. Since the organic solvent recovery system 2D returns the desorbed gas G11 to the regeneration heater 250, it is not necessary to process the air volume of the desorbed gas G11 in the cooling condensing device 100 and the first concentrating device 200. FIG. Therefore, the organic solvent recovery system 2D can contribute to miniaturization and energy saving of the cooling condensation device 100 and the first concentrating device 200 . The organic solvent recovery system 2D can contribute to energy saving of the regeneration heater 250 because the desorption gas G11 is at a high temperature.
- the desorbed gas G8 is returned to the cooling condenser 100, and the desorbed gas G11 is returned to the fourth flow path F4.
- the desorption gas G11 is returned to the second heat exchanger 112 through the fourth flow path F4 together with the cooling process gas G6.
- the organic solvent recovery system 3D eliminates the need for the air volume of the desorption gas G11 to be processed in the cooling condensation device 100 and the first concentrating device 200. FIG. Therefore, the organic solvent recovery system 3D can contribute to miniaturization and energy saving of the cooling condensation device 100 and the first concentrating device 200 .
- the organic solvent recovery system 3D can improve the temperature of the fluid flowing through the second heat exchanger 112 because the desorption gas G11 is at a high temperature, and the small size of the second heat exchanger 112 for cooling the exhaust gas G1. It can contribute to energy efficiency and energy saving.
- the desorbed gas G8 is returned to the cooling condenser 100, and the desorbed gas G11 is returned to the fifth flow path F5.
- the desorption gas G11 flows through the fifth flow path F5 together with part of the exhaust gas G1 and the cooling process gas G6 discharged from the second heat exchanger 112 and is returned to the production facility 130.
- the organic solvent recovery system 4D eliminates the need for the air volume of the desorbed gas G11 to be processed in the cooling condensation device 100 and the first concentrating device 200. FIG. Therefore, the organic solvent recovery system 4D can contribute to miniaturization and energy saving of the cooling condenser 100 and the first concentration device 200 .
- the organic solvent recovery system 4D can increase the temperature of the exhaust gas G1 discharged again from the production facility 130 because the desorption gas G11 is at a high temperature. Therefore, the organic solvent recovery system 4D can improve the temperature of the fluid flowing through the second heat exchanger 112, and contributes to downsizing and energy saving of the second heat exchanger 112 for cooling the exhaust gas G1. can contribute.
- a plurality of adsorption units 210 are arranged in the circumferential direction around the cylinder axis of a hollow columnar rotor rotating around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- the adsorption element 310 is arranged on a disk-shaped adsorption rotor that rotates around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- two concentrating devices the first concentrating device 200 and the second concentrating device 300
- the concentrator two first concentrators 200 or two second concentrators 300 may be applied depending on the air volume. Also, depending on the removal efficiency, three or more concentrators may be applied.
- Examples of the organic solvent contained in the exhaust gas G1 include organic solvents that can be liquefied and recovered by cooling to 1°C to 50°C.
- Examples of organic solvents are N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N,N-dimethylformamide, N,N-dimethylacetamide and n-decane. These are examples and are not limiting.
- the organic solvent contained may be one or more.
- FIG. 14 is a diagram schematically showing the configuration of an organic solvent recovery system 1E according to Embodiment 1E.
- the organic solvent recovery system 1E includes an organic solvent recovery system 2B1 comprising a cooling condensing device 100, a first concentrating device 200 and a second concentrating device 300, and an organic solvent recovery system 2B1 comprising a cooling condensing device 100 and a first concentrating device 200. It is composed of a collection system 2B2 and various flow paths.
- the organic solvent recovery system 2B1 has the same configuration as that of the embodiment 2B described above.
- the organic solvent recovery system 2B2 has a configuration in which the second concentrating device 300 is removed from the above-described Embodiment 2B.
- the organic solvent recovery system 1E of Embodiment 1E has one second concentrator 300 in the latter stage and two first concentrators 200 in the former stage. That is, the number of second concentrating devices 300 in the latter stage is less than the number of first concentrating devices 200 in the preceding stage.
- the organic solvent recovery system 1E of Embodiment 1E has a configuration in which a plurality of cooling condensing devices 100 and a plurality of first concentrating devices 200 are arranged in parallel with respect to the production facility 130, as shown in FIG.
- the number of first concentrators 200 is the same as the number of cooling condensers 100, but the numbers may be different.
- Various configurations of the organic solvent recovery system 1E including the organic solvent recovery system 2B1 and the organic solvent recovery system 2B2 will be specifically described below.
- the cooling/condensing device 100 has a cooling section 110 and a separating section 120 .
- An exhaust gas G1 containing an organic solvent is discharged from the production facility 130. As shown in FIG.
- the exhaust gas G1 is cooled by passing through the cooling section 110 .
- the organic solvent is liquefied and condensed.
- the exhaust gas G2 that has passed through the cooling section 110 is separated into a liquefied and condensed cooling condensate L1 and a cooling process gas G3 with a reduced organic solvent concentration by passing through the separation section 120 .
- a heater 126 is provided in the chamber 123 .
- the heater 126 slightly heats the cooled process gas G3 after cooling.
- the cooled process gas G3 can prevent the organic solvent or moisture from condensing by being slightly heated. Cooled process gas G3 is discharged from cooled condenser 100 to first concentrator 200 through chamber 123 as cooled process gas G4.
- Embodiment 1E uses a first heat exchanger 111 that cools the exhaust gas by indirect heat exchange between a refrigerant such as cooling water, cold water, and brine.
- the first heat exchanger 111 is positioned so that the exhaust gas G1 flows vertically.
- the cooling unit 110 is provided with a second heat exchanger 112 in front of the first heat exchanger 111 that cools the exhaust gas G1 by heat exchange between the cooling process gas G6 and the exhaust gas G1, which will be described later.
- the second heat exchanger 112 can reduce the heat transfer area and the amount of refrigerant required for the first heat exchanger 111 .
- a part of the exhaust gas G1 and the cooling process gas G6 is returned to the production facility 130 through the fifth flow path F5.
- Conditions such as the cooling temperature in the first heat exchanger 111 and the second heat exchanger 112 may be appropriately determined according to the organic solvent to be recovered.
- Embodiment 1E uses a reticulated structure 121 such as demisters, filters, and meshes that contact and trap droplets.
- the separation unit 120 has a funnel-shaped receiving unit 122 that receives the cooled condensate L1 containing the organic solvent that has been cooled in the cooling unit 110 .
- the cooled condensate L1 cooled in the cooling part 110 and the cooled condensate L1 trapped in the network structure 121 flow to the receiving part 122 by gravity, and then are collected in the tank 125 arranged below the receiving part 122 . It is liquefied and recovered as recovery liquid L3.
- the chamber 123 is a structure having a certain amount of space.
- a weir 124 is provided in the chamber 123 .
- the weir 124 prevents part of the cooling condensate L1 from moving toward the tip of the chamber 123 and flowing into the first flow path F1 as the cooling gas flow path.
- Weir 124 serves to ensure that cooling condensate L1 is recovered.
- the cooled process gas G3 stored in the chamber 123 for a certain period of time flows through the first flow path F1 as the cooled process gas G4 and is supplied to the first concentration device 200 .
- the direction of flow from the mesh structure 121 to the chamber 123 in the separation unit 120 is the direction of flow from the cooling unit 110 to the separation unit 120.
- the exhaust gas G1 exhaust gas G2, cooling process gas G3 flows in the L-shaped direction.
- the organic solvent recovery system 1E Since the organic solvent recovery system 1E has an L-shaped structure where the cooling unit 110 and the separation unit 120 are configured, it suppresses the exposure of the first concentration device 200 and the second concentration device 300 by droplets and splashes. can do.
- the first concentrator 200 and the second concentrator 300 may be weakened or damaged if exposed and the adsorbent gets wet.
- the organic solvent recovery system 1E can prevent the first concentration device 200 and the second concentration device 300 from being weakened or damaged by having an L-shaped structure.
- the first concentrator 200 has an adsorption rotor 212 that includes an adsorbent that adsorbs the contained organic solvent by contact with gas and desorbs the adsorbed organic solvent by contact with heated gas.
- the adsorption rotor 212 is composed of a plurality of adsorption units 210 partitioned by a plurality of partitions.
- the suction rotor 212 has a hollow cylindrical shape as a whole due to the plurality of suction units 210 .
- the adsorption rotor 212 is installed in the processing chamber and is provided so that the fluid can flow in the radial direction.
- the attraction rotor 212 is rotatable around the cylinder axis by receiving the rotational driving force of the motor.
- a part of the adsorption unit 210 constitutes an adsorption section that adsorbs the organic solvent contained in the cooled processed gas G4 supplied from the outside to the inside of the adsorption unit 210, and the adsorption unit 210 constitutes a desorption section that desorbs the organic solvent adsorbed by the adsorption unit 210 from the adsorption unit 210 by supplying heated air from the inside to the outside of the adsorption unit 210 .
- the cooled processing gas G4 supplied into the processing chamber is introduced from the outer peripheral surface of the adsorption rotor 212 into the adsorption section.
- the cooled processing gas G4 introduced into the adsorption section adsorbs the organic solvent to the plurality of adsorption units 210 positioned in the adsorption section when passing through the adsorption rotor 212 from the outer peripheral surface to the inner peripheral surface along the radial direction. It is purified by letting
- the cooled processing gases G5 and G6 as cleaned fluids to be processed are discharged from the upper portion of the adsorption unit 210 as clean gas.
- a part of the discharged clean gas flows through the second flow path F2 as the cooled processed gas G5 and is supplied to the second concentrator 300.
- a part of the discharged clean gas flows through the fourth flow path F4 as the cooled processed gas G6 and is returned to the second heat exchanger 112 .
- the cooled process gas G5 as the cleaned fluid to be processed is discharged from the upper part of the adsorption unit 210 as clean gas.
- the inner peripheral side flow path forming member 211 and the outer peripheral side flow path forming member 213 are arranged facing each other on the inner peripheral side and the outer peripheral side of the adsorption rotor 212 so as to sandwich a part of the adsorption rotor 212 in the circumferential direction. ing.
- a region of the adsorption rotor 212 sandwiched between the inner peripheral side flow path forming member 211 and the outer peripheral side flow path forming member 213 is a detachable portion.
- the hot gas G7 which is a part of the cooling process gas G5 heated by the regeneration heater 250, is introduced from the inner peripheral side passage forming member 211 to the desorption portion.
- the high-temperature gas G7 introduced into the desorption section when passing through the adsorption rotor 212, thermally desorbs the organic solvent adsorbed by the plurality of adsorption units 210 located in the desorption section.
- the desorption gas G8 containing the organic solvent is discharged as a concentrated gas from the desorption section through the outer peripheral side flow path forming member 213 to the outside of the processing chamber and returned to the third flow path F3.
- a part of the organic solvent contained in the desorption gas G8 is liquefied and condensed and collected in the tank 125 as the desorption condensate L2.
- the third flow path F3 is a portion that returns the desorption gas G8 and the later-described desorption gas G11 to the exhaust gas G1 inlet of the cooling condenser 100.
- the third flow path F3 is preferably connected so that the desorption section is arranged above the position where the desorption gas and the exhaust gas G1 supplied to the cooling/condensing device 100 join. This is because the desorbed condensate L2 generated from the desorbed gas G8 of the first concentrator 200 and the desorbed gas G11 of the second concentrator 300 easily moves to the cooling condenser 100 .
- the third flow path F3 is configured so as to pass through two points, the inlet of the exhaust gas G1 of the cooling and condensing device 100 and the tank 125 . This is because the desorbed condensed liquid L2 generated from the desorbed gas G8 and the desorbed gas G11 can be easily collected directly into the tank 125 .
- the third flow path F3 is a part that returns the desorption gas G8 to the exhaust gas G1 inlet of the cooling condenser 100. As shown in FIG.
- the adsorption unit 210 located in the adsorption section performs adsorption processing of the substance to be processed, and after the adsorption processing, the adsorption unit 210 located in the desorption section performs desorption processing of the substance to be processed. done.
- the adsorption rotor 212 rotates around the cylindrical axis, the adsorption unit 210 alternately moves between the desorption section and the adsorption section, and adsorption and desorption of the substance to be treated are continuously performed.
- Activated alumina, silica gel, activated carbon material, zeolite, and the like can be used as materials for the adsorption elements that constitute the adsorption unit 210 .
- the shape of the adsorption element in the adsorption unit 210 is not particularly limited, and may be, for example, a honeycomb-shaped sheet containing an activated carbon material or zeolite, or a laminate of activated carbon fiber nonwoven fabrics.
- the second concentrator 300 has an adsorption element 310 containing an adsorbent that adsorbs the contained organic solvent by contact with gas and desorbs the adsorbed organic solvent by contact with heated gas.
- the adsorption element 310 includes a desorption section (desorption zone) 311 and an adsorption section (adsorption zone) 312 .
- the cooling process gas G5 is introduced into the adsorbent, and the cooling process gas G5 is brought into contact with the adsorbent. is cleaned and discharged as clean gas G9.
- the high-temperature gas G10 having a higher temperature than the cooling process gas G5 is introduced into the adsorbent, whereby the organic solvent is desorbed from the adsorbent and discharged as the desorbed gas G11 containing the organic solvent.
- activated alumina, silica gel, activated carbon material, and zeolite are widely used, and among them, activated carbon and hydrophobic zeolite are particularly preferably used.
- the second concentrator 300 includes a rotating shaft and an adsorption element 310 provided around the rotating shaft.
- the second concentrating device 300 rotates the adsorption element 310 around the rotation axis, so that the adsorbent that adsorbs the organic solvent in the cooling process gas G5 introduced from the second flow path F2 is continuous in the adsorption section 312. It is configured to move to the detachable portion 311 automatically.
- the second concentration device 300 preferably has the desorption section 311 arranged below the adsorption section 312 . This is because even when part of the organic solvent contained in the desorption gas G11 is liquefied and condensed to generate the desorption condensate L2, the desorption condensate L2 is less likely to adhere to the adsorption unit 312.
- the desorbed condensate L2 falls downward from the desorption section 311 and is collected along the inner surface of the exterior of the desorption section. More preferably, the desorbing portion 311 is inclined downward so that the desorbed condensate L2 can easily fall downward.
- the second concentrating device 300 may have a cleaning section (purge section) in which the portion where the desorption processing of the desorption section 311 is completed transfers before transferring to the adsorption section 312 .
- a part of the clean gas G9 may be introduced into the purge section, and the purge section outlet gas discharged from the purge section may be introduced into the adsorption section 312 .
- the high-temperature gas G10 used for desorption is preferably a part of the clean gas G9 heated to a high temperature using heating means such as the regeneration heater 350. This is because, in the adsorption section 312, the processing air volume of the organic solvent-containing gas does not increase.
- FIGS. 15 and 16 are diagrams schematically showing the configuration of an organic solvent recovery system 2E according to Embodiment 2E.
- the organic solvent recovery system 2E includes an organic solvent recovery system 2B1 comprising a cooling condensing device 100, a first concentrating device 200 and a second concentrating device 300, and an organic solvent recovery system 2B1 comprising a cooling condensing device 100 and a first concentrating device 200. It is configured to include two recovery systems 2B2 and various flow paths.
- the channels are connected at points A and B, but due to space limitations, FIG. 1 is divided into two figures.
- Organic solvent recovery system 2B1 and organic solvent recovery system 2B2 in organic solvent recovery system 2E shown in FIGS. 15 and 16 are organic solvent recovery system 2B1 and organic solvent recovery system 2B2 included in organic solvent recovery system 1E shown in FIG. It has the same configuration as
- the organic solvent recovery system 2E of Embodiment 2E has a configuration in which the number of second concentrating devices 300 in the latter stage is less than the number of first concentrating devices 200 in the preceding stage.
- the number of second concentrators 300 in the latter stage is two, while the number of first concentrators 200 in the former stage is four.
- the number of each of the first concentrating devices 200 and the second concentrating devices 300 may be any number.
- the position to which the second concentrating device 300 in the latter stage is connected may be any position among the plurality of first concentrating devices 200 in the preceding stage.
- the organic solvent recovery system 2E of Embodiment 2E has a configuration in which a plurality of cooling condensing devices 100 and a plurality of first concentrating devices 200 are arranged in parallel with respect to the production facility 130. is.
- the number of first concentrators 200 is the same as the number of cooling condensers 100, but the numbers may be different.
- the number of cooling-condensing devices 100 may be configured to be less than the number of first concentrating devices 200 .
- the cooling process gas G4 discharged from one cooling condensing device 100 may be configured to flow into a plurality of first concentrating devices 200 .
- the organic solvent recovery systems 1E and 2E in the present embodiment cool the exhaust gas G1 containing the organic solvent, liquefy and condense the organic solvent, and discharge the cooled gas G4 with a reduced concentration of the organic solvent.
- the condensing device 100, the first circulation path F1 through which the cooled gas G4 flows, and the adsorption unit 210 adsorbs the organic solvent contained in the cooled gas G4 introduced from the first circulation path F1 to obtain an organic solvent.
- a first concentrator 200 that discharges a cooled processed gas G5 with a further reduced solvent concentration, introduces a high-temperature gas G7, desorbs the organic solvent from the adsorption unit 210, and discharges it as a desorbed gas G8, and a cooled processed gas G5.
- the concentration of the organic solvent is further reduced by adsorbing the organic solvent contained in the cooling process gas G5 introduced from the second circulation path F2 and the adsorption element 310 that is introduced from the second circulation path F2. and a second concentrator 300 that discharges the desorbed clean gas G9, introduces the hot gas G10 to desorb the organic solvent from the adsorption element 310, and discharges it as the desorbed gas G11.
- At least two or more first concentrators 200 are provided, at least one or more second concentrators 300 are provided, and the number of second concentrators 300 is less than the number of first concentrators 200 .
- the organic solvent recovery systems 1E and 2E efficiently recover the organic solvent from the exhaust gas G1 by the plurality of first concentration devices 200. be able to.
- a plurality of first concentrators 200 in the present embodiment are arranged in parallel with the production facility 130 . As a result, even when the flow rate of the exhaust gas G1 discharged from the production facility 130 is large, the organic solvent can be recovered from the exhaust gas G1 with high efficiency.
- At least two cooling-condensing devices 100 in the present embodiment are provided, and the number of first concentrating devices 200 is the same as the number of cooling-condensing devices 100 .
- the cooling and condensing device 100 in the present embodiment includes a network structure 121 that separates the condensed organic solvent and the cooling process gas G3 by contacting the exhaust gas G2 after cooling, and and a chamber 123 in which the cooled process gas G3 is stored for a certain period of time. As a result, the organic solvent can be recovered from the exhaust gas G1 with high efficiency.
- the cooling/condensing device 100 in the present embodiment further includes a first heat exchanger 111 and a second heat exchanger 112 that perform cooling by heat exchange with refrigerant. Thereby, heat exchange between the refrigerant and the exhaust gas can be effectively performed.
- a plurality of adsorption units 210 are arranged in the circumferential direction around the cylinder axis of a hollow columnar rotor rotating around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- the adsorption element 310 is arranged on a disk-shaped adsorption rotor that rotates around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- the organic solvent recovery systems 1E, 2E may be configured by any one of the organic solvent recovery systems shown in FIGS. 2 to 13, or a combination thereof.
- the number of each of the first concentrating devices 200 and the second concentrating devices 300 may be any number.
- the number of second concentrating devices 300 in the latter stage may be one, and the number of first concentrating devices 200 in the preceding stage may be three or more.
- one or more second concentrators 300 are required to discharge the clean gas G9.
- Examples of the organic solvent contained in the exhaust gas G1 include organic solvents that can be liquefied and recovered by cooling to 1°C to 50°C.
- Examples of organic solvents are N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N,N-dimethylformamide, N,N-dimethylacetamide and n-decane. These are examples and are not limiting.
- the organic solvent contained may be one or more.
- the first concentrator 200 which is a vertical cylindrical concentrator
- the second concentrator 300 which is a disc-shaped concentrator
- the concentrator may be a horizontal cylinder-type concentrator, and may be configured by any combination of a vertical cylinder-type concentrator, a horizontal cylinder-type concentrator, and a disk-type concentrator. can be anything.
- the horizontal cylinder type concentrator may be applied to the concentrator shown in any one of FIGS. 1 to 13.
- WO2016/189958 and WO2017/170207 are examples of horizontal cylindrical concentrators.
- Japanese Patent Application Laid-Open No. 84616/1988 can be cited as a vertical cylinder type concentrator.
- Japanese Unexamined Patent Application Publication No. 61-167430 can be cited. These are all examples and are not limited to the concentrators disclosed in the documents described herein.
- FIG. 17 is a diagram schematically showing the configuration of an organic solvent recovery system 1J according to Embodiment 1J.
- the organic solvent recovery system 1J is composed of an organic solvent recovery system 1K1 composed of a cooling condensing device 100 and a second concentrating device 300, an organic solvent recovery system 1K2 composed of the cooling condensing device 100, and various flow paths. ing.
- the organic solvent recovery system 1J has a configuration obtained by removing the first concentration device 200 from the organic solvent recovery system 1E of FIG. As shown in FIG. 17, the organic solvent recovery system 1J of Embodiment 1J has one second concentrating device 300 in the latter stage and two cooling condensation devices 100 in the former stage. In other words, the number of second concentrating devices 300 in the latter stage is less than the number of cooling and condensing devices 100 in the preceding stage.
- An organic solvent recovery system 1J of Embodiment 1J has a configuration in which a plurality of cooling and condensing devices 100 are arranged in parallel with respect to a production facility 130, as shown in FIG.
- Various configurations of the organic solvent recovery system 1J including the organic solvent recovery system 1K1 and the organic solvent recovery system 1K2 will be specifically described below.
- the cooling condensation device 100 used in the organic solvent recovery system 1K1 and the organic solvent recovery system 1K2 will be explained.
- the cooling-condensing device 100 has a cooling section 110 and a separating section 120 .
- An exhaust gas G1 containing an organic solvent is discharged from the production facility 130. As shown in FIG.
- the exhaust gas G1 is cooled by passing through the cooling section 110 .
- the organic solvent is liquefied and condensed.
- the exhaust gas G2 that has passed through the cooling section 110 is separated into a liquefied and condensed cooling condensate L1 and a cooling process gas G3 with a reduced organic solvent concentration by passing through the separation section 120 .
- a heater 126 is provided in the chamber 123 .
- the heater 126 slightly heats the cooled process gas G3 after cooling.
- the cooled process gas G3 can prevent the organic solvent or moisture from condensing by being slightly heated.
- the cooled process gas G3 is discharged from the cooled condenser 100 to the second concentrator 300 through the chamber 123 with a portion G22 of the cooled process gas.
- Embodiment 1J uses a first heat exchanger 111 that cools the exhaust gas by indirect heat exchange between a refrigerant such as cooling water, cold water, and brine.
- the first heat exchanger 111 is positioned so that the exhaust gas G1 flows vertically.
- the cooling unit 110 is provided with a second heat exchanger 112 in front of the first heat exchanger 111, which cools the exhaust gas G1 by heat exchange between the cooling process gas G21 and the exhaust gas G1, which will be described later.
- the second heat exchanger 112 can reduce the heat transfer area and the amount of refrigerant required for the first heat exchanger 111 .
- a part of the exhaust gas G1 and the cooling process gas G21 is returned to the production facility 130 through the fifth flow path F5.
- Conditions such as the cooling temperature in the first heat exchanger 111 and the second heat exchanger 112 may be appropriately determined according to the organic solvent to be recovered.
- Embodiment 1J uses a reticulated structure 121 such as demisters, filters, and meshes that contact and trap droplets.
- the separation unit 120 has a funnel-shaped receiving unit 122 that receives the cooled condensate L1 containing the organic solvent that has been cooled in the cooling unit 110 .
- the cooled condensate L1 cooled in the cooling part 110 and the cooled condensate L1 trapped in the network structure 121 flow to the receiving part 122 by gravity, and then are collected in the tank 125 arranged below the receiving part 122 . It is liquefied and recovered as recovery liquid L3.
- the chamber 123 is a structure having a certain amount of space.
- a weir 124 is provided in the chamber 123 .
- the weir 124 prevents part of the cooling condensate L1 from moving toward the tip of the chamber 123 and flowing into the first flow path F1 as the cooling gas flow path.
- Weir 124 serves to ensure that cooling condensate L1 is recovered.
- the cooling process gas G3 stored in the chamber 123 for a certain period of time flows through the flow path F21 as the cooling process gas G21 (return gas G21) and is returned to the cooling section 110.
- FIG. A part of the cooled processed gas G3 flows through the flow path F22 as the cooled processed gas G22 and is supplied to the second concentrator 300 .
- the cooling unit 110 In front of the first heat exchanger 111, the cooling unit 110 is provided with a second heat exchanger 112 that cools the exhaust gas G1 by heat exchange between the cooling process gas G21 and the exhaust gas G1. This reduces the heat transfer area and the amount of refrigerant required for the first heat exchanger 111 .
- the direction of flow from the mesh structure 121 to the chamber 123 in the separation unit 120 is relative to the direction of flow from the cooling unit 110 to the separation unit 120.
- the exhaust gas G1 exhaust gas G2, cooling process gas G3 flows in the L-shaped direction.
- the organic solvent recovery system 1J Since the organic solvent recovery system 1J has an L-shaped structure in the part composed of the cooling part 110 and the separation part 120, it is possible to suppress the exposure of the second concentrating device 300 due to droplets and splashes.
- the second concentrator 300 may be weakened or damaged if exposed and the adsorbent gets wet. Since the organic solvent recovery system 1J has an L-shaped structure, it is possible to prevent the second concentrator 300 from being weakened or damaged.
- the second concentration device 300 used in the organic solvent recovery system 1K1 will be explained.
- the second concentrator 300 has an adsorption element 310 containing an adsorbent that adsorbs the contained organic solvent when it comes into contact with the gas and desorbs the adsorbed organic solvent when it comes into contact with the heated gas.
- the adsorption element 310 includes a desorption section (desorption zone) 311 and an adsorption section (adsorption zone) 312 .
- the cooling process gas G22 is introduced, and the cooling process gas G22 comes into contact with the adsorbent. is cleaned and discharged as clean gas G9.
- the high-temperature gas G10 having a higher temperature than the cooling process gas G22 is introduced into the adsorbent, whereby the organic solvent is desorbed from the adsorbent and discharged as the desorbed gas G11 containing the organic solvent.
- activated alumina, silica gel, activated carbon material, and zeolite are widely used, and among them, activated carbon and hydrophobic zeolite are particularly preferably used.
- the second concentrator 300 includes a rotating shaft and an adsorption element 310 provided around the rotating shaft.
- the second concentrating device 300 rotates the adsorption element 310 around the rotation axis, so that in the adsorption section 312, the adsorbent that adsorbs the organic solvent in the cooled processed gas G22 introduced from the flow path F22 is continuously adsorbed. It is configured to move to the detachable portion 311 .
- the second concentration device 300 preferably has the desorption section 311 arranged below the adsorption section 312 . This is because even when part of the organic solvent contained in the desorption gas G11 is liquefied and condensed to generate the desorption condensate L2, the desorption condensate L2 is less likely to adhere to the adsorption unit 312.
- the desorbed condensate L2 falls downward from the desorption section 311 and is collected along the inner surface of the exterior of the desorption section. More preferably, the desorbing portion 311 is inclined downward so that the desorbed condensate L2 can easily fall downward.
- the second concentrating device 300 may have a cleaning section (purge section) in which the portion where the desorption processing of the desorption section 311 is completed transfers before transferring to the adsorption section 312 .
- a part of the clean gas G9 may be introduced into the purge section, and the purge section outlet gas discharged from the purge section may be introduced into the adsorption section 312 .
- the high-temperature gas G10 used for desorption is preferably a part of the clean gas G9 heated to a high temperature using heating means such as the regeneration heater 350. This is because, in the adsorption section 312, the processing air volume of the organic solvent-containing gas does not increase.
- the organic solvent recovery system 1K2 in the organic solvent recovery system 1J does not have the second concentration device 300 unlike the organic solvent recovery system 1K1. Therefore, all of the cooling process gas G3 stored in the chamber 123 of the cooling condensing device 100 for a certain period of time flows through the flow path F21 as the cooling process gas G21 (return gas G21) and is returned to the cooling unit 110.
- a plurality of cooling-condensing devices 100 are arranged in parallel with respect to production equipment 130, and the number of second concentrating devices 300 in the latter stage is This configuration is less than the number of cooling and condensing devices 100 .
- the number of the second concentrating device 300 in the latter stage is one
- the number of the cooling and condensing devices 100 in the former stage is two.
- Any number of the second concentrating devices 300 may be provided as long as the number of the second concentrating devices 300 in the latter stage is less than the number of the cooling-condensing devices 100 in the preceding stage.
- the position to which the second concentrating device 300 in the latter stage is connected may be any position among the plurality of cooling-condensing devices 100 in the former stage.
- the organic solvent recovery system 1J in the present embodiment is a cooling condensation device that liquefies and condenses the organic solvent by cooling the exhaust gas G1 containing the organic solvent and discharges it as a cooled processed gas G22 in which the concentration of the organic solvent is reduced.
- a flow path F22 for flowing the cooling process gas G22, and the organic solvent contained in the cooling process gas G22 introduced from the flow path F22 is adsorbed by the adsorption element 310 to further reduce the concentration of the organic solvent.
- a second concentrator 300 that discharges the desorbed clean gas G9, introduces the hot gas G10 to desorb the organic solvent from the adsorption element 310, and discharges it as the desorbed gas G11.
- At least two cooling condensing devices 100 are provided, at least one second concentrating device 300 is provided, and the number of second concentrating devices 300 is less than the number of cooling condensing devices 100 .
- the organic solvent recovery system 1J can recover the organic solvent from the exhaust gas G1 with high efficiency by the plurality of cooling and condensing devices 100. .
- a plurality of cooling and condensing devices 100 in the present embodiment are arranged in parallel with production equipment 130 . As a result, even when the flow rate of the exhaust gas G1 discharged from the production facility 130 is large, the organic solvent can be recovered from the exhaust gas G1 with high efficiency.
- the cooling and condensing device 100 in the present embodiment includes a network structure 121 that separates the condensed organic solvent and the cooling process gas G3 by contacting the exhaust gas G2 after cooling, and and a chamber 123 in which the cooled process gas G3 is stored for a certain period of time. As a result, the organic solvent can be recovered from the exhaust gas G1 with high efficiency.
- the cooling/condensing device 100 in the present embodiment further includes a first heat exchanger 111 and a second heat exchanger 112 that perform the cooling by heat exchange with the refrigerant. Thereby, heat exchange between the refrigerant and the exhaust gas can be effectively performed.
- the adsorption element 310 is arranged on a disk-shaped adsorption rotor that rotates around the cylinder axis. As a result, the organic solvent can be recovered with high efficiency.
- the organic solvent recovery system 1J has any one of the configurations obtained by removing the front-stage concentrator from the configuration of the organic solvent recovery system provided with the two-stage concentrator shown in FIGS. 2 to 13, or A combination thereof may be used.
- the second concentrator 300 which is a disk-shaped concentrator, has been described as an example.
- a plurality of adsorption units 210 are arranged in the circumferential direction around the cylinder axis of a hollow columnar rotor that rotates around the cylinder axis.
- Concentrator 200 may be used.
- the concentrating device may be a horizontal cylindrical concentrating device.
- Examples of the organic solvent contained in the exhaust gas G1 include organic solvents that can be liquefied and recovered by cooling to 1°C to 50°C.
- Examples of organic solvents are N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N,N-dimethylformamide, N,N-dimethylacetamide and n-decane. These are examples and are not limiting.
- the organic solvent contained may be one or more.
- 1A, 1B, 1C, 1D, 2B, 2C, 2D, 3C, 3D, 4C, 4D organic solvent recovery system 100 cooling condenser, 110 cooling section, 111 first heat exchanger, 112 second heat exchanger, 120 Separation section, 121 network structure, 123 chamber, 125 tank, 127 ceiling section, 128 partition section, 130 production equipment, 200 first concentrator, 210 adsorption unit, 211 inner peripheral flow path forming member, 212 adsorption rotor, 213 outer flow path forming member, 250, 350 regeneration heater, 300 second concentrator, 310 adsorption element, 311 desorption section, 312 adsorption section, F1 first flow path, F2 second flow path, F3 third flow Flow path, F4 Fourth flow path, F5 Fifth flow path, F6 Sixth flow path, G1, G2 Exhaust gas, G3, G4, G5, G6 Cooling process gas, G7, G10 High temperature gas, G8, G11 Desorption Gas, G9 clean gas, L1
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Abstract
Description
図1は、実施の形態1Aにおける有機溶剤回収システム1Aの構成を概略的に示す図である。有機溶剤回収システム1Aは、冷却凝縮装置100、濃縮装置300、第一通流経路F1、第二通流経路F2とで構成されている。
図4は、実施の形態1Bの有機溶剤回収システム1Bの構成を概略的に示す図である。有機溶剤回収システム1Bは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。
図5は、実施の形態2Bの有機溶剤回収システム2Bの構成を概略的に示す図である。有機溶剤回収システム2Bは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。有機溶剤回収システム2Bは、チャンバー123内にヒータ126が設けられている点以外は、実施の形態1Bの有機溶剤回収システム1Bと同じである。
本実施の形態における冷却凝縮装置100は、排ガスG1を通流させる冷却部110と、排ガスG1の流れる方向に沿って見た場合に、冷却部110の下流側に位置する分離部120と、を含んでいる。分離部120は、冷却部110で冷却された有機溶剤を含む冷却凝縮液L1を受ける受け部122と、冷却後の排ガスG2を接触させることで冷却凝縮液L1と冷却処理ガスG3とを分離させる網目状構造体121と、網目状構造体121を通過後の冷却処理ガスG3を一定時間貯留させるチャンバー123と、を有している。
上記実施の形態において、濃縮装置は、第一濃縮装置200と第二濃縮装置300との2つを用いていた。濃縮装置は、風量に応じて、第一濃縮装置200を2つまたは第二濃縮装置300を2つ適用しても良い。また、除去効率に応じて、濃縮装置を3つ以上適用してもよい。
図6は、実施の形態1Cの有機溶剤回収システム1Cの構成を概略的に示す図である。有機溶剤回収システム1Cは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。
図7は、実施の形態2Cの有機溶剤回収システム2Cの構成を概略的に示す図である。有機溶剤回収システム2Cは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。有機溶剤回収システム2Cは、第二濃縮装置300の脱着ガスG11が第六通流経路F6を通り再生ヒータ250に戻される点以外の構成は、実施の形態1Cの有機溶剤回収システム1Cと同じである。
図8は、実施の形態3Cの有機溶剤回収システム3Cの構成を概略的に示す図である。有機溶剤回収システム3Cは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。有機溶剤回収システム3Cは、第二濃縮装置300の脱着ガスG11が第六通流経路F6を通り第四通流経路F4に戻される。有機溶剤回収システム3Cは、第二濃縮装置300の脱着ガスG11が第六通流経路F6通り第四通流経路F4に戻される点以外の構成は、実施の形態1Cの有機溶剤回収システム1Cと同じである。
図9は、実施の形態4Cの有機溶剤回収システム4Cの構成を概略的に示す図である。有機溶剤回収システム4Cは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。有機溶剤回収システム4Cは、第二濃縮装置300の脱着ガスG11が第六通流経路F6を通り第五通流経路F5に戻される。有機溶剤回収システム4Cは、第二濃縮装置300の脱着ガスG11が第六通流経路F6通り第五通流経路F5に戻される点以外の構成は、実施の形態1Cの有機溶剤回収システム1Cと同じである。
本実施の形態における有機溶剤回収システム1Cは、有機溶剤を含有する排ガスG1を冷却することで、有機溶剤を液化凝縮し、有機溶剤の濃度が低減された冷却処理ガスG4として排出する冷却凝縮装置100と、冷却処理ガスG4を通流させる第一通流経路F1と、第一通流経路F1から導入された冷却処理ガスG4に含まれる有機溶剤を吸着ユニット210にて吸着して有機溶剤の濃度が更に低減された冷却処理ガスG5として排出し、高温ガスG7を導入して吸着ユニット210から有機溶剤を脱着して脱着ガスG8として排出する第一濃縮装置200と、冷却処理ガスG5の一部を通流させる第二通流経路F2と、第二通流経路F2から導入された冷却処理ガスG5に含まれる有機溶剤を吸着素子310にて吸着して有機溶剤の濃度が更に低減された清浄ガスG9として排出し、高温ガスG10を導入して吸着素子310から有機溶剤を脱着して脱着ガスG11として排出する第二濃縮装置300と、を備える。
上記実施の形態において、濃縮装置は、第一濃縮装置200と第二濃縮装置300との2つを用いていた。濃縮装置は、風量に応じて、第一濃縮装置200を2つまたは第二濃縮装置300を2つ適用しても良い。また、除去効率に応じて、濃縮装置を3つ以上適用してもよい。
図10は、実施の形態1Dの有機溶剤回収システム1Dの構成を概略的に示す図である。有機溶剤回収システム1Dは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。
図11は、実施の形態2Dの有機溶剤回収システム2Dの構成を概略的に示す図である。有機溶剤回収システム2Dは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。有機溶剤回収システム2Dは、第二濃縮装置300の脱着ガスG11が第六通流経路F6を通り再生ヒータ250に戻される点以外の構成は、実施の形態1Dの有機溶剤回収システム1Dと同じである。
図12は、実施の形態3Dの有機溶剤回収システム3Dの構成を概略的に示す図である。有機溶剤回収システム3Dは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。有機溶剤回収システム3Dは、第二濃縮装置300の脱着ガスG11が第六通流経路F6を通り第四通流経路F4に戻される。有機溶剤回収システム3Dは、第二濃縮装置300の脱着ガスG11が第六通流経路F6通り第四通流経路F4に戻される点以外の構成は、実施の形態1Dの有機溶剤回収システム1Dと同じである。
図13は、実施の形態4Dの有機溶剤回収システム4Dの構成を概略的に示す図である。有機溶剤回収システム4Dは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300、および各種通流経路により構成されている。有機溶剤回収システム4Dは、第二濃縮装置300の脱着ガスG11が第六通流経路F6を通り第五通流経路F5に戻される。有機溶剤回収システム4Dは、第二濃縮装置300の脱着ガスG11が第六通流経路F6通り第五通流経路F5に戻される点以外の構成は、実施の形態1Dの有機溶剤回収システム1Dと同じである。
本実施の形態における有機溶剤回収システム1Dは、有機溶剤を含有する排ガスG1を冷却することで、有機溶剤を液化凝縮し、有機溶剤の濃度が低減された冷却処理ガスG4として排出する冷却凝縮装置100と、冷却処理ガスG4の一部を通流させる第一通流経路F1と、第一通流経路F1から導入された冷却処理ガスG4に含まれる有機溶剤を吸着ユニット210にて吸着して有機溶剤の濃度が更に低減された冷却処理ガスG5として排出し、高温ガスG7を導入して吸着ユニット210から有機溶剤を脱着して脱着ガスG8として排出する第一濃縮装置200と、冷却処理ガスG5を通流させる第二通流経路F2と、第二通流経路F2から導入された冷却処理ガスG5に含まれる有機溶剤を吸着素子310にて吸着して有機溶剤の濃度が更に低減された清浄ガスG9として排出し、高温ガスG10を導入して吸着素子310から有機溶剤を脱着して脱着ガスG11として排出する第二濃縮装置300と、を備える。
上記実施の形態において、濃縮装置は、第一濃縮装置200と第二濃縮装置300との2つを用いていた。濃縮装置は、風量に応じて、第一濃縮装置200を2つまたは第二濃縮装置300を2つ適用しても良い。また、除去効率に応じて、濃縮装置を3つ以上適用してもよい。
図14は、実施の形態1Eの有機溶剤回収システム1Eの構成を概略的に示す図である。有機溶剤回収システム1Eは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300から構成される有機溶剤回収システム2B1と、冷却凝縮装置100、第一濃縮装置200から構成される有機溶剤回収システム2B2と、各種通流経路により構成されている。
図15および図16は、実施の形態2Eの有機溶剤回収システム2Eの構成を概略的に示す図である。有機溶剤回収システム2Eは、冷却凝縮装置100、第一濃縮装置200、第二濃縮装置300から構成される有機溶剤回収システム2B1と、冷却凝縮装置100、第一濃縮装置200から構成される有機溶剤回収システム2B2と、を2つずつ備えるとともに、各種通流経路を備える構成である。図15と図16とは、A点およびB点で流路が接続されているが、紙面の都合上、1図を2図に分割して記載している。
本実施の形態における有機溶剤回収システム1E、2Eは、有機溶剤を含有する排ガスG1を冷却することで、有機溶剤を液化凝縮し、有機溶剤の濃度が低減された冷却処理ガスG4として排出する冷却凝縮装置100と、冷却処理ガスG4を通流させる第一通流経路F1と、第一通流経路F1から導入された冷却処理ガスG4に含まれる有機溶剤を吸着ユニット210にて吸着して有機溶剤の濃度が更に低減された冷却処理ガスG5として排出し、高温ガスG7を導入して吸着ユニット210から有機溶剤を脱着して脱着ガスG8として排出する第一濃縮装置200と、冷却処理ガスG5の一部を通流させる第二通流経路F2と、第二通流経路F2から導入された冷却処理ガスG5に含まれる有機溶剤を吸着素子310にて吸着して有機溶剤の濃度が更に低減された清浄ガスG9として排出し、高温ガスG10を導入して吸着素子310から有機溶剤を脱着して脱着ガスG11として排出する第二濃縮装置300と、を備える。第一濃縮装置200は、少なくとも2つ以上設けられ、第二濃縮装置300は、少なくとも1つ以上設けられ、第二濃縮装置300の数が、第一濃縮装置200の数未満である。
上記実施の形態において、有機溶剤回収システム1E、2Eは、図2~図13に示す有機溶剤回収システムのいずれか、またはその組合せにより構成されるようにしてもよい。
図17は、実施の形態1Jの有機溶剤回収システム1Jの構成を概略的に示す図である。有機溶剤回収システム1Jは、冷却凝縮装置100、第二濃縮装置300から構成される有機溶剤回収システム1K1と、冷却凝縮装置100から構成される有機溶剤回収システム1K2と、各種通流経路により構成されている。
本実施の形態における有機溶剤回収システム1Jは、有機溶剤を含有する排ガスG1を冷却することで、有機溶剤を液化凝縮し、有機溶剤の濃度が低減された冷却処理ガスG22として排出する冷却凝縮装置100と、冷却処理ガスG22を通流させる通流経路F22と、通流経路F22から導入された冷却処理ガスG22に含まれる有機溶剤を吸着素子310にて吸着して有機溶剤の濃度が更に低減された清浄ガスG9として排出し、高温ガスG10を導入して吸着素子310から有機溶剤を脱着して脱着ガスG11として排出する第二濃縮装置300と、を備える。冷却凝縮装置100は、少なくとも2つ以上設けられ、第二濃縮装置300は、少なくとも1つ以上設けられ、第二濃縮装置300の数が、冷却凝縮装置100の数未満である。
上記実施の形態において、有機溶剤回収システム1Jは、図2~図13に示す2段の濃縮装置を備えた有機溶剤回収システムの構成から、前段の濃縮装置を削除した構成のうちいずれか、またはその組合せにより構成されるようにしてもよい。
Claims (12)
- 生産設備から排出される有機溶剤を含有する排ガスから前記有機溶剤を回収する有機溶剤回収システムであって、
前記有機溶剤を含有する前記排ガスを冷却することで、前記有機溶剤を液化凝縮し、前記有機溶剤の濃度が低減された冷却処理ガスとして排出する冷却凝縮装置と、
前記冷却処理ガスを通流させる第一通流経路と、
前記第一通流経路から導入された前記冷却処理ガスに含まれる前記有機溶剤を第一吸着素子にて吸着して前記有機溶剤の濃度が更に低減された第一処理ガスとして排出し、高温ガスを導入して前記第一吸着素子から前記有機溶剤を脱着して第一脱着ガスとして排出する第一濃縮装置と、
前記第一処理ガスの一部を通流させる第二通流経路と、
前記第二通流経路から導入された前記第一処理ガスに含まれる前記有機溶剤を第二吸着素子にて吸着して前記有機溶剤の濃度が更に低減された第二処理ガスとして排出し、高温ガスを導入して前記第二吸着素子から前記有機溶剤を脱着して第二脱着ガスとして排出する第二濃縮装置と、
前記第一脱着ガスおよび前記第二脱着ガスを前記冷却凝縮装置に戻す第三通流経路と、を備え、
前記第一濃縮装置は、少なくとも2つ以上設けられ、前記第二濃縮装置は、少なくとも1つ以上設けられ、
前記第二濃縮装置の数が、前記第一濃縮装置の数未満である、有機溶剤回収システム。 - 複数の前記第一濃縮装置は、前記生産設備に対して並列に配置される、請求項1に記載の有機溶剤回収システム。
- 前記冷却凝縮装置は、少なくとも2つ以上設けられ、
前記第一濃縮装置の数が、前記冷却凝縮装置の数と同じである、請求項1または請求項2に記載の有機溶剤回収システム。 - 前記冷却凝縮装置は、前記冷却後の前記排ガスを接触させることで凝縮した前記有機溶剤と前記冷却処理ガスとを分離させる網目状構造体と、前記網目状構造体を通過後の前記冷却処理ガスを一定時間貯留させるチャンバーと、をさらに備える、請求項1または請求項2に記載の有機溶剤回収システム。
- 前記冷却凝縮装置は、冷媒との熱交換により前記冷却を行う熱交換器をさらに備える、請求項1または請求項2に記載の有機溶剤回収システム。
- 前記第一濃縮装置は、前記第一吸着素子が筒軸回りに回転する中空円柱状のロータの筒軸回りの周方向に複数配置されている、請求項1または請求項2に記載の有機溶剤回収システム。
- 前記第二濃縮装置は、前記第二吸着素子が筒軸回りに回転する円盤状の吸着ロータに配置されている、請求項1または請求項2に記載の有機溶剤回収システム。
- 生産設備から排出される有機溶剤を含有する排ガスから前記有機溶剤を回収する有機溶剤回収システムであって、
前記有機溶剤を含有する前記排ガスを冷却することで、前記有機溶剤を液化凝縮し、前記有機溶剤の濃度が低減された冷却処理ガスとして排出する冷却凝縮装置と、
前記冷却処理ガスを通流させる第一通流経路と、
前記第一通流経路から導入された前記冷却処理ガスに含まれる前記有機溶剤を吸着素子にて吸着して前記有機溶剤の濃度が更に低減された第一処理ガスとして排出し、高温ガスを導入して前記吸着素子から前記有機溶剤を脱着して脱着ガスとして排出する濃縮装置と、を備え、
前記冷却凝縮装置は、少なくとも2つ以上設けられ、前記濃縮装置は、少なくとも1つ以上設けられ、
前記濃縮装置の数が、前記冷却凝縮装置の数未満である、有機溶剤回収システム。 - 複数の前記冷却凝縮装置は、前記生産設備に対して並列に配置される、請求項8に記載の有機溶剤回収システム。
- 前記冷却凝縮装置は、前記冷却後の前記排ガスを接触させることで凝縮した前記有機溶剤と前記冷却処理ガスとを分離させる網目状構造体と、前記網目状構造体を通過後の前記冷却処理ガスを一定時間貯留させるチャンバーと、をさらに備える、請求項8または請求項9に記載の有機溶剤回収システム。
- 前記冷却凝縮装置は、冷媒との熱交換により前記冷却を行う熱交換器をさらに備える、請求項8または請求項9に記載の有機溶剤回収システム。
- 前記濃縮装置は、前記吸着素子が筒軸回りに回転する円盤状の吸着ロータに配置されている、請求項8または請求項9に記載の有機溶剤回収システム。
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JPS61167430A (ja) | 1985-11-25 | 1986-07-29 | Toyobo Co Ltd | 低濃度溶剤含有ガスから溶剤を回収する方法 |
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