WO2022176296A1 - セラミック電子部品の製造方法 - Google Patents
セラミック電子部品の製造方法 Download PDFInfo
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- WO2022176296A1 WO2022176296A1 PCT/JP2021/042702 JP2021042702W WO2022176296A1 WO 2022176296 A1 WO2022176296 A1 WO 2022176296A1 JP 2021042702 W JP2021042702 W JP 2021042702W WO 2022176296 A1 WO2022176296 A1 WO 2022176296A1
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/30—Stacked capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F17/00—Fixed inductances of the signal type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
- H01F41/04—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing coils
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G13/00—Apparatus specially adapted for manufacturing capacitors; Processes specially adapted for manufacturing capacitors not provided for in groups H01G4/00 - H01G11/00
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G13/00—Apparatus specially adapted for manufacturing capacitors; Processes specially adapted for manufacturing capacitors not provided for in groups H01G4/00 - H01G11/00
- H01G13/006—Apparatus or processes for applying terminals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/008—Selection of materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/08—Inorganic dielectrics
- H01G4/12—Ceramic dielectrics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/08—Inorganic dielectrics
- H01G4/12—Ceramic dielectrics
- H01G4/1209—Ceramic dielectrics characterised by the ceramic dielectric material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/228—Terminals
- H01G4/232—Terminals electrically connecting two or more layers of a stacked or rolled capacitor
Definitions
- the present invention relates to a method for manufacturing ceramic electronic components.
- the ceramic electronic components to be manufactured in the present invention include multilayer ceramic electronic components such as multilayer ceramic capacitors, multilayer ceramic inductors, multilayer ceramic thermistors, multilayer ceramic LC components, and multilayer ceramic substrates. Ceramic electronic components to be manufactured in the present invention include non-laminated ceramic electronic components such as ceramic resonators, ceramic filters, ceramic resistors, ceramic thermistors, and ceramic substrates.
- Patent Document 1 Japanese Unexamined Patent Application Publication No. 11-233364 discloses a method for manufacturing a multilayer ceramic capacitor (ceramic electronic component).
- the method for manufacturing a multilayer ceramic capacitor disclosed in Patent Document 1 includes the steps of producing a molded body in which ceramic green sheets and internal electrode layers are laminated, and firing the molded body to obtain a sintered body. .
- the step of firing the compacts generally employs a method of placing a plurality of compacts on a ceramic sagger and firing them in a firing furnace.
- each obtained sintered body has characteristics (Electrical characteristics, etc.) and shape, etc., are subject to variation. That is, the characteristics and shape of each sintered body obtained vary depending on the position and the state of placement on the sagger, and the manufactured ceramic electronic component is affected. There is a problem that the characteristics, shape, etc., are subject to variation.
- a method for manufacturing a ceramic electronic component is a method for manufacturing a plurality of chip-shaped ceramic bodies, comprising: a jig preparation step of preparing a jig having a bottom portion for supporting the chip-shaped ceramic body from below and a side wall portion with an upper opening and having a plurality of chip storage portions formed therein; , a chip-shaped ceramic element housing step of housing chip-shaped ceramic elements one by one in one chip-containing portion of a jig; and a chip-shaped ceramic body removing step of removing the chip-shaped ceramic body from the chip storage portion of the jig.
- the method for manufacturing a ceramic electronic component of the present invention it is possible to suppress the occurrence of variations in the quality (characteristics, shape, etc.) of the ceramic electronic component.
- a ceramic electronic component of the present invention it is possible to prevent the plurality of chip-shaped ceramic bodies that have undergone the chip-shaped ceramic body processing step from adhering to each other. Therefore, the productivity of ceramic electronic components can be improved.
- FIG. 1 is a cross-sectional view of a multilayer ceramic capacitor 100.
- FIG. FIGS. 2A and 2B are explanatory diagrams each showing one step in an example of a method for manufacturing the multilayer ceramic capacitor 100.
- FIG. FIGS. 3(C) to 3(F) are continuations of FIG. 2(B), and are explanatory diagrams respectively showing one step in an example of the manufacturing method of the multilayer ceramic capacitor 100, or the multilayer ceramic capacitor being manufactured.
- FIGS. 4(G) and 4(H) are continuations of FIG. 3(F), and are explanatory diagrams each showing one step in an example of the manufacturing method of the multilayer ceramic capacitor 100.
- FIGS. 5(I) and (J) are continuations of FIG.
- FIG. FIG. 6 is a plan view of the jig 1000.
- FIG. 7A to 7D are cross-sectional views of the jig 1000, respectively.
- FIG. 8A is a plan view of the main part of the jig 1000.
- FIG. 8B and 8C are cross-sectional views of the jig 1000, respectively.
- FIG. 9A is an explanatory view showing the dimension P of the diameter of the inscribed circle of the side wall portion 8c of the chip storage portion 8 in the jig 1000.
- FIG. 9B is an explanatory diagram showing the depth dimension Q of the chip storage portion 8 in the jig 1000.
- FIGS. 10A and 10B are explanatory diagrams showing a jig 1000 according to modification 2, respectively.
- FIG. 11 is an explanatory diagram showing a jig 1000 according to Modification 3.
- FIG. 12A and 12B are cross-sectional views of a jig 1000 according to modification 4, respectively.
- FIG. 13A is a plan view of the jig 2000.
- FIG. 13B is a cross-sectional view of the jig 2000.
- each embodiment exemplifies the embodiment of the present invention, and the present invention is not limited to the content of the embodiment. Moreover, it is also possible to combine the contents described in different embodiments, and the contents of the implementation in that case are also included in the present invention.
- the drawings are intended to aid understanding of the specification, and may be schematically drawn, and the drawn components or the dimensional ratios between the components may not be the same as those described in the specification. The proportions of those dimensions may not match.
- constituent elements described in the specification are omitted in the drawings, or where the number of constituent elements is omitted.
- a jig 1000 which will be described later, is used to manufacture the multilayer ceramic capacitor 100.
- the ceramic electronic components to be manufactured are not limited to laminated ceramic capacitors, and other laminated ceramic electronic components such as laminated ceramic inductors, laminated ceramic thermistors, laminated ceramic LC components, laminated ceramic substrates, ceramic resonators, Non-laminated ceramic electronic components such as ceramic filters, ceramic resistors, ceramic thermistors, and ceramic substrates may also be used.
- the jig used for manufacturing is not limited to the jig 1000, and other jigs may be used.
- FIG. 1 shows a laminated ceramic capacitor 100 manufactured in the first embodiment. however.
- FIG. 1 is a cross-sectional view of a multilayer ceramic capacitor 100.
- a laminated ceramic capacitor 100 includes a chip-shaped ceramic element body 11 having a rectangular parallelepiped shape.
- the chip-shaped ceramic body 11 includes a laminate of a plurality of non-conductor layers 11a, a plurality of first internal electrode layers 12, and a plurality of second internal electrode layers 13. As shown in FIG.
- the material of the chip-shaped ceramic body 11 is arbitrary, for example, a dielectric ceramic containing BaTiO 3 as a main component can be used.
- a dielectric ceramic containing BaTiO 3 dielectric ceramics containing other materials as main components such as CaTiO 3 , SrTiO 3 and CaZrO 3 may be used.
- the thickness of the non-conductor layer 11a is arbitrary, but for example, it should be about 0.3 ⁇ m to 2.0 ⁇ m in the effective area for forming the capacitance where the first internal electrode layer 12 and the second internal electrode layer 13 are formed. can be done.
- the number of layers of the non-conductor layer 11a is arbitrary, for example, in the effective region of capacitance formation in which the first internal electrode layer 12 and the second internal electrode layer 13 are formed, the number may be about 1 layer to 6000 layers. can.
- the first internal electrode layer 12 and the second internal electrode layer 13 are not formed on both ends of the chip-shaped ceramic body 11 in the stacking direction, and outer layers (protective layers) composed only of the non-conductor layers 11a are provided.
- the thickness of the non-conductor layer 11a in the outer layer region may be different from the thickness of the non-conductor layer 11a in the effective capacitance forming region where the first internal electrode layers 12 and the second internal electrode layers 13 are formed.
- the material of the non-conductor layer 11a in the outer layer region may be different from the material of the non-conductor layer 11a in the effective region.
- the first internal electrode layer 12 is drawn out to one end surface (arbitrary outer surface perpendicular to the stacking direction) of the chip-shaped ceramic body 11 .
- the second internal electrode layer 13 is drawn out to the other end surface of the chip-shaped ceramic body 11 (the outer surface that is back-to-back with the one end surface).
- the first internal electrode layers 12 and the second internal electrode layers 13 are alternately laminated.
- the material of the main component (metal component) of the first internal electrode layer 12 and the second internal electrode layer 13 is arbitrary, and for example, Ni, Cu, Ag, Pd, Au, etc. can be used. Also, Ni, Cu, Ag, Pd, Au, etc. may be alloys with other metals.
- the first internal electrode layers 12 and the second internal electrode layers 13 may contain other components such as ceramics in addition to the metal component.
- the thickness of the first internal electrode layer 12 and the second internal electrode layer 13 is arbitrary, but can be, for example, about 0.3 ⁇ m to 1.5 ⁇ m.
- a first external electrode 14 is formed on one end face of the outer surface of the chip-shaped ceramic body 11 .
- a second external electrode 15 is formed on the other end face of the outer surface of the chip-shaped ceramic body 11 .
- the first internal electrode layer 12 is electrically connected to the first external electrode 14 .
- the second internal electrode layer 13 is electrically connected to the second external electrode 15 .
- the structures of the first external electrode 14 and the second external electrode 15 are arbitrary. It is also preferable to form a single layer or a plurality of plating electrode layers on the outer surfaces of the first external electrode 14 and the second external electrode 15 . However, in FIG. 1, illustration of the plating electrode layer is omitted.
- the material of the main component (metal component) of the first external electrode 14 and the second external electrode 15 is arbitrary, and for example, Ni, Cu, Ag, Pd, Au, etc. can be used. Also, Ni, Cu, Ag, Pd, Au, etc. may be alloys with other metals.
- the underlying electrode layer may contain other components such as ceramics in addition to the metal components.
- the type and number of plating electrode layers are also arbitrary, and for example, a Cu plating electrode layer, a Ni plating electrode layer, an Sn plating electrode layer, etc. can be formed.
- Example of manufacturing method of multilayer ceramic capacitor 100 A method of manufacturing the multilayer ceramic capacitor 100 according to the present embodiment will be described below with reference to FIGS. 2(A) to 5(J). In addition, in the manufacturing method of the multilayer ceramic capacitor 100 of the present embodiment, a jig 1000, which will be described later, is used.
- Ceramic Green Sheet 21a for producing the non-conductor layer 11a shown in FIG. 2A is produced.
- the ceramic green sheets 21a are preferably prepared as a mother ceramic green sheet 31a including a plurality of ceramic green sheets 21a in order to collectively manufacture a plurality of ceramic electronic components.
- FIG. 2A shows the mother ceramic green sheet 31a, and the ceramic green sheets 21a that form one ceramic electronic component are shown separated by dashed lines.
- the ceramic slurry is coated on the carrier film in the form of a sheet using, for example, a die coater, gravure coater, or micro gravure coater, and dried to produce the ceramic green sheet 21a.
- the produced ceramic green sheet 21a is appropriately peeled off from the carrier film and removed in a later step.
- internal electrode paste 22 for forming first internal electrode layers 12 and second An internal electrode paste 23 for forming the internal electrode layers 13 is applied in a desired pattern shape. Note that the internal electrode paste is not applied to the ceramic green sheets 21a serving as outer layers.
- the internal electrode paste can be applied by, for example, screen printing, inkjet printing, intaglio printing, letterpress printing, or the like. After applying the internal electrode pastes 22 and 23, a drying process is performed.
- the mother ceramic green sheets 31a shown in FIG. 2(B) are laminated in a predetermined order.
- the mother ceramic green sheets 31a include the ceramic green sheets 21a coated with the internal electrode paste 22, the ceramic green sheets 21a coated with the internal electrode paste 23, and the ceramic green sheets 21a not coated with the internal electrode paste. include. At this point, the ceramic green sheet 21a has been peeled off from the carrier film and removed.
- the mother ceramic green sheet laminate 31 includes a plurality of unfired chip-shaped ceramic bodies 21 .
- the mother ceramic green sheet laminate 31 is cut by, for example, a cutting blade 50, and as shown in FIG. Individual unfired chip-shaped ceramic bodies 21 are obtained.
- Jig Preparing Step A jig 1000 is prepared. More specifically, a jig 1000 having a bottom supporting the unfired chip-shaped ceramic bodies 21 from below and sidewalls having an upper opening and having a plurality of chip storage portions 8 formed therein is prepared. Since the jig 1000 will be collectively explained later, the explanation here is omitted.
- Chip-shaped ceramic body housing step Next, as shown in FIG. 4G, a plurality of unfired chip-shaped ceramic bodies 21 are placed on the upper surface of the jig 1000 at irregular positions and states. place. Then, the jig 1000 is vibrated, and as shown in FIG. After the storage is completed, the extra unfired chip-shaped ceramic bodies 21 can be removed from the jig 1000 by further applying vibration, tilting the jig 1000, tilting the jig 1000 while applying vibration, or the like. preferable.
- the unfired chip-shaped ceramic body 21 may be accommodated in the chip accommodating portion 8 by tilting the jig 1000 instead of vibrating the jig 1000 . Instead of placing the unfired ceramic chips 21 on the upper surface of the jig 1000, the unfired ceramic chips 21 are directly stored in the chip storage unit 8 by using an automatic machine or the like. You may do so.
- the unfired chip-shaped ceramic bodies 21 are stored one by one in one chip storage portion 8 of the jig 1000, heated together with the jig 1000, and fired. If the ceramic green sheets 21a contain a resin component, a degreasing process may be performed to reduce or remove the resin component by heating prior to the firing process.
- Firing is performed with the desired temperature profile.
- the ceramic green sheets 21 a become the non-conductor layers 11 a
- the internal electrode paste 22 becomes the first internal electrode layers 12
- the internal electrode paste 23 becomes the second internal electrode layers 13 .
- the unfired chip-shaped ceramic body 21 becomes the fired chip-shaped ceramic body 11 .
- a first external electrode 14 is formed on one end of the chip-shaped ceramic body 11, and a second external electrode 15 is formed on the other end.
- the external electrode paste is applied to both ends of the outer surface of the chip-shaped ceramic body 11 .
- the chip-shaped ceramic element body 11 coated with the external electrode paste is heated, and the external electrode paste is baked on the outer surface of the chip-shaped ceramic element body 11 to form the first external electrode 14 and the second external electrode 15 . to form
- the outer surfaces of the first external electrode 14 and the second external electrode 15 are electroplated, for example, to form a plated layer consisting of one layer or multiple layers.
- the multilayer ceramic capacitor 100 is completed.
- Modification 1 of the manufacturing method of the multilayer ceramic capacitor 100 In the above-described method for manufacturing the multilayer ceramic capacitor 100, the plurality of mother ceramic green sheets 31a are laminated, pressure-bonded, and integrated to form the mother ceramic green sheet laminate 31. After that, the mother ceramic green sheet laminate 31 is formed. , into individual unfired chip-shaped ceramic bodies 21 . Modification 1 changes this method.
- a mother ceramic green sheet 31a including a plurality of ceramic green sheets 21a is cut into individual ceramic green sheets 21a. Then, a plurality of cut ceramic green sheets 21a are laminated, pressure-bonded, and integrated to produce an unfired chip-like ceramic body 21 .
- Modification 2 of the manufacturing method of the multilayer ceramic capacitor 100 In the manufacturing method of the multilayer ceramic capacitor 100 described above, the unfired chip-shaped ceramic element bodies 21 are fired to obtain the fired chip-shaped ceramic body bodies 11, and then the external electrodes are attached to both ends of the chip-shaped ceramic body bodies 11. A paste was applied and baked to form the first external electrode 14 and the second external electrode 15 . Modification 2 changes this method.
- the external electrode paste is applied to both ends of the unfired chip-shaped ceramic body 21 . Then, in the firing step, the external electrode paste is baked to form the first external electrode 14 and the second external electrode 15 on both ends of the chip-shaped ceramic body 11, respectively.
- the method of forming the first external electrode 14 and the second external electrode 15 may be changed.
- FIG. 6 is a plan view of the jig 1000.
- FIG. 7A to 7D are cross-sectional views of the jig 1000, respectively.
- FIG. 7(A) shows the dashed-dotted line arrow S--S portion of FIG.
- FIG. 7(B) shows the dashed-dotted line arrow T--T portion of FIG.
- FIG. 7(C) shows the dashed-dotted line arrow U-U portion of FIG.
- FIG. 7(D) shows the dashed-dotted line arrow VV portion of FIG.
- FIG. 8A is a plan view of the main part of the jig 1000.
- FIG. 8A is a plan view of the main part of the jig 1000.
- 8B and 8C are cross-sectional views of the jig 1000, respectively.
- 8(A) shows the upper right end portion of the jig 1000 in FIG.
- FIG. 8(B) shows the dashed-dotted line arrow S--S part of FIG.
- FIG. 8(C) shows the dashed-dotted arrow U-U portion of FIG.
- the jig 1000 has a vertical direction X, a horizontal direction Y orthogonal to the vertical direction X, and a height direction Z orthogonal to the vertical direction X and the horizontal direction Y. may mention.
- a plane including the vertical direction X and the horizontal direction Y may be called a reference plane, and the reference plane may be referred to in the following description.
- the jig 1000 includes a first linear member group 1G, a second linear member group 2G, a third linear member group 3G, and a fourth linear member group 4G, which are stacked in order from bottom to top in the height direction Z. , a fifth linear member group 5G, a sixth linear member group 6G, and a seventh linear member group 7G.
- the number of linear member groups is not limited to seven, and can be increased or decreased from seven.
- the first linear member group 1G includes seven linear linear members 1 extending in the longitudinal direction X.
- the seven linear members 1 are arranged at an arrangement pitch D in parallel with each other. It should be noted that the arrangement pitch refers to the distance between the centers of two adjacent linear members that are arranged apart from each other.
- the second linear member group 2G includes seven linear linear members 2 extending in the horizontal direction Y.
- the seven linear members 2 are arranged at an arrangement pitch E in parallel with each other.
- the interval E may be the same size as the interval D, or may be different in size from the interval D.
- the third linear member group 3G includes eight linear linear members 3 extending in the longitudinal direction X.
- the eight linear members 3 are arranged at an arrangement pitch D in parallel with each other.
- the linear members 3 of the third linear member group 3G are located between the linear members 1 and 3 when viewed in the height direction Z with respect to the linear members 1 of the first linear member group 1G.
- the intervals are arranged so as to be uniform at all points.
- the linear members 3 of the third linear member group 3G are not visible because they are arranged directly below the linear members 7 of the seventh linear member group 7G, which will be described later.
- the fourth linear member group 4G includes eight linear linear members 4 extending in the horizontal direction Y.
- the eight linear members 4 are arranged at an arrangement pitch E in parallel with each other.
- the linear members 4 of the fourth linear member group 4G are separated from each other by the linear members 2 and 4 when viewed in the height direction Z with respect to the linear members 2 of the second linear member group 2G.
- the intervals are arranged so as to be uniform at all points.
- the linear members 4 of the fourth linear member group 4G are not visible because they are arranged directly below the linear members 6 of the sixth linear member group 6G, which will be described later.
- the fifth linear member group 5G includes eight linear linear members 5 extending in the longitudinal direction X.
- the eight linear members 5 are arranged at an arrangement pitch D in parallel with each other.
- the linear members 5 of the fifth linear member group 5G are arranged directly above the linear members 3 of the third linear member group 3G. In the plan view of FIG. 6, the linear members 5 of the fifth linear member group 5G are not visible because they are arranged directly below the linear members 7 of the seventh linear member group 7G, which will be described later.
- the sixth linear member group 6G includes eight linear linear members 6 extending in the horizontal direction Y.
- the eight linear members 6 are arranged at an arrangement pitch E in parallel with each other.
- the linear members 6 of the sixth linear member group 6G are arranged directly above the linear members 4 of the fourth linear member group 4G.
- the seventh linear member group 7G includes eight linear linear members 7 extending in the vertical direction X.
- the eight linear members 7 are arranged at an arrangement pitch D in parallel with each other.
- the linear members 7 of the seventh linear member group 7G are arranged directly above the linear members 5 of the fifth linear member group 5G.
- the number of linear members 1 to 7 is arbitrary and can be increased or decreased.
- the linear members 1, 3, 5, 7 and the linear members 2, 4, 6 are orthogonal. That is, they intersect at an angle of 90°.
- the angle at which the linear members 1, 3, 5, 7 and the linear members 2, 4, 6 intersect is not limited to 90°, and can be increased or decreased from 90°.
- the linear members 1 to 7 each have a circular cross-sectional shape and the same area and diameter.
- the cross-sectional shape, area, diameter, etc. of the linear members 1 to 7 are arbitrary and can be freely selected. Further, the cross-sectional shape, area, diameter, etc. of the linear members 1 to 7 may differ from one linear member to another.
- ceramic is used as the material (raw material) of the linear members 1 to 7.
- ceramics that can be used include SiC, zirconia, yttria-stabilized zirconia, alumina, and mullite.
- the materials of the linear members 1 to 7 are arbitrary, and instead of ceramic, metals such as nickel, aluminum, Inconel (registered trademark), SUS, polytetrafluoroethylene (PTFE; polytetrafluoroethylene), polypropylene (PP; polypropylene), acrylic resins, ABS (acrylonitrile butadiene styrene)-like resins, other resin materials such as heat-resistant resins, carbon, composite materials made of metal and ceramic, and the like.
- PTFE polytetrafluoroethylene
- PP polypropylene
- acrylic resins ABS (acrylonitrile butadiene styrene)-like resins
- other resin materials such as heat-resistant resins, carbon, composite materials made of metal and ceramic, and the like.
- the surfaces of the linear members 1 to 7 may be further coated with ceramics such as SiC, zirconia, yttria-stabilized zirconia, alumina and mullite, or metals such as nickel.
- ceramics such as SiC, zirconia, yttria-stabilized zirconia, alumina and mullite, or metals such as nickel.
- the jig 1000 for example, wet-mixes ceramic powder, binder resin, solvent, etc., and molds them to produce unfired ceramic linear members. It can be produced by producing a structure and firing the structure.
- the jig 1000 configured as described above has a plurality of chip storage portions 8 .
- the chip storage portion 8 has an opening 8a on the upper side.
- the chip housing portion 8 is for housing a chip-shaped ceramic body.
- a plurality of chip storage portions 8 are formed in the jig 1000 with regularity.
- a plurality of chip storage portions 8 are formed in a matrix (a grid pattern) on the main surface of the jig 1000 .
- the arrangement of the chip storage portions 8 is not limited to a matrix.
- Each of the chip storage portions 8 has a bottom portion 8b that supports the chip-shaped ceramic body from below, and a side wall portion 8c opened by an opening 8a.
- one chip storage portion 8 has one bottom portion 8b and four side wall portions 8c.
- the number of side wall portions 8c is not limited to four, and can be increased or decreased from four.
- the chip storage part 8 stores the chip-shaped ceramic element without restraining it.
- the bottom portion 8b of the chip storage portion 8 is formed by the top surface (ridgeline) of the linear member 2. As shown in FIG. The bottom portion 8b has a bottom through-hole 8d formed by a gap between two linear members 2 adjacent to each other and communicating with the rear surface of the bottom portion 8b.
- the side wall portion 8c of the chip storage portion 8 is formed by the linear members 4, 6 or the linear members 3, 5, 7.
- the side wall portion 8c has a gap between the linear member 4 and the linear member 6, a gap between the linear member 3 and the linear member 5, a gap between the linear member 5 and the linear member 7, and the like.
- the jig 1000 having the structure described above, it is possible to carry out the chip-shaped ceramic body processing step (for example, the firing step) while the chip-shaped ceramic bodies are individually housed in the chip housing portion 8 one by one. , variation in processing conditions for each chip-shaped ceramic body can be reduced. Therefore, the ceramic electronic component manufactured using the jig 1000 has less variation in quality (characteristics, shape, etc.).
- the chip-shaped ceramic bodies do not come into contact with each other during the chip-shaped ceramic body processing step (for example, the firing process). are difficult to adhere to each other. Moreover, even if the chip-shaped ceramic bodies are brittle, they are unlikely to be damaged by mutual collision. Therefore, the use of the jig 1000 can reduce the rejection rate of ceramic electronic components.
- the chip-like ceramic element can be easily accommodated in the chip accommodating portion 8 in a short time, so that ceramic electronic components can be manufactured with high productivity.
- the material of the jig 1000 when ceramic is used as the material (material) of the jig 1000, it has higher heat resistance than other materials. Damage and deformation of the jig 1000 can be suppressed. Moreover, if the material of the jig 1000 is ceramic, it is possible to reduce the need to consider the synthesis atmosphere and the firing atmosphere. For example, if the jig 1000 is made of nickel, it may absorb oxygen in the atmosphere and change the atmosphere. Moreover, if the material of the jig 1000 is ceramic, it is possible to reduce the consideration of the reaction with the chip-shaped ceramic body. For example, if the material of the jig 1000 is iron, it may react with the chip-shaped ceramic body.
- the jig 1000 since the jig 1000 has linear members 1 to 7 that are substantially linear and has no bent portions, it is resistant to physical impact. Moreover, even if stress is applied due to temperature change, it is difficult to break. Therefore, the jig 1000 is less likely to break even when a material such as ceramic that is weak against impact is used.
- a side wall through hole 8e is formed in the side wall portion 8c, and a bottom through hole 8d is formed in the bottom portion 8b. It is desirable that the side wall portion through-hole 8e and the bottom portion through-hole 8d have a size and a shape that the chip-shaped ceramic body cannot pass through.
- the jig 1000 has, in addition to the opening 8a, a side wall through-hole 8e and a bottom through-hole 8d through which gas can pass, and thus has good air permeability. Therefore, if the jig 1000 is used, it is possible to suppress processing defects caused by poor air permeability.
- the jig 1000 is designed so that one chip storage portion 8 can accommodate one chip-like ceramic element.
- the chip storage portion 8 stores rectangular parallelepiped chip-shaped ceramic elements in an upright state (a state in which the long sides of the chip-shaped ceramic elements are parallel to the height direction Z). I assume.
- the dimensions of the chip housing portion 8 have a margin so that the chip-like ceramic body can be easily inserted.
- the dimensions of the chip storage portion 8 must not be such that the chip-like ceramic body can be accommodated in a laid state.
- the size of the chip storage portion 8 must not be such that two or more chip-like ceramic bodies can be accommodated side by side in an upright state.
- the size of the chip housing portion 8 must not allow the chip-like ceramic element once housed in the chip housing portion 8 to easily pop out when subjected to vibration.
- the dimensions of the chip storage portion 8 should not be such that two or more chip-shaped ceramic bodies are vertically stacked and stored in an upright state.
- the dimension of the tip storage portion 8 is the diameter P , and the depth dimension Q defined by the dimension from the bottom portion 8b of the chip storage portion 8 to the opening 8a when viewed in the side direction orthogonal to the height direction shown in FIG. 1) is preferably satisfied.
- the dimensions of the chip storage portion 8 satisfy formula (1) will be described below.
- the dimensions of the chip-shaped ceramic body to be housed in the chip housing portion 8 are the shape adopted in many ceramic electronic components. Assume that the dimension is 2a.
- Equation (2) defines that ( ⁇ 2)a, which is the dimension of the diagonal of the chip-shaped ceramic body viewed in the height direction, is smaller than the dimension P of the diameter of the inscribed circle. It stipulates that the ceramic body is rotatable within the chip housing portion 8 .
- the dimensions of the chip storage part 8 must not be such that one chip-shaped ceramic element can be stored in a laid state. Moreover, the dimensions of the chip storage portion 8 should not be such that two or more chip-shaped ceramic bodies can be accommodated side by side in an upright state.
- 2a which is twice the width dimension a, twice the thickness dimension a, and is also the length dimension, should be larger than the dimension P of the diameter of the inscribed circle. That is, the following formula (3) should be satisfied.
- the depth Q of the chip accommodating portion 8 should be larger than 0.5 times (half) the length 2a of the chip-shaped ceramic body. That is, it is sufficient if 2a ⁇ 0.5 ⁇ Q, and the following formula (4) is satisfied.
- the depth Q of the chip storage section 8 must be equal to the length dimension 2a of the chip-shaped ceramic body. should be smaller than 1.5 times. Even if unnecessary chip-shaped ceramic bodies are accommodated on the top, by applying vibration, tilting the jig, or tilting the jig while applying vibration, the unnecessary chip-shaped ceramic bodies accommodated above are removed. is easily removed to the outside of the chip storage section 8 . Therefore, it suffices if Q ⁇ 2a ⁇ 1.5 and satisfies the following equation (5).
- formula (1) is established by combining formula (6) and formula (7).
- the dimension of the chip storage portion 8 is P, which is the diameter of the inscribed circle of the side wall portion 8c of the chip storage portion 8 when viewed from above in the height direction, and the dimension when viewed in the side direction orthogonal to the height direction. Further, when the depth defined by the dimension from the bottom portion 8b of the chip storage portion 8 to the opening 8a is Q, it is preferable to satisfy the formula (1).
- the chip housing portion 8 of the jig 1000 is large enough to contain the chip-shaped ceramic bodies.
- the chip storage part 8 does not store the chip-shaped ceramic bodies in a lying state and does not store two or more chip-shaped ceramic bodies side by side in an upright state. Vibration is applied to the chip-shaped ceramic bodies properly housed in the container 8 so that they do not easily fly out, and moreover, two or more chip-shaped ceramic bodies are kept standing in the chip housing part 8. They are not stacked on top of each other.
- a small chip-shaped ceramic body is processed using a jig 1000 having a large chip storage portion 8 and a large chip-shaped ceramic body is processed using a jig 1000 equipped with a small chip storage portion 8. is the case.
- a part of the jig 1000 with unique characteristics different from other parts so that the type of the jig 1000 can be easily distinguished.
- Different singular features are, for example, colors. Giving a part of the jig 1000 a color different from that of other parts is preferable because the jig 1000 does not deteriorate its air permeability, heat resistance, resistance to physical impact, and the like.
- the different peculiar features are not limited to the color, and may be a change in the shape of the jig 1000 or the addition of a mark member.
- the jig 1000 described above is composed of the linear members 1 to 7, and it is conceivable to make one type of linear member among them a different color from the other linear members.
- the color of the linear member 1 may be changed to red, blue, or green for each jig 1000. It is a method of color coding. In any jig 1000, the colors of the remaining linear members 2 to 7 are different from that of the linear member 1. FIG. This method makes it easier to distinguish between different types of jigs 1000 .
- a method of changing the color of the linear member for example, there is a method of adding heat-resistant ink, colored zirconia, or the like to the material of the linear member 1 .
- This method is preferable because it does not reduce the heat resistance of the jig 1000 even when the jig 1000 contains ceramics.
- it is more preferable to color the linear members 1 belonging to the first linear member group 1G. Since the linear members 1 belonging to the first linear member group 1G do not come into contact with the chip-shaped ceramic elements housed in the chip housing portion 8, the effect of coloring on the chip-shaped ceramic elements can be eliminated. , or can be minimized.
- FIGS. 10(A) and (B) show a modified example 2 in which the jig 1000 can be separated into a lower portion 1000A and an upper portion 1000B.
- FIG. 10A shows a state in which the lower portion 1000A and the upper portion 1000B are separated
- FIG. 10B shows a state in which the lower portion 1000A and the upper portion 1000B are combined.
- the lower portion 1000A is formed by linear members 1-5.
- the upper portion 1000B is formed by linear members 6 and 7. As shown in FIG.
- the lower portion 1000A has a lower chip storage portion 8f having a lower wall portion 8ca.
- the upper portion 1000B includes an upper chip storage portion 8g having an upper wall portion 8cb.
- the chip storage portion 8 is composed of a lower chip storage portion 8f and an upper chip storage portion 8g.
- the side wall portion 8c is composed of a lower side wall portion 8ca and an upper side wall portion 8cb.
- the head of the chip-shaped ceramic body 200 housed in the chip housing part 8 may or may not be better to come out of the chip housing part 8 through the opening 8a. .
- the head of the chip-shaped ceramic body 200 when taking out the chip-shaped ceramic body 200 from the chip storage section 8 , it is generally better for the head of the chip-shaped ceramic body 200 to come out of the chip storage section 8 .
- the chip-like ceramic body 200 is easier to take out as the depth of the chip storage portion 8 is smaller.
- the upper part 1000B of the jig 1000 can be removed and the head of the chip-shaped ceramic body 200 can be put out of the chip storage section 8. FIG. That is, the depth of the chip storage portion 8 can be reduced.
- the chip-shaped ceramic body 200 when the chip-shaped ceramic body 200 is housed in the chip housing portion 8 , it is generally preferable that the head of the chip-shaped ceramic body 200 does not protrude outside the chip housing portion 8 .
- the chip-shaped ceramic body 200 that has been previously housed in the chip housing portion 8 pushes the other chip-shaped ceramic bodies that have not yet been housed. This is because there is a risk that the body will be prevented from being stored in the other tip storage portion 8 .
- the lower portion 1000A and the upper portion 1000B are combined so that the head of the chip-shaped ceramic body 200 does not protrude outside the chip storage portion 8. FIG. That is, the depth of the chip storage portion 8 can be increased.
- the upper part 1000B is for removing or not removing the head of the chip-shaped ceramic body 200 housed in the chip housing part 8, depending on whether or not the head is put out. It is also preferable to make the height dimension of 1000A larger than the height dimension of upper portion 1000B.
- the jig 1000 may be separable into three or more parts in the height direction Z.
- the jig 1000 of modification 2 can be separated into a plurality of parts in the height direction Z, so that the depth of the chip storage section 8 can be changed.
- FIG. 11 shows a modified example 3 of the jig 1000 in which the area of the chip storage section 8 surrounded by the side wall section 8c increases from the bottom to the top.
- the diameter of each linear member 1 to 7 may be changed as appropriate.
- the method of increasing the size of the opening of the chip storage portion 8 from the bottom to the top is not limited to the method of adjusting the size of the diameter of the linear members 1 to 7, and other methods may be used. good too.
- FIGS. 12A and 12B show a jig 1000 according to Modification 4.
- FIG. 12A and 12B are cross-sectional views of the jig 1000, respectively.
- the arrangement pitch of the linear members has been changed. That is, in the jig 1000 described above, a plurality of linear members 3 extending in the vertical direction X are arranged in parallel in the horizontal direction Y at the arrangement pitch D. As shown in FIG. A plurality of linear members 4 extending in the horizontal direction Y are arranged in parallel in the vertical direction X at an arrangement pitch E. A plurality of linear members 5 extending in the vertical direction X are arranged in parallel in the horizontal direction Y at an arrangement pitch D. A plurality of linear members 6 extending in the horizontal direction Y are arranged in parallel in the vertical direction X at an arrangement pitch E. A plurality of linear members 7 extending in the vertical direction X are arranged in parallel in the horizontal direction Y with an arrangement pitch D. Chip accommodating portions 8 were formed in a matrix on the entire main surface of the jig 1000 .
- Modification 4 changes this, and in linear members 3, 4, 5, 6, and 7, the arrangement pitch, which is the distance between the centers of two adjacent linear members that are spaced apart, is partially different. Specifically, for the linear members 3, 5, and 7, a large arrangement pitch DB and a small arrangement pitch DS are alternately repeated. Also, for the linear members 4 and 6, the large arrangement pitch EB and the small arrangement pitch ES are alternately repeated. In order to improve air permeability, which will be described below, the size of the large arrangement pitch DB is preferably 120% or more of the small arrangement pitch DS. Also, the size of the large arrangement pitch EB is preferably 120% or more of the small arrangement pitch ES.
- chip storage portions 8 capable of storing chip-shaped ceramic bodies and non-chip storage portions 38 not housing chip-shaped ceramic bodies.
- the contained chip-shaped ceramic body may reduce air permeability.
- the jig 1000 according to Modification 4 is provided with the non-chip storage portion 38 in which the chip-shaped ceramic body cannot be stored, so that air permeability is improved.
- the chip-shaped ceramic body 21 is housed in the chip housing portion 8 of the jig 1000, and the chip-shaped ceramic body processing step (for example, the firing step) is carried out.
- Variation in quality is suppressed in the chip-shaped ceramic body 11 after processing. That is, the chip-shaped ceramic bodies 11 accommodated in any of the chip accommodation units 8 and processed can have extremely similar quality.
- the chip-shaped ceramic bodies 11 that have undergone the chip-shaped ceramic body processing step are prevented from adhering to each other. ing.
- the processing time treatment time
- a reaction-related step such as a degreasing step.
- the defective product rate is low, and ceramic electronic components can be manufactured with high productivity.
- the jig used in the chip-shaped ceramic body processing step is changed from the first embodiment. That is, in the first embodiment, the above-described jig 1000 is used to perform the chip-shaped ceramic body processing step (for example, the firing step). ) and (B), the jig 2000 is used to carry out the chip-shaped ceramic body processing step.
- FIG. 13A is a plan view of the jig 2000.
- FIG. 13(B) is a cross-sectional view of the jig 2000 and shows the dashed-dotted line arrow R--R portion of FIG. 13(A).
- the jig 2000 is rectangular when viewed from above in the height direction, and has a lower main surface and an upper main surface.
- the jig 2000 has a plurality of chip storage sections 28 formed in a matrix on the upper main surface. When viewed from above in the height direction, each of the chip storage portions 28 has a rectangular shape.
- Each tip storage section 28 is opened with an opening 28a on the upper side in the height direction.
- Each chip storage portion 28 has a bottom portion 28b that supports the chip-shaped ceramic body from below.
- Each chip storage portion 28 has a side wall portion 28c that separates adjacent chip storage portions 28 from each other. At least one of the bottom portion 28b and the side wall portion 28c may be formed with a through-hole having a size and a shape that the chip-like ceramic element cannot pass through.
- the jig 2000 may be made of any material, but may be made mainly of ceramic, for example.
- a multilayer ceramic capacitor 100 (ceramic electronic component) was manufactured using a jig 2000 in the same manner as in the first embodiment.
- the multilayer ceramic capacitor 100 (ceramic electronic component) in which variations in quality are suppressed.
- the chip-shaped ceramic bodies that have undergone the processing step are prevented from adhering to each other.
- a multilayer ceramic capacitor was manufactured as a ceramic electronic component, but the ceramic electronic component to be manufactured is not limited to a multilayer ceramic capacitor.
- Laminated ceramic electronic components such as ceramic LC components and laminated ceramic substrates, and non-laminated ceramic electronic components such as ceramic resonators, ceramic filters, ceramic resistors, ceramic thermistors and ceramic substrates may also be used.
- the chip-shaped ceramic body processing step is the firing step by heating, but the processing step is not limited to the synthesis step by heating.
- the chip-shaped ceramic body processing process includes, for example, a synthesis process, a degreasing process, a cleaning process, a drying process, an external electrode forming process (paste application, plating, vacuum film formation such as sputtering and vapor deposition, etc.), an external shape processing process (edge portion rounding, exposure of the end of the internal electrode, machining, mechanical polishing, sandblasting, liquid or gas phase chemical etching, laser or plasma processing, etc.), annealing process, aging process, polarization process, characteristic selection process, appearance It may be a selection process, an environmental test process (which may include stress application), or the like.
- a jig containing ceramic as a raw material for a process including heating because of its high heat resistance.
- a jig having through holes in at least one of the bottom and side walls of the chip storage section because of its high air permeability and liquid permeability. is.
- a method for manufacturing a ceramic electronic component according to one embodiment of the present invention is as described in the "Means for Solving the Problems" column.
- the step of processing the chip-shaped ceramic body is preferably a firing step.
- the plurality of fired chip-shaped ceramic bodies are less likely to adhere to each other, and the occurrence of defective products is suppressed.
- a plurality of chip-shaped ceramic elements are placed on a jig at irregular positions and states, and the jig is vibrated and/or tilted. It is also preferable that a plurality of chip-like ceramic bodies placed on the jig are housed in the chip housing. In this case, the chip-shaped ceramic body can be easily accommodated in the chip accommodating portion in a short period of time.
- the chip-shaped ceramic body manufacturing process includes a mother ceramic green sheet manufacturing process for manufacturing a mother ceramic green sheet containing a plurality of ceramic green sheets, and a mother ceramic green sheet manufacturing process for stacking and integrating a plurality of mother ceramic green sheets to form a mother ceramic. including a mother ceramic green sheet laminate producing step for producing a green sheet laminate, and a mother ceramic green sheet laminate cutting step for cutting the mother ceramic green sheet laminate into individual chip-shaped ceramic bodies. is preferred. In this case, it is possible to manufacture a multilayer ceramic electronic component in which variations in quality (characteristics, shape, etc.) are suppressed.
- the chip-shaped ceramic body manufacturing step includes an internal electrode paste application step of applying an internal electrode paste to the main surface of a predetermined ceramic green sheet.
- the internal electrodes can be easily formed inside the laminated ceramic electronic component.
- an external electrode paste application step of applying an external electrode paste to the outer surface of the unfired chip-shaped ceramic body before the chip-shaped ceramic body processing step is also preferable to include an external electrode paste application step of applying an external electrode paste to the outer surface of the unfired chip-shaped ceramic body before the chip-shaped ceramic body processing step.
- an external electrode paste application step of applying an external electrode paste to the outer surface of the fired chip-shaped ceramic body, and applying the external electrode paste to the chip-shaped ceramic body is also preferable to include an external electrode paste baking step for baking the outer surface of the element. In these cases, external electrodes can be easily formed on the outer surface of the ceramic electronic component.
- the plated electrode layer can protect the external electrodes and improve the solder wettability of the external electrodes.
- the jig contains ceramic as a material.
- the heat resistance is higher than that of other materials, damage and deformation of the jig can be suppressed even if the processing process involves heating, such as a synthesis process or a firing process.
- the material of the jig is ceramic, it is possible to reduce considerations for the synthesis atmosphere and the firing atmosphere. In addition, it is possible to reduce considerations for reaction with the chip-shaped ceramic body.
- the jig is made of a plurality of linear members. In this case, since there is no bent portion in the constituent members, a jig that is resistant to physical impact can be obtained. Also, it is possible to obtain a jig that is less likely to break even when stress is applied due to temperature changes.
- the jig has a vertical direction, a horizontal direction orthogonal to the vertical direction, and a height direction orthogonal to the vertical direction and the horizontal direction, and the plurality of linear members are arranged in any one of the plurality of linear member groups.
- a plurality of linear member groups belonging to each other are stacked in the height direction, and a plurality of linear members belonging to one linear member group are arranged parallel to each other and spaced apart from each other when viewed in the height direction.
- a linear member belonging to a linear member group laminated in a certain layer and a linear member belonging to another linear member group laminated in another adjacent layer may intersect each other. preferable.
- the linear member is substantially linear and has no bending portion, it is possible to obtain a jig that is resistant to physical impact. Also, it is possible to obtain a jig that is less likely to break even when stress is applied due to temperature changes.
- the jig has a bottom portion composed of one or more linear members belonging to one linear member group, and a sidewall portion composed of one linear member belonging to one linear member group, or two or more linear members.
- the bottom portion has a bottom through-hole communicating with the rear surface of the bottom portion, and the side wall portion communicates with another adjacent chip storage portion.
- the bottom through-hole is formed by the gap between two adjacent linear members in the linear member group constituting the bottom, and the side wall through-hole constitutes the side wall. It is also preferable to be constituted by the gaps between the linear members that are connected to each other. In this case, a jig with good air permeability can be obtained. Therefore, if the jig is used, it is possible to suppress processing defects caused by poor air permeability.
- the arrangement pitch which is the distance between the centers of two adjacent linear members arranged apart, is partially different.
- a non-chip storage section that does not store the chip-shaped ceramic body can be provided, so that air permeability can be improved.
- the chip storage portions are formed in a matrix on the main surface of the jig.
- the jig can be provided with a large number of chip storage portions, and ceramic electronic components can be manufactured with high productivity.
- the jig is separable into a plurality of parts in the height direction.
- the head of the chip-shaped ceramic element may be moved to the chip storage portion as necessary in the chip-shaped ceramic element housing step, the chip-shaped ceramic element processing step, the chip-shaped ceramic element extraction step, or the like. You can choose to let it out or not.
- the opening area of the chip storage part increases from the bottom to the top. In this case, the efficiency of the chip-shaped ceramic element housing process and the chip-shaped ceramic element extraction process is improved.
- the chip accommodating portion has sufficient room to accommodate the chip-like ceramic element, the chip-like ceramic element is not accommodated in the chip accommodating portion in a laid state, and two or more chips are provided.
- chip-shaped ceramic bodies which are not stored side by side in an upright state and which are once properly housed in a chip housing part from easily popping out due to the application of vibration, and furthermore, to store chips. There is no possibility that two or more chip-like ceramic bodies are vertically piled up and accommodated in the part.
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Abstract
Description
第1実施形態においては、後に説明するジグ1000を使用して、積層セラミックコンデンサ100を製造する。だだし、製造するセラミック電子部品は、積層セラミックコンデンサには限られず、積層セラミックインダクタ、積層セラミックサーミスタ、積層セラミックLC部品、積層セラミック基板などの他の積層型のセラミック電子部品や、セラミック共振器、セラミックフィルタ、セラミック抵抗、セラミックサーミスタ、セラミック基板などの非積層型のセラミック電子部品であってもよい。また、製造に使用するジグは、ジグ1000には限られず、他のジグを使用してもよい。
図1に、第1実施形態で製造する積層セラミックコンデンサ100を示す。ただし。図1は、積層セラミックコンデンサ100の断面図である。
以下に、図2(A)~図5(J)を参照して、本実施形態にかかる積層セラミックコンデンサ100の製造方法について説明する。なお、本実施形態の積層セラミックコンデンサ100の製造方法においては、後に説明するジグ1000を使用する。
図示は省略するが、誘電体セラミックの粉末、バインダ樹脂、溶剤などを用意し、これらを湿式混合してセラミックスラリーを作製する。
図2(A)に示す、非導電体層11aを作製するためのセラミックグリーンシート21aを作製する。セラミックグリーンシート21aは、複数のセラミック電子部品を一括して製造するために、複数のセラミックグリーンシート21aを含むマザーセラミックグリーンシート31aとして用意することが好ましい。図2(A)にはマザーセラミックグリーンシート31aを示し、1つのセラミック電子部品となるセラミックグリーンシート21aを、一点鎖線で区切って示している。
図示は省略するが、金属の粉末、バインダ樹脂、溶剤などを用意し、これらを湿式混合して内部電極用ペーストおよび外部電極用ペーストを作製する。内部電極用ペーストと外部電極用ペーストとは、相互に、材質、材質の比率、粘度などが異なっていてもよい。
図2(B)に示すように、所定のセラミックグリーンシート21aの主面に、第1内部電極層12を形成するための内部電極用ペースト22と、第2内部電極層13を形成するための内部電極用ペースト23とを、それぞれ所望のパターン形状に塗布する。なお、外層となるセラミックグリーンシート21aには、内部電極用ペーストは塗布しない。内部電極用ペーストの塗布は、たとえば、スクリーン印刷、インクジェット印刷、凹版印刷、凸版印刷などによりおこなうことができる。内部電極用ペースト22、23を塗工した後に、乾燥処理をおこなう。
まず、図2(B)に示すマザーセラミックグリーンシート31aを、所定の順番に積層する。マザーセラミックグリーンシート31aには、内部電極用ペースト22が塗布されたセラミックグリーンシート21a、内部電極用ペースト23が塗布されたセラミックグリーンシート21a、内部電極用ペーストが塗布されていないセラミックグリーンシート21aが含まれている。なお、この時点では、セラミックグリーンシート21aは、キャリアフィルムから剥離され、取り外されている。
図3(D)に示すように、マザーセラミックグリーンシート積層体31を、たとえば切断刃50によってカットし、図3(E)に示すように、複数の個々の未焼成のチップ状セラミック素体21を得る。
必要に応じて、未焼成のチップ状セラミック素体21をバレル研磨にかけ、図3(F)に示すように、未焼成のチップ状セラミック素体21の角部や稜線部に丸みRを形成する。
ジグ1000を準備する。より具体的には、未焼成のチップ状セラミック素体21を下方から支持する底部と、上方が開口された側壁部とを有する、複数のチップ収納部8が形成されたジグ1000を準備する。ジグ1000については、後でまとめて説明するので、ここでの説明は割愛する。
次に、図4(G)に示すように、ジグ1000の上面に、複数の未焼成のチップ状セラミック素体21を、位置および状態を不規則に載置する。そして、ジグ1000に振動を与え、図4(H)に示すように、未焼成のチップ状セラミック素体21を、それぞれ、ジグ1000の1つのチップ収納部8に1つずつ収納する。なお、収納が完了した後、さらに振動を与える、ジグ1000を傾ける、振動を与えながらジグ1000を傾けるなどの方法で、余分な未焼成のチップ状セラミック素体21を、ジグ1000から取り除くことも好ましい。
図4(H)に示すように、未焼成のチップ状セラミック素体21を、ジグ1000の1つのチップ収納部8に1つずつ収納した状態で、ジグ1000とともに加熱し、焼成する。なお、セラミックグリーンシート21aに樹脂成分が含まれる場合には、焼成工程に先立ち、加熱などによって、その樹脂成分を削減あるいは除去する、脱脂工程をおこなってもよい。
図5(I)に示すように、焼成済のチップ状セラミック素体11を、ジグ1000のチップ収納部8から取り出す。
図5(J)に示すように、チップ状セラミック素体11の一方の端部に第1外部電極14を形成し、他方の端部に第2外部電極15を形成する。
次に、第1外部電極14および第2外部電極15の外表面に、たとえば電解めっきを施し、1層または複数層からなる、めっき層を形成する。
上述した積層セラミックコンデンサ100の製造方法では、複数のマザーセラミックグリーンシート31aを積層し、圧着して、一体化させ、マザーセラミックグリーンシート積層体31を作製した後に、マザーセラミックグリーンシート積層体31を、個々の未焼成のチップ状セラミック素体21にカットした。変形例1では、この方法を変更する。
上述した積層セラミックコンデンサ100の製造方法では、未焼成のチップ状セラミック素体21を焼成し、焼成済のチップ状セラミック素体11を得た後に、チップ状セラミック素体11の両端に、外部電極用ペーストを塗布し、焼付けて、第1外部電極14および第2外部電極15を形成した。変形例2では、この方法を変更する。
次に、上述した積層セラミックコンデンサ100の製造方法において使用した、ジグ1000について説明する。
上述した構造からなるジグ1000を使用すれば、チップ状セラミック素体を、1つずつ独立してチップ収納部8に収納した状態でチップ状セラミック素体加工工程(たとえば焼成工程)を実施できるため、チップ状セラミック素体ごとの加工条件のばらつきを低減することができる。したがって、ジグ1000を使用して製造されたセラミック電子部品は、品質(特性や形状など)のばらつきが抑制される。
高い生産性でセラミック電子部品を製造するために、焼成工程などのチップ状セラミック素体加工工程において、チップ状セラミック素体を収納した複数のジグを、複数段に積み重ねて使用する場合がある。しかしながら、従来のジグには、複数段に積み重ねて使用すると、収納部の通気性が悪化するという問題があった。
ジグ1000は、1つのチップ収納部8に1つのチップ状セラミック素体が収納されるものとして設計されている。本実施形態においては、チップ収納部8には、直方体状のチップ状セラミック素体を立てた状態(チップ状セラミック素体の長辺を高さ方向Zと平行にした状態)で収納することを想定している。
複数の種類のセラミック電子部品を製造する工場や、同じ種類のセラミック電子部品であっても、大きさなどが異なる複数の製品を製造する工場においては、たとえば、チップ収納部8の大きさ、形状などが異なる、複数種類のジグ1000を備え、使用することが必要になる場合がある。
ジグ1000を、高さ方向Zにおいて、複数の部分に分離可能とすることも好ましい。
ジグ1000において、チップ収納部8を、下方から上方に向かうにしたがって、側壁部8cに囲まれた面積が大きくなるようにすることも好ましい。チップ状セラミック素体の収納や取り出しが容易になるからである。
図12(A)、(B)に、変形例4にかかるジグ1000を示す。ただし、図12(A)、(B)は、それぞれ、ジグ1000の断面図である。
第2実施形態は、第1実施形態から、チップ状セラミック素体加工工程において使用するジグを変更した。すなわち、第1実施形態においては、上述したジグ1000を使用して、チップ状セラミック素体加工工程(たとえば焼成工程)を実施したが、第2実施形態では、これを変更し、図13(A)、(B)に示す、ジグ2000を使用して、チップ状セラミック素体加工工程を実施する。ただし、図13(A)は、ジグ2000の平面図である。図13(B)は、ジグ2000の断面図であり、図13(A)の一点鎖線矢印R-R部分を示している。
(P/2)<Q<(3√2/2)P・・・(1)
1G・・・第1線状部材群
2G・・・第2線状部材群
3G・・・第3線状部材群
4G・・・第4線状部材群
5G・・・第5線状部材群
6G・・・第6線状部材群
7G・・・第7線状部材群
8・・・チップ収納部
8a・・・開口
8b・・・底部
8c・・・側壁部
8d・・・底部通孔
8e・・・側壁部通孔
11・・・チップ状セラミック素体
11a・・・非導電体層
12・・・第1内部電極層
13・・・第2内部電極層
14・・・第1外部電極
15・・・第2外部電極
21・・・未焼成のチップ状セラミック素体
21a・・・セラミックグリーンシート
22、23・・・内部電極用ペースト
31・・・マザーセラミックグリーンシート積層体
31a・・・マザーセラミックグリーンシート
100・・・積層セラミックコンデンサ(セラミック電子部品)
1000・・・ジグ
Claims (17)
- 複数のチップ状セラミック素体を作製する、チップ状セラミック素体作製工程と、
前記チップ状セラミック素体を下方から支持する底部と、上方が開口された側壁部とを有する、複数のチップ収納部が形成されたジグを準備する、ジグ準備工程と、
前記ジグの1つの前記チップ収納部に、前記チップ状セラミック素体を1つずつ収納する、チップ状セラミック素体収納工程と、
前記ジグの前記チップ収納部に収納された前記チップ状セラミック素体を加工する、チップ状セラミック素体加工工程と、
前記チップ状セラミック素体を、前記ジグの前記チップ収納部から取り出す、チップ状セラミック素体取り出し工程と、を備えた、
セラミック電子部品の製造方法。 - 前記チップ状セラミック素体加工工程が、焼成工程である、
請求項1に記載されたセラミック電子部品の製造方法。 - 前記チップ状セラミック素体収納工程が、
前記ジグの上に、複数の前記チップ状セラミック素体を、位置および状態を不規則に載置し、
前記ジグに振動を与える、および/または、前記ジグを傾斜させることによって、前記ジグの上に載置された複数の前記チップ状セラミック素体を、前記チップ収納部に収納するものである、
請求項1または2に記載されたセラミック電子部品の製造方法。 - 前記チップ状セラミック素体作製工程が、
複数のセラミックグリーンシートが含まれたマザーセラミックグリーンシートを作製する、マザーセラミックグリーンシート作製工程と、
複数の前記マザーセラミックグリーンシートを積層し、一体化させ、マザーセラミックグリーンシート積層体を作製する、マザーセラミックグリーンシート積層体作製工程と、
前記マザーセラミックグリーンシート積層体を、個々の前記チップ状セラミック素体にカットする、マザーセラミックグリーンシート積層体カット工程と、を含む、
請求項1ないし3のいずれか1項に記載されたセラミック電子部品の製造方法。 - 前記チップ状セラミック素体作製工程が、
所定の前記セラミックグリーンシートの主面に、内部電極用ペーストを塗布する、内部電極用ペースト塗布工程を含む、
請求項4に記載されたセラミック電子部品の製造方法。 - 前記チップ状セラミック素体加工工程の前に、
未焼成の前記チップ状セラミック素体の外表面に、外部電極用ペーストを塗布する、外部電極用ペースト塗布工程を備えた、
請求項1ないし5のいずれか1項に記載されたセラミック電子部品の製造方法。 - 前記チップ状セラミック素体加工工程の後に、
焼成後の前記チップ状セラミック素体の外表面に、外部電極用ペーストを塗布する、外部電極用ペースト塗布工程と、
前記外部電極用ペーストを、前記チップ状セラミック素体の外表面に焼き付ける、外部電極用ペースト焼付工程と、を備えた、
請求項1ないし5のいずれか1項に記載されたセラミック電子部品の製造方法。 - 前記チップ状セラミック素体の外表面に形成された外部電極の外表面に、
少なくとも1層のめっき電極層を形成する、めっき工程を備えた、
請求項6または7に記載されたセラミック電子部品の製造方法。 - 前記ジグは、素材にセラミックを含む、
請求項1ないし8のいずれか1項に記載されたセラミック電子部品の製造方法。 - 前記ジグが、複数の線状部材によって作製された、
請求項1ないし9のいずれか1項に記載されたセラミック電子部品の製造方法。 - 前記ジグは、縦方向と、前記縦方向に直交する横方向と、前記縦方向および前記横方向に直交する高さ方向と、を有し、
複数の前記線状部材は、複数の線状部材群のいずれかに属し、
複数の前記線状部材群は、前記高さ方向に積層され、
1つの前記線状部材群に属する複数の前記線状部材は、それぞれ、互いに平行に、離間して配置され、
前記高さ方向に見たとき、ある層に積層された前記線状部材群に属する前記線状部材と、隣接する他の層に積層された他の前記線状部材群に属する前記線状部材とが、相互に交差している、
請求項10に記載されたセラミック電子部品の製造方法。 - 前記ジグは、
前記底部が、1つの前記線状部材群に属する1本以上の前記線状部材によって構成され、
前記側壁部が、1つの前記線状部材群に属する1本の前記線状部材か、または、2つ以上の前記線状部材群にそれぞれ属する2本以上の前記線状部材によって構成され、
前記底部が、前記底部の裏面に連通する底部通孔を有し、
前記側壁部が、隣接する他の前記チップ収納部に連通する側壁部通孔を有し、
前記底部通孔が、前記底部を構成する前記線状部材群において、相互に隣接する2本の前記線状部材の間の間隙によって構成され、
前記側壁部通孔が、前記側壁部を構成する前記線状部材の相互の間の間隙によって構成された、
請求項11に記載されたセラミック電子部品の製造方法。 - 少なくとも1つの前記線状部材群において、
離間して配置された、隣接する2本の前記線状部材の中心間の距離である配置ピッチが、部分的に異なっている、
請求項10ないし12のいずれか1項に記載されたセラミック電子部品の製造方法。 - 前記ジグは、前記ジグの主面に、前記チップ収納部がマトリックス状に形成されている、
請求項1ないし13のいずれか1項に記載されたセラミック電子部品の製造方法。 - 前記ジグが、前記高さ方向において、複数の部分に分離可能である、
請求項1ないし14のいずれか1項に記載されたセラミック電子部品の製造方法。 - 前記チップ収納部が、前記ジグの下方から上方に向かうにしたがって、前記側壁部に囲まれた面積が大きくなる、
請求項1ないし15のいずれか1項に記載されたセラミック電子部品の製造方法。 - 上方から見た前記チップ収納部の前記側壁部の内接円の直径の寸法をP、前記チップ収納部の深さ寸法をQとしたとき、下記式(1)を満たす、
請求項1ないし16のいずれか1項に記載されたセラミック電子部品の製造方法。
(P/2)<Q<(3√2/2)P・・・(1)
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JP2018193287A (ja) * | 2017-12-11 | 2018-12-06 | 三井金属鉱業株式会社 | セラミックス格子体 |
WO2021039047A1 (ja) * | 2019-08-23 | 2021-03-04 | 株式会社村田製作所 | チップ状電子部品用治具 |
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CN116648764A (zh) | 2023-08-25 |
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