WO2022016688A1 - 一种粉末脱脂剂、其制备方法及干燥装置 - Google Patents

一种粉末脱脂剂、其制备方法及干燥装置 Download PDF

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Publication number
WO2022016688A1
WO2022016688A1 PCT/CN2020/114729 CN2020114729W WO2022016688A1 WO 2022016688 A1 WO2022016688 A1 WO 2022016688A1 CN 2020114729 W CN2020114729 W CN 2020114729W WO 2022016688 A1 WO2022016688 A1 WO 2022016688A1
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tank
stirring
drying
pure water
pipe
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PCT/CN2020/114729
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English (en)
French (fr)
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毛金成
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苏州波菲特新材料科技有限公司
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Publication of WO2022016688A1 publication Critical patent/WO2022016688A1/zh

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions

Definitions

  • the present invention relates to a powder degreasing agent, its preparation method and drying device.
  • the main purpose of the present invention is to overcome the deficiencies of the prior art, and discloses a powder degreaser, which is made up of the following weight ratio components:
  • a preparation method of powder degreasing agent comprising the following steps:
  • Step 1 the pure water is divided into three parts and injected into the stirring device respectively;
  • step 2 the sodium hydroxide is put into the first part of pure water, the EO/PO block polymer is put into the second part of pure water, and the remaining components are put into the third part of pure water, and stirred evenly;
  • Step 3 When the temperature of the first part of pure water and the third part of pure water is at 35-50°C, pour the third part of pure water after mixing into only the first part of pure water after mixing, and stir for 20-40 minutes ;
  • Step 4 When the temperature of the first part of pure water and the second part of pure water is at 20-35°C, pour the second part of pure water after mixing into the first part of pure water after mixing, and stir for 10-20 minutes , to obtain a liquid degreasing agent;
  • Step 5 put the liquid degreasing agent into the drying device for drying
  • step 6 the dried degreaser is ground and sieved to prepare a powder degreaser.
  • the stirring device includes a main tank, two sub-tanks, a water pump, a first stirring mechanism, a second stirring mechanism and a third stirring mechanism, and the first stirring mechanism for stirring is arranged in the main tank.
  • the sub-tank is provided with a second stirring mechanism for stirring, the sub-tank is attached to the main tank, and the water pump and the third stirring mechanism are arranged on the main tank through pipelines and form a circulation loop with the main tank;
  • the sub-tank is connected between the water pump and the third stirring mechanism through a pipeline,
  • the sub-tank includes a main body and a sealing cover, the main body The upper end is provided with an air inlet and a feeding port, the air inlet is connected with an air source, and the sealing cover is sealed on the feeding port.
  • the third stirring mechanism includes a casing, an installation block and a mixing pipe, an installation cavity for installing the installation block is arranged in the casing, and a plurality of penetrating installation pipes are arranged on the installation block.
  • the material pipe is arranged in the installation pipe, and the two ends of the casing are respectively provided with a liquid inlet and a liquid outlet;
  • the mixing pipe includes a pipe and a number of superimposed stirring units, and the stirring units are in a spiral shape.
  • the lower end of the stirring unit and the upper end of the other stirring unit are perpendicular to each other.
  • a drying device for powder degreasing agent comprising a drying tank, a base, a driving mechanism, a blowing mechanism, a heating device, a circulation device, a cylinder and a tank cover, the drying tank is rotatably arranged on the base, and the driving mechanism is arranged on the On the base, the drying tank is driven to rotate vertically by the driving mechanism, an opening and a sealing cover for closing the opening are arranged under the side wall of the drying tank, and the cylinder is arranged on the circumference of the drying tank.
  • the tank cover is arranged on the cylinder, and the cylinder is used to drive the tank cover to open and close the drying tank, the heating device is arranged in the side wall of the drying pipe, and the circulation device The liquid in the drying tank is sprayed on the inner wall of the drying tank, and the blowing device is arranged on the tank cover to blow air into the drying tank and discharge the water vapor in the drying tank.
  • the circulation device includes a liquid suction pipe, a liquid spray pipe, a suction pump, a filter head, and an electromagnet
  • the suction pump is arranged on the tank cover
  • the liquid suction pipe extends to the bottom of the drying tank.
  • the filter head is slidably arranged on the end of the suction pipe
  • the electromagnet is arranged on the suction pipe
  • the filter head is attracted by the electromagnet
  • the upper end of the inner wall of the drying tank is provided with an inwardly inclined step
  • the liquid spray pipe extends above the step, and an opening and a sealing cover for closing the opening are provided below the side wall of the drying tank.
  • the blowing device includes several blowing heads, an air supply pipe, a heating box, a dehumidification box, a filter cover and a blower, the blowing heads are arranged at the bottom of the tank cover, and are connected to the heating device through the air supply pipe.
  • the dehumidification box is arranged on the tank cover, an air extraction port is arranged in communication with the drying tank, the filter cover is arranged on the air extraction port, and the dehumidification box is connected to the heating box through the blower. connect.
  • blowing head forms an included angle of 50° with the inner tangent of the drying tank, and forms an included angle of 45° with the horizontal plane.
  • the driving mechanism includes a motor and a cam
  • one side of the bottom of the drying tank is rotatably connected to the base through a rotating shaft
  • the cam is rotatably arranged on the other side
  • the cam is driven by the motor to rotate.
  • the side wall of the drying tank is provided with a hollow thermal insulation layer.
  • Sodium hydroxide is used, which has strong saponification effect and strong cleaning ability; 4A zeolite is added to avoid the adhesion of oil stains and further improves cleaning ability; especially EO/PO block polymer is added, which has good deoiling effect and anti-foaming effect. Antifoaming effect. Compatibilization of EO/PO block polymers with alcohol ether glycosides.
  • the main tank body and the sub-tank body are integrated, and the sodium hydroxide reacts with water to improve the utilization of heat energy and save energy; the stirring device continuously stirs the solution in the main tank through the first stirring device and the third stirring device, and uses the second stirring device. The device is to stir the solution in the sub-tank, and the mutual stirring between the solutions is easier to mix.
  • the third stirring mechanism is composed of forehead stirring units with a spiral structure, which cuts and mixes the solution to realize the stirring of the solution; the whole solution is in an active state, which further promotes the dissolution of the solution; the first stirring mechanism promotes the solution in the main tank clockwise. While rotating, the solution entering the main tank through the third stirring mechanism rotates counterclockwise, and the two solutions collide with each other, which further promotes the dissolution of the solution.
  • the drying device uses a circulation device to promote the flow of liquid and fully contacts the side wall of the drying tank. At the same time, it uses a blower to exchange internal gas. While sucking away water vapor, drying hot air is blown into the drying tank, which further improves the drying efficiency. Clever use of electromagnets to open and close the suction pipe to prevent the dried degreaser from entering the suction pipe.
  • Fig. 1 is the three-dimensional structure schematic diagram of a kind of stirring device of the present invention
  • Fig. 2 is the structural representation of sub-tank
  • FIG. 3 is a schematic diagram of the internal structure of the sub-tank
  • Fig. 4 is the structural representation of the first stirring mechanism
  • Fig. 5 is the structural representation of the second stirring mechanism
  • Fig. 6 is the structural representation of the third stirring mechanism
  • Fig. 7 is the internal structure schematic diagram of Fig. 6;
  • Fig. 8 is the structural representation of shell
  • Fig. 10 is the structural representation of the installation block
  • Fig. 11 is the structural representation of the mixing pipe
  • Fig. 12 is the structural representation of the liquid inlet pipe
  • FIG. 13 is a schematic structural diagram of a drying device for a powder degreaser according to the present invention.
  • Figure 14 is a schematic diagram of the distribution of the liquid spray pipe
  • Fig. 15 is the structural representation of filter head
  • a preparation method of a powder degreasing agent which is composed of the following components in weight ratio:
  • Step 1 the pure water is divided into three parts and injected into the stirring device respectively;
  • step 2 the sodium hydroxide is put into the first part of pure water, the EO/PO block polymer is put into the second part of pure water, and the remaining components are put into the third part of pure water, and stirred evenly;
  • Step 3 When the temperature of the first part of pure water and the third part of pure water is at 35-50°C, pour the third part of pure water after mixing into only the first part of pure water after mixing, and stir for 20-40 minutes ;
  • Step 4 When the temperature of the first part of pure water and the second part of pure water is at 20-35°C, pour the second part of pure water after mixing into the first part of pure water after mixing, and stir for 10-20 minutes , to obtain a liquid degreasing agent;
  • Step 5 put the liquid degreasing agent into the drying device for drying
  • step 6 the dried degreaser is ground and sieved to prepare a powder degreaser.
  • a preparation method of a powder degreasing agent which is composed of the following components in weight ratio:
  • Step 1 the pure water is divided into three parts and injected into the stirring device respectively;
  • step 2 the sodium hydroxide is put into the first part of pure water, the EO/PO block polymer is put into the second part of pure water, and the remaining components are put into the third part of pure water, and stirred evenly;
  • Step 3 When the temperature of the first part of pure water and the third part of pure water is at 35-50°C, pour the third part of pure water after mixing into only the first part of pure water after mixing, and stir for 20-40 minutes ;
  • Step 4 When the temperature of the first part of pure water and the second part of pure water is at 20-35°C, pour the second part of pure water after mixing into the first part of pure water after mixing, and stir for 10-20 minutes , to obtain a liquid degreasing agent;
  • Step 5 put the liquid degreasing agent into the drying device for drying
  • step 6 the dried degreaser is ground and sieved to prepare a powder degreaser.
  • Embodiment 3 is a diagrammatic representation of Embodiment 3
  • a preparation method of a powder degreasing agent which is composed of the following components in weight ratio:
  • Step 1 the pure water is divided into three parts and injected into the stirring device respectively;
  • step 2 the sodium hydroxide is put into the first part of pure water, the EO/PO block polymer is put into the second part of pure water, and the remaining components are put into the third part of pure water, and stirred evenly;
  • Step 3 When the temperature of the first part of pure water and the third part of pure water is at 35-50°C, pour the third part of pure water after mixing into only the first part of pure water after mixing, and stir for 20-40 minutes ;
  • Step 4 When the temperature of the first part of pure water and the second part of pure water is at 20-35°C, pour the second part of pure water after mixing into the first part of pure water after mixing, and stir for 10-20 minutes , to obtain a liquid degreasing agent;
  • Step 5 put the liquid degreasing agent into the drying device for drying
  • step 6 the dried degreaser is ground and sieved to prepare a powder degreaser.
  • the invention discloses a stirring device for powder degreasing agent, comprising a main tank 1, two sub-tanks 2, a water pump 3, a first stirring mechanism 4, a second stirring mechanism and a third stirring mechanism 6.
  • a first stirring mechanism 4 for stirring is provided, and a second stirring mechanism for stirring is provided in the sub-tank 2.
  • the sub-tank 2 is attached to the side wall of the main tank 1, and is discharged by sodium hydroxide and water.
  • the thermal reaction uses heat transfer between the main tank 1 and the sub-tank 2 to heat the solution in the sub-tank 2 .
  • the main tank body 1 is provided with a liquid outlet and a liquid inlet, and the liquid outlet is once connected to the water pump 3 and the third stirring mechanism 6 through a pipeline, and returns to the liquid inlet.
  • the liquid in the main tank body 1 is pumped out by the water pump 3 and stirred by the third stirring mechanism 6 and then returned to the main tank body 1 .
  • a liquid outlet is set on the sub-tank 2, and the liquid outlet is connected between the water pump 3 and the third stirring mechanism 6 through a pipeline; and a valve is set at the liquid outlet to control the opening or closing of the liquid outlet.
  • the sub-tank 2 includes a main body 21 and a sealing cover 22.
  • the top of the main body 21 is provided with an air inlet 211 and a feeding port 212.
  • the sealing cover 22 is sealed at the feeding port 212.
  • the air inlet 211 is connected to the air source.
  • the liquid outlet valve is opened, and the gas source sends the gas into the sub-tank 2 through the air inlet 211, and then the solution in the sub-tank 2 is discharged and mixed.
  • the solution in the circuit of the main tank 1 enters the third stirring mechanism 6 for mixing at the same time. It can adjust the discharge speed of the solution in the sub-tank 2 by controlling the air pressure in the sub-tank 2 .
  • a one-way valve (not shown) is also provided at the liquid outlet of the sub-tank 2 ; to prevent the solution in the main tank 1 from being backfilled into the sub-tank 2 .
  • the first stirring mechanism 4 includes a motor 41 , a rotating shaft 42 and a blade 43 , the rotating shaft 42 is rotatably arranged in the main tank 1 , and the blade 43 is arranged around the rotating shaft 42 in the circumferential direction.
  • the motor 41 is arranged on the top of the main tank 1, and the motor 1 is used to drive the rotating shaft 42 to drive the blades 43 to rotate. Furthermore, the solution in the main tank 1 is mixed.
  • the second stirring mechanism includes an air compressor and an air intake pipe 5
  • the air intake pipe 5 is arranged at the bottom of the sub-tank 2, and is connected with the air compressor, and the air intake pipe has several air holes, The air is fed into the intake pipe by the air compressor, and the air is discharged from the air hole. Air bubbles are generated in the solution, and the solution is stirred by the air bubbles.
  • the sub-tank 2 is a closed container, the gas introduced by the second stirring mechanism is always stored in the sub-tank 2, and the pressure in the sub-tank 2 increases continuously. The pressure in the tank body 2 discharges the solution; when the pressure in the sub-tank body 2 is insufficient, the pressure is supplemented through the air inlet 211 to ensure the normal discharge of the subsequent solution.
  • the third stirring mechanism 6 includes a casing 61 , a mounting block 62 and a mixing pipe 63 , and a mounting cavity 611 for mounting the mounting block 62 is arranged in the casing 61 .
  • the mounting block 62 A plurality of installation pipes 621 penetrating therethrough are arranged on the top, the mixing pipes 63 are arranged in the installation pipes 621, and the two ends of the casing 61 are respectively provided with a liquid inlet and a liquid outlet.
  • the solution is pumped into the mixing pipe 63 from the liquid inlet through the water pump 3, and the solution is mixed through the mixing pipe and then discharged from the liquid outlet, and is guided back into the main tank 1 through the pipeline.
  • the mixing pipe 63 includes a pipe body 631 and several superimposed stirring units 632 .
  • the stirring units 632 are helical, and the lower end of one stirring unit 632 and the upper end of the other stirring unit 632 are perpendicular to each other. It can be seen that a stirring unit 632 cuts and rotates the solution and then passes through the next shift unit 632 to cut again, thereby realizing mixing of the solution.
  • the housing 61 includes an outer casing 612, a sealing strip 613 and an outer cover 614.
  • the installation cavity 611 is recessed in the outer casing 612.
  • the upper surface of the outer casing 612 has a concave sealing groove 615 around the periphery of the installation cavity 611, and at the corresponding position of the outer cover 614.
  • the sealing flange 616 matched with the sealing groove 615, the sealing strip 613 is arranged in the sealing groove,
  • a positioning block 633 is provided on the side wall of the mixing pipe 63 , and a positioning groove matched with the positioning block 633 is provided on the inner wall of the installation pipe 621 . During installation, the positioning block 633 is placed in the positioning groove to prevent the mixing pipe 63 from rotating.
  • the liquid outlet end of the third stirring mechanism 6 is connected to a three-way valve 64, and one end of the three-way valve 64 is connected to the three-way valve 64.
  • the main tank body 1 is connected, and the other end is a liquid discharge port 65 .
  • the three-way valve 64 is connected to the third stirring mechanism 6 and the main tank 1; when discharging, the three-way valve 64 is connected to the third stirring mechanism 6 and the liquid discharge port 65, and the main tank 1 is pumped through the water pump 3.
  • the liquid extracted is discharged from the liquid discharge port 65 through the third stirring mechanism 6 .
  • a liquid inlet pipe 7 is also included, and the liquid inlet pipe 7 includes a main pipe 71 and a sub-pipe 72 axially arranged in the 71 ; the main pipe 71 is provided with a liquid inlet, and the sub-pipe 72 is provided with Liquid outlet.
  • the liquid inlet of the liquid inlet pipe 7 is connected to the three-way valve 64 , the liquid outlet is connected to the main tank 1 , and the liquid inlet direction is tangential to the main tank 1 .
  • the liquid in the main tank 1 is stirred clockwise by the first stirring mechanism 4, so that the solution flows clockwise, and the solution discharged from the liquid outlet flows counterclockwise along the inner wall of the main tank 1, and the two solutions collide with each other, Improve solution mixing efficiency.
  • the present invention also discloses a drying device for powder degreasing agent, as shown in Figures 13-15, comprising a drying tank 91, a base 92, a driving mechanism 93, a blowing mechanism 94, a heating device 95, a circulation device 96, a cylinder 97 and a tank
  • a drying device for powder degreasing agent comprising a drying tank 91, a base 92, a driving mechanism 93, a blowing mechanism 94, a heating device 95, a circulation device 96, a cylinder 97 and a tank
  • the cover 98, the drying tank 91 is rotatably arranged on the base 92, the driving mechanism 93 is arranged on the base 92, the drying tank 91 is driven to rotate vertically by the driving mechanism 93, and a sealing cover for opening and closing the opening is provided under the side wall of the drying tank 91 911, four cylinders 97 are provided, which are arranged on the side wall of the drying tank 91 at equal
  • the circulation device 96 makes the liquid in the drying tank 91 flow so as to sufficiently contact the inner wall of the drying tank 91 .
  • the blowing device 95 blows air into the drying tank 91 to promote the flow of gas in the drying tank 91 and discharge the water vapor in the drying tank 91 .
  • the circulation device 96 includes a liquid suction pipe 961, a liquid spray pipe 962, a suction pump 963, a filter head 964, and an electromagnet 965.
  • the suction pump 963 is arranged on the tank cover 98, One end of the suction pipe 961 is connected to the suction pump 963, and the other end extends to the bottom of the drying tank 91.
  • the filter head 964 is slidably arranged at the end of the suction pipe and slides along the axial direction of the suction pipe 961.
  • the electromagnet 965 is arranged at the end of the suction pipe 961.
  • the filter head 964 includes an end cover 966 and an upwardly protruding annular filter screen 967. When opened, the liquid enters the suction pipe 961 from the filter screen 967; when closed, the filter head 964 moves up, and the end cover 966 blocks the suction pipe 961. Liquid line 961.
  • the water flow will adsorb the filter head 964, and then close the suction pipe 961, and an electromagnet 965 is also arranged at the bottom of the drying tank 91.
  • an electromagnet 965 is also arranged at the bottom of the drying tank 91.
  • the electromagnet 965 at the bottom works , the filter head 964 is adsorbed.
  • the upper end of the inner wall of the drying tank 91 is provided with an inwardly inclined step, one end of the liquid spray pipe 962 is connected to the suction pump 963, and the other end extends above the step.
  • the blowing device 94 includes several blowing heads 941, an air supply pipe 942, a heating box 943, a dehumidifying box 944, a filter cover 945 and a blower 946, and the blowing heads 941 are arranged on the tank cover.
  • the bottom of 98 is connected with the heating box 963 through the air supply pipe 942, the dehumidification box 944 is arranged on the tank cover 98, and the air outlet communicated with the drying tank 91 is arranged, and the filter cover 945 is arranged on the air outlet to ensure that only water vapor is drawn out;
  • the dehumidification box 944 is connected to the heating box 943 through a blower 946 .
  • the circulation of the internal gas is realized by the blowing device 94, and the heated and evaporated water vapor is discharged. Hot air is blown into the drying box 91 through the heating box 943 .
  • the blowing head 941 forms an included angle with the inner tangent of the drying tank 91 of 50°, and forms an included angle with the horizontal plane of 45°. Makes the incoming wind a whirlwind.
  • the driving mechanism 93 includes a motor 931 and a cam 932 .
  • One side of the bottom of the drying tank 91 is rotatably connected to the base 92 through a rotating shaft, and the cam 932 is rotated on the other side, and the motor 931 is used.
  • the drive cam 932 rotates.
  • the drying tank 91 is inclined by 15°, so that the dried material inside the drying tank 91 is taken out from the opening.
  • the drying tank 91 is placed horizontally.
  • several spacers are arranged on the base to support the drying tank 91 and reduce the load of the cam 932 .
  • a hollow insulating layer 99 is provided on the side wall of the drying tank 91 . to reduce heat loss.
  • the circulation device stops, and the electromagnet on the suction pipe works to close the suction pipe to prevent the dried degreaser from entering the suction pipe.
  • the sealing cover 911 is opened, and the driving mechanism 93 is activated, so that the drying tank 91 is inclined, and the dried degreaser is discharged from the opening.

Abstract

一种粉末脱脂剂、其制备方法及干燥装置,采用氢氧化钠,皂化作用强,具有较强的清洗能力;加入4A沸石避免油污附着,进一步提高清洁能力;特别加入EO/PO嵌段聚合物,具有很好的脱油作用,并且具有抑泡消泡作用。利用醇醚糖苷对EO/PO嵌段聚合物增容。主罐体(1)和子罐体(2)一体设置,利用氢氧化钠遇水热反应,提高热能的利用,节约能源;搅拌装置通过第一搅拌机构(4)和第三搅拌机构(6)对主罐体(1)内溶液不断搅拌,利用第二搅拌机构是子罐体(2)内溶液搅拌,溶液间的相互搅拌更加容易混合。第三搅拌机构(6)采用螺旋结构的搅拌单元叠加组成,对溶液切开混合,实现对溶液的搅拌;整个溶液均处于活动状态,进一步促进溶液的溶解。

Description

一种粉末脱脂剂、其制备方法及干燥装置 技术领域
本发明涉及一种粉末脱脂剂、其制备方法及干燥装置。
背景技术
在工业生产中,需要用到多种油脂组成的乳化液对产品进行润滑和冷却,因此,这种油脂润滑剂在产品完成后在其表面回头残留,在对产品退火前,必须通过化学脱脂和电解脱脂的方法将这层油污去除;以防止这层油污退火时在钢板表面碳化而出现渗碳现象和形成碳质污斑,影响产品在后工艺进行涂镀或其它加工处理时的性能和质量。现在市场上销售的大量脱脂剂碱度低、泡沫大,不但造成清洗不彻底的问题,钢厂使用时脱脂剂的消耗量也大,而且需要额外投加消泡剂,这就大幅增加了现场工人的劳动强度,清洗成本也随之上升。
发明内容
针对以上现有技术存在的缺陷,本发明的主要目的在于克服现有技术的不足之处,公开了一种粉末脱脂剂,该脱脂剂由下列重量比例成分组成:
Figure PCTCN2020114729-appb-000001
Figure PCTCN2020114729-appb-000002
一种粉末脱脂剂的制备方法,包括以下步骤:
步骤一,将纯水分成三份,分别注入搅拌装置内;
步骤二,将氢氧化钠投第一份纯水中,EO/PO嵌段聚合物投入其中第二份纯水中,剩余组分投入第三份纯水中,并且搅拌均匀;
步骤三,当第一份纯水和第三份纯水中温度在35-50℃时,将第三份混合后的纯水注入只第一份混合后的纯水中,搅拌20-40分钟;
步骤四,当第一份纯水和第二份纯水中的温度在20-35℃时,将混合后的第二份纯水注入第一份混合后的纯水中,搅拌10-20分钟,制得液态脱脂剂;
步骤五,将液态脱脂剂投入干燥装置内进行干燥;
步骤六,将干燥后的脱脂剂研磨过筛,制成粉末脱脂剂。
进一步地,所述搅拌装置包括主罐体、两个子罐体、水泵、第一搅拌机构、第二搅拌机构和第三搅拌机构,所述主罐体内设置用于搅拌的所述第一搅拌机构,所述子罐体内设置用于搅拌的第二搅拌机构,所述子罐体贴合在所述主罐体上,所述水泵和所述第三搅拌机构通过管路设置在所述主罐体上,并且与所述主罐体形成循环回路;所述子罐体通过管路连接在所述水泵和所述第三搅拌机构之间,所述子罐体包括本体和密封盖,所述本体上端设置进气孔和进料口,所述进气孔与气源连接,所述密封盖密封设置在所述进料口上。
进一步地,所述第三搅拌机构包括壳体、安装块和混料管,所述壳体内设置安装所述安装块的安装腔,所述安装块上设置若干个贯穿的安装管,所述混料管设置在所述安装管内,所述壳体的两端分别设置进液口与出液口;所述混料管包括管和若干个叠加的搅拌单元,所述搅拌单元呈螺旋状, 一所述搅拌单元的下端与另一所述搅拌单元的上端相互垂直。
一种粉末脱脂剂的干燥装置,包括干燥罐、底座、驱动机构、吹风机构、加热装置、循环装置、气缸和罐盖,所述干燥罐转动设置在所述底座上,所述驱动机构设置在所述底座上,利用所述驱动机构驱动所述干燥罐竖直转动,所述干燥罐的侧壁的下方设置开口和闭合所述开口的密封盖,所述气缸设置在所述干燥罐的周向,所述罐盖设置在所述气缸上,利用所述气缸驱动罐盖打开和关闭所述干燥罐,所述加热装置设置在所述干燥管的侧壁内,所述循环装置将所述干燥罐内的液体喷射在所述干燥罐的内壁上,所述吹风装置设置在所述罐盖上,对所述干燥罐内吹风并将所述干燥罐内的水汽排出。
进一步地,所述循环装置包括抽液管、喷液管、抽水泵、过滤头、电磁铁,所述抽水泵设置在所述罐盖上,抽液管延伸至所述干燥罐底部,所述过滤头滑动设置在所述抽液管端部,所述电磁铁设置在所述抽液管上,利用所述电磁铁吸引所述过滤头,所述干燥罐内壁上端设置向内倾斜的台阶,所述喷液管延伸至台阶上方,所述干燥罐的侧壁的下方设置开口和闭合所述开口的密封盖。
进一步地,所述吹风装置包括若干吹风头、送风管、加热箱、除湿箱、过滤罩和吹风机,所述吹风头设置在所述罐盖的底部,通过所述送风管与所述加热箱连接,所述除湿箱设置在所述罐盖上,设置与所述干燥罐连通的抽风口,所述过滤罩设置在所述抽风口上,所述除湿箱通过所述吹风机与所述加热箱连接。
进一步地,所述吹风头与所述干燥罐内切线呈50°夹角,并且与所述水平面呈45°夹角。
进一步地,所述驱动机构包括电机和凸轮,所述干燥罐底部一侧通过转轴与所述底座转动连接,在另一侧转动设置所述凸轮,利用所述电机驱动所述凸轮转动。
进一步地,所述干燥罐侧壁设置中空隔热层。
本发明取得的有益效果:
采用氢氧化钠,皂化作用强,具有较强的清洗能力;加入4A沸石避免油污附着,进一步提高清洁能力;特别加入EO/PO嵌段聚合物,具有很好的脱油作用,并且具有抑泡消泡作用。利用醇醚糖苷对EO/PO嵌段聚合物增容。主罐体和子罐体一体设置,利用氢氧化钠遇水热反应,提高热能的利用,节约能源;搅拌装置通过第一搅拌装置和第三搅拌装置对主罐体内溶液不断搅拌,利用第二搅拌装置是子罐体内溶液搅拌,溶液间的相互搅拌更加容易混合。第三搅拌机构采用螺旋结构的额搅拌单元叠加组成,对溶液切开混合,实现对溶液的搅拌;整个溶液均处于活动状态,进一步促进溶液的溶解;第一搅拌机构促进主罐体内溶液顺时针转动,同时通过第三搅拌机构进入主罐体的溶液逆时针转动,两股溶液相互撞击,进一步促进溶液溶解。干燥装置利用循环装置促进液体流动,与干燥罐侧壁充分接触,同时利用吹风机进行内部气体交换,吸走水汽的同时干燥罐内吹入干燥的热风,进一步提高了干燥效率。巧妙的利用电磁铁实现抽液管的打开和关闭,防止干燥后的脱脂剂进入抽液管中。
附图说明
图1为本发明为本发明一种搅拌装置的立体结构示意图;
图2为子罐体的结构示意图;
图3为子罐体的内部结构示意图;
图4为第一搅拌机构的结构示意图;
图5为第二搅拌机构的结构示意图;
图6为第三搅拌机构的结构示意图;
图7为图6的内部结构示意图;
图8为外壳的结构示意图;
图9为外盖的结构示意图;
图10为安装块的结构示意图;
图11为混料管的结构示意图;
图12为进液管的结构示意图;
图13为本发明一种粉末脱脂剂的干燥装置的结构示意图;
图14为喷液管的分布示意图;
图15为过滤头的结构示意图;
附图标记如下:
1、主罐体,2、子罐体,3、水泵,4、第一搅拌机构,5、进气管,6、第三搅拌机构,7、进液管,21、本体,22、密封盖,41、电机,42、旋转轴,43、叶片,61、壳体,62、安装块,63、混料管,64、三通阀门,71、主管,72、子管,611、安装腔,612、外壳,613、密封条,614、外盖,615、密封槽,616、密封凸缘,621、安装管,631、管体,632、搅拌单元,633、定位块,211、进气口,212、进料口,91、干燥罐,92、底座,93、驱动机构,94、吹风机构,95、加热装置,96、循环装置,97、气缸,98、罐盖,99、中空隔热层,911、密封盖,931、电机,932、凸轮,941、吹风头,942、送风管,943、加热箱,944、除湿箱,945、过滤罩,946、吹风机,961、抽液管,962、喷液管,963、抽水泵,964、过滤头,965、电磁铁,966、端盖,967、过滤网。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,下面结合附图及实施例对本发明作进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。
实施例1:
一种粉末脱脂剂的制备方法,由下列重量比例成分组成:
Figure PCTCN2020114729-appb-000003
Figure PCTCN2020114729-appb-000004
包括以下步骤:
步骤一,将纯水分成三份,分别注入搅拌装置内;
步骤二,将氢氧化钠投第一份纯水中,EO/PO嵌段聚合物投入其中第二份纯水中,剩余组分投入第三份纯水中,并且搅拌均匀;
步骤三,当第一份纯水和第三份纯水中温度在35-50℃时,将第三份混合后的纯水注入只第一份混合后的纯水中,搅拌20-40分钟;
步骤四,当第一份纯水和第二份纯水中的温度在20-35℃时,将混合后的第二份纯水注入第一份混合后的纯水中,搅拌10-20分钟,制得液态脱脂剂;
步骤五,将液态脱脂剂投入干燥装置内进行干燥;
步骤六,将干燥后的脱脂剂研磨过筛,制成粉末脱脂剂。
实施例2:
一种粉末脱脂剂的制备方法,由下列重量比例成分组成:
Figure PCTCN2020114729-appb-000005
Figure PCTCN2020114729-appb-000006
包括以下步骤:
步骤一,将纯水分成三份,分别注入搅拌装置内;
步骤二,将氢氧化钠投第一份纯水中,EO/PO嵌段聚合物投入其中第二份纯水中,剩余组分投入第三份纯水中,并且搅拌均匀;
步骤三,当第一份纯水和第三份纯水中温度在35-50℃时,将第三份混合后的纯水注入只第一份混合后的纯水中,搅拌20-40分钟;
步骤四,当第一份纯水和第二份纯水中的温度在20-35℃时,将混合后的第二份纯水注入第一份混合后的纯水中,搅拌10-20分钟,制得液态脱脂剂;
步骤五,将液态脱脂剂投入干燥装置内进行干燥;
步骤六,将干燥后的脱脂剂研磨过筛,制成粉末脱脂剂。
实施例3:
一种粉末脱脂剂的制备方法,由下列重量比例成分组成:
Figure PCTCN2020114729-appb-000007
Figure PCTCN2020114729-appb-000008
包括以下步骤:
步骤一,将纯水分成三份,分别注入搅拌装置内;
步骤二,将氢氧化钠投第一份纯水中,EO/PO嵌段聚合物投入其中第二份纯水中,剩余组分投入第三份纯水中,并且搅拌均匀;
步骤三,当第一份纯水和第三份纯水中温度在35-50℃时,将第三份混合后的纯水注入只第一份混合后的纯水中,搅拌20-40分钟;
步骤四,当第一份纯水和第二份纯水中的温度在20-35℃时,将混合后的第二份纯水注入第一份混合后的纯水中,搅拌10-20分钟,制得液态脱脂剂;
步骤五,将液态脱脂剂投入干燥装置内进行干燥;
步骤六,将干燥后的脱脂剂研磨过筛,制成粉末脱脂剂。
本发明公开了一种粉末脱脂剂的搅拌装置,包括主罐体1、两个子罐体2、水泵3、第一搅拌机构4、第二搅拌机构和第三搅拌机构6,主罐体1内设置用于搅拌的第一搅拌机构4,子罐体2内设置用于搅拌的第二搅拌机构,子罐体2贴合在主罐体1的侧壁上,利用氢氧化钠与水发生放热反应,利用主罐体1与子罐体2之间的热传递,对子罐体2内的溶液进行加热。主罐体1上设置出液口和进液口,其出液口通过管路一次连接水泵3和第三搅拌机构6,并且回流至进液口。通过水泵3将主罐体1内的液体抽出经过第三搅拌机构6搅拌后回入主罐体1内。子罐体2上设置出液口,该出液口通过管路连接在水泵3和第三搅拌机构6之间;并且在该出液口处设置阀门,以控制出液口的打开或者关闭。其中,子罐体2包括本体21和密封盖22,本体21顶部设置进气口211和进料口212,密封盖22密封设置在进料口212处;进气口211与气源连接。子罐体2内的液体通过第二搅拌机构搅拌完成后,打开出液口阀门,气源通过进气口211将气体送入子罐体2内,进而将子罐体2内的溶液排出与主罐体1回路内的溶液同时进入第三搅拌机构6混合。其能够通过控制子罐体2内的气压以调节子罐体2 内溶液排出速度。优选的,子罐体2的出液口还设置单向阀(未示出);以防止主罐体1回路内的溶液反灌入子罐体2内。
在一实施例中,如图4所示,第一搅拌机构4包括电机41、旋转轴42和叶片43,旋转轴42转动设置在主罐体1内,叶片43环绕设置在旋转轴42周向,电机41设置在主罐体1的顶部,利用电机1驱动旋转轴42以带动叶片43转动。进而对主罐体1内的溶液进行混料。
在一实施例中,如图5所示,第二搅拌机构包括空气压缩机和进气管5,进气管5设置在子罐体2底部,并且与空气压缩机连接,进气管具有若干个气孔,利用空气压缩机将气体送入进气管,从气孔将气体排出。在溶液中产生气泡,利用气泡对溶液进行搅拌。另外,由于子罐体2为密闭容器,由第二搅拌机构通入的气体始终储存于子罐体2内,子罐体2内的压力不断增加,当出液口的阀门打开后,利用子罐体2内的压力将溶液排出;当子罐体2内压力不足时,通过进气孔211进行压力补充,以保证后续溶液正常排出。
在一实施例中,如图6-11所示,第三搅拌机构6包括壳体61、安装块62和混料管63,壳体61内设置安装安装块62的安装腔611,安装块62上设置若干个贯穿的安装管621,混料管63设置在安装管621内,壳体61的两端分别设置进液口与出液口。通过水泵3将溶液从进液口打入混料管63内,通过混料管对溶液混料后从出液口排出,经管路引导回入主罐体1内。其中,混料管63包括管体631和若干个叠加的搅拌单元632,搅拌单元632呈螺旋状,一搅拌单元632的下端与另一搅拌单元632的上端相互垂直。可见,一搅拌单元632将溶液分切旋转后通过下一个交班单元632再分切,进而实现对溶液的混料。壳体61包括外壳612、密封条613和外盖614,安装腔611凹设在所述外壳612内,外壳612上表面绕安装腔611周边凹设密封槽615,在并且在外盖614得对应位置与密封槽615配合的密封凸缘616,密封条613设置在密封槽内,
在上述实施例中,如图6-11所示,混料管63侧壁上设置定位块633,安装管621内壁设置与定位块633配合的定位槽。安装时,定位块633至 于定位槽内,防止混料管63转动。
在一实施例中,如图6-11所示,为了方便将主罐体1内搅拌完毕的液体排出,第三搅拌机构6的出液端连接三通阀门64,三通阀门64的一端与主罐体1连接,另一端为排液口65。当搅拌时,三通阀门64连接第三搅拌机构6和主罐体1;当排料时,三通阀门64连接第三搅拌机构6和排液口65,通过水泵3将主罐体1内的液体抽出通过第三搅拌机构6从排液口65排出。
在一实施例中,如图12所示,还包括进液管7,进液管7包括主管71和轴向排列在71的子管72;主管71上设置进液口,子管72上设置出液口。进液管7的进液口与三通阀门64连接,出液口与主罐体1连接,并且进液方向与主罐体1相切。主罐体1内的液体通过第一搅拌机构4进行顺时针搅拌,使得溶液顺时针流动,而从出液口排出的溶液顺着主罐体1的内壁逆时针流动,两股溶液相互撞击,提高溶液混料效率。
本发明还公开了一种粉末脱脂剂的干燥装置,如图13-15所示,包括干燥罐91、底座92、驱动机构93、吹风机构94、加热装置95、循环装置96、气缸97和罐盖98,干燥罐91转动设置在底座92上,驱动机构93设置在底座92上,利用驱动机构93驱动干燥罐91竖直转动,干燥罐91的侧壁的下方设置开口和闭合开口的密封盖911,气缸97设置四个,分别等间距的设置在干燥罐91的侧壁上,罐盖98设置在气缸97上,利用气缸97驱动罐盖98打开和关闭干燥罐91,干干燥罐91侧壁内设置隔层,加热装置95设置在隔层内,对干燥罐91进行加热;通常,加热装置95为电热丝。循环装置96使干燥罐91内的液体流动,与干燥罐91内壁充分接触。吹风装置95对干燥罐91内吹风,以促进干燥罐91内气体流动,并且将干燥罐91内的水汽排出。
在一实施例中,如图13-15所示,循环装置96包括抽液管961、喷液管962、抽水泵963、过滤头964、电磁铁965,抽水泵963设置在罐盖98上,抽液管961的一端连接抽水泵963,另一端延伸至干燥罐91的底部,过滤头964滑动设置在抽液管的端部,并且沿抽液管961的轴向滑动,电 磁铁965设置在抽液管961上;当电磁铁965断电时,过滤头964利用其自身重量下滑,使得抽液管961打开;当循环装置96停止使用时,电磁铁965通电,利用磁性吸引过滤头964上移,将抽液管961关闭。具体的,过滤头964包括端盖966和向上凸起的环形过滤网967,打开时,液体从过滤网967进入抽液管961内;关闭时,过滤头964上移,端盖966堵住抽液管961。优选的,为了防止抽水泵963工作时,水流将过滤头964吸附,进而关闭抽液管961,在干燥罐91的底部也设置电磁铁965,当循环装置96工作室,底部的电磁铁965工作,将过滤头964吸附。干燥罐91内壁上端设置向内倾斜的台阶,喷液管962的一端连接抽水泵963,另一端延伸至台阶上方。
在一实施例中,如图13-15所示,吹风装置94包括若干吹风头941、送风管942、加热箱943、除湿箱944、过滤罩945和吹风机946,吹风头941设置在罐盖98的底部,通过送风管942与加热箱963连接,除湿箱944设置在罐盖98上,设置与干燥罐91连通的抽风口,过滤罩945设置在抽风口上,以保证仅水汽被抽出;除湿箱944通过吹风机946与加热箱943连接。通过吹风装置94实现内部气体的循环,并且将加热蒸发的水汽排出。通过加热箱943使得干燥箱91内吹入热风。优选的,吹风头941与干燥罐91内切线呈50°夹角,并且与水平面呈45°夹角。使得吹入的风呈旋风状。
在一实施例中,如图13-15所示,驱动机构93包括电机931和凸轮932,干燥罐91底部一侧通过转轴与底座92转动连接,在另一侧转动设置凸轮932,利用电机931驱动凸轮932转动。当凸轮932旋转至长直径竖直设置时,干燥罐91倾斜15°,使得干燥罐91内部的干燥物从开口去取出。当凸轮932端直径竖直设置时,干燥罐91水平放置。优选的,使干燥罐91工作时更加稳定,底座上设置若干个垫块,以支撑干燥罐91,并且减少凸轮932的负载。
在一实施例中,如图13-15所示,干燥罐91侧壁设置中空隔热层99。以减少热量散失。
本发明的干燥装置在使用时,如图13-15所示,打开罐盖98,将液态 的脱脂剂倒入干燥罐91中,关闭罐盖98,启动加热装置95对干燥罐91进行加热,启动循环装置,将脱脂剂抽至干燥罐91上端,与其侧壁充分接触,同时流动的液体,避免过热使得脱脂剂黏在内部上,启动吹风装置,将干燥罐91内蒸发的水汽吸走,并且吹去热风,促进干燥罐91内气体流动。当吸走总质量50%的水后,循环装置停机,抽液管上的电磁铁工作将抽液管关闭,防止干燥后的脱脂剂进入抽液管中。利用吹风装置94直至干燥罐91内脱脂剂干燥。打开密封盖911,启动驱动机构93,使得干燥罐91倾斜,干燥后的脱脂剂从开口排出。
以上仅为本发明的较佳实施例,并非用来限定本发明的实施范围;如果不脱离本发明的精神和范围,对本发明进行修改或者等同替换,均应涵盖在本发明权利要求的保护范围当中。

Claims (10)

  1. 一种粉末脱脂剂,其特征在于,该脱脂剂由下列重量比例成分组成:
    Figure PCTCN2020114729-appb-100001
  2. 一种粉末脱脂剂的制备方法,其特征在于,包括以下步骤:
    步骤一,将纯水分成三份,分别注入搅拌装置内;
    步骤二,将氢氧化钠投第一份纯水中,EO/PO嵌段聚合物投入其中第二份纯水中,剩余组分投入第三份纯水中,并且搅拌均匀;
    步骤三,当第一份纯水和第三份纯水中温度在35-50℃时,将第三份混合后的纯水注入只第一份混合后的纯水中,搅拌20-40分钟;
    步骤四,当第一份纯水和第二份纯水中的温度在20-35℃时,将混合后的第二份纯水注入第一份混合后的纯水中,搅拌10-20分钟,制得液态脱脂剂;
    步骤五,将液态脱脂剂投入干燥装置内进行干燥;
    步骤六,将干燥后的脱脂剂研磨过筛,制成粉末脱脂剂。
  3. 根据权利要求2所述的一种粉末脱脂剂的制备方法,其特征在于,所述搅拌装置包括主罐体、两个子罐体、水泵、第一搅拌机构、第二搅拌机构和第三搅拌机构,所述主罐体内设置用于搅拌的所述第一搅拌机构,所述子罐体内设置用于搅拌的第二搅拌机构,所述子罐体贴合在所述主罐体上,所 述水泵和所述第三搅拌机构通过管路设置在所述主罐体上,并且与所述主罐体形成循环回路;所述子罐体通过管路连接在所述水泵和所述第三搅拌机构之间,所述子罐体包括本体和密封盖,所述本体上端设置进气孔和进料口,所述进气孔与气源连接,所述密封盖密封设置在所述进料口上。
  4. 根据权利要求3所述的一种粉末脱脂剂的制备方法,其特征在于,所述第三搅拌机构包括壳体、安装块和混料管,所述壳体内设置安装所述安装块的安装腔,所述安装块上设置若干个贯穿的安装管,所述混料管设置在所述安装管内,所述壳体的两端分别设置进液口与出液口;所述混料管包括管和若干个叠加的搅拌单元,所述搅拌单元呈螺旋状,一所述搅拌单元的下端与另一所述搅拌单元的上端相互垂直。
  5. 一种粉末脱脂剂的干燥装置,其特征在于,包括干燥罐、底座、驱动机构、吹风机构、加热装置、循环装置、气缸和罐盖,所述干燥罐转动设置在所述底座上,所述驱动机构设置在所述底座上,利用所述驱动机构驱动所述干燥罐竖直转动,所述干燥罐的侧壁的下方设置开口和闭合所述开口的密封盖,所述气缸设置在所述干燥罐的周向,所述罐盖设置在所述气缸上,利用所述气缸驱动罐盖打开和关闭所述干燥罐,所述加热装置设置在所述干燥管的侧壁内,所述循环装置将所述干燥罐内的液体喷射在所述干燥罐的内壁上,所述吹风装置设置在所述罐盖上,对所述干燥罐内吹风并将所述干燥罐内的水汽排出。
  6. 根据权利要求5所述的一种粉末脱脂剂的干燥装置,其特征在于,所述循环装置包括抽液管、喷液管、抽水泵、过滤头、电磁铁,所述抽水泵设置在所述罐盖上,抽液管延伸至所述干燥罐底部,所述过滤头滑动设置在所述抽液管端部,所述电磁铁设置在所述抽液管上,利用所述电磁铁吸引所述过滤头,所述干燥罐内壁上端设置向内倾斜的台阶,所述喷液管延伸至台阶上方,所述干燥罐的侧壁的下方设置开口和闭合所述开口的密封盖。
  7. 根据权利要求5所述的一种粉末脱脂剂的干燥装置,其特征在于,所述吹风装置包括若干吹风头、送风管、加热箱、除湿箱、过滤罩和吹风机,所述吹风头设置在所述罐盖的底部,通过所述送风管与所述加热箱连接,所 述除湿箱设置在所述罐盖上,设置与所述干燥罐连通的抽风口,所述过滤罩设置在所述抽风口上,所述除湿箱通过所述吹风机与所述加热箱连接。
  8. 根据权利要求7所述的一种粉末脱脂剂的干燥装置,其特征在于,所述吹风头与所述干燥罐内切线呈50°夹角,并且与所述水平面呈45°夹角。
  9. 根据权利要求5所述的一种粉末脱脂剂的干燥装置,其特征在于,所述驱动机构包括电机和凸轮,所述干燥罐底部一侧通过转轴与所述底座转动连接,在另一侧转动设置所述凸轮,利用所述电机驱动所述凸轮转动。
  10. 根据权利要求5所述的一种粉末脱脂剂的干燥装置,其特征在于,所述干燥罐侧壁设置中空隔热层。
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