WO2022011071A1 - Textured region of a substrate to reduce specular reflectance incorporating surface features with an elliptical perimeter or segments thereof, and method of making the same - Google Patents
Textured region of a substrate to reduce specular reflectance incorporating surface features with an elliptical perimeter or segments thereof, and method of making the same Download PDFInfo
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- WO2022011071A1 WO2022011071A1 PCT/US2021/040773 US2021040773W WO2022011071A1 WO 2022011071 A1 WO2022011071 A1 WO 2022011071A1 US 2021040773 W US2021040773 W US 2021040773W WO 2022011071 A1 WO2022011071 A1 WO 2022011071A1
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- surface features
- substrate
- ellipses
- textured region
- area
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
- G02B1/115—Multilayers
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/225—Nitrides
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
- C03C17/3435—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a nitride, oxynitride, boronitride or carbonitride
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/021—Cleaning or etching treatments
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
- C23C14/042—Coating on selected surface areas, e.g. using masks using masks
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0227—Pretreatment of the material to be coated by cleaning or etching
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/042—Coating on selected surface areas, e.g. using masks using masks
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/118—Anti-reflection coatings having sub-optical wavelength surface structures designed to provide an enhanced transmittance, e.g. moth-eye structures
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/42—Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect
- G02B27/4205—Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect having a diffractive optical element [DOE] contributing to image formation, e.g. whereby modulation transfer function MTF or optical aberrations are relevant
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/42—Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect
- G02B27/4272—Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect having plural diffractive elements positioned sequentially along the optical path
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
- G02B5/021—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
- G02B5/021—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures
- G02B5/0221—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures the surface having an irregular structure
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0268—Diffusing elements; Afocal elements characterized by the fabrication or manufacturing method
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
- G09F9/30—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/08—Glass having a rough surface
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
- C03C2218/153—Deposition methods from the vapour phase by cvd by plasma-enhanced cvd
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
- C03C2218/155—Deposition methods from the vapour phase by sputtering by reactive sputtering
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/34—Masking
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B2207/00—Coding scheme for general features or characteristics of optical elements and systems of subclass G02B, but not including elements and systems which would be classified in G02B6/00 and subgroups
- G02B2207/101—Nanooptics
Definitions
- the surface features having such an elliptical or partially elliptical shape when randomly distributed and oriented, provide low specular reflection with minimal transmission haze and pixel power deviation and with minimal or unperceivable reflected color artifacts.
- the surface features are randomly distributed and oriented, the surface features are specifically placed by design.
- the textured region can be reproduced from substrate to substrate.
- the method of the thirty ⁇ second aspect wherein the points randomly distributed within the area are separated by a minimum distance.
- the method of any one of the thirtieth through thirty ⁇ third aspects further comprises: forming secondary surface features into one or more sections of the textured region, thereby increasing the surface roughness (R a ) of at the one or more sections to within a range of 5 nm to 100 nm.
- FIG. 20A pertaining to Example 16, are white light interferometer graphs illustrating the topography of the elliptical surface features and the surrounding portion (top) and the secondary surface features (bottom) disposed at the elliptical surface features (left) and the surrounding portion (right); and [0081] FIG. 20B, pertaining to Example 16, are atomic force microscopy images of the secondary surface features disposed at an elliptical surface feature (left) and the surrounding portion (right), illustrating that the secondary surface features at the surrounding portion imparted a higher surface roughness (R a ) than the at the elliptical surface feature (because the surrounding portion was not previously etched and thus more sensitive to the etching that imparted the secondary surface features).
- R a surface roughness
- the lower mean elevation 44 provided by the one or more lower surfaces 41 differs from the higher mean elevation 42 provided by the one or more higher surfaces 40 by a distance 48 of 0.05 ⁇ m, 0.10 ⁇ m, 0.15 ⁇ m, 0.20 ⁇ m, 0.25 ⁇ m, 0.30 ⁇ m, 0.35 ⁇ m, 0.40 ⁇ m, 0.45 ⁇ m, 0.50 ⁇ m, 0.55 ⁇ m, 0.60 ⁇ m, 0.65 ⁇ m, 0.70 ⁇ m or within any range defined by any two of those values (e.g., 0.10 ⁇ m to 0.20 ⁇ m, 0.05 ⁇ m to 0.70 ⁇ m, 0.05 ⁇ m to 0.60 ⁇ m, and so on).
- the larger surface features 26L and (ii) the smaller surface features 26S that project from the surrounding portion 32 provide the one or more higher surfaces 40 residing at the higher mean elevation 42.
- the surrounding portion 32 and the smaller surface features 26S that are set into larger surface features 26L provide the one or more lower surfaces 41 residing at the lower mean elevation 44.
- Such a configuration can be the result of a one step ⁇ etching process. A single etching step etches away the substrate 12 to form all of (i) the larger surface features 26L projecting from the surrounding portion 32, (ii) the smaller surface features 26S projecting from the surrounding portion 32, and (iii) the smaller surface features 26S set into the larger surface features 26L.
- the larger surface features 26L provide at least a portion of the one or more lower surfaces 41 disposed at the lower mean elevation 44.
- the larger surface features 26L are set into the surrounding portion 32.
- the surrounding portion 32 provides the one or more intermediate surfaces 43b disposed at the intermediate mean elevation 45b.
- some of the smaller surface features 26S project from the larger surface features 26L, and provide the one or more intermediate surfaces 43a disposed at the intermediate mean elevation 45a.
- the remaining smaller surface features 26S, those that do not project from the from the larger surface features 26L, project from the surrounding portion 32, and provide the one or more higher surfaces 40 residing at the higher mean elevation 42.
- the higher mean elevation 44 differs from the lower mean elevation 42, in these embodiments with the first portion 58 and the second portion 60, by the distance 48, which again is 0.05 ⁇ m, 0.10 ⁇ m, 0.15 ⁇ m, 0.20 ⁇ m, 0.25 ⁇ m, 0.30 ⁇ m, 0.35 ⁇ m, 0.40 ⁇ m, 0.45 ⁇ m, 0.50 ⁇ m, 0.55 ⁇ m, 0.60 ⁇ m, 0.65 ⁇ m, 0.70 ⁇ m or within any range defined by any two of those values (e.g., 0.10 ⁇ m to 0.20 ⁇ m, 0.05 ⁇ m to 0.70 ⁇ m, 0.05 ⁇ m to 0.60 ⁇ m, and so on).
- the second portion 60 of the textured region 20 residing at the second elevation 64 is everything else that is not the first portion 58 of the textured region 20.
- incorporation of relatively large surface features 28 that are spaced relatively far apart but with a fill ⁇ factor of about 50% can force intensity of reflected light to peak at about 0.3 degrees while maximizing interferometric suppression of specular reflection.
- relatively small surface features 26 of two size ranges are utilized and the difference between the two size ranges is relatively small.
- at least some of the larger elliptical perimeters 28L entirely encompass more than one of the smaller elliptical perimeters 28S.
- the substrate 12 may further comprise at least one alkaline earth metal oxide such as, but not limited to, MgO or CaO.
- the substrate 12 has a bulk composition that is substantially free of lithium; i.e., the glass comprises less than 1 mol % Li 2 O and, in other embodiments, less than 0.1 mol % Li 2 O and, in other embodiments, 0.01 mol % Li 2 O, and in still other embodiments, 0 mol % Li 2 O.
- the etching mask 128 is either shaped to match the inside of the ellipses 104, or shaped to match the outside of the ellipses 104 generated at the step 102.
- the black inside the ellipses 104 of the illustration at FIG. 12 pertaining to a step 130 represents the etching mask 128.
- the white outside of the ellipses 104 is the primary surface 18 of the substrate 12. The opposite scenario would have existed if the lithography mask 112 was formed in the opposite manner.
- the method 100 further includes contacting the substrate 12 with the etching mask 128 with an etchant 132.
- the new area 220 is the combination of the first ellipses 204 and the second ellipses 210 within the same new area 220.
- the new area 220 includes free portions 222 of the first ellipses 204 and the second ellipses 210 that do not overlap.
- the free portions 222 would include any of the first ellipses 204 and the second ellipses 210 that do not overlap at all, and the portions of the first ellipses 204 and the second ellipses 210 that are not overlapped.
- the new area 220 further includes overlapping portions 224 of the first ellipses 204 and the second ellipses 210.
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- General Chemical & Material Sciences (AREA)
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- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Theoretical Computer Science (AREA)
- Laminated Bodies (AREA)
- Optical Elements Other Than Lenses (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Diffracting Gratings Or Hologram Optical Elements (AREA)
- Electroluminescent Light Sources (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
A substrate for a display article includes: a primary surface; a textured region on at least a portion of the primary surface, the textured region comprising surface features that reflect a random distribution, each of the surface features comprising a perimeter that is parallel to a base-plane extending through a thickness of the substrate below the textured region, wherein the perimeter is elliptical. The textured region can further include (i) one or more higher surfaces residing at a higher mean elevation from the base-plane and (ii) one or more lower surfaces residing at a lower mean elevation from the base-plane that is closer to the base-plane than the higher mean elevation. The higher mean elevation can differ from the lower mean elevation by a distance within a range of 0.05 µm to 0.70 µm.
Description
TEXTURED REGION OF A SUBSTRATE TO REDUCE SPECULAR REFLECTANCE INCORPORATING SURFACE FEATURES WITH AN ELLIPTICAL PERIMETER OR SEGMENTS THEREOF, AND METHOD OF MAKING THE SAME CLAIM OF PRIORITY [0001] This patent application claims priority under 35 U.S.C. §119(e) to U.S. Provisional Patent Application No. 63/049,843, entitled “DISPLAY ARTICLES WITH DIFFRACTIVE, ANTIGLARE SURFACES AND METHODS OF MAKING THE SAME,” filed July 9, 2020, the entire disclosure of which is incorporated herein by reference. CROSS‐REFERENCE TO RELATED APPLICATIONS [0002] The present application relates to, but does not claim priority to, commonly owned and assigned U.S. Patent Application Serial No. __________ (D31977), entitled “TEXTURED REGION TO REDUCE SPECULAR REFLECTANCE INCLUDING A LOW REFRACTIVE INDEX SUBSTRATE WITH HIGHER ELEVATED SURFACES AND LOWER ELEVATED SURFACES AND A HIGH REFRACTIVE INDEX MATERIAL DISPOSED ON THE LOWER ELEVATED SURFACES” and filed on ______________; U.S. Patent Application Serial No. __________ (D31038/32632), entitled “ANTI‐GLARE SUBSTRATE FOR A DISPLAY ARTICLE INCLUDING A TEXTURED REGION WITH PRIMARY SURFACE FEATURES AND SECONDARY SURFACE FEATURES IMPARTING A SURFACE ROUGHNESS THAT INCREASES SURFACE SCATTERING” and filed on ______________; U.S. Patent Application Serial No. __________ (D32647), entitled “DISPLAY ARTICLES WITH DIFFRACTIVE, ANTIGLARE SURFACES AND THIN, DURABLE ANTIREFLECTION COATINGS” and filed on __________; and U.S. Patent Application Serial No. __________ (D32623), entitled “DISPLAY ARTICLES WITH DIFFRACTIVE, ANTIGLARE SURFACES AND THIN, DURABLE ANTIREFLECTION COATINGS” and filed on __________. The entire disclosures of each of the foregoing U.S. patent applications, publications and patent documents are incorporated herein by reference. FIELD OF INVENTION [0003] The disclosure relates to a substrate for a display article where the substrate includes a textured region that reduces specular reflectance by incorporating surface features with an elliptical perimeter or segments thereof. The disclosure also relates to a method of making the same.
BACKGROUND [0004] Substrates transparent to visible light are utilized to cover displays of display articles. Such display articles include smart phones, tablets, televisions, computer monitors, and the like. The displays are often liquid crystal displays, organic light emitting diodes, among others. The substrate protects the display, while the transparency of the substrate allows the user of the device to view the display. [0005] The substrate reflecting ambient light, especially specular reflection, reduces the ability of the user to view the display through the substrate. Specular reflection in this context is the mirror‐like reflection of ambient light off the substrate. For example, the substrate may reflect visible light reflecting off or emitted by an object in the environment around the device. The visible light reflecting off the substrate reduces the contrast of the light from the display transmitting to the eyes of the user through the substrate. At some viewing angles, instead of seeing the visible light that the display emits, the user sees a specularly reflected image. Thus, attempts have been made to reduce specular reflection of visible ambient light off the substrate. [0006] Attempts have been made to reduce specular reflection off the substrate by texturing the reflecting surface of the substrate. The resulting surface is sometimes referred to as an "antiglare surface." For examples, sandblasting and liquid etching the surface of the substrate can texture the surface, which generally causes the surface to reflect ambient light diffusely rather than specularly. Diffuse reflection generally means that the surface still reflects the same intensity of ambient light but the texture of the reflecting surface scatters the light upon reflection. The more diffuse reflection interferes less with the ability of the user to see the visible light that the display emits. [0007] Such methods of texturing (i.e., sandblasting and liquid etching) generate features on the surface with imprecise and unrepeatable geometry (the features provide the texture). The geometry of the textured surface of one substrate formed via sandblasting or liquid etching can never be exactly the same as the geometry of the textured surface of another substrate formed via sandblasting or liquid etching. Commonly, only a quantification of the surface roughness (i.e., Ra) of the textured surface of the substrate is a repeatable target of the texturing.
[0008] There are a variety of metrics by which the quality of the "antiglare" surface is judged. Those metrics include (1) the distinctness‐of‐image, (2) pixel power deviation, (3) apparent Moiré interference fringes, (4) transmission haze, and (5) reflection color artifacts. Distinctness‐of‐ image, which more aptly might be referred to as distinctness‐of‐reflected‐image, is a measure of how distinct an image reflecting off the surface appears. The lower the distinctness‐of‐image, the more the textured surface is diffusely reflecting rather than specularly reflecting. Surface features can magnify various pixels of the display, which distorts the image that the user views. Pixel power deviation, also referred to as "sparkle," is a quantification of such an effect. The lower the pixel power deviation the better. Moiré interference fringes are large scale interference patterns, which, if visible, distort the image that the user sees. Preferably, the textured surface produces no apparent Moiré interference fringes. Transmission haze is a measure of how much the textured surface is diffusing the visible light that the display emitted upon transmitting through the substrate. The greater the transmission haze, the less sharp the display appears (i.e., lowered apparent resolution). Reflection color artifacts are a sort of chromatic aberration where the textured surface diffracts light upon reflection as a function of wavelength ‐ meaning that the reflected light, although relatively diffuse, appears segmented by color. The less reflected color artifacts that the textured surface produces the better. All of these attributes are discussed in greater detail below. [0009] Targeting a specific surface roughness cannot optimize all of those metrics simultaneously. A relatively high surface roughness that sandblasting or liquid etching produces might adequately transform specular reflection into diffuse reflection. However, the high surface roughness can additionally generate high transmission haze and pixel power deviation. A relatively low surface roughness, while decreasing transmission haze, might fail to sufficiently transform specular reflection into diffuse reflection ‐ defeating the "antiglare" purpose of the texturing. [0010] Accordingly, a new approach to providing a textured region of the substrate is needed ‐ one that causes the textured surface to reflect ambient light sufficiently diffusely rather than specularly so as to be "antiglare" (e.g., a low distinctness‐of‐image) but simultaneously also delivers low pixel power deviation, low transmission haze, and low reflection color artifacts.
SUMMARY [0011] The present disclosure addresses that need with a textured region of a substrate that incorporates randomly distributed and oriented elliptical surface features or segments thereof. The surface features having such an elliptical or partially elliptical shape, when randomly distributed and oriented, provide low specular reflection with minimal transmission haze and pixel power deviation and with minimal or unperceivable reflected color artifacts. Although the surface features are randomly distributed and oriented, the surface features are specifically placed by design. Thus, the textured region can be reproduced from substrate to substrate. [0012] According to a first aspect of the present disclosure, a substrate for a display article, the substrate comprising: (i) a primary surface; and (ii) a textured region on at least a portion of the primary surface, the textured region comprising surface features that reflect a random distribution, each of the surface features comprising a perimeter that is parallel to a base‐plane extending through a thickness of the substrate below the textured region, wherein the perimeter is elliptical. [0013] According to a second aspect of the present disclosure, the substrate of the first aspect, wherein the textured region further comprises (i) one or more higher surfaces residing at a higher mean elevation from the base‐plane and (ii) one or more lower surfaces residing at a lower mean elevation from the base‐plane that is closer to the base‐plane than the higher mean elevation. [0014] According to a third aspect of the present disclosure, the substrate of the second aspect, wherein (a) the textured region further comprises a surrounding portion, into which the surface features are set, or from which the surface features project; (b) the surrounding portion provides either (i) the one or more higher surfaces or (ii) the one or more lower surfaces; and (c) the surface features provide the other of (i) the one or more higher surfaces and (ii) the one or more lower surfaces, whichever the surrounding portion does not provide. [0015] According to a fourth aspect of the present disclosure, the substrate of any one of the second through third aspects, wherein the higher mean elevation differs from the lower mean elevation by a distance within a range of 0.05 µm to 0.70 µm. [0016] According to a fifth aspect of the present disclosure, the substrate of any one of the first through fourth aspects, wherein (i) the perimeter of each of the surface features comprises a
longest dimension parallel to the base‐plane; and (ii) the longest dimensions of the perimeters of the surface features are not all parallel to each other. [0017] According to a sixth aspect of the present disclosure, the substrate of the fifth aspect, wherein the longest dimension of the perimeter of each of the surface features is within a range of 5 µm to 150 µm. [0018] According to a seventh aspect of the present disclosure, the substrate of any one of the first through sixth aspects, wherein the surface features comprise a fill‐fraction that is within a range of 40% to 60%. [0019] According to an eighth aspect of the present disclosure, the substrate of the first aspect, wherein (i) the surface features comprise larger surface features and smaller surface features; (ii) the perimeters of the larger surface features comprise a range of longest dimensions parallel to the base‐plane; (iii) the perimeters of the smaller surface features comprise another range of longest dimensions parallel to the base‐plane; and (iv) the longest dimensions of the range of longest dimensions of the larger surface features are longer than the longest dimensions of the range of longest dimensions of the smaller surface features. [0020] According to a ninth aspect of the present disclosure, the substrate of the eighth aspect, wherein (i) the perimeters of the larger surface features totally surround the perimeters of some of the smaller surface features; and (ii) the perimeters of some the smaller surface features reside entirely outside of the perimeters. [0021] According to a tenth aspect of the present disclosure, the substrate of the eighth aspect, wherein the perimeter of at least one of the smaller surface features partially overlaps with the perimeter of one of the larger surface features, such that (i) part of the perimeter of the smaller surface features is inside the perimeter of the larger surface feature and (ii) part of the perimeter of the smaller surface features is outside the perimeter of the larger surface feature. [0022] According to an eleventh aspect of the present disclosure, the substrate of any one of the eighth through tenth aspects, wherein the textured region further comprises (i) one or more higher surfaces residing at a higher mean elevation from the base‐plane, (ii) one or more lower surfaces residing at a lower mean elevation from the base‐plane that is closer to the base‐plane
than the higher mean elevation, and (iii) a surrounding portion, into which the larger surface features are set, or from which the larger surface features project. [0023] According to a twelfth aspect of the present disclosure, the substrate of the eleventh aspect, wherein (i) the larger surface features project from the surrounding portion, some of the smaller surface features project from the surrounding portion, and the remaining smaller surface features, those that do not project from the surrounding portion, are set into the larger surface features; (ii) the larger surface features and smaller surface features that project from the surrounding portion provide the one or more higher surfaces residing at the higher mean elevation; and the surrounding portion and the smaller surface features that are set into larger surface features provide the one or more lower surfaces residing at the lower mean elevation. [0024] According to a thirteenth aspect of the present disclosure, the substrate of the eleventh aspect, wherein (i) the larger surface features are set into the surrounding portion, some of the smaller surface features are set into the surrounding portion, and the remaining smaller surface features, those that are not set into the surrounding portion, project from the larger surface features; (ii) the larger surface features and the smaller surface features that are set into the surrounding portion provide the one or more lower surfaces residing at the lower mean elevation; and (iii) the surrounding portion and the smaller surface features that project from the larger surface features provide the one or more higher surfaces residing at the higher mean elevation. [0025] According to a fourteenth aspect of the present disclosure, the substrate of the eighth aspect, wherein the textured region further comprises (i) one or more higher surfaces residing at a higher mean elevation from the base‐plane, (ii) one or more lower surfaces residing at a lower mean elevation from the base‐plane that is closer to the base‐plane than the higher mean elevation, (iii) one or more intermediate surfaces residing at one or two intermediate mean elevations from the base‐plane, wherein the one or two intermediate mean elevations are disposed between the higher mean elevation and the lower mean elevation, and (iv) a surrounding portion, into which the larger surface features are set, or from which the larger surface features project.
[0026] According to a fifteenth aspect of the present disclosure, the substrate of the fourteenth aspect, wherein the larger surface features provide at least a portion of the one or more higher surfaces residing at the higher mean elevation. [0027] According to a sixteenth aspect of the present disclosure, the substrate of the fourteenth aspect, wherein the larger surface features provide at least a portion of the one or more lower surfaces disposed at the lower mean elevation. [0028] According to a seventeenth aspect of the present disclosure, the substrate of any one of the first through sixteenth aspects, wherein the textured region further comprises one or more sections comprising secondary surface features imparting a surface roughness (Ra) within a range of 5 nm to 100 nm. [0029] According to a eighteenth aspect of the present disclosure, the substrate of any one of the first through seventeenth aspects, wherein (i) the textured region exhibits a transmission haze within a range of 0.5% to 5.0%; (ii) the textured region exhibits a pixel power deviation within a range of 1.0% to 3.0%; (iii) the textured region exhibits a distinctness‐of‐image within a range of 5% to 70%; (iv) the textured region exhibits a specular reflectance within a range of 4 GU to 40 GU; and (v) the textured region exhibits corrected color shifts ΔCx _corrected and ΔCy _corrected that are each respectively within a range of 0.03 to 0.6. [0030] According to a nineteenth aspect of the present disclosure, the substrate of any one of the first through eighteenth aspects, wherein the substrate comprises a glass or glass‐ceramic. [0031] According to a twentieth aspect of the present disclosure, a substrate for a display article, the substrate comprising: (a) a primary surface; (b) a base‐plane extending through the substrate below the primary surface; and (c) a textured region at the primary surface, the textured region comprising (i) one or more higher surfaces residing at a higher mean elevation from the base‐ plane, (ii) one or more lower surfaces residing at a lower mean elevation from the base‐plane, (iii) a first portion providing either the one or more higher surfaces or the one or more lower surfaces, and (iv) a second portion providing the other of the one or more higher surfaces and the one or more higher surfaces, whichever the first portion is not providing; wherein, elliptical perimeters which lie in planes parallel to the base‐plane and reflect a random distribution, define
the first portion except for overlapping portions of the elliptical perimeters, where the overlapping portions define in part the second portion. [0032] According to a twenty‐first aspect of the present disclosure, the substrate of the twentieth aspect, wherein in addition to the overlapping portions of the elliptical perimeters, the second portion of the textured region further comprises any part of the textured region that is not the first portion. [0033] According to a twenty‐second aspect of the present disclosure, the substrate of any one of the twentieth through twenty‐first aspects, wherein (i) each of the elliptical perimeters comprises a longest dimension parallel to the base‐plane; and (ii) the longest dimensions of the elliptical perimeters are not all parallel with each other. [0034] According to a twenty‐third aspect of the present disclosure, the substrate of any one of the twentieth through twenty‐second aspects, wherein the higher mean elevation differs from the second elevation by a distance within a range of 0.02 µm to 0.70 µm. [0035] According to a twenty‐fourth aspect of the present disclosure, the substrate of any one of the twentieth through twenty‐third aspects, wherein (a) the elliptical perimeters comprise larger elliptical perimeters and smaller elliptical perimeters, which are smaller than the first elliptical perimeters; and (b) the first portion of the textured region is bounded by (i) the smaller elliptical perimeters that do not overlap or intersect with the larger elliptical perimeters, (ii) portions of the smaller elliptical perimeters outside of the first elliptical perimeters that partially overlap with the larger elliptical perimeters, and (iii) portions of the larger elliptical perimeters that do not overlap with the smaller elliptical perimeters. [0036] According to a twenty‐fifth aspect of the present disclosure, the substrate of the twenty‐ fourth aspect, wherein at least some of the larger elliptical perimeters entirely encompass more than one of the smaller elliptical perimeters. [0037] According to a twenty‐sixth aspect of the present disclosure, the substrate of any one of the twenty‐fourth through twenty‐fifth aspects, wherein (i) a fill‐fraction of the larger elliptical perimeters is within a range of 40% to 60%; and (ii) a fill‐fraction of the smaller elliptical perimeters is within a range of 10% to 30%.
[0038] According to a twenty‐seventh aspect of the present disclosure, the substrate of any one of the twentieth through twenty‐sixth aspects, wherein the textured region further comprises one or more sections comprising secondary surface features imparting a surface roughness (Ra) within a range of 5 nm to 100 nm. [0039] According to a twenty‐eighth aspect of the present disclosure, the substrate of any one of the twentieth through twenty‐seventh aspects, wherein (i) the textured region exhibits a transmission haze within a range of 0.3% to 8.0%; (ii) the textured region exhibits a pixel power deviation within a range of 0.7% to 3.5%; (iii) the textured region exhibits a distinctness‐of‐image within a range of 25% to 100%; (iv) the textured region exhibits a specular reflectance within a range of 5 GU to 30 GU; and (v) the textured region exhibits corrected color shifts ΔCx _corrected and ΔCy _corrected that are each respectively within a range of 0.00 to 0.50. [0040] According to a twenty‐ninth aspect of the present disclosure, the substrate of any one of the twentieth through twenty‐eighth aspects, wherein the substrate comprises a glass or glass‐ ceramic. [0041] According to a thirtieth aspect of the present disclosure, a method of forming a textured region of a substrate of a display article, the method comprising: (I) generating a random distribution of ellipses within an area; (II) preparing a lithography mask comprising (a) an area matching the area of the plane; (b) material throughout the matching area; and (c) voids through the material, wherein the random distribution of the ellipses define either (i) the material throughout the matching area or (ii) the voids through the material; (III) exposing a workpiece comprising a substrate, a lithography ink disposed on the substrate, and the lithography mask disposed on the lithography ink, to a curing agent that transmits through the voids through the material of the lithography mask to cure exposed portions of the lithography ink, wherein non‐ exposed portions of the lithography ink blocked from exposure to the curing agent are not cured and removed along with the lithography mask, and the exposed portions of the lithography ink remain on the substrate as an etching mask; and (IV) contacting the substrate with the etching mask with an etchant, thus forming the textured region. [0042] According to a thirty‐first aspect of the present disclosure, the method of the thirtieth aspect further comprises: (I) generating a random distribution of second ellipses within a second
area; (II) preparing a second lithography mask comprising (a) a second area matching the area of the second plane; (b) material throughout the matching second area; and (c) voids through the material, wherein the random distribution of the second ellipses define either (i) the material throughout the matching second area or (ii) the voids through the material; (III) exposing a second workpiece comprising the substrate, new lithography ink disposed on the textured region of the substrate, and the second lithography mask disposed on the new lithography ink, to a curing agent that transmits through the voids through the material of the second lithography mask to cure exposed portions of the new lithography ink, wherein non‐exposed portions of the new lithography ink blocked from exposure to the curing agent are not cured and removed along with the second lithography mask, and the exposed portions of the new lithography ink remain on the substrate as a second etching mask; and (IV) contacting the substrate with the second etching mask with an etchant. [0043] According to a thirty‐second aspect of the present disclosure, the method of any one of the thirtieth through thirty‐first aspects, wherein generating the random distribution of the ellipses comprises: (i) distributing points randomly within an area; (ii) triangulating the points so that each point is made a vertex of a triangle thus forming a plurality of triangles, and none of the triangles overlap; (iii) drawing an ellipse inside each triangle of the plurality of triangles; and (iv) removing the points and the triangles so that only the ellipses that were drawn in the triangles remain on the area. [0044] According to a thirty‐third aspect of the present disclosure, the method of the thirty‐ second aspect, wherein the points randomly distributed within the area are separated by a minimum distance. [0045] According to a thirty‐fourth aspect of the present disclosure, the method of any one of the thirtieth through thirty‐third aspects further comprises: forming secondary surface features into one or more sections of the textured region, thereby increasing the surface roughness (Ra) of at the one or more sections to within a range of 5 nm to 100 nm. [0046] According to a thirty‐fifth aspect of the present disclosure, a method of forming a textured region of a substrate of a display article, the method comprises: (I) generating a random distribution of first ellipses within a first area; (II) generating a random distribution of second
ellipses within a second area, wherein the first ellipses comprise longest dimensions that are on average longer than longest dimensions of the second ellipses on average; (III) forming a new area that superimposes the first ellipses of the first area and the second ellipses of the second area, the new area comprising (a) free portions of the first ellipses and the second ellipses that do not overlap; (b) overlapping portions of the first ellipses and the second ellipses; and (c) empty portions where neither the first ellipses nor the second ellipses are present; (IV) preparing a lithography mask comprising (a) an area; (b) material within the area defined by either (i) the free portions or (ii) a combination of the overlapping portions and the empty portions; and (c) voids through the material defined by whichever of (i) the free portions and (ii) the combination of the overlapping portions and the empty portions do not define the material within the area; (V) exposing a workpiece comprising a substrate, a lithography ink disposed on the substrate, and the lithography mask disposed on the lithography ink, to a curing agent that transmits through the voids through the material of the lithography mask to cure exposed portions of the lithography ink, wherein non‐exposed portions of the lithography ink blocked from exposure to the curing agent are not cured and removed along with the lithography mask, and the exposed portions of the lithography ink remain on the substrate as an etching mask; and (VI) contacting the substrate with the etching mask with an etchant. [0047] According to a thirty‐sixth aspect of the present disclosure, the method of the thirty‐fifth aspect further comprises: before preparing the lithography mask, removing from the new area any of the second ellipses that the first ellipses partially but not fully overlap. [0048] According to a thirty‐seventh aspect of the present disclosure, the method of any one of the thirty‐fifth through thirty‐sixth aspects, wherein generating the random distribution of the first ellipses and generating the random distribution of the second ellipses both separately comprise: (i) distributing points randomly within an area, each of the points separated by a minimum distance; (ii) triangulating the points so that each point is made a vertex of a triangle thus forming a plurality of triangles, and none of the triangles overlap; (iii) drawing an ellipse inside each triangle of the plurality of triangles; and removing the points and the triangles so that only the ellipses that were drawn in the triangles remain on the area.
[0049] According to a thirty‐eighth aspect of the present disclosure, the method of the thirty‐ seventh aspect, wherein (i) the minimum distance separating each of the points of the area for the random distribution of the first ellipses is within a range of 80 µm to 130 µm; and (ii) the minimum distance separating each of the points of the area for the random distribution of the second ellipses is within a range of 15 µm to 40 µm. [0050] According to a thirty‐ninth aspect of the present disclosure, the method of the thirty‐ seventh aspect, wherein (i) the minimum distance separating each of the points of the area for the random distribution of the first ellipses is less than or equal 20 µm; (ii) the minimum distance separating each of the points of the area for the random distribution of the second ellipses is less than or equal 18 µm; and the minimum distance separating each of the points of the area for the random distribution of the first ellipses differs from the minimum distance separating each of the points of the plane for the random distribution of the second ellipses by a value within a range of 1 µm to 3 µm. [0051] According to a fortieth aspect of the present disclosure, the method of any one of the thirty‐fifth through thirty‐ninth aspects further comprises: forming secondary surface features into one or more sections of the textured region, thereby increasing the surface roughness (Ra) of at the one or more sections to within a range of 5 nm to 100 nm. BRIEF DESCRIPTION OF THE DRAWINGS [0052] In the figures: [0053] FIG. 1 is a perspective view of a display article, illustrating a substrate including a primary surface with a textured region; [0054] FIG. 2 is a magnified illustration of a portion of an embodiment of the textured region of FIG. 1, illustrating elliptical surface features projecting from a surrounding portion; [0055] FIG. 3 is an elevation view of a cross‐section taken through line III‐III of FIG. 2, illustrating the elliptical surface features projecting from the surrounding portion, with the elliptical surface features providing higher surfaces that reside at a higher mean elevation from a base‐plane extending through the substrate below the textured region, and with the surrounding portion providing a lower surface that resides at a lower mean elevation from the base‐plane;
[0056] FIG. 4 is a close‐up perspective view of area IV of FIG. 2, illustrating an elliptical surface feature projecting from the surrounding portion and providing a higher surface, which is relatively planar; [0057] FIG. 5 is a close‐up view of area V of FIG. 2, illustrating the elliptical surface features having a perimeter and a longest dimension, as well as the surface features being separated by a center‐ to‐center distance; [0058] FIG. 6 is a magnified illustration of a portion of an embodiment of the textured region of FIG. 1, illustrating larger elliptical surface features projecting from or set into a surrounding portion and smaller elliptical surface features projecting from or set into the larger elliptical surface features and projecting from or set into the surrounding portion; [0059] FIG. 7 is a close‐up view of area VII of FIG. 6, illustrating the smaller elliptical surface features having a shorter longest dimension than the longest dimension of the larger elliptical surface features; [0060] FIGS. 8A‐8C are elevational views of a cross‐section of FIG. 6, illustrating several possible variations for relative elevations of the larger elliptical surface features, the smaller elliptical surface features, and the surrounding portion from the base‐plane, depending on whether a two‐ step or one‐step etching process was utilized to form the textured region; [0061] FIGS. 9A and 9B are magnified illustrations of a portion of an embodiment of the textured region of FIG. 1, illustrating a first portion at a first elevation from the base‐plane and a second portion at a second elevation from the base‐plane, both incorporating elliptical surface features or segments thereof, a consequence of superimposing a first random distribution of larger ellipses and a second random distribution of smaller ellipses; [0062] FIGS. 10A and 10B are like FIGS. 9A and 9B but are a consequence of superimposing larger ellipses that are closer in size to the smaller ellipses than at FIGS. 9A and 9B; [0063] FIGS. 10C and 10D are elevational views of a cross‐section taken through line XC‐XC of FIG. 10B, illustrating the first portion and the second portion residing at different elevations from the base‐plane, either with the first portion projecting from the second portion (FIG. 10C) or with the first portion set into the second portion (FIG. 10D);
[0064] FIG. 11 is a schematic diagram of a set‐up used to measure a color shift of ambient light reflecting off the textured region of FIG. 1; [0065] FIG. 12 is a schematic flow chart of a method of forming an embodiment of the textured region of FIG. 1, illustrating steps of randomly distributing ellipses within an area, forming a lithography mask that incorporates the design of the area as a positive or a negative, forming an etching mask that incorporates the design of the area as a positive or negative on the substrate by using the lithography mask to selectively cure lithography ink, and then etching the substrate with the etching mask to form the textured region as either a positive or a negative of the area with the randomly distributed ellipses; [0066] FIG. 13 is a schematic illustrating an example generation of a random distribution of ellipses, where points are randomly generated (such as by using a Poisson disk random distribution algorithm), the points are triangulated, and then Steiner inellipses are drawn within the triangles, which are then later scaled down to a desired fill fraction; [0067] FIG. 14 is a schematic flow chart of another method of forming an embodiment of the textured region of FIG. 1, illustrating two different areas each including a random distribution of ellipses superimposed into one area, with overlapping portions of the ellipses differentiated from non‐overlapping portions; [0068] FIGS. 15A‐15C, pertaining to a Comparative Example 1A, illustrate circular surface features producing color‐separated reflected color artifacts; [0069] FIGS. 16A‐16C, pertaining to an Example 1B, illustrate an embodiment of the textured region of FIG. 1 incorporating elliptical surface features not producing color‐separated reflected color artifacts; [0070] FIGS. 17A and 17B, pertaining to an Example 2A and a Comparative Example 2B, illustrate elliptical surface features again producing less reflected color artifacts than circular color features, a consequence of having peak intensity of reflected light at close to 0.3 degrees scattering angle and only a minor secondary peak at 3 degrees scattering angle where the scattered intensity is reduced;
[0071] FIG. 18A, pertaining to Examples 14A‐14O, is a graph that illustrates that the presence of secondary surface features (to impart surface roughness) results in a lower pixel power deviation compared to substrates that did not have the secondary surface features; [0072] FIG. 18B, pertaining to Examples 14A‐14O, is a graph that illustrates that the presence of secondary surface features results in a lower specular reflectance compared to substrates that did not have the secondary surface features; [0073] FIG. 18C, pertaining to Examples 14A‐14O, is a graph that illustrates that the presence of secondary surface features resulted in a higher distinctness‐of‐image compared to substrates that did not have the secondary surface features; [0074] FIG. 18D, pertaining to Examples 14A‐14O, is a graph that illustrates that the presence of secondary surface features resulted in a higher transmission haze compared to substrates that did not have the secondary surface features; [0075] FIG. 19A, pertaining to Examples 15A‐15B, are atomic force microscopy images of the elliptical surface features and the surrounding portion (left) and the secondary surface features (middle and right), for both when the secondary surface features were disposed only on the elliptical surface features (top) and when the secondary surface features were disposed over both the elliptical surface features and the surrounding portion (bottom); [0076] FIG. 19B, pertaining to Examples 15A‐15B, is a graph illustrating that incorporating the secondary surface features over the entire textured region resulted in a lowed pixel power deviation compared to substrates where the secondary surface features were incorporated only on the elliptical surface features; [0077] FIG. 19C, pertaining to Examples 15A‐15B, is a graph illustrating that incorporating the secondary surface features over the entire textured region resulted in a higher transmission haze compared to substrates where the secondary surface features were incorporated only on the elliptical surface features; [0078] FIG. 19D, pertaining to Examples 15A‐15B, is a graph illustrating that incorporating the secondary surface features over the entire textured region did not substantially affect specular reflectance compared to substrates where the secondary surface features were incorporated only on the elliptical surface features;
[0079] FIG. 19E, pertaining to Examples 15A‐15B, is a graph illustrating that incorporating the secondary surface features over the entire textured region slightly affected specular reflectance compared to substrates where the secondary surface features were incorporated only on the elliptical surface features, and increasingly so as wavelength deviated from about 455 nm; [0080] FIG. 20A, pertaining to Example 16, are white light interferometer graphs illustrating the topography of the elliptical surface features and the surrounding portion (top) and the secondary surface features (bottom) disposed at the elliptical surface features (left) and the surrounding portion (right); and [0081] FIG. 20B, pertaining to Example 16, are atomic force microscopy images of the secondary surface features disposed at an elliptical surface feature (left) and the surrounding portion (right), illustrating that the secondary surface features at the surrounding portion imparted a higher surface roughness (Ra) than the at the elliptical surface feature (because the surrounding portion was not previously etched and thus more sensitive to the etching that imparted the secondary surface features). DETAILED DESCRIPTION [0082] Referring now to FIG. 1, a display article 10 includes a substrate 12. In embodiments, the display article 10 further includes a housing 14 to which the substrate 12 is coupled and a display 16 within the housing 14. In such embodiments, the substrate 12 at least partially covers the display 16 such that light that the display 16 emits can transmit through the substrate 12. [0083] The substrate 12 includes a primary surface 18, a textured region 20 defined on the primary surface 18, and a thickness 22 that the primary surface 18 bounds in part. The primary surface 18 generally faces toward an external environment 24 surrounding the display article 10 and away from the display 16. The display 16 emits visible light that transmits through the thickness 22 of the substrate 12, out the primary surface 18, and into the external environment 24. [0084] Referring now to FIGS. 2‐5, in embodiments, the textured region 20 includes surface features 26. The surface features 26 are randomly distributed. Each of the surface features 26 has a perimeter 28. The perimeter 28 is parallel to a base‐plane 30 extending through the
thickness 22 of the substrate 12 below the textured region 20. The perimeter 28 is elliptical. The base‐plane 30 provides a conceptual reference and not a structural component. [0085] The textured region 20 further includes a surrounding portion 32. In embodiments, the surface features 26 are set into the surrounding portion 32. In those embodiments, the surface features 26 are elliptical blind holes that extend down into the thickness 22 of the substrate 12 toward the base‐plane 30. In other embodiments, the surface features 26 project from the surrounding portion 32. In those embodiments, the surface features 26 are elliptical pillars that project from the surrounding portion 32 away from the base‐plane 30 and toward the external environment 24. The surrounding portion 32 forms a contiguous surface from which the surface features 26 either project from or are set into. [0086] As mentioned, the perimeter 28 of each of the surface features 26 is elliptical – that is, the shape of the perimeter 28 is an ellipsis. Each perimeter 28 thus has a longest dimension 34, which is twice a longest axis from a center 36 of the ellipse. In addition, each perimeter 28 has a width 38, which is twice a shortest axis from the center 36 of the ellipse. The incorporation of the surface features 26 having the perimeter 28 that is elliptical has a meaningful effect on anti‐ glare performance. Efforts leading to this disclosure also investigated surface features 26 having a circular perimeter 28. Substrates incorporating circular surface features as the textured region tended to produce observable reflection color artifacts upon reflecting ambient light. Comparative Example 1A below further elaborates that point. The surface features 26 with the perimeter 28 that is elliptical, or that incorporate elliptical segments, reflect light with reduced color artifacts, as well as provide beneficial transmission haze, pixel power deviation, and distinctiveness‐of‐image values. [0087] As mentioned, the surface features 26 are randomly distributed. In other words, the surface features 26 are aligned with each other and the surface features 26 are not arranged in a pattern. For example, the longest dimensions 34 of the surface features 26 are not all parallel with each other (i.e., not all aligned to be extending in the same directions). In addition, no grouping of the surface features 26 is arranged geometrically the same as any other grouping of the surface features 26.
[0088] The textured region 20 further includes (i) one or more higher surfaces 40 that reside at a higher mean elevation 42 from the base‐plane 30 and (ii) one or more lower surfaces 41 that reside at a lower mean elevation 44 from the base‐plane 30. The lower mean elevation 44 is closer to the base‐plane 30 than the higher mean elevation 42. The one or more higher surfaces 40 all reside at the same elevation within manufacturing tolerances. The one or more lower surfaces 41 all reside at the same elevation within manufacturing tolerances. In embodiments, the surface features 26 provide the one or more higher surfaces 40 and the surrounding portion 32 provides the one or more lower surfaces 41. In such circumstances, the surface features 26 project from the surrounding portion 32. In embodiments, the surface features 26 provide the one or more lower surfaces 41 and the surrounding portion 32 provides the one or more higher surfaces 42. In such circumstances, the surface features 26 are set into the surrounding portion 32. [0089] In embodiments, the longest dimension 34 of each surface feature 26 is 5 µm, 10 µm, 15 µm, 20 µm, 25 µm, 30 µm, 40 µm, 50 µm, 60 µm, 70 µm, 80 µm, 90 µm, 100 µm, 110 µm, 120 µm, 130 µm, 140 µm, 150 µm, or within any range bounded by any two of those values (e.g., 100 µm to 110 µm, 15 µm to 40 µm, 5 µm to 15 µm, and so on). In embodiments, the longest dimension 34 of each surface features 26, on average, is about 100 µm. [0090] In embodiments, the surface features 26 have a fill‐fraction of the textured region 20 of 30%, 40%, 50%, 60%, 70%, or within any range defined by any two of those values (e.g., 40% to 60%, and so on). The perimeter 28 of each surface feature 26 encompasses an area of a planar cross‐section of the textured region 20 parallel to the base‐plane 30. The sum of the areas of all of the perimeters 28 of all of the surface features 26 divided by the total area of the planar cross‐ section of the textured region 20 is the “fill‐fraction” of the surface features 26. It is believed that a fill‐fraction of about 50% suppresses specular reflection. In other words, some the ambient light reflects off the surface features 26, and some of the light reflects off the surrounding portion 32. A fill‐fraction of about 50% provides maximum destructive interference between the ambient light reflecting off the surface features 26 and the ambient light reflecting off the surrounding portion 32.
[0091] In embodiments, a distance 46 separates the center 36 of one surface feature 26 from the center 36 of the next nearest surface features 26. This document may refer to the distance 46 as “the pitch” of the surface features 26. In embodiments, the average of these distances 46 throughout the textured region 20 is 80 µm, 90 µm, 100 µm, 110 µm, 120 µm, 130 µm, 140 µm, 150 µm, or within any range bounded by any two of those values (e.g., 90 µm to 120 µm, 100 µm to 130 µm, and so on). It is believed that to cause the textured region 20 to reflect light where the peak intensity of reflected light is at a small angle (such as about 0.3 degrees), then the distance 46 separating the centers 36 of the surface features 26 should be within the range of about 90 µm to 120 µm. For example, considering the 550 nm wavelength portion of reflected ambient light, when the distance 46 is 105 µm, then the scattering angle providing the peak intensity of reflected light (at 550 nm wavelength) ought to be 0.3 degrees (because pitch ≅ wavelength /sin (ϑ)) . [0092] In embodiments, the lower mean elevation 44 provided by the one or more lower surfaces 41 differs from the higher mean elevation 42 provided by the one or more higher surfaces 40 by a distance 48 of 0.05 µm, 0.10 µm, 0.15 µm, 0.20 µm, 0.25 µm, 0.30 µm, 0.35 µm, 0.40 µm, 0.45 µm, 0.50 µm, 0.55 µm, 0.60 µm, 0.65 µm, 0.70 µm or within any range defined by any two of those values (e.g., 0.10 µm to 0.20 µm, 0.05 µm to 0.70 µm, 0.05 µm to 0.60 µm, and so on). When the surface features 26 project from the surrounding portion 32, the difference 48 is a height of the surface features 26 from the surrounding portion 32. When the surface features 26 are set into the surrounding portion 32, the difference 48 is a depth of the surface features 26 from the surrounding portion 32. [0093] Referring now to FIGS. 6‐8C, in embodiments of the textured region 20, the surface features 26 include or are separated into larger surface features 26L and smaller surface features 26S. “Larger” and “smaller” here are relative terms meaning that the larger surface features 26L are larger than the smaller surface features 26S. Each larger surface features 26L and each smaller surface feature 26S have a perimeter 28L, 28S, respectively, which is elliptical. Each perimeter 28L, 28S has a longest dimension 34L, 34S, respectively. The longest dimensions 34L of the larger surface features 26L fall within a range of longest dimensions 34L. The longest dimensions 34S of the larger surface features 26S fall within a range of longest dimensions 34S,
that are exclusive of the range of longest dimensions 34L of the larger surface features 26L. The longest dimensions 34L of the range of longest dimensions 34L of the larger surface features 26L are longer than the longest dimensions 34S of the range of longest dimensions 34S of the smaller surface features 26S. [0094] As mentioned above, in an attempt to force the intensity of reflected light off the textured region 20 to peak at about 0.3 degrees, the distance 46 between the centers 36 of the surface features 26 ought to be about 105 µm. As additionally mentioned above, to maximize specular reflection suppression via destruction interference, the fill‐fraction of the surface features 26 ought to be about 50%. To accommodate both of those criteria, then the longest dimensions 34 of the surface features 26 ought to be 100 µm. However, surface features 26 having such a longest dimension 34 on the 100 µm scale have a tendency to generate relatively high pixel power deviation. The addition of the smaller surface features 26S mitigates that consequence and generally results in a more acceptable, lower, pixel power deviation. The incorporation of the smaller surface features 26S can improve the pixel power deviation compared to if only the larger surface features 26L were incorporated. [0095] In embodiments, the perimeters 28L of the larger surface features 26L totally surround the perimeters 28S of some of the smaller surface features 26S. In embodiments, the perimeters 28S of some or all of the smaller surface features 26S reside entirely outside of the perimeters 28L of the larger surface features 26L. In embodiments, the perimeter 28S of any given smaller surface features 26S partially overlaps with the perimeter 28L of any given larger surface feature 28L, such that (i) part of the perimeter 28S of the smaller surface features 26S is inside the perimeter 28L of the larger surface feature 26L and (ii) part of the perimeter 28S of the smaller surface features 26S is outside the perimeter 28L of the larger surface feature 26L. Further, although not separately illustrated, the smaller surface features 26S, instead of having the perimeter 28S that is elliptical, have the perimeter 28S that can be circular. [0096] As mentioned, in embodiments, the textured region includes the two elevations (see, e.g., FIG. 8C) – the higher mean elevation 42 and the lower mean elevation 44. In embodiments, the larger surface features 26L provide at least a portion of the one or more higher surfaces 40 residing at the higher mean elevation 42. For example, in embodiments, the larger surface
features 26L project from the surrounding portion 32, some of the smaller surface features 26S project from the surrounding portion 32, and the remaining smaller surface features 26S, those that do not project from the surrounding portion 32, are set into the larger surface features 26L. In such embodiments, (i) the larger surface features 26L and (ii) the smaller surface features 26S that project from the surrounding portion 32 provide the one or more higher surfaces 40 residing at the higher mean elevation 42. The surrounding portion 32 and the smaller surface features 26S that are set into larger surface features 26L provide the one or more lower surfaces 41 residing at the lower mean elevation 44. Such a configuration can be the result of a one step‐ etching process. A single etching step etches away the substrate 12 to form all of (i) the larger surface features 26L projecting from the surrounding portion 32, (ii) the smaller surface features 26S projecting from the surrounding portion 32, and (iii) the smaller surface features 26S set into the larger surface features 26L. [0097] In embodiments (not separately illustrated, but the inverse of FIG. 8C), the larger surface features 26L provide at least a portion of the one or more lower surfaces 41 residing at the lower mean elevation 44. For example, in embodiments, the larger surface features 26L are set into the surrounding portion 32, some of the smaller surface features 26S are set into the surrounding portion 32, and the remaining smaller surface features 26S, those that are not set into the surrounding portion 32, project from the larger surface features 26L. In such embodiments, (i) the larger surface features 26L and (ii) the smaller surface features 26S that are set into the surrounding portion 32 provide the one or more lower surfaces 41 residing at the lower mean elevation 44. The surrounding portion 32 and the smaller surface features 26S that project from the larger surface features 26L provide the one or more higher surfaces 40 residing at the higher mean elevation 42. Such a configuration can be the result of a one step‐etching process. [0098] In embodiments (see FIGS. 8A and 8B), the textured region 20 further includes one or more intermediate surfaces 43 (e.g., 43a, 43b) that reside at one or more intermediate mean elevations 45 (e.g., 45a, 45b) from the base‐plane 30. The one or more intermediate mean elevations 45 (e.g., 45a, 45b) are between the higher mean elevation 42 and the lower mean elevation 44. These embodiments of the textured region 20 thus have surfaces at three or four distinct elevations from the base‐plane 30.
[0099] For example (see FIG. 8A), in embodiments, the larger surface features 26L provide at least a portion of the one or more higher surfaces 40 residing at the higher mean elevation 42. In these embodiments, the larger surface features 26L project from the surrounding portion 32. The surrounding portion 32 provides the one or more intermediate surfaces 43b that reside at the intermediate elevation 45b. In addition, some of the smaller surface features 26S are set into the surrounding portion 32 and provide the one or more lower surfaces 41 that reside at the lower mean elevation 44. The remaining smaller surface features 26S, those that are not set into the surrounding portion 32, are set into the larger surface features 26L, and provide the one or more intermediate surfaces 43a residing at the intermediate mean elevation 45a. Such a configuration can be the result of a two‐step etching process. A first etching step etches away the substrate 12 to form the surrounding portion 32 and the larger surface features 26L projecting therefrom. A second etching step etches away the substrate 12 to form the smaller surface features 26S set into the larger surface features 26L and the surrounding portion 32. [0100] Note that, when the depth of substrate 12 removed during the second etching step is equal to the depth of substrate 12 that was removed during the first etching step, the textured region 20 would only include three distinct elevations – the higher mean elevation 42, the lower mean elevation 44, and a single intermediate mean elevation 45. As applied to the example of FIG. 8A, both the smaller surface features 26S set into the larger surface features 26L and the surrounding portion 32 would provide the one or more intermediate surfaces 43 residing at the single intermediate mean elevation 45. [0101] As another example (see FIG. 8B), the larger surface features 26L provide at least a portion of the one or more lower surfaces 41 disposed at the lower mean elevation 44. In these embodiments, the larger surface features 26L are set into the surrounding portion 32. The surrounding portion 32 provides the one or more intermediate surfaces 43b disposed at the intermediate mean elevation 45b. In addition, some of the smaller surface features 26S project from the larger surface features 26L, and provide the one or more intermediate surfaces 43a disposed at the intermediate mean elevation 45a. The remaining smaller surface features 26S, those that do not project from the from the larger surface features 26L, project from the surrounding portion 32, and provide the one or more higher surfaces 40 residing at the higher
mean elevation 42. Again, the textured region 20 includes four distinct elevations 42, 45a, 45b, and 44. Such a configuration can be the result again of a two‐step etching process. A first etching step etches away the substrate 12 to form the larger surface features 26L set into the surrounding portion 32. A second etching step etches away the substrate 12 to form the smaller surface features 26S projecting from the larger surface features 26L and the surrounding portion 32. Note that, when the depth of substrate 12 removed during the second etching step is equal to the depth of substrate 12 that was removed during the first etching step, the textured region 20 would only include three distinct elevations – the higher mean elevation 42, the lower mean elevation 44, and a single intermediate mean elevation 45. [0102] In embodiments, in additional reference to FIGS. 9A‐10D, the textured region 20 includes a first portion 58 and a second portion 60. Either the first portion 58 or the second portion 60 provides the one or more higher surfaces 40 residing at the higher mean elevation 42. The other of the first portion 58 and the second portion 60 provides the one or more lower surfaces 41 residing at the lower mean elevation 44. The textured region 20 in these embodiments thus provide two distinct elevations 42, 44. The first portion 58 is everything colored white in the examples of FIGS. 9A‐10B and the second portion 60 is everything colored black. The opposite scenario is just as valid – the first portion 58 could be everything that is black and the second portion 60 could be everything that is white. [0103] As perhaps best illustrated in FIGS. 9B and 10B, elliptical perimeters 28 define the first portion 58, except for overlapping portions 66 of the elliptical perimeters 28. Two ellipses 28 in a plane are said to overlap if their area intersection is non‐empty. The overlapping portions 66 of the elliptical perimeters 28 define, in part, the second portion 60. For example, referring specifically to FIG. 9B, elliptical perimeter 28A does not overlap any other elliptical perimeter 28. Thus, everything that the elliptical perimeter 28A bounds is part of the first portion 58. Moving to perimeter 28B, perimeter 28B is entirely overlapped (i.e., surrounded) by perimeter 28C. Thus, everything that the elliptical perimeter 28B bounds is part of the second portion 60. Now considering perimeter 28D, perimeter 28D only partially overlaps with perimeter 28C – part of perimeter 28D is inside perimeter 28C and part of perimeter 28D is outside perimeter 28C. The part of perimeter 28D that is outside perimeter 28C is not an overlapping portion 66 and thus
forms part of the first portion 58. However, the part of perimeter 28D that is inside perimeter 28C is an overlapping portion and thus forms part of the second portion 60. Finally, looking at perimeter 28C, perimeter 28C fully overlaps perimeter 28B, partially overlaps perimeter 28D, and fully or partially overlaps several other perimeters. Those portions of perimeter 28C, overlapping other perimeters 28, form part of the second portion 60. The remainder of perimeter 28C does not overlap any other perimeter 28 and thus forms part of the first portion 58. [0104] In addition to the overlapping portions 66 of the elliptical perimeters 28, the second portion 60 of the textured region 20 further comprises any part of the textured region 20 that is not the first portion 58. More specifically, any parts 70 of the textured region 20 outside of any of the elliptical perimeters 28 form part of the second portion 60. [0105] Like the embodiments previously discussed, each of the elliptical perimeters 28 of the textured region 20 is randomly distributed and randomly oriented. Each of the elliptical perimeters 28 comprises a longest dimension 34. The longest dimensions 34 of the elliptical perimeters 28 are not all parallel to each other. Thus, the longest dimensions 34 of the elliptical perimeters 28 are not all commonly aligned. The random distribution and orientation of the elliptical perimeters 28 and lack of pattern prevent or reduce the ability of the textured region 20 to generate Moiré interference fringes and other optical distortions upon reflecting ambient light. [0106] As mentioned, referring to FIGS. 10C and 10D, either the first portion 58 or the second portion 60 provides the one or more higher surfaces 40 residing at the higher mean elevation 42, while the other of the first portion 58 and the second portion 60 provides the one or more lower surfaces 41 residing at the lower mean elevation 44. In embodiments, such as illustrated at FIG. 10C, the first portion 58 provides the one or more higher surfaces 40 residing at the higher mean elevation 42. The second portion 60 provides the one or more lower surfaces 41 residing at the lower mean elevation 44. Stated another way, in these embodiments, the first portion 58 projects out toward the external environment 24 from the second portion 60. [0107] In other embodiments, such as illustrated at FIG. 10D, the first portion 58 provides the one or more lower surfaces 41 residing at the lower mean elevation 42. The second portion 60 provides the one or more higher surfaces 40 residing at the higher mean elevation 44. Stated
another way, in these embodiments, the second portion 60 projects out toward the external environment 24 from the first portion 58. [0108] The higher mean elevation 44 differs from the lower mean elevation 42, in these embodiments with the first portion 58 and the second portion 60, by the distance 48, which again is 0.05 µm, 0.10 µm, 0.15 µm, 0.20 µm, 0.25 µm, 0.30 µm, 0.35 µm, 0.40 µm, 0.45 µm, 0.50 µm, 0.55 µm, 0.60 µm, 0.65 µm, 0.70 µm or within any range defined by any two of those values (e.g., 0.10 µm to 0.20 µm, 0.05 µm to 0.70 µm, 0.05 µm to 0.60 µm, and so on). A one‐step etching process can produce embodiments including the first portion 58 and the second portion 60 as described. [0109] In embodiments, the elliptical perimeters 28 are divided by size into two different subsets – larger elliptical perimeters 28L and smaller elliptical perimeters 28S, which are smaller than the larger elliptical perimeters 28L. The larger elliptical perimeters 28L are larger than the smaller elliptical perimeters 28L in the sense that the longest dimensions 34 of the larger elliptical perimeters 28L are part of a range of longest dimensions 34 that is longer than a range of longest dimensions 34 of which the longest dimensions 34 of the smaller elliptical perimeters 28S are a part. For example, referring to FIG. 9B, the longest dimension 34 of perimeter 28C, belonging to the larger elliptical perimeters 28L, is longer than the longest dimensions 34 of perimeters 28A, 28B, and 28D, which all belong to the smaller elliptical perimeters 28S. The first portion 58 of the textured region 20 having the first elevation 62 from the base‐plane 30 is bounded by (i) the smaller elliptical perimeters 28S that do not overlap or intersect with the larger elliptical perimeters 28L, (ii) portions of the smaller elliptical perimeters 28S outside of the first elliptical perimeters 28S that partially overlap with the larger elliptical perimeters 28L, and (iii) portions of the larger elliptical perimeters 28L that do not overlap with the smaller elliptical perimeters 28S. The second portion 60 of the textured region 20 residing at the second elevation 64 is everything else that is not the first portion 58 of the textured region 20. [0110] As discussed above, incorporation of relatively large surface features 28 that are spaced relatively far apart but with a fill‐factor of about 50% can force intensity of reflected light to peak at about 0.3 degrees while maximizing interferometric suppression of specular reflection.
However, the same result can be achieved if relatively small surface features 26 of two size ranges are utilized and the difference between the two size ranges is relatively small. [0111] In embodiments, as illustrated at FIGS. 9A and 9B, at least some of the larger elliptical perimeters 28L entirely encompass more than one of the smaller elliptical perimeters 28S. Note that in some embodiments, such as that illustrated at FIG. 6, at least some of the larger elliptical perimeters 28L encompass more than one of the smaller elliptical perimeters 28S but without any of the larger elliptical perimeters 28S only partially overlapping any of the smaller elliptical perimeters 28S. The elimination of smaller elliptical perimeters 28S that would only partially overlap the larger elliptical perimeter s8L is thought to reduce large angle scattering of reflected light. Large angle scattering can increase haze. In addition, the lithography masks that incorporate the designs that permit etching of such a textured region 20 have a resolution limit – too small a structure, such as where a small elliptical perimeter 28S only partially overlaps a larger elliptical perimeter 28L, can cause aliasing if sampled with insufficient resolution. [0112] In embodiments, a fill‐fraction of the larger elliptical perimeters 28L is within a range of 40% to 60%, while a fill‐fraction of the smaller elliptical perimeters 28S is within a range of 10% to 30%. The textured region 20 occupies an area 72. The fill‐fraction of the larger elliptical perimeters 28L here is the percentage of the area 72 encompassed by all of the larger elliptical perimeters 28L. The fill‐fraction of the smaller elliptical perimeters 28S here is the percentage of the area 72 encompassed by all of smaller elliptical perimeters 28S. The smaller elliptical perimeters 28S having a lower fill‐fraction limits the impact of the smaller elliptical perimeters 28S on the scattering spectrum of the overall design of the textured region 20. [0113] In embodiments (see, e.g., FIG. 3), the textured region 20 further includes one or more sections 80 that have secondary surface features 82. The secondary surface features 82 impart a surface roughness to the one or more sections 80 of the textured region 20. The increased surface roughness imparts surface scattering to the textured region 20, which generally lowers pixel power deviation and distinctness of image. The surface roughness imparted is 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm, 55 nm, 60 nm, 65 nm, 70 nm, 80 nm, 90 nm, or 100 nm or within any range bounded by any two of those values (e.g., 5 nm to 100 nm, and so on). As used herein, surface roughness (Ra) is measured with an atomic force microscope,
such as an atomic force microscope controlled by a NanoNavi control station distributed by Seiko Instruments Inc. (Chiba, Japan), with a scan size of 5 µm by 5 µm. Surface roughness (Ra), as opposed to other types of surface roughness values such as Rq, is the arithmetical mean of the absolute values of the deviations from a mean line of the measured roughness profile. [0114] In embodiments, the one or more sections 80 that include the secondary surface features 50 include the one or more higher surfaces 40, the one or more lower surfaces 41, and if present, the one or more intermediate surfaces 43a, 43b. In embodiments, the secondary surface features 82 are disposed on the surface features 26 but not the surrounding portion 32. In embodiments, the secondary surface features 82 are disposed on the surrounding portion 32 but not the surface features 26. In embodiments, the secondary surface features 82 are disposed on both the surrounding portion 32 and the surface features 26. In embodiments, the secondary surface features 82 are disposed on the first portion 58 and not the second portion 60, or vise‐ versa. In embodiments, the secondary surface features 82 are disposed on the first portion 58 and the second portion 60. In embodiments, the one or more sections 80 that includes the secondary surface features 82 is coextensive with the textured region 20 meaning that the secondary surface features 82 are disposed throughout the entirety of the textured region 20. In embodiments, the surface roughness (Ra) imparted by the second surface features 82 at the surface features 26 is less than the surface roughness at the surrounding portion 32. [0115] In embodiments, the substrate 12 includes a glass substrate or a glass‐ceramic substrate. In embodiments, the substrate 12 is a multi‐component glass composition having about 40 mol % to 80 mol % silica and a balance of one or more other constituents, e.g., alumina, calcium oxide, sodium oxide, boron oxide, etc. In some implementations, the bulk composition of the substrate 12 is selected from the group consisting of aluminosilicate glass, a borosilicate glass, and a phosphosilicate glass. In other implementations, the bulk composition of the substrate 12 is selected from the group consisting of aluminosilicate glass, a borosilicate glass, a phosphosilicate glass, a soda lime glass, an alkali aluminosilicate glass, and an alkali aluminoborosilicate glass. In further implementations, the substrate 12 is a glass‐based substrate, including, but not limited to, glass‐ceramic materials that comprise a glass component at about 90% or greater by weight and a ceramic component. In other implementations of the display article 10, the substrate 12
can be a polymer material, with durability and mechanical properties suitable for the development and retention of the textured region 20. [0116] In embodiments, the substrate 12 has a bulk composition that comprises an alkali aluminosilicate glass that comprises alumina, at least one alkali metal and, in some embodiments, greater than 50 mol % SiO2, in other embodiments, at least 58 mol % SiO2, and in still other embodiments, at least 60 mol % SiO2, wherein the ratio (Al2O3 (mol%) + B2O3 (mol%)) / ∑ alkali metal modifiers (mol%) > 1, where the modifiers are alkali metal oxides. This glass, in particular embodiments, comprises, consists essentially of, or consists of: about 58 mol % to about 72 mol % SiO2; about 9 mol % to about 17 mol % Al2O3; about 2 mol % to about 12 mol % B2O3; about 8 mol % to about 16 mol % Na2O; and 0 mol % to about 4 mol % K2O, wherein the ratio (Al2O3 (mol%) + B2O3 (mol%)) / ∑ alkali metal modifiers (mol%) > 1, where the modifiers are alkali metal oxides. [0117] In embodiments, the substrate 12 has a bulk composition that comprises an alkali aluminosilicate glass comprising, consisting essentially of, or consisting of: about 61 mol % to about 75 mol % SiO2; about 7 mol % to about 15 mol % Al2O3; 0 mol % to about 12 mol % B2O3; about 9 mol % to about 21 mol % Na2O; 0 mol % to about 4 mol % K2O; 0 mol % to about 7 mol % MgO; and 0 mol % to about 3 mol % CaO. [0118] In embodiments, the substrate 12 has a bulk composition that comprises an alkali aluminosilicate glass comprising, consisting essentially of, or consisting of: about 60 mol % to about 70 mol % SiO2; about 6 mol % to about 14 mol % Al2O3; 0 mol % to about 15 mol % B2O3; 0 mol % to about 15 mol % Li2O; 0 mol % to about 20 mol % Na2O; 0 mol % to about 10 mol % K2O; 0 mol % to about 8 mol % MgO; 0 mol % to about 10 mol % CaO; 0 mol % to about 5 mol % ZrO2; 0 mol % to about 1 mol % SnO2; 0 mol % to about 1 mol % CeO2; less than about 50 ppm As2O3; and less than about 50 ppm Sb2O3; wherein 12 mol %≦Li2O+Na2O+K2O≦20 mol % and 0 mol %≦MgO+Ca≦10 mol %. [0119] In embodiments, the substrate 12 has a bulk composition that comprises an alkali aluminosilicate glass comprising, consisting essentially of, or consisting of: about 64 mol % to about 68 mol % SiO2; about 12 mol % to about 16 mol % Na2O; about 8 mol % to about 12 mol % Al2O3; 0 mol % to about 3 mol % B2O3; about 2 mol % to about 5 mol % K2O; about 4 mol % to
about 6 mol % MgO; and 0 mol % to about 5 mol % CaO, wherein: 66 mol %≦SiO2+B2O3+CaO≦69 mol %; Na2O+K2O+B2O3+MgO+CaO+SrO>10 mol %; 5 mol %≦MgO+CaO+SrO≦8 mol %; (Na2O+B2O3)—Al2O3≦2 mol %; 2 mol %≦Na2O—Al2O3≦6 mol %; and 4 mol %≦(Na2O+K2O)— Al2O3≦10 mol %. [0120] In embodiments, the substrate 12 has a bulk composition that comprises SiO2, Al2O3, P2O5, and at least one alkali metal oxide (R2O), wherein 0.75>[(P2O5 (mol %)+R2O (mol %))/M2O3 (mol %)]≦1.2, where M2O3═Al2O3 +B2O3. In embodiments, [(P2O5 (mol %)+R2O (mol %))/M2O3 (mol %)]=1 and, in embodiments, the glass does not include B2O3 and M2O3═Al2O3. The substrate 12 comprises, in embodiments: about 40 to about 70 mol % SiO2; 0 to about 28 mol % B2O3; about 0 to about 28 mol % Al2O3; about 1 to about 14 mol % P2O5; and about 12 to about 16 mol % R2O. In some embodiments, the glass substrate comprises: about 40 to about 64 mol % SiO2; 0 to about 8 mol % B2O3; about 16 to about 28 mol % Al2O3; about 2 to about 12 mol % P2O5; and about 12 to about 16 mol % R2O. The substrate 12 may further comprise at least one alkaline earth metal oxide such as, but not limited to, MgO or CaO. [0121] In some embodiments, the substrate 12 has a bulk composition that is substantially free of lithium; i.e., the glass comprises less than 1 mol % Li2O and, in other embodiments, less than 0.1 mol % Li2O and, in other embodiments, 0.01 mol % Li2O, and in still other embodiments, 0 mol % Li2O. In some embodiments, such glasses are free of at least one of arsenic, antimony, and barium; i.e., the glass comprises less than 1 mol % and, in other embodiments, less than 0.1 mol %, and in still other embodiments, 0 mol % of As2O3, Sb2O3, and/or BaO. [0122] In embodiments, the substrate 12 has a bulk composition that comprises, consists essentially of or consists of a glass composition, such as Corning® Eagle XG® glass, Corning® Gorilla® glass, Corning® Gorilla® Glass 2, Corning® Gorilla® Glass 3, Corning® Gorilla® Glass 4, or Corning® Gorilla® Glass 5. [0123] In embodiments, the substrate 12 has an ion‐exchangeable glass composition that is strengthened by either chemical or thermal means that are known in the art. In embodiments, the substrate 12 is chemically strengthened by ion exchange. In that process, metal ions at or near the primary surface 18 of the substrate 12 are exchanged for larger metal ions having the same valence as the metal ions in the substrate 12. The exchange is generally carried out by
contacting the substrate 12 with an ion exchange medium, such as, for example, a molten salt bath that contains the larger metal ions. The metal ions are typically monovalent metal ions, such as, for example, alkali metal ions. In one non‐limiting example, chemical strengthening of a substrate 12 that contains sodium ions by ion exchange is accomplished by immersing the substrate 12 in an ion exchange bath comprising a molten potassium salt, such as potassium nitrate (KNO3) or the like. In one particular embodiment, the ions in the surface layer of the substrate 12 contiguous with the primary surface 18 and the larger ions are monovalent alkali metal cations, such as Li+ (when present in the glass), Na+, K+, Rb+, and Cs+. Alternatively, monovalent cations in the surface layer of the substrate 12 may be replaced with monovalent cations other than alkali metal cations, such as Ag+ or the like. [0124] In such embodiments, the replacement of small metal ions by larger metal ions in the ion exchange process creates a compressive stress region in the substrate 12 that extends from the primary surface 18 to a depth (referred to as the “depth of layer”) that is under compressive stress. This compressive stress of the substrate 12 is balanced by a tensile stress (also referred to as “central tension”) within the interior of the substrate 12. In some embodiments, the primary surface 18 of the substrate 12 described herein, when strengthened by ion exchange, has a compressive stress of at least 350 MPa, and the region under compressive stress extends to a depth, i.e., depth of layer, of at least 15 μm below the primary surface 18 into the thickness 22. [0125] Ion exchange processes are typically carried out by immersing the substrate 12 in a molten salt bath containing the larger ions to be exchanged with the smaller ions in the glass. It will be appreciated by those skilled in the art that parameters for the ion exchange process, including, but not limited to, bath composition and temperature, immersion time, the number of immersions of the glass in a salt bath (or baths), use of multiple salt baths, additional steps such as annealing, washing, and the like, are generally determined by the composition of the glass and the desired depth of layer and compressive stress of the glass as a result of the strengthening operation. By way of example, ion exchange of alkali metal‐containing glasses may be achieved by immersion in at least one molten bath containing a salt, such as, but not limited to, nitrates, sulfates, and chlorides, of the larger alkali metal ion. The temperature of the molten salt bath
typically is in a range from about 380°C up to about 450°C, while immersion times range from about 15 minutes up to about 16 hours. However, temperatures and immersion times different from those described above may also be used. Such ion exchange treatments, when employed with a substrate 12 having an alkali aluminosilicate glass composition, result in a compressive stress region having a depth (depth of layer) ranging from about 10 μm up to at least 50 μm, with a compressive stress ranging from about 200 MPa up to about 800 MPa, and a central tension of less than about 100 MPa. [0126] As the etching processes that can be employed to create the textured region 20 of the substrate 12 can remove alkali metal ions from the substrate 12 that would otherwise be replaced by a larger alkali metal ion during an ion exchange process, a preference exists for developing the compressive stress region in the display article 10 after the formation and development of the textured region 20. [0127] In embodiments, the display article 10 exhibits a pixel power deviation (“PPD”). The details of a measurement system and image processing calculation used to obtain PPD values described in U.S. Patent No. 9,411,180 entitled “Apparatus and Method for Determining Sparkle,” and the salient portions of which are related to PPD measurements are incorporated by reference herein in their entirety. Further, unless otherwise noted, the SMS‐1000 system (Display‐Messtechnik & Systeme GmbH & Co. KG) is employed to generate and evaluate the PPD measurements of this disclosure. The PPD measurement system includes: a pixelated source comprising a plurality of pixels (e.g., a Lenovo Z50 140 ppi laptop), wherein each of the plurality of pixels has referenced indices i and j; and an imaging system optically disposed along an optical path originating from the pixelated source. The imaging system comprises: an imaging device disposed along the optical path and having a pixelated sensitive area comprising a second plurality of pixels, wherein each of the second plurality of pixels is referenced with indices m and n; and a diaphragm disposed on the optical path between the pixelated source and the imaging device, wherein the diaphragm has an adjustable collection angle for an image originating in the pixelated source. The image processing calculation includes: acquiring a pixelated image of the transparent sample, the pixelated image comprising a plurality of pixels; determining boundaries between adjacent pixels in the pixelated image; integrating within the boundaries to obtain an
integrated energy for each source pixel in the pixelated image; and calculating a standard deviation of the integrated energy for each source pixel, wherein the standard deviation is the power per pixel dispersion. As used herein, all PPD values, attributes and limits are calculated and evaluated with a test set‐up employing a display device having a pixel density of 140 pixels per inch (PPI). In embodiments, the display article 10 exhibits a PPD of 0.8%, 0.9%, 1.0%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%, 1.9%, 2.0%, 2.25%, 2.5%, 2.75%, 3.0%, 3.25%, 3.5%, 3.75%, 4.0%, 4.25%, 4.5%, 4.75%, 5.0%, 5.25%, 5.5%, 5.75%, 6.0%, or within any range bounded by any two of those values (e.g., 0.8% to 2.0%, 0.9% to 2.25%, 2.0% to 6.0%, and so on). In embodiments, the display article 10 exhibits a PPD of less than 2.0%. [0128] In embodiments, the substrate 12 exhibits a distinctness‐of‐image (“DOI”). As used herein, “DOI” is equal to 100*(RS‐ R0.3˚)/RS, where RS is the first surface specular reflectance flux measured from incident light (at 20˚ from normal) directed onto the textured region 20, and R0.3 is the reflectance flux measured from the same incident light at 0.3˚ from the specular reflectance flux, RS. The sample is optically coupled to flat black glass with index‐matching oil on the back side to eliminate second‐surface reflections. Unless otherwise noted, the DOI values and measurements reported in this disclosure are obtained according to the ASTM D5767‐18, entitled “Standard Test Method for Instrumental Measurement of Distinctness‐of‐Image (DOI) Gloss of Coated Surfaces using a Rhopoint IQ Gloss Haze & DOI Meter” (Rhopoint Instruments Ltd.). In embodiments, the substrate 12 exhibits a distinctness‐of‐image (“DOI”) of 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 90%, 95%, 96%, or within any range bounded by any two of those values (e.g., 20% to 40%, 10% to 96%, 35% to 60%, and so on). [0129] In embodiments, the substrate 12 exhibits a transmission haze. As used herein, the term “transmission haze” refers to the percentage of transmitted light scattered outside an angular cone of about ±2.5° in accordance with ASTM D1003, entitled “Standard Test Method for Haze and Luminous Transmittance of Transparent Plastics,” the contents of which are incorporated by reference herein in their entirety. Note that although the title of ASTM D1003 refers to plastics, the standard has been applied to substrates comprising a glass material as well. For an optically smooth surface, transmission haze is generally close to zero. In embodiments, the substrate 12 exhibits a transmission haze of 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%. 1.0%, 1.5%, 2%, 3%,
4%, 5%, 6%, 7%, 8%, 9%, 10%, 12.5%, 15%, or within any range bounded by any two of those values (e.g., 0.3% to 15%, 0.9% to 1.0%, and so on). [0130] As used herein, “corrected color shift” is a measure of the amount of reflection color artifacts that the substrate 12 generates while reflecting ambient light from the textured region 20. Referring now to FIG. 11, to determine the corrected color shift, the substrate 12 with the textured region 20 to be tested is placed over the display 16, with oil 74 disposed between the substrate 12 and the display 16 to suppress the light reflections of the surface of the substrate 12 facing the display 16 and the surface of the display 16. The oil 74 has a refractive index matching a refractive index of the substrate 12. Room lights 76 emit light as they normally would. A white light source 78 illuminates the substrate 12. The textured region 20 of the substrate 12 faces toward the white light source 78. Since the reflection color artifacts of the substrate 12 are much more easily observed and are more accurately measured when the display 16 is turned off, the display 16 is switched‐off when color separation measurements are conducted. The textured region 20 reflects a portion of the light that the white light source 78 emits as a scatted light pattern. A color CCD camera 80 captures an image of the scattered light pattern. The image is then digitally processed, and chromaticity coefficients (Cx and Cy ) along a selected straight line through the locations with maximum Cx (or Cy ) and minimum Cx (or Cy ) are calculated. Here, chromaticity coefficients Cx and Cy are defined as Cx = PR / (PR +PG +PB ) and Cy = PG / (PR+ PG + PB) respectively, in which PR, P G , and PB are the powers (or intensities) of red, green, and blue light, respectively, at a location of the scattered light pattern detected by the color CCD camera 80. Chromaticity is an objective specification of the quality of a color regardless of its luminance. The color shifts along the selected line, Δ Cx and Δ Cy , are calculated as the difference between the maximum Cx and the minimum Cx for Δ Cx , and the difference between the maximum Cy and the minimum Cy for Δ Cy . The color shifts Δ Cx and Δ Cy are then corrected to account for the fact that the visibility of color change that human eyes see is relative to not only the color shifts (Δ Cx and Δ Cy ) but also an angle separation 82 between the locations of the maximum and minimum Cx (for Δ Cx ) and the maximum and minimum Cy (for Δ Cy ). These corrected colors shifts are defined as
The dθr is reference angle separation arbitrarily set at dθr = 0.84degrees . This reference angle is chosen from the angle between two adjacent measurement points of 455 point color and luminance measurement of a 300x110mm display viewed at 500mm distance. The dθx and dθy are the angle separations in degree between the locations of maximum and minimum for Cx and Cy respectively. When the corrected color shifts Δ Cx _corrected and Δ Cy _corrected are each less than 0.3, it is assumed that human eyes cannot perceive any reflection color artifacts that the substrate 12 is producing. In embodiments, the substrate 12 exhibits corrected color shifts Δ Cx _corrected and Δ Cy _corrected of 0.00, 0.01, 0.05, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, or within any range bounded by any two of those values (0.01 to 0.3, 0.05 to 1.0, and so on). In embodiments, the substrate 12 exhibits corrected color shifts Δ Cx _corrected and Δ Cy _corrected of less than 0.3, less than 0.2, less than 0.1, or even 0.0. [0131] In embodiments, the substrate 12 exhibits a specular reflectance of 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40, 45%, 50%, 55%, 60%, or 65%, or within any range bounded by any two of those values (e.g., 5% to 65%, 5% to 30%, and so on). In embodiments, the substrate 12 exhibits a specular reflectance that is less than 30%, less than 25%, less than 20%, or less than 10%. Specular reflectance here, noted as “c‐Rspec” in the Examples that follow, refers to the value obtained using a Rhopoint IQ goniophotometer, and are reported in gloss units (GU). 100 gloss units is defined to be the specular reflection intensity from a highly polished piece of flat black glass with refractive index 1.567. The values are indicative of how much specular reflection is measured when the sample is optically coupled with oil to a black glass of matching index to remove second‐surface reflections. [0132] Referring now to FIG. 12, a method 100 of forming the textured region 20 of the substrate 12 of the display article 10 is herein described. At a step 102, the method 100 includes generating a random distribution of ellipses 104 within an area 106 of a plane 108. [0133] At a step 110, the method 100 further includes preparing a lithography mask 112. The designof thelithographymask112matchestherandomdistributionofellipses104generated at
the step 102. The lithography mask 112 has an area 114. The area 114 matches the area 112 of the plane 108 within which the ellipses 104 were randomly distributed. The lithography mask 112 includes material 116 throughout the area 114. The lithography mask 112 further includes voids 118 through the material 116. The random distribution of the ellipses 104 generated at the step 102 define either (a) the material 116 throughout the area 114 or (b) the voids 118 through the material 116. In the illustration at FIG. 12, the black portions outside of the ellipses 104 represents the material 116 of the lithography mask 112, while the white portions inside of the ellipses 104 are the voids 118 through the material 116 of the lithography mask 112. The lithography mask 112 can be prepared to have the opposite relationship – the inside of the ellipses 104 (e.g., the white in FIG. 12) can represent the material 116 of the lithography mask 112, while outside of the ellipses 104 (e.g., the black in FIG. 12) can represent the voids 118 through the material 116 of the lithography mask 112. [0134] A workpiece 120 is prepared that incorporates the lithography mask 112. The workpiece 120 includes the substrate 12, lithography ink 122 on the primary surface 18 of the substrate 12 at which the textured region 20 is desired to be formed, and the lithography mask 112 over the lithography ink 122. [0135] At a step 124, the method 100 further includes exposing the workpiece 120 to a curing agent 126. The curing agent 126 can cure the lithography ink 122. The curing agent 126 can be ultraviolet light, among other things. The lithography mask 112 allows for selective curing of the lithography ink 122. The curing agent 126 transmits through the voids 118 in the material 116 of the lithography mask 112 to cure exposed portions of the lithography ink 122. However, the material 116 of the lithography mask 112 blocks non‐exposed portions of the lithography ink 122 from exposure to the curing agent 126. Thus, the non‐exposed portions of the lithography ink 122 are not cured. After curing, the lithography mask 112 and the non‐exposed portions of the lithography ink 122 are removed from the substrate 12. The exposed portions of the lithography ink 122 remain on the substrate 12 in cured formed as an etching mask 128. [0136] The random distribution of ellipses 104 generated at the step 102 defined the material 116 and the voids 118 through the material of the lithography mask 112, and thus, the etching mask 128 on the substrate 12. In other words, the etching mask 128 is either shaped to match
the inside of the ellipses 104, or shaped to match the outside of the ellipses 104 generated at the step 102. The black inside the ellipses 104 of the illustration at FIG. 12 pertaining to a step 130 represents the etching mask 128. The white outside of the ellipses 104 is the primary surface 18 of the substrate 12. The opposite scenario would have existed if the lithography mask 112 was formed in the opposite manner. [0137] At the step 130, the method 100 further includes contacting the substrate 12 with the etching mask 128 with an etchant 132. The etchant 132 selectively etches the etching mask 128 because the etching mask 128 allows the etchant 132 to contact some portions of the primary surface 18 of the substrate 12 and prevents the etchant 132 from contacting other portions of the primary surface 18 of the substrate 12. Depending on how the lithography mask 112 was formed, the etching mask 128 either (i) allows the etchant 132 to etch into the substrate 12 inside the ellipses 104 in accordance with the random generation thereof from the step 102 and prevents the etchant 132 from etching into the substrate 12 outside of the ellipses 104, or (ii) prevents the etchant 132 from etching into the substrate 12 inside the ellipses 104 in accordance with the random generation thereof from the step 102 and allows the etchant 132 to etch into the substrate 12 outside of the ellipses 104. Thereafter, the etching mask 128 is removed. The substrate 12 now has the textured region 20 on the primary surface 18 thereof, with the topography of the textured region 20 matching the random distribution of ellipses 104 generated at the step 102. [0138] In embodiments, the method 100 further comprises repeating the steps 102, 110, 124, 130 so that the substrate 12 with the textured region 20 is etched again. To elaborate, a random distribution of second ellipses 104 (different than the random distribution of the ellipses 104 from the initial step 102) is generated within an area 106 of a second plane 108. These second ellipses 104 can have a range of longest dimensions 34 that are different (e.g., smaller) than a range of longest dimensions 34 of the ellipses 104 previously generated. A second lithography mask 112 is then prepared that incorporates the second ellipses 104 either as the material 116 or the voids 118 through the material 116. A second workpiece 120 is prepared that includes the substrate 12, new lithography ink 122 disposed on the textured region 20 of the substrate 12, and the second lithography mask 112 disposed on the new lithography ink 122. The second
workpiece 120 is then exposed to a curing agent 126. The curing agent 126 transmits through the voids 118 through the material 116 of the second lithography mask 112 to cure exposed portions of the new lithography ink 122. The material 116 of the second lithography mask 112 blocks non‐exposed portions of the new lithography ink 122 from exposure to the curing agent 126. Thus, the non‐exposed portions of the new lithography ink 122 are not cured and are removed along with the second lithography mask 112. The exposed portions of the new lithography ink 122 remain on the substrate 12 as a second etching mask 128. The substrate 12 with the second etching mask 128 is then contacted with an etchant 132. Such two‐step etching processes can form the textured region 20 with three or four elevations 50‐56 from the base‐ plane 30 as explained in connection with FIGS. 8A‐8C. [0139] In embodiments, referring to FIG. 13, the step 102 of generating the random distribution of the ellipses 104 includes first distributing points 134 randomly within the area 106 of the plane 108. Each of the points 134 so randomly distributed is separated by a minimum distance 136. The points 134 can be randomly distributed pursuant to a random distribution algorithm, such as a Poisson disk distribution algorithm. Other algorithms such as maxi‐min are possible as well. However, some distribution algorithms such as maxi‐min tend to arrange the points 134 too hexagonally, which causes the resulting ellipses 104 to be very similar to one another in terms of major and minor axis lengths and eccentricities. This can lead to color artifacts. The Poisson disk distribution algorithm enforces the minimum distance 136 between the distributed points 134 but does not produce highly hexagonal arrangements. [0140] More specifically, Poisson disk sampling inserts a first point 134 into the area 106. Then the algorithm inserts a second point 134 within the area 106, placing the center at a random point within the area 106. If the placement of the second point 134 satisfies the minimum distance 136 from the first point 134, then the second point 134 stays in the area 106. The algorithm then repeats this process until no more such points 134 can be placed within the area 106 that satisfies the minimum distance 136. The result is a random distribution, but specific placement, of the points 134. [0141] The maxi‐min spacing algorithm is so named because it attempts to maximize the minimum nearest‐neighbor distance 136 of a point 134 distribution. Because it proceeds
iteratively, moving each point 134 to another place where it is further from any neighbors, the algorithm usually does not achieve a perfect hexagonal lattice. It produces a random distribution with a relatively high degree of mean hexagonality, often exceeding 90%. [0142] After the points 134 are randomly distributed within the area 106 of the plane 108, the points 134 are triangulated. By triangulating the points 134, each point 134 is made a vertex of a triangle 138. A plurality of triangles 138 are thus formed, none of which overlap. For example, the points 134 can be triangulated via a Delaunay triangulation. Other triangulation methods are possible. Some of those would likely produce a larger range of longest dimensions 34 for the surface features 26. [0143] After the points 134 have been triangulated, an ellipse 104 is drawn inside each triangle 138 of the plurality of triangles 138, resulting in a plurality of triangles 138 in the area 106 of the plane 108. For example, each ellipse 104 can be a Steiner inellipse. An inellipse is an ellipse 104 that touches the three sides of the triangle 138 in which the ellipse 104 is drawn. A Steiner inellipse is an ellipse 104 that touches the triangle 138 at the midpoint of the sides of the triangle 138 and provides the maximum area for the ellipse 104 (a Steiner inellipse occupies ^√3/9 or about 60.46% of the area of the triangle 138, regardless of the triangle dimensions). The center of Steiner inellipse is the centroid (i.e., the point where the three medians of the triangle coincide) of the triangle 138 within which it is drawn. [0144] After the plurality of ellipses 104 have been drawn, the points 134 and the triangles 138 are removed from the area 106 of the plane 108. Only the ellipses 104 that were drawn in the triangles 138 remain on the area 106 of the plane 108. In embodiments, the sizes of the ellipses 104 are scaled down so that the fill‐fraction of the ellipses 104 in the area 106 of the plane 108 is within a range of 45% to 55%. The fill‐fraction here is the percentage of the area 106 of the plane 108 that the ellipses 104 occupy. As mentioned, if Steiner inellipses are drawn, then the fill‐factor of the ellipses 104 before scaling down is about 60.46%. In embodiments, the sizes of the ellipses 104 are scaled down so that the fill‐fraction of the ellipses 104 in the area 106 of the plane 108 is 50%. Each ellipse 104 has a longest dimension 140, and to scale down the ellipses 104, the longest dimension 140 of each of the ellipses 104 can be decreased by a percentage that is identical, with the centers of the ellipses 104 remaining in the same position.
[0145] Referring now to FIG. 14, another method 200 of forming the textured region 20 of the substrate 12 of the display article 10 is herein disclosed. At a step 202, the method 200 includes generating a random distribution of first ellipses 204 within a first area 206. Similarly, at a step 208, the method 200 further includes generating a random distribution of second ellipses 210 within a second area 212. Longest dimensions 214 of first ellipses 204 are longer than longest dimensions 216 of the second ellipses 210. [0146] The steps 202, 208 thus are generally the same as the step 102 of the method 100 and can be executed in the same manner. In other words, and referring back to FIG. 13, the steps 202, 208 of generating the random distribution of the first ellipses 204 and generating the random distribution of the second ellipses 210 both separately include (i) distributing points 134 randomly within an area 106 of a 108, each of the points 134 separated by a minimum distance 136; (ii) triangulating the points 134 so that each point is made a vertices of a triangle 138 thus forming a plurality of triangles 138, and none of the triangles 138 overlap; (iii) drawing an ellipse 104 inside each triangle 138 of the plurality of triangles 138; and removing the points 134 and the triangles 138 so that only the ellipses 104 that were drawn in the triangles 138 remain on the area 106 of the plane 108. [0147] With the method 200, there is the further caveat that the minimum distance 136 separating each of the points 134 of the plane 108 for the random distribution of the first ellipses 204 is greater than the minimum distance 136 separating each of the points 134 of the plane 108 for the random distribution of the second ellipses 210. The longer minimum distance 136 for the points 134 from which the first ellipses 204 are generated results in the longest dimensions 140 of the first ellipses 204 being longer than the longest dimensions 140 of the second ellipses 210. In embodiments, the minimum distance separating each of the points 134 of the plane 108 for the random distribution of the first ellipses 204 is 15 µm, 16 µm, 17 µm, 18 µm, 19 µm, 20 µm, 30 µm, 40 µm, 50 µm, 60 µm, 70 µm, 80 µm, 90 µm, 100 µm, 110 µm, 120 µm, 130 µm, 140 µm, or within a range bounded by any two of those values (e.g., 100 µm to 120 µm, 80 µm to 130 µm, and so on). In embodiments, the minimum distance 136 separating each of the points 134 of the plane 108 for the random distribution of the second ellipses 210 is within 13 µm, 14 µm, 15 µm,
16 µm, 17 µm, 18 µm, 19 µm, 20 µm, 25 µm, 30 µm, 35 µm, 40 µm, or within any range bounded by any two of those values (e.g., 20 µm to 30 µm, 15 µm to 40 µm and so on). [0148] In embodiments, the minimum distance 136 separating each of the points 134 of the plane 108 for the random distribution of the first ellipses 204 is less than or equal 20 µm. In these embodiments, the minimum distance 136 separating each of the points 134 of the plane 108 for the random distribution of the second ellipses 210 is less than or equal 18 µm. The minimum distance 136 separating each of the points 134 of the plane 108 for the random distribution of the first ellipses 204 differs from the minimum distance 136 separating each of the points 134 of the plane 108 for the random distribution of the second ellipses 210 by a value within a range of 1 µm to 3 µm. [0149] At a step 218, the method 200 further includes forming a new area 220 that superimposes the first ellipses 204 of the first area 206 and the second ellipses 210 of the second area 212. The new area 220 is the combination of the first ellipses 204 and the second ellipses 210 within the same new area 220. The new area 220 includes free portions 222 of the first ellipses 204 and the second ellipses 210 that do not overlap. The free portions 222 would include any of the first ellipses 204 and the second ellipses 210 that do not overlap at all, and the portions of the first ellipses 204 and the second ellipses 210 that are not overlapped. The new area 220 further includes overlapping portions 224 of the first ellipses 204 and the second ellipses 210. The overlapping portions 224 are where the first ellipses 204 and the second ellipses 210 occupy the same space of the new area 220. Finally, the new area 220 further includes empty portions 226 where neither the first ellipses 204 nor the second ellipses 210 are present. The empty portions 226 are outside of the first ellipses 204 and outside of the second ellipses 210. [0150] In embodiments, the method 200 further includes removing from the new area 220 any of the second ellipses 210 that the first ellipses 204 partially but not fully overlap. Such a new area 220 would appear like FIG. 6, where all of the smaller ellipses are either fully inside the larger ellipses or fully outside of the larger ellipses. None of the smaller ellipses are partially inside and partially outside of the larger ellipses. Those smaller ellipses are removed in these embodiments. [0151] At a step 228, the method 200 further includes preparing a lithography mask 112. The lithography mask 112 includes an area 114, material 116 within the area 114, and voids 118
through the material 116. The material 116 within the area 114 is defined by (i.e., matches) the either (i) the free portions 222 of the first ellipses 204 and the second ellipses 210 that do not overlap or (ii) a combination of the overlapping portions 224 and the empty portions 226. The voids 118 through the material 116 are defined by (i.e., match) whichever of (i) and (ii) from the previous sentence does not define the material 116 within the 114. The lithography mask 112 is then incorporated into a workpiece 120 that includes the substrate 12, lithography ink 122 disposed on the substrate 12, and the lithography mask 112 disposed on the lithography ink 122. [0152] At a step 230, the method 200 further includes exposing the workpiece 120 to a curing agent 126. The curing agent 126, such as ultraviolet light, transmits through the voids 118 through the material 116 of the lithography mask 112 to cure exposed portions of the lithography ink 122. The material 116 of the lithography mask 112 blocks non‐exposed portions of the lithography ink 122 from exposure to the curing agent 126 and thus the non‐exposed portions are not cured. The non‐exposed portions are removed from the substrate 12 along with the lithography mask 112. The exposed portions of the lithography ink 122 remain on the substrate 12 as an etching mask 128. [0153] At a step 232, the method 200 further includes contacting the substrate 12 with the etching mask 128 with an etchant 132. The etchant 132 selectively etches the etching mask 128. Depending on how the lithographic mask 112 was formed, the etching mask 128 could allow the etchant 132 to etch into the substrate 12 the free portions 222 of the first ellipses 204 and the second ellipses 210 that do not overlap, and prevent the etchant 132 from etching into the substrate 12 the combination of the overlapping portions 224 and the empty portions 226. Alternatively, the etching mask 128 could allow the etchant 132 to etch into the substrate 12 the combination of the overlapping portions 224 and the empty portions 226, and prevent the etchant 132 from etching into the substrate 12 the free portions 222 of the first ellipses 204 and the second ellipses 210 that do not overlap. In any event, after the etching step 232, the etching mask 128 is removed. The substrate 12 has the textured region 20 on the primary surface 18. [0154] In embodiments, the method 100 and method 200 each include, after the aforementioned etching steps have been performed, forming the secondary surface features 82 into the one or more sections 80 of the textured region 20. This step increases the surface
roughness (Ra) at the one or more sections 34 to within the range of 5 nm to 100 nm. In embodiments, the step of forming the secondary surface features 82 into one or more sections 80 of the textured region 20 comprises contacting the one or more sections 80 of the textured region 20 of the substrate 12 with another etchant. This etchant is different than the etchant 132. In embodiments, this etchant includes acetic acid and ammonium fluoride. In embodiments, the etchant includes (in wt%): 85 to 98 acetic acid, 0.5 to 7.5 ammonium fluoride, and 0 to 11 water. The water can be deionized water. In embodiments, the etchant contacts the one or more sections 80 for a time period within a range of 15 seconds to 5 minutes. In embodiments, the etchant contacts the one or more sections 80 while the etching mask 128 remains on the substrate 12. After the period of time has concluded the substrate 12 is rinsed with deionized water and dried. The etching steps 130, 232 and the etching step to form the secondary surface features 82 can be conducted at room temperature. [0155] EXAMPLES [0156] Comparative Example 1A and Example 1B – For Comparative Example 1A, a one‐step etching process was utilized to generate a textured region of a substrate with surface features having a circular rather than elliptical perimeter. The surface features were still randomly distributed but had a constant diameter and the perimeters were circular. This is illustrated at FIG. 15A. The textured surface was illuminated. An image of the reflected light from the textured region was captured. The image is produced at FIG. 15B. The intensity of the light that the textured surface reflected as a function of scattering angle was measured by using the TSW CASITM Scatterometer made by the Scatter Works Inc (for light having a wavelength of 550 nm). A graph of the measurements is reproduced at FIG. 15C. [0157] As the image of FIG. 15B reveals, surface features having a circular perimeter, although randomly distributed, generate color artifacts when reflecting light. Color labels have been added to the FIG. 15B, in case the graph is reproduced in black and white. The reader should understand that the reflected light resembles circular rainbows that repeat moving outward from the center. The circular perimeter of the surface features causes the circular color rings. [0158] The graph of FIG. 15C also illustrates that aspect. The graph is for the specific wavelength of 550 nm, which appears greenish yellow. Intensity of the reflected light at this wavelength is
shown to peak several times as a function of scattering angle. The scattering angle at which peak intensity occurs is additionally a function of wavelength. Thus, the scattering angles at which intensity peaks occur for the wavelength of 550 nm will be different than the scattering angles at which intensity peaks occur for other wavelengths. The wavelength dependency increases as the scattering angle increases as well. This accounts for the color splitting being more obvious in the image of FIG. 15B moving away from the center of the image. Scattering angle increases as a function of increasing position away from the center of the image. [0159] For Example 1B, a one‐step etching process was utilized to generate a textured region of a substrate with surface features having an elliptical rather than a circular perimeter. The surface features were randomly distributed. This is illustrated at FIG. 16A. The textured surface was illuminated. An image of the reflected light from the textured region was captured. The image is produced at FIG. 16B. The intensity of the light that the textured surface reflected as a function of scattering angle was measured (for light having a wavelength of 550 nm). A graph of the measurements is reproduced at FIG. 16C. [0160] As the image of FIG. 16B reveals, the elliptical surface features of Example 1A generate much less color artifacts upon reflecting ambient light than the circular surface features of Example 1B. The image of FIG. 16B lacks any noticeable color‐separated rings. [0161] As the graph of FIG. 16C reveals, the major peak of reflected light intensity occurs at a lower scattering angle (i.e., closer to the center of image of FIG. 16B) than compared to FIG. 15C, and the peak is narrower than the peak in FIG. 15C. Further, the graph of FIG. 16C lacks the second and third peaks as the scattering angle increases. Thus, the elliptical surface features of Example 1B do not generate the same color‐separated rings moving outward from the center of the reflection as the circular surface features of Comparative Example 1A do. When the various wavelengths of visible light all produce an intensity peak at approximately the same scattering angle, the reflected light is white (the combination of all the wavelengths) and does not appear separated by color. [0162] Example 2A and Comparative Example 2B – For Example 2A, and in reference to FIGS. 10A, 10B, 17A, and 17B, first random distribution of points in a first area was generated having a minimum point‐to‐point distance of 13 µm. The points were triangulated and ellipses drawn and
scaled down according to the process discussed above. A second random distribution of points in a second area was generated, but this time having a minimum point‐to‐point distance of 15 µm. The points were again triangulated and ellipses drawn and scaled down. The two areas were superimposed into one area. Using a computer model, the superimposed area was assumed to be a textured region with two elevations. The first elevation, illustrated in white, is where the superimposed ellipses do not overlap. The second elevation, illustrated in black, is where no ellipses are present and where the superimposed ellipses overlap. [0163] The intensity of light (having the 550 nm wavelength) reflecting off the textured region as a function of the angle at which the light is scattered was modeled. A graph of the modeled results is reproduced at FIG. 17A. The peak intensity was at 0.3 degrees, which is desirable to tightly pack the peak intensities of reflected wavelengths to avoid color separation. The graph additional shows a peak in intensity at about 3.5 degrees. The further away from center (i.e., the higher the number of degrees) these secondary peak intensities occur, the less visible the color separation is. In this instance, at higher saturations, the color separation might be visible. That aspect is illustrated in the computer‐modeled images reproduced at FIG. 17B (top), which shows predicted reflection from the textured region as a function of saturation. [0164] For Comparative Example 2B, the same process was used with the same parameters but, instead of ellipses, circles were utilized. Computer‐modeled images of predicted reflection from the textured region as a function of saturation are reproduced at FIG. 17B (bottom). As the computer‐modeled images show, the surface features generated from overlapping circular segments reflected light having easily distinguishable color bands even at 0% saturation. The color artifacts that the surface features generated from overlapping elliptical segments were not noticeable at saturations lower than 15%, and even at saturations of 15% and 20%, color banding is not readily evident. [0165] Examples 3‐5 – Examples 3‐5 are each a summary of samples where the textured region most resembles that of FIG 2. The random but specific distribution of the surface features with an elliptical perimeter began with a random distribution of points having a minimum point‐to‐ point distance of 110 µm for Example 3, 25 µm for Example 4, and 10 µm for Example 5. Triangulation was performed and ellipses drawn and scaled so that the ellipses had a fill‐fraction
of 50%. A one‐step etching process produced surface features with an elliptical perimeter at one elevation and a surrounding portion at another elevation from a base‐plane. The one‐step etching process removed, depending on the sample, 0.11 µm to 0.16 µm of the thickness of the substrate for Example 3, 0.12 µm to 0.17 µm for Example 4, and 0.08 µm to 0.17 µm for Example 5. Various anti‐glare performance metrics were measured for all samples. More specifically, the transmission haze (“haze”), the pixel‐power deviation (“PPD”), the distinctiveness‐of‐image (“c‐ DOI”), specular reflectance (“c‐Rspec”), and corrected color shifts ΔCx_corrected and ΔCy_corrected were measured and recorded. The results are set forth in Table 1 below. “Min Rspec(λ)” and “max Rspec(λ)” in the tables below refer to far field first surface specular reflectance spectra as measured with a camera with a 2 degree aperture illuminating the sample at a 6 degree angle of incidence. These values are different from the optically coupled Rspec (peak gloss) measurement made with a Rhopoint goniometer (“GU” means Gloss Units). The minimum and maximum are over the visible wavelength range, 400 – 700 nm.
As mentioned above, Example 3 with the larger surface features produced little measured reflected color artifacts and low transmission haze but had generated a relatively high pixel power deviation. The smaller surface features generated less pixel power deviation but at the expense of increased haze and reflected color artifacts.
[0166] Examples 6‐9 – These examples are each a summary of samples where the textured region most resembles that of FIG 6, with larger surface features having an elliptical perimeter introduced in a first etching step and then smaller surface features added in a second etching step. The larger surface features for each example began with a random distribution of points having a minimum point‐to‐point distance of 110 µm. Triangulation was performed and ellipses drawn and scaled so that the ellipses had a fill‐fraction of 50. The first etching step removed, depending on the sample, 0.26 µm to 0.28 µm of the thickness of the substrate for Example 6, 0.13 µm to 0.21 µm for Example 7, 0.13 µm to 0.19 µm for Example 8, and 0.13 µm to 0.17 µm for Example 9. For Example 6, smaller surface features having an elliptical perimeter and a fill‐ fraction of 50%, generated from random distribution algorithm using a minimum point‐to‐point distance of 25 µm, were added to the textured region in a second etching step. For Example 7, smaller surface features having a circular perimeter, generated from random distribution algorithm using a minimum center‐to‐center distance of 15 µm to 25 µm, were added to the textured region in a second etching step. For Example 8, smaller surface features having a circular perimeter, generated from random distribution algorithm using a minimum center‐to‐center distance of 20 µm to 25 µm, were added to the textured region in a second etching step. For Example 9, secondary surface features to impart surface roughness (Ra) within a range of 5 nm to 100 nm were added to the textured region in an etching step. The same anti‐glare performance metrics were measured for all samples, and the results are set forth in Table 2 below.
The incorporation of the smaller surfaces generally resulted in very low reflected color artifacts values. Examples 8 and 9 in particular had measured reflected color artifact values of under 0.3, imperceptible by human eyes. [0167] Examples 10‐13 – These examples are each a summary of samples where the textured region most resembles that of FIG 9A, where a first area of larger elliptical perimeters was superimposed with a second area of smaller elliptical perimeters. Then a single etching step produced a textured region with a first elevation including the non‐overlapping elliptical segments and a second elevation including the overlapping elliptical segments and areas outside of any elliptical perimeter. For Examples 11 and 12, the smaller elliptical perimeters that only partially overlapped the larger elliptical perimeters were removed from the design. [0168] The larger elliptical perimeters for each example began with a random distribution of points having a minimum point‐to‐point distance of 105 µm, except for Example 13, where the minimum point‐to‐point distance was 15 µm. Triangulation was performed and ellipses drawn and scaled so that the ellipses had a fill‐fraction of 50. The minimum point‐to‐point distances utilized to generate the smaller elliptical perimeters of Examples 10‐12 were 25 µm and 13 µm for Example 13. Triangulation was performed and ellipses drawn and scaled so that the ellipses had fill‐fractions of 20 for Examples 10‐12 and 50 Example 13. [0169] A single etching step formed the textured region, removing, depending on the sample, 0.12 µm to 0.17 µm of the thickness of the substrate for Example 10, 0.06 µm to 0.20 µm for Example 11, 0.16 µm for Example 12, and 0.14 µm to 0.16 µm for Example 13. With Example 12, secondary surface features to impart surface roughness (Ra) within a range of 5 nm to 100 nm were added to the textured region in an etching step. The same anti‐glare performance metrics were measured for all samples, and the results are set forth in Table 3 below.
Example 10 generated very good results, including acceptable haze values, a low pixel power deviation, very low specular reflectance, and reflected color artifacts well under 0.3 and considered to be imperceptible. [0170] Examples 14A‐14O – For Examples 14A‐14O, a spacing distribution algorithm was utilized to randomly but specifically place points within an area. Each of the points were to be separated by a minimum distance of 105 µm. The points were then triangulated, an inellipse drawn in each triangle, and then the points and triangles were removed. The longest dimension of the ellipses now remaining in the area were scaled down so that the ellipses occupied 50 percent of the area. The placement of the ellipses was then transferred to a lithography mask. The lithography mask was used to form an etching mask on the primary surface of a glass substrate. Each substrate was then etched with the etching mask on the substrate. The etchant utilized had a composition of 0.15wt% hydrofluoric acid and 1wt% nitric acid. The etchant contacted the primary surface with the etching mask for a period of time set forth in Table 4 immediately below that varied among the samples. The etchant formed surface features having an elliptical perimeter set into a surrounding portion. The depth of the surface features varied, and the depth for each sample is set forth below.
[0171] After removal of the etching mask, the samples of 14M‐14O were then subjected to a second etching step to form secondary surface features at the primary surface. The second etching step used an etchant with a composition of 92 wt% acetic acid, 2 wt% ammonium fluoride, and 6 wt% water (deionized). The etchant contacted the substrate for a time period of 120 seconds. The secondary surface features so formed imparted a surface roughness (Ra) of ~ 28nm to the textured region at the primary surface. [0172] The pixel power deviation, distinctness‐of‐image, specular reflection, and transmission haze were measured for the sample of each of Examples 14A‐14O. The measured results are set forth in the graphs of FIGS. 18A‐18D, which plot the measured value as a function of the depth of the surface features with the elliptical perimeter. Analysis of the graphs reveal that the secondary surface features to impart surface roughness of Examples 14M‐14O resulted in a lower
pixel power deviation and specular reflectance compared to when no such secondary surface features were included in Examples 14A‐14L. However, the secondary surface features to impart surface roughness of Examples 14M‐14O resulted in a higher distinctness‐of‐image and transmission haze compared to when no such secondary surface features were included in Examples 14A‐14L. In general, the introducing of the secondary surface features to the surface features can be either increase or decrease the distinctness‐of‐image, which depends on the design of the surface features. [0173] Example 15A‐15C –Examples 15A and 15B are two different sets of samples, each with surface features having an elliptical perimeter, just as in Examples 14A‐14O. The difference was that for the samples of Example 15A, the etching mask used while forming the surface features was kept on the substrate while the another etching step was performed to generate the secondary surface features. For the samples of Example 15B, the etching mask was removed before the etching step was performed to generate the secondary surface features. Thus, in the samples of Example 15A, the secondary surface features and the added surface roughness were formed only on surfaces provided by the elliptical surface features and not the surrounding portion. In contrast, with the samples of Example 15B, the secondary surface features and the added surface roughness were formed on the entire textured region including both the surrounding portion and the surfaces provided by the elliptical surface features. [0174] A scanning electron microscope captured images of a sample from both Example 15A and Example 15B. The images are reproduced at FIG. 19A. The images on the left show the surface features with the elliptical perimeters set into the surrounding portion. The images in the middle show the secondary surface features. The images on the right show the etching depth of the secondary surface features. [0175] The pixel power deviation, transparency haze, and specular reflectance of samples from both Examples 15A and 15B were measured. A Rhopoint instrument was utilized to determine specular reflectance. The graphs reproduced at FIGS. 19B‐19D set forth the measured data. Analysis of the graphs reveal that the samples of Example 15B, where the etching mask was removed before the second etching step to impart secondary surface features throughout the entire textured region, resulted in a lower pixel power deviation but higher transmission haze
compared to the samples of Example 15A, where the etching mask was maintained during the second etching step and thus the secondary surface features were imparted only to the surfaces provided by the elliptical surface features. [0176] The Rhopoint instrument utilized to measure specular reflectance did not measure a difference between the samples of Examples 15A and 15B. However, the device could measure differences in specular reflectance when a 6 degree angle of incidence for the light to be reflected and a 2 degree aperture to measure the specular reflectance. The graph reproduced at FIG. 19E shows the measured data for samples of Examples 15A and 15B, as well as for a sample (Example 15C) where only the elliptical surface features were present and did not include the secondary surface features to impart surface roughness. Analysis of the graph of FIG. 19E reveals that the presence of the secondary surface features in Examples 15A and 15B reduced specular reflectance compared to when the secondary surface features were absent in Example 15C. The difference in specular reflectance between Examples 15A and 15B is wavelength dependent. [0177] Example 16 – For Example 16, a sample was prepared similar to the samples Examples 14M‐14O, where surface features with an elliptical perimeter are set into a surrounding portion in a first etching step forming textured region, and then secondary surface features are etched throughout the entire textured region to increase surface roughness. The sample so prepared was then analyzed with a white light interferometer to measure the three dimensional profile of the textured region. FIG. 20A illustrates the three dimensional profile that was measured. The top half illustrates relative elevation differences between elliptical surface features and the surrounding portion. The bottom half illustrates the topography of the secondary surface features, with the topography of the secondary surface features added to the surfaces that the elliptical surface features are provided illustrated at the left, and the topography of the secondary surface features added to the surrounding portion illustrated at the right. The three dimensional profile of the secondary features within the elliptical surface features is measurably different than the three dimensional profile of the secondary features at the surrounding portion – with the surrounding portion showing deeper secondary features. [0178] An atomic force microscope was utilized to image and determine the surface roughness (Ra) imparted by the secondary surface features at both (i) a surface provided by an elliptical
surface feature and (ii) at the surrounding portion. The images are reproduced at FIG. 20B. The image on the left is of the secondary surface features at the surface provided by the elliptical surface feature, and shows a surface roughness (Ra) of 15.3 nm. The image on the right is of the secondary surface features at the surrounding portion, and shows a surface roughness (Ra) of 33.5 nm. The image on the right and the higher surface roughness (Ra) value at the surrounding portion matches the topography data illustrated at FIG. 20A. The surrounding portion was covered by the etching mask during the formation of the elliptical surface features and thus had not been contacted with an etchant, unlike the elliptical surface features which were created by the first etching step. Thus, it is believed that the surrounding portion, previously untouched by an etchant, was more sensitive to the second etching step to impart the secondary surface features.
Claims
CLAIM(S) What is claimed is: 1. A substrate for a display article, the substrate comprising: a primary surface; and a textured region on at least a portion of the primary surface, the textured region comprising surface features that reflect a random distribution, each of the surface features comprising a perimeter that is parallel to a base‐plane extending through a thickness of the substrate below the textured region, wherein the perimeter is elliptical. 2. The substrate of claim 1, wherein the textured region further comprises (i) one or more higher surfaces residing at a higher mean elevation from the base‐plane and (ii) one or more lower surfaces residing at a lower mean elevation from the base‐plane that is closer to the base‐plane than the higher mean elevation. 3. The substrate of claim 2, wherein the textured region further comprises a surrounding portion, into which the surface features are set, or from which the surface features project; the surrounding portion provides either (i) the one or more higher surfaces or (ii) the one or more lower surfaces; and the surface features provide the other of (i) the one or more higher surfaces and (ii) the one or more lower surfaces, whichever the surrounding portion does not provide. 4. The substrate of any one of claims 2‐3, wherein the higher mean elevation differs from the lower mean elevation by a distance within a range of 0.05 µm to 0.70 µm. 5. The substrate of any one of claims 1‐4, wherein the perimeter of each of the surface features comprises a longest dimension parallel to the base‐plane; and
the longest dimensions of the perimeters of the surface features are not all parallel to each other. 6. The substrate of claim 5, wherein the longest dimension of the perimeter of each of the surface features is within a range of 5 µm to 150 µm. 7. The substrate of any one of claims 1‐6, wherein the surface features comprise a fill‐fraction that is within a range of 40% to 60%. 8. The substrate of claim 1, wherein the surface features comprise larger surface features and smaller surface features; the perimeters of the larger surface features comprise a range of longest dimensions parallel to the base‐plane; the perimeters of the smaller surface features comprise another range of longest dimensions parallel to the base‐plane; and the longest dimensions of the range of longest dimensions of the larger surface features are longer than the longest dimensions of the range of longest dimensions of the smaller surface features. 9. The substrate of claim 8, wherein the perimeters of the larger surface features totally surround the perimeters of some of the smaller surface features; and the perimeters of some the smaller surface features reside entirely outside of the perimeters. 10. The substrate of claim 8, wherein the perimeter of at least one of the smaller surface features partially overlaps with the perimeter of one of the larger surface features, such that (i) part of the perimeter of the smaller
surface features is inside the perimeter of the larger surface feature and (ii) part of the perimeter of the smaller surface features is outside the perimeter of the larger surface feature. 11. The substrate of any one of claims 8‐10, wherein the textured region further comprises (i) one or more higher surfaces residing at a higher mean elevation from the base‐plane, (ii) one or more lower surfaces residing at a lower mean elevation from the base‐plane that is closer to the base‐plane than the higher mean elevation, and (iii) a surrounding portion, into which the larger surface features are set, or from which the larger surface features project. 12. The substrate of claim 11, wherein the larger surface features project from the surrounding portion, some of the smaller surface features project from the surrounding portion, and the remaining smaller surface features, those that do not project from the surrounding portion, are set into the larger surface features; the larger surface features and smaller surface features that project from the surrounding portion provide the one or more higher surfaces residing at the higher mean elevation; and the surrounding portion and the smaller surface features that are set into larger surface features provide the one or more lower surfaces residing at the lower mean elevation. 13. The substrate of claim 11, wherein the larger surface features are set into the surrounding portion, some of the smaller surface features are set into the surrounding portion, and the remaining smaller surface features, those that are not set into the surrounding portion, project from the larger surface features; the larger surface features and the smaller surface features that are set into the surrounding portion provide the one or more lower surfaces residing at the lower mean elevation; and the surrounding portion and the smaller surface features that project from the larger surface features provide the one or more higher surfaces residing at the higher mean elevation.
14. The substrate of claim 8, wherein the textured region further comprises (i) one or more higher surfaces residing at a higher mean elevation from the base‐plane, (ii) one or more lower surfaces residing at a lower mean elevation from the base‐plane that is closer to the base‐plane than the higher mean elevation, (iii) one or more intermediate surfaces residing at one or two intermediate mean elevations from the base‐plane, wherein the one or two intermediate mean elevations are disposed between the higher mean elevation and the lower mean elevation, and (iv) a surrounding portion, into which the larger surface features are set, or from which the larger surface features project. 15. The substrate of claim 14, wherein the larger surface features provide at least a portion of the one or more higher surfaces residing at the higher mean elevation. 16. The substrate of claim 14, wherein the larger surface features provide at least a portion of the one or more lower surfaces disposed at the lower mean elevation. 17. The substrate of any one of claims 1‐16, wherein the textured region further comprises one or more sections comprising secondary surface features imparting a surface roughness (Ra) within a range of 5 nm to 100 nm. 18. The substrate of any one of claims 1‐17, wherein the textured region exhibits a transmission haze within a range of 0.5% to 5.0%; the textured region exhibits a pixel power deviation within a range of 1.0% to 3.0%; the textured region exhibits a distinctness‐of‐image within a range of 5% to 70%; the textured region exhibits a specular reflectance within a range of 4 GU to 40 GU; and the textured region exhibits corrected color shifts Δ Cx _corrected and Δ Cy _corrected that are each respectively within a range of 0.03 to 0.6.
19. The substrate of any one of claims 1‐18, wherein the substrate comprises a glass or glass‐ceramic. 20. A substrate for a display article, the substrate comprising: a primary surface; a base‐plane extending through the substrate below the primary surface; and a textured region at the primary surface, the textured region comprising (i) one or more higher surfaces residing at a higher mean elevation from the base‐plane, (ii) one or more lower surfaces residing at a lower mean elevation from the base‐plane, (iii) a first portion providing either the one or more higher surfaces or the one or more lower surfaces, and (iv) a second portion providing the other of the one or more higher surfaces and the one or more higher surfaces, whichever the first portion is not providing; wherein, elliptical perimeters which lie in planes parallel to the base‐plane and reflect a random distribution, define the first portion except for overlapping portions of the elliptical perimeters, where the overlapping portions define in part the second portion. 21. The substrate of claim 20, wherein in addition to the overlapping portions of the elliptical perimeters, the second portion of the textured region further comprises any part of the textured region that is not the first portion. 22. The substrate of any one of claims 20‐21, wherein each of the elliptical perimeters comprises a longest dimension parallel to the base‐plane; and the longest dimensions of the elliptical perimeters are not all parallel with each other. 23. The substrate of any one of claims 20‐22, wherein the higher mean elevation differs from the second elevation by a distance within a range of 0.02 µm to 0.70 µm.
24. The substrate of any one of claims 20‐23, wherein the elliptical perimeters comprise larger elliptical perimeters and smaller elliptical perimeters, which are smaller than the first elliptical perimeters; and the first portion of the textured region is bounded by (i) the smaller elliptical perimeters that do not overlap or intersect with the larger elliptical perimeters, (ii) portions of the smaller elliptical perimeters outside of the first elliptical perimeters that partially overlap with the larger elliptical perimeters, and (iii) portions of the larger elliptical perimeters that do not overlap with the smaller elliptical perimeters. 25. The substrate of claim 24, wherein at least some of the larger elliptical perimeters entirely encompass more than one of the smaller elliptical perimeters. 26. The substrate of any one of claims 24‐25, wherein a fill‐fraction of the larger elliptical perimeters is within a range of 40% to 60%; and a fill‐fraction of the smaller elliptical perimeters is within a range of 10% to 30%. 27. The substrate of any one of claims 20‐26, wherein the textured region further comprises one or more sections comprising secondary surface features imparting a surface roughness (Ra) within a range of 5 nm to 100 nm. 28. The substrate of any one of claims 20‐27, wherein the textured region exhibits a transmission haze within a range of 0.3% to 8.0%; the textured region exhibits a pixel power deviation within a range of 0.7% to 3.5%; the textured region exhibits a distinctness‐of‐image within a range of 25% to 100%; the textured region exhibits a specular reflectance within a range of 5 GU to 30 GU; and the textured region exhibits corrected color shifts Δ Cx _corrected and Δ Cy _corrected that are each respectively within a range of 0.00 to 0.50.
29. The substrate of any one of claims 20‐28, wherein the substrate comprises a glass or glass‐ceramic. 30. A method of forming a textured region of a substrate of a display article, the method comprising: generating a random distribution of ellipses within an area; preparing a lithography mask comprising (a) an area matching the area of the plane; (b) material throughout the matching area; and (c) voids through the material, wherein the random distribution of the ellipses define either (i) the material throughout the matching area or (ii) the voids through the material; exposing a workpiece comprising a substrate, a lithography ink disposed on the substrate, and the lithography mask disposed on the lithography ink, to a curing agent that transmits through the voids through the material of the lithography mask to cure exposed portions of the lithography ink, wherein non‐exposed portions of the lithography ink blocked from exposure to the curing agent are not cured and removed along with the lithography mask, and the exposed portions of the lithography ink remain on the substrate as an etching mask; and contacting the substrate with the etching mask with an etchant, thus forming the textured region. 31. The method of claim 30 further comprising: generating a random distribution of second ellipses within a second area; preparing a second lithography mask comprising (a) a second area matching the area of the second plane; (b) material throughout the matching second area; and (c) voids through the material, wherein the random distribution of the second ellipses define either (i) the material throughout the matching second area or (ii) the voids through the material; exposing a second workpiece comprising the substrate, new lithography ink disposed on the textured region of the substrate, and the second lithography mask disposed on the new lithography ink, to a curing agent that transmits through the voids through the material of the
second lithography mask to cure exposed portions of the new lithography ink, wherein non‐ exposed portions of the new lithography ink blocked from exposure to the curing agent are not cured and removed along with the second lithography mask, and the exposed portions of the new lithography ink remain on the substrate as a second etching mask; and contacting the substrate with the second etching mask with an etchant. 32. The method of any one of claims 30‐31, wherein generating the random distribution of the ellipses comprises: distributing points randomly within an area; triangulating the points so that each point is made a vertex of a triangle thus forming a plurality of triangles, and none of the triangles overlap; drawing an ellipse inside each triangle of the plurality of triangles; and removing the points and the triangles so that only the ellipses that were drawn in the triangles remain on the area. 33. The method of claim 32, wherein the points randomly distributed within the area are separated by a minimum distance. 34. The method of any one of claims 30‐33 further comprising: forming secondary surface features into one or more sections of the textured region, thereby increasing the surface roughness (Ra) of at the one or more sections to within a range of 5 nm to 100 nm. 35. A method of forming a textured region of a substrate of a display article, the method comprising: generating a random distribution of first ellipses within a first area; generating a random distribution of second ellipses within a second area, wherein the first ellipses comprise longest dimensions that are on average longer than longest dimensions of the second ellipses on average;
forming a new area that superimposes the first ellipses of the first area and the second ellipses of the second area, the new area comprising (a) free portions of the first ellipses and the second ellipses that do not overlap; (b) overlapping portions of the first ellipses and the second ellipses; and (c) empty portions where neither the first ellipses nor the second ellipses are present; preparing a lithography mask comprising (a) an area; (b) material within the area defined by either (i) the free portions or (ii) a combination of the overlapping portions and the empty portions; and (c) voids through the material defined by whichever of (i) the free portions and (ii) the combination of the overlapping portions and the empty portions do not define the material within the area; exposing a workpiece comprising a substrate, a lithography ink disposed on the substrate, and the lithography mask disposed on the lithography ink, to a curing agent that transmits through the voids through the material of the lithography mask to cure exposed portions of the lithography ink, wherein non‐exposed portions of the lithography ink blocked from exposure to the curing agent are not cured and removed along with the lithography mask, and the exposed portions of the lithography ink remain on the substrate as an etching mask; and contacting the substrate with the etching mask with an etchant. 36. The method of claim 35 further comprising: before preparing the lithography mask, removing from the new area any of the second ellipses that the first ellipses partially but not fully overlap. 37. The method of any one of claims 35‐37, wherein generating the random distribution of the first ellipses and generating the random distribution of the second ellipses both separately comprise: distributing points randomly within an area, each of the points separated by a minimum distance; triangulating the points so that each point is made a vertex of a triangle thus forming a plurality of triangles, and none of the triangles overlap;
drawing an ellipse inside each triangle of the plurality of triangles; and removing the points and the triangles so that only the ellipses that were drawn in the triangles remain on the area. 38. The method of claim 37, wherein the minimum distance separating each of the points of the area for the random distribution of the first ellipses is within a range of 80 µm to 130 µm; and the minimum distance separating each of the points of the area for the random distribution of the second ellipses is within a range of 15 µm to 40 µm. 39. The method of claim 37, wherein the minimum distance separating each of the points of the area for the random distribution of the first ellipses is less than or equal 20 µm; the minimum distance separating each of the points of the area for the random distribution of the second ellipses is less than or equal 18 µm; and the minimum distance separating each of the points of the area for the random distribution of the first ellipses differs from the minimum distance separating each of the points of the plane for the random distribution of the second ellipses by a value within a range of 1 µm to 3 µm. 40. The method of any one of claims 35‐39 further comprising: forming secondary surface features into one or more sections of the textured region, thereby increasing the surface roughness (Ra) of at the one or more sections to within a range of 5 nm to 100 nm.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11940593B2 (en) | 2020-07-09 | 2024-03-26 | Corning Incorporated | Display articles with diffractive, antiglare surfaces and methods of making the same |
| US12019209B2 (en) | 2018-01-09 | 2024-06-25 | Corning Incorporated | Coated articles with light-altering features and methods for the production thereof |
| US12195384B2 (en) | 2013-05-07 | 2025-01-14 | Corning Incorporated | Scratch-resistant laminates with retained optical properties |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111204989A (en) * | 2018-11-22 | 2020-05-29 | 康宁股份有限公司 | Low warpage reinforced article and asymmetric ion exchange method for making same |
| WO2022115553A1 (en) * | 2020-11-30 | 2022-06-02 | Corning Incorporated | Textured glass-based articles with multiple haze levels and processes of producing the same |
| CN117836248A (en) * | 2021-07-06 | 2024-04-05 | 康宁公司 | Anti-glare substrate for display articles having a textured region including one or more surfaces at two, three or four elevations and surface features providing at least a portion of one or more surfaces and methods of making the same |
| EP4499581A1 (en) * | 2022-03-30 | 2025-02-05 | Corning Incorporated | Multi-level structured surface for anti-glare application and associated methods |
| US20240028070A1 (en) * | 2022-07-22 | 2024-01-25 | Apple Inc. | Coatings for Textured Glass |
| WO2024091468A1 (en) * | 2022-10-28 | 2024-05-02 | Corning Incorporated | Articles with anti-glare surfaces exhibiting low sparkle with minimal color artifacts |
| CN120153291A (en) * | 2022-10-28 | 2025-06-13 | 康宁股份有限公司 | Articles having an anti-glare surface with an inclined transition surface and related methods |
| WO2024118373A1 (en) * | 2022-11-30 | 2024-06-06 | Corning Incorporated | Textured articles and methods for making the same |
| US20240191099A1 (en) | 2022-12-08 | 2024-06-13 | Corning Incorporated | Coated articles with an anti-fingerprint coating or surface-modifying layer and methods of making the same |
| WO2024196577A1 (en) * | 2023-03-17 | 2024-09-26 | Corning Incorporated | Screen protectors tailored for electronic device displays |
| KR20260048290A (en) * | 2023-08-03 | 2026-04-09 | 코닝 인코포레이티드 | Glare-resistant surface with wear resistance |
| WO2025136775A1 (en) * | 2023-12-21 | 2025-06-26 | Corning Incorporated | Antiglare articles |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100177398A1 (en) * | 2009-01-09 | 2010-07-15 | Sony Corporation | Optical element and method for making the same, master and method for making the same, and display apparatus |
| US20150174625A1 (en) * | 2011-11-30 | 2015-06-25 | Corning Incorporated | Articles with monolithic, structured surfaces and methods for making and using same |
| US9411180B2 (en) | 2011-02-28 | 2016-08-09 | Corning Incorporated | Apparatus and method for determining sparkle |
| EP3178796A1 (en) * | 2010-04-30 | 2017-06-14 | Corning Incorporated | Glass article comprising anti-glare surface |
| US20180128957A1 (en) * | 2015-05-15 | 2018-05-10 | Corning Incorporated | Glass article comprising light extraction features and methods for making the same |
| WO2020013012A1 (en) * | 2018-07-09 | 2020-01-16 | 日本板硝子株式会社 | Glass plate suitable for image display device |
Family Cites Families (880)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD31977S (en) | 1899-11-16 | 1899-12-12 | John Schmitt | Design for a housing for gear-wheels |
| US3067021A (en) | 1955-12-08 | 1962-12-04 | Wheelabrator Corp | Subbing surfaces |
| US3150032A (en) | 1956-06-25 | 1964-09-22 | Rubenstein David | Abuse resistant articles of manufacture and method of making |
| US3413058A (en) | 1964-07-09 | 1968-11-26 | Minnesota Mining & Mfg | Reflex-reflecting articles |
| US3934961A (en) | 1970-10-29 | 1976-01-27 | Canon Kabushiki Kaisha | Three layer anti-reflection film |
| JPS5314227B2 (en) | 1973-06-18 | 1978-05-16 | ||
| GB1517585A (en) | 1974-11-13 | 1978-07-12 | Mobay Chemical Corp | Process for the production of a polyamino-polyphenyl-(poly)-methylene polyamine |
| US3989350A (en) | 1975-09-12 | 1976-11-02 | Bell Telephone Laboratories, Incorporated | Multimode optical fiber |
| US4033667A (en) | 1975-09-12 | 1977-07-05 | Bell Telephone Laboratories, Incorporated | Multimode optical fiber |
| CA1077787A (en) | 1975-11-21 | 1980-05-20 | National Aeronautics And Space Administration | Abrasion resistant coatings for plastic surfaces |
| US4423925A (en) | 1979-07-13 | 1984-01-03 | Times Fiber Communications, Inc. | Graded optical waveguides |
| US4298366A (en) | 1979-07-13 | 1981-11-03 | Times Fiber Communications, Inc. | Graded start rods for the production of optical waveguides |
| US4310595A (en) | 1980-10-31 | 1982-01-12 | Corning Glass Works | Peraluminious nepheline/kalsilite glass-ceramics |
| US4504519A (en) | 1981-10-21 | 1985-03-12 | Rca Corporation | Diamond-like film and process for producing same |
| JPS58127463A (en) | 1982-01-25 | 1983-07-29 | Nippon Telegr & Teleph Corp <Ntt> | Close contact type image sensor |
| DE3230388A1 (en) | 1982-08-14 | 1984-02-16 | Karl Schmidt Gmbh, 7107 Neckarsulm | METHOD FOR CONNECTING AN INLET POWDERED INTO A COMPONENT MOLDED IN A LIGHT METAL MATERIAL FOR INTERNAL COMBUSTION ENGINE |
| DE3248103C1 (en) | 1982-12-24 | 1987-11-12 | W.C. Heraeus Gmbh, 6450 Hanau | Crucible for pulling single crystals |
| JPS59138440A (en) | 1983-01-27 | 1984-08-08 | 豊田合成株式会社 | Resin shape with ceramics coating layer |
| NL8301824A (en) | 1983-05-24 | 1984-12-17 | Philips Nv | OPTICAL ELEMENT COMPRISING A TRANSPARENT SUBSTRATE AND ANTI-REFLECTIVE CLOTHING FOR THE WAVE LENGTH AREA IN THE NEAR INFRARED. |
| JPS60119114A (en) | 1983-11-30 | 1985-06-26 | Murata Mfg Co Ltd | Surface wave device |
| DE3422289A1 (en) | 1984-06-15 | 1985-12-19 | Hoechst Ag, 6230 Frankfurt | METHOD FOR IMPROVING THE USE PROPERTIES OF TUFTED FLOORING |
| EP0166363B1 (en) | 1984-06-26 | 1991-08-07 | Asahi Glass Company Ltd. | Low reflectance transparent material having antisoiling properties |
| US4705356A (en) | 1984-07-13 | 1987-11-10 | Optical Coating Laboratory, Inc. | Thin film optical variable article having substantial color shift with angle and method |
| US5300951A (en) | 1985-11-28 | 1994-04-05 | Kabushiki Kaisha Toshiba | Member coated with ceramic material and method of manufacturing the same |
| US4995684A (en) | 1986-06-18 | 1991-02-26 | Raytheon Company | Impact resistant and tempered optical elements |
| US5071206A (en) | 1986-06-30 | 1991-12-10 | Southwall Technologies Inc. | Color-corrected heat-reflecting composite films and glazing products containing the same |
| US5332888A (en) | 1986-08-20 | 1994-07-26 | Libbey-Owens-Ford Co. | Sputtered multi-layer color compatible solar control coating |
| LU86722A1 (en) | 1986-12-23 | 1988-07-14 | Glaverbel | SHEET OF GLASS MATERIAL CARRYING A SERIOUS DRAWING AND METHOD FOR ENGRAVING A DRAWING ON A SUBSTRATE OF GLASS MATERIAL |
| JPS63238260A (en) | 1987-03-25 | 1988-10-04 | Unitika Ltd | Formation of heat ray reflecting film |
| JPS63265846A (en) | 1987-04-22 | 1988-11-02 | Nippon Sheet Glass Co Ltd | Bent heat ray reflection glass and production thereof |
| JPH0735267B2 (en) | 1987-04-22 | 1995-04-19 | 日本板硝子株式会社 | Method for manufacturing bent heat ray reflective glass |
| US4945282A (en) | 1987-12-10 | 1990-07-31 | Hitachi, Ltd. | Image display panel having antistatic film with transparent and electroconductive properties and process for processing same |
| US4851095A (en) | 1988-02-08 | 1989-07-25 | Optical Coating Laboratory, Inc. | Magnetron sputtering apparatus and process |
| US4946923A (en) | 1988-02-18 | 1990-08-07 | Mitsui Toatsu Chemicals, Inc. | S-alkyl thiocarbamate base resin, plastic lens comprising the resin, and process for making the lens |
| US5605609A (en) | 1988-03-03 | 1997-02-25 | Asahi Glass Company Ltd. | Method for forming low refractive index film comprising silicon dioxide |
| US4826734A (en) | 1988-03-03 | 1989-05-02 | Union Carbide Corporation | Tungsten carbide-cobalt coatings for various articles |
| US4896928A (en) | 1988-08-29 | 1990-01-30 | Coherent, Inc. | Chromatically invariant multilayer dielectric thin film coating |
| JPH02156448A (en) | 1988-12-08 | 1990-06-15 | Daicel Chem Ind Ltd | Magneto-optical recording medium |
| JPH0277434A (en) | 1989-05-29 | 1990-03-16 | Toray Ind Inc | Molding containing transparent coating layer |
| CA2017471C (en) | 1989-07-19 | 2000-10-24 | Matthew Eric Krisl | Optical interference coatings and lamps using same |
| USD326303S (en) | 1989-07-25 | 1992-05-19 | Ray Cook Company | Golf putter head |
| KR0151706B1 (en) | 1989-09-29 | 1998-12-15 | 나가이 야따로 | Refractive distribution type optical transmitter and its manufacturing method |
| US5178911A (en) | 1989-11-30 | 1993-01-12 | The President And Fellows Of Harvard College | Process for chemical vapor deposition of main group metal nitrides |
| US5637353A (en) | 1990-09-27 | 1997-06-10 | Monsanto Company | Abrasion wear resistant coated substrate product |
| US5268217A (en) | 1990-09-27 | 1993-12-07 | Diamonex, Incorporated | Abrasion wear resistant coated substrate product |
| US5527596A (en) | 1990-09-27 | 1996-06-18 | Diamonex, Incorporated | Abrasion wear resistant coated substrate product |
| JPH04250834A (en) | 1991-01-07 | 1992-09-07 | Fuji Photo Film Co Ltd | Precision filter membrane |
| US5535056A (en) | 1991-05-15 | 1996-07-09 | Donnelly Corporation | Method for making elemental semiconductor mirror for vehicles |
| DE4128547A1 (en) | 1991-08-28 | 1993-03-04 | Leybold Ag | METHOD AND DEVICE FOR THE PRODUCTION OF A RE-MIRRORING LAYER ON LENSES |
| TW266301B (en) | 1991-09-19 | 1995-12-21 | Philips Nv | |
| DE4131517A1 (en) * | 1991-09-21 | 1993-03-25 | Hoechst Ag | METHOD FOR PRODUCING REFLECTED SURFACES |
| JP2668472B2 (en) | 1991-10-17 | 1997-10-27 | 信越化学工業株式会社 | Fluorine-containing organosilicon compound |
| DE69219300T2 (en) | 1991-12-26 | 1997-08-14 | Asahi Glass Co Ltd | A transparent film coated substrate |
| US5234769A (en) | 1992-04-16 | 1993-08-10 | Deposition Sciences, Inc. | Wear resistant transparent dielectric coatings |
| US5342681A (en) | 1992-08-28 | 1994-08-30 | Texas Instruments Incorporated | Absorbing, low reflecting coating for visible and infrared light |
| EP0592986B1 (en) | 1992-10-12 | 1998-07-08 | Sumitomo Electric Industries, Limited | Ultra-thin film laminate |
| FR2697242B1 (en) | 1992-10-22 | 1994-12-16 | Saint Gobain Vitrage Int | Chemical toughened glazing. |
| US5557313A (en) | 1992-11-12 | 1996-09-17 | Tdk Corporation | Wear-resistant protective film for thermal head and method of producing the same |
| JP2875945B2 (en) | 1993-01-28 | 1999-03-31 | アプライド マテリアルズ インコーポレイテッド | Method of depositing silicon nitride thin film on large area glass substrate at high deposition rate by CVD |
| JP2974879B2 (en) | 1993-04-07 | 1999-11-10 | アルプス電気株式会社 | Synthesis method by plasma CVD |
| US5549953A (en) | 1993-04-29 | 1996-08-27 | National Research Council Of Canada | Optical recording media having optically-variable security properties |
| BE1007662A3 (en) | 1993-10-18 | 1995-09-05 | Philips Electronics Nv | A picture display device having a display screen having an antistatic and light absorbing coating layer. |
| US5737472A (en) | 1993-12-17 | 1998-04-07 | Audio-Images S.A.R.L. | Optical fiber with multiple point lateral illumination |
| GB9400259D0 (en) * | 1994-01-07 | 1994-03-02 | Pilkington Plc | Substrate for a magnetic disc and manufacture thereof |
| US5909314A (en) | 1994-02-15 | 1999-06-01 | Dai Nippon Printing Co., Ltd. | Optical functional materials and process for producing the same |
| US5618619A (en) | 1994-03-03 | 1997-04-08 | Monsanto Company | Highly abrasion-resistant, flexible coatings for soft substrates |
| US5846649A (en) | 1994-03-03 | 1998-12-08 | Monsanto Company | Highly durable and abrasion-resistant dielectric coatings for lenses |
| JP3374299B2 (en) | 1994-04-20 | 2003-02-04 | 大日本印刷株式会社 | Anti-glare film |
| JPH07331115A (en) | 1994-06-10 | 1995-12-19 | Toyo Ink Mfg Co Ltd | Composition for antireflection film |
| JPH0864848A (en) | 1994-08-23 | 1996-03-08 | Canon Inc | Photoelectric conversion device, antireflection film, and electrode substrate |
| DE4430363A1 (en) | 1994-08-26 | 1996-02-29 | Leybold Ag | Optical lens made of a clear plastic |
| KR960014166A (en) | 1994-10-14 | 1996-05-22 | 양승택 | Manufacturing Method of Polymeric GRIN Lens Using Sulfide |
| DE4445427C2 (en) | 1994-12-20 | 1997-04-30 | Schott Glaswerke | Plasma CVD method for producing a gradient layer |
| US5811191A (en) | 1994-12-27 | 1998-09-22 | Ppg Industries, Inc. | Multilayer antireflective coating with a graded base layer |
| EP0728618A3 (en) | 1995-02-22 | 1996-11-06 | Gentex Corp | Anti-glare rear view mirror for motor vehicles |
| FR2730990B1 (en) | 1995-02-23 | 1997-04-04 | Saint Gobain Vitrage | TRANSPARENT SUBSTRATE WITH ANTI-REFLECTIVE COATING |
| EP0730044B1 (en) | 1995-03-01 | 2001-06-20 | Sumitomo Electric Industries, Limited | Boron-aluminum nitride coating and method of producing same |
| US5719705A (en) | 1995-06-07 | 1998-02-17 | Sola International, Inc. | Anti-static anti-reflection coating |
| FR2736632B1 (en) | 1995-07-12 | 1997-10-24 | Saint Gobain Vitrage | GLAZING PROVIDED WITH A CONDUCTIVE AND / OR LOW-EMISSIVE LAYER |
| JPH0968602A (en) | 1995-08-30 | 1997-03-11 | Nikon Corp | Optical article having antireflection layer |
| DE19537263C2 (en) | 1995-10-06 | 1998-02-26 | Fraunhofer Ges Forschung | Transparent heat protection film and process for its production |
| US5846650A (en) | 1996-05-10 | 1998-12-08 | Minnesota Mining And Manufacturing Company | Anti-reflective, abrasion resistant, anti-fogging coated articles and methods |
| JP3225348B2 (en) | 1996-06-15 | 2001-11-05 | 有限会社野上商事 | Weeding sickle |
| WO1998010916A1 (en) | 1996-09-12 | 1998-03-19 | University Of Florida | A novel production method for objects with radially-varying properties |
| US6172812B1 (en) | 1997-01-27 | 2001-01-09 | Peter D. Haaland | Anti-reflection coatings and coated articles |
| FR2759362B1 (en) | 1997-02-10 | 1999-03-12 | Saint Gobain Vitrage | TRANSPARENT SUBSTRATE EQUIPPED WITH AT LEAST ONE THIN LAYER BASED ON SILICON NITRIDE OR OXYNITRIDE AND ITS PROCESS FOR OBTAINING IT |
| GB9703616D0 (en) | 1997-02-21 | 1997-04-09 | Univ Paisley | Thin films |
| JPH10253840A (en) | 1997-03-07 | 1998-09-25 | Sumitomo Wiring Syst Ltd | Manufacture of refractive index distribution type plastic optical fiber and manufacturing device therefor |
| US6482524B1 (en) | 1997-03-11 | 2002-11-19 | Nippon Sheet Glass Co., Ltd. | Substrate having a treatment surface |
| CN1130575C (en) | 1997-05-16 | 2003-12-10 | 保谷株式会社 | Plastic optical device with antireflection film and mechanism for making thickness of antireflection film uniform |
| US6495251B1 (en) | 1997-06-20 | 2002-12-17 | Ppg Industries Ohio, Inc. | Silicon oxynitride protective coatings |
| CN1262611A (en) | 1997-07-02 | 2000-08-09 | 纽创基纳有限公司 | Methods of treating seborrheic dermatitis, dandruff, psoriasis and acne with dichlorophenylimidazodioxolane-containing compositions and compositions thereof |
| US5935716A (en) | 1997-07-07 | 1999-08-10 | Libbey-Owens-Ford Co. | Anti-reflective films |
| US6129980A (en) | 1997-07-11 | 2000-10-10 | Fuji Photo Film Co., Ltd. | Anti-reflection film and display device having the same |
| EP0893715B1 (en) | 1997-07-21 | 2004-02-04 | European Atomic Energy Community (EURATOM) | Method of producing an optical fibre resonant cavity, in particular for an interferometric sensor, and optical fibre resonant cavity produced thereby |
| CN1112594C (en) | 1997-10-02 | 2003-06-25 | 旭硝子株式会社 | Refractivity distributing optical resin material |
| US5867239A (en) | 1997-10-17 | 1999-02-02 | Minnesota Mining And Manufacturing Company | Wide angle optical retarder |
| JPH11125704A (en) | 1997-10-22 | 1999-05-11 | Dainippon Printing Co Ltd | Lenticular lens sheet and manufacturing method thereof |
| US6607829B1 (en) | 1997-11-13 | 2003-08-19 | Massachusetts Institute Of Technology | Tellurium-containing nanocrystalline materials |
| EP0918044A1 (en) | 1997-11-19 | 1999-05-26 | Glaverbel | Solar control glazing |
| US6074730A (en) | 1997-12-31 | 2000-06-13 | The Boc Group, Inc. | Broad-band antireflection coating having four sputtered layers |
| US6045894A (en) | 1998-01-13 | 2000-04-04 | 3M Innovative Properties Company | Clear to colored security film |
| TW415888B (en) | 1998-02-17 | 2000-12-21 | Nippon Kayaku Kk | Transparent sheet or film |
| US6800378B2 (en) | 1998-02-19 | 2004-10-05 | 3M Innovative Properties Company | Antireflection films for use with displays |
| EP1067407B1 (en) | 1998-02-24 | 2006-04-26 | Asahi Glass Co., Ltd. | Light absorption antireflective body and method of producing the same |
| JP3938636B2 (en) | 1998-02-25 | 2007-06-27 | Hoya株式会社 | High refractive index plastic lens and manufacturing method thereof |
| EP0947601A1 (en) | 1998-03-26 | 1999-10-06 | ESSILOR INTERNATIONAL Compagnie Générale d'Optique | Organic substrate having optical layers deposited by magnetron sputtering and method for preparing it |
| US6391400B1 (en) | 1998-04-08 | 2002-05-21 | Thomas A. Russell | Thermal control films suitable for use in glazing |
| US6583935B1 (en) | 1998-05-28 | 2003-06-24 | Cpfilms Inc. | Low reflection, high transmission, touch-panel membrane |
| FR2781062B1 (en) | 1998-07-09 | 2002-07-12 | Saint Gobain Vitrage | GLAZING WITH ELECTRICALLY CONTROLLED OPTICAL AND / OR ENERGY PROPERTIES |
| US7378146B1 (en) | 1998-08-05 | 2008-05-27 | International Business Machines Corporation | Transparent hard coats for optical elements |
| US6165598A (en) | 1998-08-14 | 2000-12-26 | Libbey-Owens-Ford Co. | Color suppressed anti-reflective glass |
| US6217272B1 (en) | 1998-10-01 | 2001-04-17 | Applied Science And Technology, Inc. | In-line sputter deposition system |
| JP2000121806A (en) | 1998-10-19 | 2000-04-28 | Fuji Photo Film Co Ltd | Antireflection film |
| FR2784984B1 (en) | 1998-10-22 | 2001-10-26 | Saint Gobain Vitrage | TRANSPARENT SUBSTRATE PROVIDED WITH A STACK OF THIN FILMS |
| JP3900506B2 (en) | 1998-11-06 | 2007-04-04 | Jsr株式会社 | Liquid curable resin composition, cured product thereof and antireflection film |
| DE69932594T2 (en) | 1998-11-30 | 2007-08-02 | Asahi Glass Co., Ltd. | MIRRORING FILM FOR WINDOWS OF A TRANSPORTING DEVICE, GLASS WITH RELATED FILM, LAMINATED GLASS AND MANUFACTURING METHOD |
| JP2000171601A (en) | 1998-12-08 | 2000-06-23 | Sony Corp | Antireflection film and display device |
| JP2000171605A (en) | 1998-12-08 | 2000-06-23 | Sony Corp | Antireflection film and display device |
| US6398925B1 (en) | 1998-12-18 | 2002-06-04 | Ppg Industries Ohio, Inc. | Methods and apparatus for producing silver based low emissivity coatings without the use of metal primer layers and articles produced thereby |
| US6088166A (en) | 1998-12-22 | 2000-07-11 | Dicon Fiberoptics, Inc. | Miniaturization of gradient index lens used in optical components |
| JP2000214302A (en) | 1999-01-20 | 2000-08-04 | Dainippon Printing Co Ltd | Antireflection film and method for producing the same |
| JP2000275404A (en) | 1999-03-24 | 2000-10-06 | Fuji Photo Film Co Ltd | Antireflection film having antiglare property and method for producing the same |
| US6173979B1 (en) | 1999-04-30 | 2001-01-16 | Bernard Mould Ltd. | Vehicle running board construction |
| US6338901B1 (en) | 1999-05-03 | 2002-01-15 | Guardian Industries Corporation | Hydrophobic coating including DLC on substrate |
| US6303225B1 (en) | 2000-05-24 | 2001-10-16 | Guardian Industries Corporation | Hydrophilic coating including DLC on substrate |
| MXPA01011771A (en) | 1999-05-18 | 2002-11-04 | Cardinal Cg Co | Hard, scratch-resistant coatings for substrates. |
| FR2793889B1 (en) | 1999-05-20 | 2002-06-28 | Saint Gobain Vitrage | TRANSPARENT SUBSTRATE WITH ANTI-REFLECTIVE COATING |
| US6355344B1 (en) | 1999-05-21 | 2002-03-12 | Tyco Adhesives Lp | Non-fogging pressure sensitive adhesive film material |
| US9786194B2 (en) | 1999-06-11 | 2017-10-10 | Sydney Hyman | Image making medium compositions and images |
| AU5871500A (en) | 1999-06-11 | 2001-01-02 | Sydney Hyman | Image making medium |
| US6440551B1 (en) | 1999-06-14 | 2002-08-27 | Cpfilms, Inc. | Light-stable colored transparent composite films |
| EP1069088A1 (en) | 1999-07-16 | 2001-01-17 | Asahi Glass Co., Ltd. | Antiglare-antireflection film and process for producing it |
| LU90420B1 (en) | 1999-07-20 | 2001-01-22 | Glaverbel | Pyrolitic layer of aluminum oxynitride and glazing comprising this layer |
| US6254913B1 (en) | 1999-08-27 | 2001-07-03 | Morinda, Inc. | Morinda citrifolia dietary fiber and method |
| JP4250834B2 (en) | 1999-10-29 | 2009-04-08 | ソニー株式会社 | Method for forming a thin film by catalytic sputtering |
| FR2800998B1 (en) | 1999-11-17 | 2002-04-26 | Saint Gobain Vitrage | TRANSPARENT SUBSTRATE HAVING AN ANTI-REFLECTIVE COATING |
| JP2001192821A (en) | 2000-01-07 | 2001-07-17 | Nippon Sheet Glass Co Ltd | Method for depositing film on substrate, and article obtained by the method |
| JP2001281406A (en) | 2000-03-28 | 2001-10-10 | Fuji Photo Film Co Ltd | Glare proof antireflection film, polarizing plate and liquid crystal display |
| JP2001281402A (en) | 2000-03-29 | 2001-10-10 | Fuji Photo Film Co Ltd | Glare proof film, glare proof antireflection film, polarizing plate and image display device |
| DE10018935A1 (en) | 2000-04-17 | 2001-10-18 | Bayer Ag | Coating, useful as a protective layer on polycarbonate, wood and textiles, comprises an epoxy resin primer layer and an epoxide group containing hydrolysable silane scratch resistant covering layer. |
| EP1148037A1 (en) | 2000-04-19 | 2001-10-24 | Blösch Holding AG | Process for the production of an anti-reflective coating on watchcover glasses |
| KR100761184B1 (en) | 2000-04-20 | 2007-10-04 | 디에스엠 아이피 어셋츠 비.브이. | Curable resin composition, cured film, and composite product |
| JP2001303246A (en) | 2000-04-27 | 2001-10-31 | Nippon Sheet Glass Co Ltd | Deposition method for water repellent film and article deposited with water repellent film obtained by this method |
| JP2001311806A (en) | 2000-04-27 | 2001-11-09 | Mitsubishi Rayon Co Ltd | Light-diffusing sheet, method for producing the same, and transmission screen |
| US6337771B1 (en) | 2000-05-03 | 2002-01-08 | Applied Vacuum Coating Technologies Co., Ltd. | Anti-reflection high conductivity multi-layer coating on CRT surface made by vacuum sputtering and wet coating |
| WO2002000772A1 (en) | 2000-06-28 | 2002-01-03 | Teijin Limited | Biaxially oriented polyester film, adhesive film, and laminated film |
| JP2002116303A (en) | 2000-07-27 | 2002-04-19 | Asahi Glass Co Ltd | Substrate with antireflection film and method of manufacturing the same |
| DE60122837T2 (en) | 2000-07-27 | 2007-09-06 | Asahi Glass Co., Ltd. | Antireflection film-equipped substrate and its production process |
| US6416872B1 (en) | 2000-08-30 | 2002-07-09 | Cp Films, Inc. | Heat reflecting film with low visible reflectance |
| JP4225675B2 (en) | 2000-09-07 | 2009-02-18 | 富士フイルム株式会社 | Antiglare antireflection film and liquid crystal display device |
| US6743516B2 (en) | 2000-09-29 | 2004-06-01 | Guardian Industries Corporation | Highly durable hydrophobic coatings and methods |
| US6485854B1 (en) | 2000-10-19 | 2002-11-26 | General Motors Corporation | Gas-liquid separator for fuel cell system |
| JP2002202402A (en) | 2000-10-31 | 2002-07-19 | Fuji Photo Film Co Ltd | Antidazzle reflection preventing film and picture display device |
| KR100381014B1 (en) | 2000-11-01 | 2003-04-26 | 한국전자통신연구원 | Amplitude noise suppression optical intensity modulation apparatus and method using linear optical modulator |
| ATE350677T1 (en) | 2000-11-14 | 2007-01-15 | Cpfilms Inc | OPTICALLY ACTIVE LAYER COMPOSITION |
| US6535333B1 (en) | 2000-11-21 | 2003-03-18 | 3M Innovative Properties Company | Optical system with reduced color shift |
| US6690499B1 (en) | 2000-11-22 | 2004-02-10 | Displaytech, Inc. | Multi-state light modulator with non-zero response time and linear gray scale |
| JP2002174810A (en) | 2000-12-08 | 2002-06-21 | Hoya Corp | Glass substrate for display, manufacturing method for the same and display using the same |
| FR2818272B1 (en) | 2000-12-15 | 2003-08-29 | Saint Gobain | GLAZING PROVIDED WITH A STACK OF THIN FILMS FOR SUN PROTECTION AND / OR THERMAL INSULATION |
| US7253861B2 (en) | 2000-12-28 | 2007-08-07 | Asahi Glass Company | Liquid crystal optical element comprising a resin layer having a surface hardness of b or less |
| JP4795588B2 (en) | 2001-01-12 | 2011-10-19 | 株式会社東芝 | Wear resistant parts made of silicon nitride |
| KR100905142B1 (en) | 2001-01-15 | 2009-06-29 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | Multi-layered infrared reflecting film having a high and smooth transmittance in the visible wavelength range and laminate products made therefrom |
| CN1318722A (en) | 2001-01-17 | 2001-10-24 | 任春严 | Multiple power source utilizing mechanism |
| JP2002210906A (en) | 2001-01-23 | 2002-07-31 | Teijin Ltd | Optical polyester film and laminate |
| JP2002212317A (en) | 2001-01-24 | 2002-07-31 | Teijin Ltd | Optical films and laminates |
| CN1312450A (en) | 2001-02-28 | 2001-09-12 | 任春严 | Water and power saving device and method |
| JP2002267835A (en) | 2001-03-09 | 2002-09-18 | Asahi Optical Co Ltd | Method for determining refractive index dispersion and method for determining refractive index distribution |
| US6875468B2 (en) | 2001-04-06 | 2005-04-05 | Rwe Solar Gmbh | Method and device for treating and/or coating a surface of an object |
| US6950236B2 (en) | 2001-04-10 | 2005-09-27 | Fuji Photo Film Co., Ltd. | Antireflection film, polarizing plate, and apparatus for displaying an image |
| US20040005482A1 (en) | 2001-04-17 | 2004-01-08 | Tomio Kobayashi | Antireflection film and antireflection layer-affixed plastic substrate |
| US6524714B1 (en) | 2001-05-03 | 2003-02-25 | Guardian Industries Corp. | Heat treatable coated articles with metal nitride layer and methods of making same |
| US20020167629A1 (en) | 2001-05-11 | 2002-11-14 | Blanchard Randall D. | Sunlight readable display with reduced ambient specular reflection |
| US6667121B2 (en) | 2001-05-17 | 2003-12-23 | Guardian Industries Corp. | Heat treatable coated article with anti-migration barrier between dielectric and solar control layer portion, and methods of making same |
| DE60215168T2 (en) | 2001-05-29 | 2007-08-23 | Essilor International Compagnie Générale d'Optique | METHOD FOR TRANSFERRING A HYDROPHOBIC COATING LAYER FROM A MOLDING TO AN OPTICAL SUBSTRATE |
| US6986857B2 (en) | 2001-05-29 | 2006-01-17 | Essilor International Compagnie Generale D'optique | Method for preparing a mold part useful for transferring a coating onto an optical substrate |
| JP4421142B2 (en) | 2001-06-08 | 2010-02-24 | Agcテクノグラス株式会社 | Optical device and method for manufacturing optical device |
| JP3656591B2 (en) | 2001-06-28 | 2005-06-08 | ソニー株式会社 | Method of manufacturing stamper for manufacturing optical recording medium and method of manufacturing optical recording medium |
| EP1275623A1 (en) | 2001-07-09 | 2003-01-15 | VIDEOCOLOR S.p.A. | Method for manufacturing a glass front plate for CRT coated with a both glossy and friction-resistant external layer |
| WO2003009767A1 (en) | 2001-07-20 | 2003-02-06 | Element Six B.V. | Cutting tool and method |
| JP2003026826A (en) | 2001-07-23 | 2003-01-29 | Fuji Photo Film Co Ltd | Polyester film for optics, hard-coated film and method for producing the same |
| FR2827855B1 (en) | 2001-07-25 | 2004-07-02 | Saint Gobain | GLAZING PROVIDED WITH A STACK OF THIN FILMS REFLECTING INFRARED AND / OR SOLAR RADIATION |
| AUPR678701A0 (en) | 2001-08-03 | 2001-08-23 | Sola International Holdings Ltd | Scratch masking coatings for optical substrates |
| KR20040027940A (en) | 2001-08-20 | 2004-04-01 | 노바-플라즈마 인크. | Coatings with low permeation of gases and vapors |
| US6908480B2 (en) | 2001-08-29 | 2005-06-21 | Swaminathan Jayaraman | Structurally variable stents |
| KR100953927B1 (en) | 2001-09-04 | 2010-04-22 | 다이니폰 인사츠 가부시키가이샤 | Coating compositions, coatings formed thereon, antireflective films, antireflective films and image displays |
| JP2003082127A (en) | 2001-09-07 | 2003-03-19 | Teijin Dupont Films Japan Ltd | Biaxially oriented polyester film for optical and laminate thereof |
| US6605358B1 (en) | 2001-09-13 | 2003-08-12 | Guardian Industries Corp. | Low-E matchable coated articles, and methods |
| AT413560B (en) | 2001-09-26 | 2006-03-15 | Swarco Futurit Verkehrssignals | ROADWAY MARKER LIGHT |
| US7351447B2 (en) | 2001-10-12 | 2008-04-01 | Bridgestone Corporation | Method of producing anti-reflection film |
| JP2003131011A (en) | 2001-10-29 | 2003-05-08 | Nippon Electric Glass Co Ltd | Multilayer film and substrate with multilayer film using the multilayer film |
| JP4016178B2 (en) | 2001-11-06 | 2007-12-05 | ソニー株式会社 | Display device and antireflection substrate |
| US7241485B2 (en) | 2001-11-09 | 2007-07-10 | Toray Industries, Inc. | Protective film for glass |
| JP2003215310A (en) | 2001-11-15 | 2003-07-30 | Konica Corp | Optical lens and optical information recording and reproducing device |
| JP4036076B2 (en) | 2001-12-12 | 2008-01-23 | チッソ株式会社 | Liquid crystalline fluorene derivative and polymer thereof |
| US7414009B2 (en) | 2001-12-21 | 2008-08-19 | Showa Denko K.K. | Highly active photocatalyst particles, method of production therefor, and use thereof |
| JP3958055B2 (en) | 2002-02-04 | 2007-08-15 | キヤノン株式会社 | Ranging and photometry equipment |
| JP3953829B2 (en) | 2002-02-20 | 2007-08-08 | 大日本印刷株式会社 | Anti-reflection layer, anti-reflection material, and anti-reflection body with enhanced surface |
| AU2003208610A1 (en) | 2002-02-25 | 2003-09-09 | Fuji Photo Film Co., Ltd. | Antiglare and antireflection film, polarizing plate and display device |
| DE10219812A1 (en) | 2002-05-02 | 2003-11-13 | Univ Dresden Tech | Components with crystalline coatings of the aluminum oxide / silicon oxide system and process for their production |
| FR2836912B1 (en) | 2002-03-06 | 2004-11-26 | Saint Gobain | TRANSPARENT SUSBRATE WITH ANTI-REFLECTIVE COATING WITH ABRASION RESISTANCE PROPERTIES |
| DE10209949A1 (en) | 2002-03-06 | 2003-09-25 | Schott Glas | Glass body with porous coating |
| JP2003266607A (en) | 2002-03-14 | 2003-09-24 | Fuji Photo Film Co Ltd | Hard coat film and image display device provided with the same |
| JP4174344B2 (en) | 2002-03-15 | 2008-10-29 | 日東電工株式会社 | Antireflection film, method for producing the same, optical element, and image display device |
| US6783253B2 (en) | 2002-03-21 | 2004-08-31 | Guardian Industries Corp. | First surface mirror with DLC coating |
| JP2003285343A (en) | 2002-03-29 | 2003-10-07 | Konica Corp | Method for producing optical thin film and optical thin film |
| US6919946B2 (en) | 2002-04-16 | 2005-07-19 | 3M Innovative Properties Company | Compensators for liquid crystal displays and the use and manufacture of the compensators |
| US20050233091A1 (en) | 2002-05-08 | 2005-10-20 | Devendra Kumar | Plasma-assisted coating |
| TWI290328B (en) | 2002-05-23 | 2007-11-21 | Nof Corp | Transparent conductive laminated film and touch panel |
| JP4096163B2 (en) | 2002-06-05 | 2008-06-04 | 富士ゼロックス株式会社 | Image structure and image forming apparatus for creating the same |
| JP2004029240A (en) | 2002-06-24 | 2004-01-29 | Fuji Photo Film Co Ltd | Method for producing antiglare antireflection film |
| FR2841894B1 (en) | 2002-07-03 | 2006-03-10 | Saint Gobain | TRANSPARENT SUBSTRATE HAVING ANTIREFLECTION COATING |
| JP4393042B2 (en) | 2002-08-05 | 2010-01-06 | 大日本印刷株式会社 | Antiglare antireflection member and optical member |
| ATE474239T1 (en) | 2002-08-15 | 2010-07-15 | Fujifilm Corp | ANTIREFLEX FILM, POLARIZATION PLATE AND IMAGE DISPLAY DEVICE |
| US7426328B2 (en) | 2002-08-28 | 2008-09-16 | Phosistor Technologies, Inc. | Varying refractive index optical medium using at least two materials with thicknesses less than a wavelength |
| US7643719B1 (en) | 2003-03-14 | 2010-01-05 | Phosistor Technologies, Inc. | Superlens and a method for making the same |
| US7015640B2 (en) | 2002-09-11 | 2006-03-21 | General Electric Company | Diffusion barrier coatings having graded compositions and devices incorporating the same |
| KR100885083B1 (en) | 2002-09-14 | 2009-02-25 | 쇼오트 아게 | Methods of manufacturing layers and layer systems and coated substrates |
| US6707610B1 (en) | 2002-09-20 | 2004-03-16 | Huper Optik International Pte Ltd | Reducing the susceptibility of titanium nitride optical layers to crack |
| US8618219B2 (en) | 2002-10-15 | 2013-12-31 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
| JP2004138662A (en) | 2002-10-15 | 2004-05-13 | Fuji Photo Film Co Ltd | Anti-reflection coating, anti-reflection film, and image display device |
| JP2004147246A (en) | 2002-10-28 | 2004-05-20 | Matsushita Electric Ind Co Ltd | Piezoelectric vibrator, filter using the same, and method of adjusting piezoelectric vibrator |
| EP1418448A1 (en) | 2002-11-06 | 2004-05-12 | Koninklijke DSM N.V. | Preparation of a mechanically durable single layer coating with anti-reflective properties |
| JP2004163549A (en) | 2002-11-11 | 2004-06-10 | Pentax Corp | Anti-reflective coating |
| WO2004049018A1 (en) | 2002-11-25 | 2004-06-10 | Fuji Photo Film Co., Ltd. | Anti-reflection film, polarizing plate and liquid crystal display device |
| TW586322B (en) | 2002-12-18 | 2004-05-01 | Prodisc Technology Inc | Rear projection screen, optical component of a rear projection screen and method for manufacturing thereof |
| JP4174509B2 (en) | 2003-01-21 | 2008-11-05 | 帝人デュポンフィルム株式会社 | Laminated film |
| DK1594812T3 (en) | 2003-02-14 | 2008-07-28 | Agc Flat Glass Europe Sa | Window panel carrying a coating table |
| JP2004244594A (en) | 2003-02-17 | 2004-09-02 | Asahi Kasei Corp | Cyclic conjugated diene copolymer |
| US7463821B2 (en) | 2003-03-20 | 2008-12-09 | Pixar | Flat panel image to film transfer method and apparatus |
| JP2004291303A (en) | 2003-03-26 | 2004-10-21 | Fuji Photo Film Co Ltd | Method and apparatus for producing antiglare antireflection film and antiglare antireflection film |
| JP2004294616A (en) | 2003-03-26 | 2004-10-21 | Fuji Photo Film Co Ltd | Method and apparatus for producing antiglare antireflection film and antiglare antireflection film |
| TWI305865B (en) | 2003-03-31 | 2009-02-01 | Shinetsu Chemical Co | Photomask blank, photomask, and method of manufacture |
| US20050037240A1 (en) | 2003-03-31 | 2005-02-17 | Daisaku Haoto | Protective coat and method for manufacturing thereof |
| JP4217097B2 (en) | 2003-04-03 | 2009-01-28 | ダイセル化学工業株式会社 | Anti-glare film |
| JP2004333901A (en) | 2003-05-08 | 2004-11-25 | Optimax Technology Corp | Manufacturing method of anti-glare anti-reflection film |
| US20040233174A1 (en) | 2003-05-19 | 2004-11-25 | Robrecht Michael J. | Vibration sensing touch input device |
| FR2856627B1 (en) | 2003-06-26 | 2006-08-11 | Saint Gobain | TRANSPARENT SUBSTRATE WITH COATING WITH MECHANICAL STRENGTH PROPERTIES |
| JP4475016B2 (en) | 2003-06-30 | 2010-06-09 | 東レ株式会社 | Hard coat film, antireflection film and image display device |
| KR20050007940A (en) | 2003-07-12 | 2005-01-21 | 삼성전자주식회사 | Surface light source device, method for manufacturing thereof, back light assembly using the same and liquid crystal display device having the same |
| JP2005042072A (en) | 2003-07-25 | 2005-02-17 | Fuji Photo Film Co Ltd | Curable composition and cured product using the same |
| JP2005070724A (en) | 2003-08-05 | 2005-03-17 | Asahi Glass Co Ltd | Optical filter for plasma display panel |
| FR2858816B1 (en) | 2003-08-13 | 2006-11-17 | Saint Gobain | TRANSPARENT SUBSTRATE HAVING ANTIREFLECTION COATING |
| DE10342397B4 (en) | 2003-09-13 | 2008-04-03 | Schott Ag | Transparent protective layer for a body and its use |
| DE10342398B4 (en) | 2003-09-13 | 2008-05-29 | Schott Ag | Protective layer for a body, and methods of making and using protective layers |
| CN100564349C (en) | 2003-10-01 | 2009-12-02 | 大阪瓦斯株式会社 | Multifunctional (meth)acrylate and preparation method thereof |
| TW200517458A (en) | 2003-10-06 | 2005-06-01 | Dainippon Printing Co Ltd | Antiglare film |
| JP2005114649A (en) | 2003-10-10 | 2005-04-28 | Citizen Watch Co Ltd | Cover glass for timepiece |
| US7727917B2 (en) | 2003-10-24 | 2010-06-01 | Schott Ag | Lithia-alumina-silica containing glass compositions and glasses suitable for chemical tempering and articles made using the chemically tempered glass |
| FR2861853B1 (en) | 2003-10-30 | 2006-02-24 | Soitec Silicon On Insulator | SUBSTRATE WITH INDEX ADAPTATION |
| TWI354120B (en) | 2003-11-05 | 2011-12-11 | Sumitomo Chemical Co | Antiglare film and image display device |
| JP2007519037A (en) | 2003-12-18 | 2007-07-12 | エーエフジー インダストリーズ,インコーポレイテッド | Protective layer for optical coating with improved corrosion and scratch resistance |
| JP2005187640A (en) | 2003-12-25 | 2005-07-14 | Tosoh Corp | Maleimide / olefin copolymer composition |
| JP2005187639A (en) | 2003-12-25 | 2005-07-14 | Tosoh Corp | Transparency resin composition |
| TWI388876B (en) | 2003-12-26 | 2013-03-11 | Fujifilm Corp | Antireflection film, polarizing plate, method for producing them, liquid crystal display element, liquid crystal display device, and image display device |
| JP2005219223A (en) | 2004-02-03 | 2005-08-18 | Konica Minolta Opto Inc | Anti-staining layer, its manufacturing method, anti-staining antireflection film, polarizing plate and image display device |
| JP2005227415A (en) | 2004-02-12 | 2005-08-25 | Crd:Kk | Reflection preventive film and plate for display |
| FR2866643B1 (en) | 2004-02-24 | 2006-05-26 | Saint Gobain | SUBSTRATE, ESPECIALLY GLASS, WITH A HYDROPHOBIC SURFACE, WITH IMPROVED DURABILITY OF HYDROPHOBIC PROPERTIES |
| US7189456B2 (en) | 2004-03-04 | 2007-03-13 | Transitions Optical, Inc. | Photochromic optical article |
| JP2005246296A (en) | 2004-03-05 | 2005-09-15 | Hitachi Chem Co Ltd | Mixed solution of photocatalytic metal oxide and organic substance for direct coating of organic matter, metal oxide-containing composition, method for producing photocatalytic film, and obtained photocatalytic film and photocatalytic member |
| US9222169B2 (en) | 2004-03-15 | 2015-12-29 | Sharp Laboratories Of America, Inc. | Silicon oxide-nitride-carbide thin-film with embedded nanocrystalline semiconductor particles |
| JP2005274527A (en) | 2004-03-26 | 2005-10-06 | Cimeo Precision Co Ltd | Cover glass for clock |
| JP4707656B2 (en) | 2004-03-29 | 2011-06-22 | Hoya株式会社 | Optical member having antireflection film |
| JP4544952B2 (en) | 2004-03-31 | 2010-09-15 | 大日本印刷株式会社 | Anti-reflection laminate |
| WO2005096502A1 (en) | 2004-04-02 | 2005-10-13 | Kaben Research Inc. | Multiple stage delta sigma modulators |
| JP2005300576A (en) | 2004-04-06 | 2005-10-27 | Konica Minolta Opto Inc | Glare-proof antireflection film, polarizing plate and display device |
| US7202504B2 (en) | 2004-05-20 | 2007-04-10 | Semiconductor Energy Laboratory Co., Ltd. | Light-emitting element and display device |
| JPWO2005121265A1 (en) | 2004-06-11 | 2008-04-10 | 東レ株式会社 | Siloxane-based paint, optical article, and method for producing siloxane-based paint |
| US20070063147A1 (en) | 2004-06-14 | 2007-03-22 | Semiconductor Energy Laboratory Co., Ltd. | Doping device |
| JP2006003676A (en) | 2004-06-18 | 2006-01-05 | Lintec Corp | Functional film for display screen and manufacturing method for same |
| TWI245919B (en) | 2004-06-24 | 2005-12-21 | Polylite Taiwan Co Ltd | Method for manufacturing a light deflect/color change lens from polycarbonate and other plastic materials |
| US7311975B2 (en) | 2004-06-25 | 2007-12-25 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article having low-E coating with ion beam treated IR reflecting layer and corresponding method |
| US7585396B2 (en) | 2004-06-25 | 2009-09-08 | Guardian Industries Corp. | Coated article with ion treated overcoat layer and corresponding method |
| US7229533B2 (en) | 2004-06-25 | 2007-06-12 | Guardian Industries Corp. | Method of making coated article having low-E coating with ion beam treated and/or formed IR reflecting layer |
| US7550067B2 (en) | 2004-06-25 | 2009-06-23 | Guardian Industries Corp. | Coated article with ion treated underlayer and corresponding method |
| JP4449616B2 (en) | 2004-07-21 | 2010-04-14 | パナソニック株式会社 | Touch panel |
| US7255940B2 (en) | 2004-07-26 | 2007-08-14 | General Electric Company | Thermal barrier coatings with high fracture toughness underlayer for improved impact resistance |
| JP2006047504A (en) | 2004-08-02 | 2006-02-16 | Dainippon Printing Co Ltd | Anti-reflection laminate |
| JP2006079067A (en) | 2004-08-12 | 2006-03-23 | Fuji Photo Film Co Ltd | Anti-reflection film |
| US20070285776A1 (en) | 2004-08-12 | 2007-12-13 | Fujifilm Corporation | Anti-Reflection Film |
| WO2007001337A2 (en) | 2004-08-18 | 2007-01-04 | Dow Corning Corporation | Coated substrates and methods for their preparation |
| ES2318529T3 (en) | 2004-09-03 | 2009-05-01 | Fraunhofer-Gesellschaft Zur Forderung Der Angewandten Forschung E.V. | FILM FORMATION MATERIAL AND PREPARATION OF A SURFACE RELIEF AND OPTICALLY ANISOTROPIC STRUCTURES IRRADIATING A FILM OF SUCH MATERIAL. |
| KR20060024545A (en) | 2004-09-14 | 2006-03-17 | (주)케이디티 | High brightness organic light emitting display |
| KR20070083557A (en) | 2004-09-23 | 2007-08-24 | 엘리먼트 씩스 (프티) 리미티드 | Polycrystalline abrasive materials and method of manufacture |
| JP4429862B2 (en) | 2004-10-06 | 2010-03-10 | 日東電工株式会社 | Hard coat film, antireflection hard coat film, optical element and image display device |
| JP4674074B2 (en) | 2004-10-12 | 2011-04-20 | リケンテクノス株式会社 | Hard coat film and antireflection film |
| JP4887612B2 (en) | 2004-10-20 | 2012-02-29 | 日油株式会社 | Anti-reflection material and electronic image display device using the same |
| JP4612827B2 (en) | 2004-10-25 | 2011-01-12 | キヤノン株式会社 | Anti-reflection coating |
| US20060153979A1 (en) | 2004-11-30 | 2006-07-13 | Fuji Photo Film Co., Ltd. | Anti-glare and anti-reflection film, polarizing plate using the anti-glare and anti-reflection film, and liquid crystal display device using the polarizing plate |
| US20060115651A1 (en) | 2004-11-30 | 2006-06-01 | Guardian Industries Corp. | Painted glass tiles, panels and the like and method for producing painted glass tiles and panels |
| KR100715500B1 (en) | 2004-11-30 | 2007-05-07 | (주)케이디티 | Light source using microcavity organic light emitting device and photoexcitation light emitting layer |
| BRPI0515784A (en) | 2004-12-17 | 2008-08-05 | Afg Ind Inc | scratch resistant airborne protective layer article for optical coatings and method for improving scratch protection of these coatings |
| US7498058B2 (en) | 2004-12-20 | 2009-03-03 | Ppg Industries Ohio, Inc. | Substrates coated with a polycrystalline functional coating |
| KR20060072072A (en) | 2004-12-22 | 2006-06-27 | 닛토덴코 가부시키가이샤 | Anti-glare hard coating film and manufacturing method thereof |
| US8619365B2 (en) | 2004-12-29 | 2013-12-31 | Corning Incorporated | Anti-reflective coating for optical windows and elements |
| CN100502609C (en) | 2004-12-29 | 2009-06-17 | 郑岩 | Electroluminescence lines |
| US20060154044A1 (en) | 2005-01-07 | 2006-07-13 | Pentax Corporation | Anti-reflection coating and optical element having such anti-reflection coating for image sensors |
| JP2006208726A (en) | 2005-01-27 | 2006-08-10 | Dainippon Printing Co Ltd | Optical function sheet |
| JP4855781B2 (en) | 2005-02-01 | 2012-01-18 | 日東電工株式会社 | Antireflection hard coat film, optical element and image display device |
| EP2279909B1 (en) | 2005-02-02 | 2012-06-06 | Flabeg GmbH & Co. KG | Rear view mirror for vehicles |
| TW200700510A (en) | 2005-02-25 | 2007-01-01 | Optimax Tech Corp | Inorganic-organic hybrid nanocomposite antiglare and antireflection coatings |
| EP1705162A1 (en) | 2005-03-23 | 2006-09-27 | EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt | Coated substrate and process for the manufacture of a coated substrate |
| US7149032B2 (en) | 2005-03-29 | 2006-12-12 | Tomoegawa Paper Co., Ltd. | Anti-glare film |
| CN1653880A (en) | 2005-04-07 | 2005-08-17 | 杨崇杰 | Facility sited sun-facing garden |
| JP2006352105A (en) | 2005-05-19 | 2006-12-28 | Sharp Corp | Optical transmission device and light source device using the same |
| JP4760275B2 (en) | 2005-05-23 | 2011-08-31 | ソニー株式会社 | Liquid crystal display |
| CN100394215C (en) | 2005-05-26 | 2008-06-11 | 财团法人工业技术研究院 | Three-dimensional nanoporous film and method of making same |
| US7535462B2 (en) | 2005-06-02 | 2009-05-19 | Eastman Kodak Company | Touchscreen with one carbon nanotube conductive layer |
| US7593004B2 (en) | 2005-06-02 | 2009-09-22 | Eastman Kodak Company | Touchscreen with conductive layer comprising carbon nanotubes |
| US20060286465A1 (en) | 2005-06-15 | 2006-12-21 | Ji-Suk Kim | Film type filter and display apparatus comprising the same |
| US7781493B2 (en) | 2005-06-20 | 2010-08-24 | Dow Global Technologies Inc. | Protective coating for window glass |
| JP5283146B2 (en) | 2005-07-01 | 2013-09-04 | 株式会社ジャパンディスプレイ | Liquid crystal display |
| TWI292340B (en) | 2005-07-13 | 2008-01-11 | Ind Tech Res Inst | Antireflective transparent zeolite hardcoat film, method for fabricating the same, and solution capable of forming said transparent zeolite film |
| US7423442B2 (en) | 2005-07-22 | 2008-09-09 | Texas Instruments Incorporated | System and method for early qualification of semiconductor devices |
| FR2889202B1 (en) | 2005-08-01 | 2007-09-14 | Saint Gobain | METHOD FOR DEPOSITING ANTI-SCRATCH LAYER |
| US20070030569A1 (en) | 2005-08-04 | 2007-02-08 | Guardian Industries Corp. | Broad band antireflection coating and method of making same |
| DE102005040266A1 (en) | 2005-08-24 | 2007-03-01 | Schott Ag | Method and device for inside plasma treatment of hollow bodies |
| JP2007055064A (en) | 2005-08-24 | 2007-03-08 | Toray Ind Inc | Laminated polyester film |
| US8480282B2 (en) | 2005-08-30 | 2013-07-09 | Lg Display Co., Ltd. | Reflective plate and method for manufacturing the same and backlight unit for liquid crystal display device using the same |
| JP2007072372A (en) | 2005-09-09 | 2007-03-22 | Fujifilm Corp | Antireflection film, method for producing the same, and image display device |
| US8304078B2 (en) | 2005-09-12 | 2012-11-06 | Saxon Glass Technologies, Inc. | Chemically strengthened lithium aluminosilicate glass having high strength effective to resist fracture upon flexing |
| CN1936623A (en) | 2005-09-20 | 2007-03-28 | 车王电子股份有限公司 | glass lens for rearview mirror |
| WO2007034715A1 (en) | 2005-09-21 | 2007-03-29 | Konica Minolta Opto, Inc. | Anti-glare, anti-reflection film and method for manufacture thereof |
| JP2007086521A (en) | 2005-09-22 | 2007-04-05 | Fujifilm Corp | Anti-reflection laminate |
| JP4765069B2 (en) | 2005-09-26 | 2011-09-07 | 国立大学法人東北大学 | Nitride coating method |
| CN1940601A (en) | 2005-09-26 | 2007-04-04 | 力特光电科技股份有限公司 | Antiglare and antireflection film, polarizing plate and display device using same |
| WO2007039161A1 (en) | 2005-09-27 | 2007-04-12 | Schott Ag | Mask blanc and photomasks having antireflective properties |
| JP2007099557A (en) | 2005-10-04 | 2007-04-19 | Nippon Electric Glass Co Ltd | Tempered glass article and method for producing the same |
| JP2007114377A (en) | 2005-10-19 | 2007-05-10 | Fujifilm Corp | Anti-glare film, anti-glare antireflection film, polarizing plate and image display device |
| JP2009037735A (en) | 2005-10-28 | 2009-02-19 | Toshiba Corp | Flat image display device |
| US20070097509A1 (en) | 2005-10-31 | 2007-05-03 | Nevitt Timothy J | Optical elements for high contrast applications |
| FR2893023B1 (en) | 2005-11-08 | 2007-12-21 | Saint Gobain | SUBSTRATE PROVIDED WITH A STACK WITH THERMAL PROPERTIES |
| KR100709879B1 (en) | 2005-11-18 | 2007-04-20 | 삼성에스디아이 주식회사 | Film filter of plasma display panel |
| KR20070054850A (en) | 2005-11-24 | 2007-05-30 | 삼성에스디아이 주식회사 | Film type front filter for plasma display panel and manufacturing method thereof |
| JP4790396B2 (en) | 2005-12-02 | 2011-10-12 | 学校法人東京理科大学 | Method for producing transparent film |
| JP2007156205A (en) | 2005-12-07 | 2007-06-21 | Toray Ind Inc | Flat display filter, flat display, and flat display filter manufacturing method |
| KR101224621B1 (en) | 2005-12-14 | 2013-01-22 | 도레이첨단소재 주식회사 | Method of producing hard coat and anti-reflection glaring film with conductive/magnetic particle |
| US7553543B2 (en) | 2005-12-16 | 2009-06-30 | E. I. Du Pont De Nemours And Company | Composite structure having a fluoroelastomeric anti-reflective coating with non-fluorinated cross-linking |
| FR2895522B1 (en) | 2005-12-23 | 2008-04-11 | Saint Gobain | TRANSPARENT SUBSTRATE HAVING ANTIREFLECTION COATING |
| JP5144538B2 (en) | 2005-12-23 | 2013-02-13 | スリーエム イノベイティブ プロパティズ カンパニー | Films containing thermoplastic silicone block copolymers |
| JP4796077B2 (en) | 2005-12-28 | 2011-10-19 | 東海光学株式会社 | Eyeglass lenses and eyeglasses |
| CN2859579Y (en) | 2005-12-29 | 2007-01-17 | 深圳市中柏电脑技术有限公司 | LCD display with inhibitory coating |
| US8013845B2 (en) | 2005-12-30 | 2011-09-06 | Flatfrog Laboratories Ab | Optical touch pad with multilayer waveguide |
| JP4958536B2 (en) | 2006-01-12 | 2012-06-20 | 富士フイルム株式会社 | Anti-reflection coating |
| DE102006002596A1 (en) | 2006-01-18 | 2007-07-19 | Tesa Ag | composite film |
| ITMI20060094A1 (en) | 2006-01-20 | 2007-07-21 | Alice Engineering | TRANSFERABLE FILM FOR SURFACE COATING PROCEDURE FOR ITS IMPLEMENTATION AND APPLICATION PROCEDURE |
| TWI447443B (en) | 2006-02-28 | 2014-08-01 | Fujifilm Corp | Polarizing plate and liquid crystal display |
| EP1829835A1 (en) | 2006-03-03 | 2007-09-05 | Applied Materials GmbH & Co. KG | Infrared radiation reflecting coating system and method of its production |
| JP2007240707A (en) | 2006-03-07 | 2007-09-20 | Konica Minolta Opto Inc | Method of manufacturing glare-proof antireflection film, glare-proof antireflection film, and image display device |
| FR2898295B1 (en) | 2006-03-10 | 2013-08-09 | Saint Gobain | TRANSPARENT ANTIREFLECTION SUBSTRATE WITH NEUTRAL COLOR IN REFLECTION |
| US8882267B2 (en) | 2006-03-20 | 2014-11-11 | High Performance Optics, Inc. | High energy visible light filter systems with yellowness index values |
| US8360574B2 (en) | 2006-03-20 | 2013-01-29 | High Performance Optics, Inc. | High performance selective light wavelength filtering providing improved contrast sensitivity |
| US8124215B2 (en) | 2006-03-28 | 2012-02-28 | Nitto Denko Corporation | Hard-coated antiglare film, method of manufacturing the same, optical device, polarizing plate, and image display |
| JP2007271953A (en) | 2006-03-31 | 2007-10-18 | Toppan Printing Co Ltd | Lens array sheet and transmissive screen |
| JP2007271958A (en) | 2006-03-31 | 2007-10-18 | Toppan Printing Co Ltd | Anti-reflection laminate, manufacturing method thereof, optical functional filter, and optical display device |
| US20070237918A1 (en) | 2006-04-06 | 2007-10-11 | 3M Innovative Properties Company | Wrapping material comprising a multilayer film as tear strip |
| JP5934459B2 (en) | 2006-04-17 | 2016-06-15 | オムニビジョン テクノロジーズ, インコーポレイテッド | Arrayed imaging system and related method |
| EP1847569B1 (en) | 2006-04-21 | 2010-01-06 | Ems-Chemie Ag | Transparent polyamide moulding compositions |
| JP2007298667A (en) | 2006-04-28 | 2007-11-15 | Hitachi Chem Co Ltd | Optical filter |
| JP5252811B2 (en) | 2006-05-16 | 2013-07-31 | 日東電工株式会社 | Anti-glare hard coat film, polarizing plate and image display device |
| DE102006024524A1 (en) | 2006-05-23 | 2007-12-06 | Von Ardenne Anlagentechnik Gmbh | Transparent multi-layer composite system capable of reflecting infrared radiation for hardening and/or shaping of substrates and temperature process, comprises layers, anti-reflection coating, blocking layer and dielectric interface layer |
| JP4119925B2 (en) | 2006-05-25 | 2008-07-16 | 大日本印刷株式会社 | Antireflection film |
| US7796123B1 (en) | 2006-06-20 | 2010-09-14 | Eastman Kodak Company | Touchscreen with carbon nanotube conductive layers |
| JP2008003425A (en) | 2006-06-23 | 2008-01-10 | Nippon Zeon Co Ltd | Polarizer |
| US7903338B1 (en) | 2006-07-08 | 2011-03-08 | Cirrex Systems Llc | Method and system for managing light at an optical interface |
| JP2008032949A (en) | 2006-07-28 | 2008-02-14 | Sony Corp | Antireflection film, metal film heating method, and heating apparatus |
| US20090135492A1 (en) | 2006-08-11 | 2009-05-28 | Kouji Kusuda | Anti-reflective film, polarizer, liquid crystal display element and display element |
| US8163372B2 (en) | 2006-08-14 | 2012-04-24 | Dai Nippon Printing Co., Ltd. | Anti-dazzling optical laminate |
| CN101506692B (en) | 2006-08-18 | 2011-08-17 | 大日本印刷株式会社 | Optical layered body, polarizing plate and image display device |
| US8088502B2 (en) | 2006-09-20 | 2012-01-03 | Battelle Memorial Institute | Nanostructured thin film optical coatings |
| JP2008133535A (en) | 2006-10-26 | 2008-06-12 | Ube Nitto Kasei Co Ltd | Method for producing metal nanoparticle-attached substrate, composition for forming substrate-adhesive metal nanoparticles, method for producing metal-layer-coated substrate, pretreatment method for electroless plating, composition for pretreatment for electroless plating, and electroless plating Goods |
| TW200835597A (en) | 2006-10-30 | 2008-09-01 | Lofo High Tech Film Gmbh | Plasticizer for protective films |
| JP5125345B2 (en) | 2007-09-19 | 2013-01-23 | 日立化成工業株式会社 | Liquid crystal display |
| JP5048304B2 (en) | 2006-11-02 | 2012-10-17 | リケンテクノス株式会社 | Hard coat film and antireflection film |
| WO2008062605A1 (en) | 2006-11-21 | 2008-05-29 | Nittetsu Mining Co., Ltd | Resin composition, anti-reflection coating material, anti-dazzling coating material, anti-reflection coating, anti-reflection film, anti-dazzling film, corrosion protective coating, corrosion protective coating material, coating material, and coating film |
| FR2909187B1 (en) | 2006-11-23 | 2009-01-02 | Essilor Int | OPTICAL ARTICLE COMPRISING A BICOUCHE ANTI-ABRASION AND ANTI-SCRATCH COATING AND METHOD OF MANUFACTURE |
| KR20080048578A (en) | 2006-11-29 | 2008-06-03 | 김현회 | Method of manufacturing protection filter for display with advertising function and protection filter |
| KR20080057443A (en) | 2006-12-20 | 2008-06-25 | 삼성전자주식회사 | Liquid crystal display |
| JP2008158156A (en) | 2006-12-22 | 2008-07-10 | Konica Minolta Opto Inc | Anti-glare anti-reflection film, method for manufacturing the same, and display device |
| KR101375485B1 (en) | 2007-01-12 | 2014-03-18 | 코니카 미놀타 어드밴스드 레이어즈 인코포레이티드 | Antireflection film, process for producing antireflection film, polarizing plate, and display device |
| CN101236264A (en) | 2007-02-01 | 2008-08-06 | 甘国工 | High light transmittance ratio transparent resin display protection panel and LCD device using same |
| TW200845405A (en) | 2007-02-06 | 2008-11-16 | American Solar Technologies Inc | Solar electric module with redirection of incident light |
| BE1017460A6 (en) | 2007-02-09 | 2008-10-07 | Leo Vermeulen Consulting Lvc | LENTICULAR FOIL. |
| EP1962110A1 (en) | 2007-02-14 | 2008-08-27 | Sony Corporation | Anti-glare film, method for manufacturing the same, and display device using the same |
| JP4155337B1 (en) | 2007-02-21 | 2008-09-24 | ソニー株式会社 | Anti-glare film, method for producing the same, and display device |
| JP5140288B2 (en) | 2007-02-21 | 2013-02-06 | 株式会社ビッグバイオ | Antibacterial treatment method |
| JP2008242425A (en) | 2007-02-26 | 2008-10-09 | Seiko Epson Corp | Optical article and manufacturing method thereof |
| TWI486320B (en) | 2007-03-02 | 2015-06-01 | Nippon Electric Glass Co | Reinforced plate glass and manufacturing method thereof |
| KR101384382B1 (en) | 2007-03-12 | 2014-04-10 | 코니카 미놀타 어드밴스드 레이어즈 인코포레이티드 | Process for producing antiglare antireflection film, antiglare antireflection film, polarizer, and display |
| JP5271575B2 (en) | 2007-03-20 | 2013-08-21 | 富士フイルム株式会社 | Antireflection film, polarizing plate, and image display device |
| CN100570406C (en) | 2007-04-27 | 2009-12-16 | 甘国工 | Safety glass protective screen for liquid crystal display and liquid crystal display using the same |
| TW200848835A (en) | 2007-06-12 | 2008-12-16 | Eternal Chemical Co Ltd | Scratch-resistant optical film having organic particles with highly uniform particle size |
| FR2917510B1 (en) | 2007-06-13 | 2012-01-27 | Essilor Int | OPTICAL ARTICLE COATED WITH ANTIREFLECTIVE COATING COMPRISING A PARTIALLY FORMED UNDER-LAYER WITH ION ASSISTANCE AND METHOD OF MANUFACTURE |
| JPWO2009001911A1 (en) | 2007-06-28 | 2010-08-26 | ソニー株式会社 | OPTICAL FILM, ITS MANUFACTURING METHOD, AND ANTIGLARE POLARIZER AND DISPLAY DEVICE USING THE SAME |
| US7978402B2 (en) | 2007-06-28 | 2011-07-12 | General Electric Company | Robust window for infrared energy |
| US20110043719A1 (en) | 2007-07-03 | 2011-02-24 | Thunhorst Kristin L | Optically transmissive composite film frame |
| JP5168278B2 (en) | 2007-07-10 | 2013-03-21 | コニカミノルタアドバンストレイヤー株式会社 | Antiglare film, antiglare antireflection film using the same, polarizing plate, and display device |
| DE102007033338B4 (en) | 2007-07-16 | 2010-06-02 | Schott Ag | Hard material-coated glass or glass-ceramic article and method for its production and use of the glass or glass-ceramic article |
| JP2009025384A (en) | 2007-07-17 | 2009-02-05 | Fujifilm Corp | Antireflection film, polarizing plate, and image display device |
| KR20090009612A (en) | 2007-07-20 | 2009-01-23 | 엘지디스플레이 주식회사 | Inorganic insulating film formation method through sputtering |
| JP5467490B2 (en) | 2007-08-03 | 2014-04-09 | 日本電気硝子株式会社 | Method for producing tempered glass substrate and tempered glass substrate |
| US8208097B2 (en) | 2007-08-08 | 2012-06-26 | Samsung Corning Precision Materials Co., Ltd. | Color compensation multi-layered member for display apparatus, optical filter for display apparatus having the same and display apparatus having the same |
| US20120131730A1 (en) | 2007-08-10 | 2012-05-31 | Gilad Shoham | Contoured Face Shields and Method of Producing Optically Clear Parts |
| JP5076729B2 (en) | 2007-08-20 | 2012-11-21 | 凸版印刷株式会社 | Antireflection film and polarizing plate using the same |
| TW200910169A (en) | 2007-08-24 | 2009-03-01 | Onetouch Technologies Co Ltd | Touch panel structure |
| JP4380752B2 (en) | 2007-09-11 | 2009-12-09 | 凸版印刷株式会社 | Method for manufacturing antireflection laminate |
| EP2188406B1 (en) | 2007-09-12 | 2018-03-07 | Flisom AG | Method for manufacturing a compound film |
| JP2009088503A (en) | 2007-09-14 | 2009-04-23 | Mitsubishi Chemicals Corp | Laminated cover substrate for solar cell, solar cell, and method for producing laminated cover substrate for solar cell |
| EP2188048A4 (en) | 2007-09-21 | 2012-08-08 | Chemwelltech Co Ltd | PHOTOCATALYTIC COMPOSITION FOR ANTIREFLECTION TREATMENT AND GLASS SUBSTRATE COATED WITH THE COMPOSITION |
| JP2009098657A (en) * | 2007-09-26 | 2009-05-07 | Fujifilm Corp | Liquid crystal display device |
| WO2009041528A1 (en) | 2007-09-26 | 2009-04-02 | Citizen Holdings Co., Ltd. | Cover glass for watch |
| CN101689376B (en) | 2007-09-28 | 2012-07-11 | Hoya株式会社 | Glass substrate for magnetic disk, manufacturing method thereof, and magnetic disk |
| US7978744B2 (en) | 2007-09-28 | 2011-07-12 | Sanyo Electric Co., Ltd. | Nitride based semiconductor laser device with oxynitride protective films on facets |
| US7924898B2 (en) | 2007-09-28 | 2011-04-12 | Sanyo Electric Co., Ltd. | Nitride based semiconductor laser device with oxynitride protective coatings on facets |
| AU2007360138B2 (en) | 2007-10-18 | 2013-09-19 | Midwest Research Institue | High temperature solar selective coatings |
| SG185934A1 (en) | 2007-10-30 | 2012-12-28 | 3M Innovative Properties Co | Multi-stack optical bandpass film with electro magnetic interference shielding for optical display filters |
| JP5262066B2 (en) | 2007-10-31 | 2013-08-14 | 凸版印刷株式会社 | Manufacturing method of antireflection film and manufacturing method of polarizing plate including the same |
| JP2009116219A (en) | 2007-11-09 | 2009-05-28 | Seiko Epson Corp | Antireflection film, method for forming antireflection film, and translucent member |
| JP2009116218A (en) | 2007-11-09 | 2009-05-28 | Seiko Epson Corp | Antireflection film, method for forming antireflection film, and translucent member |
| JP2009116220A (en) | 2007-11-09 | 2009-05-28 | Seiko Epson Corp | Antireflection film, method for forming antireflection film, and translucent member |
| WO2009065490A2 (en) | 2007-11-21 | 2009-05-28 | Lofo High Tech Film Gmbh | Use of a specific uv-absorbers in planar materials and/or lenses and objects associated therewith |
| JP2009128820A (en) | 2007-11-27 | 2009-06-11 | Hoya Corp | Plastic lens having multilayer antireflection layer and method of manufacturing the same |
| JP2011505465A (en) | 2007-11-30 | 2011-02-24 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Low refractive index composition, abrasion resistant anti-reflective coating and method of forming an abrasion resistant anti-reflective coating |
| KR101415573B1 (en) | 2007-11-30 | 2014-07-04 | 삼성디스플레이 주식회사 | Liquid crystal display |
| US8888965B2 (en) | 2007-11-30 | 2014-11-18 | Anna University—Chennai | Non-stoichiometric titanium nitride films |
| WO2009075348A1 (en) | 2007-12-12 | 2009-06-18 | Bridgestone Corporation | Optical filter, optical filter for display, display provided with such filter, and plasma display panel |
| CN201165502Y (en) | 2007-12-13 | 2008-12-17 | 叶隆泰 | Anti-reflection anti-static transparent adhesive film |
| WO2009078406A1 (en) | 2007-12-18 | 2009-06-25 | Hoya Corporation | Cover glass for portable terminal, method for manufacturing cover glass for portable terminal, and portable terminal apparatus |
| JP2009149468A (en) | 2007-12-20 | 2009-07-09 | Nippon Electric Glass Co Ltd | Manufacturing method of crystallized glass substrate, and crystallized glass substrate |
| JP2009175725A (en) | 2007-12-28 | 2009-08-06 | Nippon Shokubai Co Ltd | Antiglare laminate |
| EP2239136B1 (en) | 2008-02-01 | 2019-02-27 | Toray Industries, Inc. | Laminated film and molding and reflector |
| KR20100125279A (en) | 2008-02-05 | 2010-11-30 | 코닝 인코포레이티드 | Damage resistant glass article for use as a cover plate in electronic devices |
| JP5285300B2 (en) | 2008-02-25 | 2013-09-11 | Hoya株式会社 | Optical member |
| JP2009204837A (en) | 2008-02-27 | 2009-09-10 | Sumitomo Chemical Co Ltd | Anti-glare film, anti-glare polarizing sheet, and image display device |
| JP2009204506A (en) | 2008-02-28 | 2009-09-10 | Seiko Epson Corp | Timepiece, light-transmitting member, and its manufacturing method |
| US20090223437A1 (en) | 2008-03-07 | 2009-09-10 | Ballard Claudio R | Gauge having synthetic sapphire lens |
| FR2928461B1 (en) | 2008-03-10 | 2011-04-01 | Saint Gobain | TRANSPARENT SUBSTRATE HAVING ANTIREFLECTION COATING |
| HUE044108T2 (en) | 2008-03-20 | 2019-09-30 | Agc Glass Europe | Window coated with fine layers |
| TWI425244B (en) | 2008-03-26 | 2014-02-01 | Nat Applied Res Laboratories | Antireflective film and method for manufacturing the same |
| US20110120554A1 (en) | 2008-03-27 | 2011-05-26 | Rensselaer Polytechnic Institute | Ultra-low reflectance broadband omni-directional anti-reflection coating |
| JP2009265601A (en) | 2008-03-31 | 2009-11-12 | Kyocera Corp | Multiple-fiber ferrule and method for manufacturing thereof |
| CN201201777Y (en) | 2008-04-17 | 2009-03-04 | 王俭 | Foot fossa type safety belt box |
| WO2009131206A1 (en) | 2008-04-24 | 2009-10-29 | 旭硝子株式会社 | Low reflection glass and protective plate for display |
| KR101374400B1 (en) | 2008-04-24 | 2014-03-17 | 닛토덴코 가부시키가이샤 | Transparent substrate |
| KR101385262B1 (en) | 2008-04-29 | 2014-04-16 | 에이전시 포 사이언스, 테크놀로지 앤드 리서치 | Inorganic graded barrier film and methods for their manufacture |
| JPWO2009133833A1 (en) | 2008-04-30 | 2011-09-01 | Hoya株式会社 | Optical element and antireflection film |
| JP5478836B2 (en) | 2008-05-01 | 2014-04-23 | ソニー株式会社 | Optical recording medium, liquid active energy ray-curable reactive cross-linked resin composition |
| CA2629555A1 (en) | 2008-05-14 | 2009-11-14 | Gerard Voon | Related/overlapping innovations in health/energy/transport/farming and infrastructure |
| US7858194B2 (en) | 2008-05-27 | 2010-12-28 | Innovation & Infinity Global Corp. | Extreme low resistivity light attenuation anti-reflection coating structure in order to increase transmittance of blue light and method for manufacturing the same |
| US8491718B2 (en) | 2008-05-28 | 2013-07-23 | Karin Chaudhari | Methods of growing heteroepitaxial single crystal or large grained semiconductor films and devices thereon |
| JP5444846B2 (en) | 2008-05-30 | 2014-03-19 | 旭硝子株式会社 | Glass plate for display device |
| JP2011527661A (en) | 2008-07-11 | 2011-11-04 | コーニング インコーポレイテッド | Glass with compression surface for consumer use |
| FR2933961B1 (en) | 2008-07-16 | 2013-06-21 | Valois Sas | FLUID PRODUCT APPLICATOR DEVICE. |
| US8187671B2 (en) | 2008-07-28 | 2012-05-29 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film including removal of protective film via blasting |
| WO2010014163A1 (en) | 2008-07-29 | 2010-02-04 | Corning Incorporated | Dual stage ion exchange for chemical strengthening of glass |
| JP5326407B2 (en) | 2008-07-31 | 2013-10-30 | セイコーエプソン株式会社 | Watch cover glass and watch |
| KR20100013836A (en) | 2008-08-01 | 2010-02-10 | 제일모직주식회사 | Optical sheet having excellent sheet resistance and backlight unit for liquid crystal display device using the same |
| FR2934689B1 (en) | 2008-08-04 | 2010-09-17 | Essilor Int | OPTICAL ARTICLE COMPRISING AN ANSTATIC LAYER LIMITING PERCEPTION OF FRINGES OF INTERFERENCE, HAVING EXCELLENT LIGHT TRANSMISSION AND METHOD OF MANUFACTURING THE SAME. |
| KR20100019922A (en) | 2008-08-11 | 2010-02-19 | 주식회사 룩스온 | Nano porous antireflection film and its forming method |
| US20100074949A1 (en) | 2008-08-13 | 2010-03-25 | William Rowe | Pharmaceutical composition and administration thereof |
| KR20110050522A (en) | 2008-08-21 | 2011-05-13 | 코닝 인코포레이티드 | Durable Glass Housings / Enclosures for Electronic Devices |
| JP2010061044A (en) | 2008-09-05 | 2010-03-18 | Fujifilm Corp | Anti-reflection film, polarizing plate, and image forming device |
| DE102008041869A1 (en) | 2008-09-08 | 2010-03-25 | Carl Zeiss Vision Gmbh | Spectacle lens with color-neutral anti-reflection coating and method for its production |
| CN101349769A (en) | 2008-09-11 | 2009-01-21 | 北京有色金属研究总院 | Method for preparing ALON protection film for optical element |
| JP5439783B2 (en) | 2008-09-29 | 2014-03-12 | ソニー株式会社 | Optical element, optical component with antireflection function, and master |
| CN101724812A (en) | 2008-10-24 | 2010-06-09 | 山东力诺新材料有限公司 | Coating and preparation method thereof |
| DE102008054139B4 (en) | 2008-10-31 | 2010-11-11 | Schott Ag | Glass or glass-ceramic substrate with scratch-resistant coating, its use and process for its preparation |
| WO2010053092A1 (en) | 2008-11-07 | 2010-05-14 | 日東電工株式会社 | Transparent substrate and method for production thereof |
| JP2010153810A (en) | 2008-11-21 | 2010-07-08 | Sanyo Electric Co Ltd | Nitride-based semiconductor laser device and optical pickup |
| DE102008058318B3 (en) | 2008-11-21 | 2010-06-17 | Schott Ag | Scratch-resistant silicone coating for cooking surfaces made of glass or glass ceramic |
| JP2010125719A (en) | 2008-11-28 | 2010-06-10 | Nippon Steel Chem Co Ltd | Glass with scattering preventing performance |
| JP4513921B2 (en) | 2008-12-09 | 2010-07-28 | ソニー株式会社 | Optical body and manufacturing method thereof, window material, blind, roll curtain, and shoji |
| US20100149483A1 (en) | 2008-12-12 | 2010-06-17 | Chiavetta Iii Stephen V | Optical Filter for Selectively Blocking Light |
| US20110262742A1 (en) | 2008-12-25 | 2011-10-27 | Tokai Rubber Industries, Ltd. | Transparent laminated film and method for producing the same |
| JP2010167410A (en) | 2008-12-26 | 2010-08-05 | Fujifilm Corp | Method for manufacturing hollow particulate, hollow particulate obtained by this method and its dispersion, and antireflection film using the hollow particulate |
| JP4678437B2 (en) | 2008-12-29 | 2011-04-27 | ソニー株式会社 | OPTICAL ELEMENT, ITS MANUFACTURING METHOD, AND DISPLAY DEVICE |
| KR20110110240A (en) | 2008-12-30 | 2011-10-06 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | Anti-reflective article and manufacturing method thereof |
| CN102325650A (en) | 2008-12-30 | 2012-01-18 | 3M创新有限公司 | Architectural articles comprising fluoropolymer multilayer optical films and methods of making the same |
| FR2940966B1 (en) | 2009-01-09 | 2011-03-04 | Saint Gobain | HYDROPHOBIC SUBSTRATE COMPRISING A PLASMA ACTIVATED SILICON OXYCARBIDE PREMIUM |
| JP2010191412A (en) | 2009-01-21 | 2010-09-02 | Toppan Printing Co Ltd | Antiglare film |
| JP5659494B2 (en) | 2009-02-17 | 2015-01-28 | 凸版印刷株式会社 | Antireflection film and manufacturing method thereof, polarizing plate, transmissive liquid crystal display |
| US8341976B2 (en) | 2009-02-19 | 2013-01-01 | Corning Incorporated | Method of separating strengthened glass |
| JP2010244016A (en) | 2009-03-18 | 2010-10-28 | Toppan Printing Co Ltd | Antiglare film, polarizing plate, transmissive liquid crystal display |
| WO2010114135A1 (en) | 2009-03-30 | 2010-10-07 | 新日本製鐵株式会社 | Precoated metal sheet and process for producing same |
| JP5658435B2 (en) | 2009-03-31 | 2015-01-28 | リンテック株式会社 | Mask film member, mask film manufacturing method using the same, and photosensitive resin printing plate manufacturing method |
| US8864897B2 (en) | 2009-04-30 | 2014-10-21 | Enki Technology, Inc. | Anti-reflective and anti-soiling coatings with self-cleaning properties |
| US9376593B2 (en) | 2009-04-30 | 2016-06-28 | Enki Technology, Inc. | Multi-layer coatings |
| JP5486840B2 (en) | 2009-05-14 | 2014-05-07 | リンテック株式会社 | Antireflection film and polarizing plate using the same |
| JP5273673B2 (en) | 2009-05-15 | 2013-08-28 | スターテング工業株式会社 | Small engine starter |
| TWI477615B (en) | 2009-06-05 | 2015-03-21 | 住友化學股份有限公司 | Production method of Inorganic particle composite |
| JP5927457B2 (en) | 2009-06-16 | 2016-06-01 | 東海光学株式会社 | Optical products and eyeglass plastic lenses |
| JP2011017782A (en) | 2009-07-07 | 2011-01-27 | Olympus Corp | Antireflective film |
| US20120107607A1 (en) | 2009-07-17 | 2012-05-03 | Mitsui Chemicals, Inc. | Multilayered material and method of producing the same |
| JP5588135B2 (en) | 2009-08-10 | 2014-09-10 | ホーヤ レンズ マニュファクチャリング フィリピン インク | Method for manufacturing optical article |
| CN201483977U (en) | 2009-08-31 | 2010-05-26 | 沈阳木本实业有限公司 | Multifunctional writing board |
| FR2949775B1 (en) | 2009-09-10 | 2013-08-09 | Saint Gobain Performance Plast | PROTECTIVE SUBSTRATE FOR COLOR DEVICE OR RADIATION TRANSMITTER |
| CN102024508B (en) | 2009-09-14 | 2013-05-01 | 群康科技(深圳)有限公司 | Conducting plate structure |
| WO2011034845A1 (en) | 2009-09-16 | 2011-03-24 | 3M Innovative Properties Company | Fluorinated coating and phototools made therewith |
| WO2011046149A1 (en) | 2009-10-16 | 2011-04-21 | 大日本印刷株式会社 | Optical film and display panel |
| JP5433372B2 (en) | 2009-10-20 | 2014-03-05 | フクビ化学工業株式会社 | Method for producing antireflection tempered glass |
| KR101811893B1 (en) | 2009-10-22 | 2017-12-22 | 닛토덴코 가부시키가이샤 | Transparent substrate |
| DE102009050568A1 (en) | 2009-10-23 | 2011-04-28 | Schott Ag | Cover disk for a signaling system in railway areas and street area and for display- and traffic light device in traffic and scoreboard, comprises a substrate on which a coating is applied and which is a soda-lime glass disk |
| JP5416546B2 (en) | 2009-10-23 | 2014-02-12 | 日東電工株式会社 | Transparent substrate |
| JP5448064B2 (en) | 2009-10-28 | 2014-03-19 | 日本電気硝子株式会社 | Tempered plate glass and manufacturing method thereof |
| KR20110047596A (en) | 2009-10-30 | 2011-05-09 | 동우 화인켐 주식회사 | Composition for hard coating, hard coating film and polarizing film comprising the same |
| US9987820B2 (en) | 2009-11-17 | 2018-06-05 | Arkema France | Multilayer structures containing biopolymers |
| WO2011065293A1 (en) | 2009-11-25 | 2011-06-03 | 旭硝子株式会社 | Glass base plate for display cover glass, and process for production thereof |
| DE102009056933A1 (en) | 2009-12-04 | 2011-06-09 | Giesecke & Devrient Gmbh | Security element with color filter, value document with such a security element and production method of such a security element |
| JP5549216B2 (en) | 2009-12-22 | 2014-07-16 | 凸版印刷株式会社 | Transparent conductive laminate, method for producing the same, and touch panel |
| JP5589379B2 (en) | 2009-12-25 | 2014-09-17 | 旭硝子株式会社 | Manufacturing method of glass substrate for display cover glass |
| KR101103041B1 (en) | 2009-12-30 | 2012-01-05 | 미래나노텍(주) | Anti-reflection film and its manufacturing method |
| KR101276621B1 (en) | 2009-12-31 | 2013-06-19 | 코오롱인더스트리 주식회사 | Protective film |
| JP2011150821A (en) | 2010-01-20 | 2011-08-04 | Fujifilm Corp | Electroluminescent element |
| WO2011096276A1 (en) * | 2010-02-05 | 2011-08-11 | Semiconductor Energy Laboratory Co., Ltd. | Liquid crystal display device |
| US8939606B2 (en) | 2010-02-26 | 2015-01-27 | Guardian Industries Corp. | Heatable lens for luminaires, and/or methods of making the same |
| DE102010009584B4 (en) | 2010-02-26 | 2015-01-08 | Schott Ag | Chemically toughened glass, process for its preparation and use thereof |
| US20120301676A1 (en) | 2010-03-05 | 2012-11-29 | Hiroaki Ushida | Optical film and process for producing the same |
| KR20180049184A (en) | 2010-03-26 | 2018-05-10 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | Textured film and process for manufacture thereof |
| CN201732354U (en) | 2010-04-11 | 2011-02-02 | 宸鸿科技(厦门)有限公司 | Stack structure with enhanced touch panel bonding strength |
| CN102844684B (en) | 2010-04-15 | 2015-03-25 | 日东电工株式会社 | Hard coat film, polarizing film, image display device, and hard coat film manufacturing method |
| US9017566B2 (en) | 2010-04-30 | 2015-04-28 | Corning Incorporated | Anti-glare surface treatment method and articles thereof |
| KR20130069621A (en) | 2010-05-07 | 2013-06-26 | 가부시키가이샤 니콘 | Conductive sliding film, member formed from conductive sliding film, and method for producing same |
| CN201707457U (en) | 2010-05-21 | 2011-01-12 | 许福义 | Multi-layer film screen protector |
| JP5533257B2 (en) | 2010-05-25 | 2014-06-25 | Jnc株式会社 | Polymerizable liquid crystal compound, composition and polymer thereof |
| BE1019346A3 (en) | 2010-05-25 | 2012-06-05 | Agc Glass Europe | GLAZING OF SOLAR CONTROL. |
| FR2960654B1 (en) | 2010-05-27 | 2012-06-15 | Commissariat Energie Atomique | CLEAN OPTICAL FILTER FOR TREATING A VARIABLE INCIDENCE RADIATION AND DETECTOR COMPRISING SUCH A FILTER |
| US8471282B2 (en) | 2010-06-07 | 2013-06-25 | Koninklijke Philips Electronics N.V. | Passivation for a semiconductor light emitting device |
| MX2012013699A (en) | 2010-06-10 | 2012-12-17 | 3M Innovative Properties Co | Display device and method of lc panel protection. |
| JP2010202514A (en) | 2010-06-10 | 2010-09-16 | Hoya Corp | Glass substrate for mobile liquid crystal display and method for producing the same, and mobile liquid crystal display using the same |
| JP5508946B2 (en) | 2010-06-16 | 2014-06-04 | デクセリアルズ株式会社 | Optical body, window material, joinery, solar shading device, and building |
| US9056584B2 (en) | 2010-07-08 | 2015-06-16 | Gentex Corporation | Rearview assembly for a vehicle |
| TWI547746B (en) | 2010-07-13 | 2016-09-01 | 元太科技工業股份有限公司 | Display device |
| JPWO2012008587A1 (en) | 2010-07-16 | 2013-09-09 | 旭硝子株式会社 | Infrared reflective substrate and laminated glass |
| KR101147416B1 (en) | 2010-07-26 | 2012-05-23 | 삼성모바일디스플레이주식회사 | Display device |
| EP2598456A2 (en) | 2010-07-29 | 2013-06-05 | AGC Glass Europe | Glass substrate with interference colouration for a facing panel |
| CN102345093B (en) | 2010-07-29 | 2016-01-13 | 鸿富锦精密工业(深圳)有限公司 | Housing and preparation method thereof |
| KR20130097736A (en) | 2010-08-05 | 2013-09-03 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | Multilayer film comprising matte surface layer and articles |
| US8973401B2 (en) | 2010-08-06 | 2015-03-10 | Corning Incorporated | Coated, antimicrobial, chemically strengthened glass and method of making |
| JP5586017B2 (en) | 2010-08-20 | 2014-09-10 | 東海光学株式会社 | Optical products and eyeglass plastic lenses |
| US20120052271A1 (en) | 2010-08-26 | 2012-03-01 | Sinue Gomez | Two-step method for strengthening glass |
| US8693097B2 (en) | 2010-09-03 | 2014-04-08 | Guardian Industries Corp. | Temperable three layer antireflective coating, coated article including temperable three layer antireflective coating, and/or method of making the same |
| US9796619B2 (en) | 2010-09-03 | 2017-10-24 | Guardian Glass, LLC | Temperable three layer antirefrlective coating, coated article including temperable three layer antirefrlective coating, and/or method of making the same |
| JP5255611B2 (en) | 2010-09-17 | 2013-08-07 | Hoya株式会社 | GLASS SUBSTRATE FOR DISPLAY, PROCESS FOR PRODUCING THE SAME AND DISPLAY USING THE SAME |
| US20120070603A1 (en) | 2010-09-21 | 2012-03-22 | Fu-Yi Hsu | Screen protective sticker |
| CN103201845A (en) | 2010-09-22 | 2013-07-10 | 道康宁公司 | Electronic article and method of forming |
| KR20130119926A (en) | 2010-09-30 | 2013-11-01 | 다이니폰 인사츠 가부시키가이샤 | Optical laminate, polarizing plate and image display device |
| WO2012048040A2 (en) | 2010-10-05 | 2012-04-12 | Anpac Bio-Medical Science Co., Ltd. | Micro-devices for disease detection |
| AU2015252116A1 (en) | 2010-10-05 | 2015-11-26 | Anpac Bio-Medical Science Co., Ltd. | Micro-Devices For Disease Detection |
| GB2485522B (en) | 2010-10-11 | 2012-10-31 | Fu-Yi Hsu | Screen protective sticker structure |
| US9463256B2 (en) | 2010-10-14 | 2016-10-11 | Koninklijke Philips N.V. | Pretargeting kit, method and agents used therein |
| US8469551B2 (en) | 2010-10-20 | 2013-06-25 | 3M Innovative Properties Company | Light extraction films for increasing pixelated OLED output with reduced blur |
| US20120099188A1 (en) | 2010-10-20 | 2012-04-26 | AEgis Technologies Group, Inc. | Laser Protection Structures and Methods of Fabrication |
| FR2966934B3 (en) | 2010-10-27 | 2012-12-21 | Fu-Yi Hsu | ADHESIVE SCREEN PROTECTOR STRUCTURE |
| US9652089B2 (en) | 2010-11-09 | 2017-05-16 | Tpk Touch Solutions Inc. | Touch panel stackup |
| CN102109630B (en) | 2011-01-18 | 2013-01-23 | 深圳市盛波光电科技有限公司 | Three-dimensional display polarizer and a preparation method thereof |
| CN201945707U (en) | 2011-01-18 | 2011-08-24 | 深圳市盛波光电科技有限公司 | 3D (three-dimensional) stereo display polaroid |
| EP2492251B1 (en) | 2011-02-23 | 2017-01-04 | Schott Ag | Substrate with antireflective coating and method for producing same |
| JP6105205B2 (en) | 2011-02-28 | 2017-03-29 | Hoya株式会社 | Optical lens |
| EP2681163A1 (en) | 2011-02-28 | 2014-01-08 | Corning Incorporated | Glass having antiglare surface with low display sparkle |
| CN102681042A (en) | 2011-03-08 | 2012-09-19 | 东莞市纳利光学材料有限公司 | Preparation method of anti-dazzle film |
| JP2012189760A (en) | 2011-03-10 | 2012-10-04 | Seiko Epson Corp | Optical filter, optical filter module, spectrometer, and optical device |
| CN201984393U (en) | 2011-03-18 | 2011-09-21 | 深圳市中柏电脑技术有限公司 | All-in-one computer |
| EA034095B1 (en) | 2011-03-24 | 2019-12-26 | Сэн-Гобэн Гласс Франс | Transparent substrate equipped with a thin-film multilayer, and multiple glazing unit |
| JP5655660B2 (en) | 2011-03-25 | 2015-01-21 | 日油株式会社 | Near-infrared shielding film and near-infrared shielding body using the same |
| TWI444944B (en) | 2011-03-29 | 2014-07-11 | E Ink Holdings Inc | Color display and method for manufacturing color display |
| CN103534623B (en) | 2011-03-29 | 2016-02-17 | 富士胶片株式会社 | Blooming, 3D image display element and 3D image display system |
| US8981015B2 (en) | 2011-03-31 | 2015-03-17 | Sabic Global Technologies B.V. | Flame retardant poly(siloxane) copolymer compositions, methods of manufacture, and articles formed therefrom |
| JP5556724B2 (en) | 2011-03-31 | 2014-07-23 | 旭硝子株式会社 | Method for producing chemically strengthened glass |
| JP5736214B2 (en) | 2011-03-31 | 2015-06-17 | 株式会社日本触媒 | Method for producing molded product containing (meth) acrylic polymer |
| US9499436B2 (en) | 2011-04-01 | 2016-11-22 | Guardian Industries Corp. | Light scattering coating for greenhouse applications, and/or coated article including the same |
| US9042019B2 (en) | 2011-04-15 | 2015-05-26 | Qspex Technologies, Inc. | Anti-reflective lenses and methods for manufacturing the same |
| US9446979B2 (en) * | 2011-11-02 | 2016-09-20 | Corning Incorporated | Method for sparkle control and articles thereof |
| EP2699952A4 (en) | 2011-04-20 | 2015-06-24 | Univ Michigan | SPECTRAL FILTERING FOR VISUAL DISPLAYS AND IMAGING SYSTEM HAVING MINIMUM ANGULAR DEPENDENCY |
| US9272947B2 (en) | 2011-05-02 | 2016-03-01 | Corning Incorporated | Glass article having antireflective layer and method of making |
| CN103492173B (en) | 2011-04-22 | 2015-05-20 | 旭硝子株式会社 | Laminate, method for producing same, and use of same |
| JP6117478B2 (en) | 2011-04-22 | 2017-04-19 | 日東電工株式会社 | Adhesive functional film and display device |
| JP2012228811A (en) | 2011-04-26 | 2012-11-22 | Mitsubishi Gas Chemical Co Inc | Synthetic resin laminate |
| JP2012230290A (en) | 2011-04-27 | 2012-11-22 | Seiko Epson Corp | Optical filter, optical filter module, spectrometer and optical apparatus |
| EP2703851B1 (en) | 2011-04-28 | 2016-05-25 | Asahi Glass Company, Limited | Antireflection stack |
| KR101121207B1 (en) | 2011-05-03 | 2012-03-22 | 윤택진 | Low-refractive anti-reflection coating composition having excellent corrosion resistance and producing method of the same |
| CN102278833A (en) | 2011-05-16 | 2011-12-14 | 山东桑乐光热设备有限公司 | High-temperature resistant selective absorption coating and manufacturing method thereof |
| JP2012242449A (en) | 2011-05-16 | 2012-12-10 | Sony Chemical & Information Device Corp | Phase difference element and manufacturing method for the same |
| CN103688195B (en) | 2011-05-17 | 2017-03-08 | 佳能电子株式会社 | Optical filter and optical device |
| US20120291840A1 (en) * | 2011-05-18 | 2012-11-22 | Glenn Eric Kohnke | Patterned textured glass compatible with laser scribing |
| KR20120129643A (en) | 2011-05-20 | 2012-11-28 | 동우 화인켐 주식회사 | Coating composition for anti-glare and anti-reflection, film using the same, polarizing plate, and display device |
| BE1019988A3 (en) | 2011-05-24 | 2013-03-05 | Agc Glass Europe | TRANSPARENT VERRIER SUBSTRATE CARRYING A COATING OF SUCCESSIVE LAYERS. |
| US9535280B2 (en) * | 2011-05-27 | 2017-01-03 | Corning Incorporated | Engineered antiglare surface to reduce display sparkle |
| US9573842B2 (en) | 2011-05-27 | 2017-02-21 | Corning Incorporated | Transparent glass substrate having antiglare surface |
| JP6036689B2 (en) | 2011-06-06 | 2016-11-30 | 旭硝子株式会社 | Optical filter, solid-state imaging device, lens for imaging device, and imaging device |
| US20120327568A1 (en) | 2011-06-24 | 2012-12-27 | Anna-Katrina Shedletsky | Thin Film Coatings for Glass Members |
| BR112013033726A2 (en) | 2011-06-30 | 2017-01-31 | Agc Glass Europe | layers of temperable and non-temperable transparent nanocomposites |
| US8694474B2 (en) | 2011-07-06 | 2014-04-08 | Microsoft Corporation | Block entropy encoding for word compression |
| US20130021669A1 (en) | 2011-07-21 | 2013-01-24 | Raydex Technology, Inc. | Spectrally Tunable Optical Filter |
| WO2013023359A1 (en) | 2011-08-16 | 2013-02-21 | 深圳市盛波光电科技有限公司 | Film-type integrated 3d stereoscopic display polaroid and preparing method thereof |
| CN202177751U (en) | 2011-08-19 | 2012-03-28 | 天马微电子股份有限公司 | Liquid crystal light valve glasses and stereoscopic display system |
| DE102011081234A1 (en) | 2011-08-19 | 2013-02-21 | Schott Ag | Glass ceramic, which is at least partially provided with a hard material layer |
| CN202177765U (en) | 2011-08-19 | 2012-03-28 | 天马微电子股份有限公司 | Liquid crystal light valve spectacles and three-dimensional display system |
| CN202615053U (en) | 2011-08-19 | 2012-12-19 | 天马微电子股份有限公司 | 3D (three dimensional) liquid crystal glasses |
| CN202182978U (en) | 2011-08-19 | 2012-04-04 | 天马微电子股份有限公司 | Liquid crystal light valve glasses and stereoscopic display system |
| CN202171708U (en) | 2011-08-19 | 2012-03-21 | 天马微电子股份有限公司 | Liquid crystal light valve glasses and stereoscopic display system |
| TWI509292B (en) | 2011-09-07 | 2015-11-21 | Hon Hai Prec Ind Co Ltd | Lens and lens module having lens |
| KR20130031689A (en) | 2011-09-21 | 2013-03-29 | 삼성코닝정밀소재 주식회사 | Multi-layered article |
| JP5816040B2 (en) | 2011-09-28 | 2015-11-17 | 三菱電線工業株式会社 | Spark tester head |
| KR101194257B1 (en) | 2011-10-12 | 2012-10-29 | 주식회사 케이씨씨 | Transparent substrate for solar cell having a broadband anti-reflective multilayered coating thereon and method for preparing the same |
| JP5938189B2 (en) | 2011-10-12 | 2016-06-22 | デクセリアルズ株式会社 | Optical body, window material, joinery and solar shading device |
| EP2581789B1 (en) | 2011-10-14 | 2020-04-29 | Fundació Institut de Ciències Fotòniques | Optically transparent and electrically conductive coatings and method for their deposition on a substrate |
| JP5662982B2 (en) | 2011-10-28 | 2015-02-04 | Hoya株式会社 | Antireflection film and optical element |
| JP2013097356A (en) | 2011-11-07 | 2013-05-20 | Toppan Printing Co Ltd | Antireflection film manufacturing method, antireflection film, polarizing plate, and display device |
| TWI479486B (en) | 2011-11-15 | 2015-04-01 | Ritedia Corp | Light transmittive aln protective layers and associated devices and methods |
| FR2982607A1 (en) | 2011-11-16 | 2013-05-17 | Saint Gobain | Material, useful in glazing for land transport, aquatic or air vehicle, preferably e.g. car windshield, glazing for building, interior installation or street furniture, comprises a glass substrate coated with a layer or a stack of layers |
| FR2982754B1 (en) | 2011-11-21 | 2014-07-25 | Seb Sa | MACHINING-RESISTANT COOKING SURFACE AND CULINARY ARTICLE OR HOUSEHOLD APPLIANCE COMPRISING SUCH A COOKING SURFACE |
| US20130127202A1 (en) | 2011-11-23 | 2013-05-23 | Shandon Dee Hart | Strengthened Glass and Glass Laminates Having Asymmetric Impact Resistance |
| BE1020331A4 (en) | 2011-11-29 | 2013-08-06 | Agc Glass Europe | GLAZING OF SOLAR CONTROL. |
| US9957609B2 (en) | 2011-11-30 | 2018-05-01 | Corning Incorporated | Process for making of glass articles with optical and easy-to-clean coatings |
| TWI661065B (en) | 2011-11-30 | 2019-06-01 | 美商康寧公司 | Magnetic substrate carrier and magnetic carrier |
| US9023457B2 (en) | 2011-11-30 | 2015-05-05 | Corning Incorporated | Textured surfaces and methods of making and using same |
| US10077207B2 (en) | 2011-11-30 | 2018-09-18 | Corning Incorporated | Optical coating method, apparatus and product |
| JP2015506893A (en) | 2011-11-30 | 2015-03-05 | コーニング インコーポレイテッド | Method for making glass articles having optical coating and easy-to-clean coating |
| US8968831B2 (en) | 2011-12-06 | 2015-03-03 | Guardian Industries Corp. | Coated articles including anti-fingerprint and/or smudge-reducing coatings, and/or methods of making the same |
| EP2602655B1 (en) | 2011-12-08 | 2024-04-03 | Essilor International | Ophthalmic filter |
| EP2602653B1 (en) | 2011-12-08 | 2020-09-16 | Essilor International | Method of determining the configuration of an ophthalmic filter |
| JP6099236B2 (en) | 2011-12-09 | 2017-03-22 | コニカミノルタ株式会社 | Anti-reflection coating |
| KR20150040367A (en) | 2011-12-16 | 2015-04-14 | 아사히 가라스 가부시키가이샤 | Display cover glass and display cover glass fabrication method |
| CN103171230A (en) | 2011-12-21 | 2013-06-26 | 鼎力光学有限公司 | Manufacturing method of functional protective sticker |
| US9932663B2 (en) | 2011-12-23 | 2018-04-03 | Hong Kong Baptist University | Sapphire thin film coated substrate |
| US9695501B2 (en) | 2014-09-12 | 2017-07-04 | Hong Kong Baptist University | Sapphire thin film coated substrate |
| CN104160311A (en) | 2012-01-04 | 2014-11-19 | 瑞达克斯科技有限公司 | Method and structure of optical thin film using crystallized nano-porous material |
| KR20130081575A (en) | 2012-01-09 | 2013-07-17 | (주)도 은 | Anti reflective coating layer and manufacturing method thereof |
| CN104040379B (en) | 2012-01-10 | 2016-02-10 | 纳卢克斯株式会社 | Optical multilayer film |
| EP2811324A4 (en) | 2012-01-11 | 2015-09-16 | Konica Minolta Inc | Infrared shielding film |
| JP2013142817A (en) | 2012-01-11 | 2013-07-22 | Dainippon Printing Co Ltd | Antireflection film, polarizer and picture display unit |
| US20130183489A1 (en) | 2012-01-13 | 2013-07-18 | Melissa Danielle Cremer | Reflection-resistant glass articles and methods for making and using same |
| JP2013156523A (en) | 2012-01-31 | 2013-08-15 | Topcon Corp | Substrate |
| US9725357B2 (en) | 2012-10-12 | 2017-08-08 | Corning Incorporated | Glass articles having films with moderate adhesion and retained strength |
| DE102012002927A1 (en) | 2012-02-14 | 2013-08-14 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | An article with reflection-reducing coating and process for its production |
| CN103305816B (en) | 2012-03-14 | 2015-07-15 | 北京科技大学 | High power microwave plasma chemical vapor deposition device for diamond film |
| JP2012132022A (en) | 2012-03-26 | 2012-07-12 | Grandex Co Ltd | Coating paint |
| JP2013205634A (en) | 2012-03-28 | 2013-10-07 | Toppan Printing Co Ltd | Optical film and method for manufacturing the same |
| KR101890790B1 (en) | 2012-03-30 | 2018-08-22 | 어플라이드 머티어리얼스, 인코포레이티드 | Transparent body for use in a touch screen panel manufacturing method and system |
| KR101890781B1 (en) | 2012-03-30 | 2018-08-22 | 어플라이드 머티어리얼스, 인코포레이티드 | Transparent body for use in a touch panel and its manufacturing method and apparatus |
| CN102627407B (en) | 2012-04-13 | 2014-06-18 | 苏州耀亮光电科技有限公司 | Complete anti-glare and local glare treatment process of glass |
| TW201406543A (en) | 2012-04-17 | 2014-02-16 | Mitsubishi Gas Chemical Co | Laminate body |
| JP2013226666A (en) | 2012-04-24 | 2013-11-07 | Mitsubishi Gas Chemical Co Inc | Synthetic resin laminate |
| WO2013160233A1 (en) | 2012-04-24 | 2013-10-31 | Empa Eidgenössische Materialprüfungs- Und Forschungsanstalt | Scratch resistant coating structure and use as optical filter or uv-blocking filter |
| ES2771099T3 (en) | 2012-05-22 | 2020-07-06 | Dsm Ip Assets Bv | Composition and process to produce a porous inorganic oxide coating |
| DE102012208700A1 (en) * | 2012-05-24 | 2013-11-28 | Takata AG | retractor |
| CN104684858B (en) * | 2012-05-29 | 2017-10-24 | 康宁股份有限公司 | Textured method is carried out to glass surface |
| US9007937B2 (en) | 2012-06-02 | 2015-04-14 | International Business Machines Corporation | Techniques for segregating circuit-switched traffic from packet-switched traffic in radio access networks |
| JP2013252992A (en) | 2012-06-07 | 2013-12-19 | Nippon Electric Glass Co Ltd | Dielectric multilayer film, glass plate with dielectric multilayer film and method for producing glass plate with dielectric multilayer film |
| JP2013258209A (en) | 2012-06-11 | 2013-12-26 | Nitto Denko Corp | Sealing sheet, light emitting diode divice, and manufacturing method of light emitting diode divice |
| CN103508678B (en) | 2012-06-14 | 2015-06-17 | 中国科学院理化技术研究所 | Preparation method of wear-resistant anti-reflection coating containing mesopores and wear-resistant anti-reflection coating containing mesopores |
| CN202661651U (en) | 2012-06-21 | 2013-01-09 | 绵阳龙华薄膜有限公司 | Optical thin film |
| CN102736136B (en) | 2012-06-21 | 2015-04-22 | 四川龙华光电薄膜股份有限公司 | Optical film |
| DE102012105571B4 (en) * | 2012-06-26 | 2017-03-09 | Ovd Kinegram Ag | Decorative element as well as security document with a decorative element |
| CN202904161U (en) | 2012-06-28 | 2013-04-24 | 天马微电子股份有限公司 | Liquid crystal light valve and liquid crystal light valve three-dimensional (3D) glasses |
| WO2014011328A1 (en) | 2012-07-09 | 2014-01-16 | Corning Incorporated | Anti-glare and anti-sparkle transparent structures |
| US9588263B2 (en) | 2012-08-17 | 2017-03-07 | Corning Incorporated | Display element having buried scattering anti-glare layer |
| FR2995451B1 (en) | 2012-09-11 | 2014-10-24 | Commissariat Energie Atomique | METHOD FOR METALLIZING A PHOTOVOLTAIC CELL AND PHOTOVOLTAIC CELL THUS OBTAINED |
| JP6051710B2 (en) | 2012-09-14 | 2016-12-27 | リコーイメージング株式会社 | Antireflection film, optical member using the same, and optical instrument |
| TWI606986B (en) | 2012-10-03 | 2017-12-01 | 康寧公司 | Physical vapor deposited layers for protection of glass surfaces |
| EP2903823B1 (en) | 2012-10-03 | 2021-09-22 | Corning Incorporated | Surface-modified glass substrate |
| JP5825685B2 (en) | 2012-10-11 | 2015-12-02 | 株式会社タムロン | Method for manufacturing antireflection film |
| KR101949561B1 (en) | 2012-10-12 | 2019-02-18 | 코닝 인코포레이티드 | Articles having retained strength |
| JP2014081522A (en) | 2012-10-17 | 2014-05-08 | Fujifilm Corp | Optical member provided with anti-reflection film and manufacturing method of the same |
| JP2016001201A (en) | 2012-10-17 | 2016-01-07 | 旭硝子株式会社 | Method for producing glass having antireflection property |
| US20140113120A1 (en) | 2012-10-19 | 2014-04-24 | Ppg Industries Ohio, Inc. | Anti-color banding topcoat for coated articles |
| US20140111859A1 (en) | 2012-10-19 | 2014-04-24 | Corning Incorporated | Scratch resistant polarizing articles and methods for making and using same |
| US8854623B2 (en) | 2012-10-25 | 2014-10-07 | Corning Incorporated | Systems and methods for measuring a profile characteristic of a glass sample |
| CN102967947A (en) | 2012-10-30 | 2013-03-13 | 丁鹏飞 | Manufacturing method of glasses lens film layer |
| CN202924088U (en) | 2012-11-06 | 2013-05-08 | 东莞市纳利光学材料有限公司 | An anti-glare protective film |
| CN202924096U (en) | 2012-11-07 | 2013-05-08 | 东莞市纳利光学材料有限公司 | A shock-resistant self-repairing anti-glare film |
| US20140131091A1 (en) | 2012-11-09 | 2014-05-15 | Nicholas James Smith | Phase transformation coating for improved scratch resistance |
| KR20140061842A (en) | 2012-11-14 | 2014-05-22 | 백승호 | Preparation of photocatalytic water system having anti-reflection effect, super-hydrophilicity action and uv-cut character, and the glass substrate coated with the composition |
| CN203025361U (en) | 2012-11-14 | 2013-06-26 | 东莞市纳利光学材料有限公司 | Anti-glare film for liquid crystal display |
| US9718249B2 (en) | 2012-11-16 | 2017-08-01 | Apple Inc. | Laminated aluminum oxide cover component |
| CN102923969B (en) | 2012-11-22 | 2015-01-07 | 江苏秀强玻璃工艺股份有限公司 | Coated glass with dual functions of visible light antireflection and oil resistance and preparation method thereof |
| US20140154661A1 (en) | 2012-11-30 | 2014-06-05 | Corning Incorporated | Durable glass articles for use as writable erasable marker boards |
| CN107255841B (en) | 2012-11-30 | 2020-01-03 | Agc株式会社 | Near infrared cut-off filter |
| KR102243475B1 (en) | 2012-11-30 | 2021-04-23 | 코닝 인코포레이티드 | Reduced reflection glass articles and methods for making and using same |
| CN103013219B (en) | 2012-12-10 | 2014-07-16 | 合肥乐凯科技产业有限公司 | Curing resin composition for anti-dazzle hard coating and anti-dazzle hard coating |
| CN103013196A (en) | 2012-12-18 | 2013-04-03 | 上海迪道科技有限公司 | Method for manufacturing ultrathin nano-coating used for surface modification of inorganic nonmetallic material |
| US9568362B2 (en) | 2012-12-19 | 2017-02-14 | Viavi Solutions Inc. | Spectroscopic assembly and method |
| US20140174532A1 (en) | 2012-12-21 | 2014-06-26 | Michael P. Stewart | Optimized anti-reflection coating layer for crystalline silicon solar cells |
| US20150346403A1 (en) | 2012-12-27 | 2015-12-03 | Konica Minolta, Inc. | Ir cut filter and image capturing device including same |
| KR20140084686A (en) | 2012-12-27 | 2014-07-07 | 코닝정밀소재 주식회사 | Transparent conductive substrate, manufacturing method thereof, and touch panel having the same |
| JP5617063B1 (en) | 2012-12-28 | 2014-10-29 | 旭硝子株式会社 | Near-infrared cut filter |
| TWI493270B (en) | 2012-12-28 | 2015-07-21 | E Ink Holdings Inc | Display device and fabrication method of display device |
| JP6452620B2 (en) | 2013-01-08 | 2019-01-16 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | Rear projection film with "day / night" effect |
| WO2014117333A1 (en) | 2013-01-30 | 2014-08-07 | Stokvis Tapes (Shanghai) Co. Ltd. | Display devices and methods of assembly |
| CN103099529B (en) | 2013-01-30 | 2013-12-04 | 华建耐尔特(北京)低碳科技有限公司 | Energy-saving light-guiding multifunctional curtain |
| TWI637926B (en) | 2013-02-08 | 2018-10-11 | 康寧公司 | Articles with anti-reflective high-hardness coatings and related methods |
| CN103073196B (en) | 2013-02-08 | 2015-12-02 | 福耀玻璃工业集团股份有限公司 | A kind of low radiation coated glass and laminated glass articles thereof |
| US9977157B2 (en) | 2013-02-13 | 2018-05-22 | Guardian Europe S.à r.l. | Dielectric mirror |
| KR102161958B1 (en) | 2013-02-19 | 2020-10-06 | 에이지씨 가부시키가이샤 | Method for evaluating optical properties of transparent substrate |
| US20140233106A1 (en) | 2013-02-21 | 2014-08-21 | Fraunhofer-Gesellschaft zur Foerderung der angewandten Forschung e.V. | Object with reflection-reducing coating and method for the production thereof |
| JP2014194530A (en) | 2013-02-28 | 2014-10-09 | Asahi Glass Co Ltd | Optical element |
| US9323097B2 (en) | 2013-03-01 | 2016-04-26 | Vladimir Kleptsyn | Reflective color filter and color display device |
| KR101336936B1 (en) | 2013-03-05 | 2013-12-03 | 크루셜텍 (주) | Method of manufacturing cover glass |
| US9328422B2 (en) | 2013-03-06 | 2016-05-03 | Corning Incorporated | Crystallization and bleaching of diamond-like carbon and silicon oxynitride thin films |
| US9012261B2 (en) | 2013-03-13 | 2015-04-21 | Intermolecular, Inc. | High productivity combinatorial screening for stable metal oxide TFTs |
| US8974066B2 (en) * | 2013-03-14 | 2015-03-10 | Intermolecular, Inc. | Optical coatings with plate-shaped particles and methods for forming the same |
| WO2014193513A2 (en) | 2013-03-15 | 2014-12-04 | Enki Technology, Inc. | Tuning the anti-reflective, abrasion resistance, anti-soiling and self-cleaning properties of transparent coatings for different glass substrates and solar cells |
| KR101578914B1 (en) | 2013-03-15 | 2015-12-18 | 주식회사 엘지화학 | Plastic film |
| CN105517976A (en) | 2013-03-28 | 2016-04-20 | 陶瓷技术-Etec有限责任公司 | Ceramic having a functional coating |
| JP2014201456A (en) | 2013-04-02 | 2014-10-27 | 旭硝子株式会社 | Method of manufacturing glass structure, and glass structure |
| CN103254670B (en) | 2013-04-03 | 2016-05-11 | 沭阳凤凰美术颜料有限公司 | A kind of glass-painting pigment |
| WO2014168190A1 (en) | 2013-04-10 | 2014-10-16 | 旭硝子株式会社 | Infrared shielding filter, solid-state imaging element, and imaging/display device |
| JP6443329B2 (en) | 2013-04-10 | 2018-12-26 | Agc株式会社 | Infrared shielding filter and imaging device |
| GB201306611D0 (en) | 2013-04-11 | 2013-05-29 | Pilkington Group Ltd | Heat treatable coated glass pane |
| KR20140126039A (en) | 2013-04-22 | 2014-10-30 | 삼성전자주식회사 | Display device |
| US20140320422A1 (en) | 2013-04-26 | 2014-10-30 | Georgia Tech Research Coporation | Touch-sensitive panel for a communication device |
| US9798163B2 (en) | 2013-05-05 | 2017-10-24 | High Performance Optics, Inc. | Selective wavelength filtering with reduced overall light transmission |
| CN104350010B (en) | 2013-05-06 | 2017-03-22 | 麻省理工学院 | Alkali metal ion sources and methods of formation with moderate ion release rates |
| US9684097B2 (en) | 2013-05-07 | 2017-06-20 | Corning Incorporated | Scratch-resistant articles with retained optical properties |
| US9359261B2 (en) | 2013-05-07 | 2016-06-07 | Corning Incorporated | Low-color scratch-resistant articles with a multilayer optical film |
| US9703011B2 (en) | 2013-05-07 | 2017-07-11 | Corning Incorporated | Scratch-resistant articles with a gradient layer |
| US9110230B2 (en) | 2013-05-07 | 2015-08-18 | Corning Incorporated | Scratch-resistant articles with retained optical properties |
| US9366784B2 (en) | 2013-05-07 | 2016-06-14 | Corning Incorporated | Low-color scratch-resistant articles with a multilayer optical film |
| CN203260587U (en) | 2013-05-13 | 2013-10-30 | 明基材料有限公司 | Organic light-emitting display |
| CN105764866A (en) | 2013-05-23 | 2016-07-13 | 康宁股份有限公司 | Glass-film laminates with controlled failure strength |
| CN103302934B (en) | 2013-05-25 | 2015-09-23 | 甘春丽 | A kind of antifouling light modulation thermal isolation film |
| KR101616918B1 (en) | 2013-05-31 | 2016-04-29 | 제일모직주식회사 | Optical film for reducing color shift and organic light emitting display employing the same |
| US20140368029A1 (en) | 2013-06-13 | 2014-12-18 | Hyundai Motor Company | System for providing vehicle manipulation device information |
| US20160137873A1 (en) | 2013-06-14 | 2016-05-19 | Covestro Deutschland Ag | Glare-free, microstructured, and specially coated film |
| TWI576621B (en) | 2013-06-21 | 2017-04-01 | Lg化學股份有限公司 | A polarizer protecting film, a method for preparing the same, and a polarizer plate comprising the same |
| JP2015006650A (en) | 2013-06-26 | 2015-01-15 | 須知 晃一 | Manufacturing method and constituent materials of cell structure structure cell composite objects |
| CN105359005B (en) | 2013-07-05 | 2018-01-12 | 埃西勒国际通用光学公司 | Optical articles comprising antireflective coatings having very low reflection in the visible region |
| ES2703359T3 (en) | 2013-07-17 | 2019-03-08 | Ferro Corp | Method for forming durable glass enamel |
| JP5650347B1 (en) | 2013-07-18 | 2015-01-07 | 日本合成化学工業株式会社 | Resin molded body, protective plate for display and touch panel substrate, and self-repairing method of resin molded body |
| JP5435168B2 (en) | 2013-07-23 | 2014-03-05 | セイコーエプソン株式会社 | Translucent member and watch |
| WO2015015338A2 (en) | 2013-07-27 | 2015-02-05 | Zeguo Qiu | A method for automatic classification separately collection and automatic transportation of solid waste |
| CN103395247B (en) | 2013-07-30 | 2015-05-13 | 深圳欧菲光科技股份有限公司 | Cover plate glass and preparation method thereof |
| CN203620645U (en) | 2013-08-01 | 2014-06-04 | 京程科技股份有限公司 | Structure of TiO2-Silica Photocatalyst Thin Film |
| EP3027572B1 (en) | 2013-08-01 | 2018-03-07 | Corning Incorporated | Methods and apparatus providing a substrate having a coating with an elastic modulus gradient |
| CN203535376U (en) | 2013-08-22 | 2014-04-09 | 威赛尼特科技有限公司 | Optical front projection hard screen |
| JP2013234571A (en) | 2013-08-28 | 2013-11-21 | Taruno Kazuo | Lifetime care system |
| CN104418511B (en) | 2013-08-28 | 2016-12-28 | 中国科学院理化技术研究所 | Method for constructing super-hydrophilic anti-reflection composite coating on glass substrate |
| WO2015031428A2 (en) | 2013-08-29 | 2015-03-05 | Corning Incorporated | Laminates with a polymeric scratch resistant layer |
| WO2015030118A1 (en) | 2013-08-30 | 2015-03-05 | 株式会社日本触媒 | (meth)acrylic resin |
| TWI500978B (en) | 2013-09-02 | 2015-09-21 | Largan Precision Co Ltd | Infrared filter |
| CN104422971A (en) | 2013-09-11 | 2015-03-18 | 佛山普立华科技有限公司 | Preparation method of antireflection film |
| TWI652501B (en) | 2013-09-13 | 2019-03-01 | 美商康寧公司 | Low color anti-scratch object with multilayer optical film |
| US10160688B2 (en) | 2013-09-13 | 2018-12-25 | Corning Incorporated | Fracture-resistant layered-substrates and articles including the same |
| CN105555729A (en) | 2013-09-18 | 2016-05-04 | 旭硝子株式会社 | Tempered glass plate with low reflective coating and production method therefor |
| JP6152761B2 (en) | 2013-09-18 | 2017-06-28 | 日本電気硝子株式会社 | Film-coated member and manufacturing method thereof |
| JP6071822B2 (en) | 2013-09-18 | 2017-02-01 | 富士フイルム株式会社 | Image forming method |
| JP2015068944A (en) | 2013-09-27 | 2015-04-13 | 大日本印刷株式会社 | Anti-reflection articles |
| CN103499852B (en) | 2013-10-10 | 2016-01-13 | 中国科学院上海技术物理研究所 | blue light filter film for visible light communication |
| JP6280642B2 (en) | 2013-10-14 | 2018-02-14 | コーニング インコーポレイテッド | Glass article with a film having moderate adhesion and residual strength |
| US9480766B2 (en) | 2013-10-21 | 2016-11-01 | Peter C. Van Buskirk | Photocatalytic devices and systems |
| US10324353B2 (en) | 2013-10-22 | 2019-06-18 | Vlyte Innovations Limited | Wide operating temperature range electrophoretic device |
| CN104559625A (en) | 2013-10-28 | 2015-04-29 | 常州光辉化工有限公司 | Hot-melt self-luminous road marking coating and production process thereof |
| KR101517051B1 (en) | 2013-10-30 | 2015-05-04 | 김종현 | Safety mirror and manufacturing method therefor |
| JP2015111241A (en) | 2013-10-30 | 2015-06-18 | 日本電波工業株式会社 | Optical components |
| US9663400B2 (en) | 2013-11-08 | 2017-05-30 | Corning Incorporated | Scratch-resistant liquid based coatings for glass |
| WO2015070254A1 (en) | 2013-11-11 | 2015-05-14 | General Plasma, Inc. | Multiple layer anti-reflective coating |
| CN203567294U (en) | 2013-11-21 | 2014-04-30 | 深圳市瑞丰锦铭科技有限公司 | Novel screen protective film |
| WO2015084253A1 (en) | 2013-12-02 | 2015-06-11 | Ng Poh Mun Louis | We glass business and coating technology |
| WO2015084247A1 (en) | 2013-12-05 | 2015-06-11 | Delaval Holding Ab | Time-of-flight camera system, robot milking system comprising a time-of-flight camera system and method of operating a time-of-flight camera system |
| WO2015085283A1 (en) | 2013-12-06 | 2015-06-11 | General Plasma Inc. | Durable anti-reflective coated substrates for use in electronic-devices displays and other related technology |
| US9880328B2 (en) | 2013-12-12 | 2018-01-30 | Corning Incorporated | Transparent diffusers for lightguides and luminaires |
| KR102396551B1 (en) | 2013-12-19 | 2022-05-12 | 코닝 인코포레이티드 | Textured surfaces for display applications |
| TWI522241B (en) | 2013-12-25 | 2016-02-21 | 恆顥科技股份有限公司 | Film for bonding to a substrate |
| CN203689480U (en) | 2013-12-25 | 2014-07-02 | 龚士杰 | A dual-touch smart mirror screen |
| CN103707578B (en) | 2013-12-26 | 2015-08-05 | 贵阳嘉瑜光电科技咨询中心 | The preparation method of a kind of sapphire-glassy layer compressing tablet |
| US20150185554A1 (en) | 2013-12-31 | 2015-07-02 | Shenzhen China Star Optoelectronics Technology Co. Ltd. | Liquid crystal display and method for manufacturing the same |
| WO2015108266A1 (en) | 2014-01-20 | 2015-07-23 | 엠엔지솔루션 주식회사 | Protective glass production method |
| JP6320057B2 (en) | 2014-01-29 | 2018-05-09 | キヤノン株式会社 | Optical filter and optical device |
| WO2015115154A1 (en) | 2014-01-29 | 2015-08-06 | 日本合成化学工業株式会社 | Molded resin object and use thereof |
| CN103823307B (en) | 2014-02-14 | 2016-08-17 | 京东方科技集团股份有限公司 | True three-dimensional imaging device and display device |
| WO2015125498A1 (en) | 2014-02-24 | 2015-08-27 | キヤノンオプトロン株式会社 | Optical member having antifouling film, and touchscreen |
| JP2015169874A (en) | 2014-03-10 | 2015-09-28 | キヤノン株式会社 | Optical element, optical system, and optical element manufacturing method |
| JP2015171770A (en) | 2014-03-11 | 2015-10-01 | 新日鉄住金化学株式会社 | Glass with anti-scattering performance |
| KR102225279B1 (en) | 2014-03-14 | 2021-03-09 | 니폰 덴키 가라스 가부시키가이샤 | Display cover member and method for manufacturing same |
| KR101617438B1 (en) * | 2014-03-17 | 2016-05-03 | 고봉홍 | Smart ammunition suppling system |
| CN106103370B (en) | 2014-03-21 | 2020-05-01 | 康宁股份有限公司 | Article having a patterned coating |
| DE102014104799B4 (en) | 2014-04-03 | 2021-03-18 | Schott Ag | Substrate with a coating to increase scratch resistance, process for its production and its use |
| DE102014104798B4 (en) | 2014-04-03 | 2021-04-22 | Schott Ag | Hard anti-reflective coatings as well as their manufacture and use |
| CN103921487B (en) | 2014-04-04 | 2015-09-30 | 武汉理工大学 | A kind of anti-dazzle and visible light anti-reflection bifunctional coated glass and preparation method thereof |
| KR102025965B1 (en) | 2014-04-08 | 2019-09-26 | 가부시키가이샤 도모에가와 세이시쇼 | Protective film, film layered product and polarizer |
| CN106461811B (en) | 2014-04-09 | 2019-03-12 | 美国陶氏有机硅公司 | Optical element |
| CN103934756B (en) | 2014-04-20 | 2016-10-05 | 杭州道盈信息科技有限公司 | The processing technology of glare proof glass |
| TWI599489B (en) | 2014-04-25 | 2017-09-21 | 財團法人工業技術研究院 | Panel encapsulation structure |
| US9335444B2 (en) | 2014-05-12 | 2016-05-10 | Corning Incorporated | Durable and scratch-resistant anti-reflective articles |
| CN103964705A (en) | 2014-05-12 | 2014-08-06 | 无锡海特新材料研究院有限公司 | Method for preparing multifunctional automobile glass window film |
| KR101489358B1 (en) | 2014-05-12 | 2015-02-06 | 이상필 | Purification apparatus for compressed air |
| US11267973B2 (en) | 2014-05-12 | 2022-03-08 | Corning Incorporated | Durable anti-reflective articles |
| CN106537190B (en) | 2014-05-23 | 2019-08-16 | 康宁股份有限公司 | Low-contrast anti-reflective articles with reduced scratch and fingerprint visibility |
| KR20170015459A (en) | 2014-06-10 | 2017-02-08 | 후지필름 가부시키가이샤 | Optical functional layer formation composition, solid-state imaging element and camera module using same, pattern formation method for optical functional layer, and method for manufacturing solid-state imaging element and camera module |
| JP2016009172A (en) | 2014-06-26 | 2016-01-18 | 大日本印刷株式会社 | Dimmer and partition member |
| ES2770697T3 (en) | 2014-07-09 | 2020-07-02 | Agc Glass Europe | Low reflection glass sheet |
| CN106536440B (en) | 2014-07-16 | 2020-09-01 | Agc株式会社 | cover glass |
| GB2523859B (en) | 2014-08-01 | 2016-10-19 | Dupont Teijin Films U S Ltd Partnership | Polyester film assembly |
| US9790593B2 (en) | 2014-08-01 | 2017-10-17 | Corning Incorporated | Scratch-resistant materials and articles including the same |
| JP2016041778A (en) | 2014-08-14 | 2016-03-31 | 株式会社巴川製紙所 | Protective film, film laminate and polarizing plate |
| CN105445820A (en) | 2014-08-21 | 2016-03-30 | 宸鸿科技(厦门)有限公司 | Optical film assembly |
| CN105446558B (en) | 2014-08-27 | 2019-06-28 | 欧浦登(顺昌)光学有限公司 | A kind of capacitive touch screen and manufacturing method of dual-layer, single-sided conductor wire electrode film |
| CN106604900B (en) | 2014-08-28 | 2020-05-01 | 康宁股份有限公司 | Method and apparatus for mitigating strength and/or strain loss in coated glass |
| DE102014013528B4 (en) * | 2014-09-12 | 2022-06-23 | Schott Ag | Coated glass or glass-ceramic substrate with stable multifunctional surface properties, method for its production and its use |
| DE102014013550A1 (en) | 2014-09-12 | 2016-03-31 | Schott Ag | Coated chemically tempered flexible thin glass |
| DE102014013527A1 (en) | 2014-09-12 | 2016-03-17 | Schott Ag | Process for producing a coated, chemically tempered glass substrate with anti-fingerprint properties and the glass substrate produced |
| EP3199985A4 (en) | 2014-09-22 | 2017-09-06 | Panasonic Intellectual Property Management Co., Ltd. | Antireflection member |
| BR112017006724A2 (en) * | 2014-10-03 | 2017-12-19 | 3M Innovative Properties Co | methods for managing incident light scattering and articles created from them |
| US20160368308A1 (en) | 2014-10-14 | 2016-12-22 | Corning Incorporated | Method of decorating a substrate surface and articles thereby |
| US10690818B2 (en) * | 2014-10-31 | 2020-06-23 | Corning Incorporated | Anti-glare substrates with a uniform textured surface and low sparkle and methods of making the same |
| WO2016076168A1 (en) | 2014-11-11 | 2016-05-19 | シャープ株式会社 | Semiconductor device and method for making same |
| US9586857B2 (en) | 2014-11-17 | 2017-03-07 | International Business Machines Corporation | Controlling fragmentation of chemically strengthened glass |
| JP6693420B2 (en) | 2014-11-20 | 2020-05-13 | Agc株式会社 | Transparent plate, touch pad, and touch panel |
| CN105737103B (en) | 2014-12-10 | 2018-07-20 | 深圳市光峰光电技术有限公司 | Wavelength converter and fluorescence associated colour wheel and projection arrangement |
| CN104553126B (en) | 2014-12-24 | 2017-08-11 | 宜昌南玻显示器件有限公司 | Anti reflection glass and preparation method thereof |
| CN104845544B (en) | 2014-12-31 | 2017-05-03 | 东莞市纳利光学材料有限公司 | Antibacterial, anti-glare and anti-scratch protective film with double structures and preparation method thereof |
| CN204727835U (en) | 2014-12-31 | 2015-10-28 | 东莞市纳利光学材料有限公司 | A dual-structure antibacterial, anti-glare and anti-scratch protective film |
| US11229131B2 (en) | 2015-01-19 | 2022-01-18 | Corning Incorporated | Enclosures having an anti-fingerprint surface |
| CN104659066B (en) | 2015-02-05 | 2018-02-13 | 京东方科技集团股份有限公司 | A kind of display panel and preparation method thereof and display device |
| US20180050959A1 (en) * | 2015-03-24 | 2018-02-22 | Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften E.V. | Fabrication of nanostructures in and on organic and inorganic substrates using mediating layers |
| JP6720473B2 (en) | 2015-04-09 | 2020-07-08 | Dic株式会社 | Light emitting device, lighting fixture, information display device, and method for manufacturing light emitting device |
| KR20180001556A (en) | 2015-05-22 | 2018-01-04 | 다이킨 고교 가부시키가이샤 | Method for manufacturing article having surface treated layer |
| US9809730B2 (en) | 2015-06-10 | 2017-11-07 | Upm Raflatac Oy | Printable label comprising a clear face layer and a clear adhesive layer |
| WO2016204009A1 (en) | 2015-06-16 | 2016-12-22 | Jxエネルギー株式会社 | Sheet transparent laminate, transparent screen provided therewith, and image projection system provided therewith |
| DE102015007830B4 (en) * | 2015-06-18 | 2017-12-28 | e.solutions GmbH | Optical assembly, electronic device and motor vehicle with an optical assembly and method for producing an optical assembly |
| JP2015167470A (en) | 2015-06-23 | 2015-09-24 | 墫野 和夫 | Foundation-managed future agriculture, fishery and forestry integrated small to medium enterprise system |
| EP3320381B1 (en) | 2015-07-07 | 2022-08-31 | 3M Innovative Properties Company | Polyurethane layer for a light directing article |
| DE102015213075A1 (en) | 2015-07-13 | 2017-01-19 | Schott Ag | Asymmetrically constructed thin-glass pane chemically tempered on both sides of the surface, process for their production and their use |
| US20170018408A1 (en) * | 2015-07-15 | 2017-01-19 | Lam Research Corporation | Use of sintered nanograined yttrium-based ceramics as etch chamber components |
| CN106378880A (en) | 2015-07-27 | 2017-02-08 | 惠州市德赛西威汽车电子股份有限公司 | Manufacturing method for mold internal decoration molding of vehicle-mounted center control integrated plastic curved surface panel |
| CN204894681U (en) | 2015-08-19 | 2015-12-23 | 东莞市银通玻璃有限公司 | A high-strength decorative glass |
| KR20170028190A (en) | 2015-09-03 | 2017-03-13 | 주식회사 엠코드 | Glass or Film Coating Layers of Vehicle Display and the Coating Method for It |
| DE102015114877B4 (en) | 2015-09-04 | 2020-10-01 | Schott Ag | Scratch-resistant anti-reflective coating and mobile electronic device |
| CN108025962B (en) | 2015-09-11 | 2021-04-30 | 肖特玻璃科技(苏州)有限公司 | Method for producing a tempered glass article with a durable functional coating and tempered glass article with a durable functional coating |
| JP6915541B2 (en) | 2015-09-11 | 2021-08-04 | 日本電気硝子株式会社 | Display cover member and its manufacturing method |
| EP3770649A1 (en) | 2015-09-14 | 2021-01-27 | Corning Incorporated | High light transmission and scratch-resistant anti-reflective articles |
| CN106338783B (en) | 2015-09-17 | 2018-08-14 | 湖北航天化学技术研究所 | A kind of anti-dazzle antireflective optical film and its preparation method and application |
| JP6582974B2 (en) | 2015-12-28 | 2019-10-02 | Agc株式会社 | Cover glass and manufacturing method thereof |
| CN205368144U (en) | 2016-01-12 | 2016-07-06 | 慧思维(天津)科技有限公司 | Anti -dazzle anti -reflection glass |
| US11795102B2 (en) | 2016-01-26 | 2023-10-24 | Corning Incorporated | Non-contact coated glass and related coating system and method |
| WO2017135261A1 (en) | 2016-02-01 | 2017-08-10 | 旭硝子株式会社 | Translucent structure |
| US10462273B2 (en) | 2016-02-05 | 2019-10-29 | Sabic Global Technologies B.V. | Foldable cover assembly, method of manufacture, and device comprising the foldable cover assembly |
| CN105688560A (en) | 2016-02-26 | 2016-06-22 | 侯英翔 | Manufacturing method for improving coal economic value and using coal as dust reduction material |
| EP3210947A1 (en) | 2016-02-29 | 2017-08-30 | Agfa-Gevaert | Method of manufacturing an etched glass article |
| CN109071302B (en) | 2016-03-09 | 2022-04-26 | 康宁股份有限公司 | Cold forming of complexly curved glass articles |
| CN105859148B (en) | 2016-03-29 | 2018-03-20 | 中科院广州化学有限公司南雄材料生产基地 | A kind of anti-dazzle coating material of glass surface and preparation method thereof |
| CN205687804U (en) | 2016-04-01 | 2016-11-16 | 江苏秀强玻璃工艺股份有限公司 | Cut-off royal purple light and antireflective visible ray display screen protection substrate |
| US10401539B2 (en) | 2016-04-21 | 2019-09-03 | Corning Incorporated | Coated articles with light-altering features and methods for the production thereof |
| CN115028356B (en) | 2016-04-29 | 2024-07-12 | 肖特玻璃科技(苏州)有限公司 | High strength ultra-thin glass and method for manufacturing same |
| CN105843452B (en) | 2016-05-13 | 2019-11-01 | 中航华东光电有限公司 | A kind of low reflection OLED display of integrated resistor touch function |
| EP3468931B1 (en) | 2016-06-13 | 2023-05-10 | Corning Incorporated | Scratch-resistant and optically transparent materials and articles |
| JP6844396B2 (en) | 2016-06-30 | 2021-03-17 | Agc株式会社 | UV transmission filter |
| CN205818592U (en) | 2016-07-08 | 2016-12-21 | 安徽省光学膜材料工程研究院有限公司 | A kind of screen optical filtering screening glass |
| CN106113837A (en) | 2016-07-08 | 2016-11-16 | 安徽省光学膜材料工程研究院有限公司 | A kind of screen optical filtering screening glass |
| US9991133B2 (en) * | 2016-08-11 | 2018-06-05 | Tokyo Electron Limited | Method for etch-based planarization of a substrate |
| JP2019189465A (en) | 2016-08-29 | 2019-10-31 | Agc株式会社 | Method of producing antiglare plate glass |
| CN106199812B (en) | 2016-08-30 | 2019-08-06 | 苏州柔彩新材料科技有限公司 | A kind of thinning functional polarizing piece and its preparation method and application |
| CN106431004A (en) | 2016-09-06 | 2017-02-22 | 江苏秀强玻璃工艺股份有限公司 | Blue-light-cutoff and anti-reflexion dual-function coated glass and preparation method therefor |
| KR102616406B1 (en) | 2016-09-30 | 2023-12-20 | 엘지디스플레이 주식회사 | Display device |
| KR102505252B1 (en) | 2016-12-30 | 2023-03-03 | 코닝 인코포레이티드 | Coated products with optical coatings with residual compressive stress |
| US10725230B1 (en) * | 2017-04-18 | 2020-07-28 | Amazon Technologies, Inc. | Dual-color frontlit displays with near uniform color mixing |
| CN106941545A (en) | 2017-05-05 | 2017-07-11 | 浙江昱鑫光电科技有限公司 | Mobile phone 3D curved surface cover plates |
| EP3622332A2 (en) | 2017-05-08 | 2020-03-18 | Corning Incorporated | Reflective, colored, or color-shifting scratch resistant coatings and articles |
| CN107310209A (en) | 2017-05-19 | 2017-11-03 | 合肥市惠科精密模具有限公司 | A kind of multi-functional AMOLED screen protections cuticula |
| CN107042642A (en) | 2017-06-14 | 2017-08-15 | 深圳市利和腾鑫科技有限公司 | A kind of processing method of rupture pressure disc |
| WO2019026468A1 (en) | 2017-08-04 | 2019-02-07 | 株式会社ダイセル | Antiglare film |
| US10919473B2 (en) | 2017-09-13 | 2021-02-16 | Corning Incorporated | Sensing system and glass material for vehicles |
| US11548810B2 (en) | 2017-09-14 | 2023-01-10 | Corning Incorporated | Textured glass-based articles with scratch resistance and methods of making the same |
| FR3072958B1 (en) * | 2017-10-30 | 2022-05-06 | Eurokera | VITROCERAMIC ARTICLE PROVIDED WITH A LAYER AND METHOD FOR OBTAINING |
| TWI821234B (en) | 2018-01-09 | 2023-11-11 | 美商康寧公司 | Coated articles with light-altering features and methods for the production thereof |
| WO2019169293A1 (en) * | 2018-03-02 | 2019-09-06 | Corning Incorporated | Anti-reflective coatings and articles and methods of forming the same |
| JPWO2019187512A1 (en) | 2018-03-27 | 2020-12-03 | 富士フイルム株式会社 | Translucent member, image display device and clock |
| EP3837223A1 (en) | 2018-08-17 | 2021-06-23 | Corning Incorporated | Inorganic oxide articles with thin, durable anti-reflective structures |
| US12092836B2 (en) * | 2018-10-26 | 2024-09-17 | Viavi Solutions Inc. | Optical element and optical system |
| EP3939819A1 (en) | 2018-12-10 | 2022-01-19 | Corning Incorporated | Dynamically bendable automotive interior display systems |
| US11372137B2 (en) | 2019-05-29 | 2022-06-28 | Apple Inc. | Textured cover assemblies for display applications |
| US11306024B2 (en) | 2019-05-30 | 2022-04-19 | Corning Incorporated | Textured glass articles and methods of making the same |
| US11109500B2 (en) * | 2019-06-05 | 2021-08-31 | Apple Inc. | Textured glass component for an electronic device enclosure |
| US12030805B2 (en) | 2019-09-09 | 2024-07-09 | Corning Incorporated | Textured, antiglare glass articles and methods of making the same |
| US12147009B2 (en) | 2020-07-09 | 2024-11-19 | Corning Incorporated | Textured region to reduce specular reflectance including a low refractive index substrate with higher elevated surfaces and lower elevated surfaces and a high refractive index material disposed on the lower elevated surfaces |
| US20240036236A1 (en) | 2020-12-11 | 2024-02-01 | Corning Incorporated | Cover glass articles for camera lens and sensor protection and apparatus with the same |
| CN112919819B (en) | 2021-02-23 | 2022-05-27 | 芜湖长信科技股份有限公司 | A kind of manufacturing method of anti-glare glass without flash point |
| CN215365506U (en) | 2021-06-21 | 2021-12-31 | 芜湖长信科技股份有限公司 | Circular hole etching glass |
| JP7845232B2 (en) | 2023-03-09 | 2026-04-14 | トヨタ自動車株式会社 | Thermal management system |
| JP2025019888A (en) | 2023-07-28 | 2025-02-07 | ブラザー工業株式会社 | Feeding device |
-
2021
- 2021-07-07 US US17/369,279 patent/US12147009B2/en active Active
- 2021-07-07 US US17/369,315 patent/US12386101B2/en active Active
- 2021-07-07 US US17/369,301 patent/US20220009824A1/en not_active Abandoned
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-
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Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100177398A1 (en) * | 2009-01-09 | 2010-07-15 | Sony Corporation | Optical element and method for making the same, master and method for making the same, and display apparatus |
| EP3178796A1 (en) * | 2010-04-30 | 2017-06-14 | Corning Incorporated | Glass article comprising anti-glare surface |
| US9411180B2 (en) | 2011-02-28 | 2016-08-09 | Corning Incorporated | Apparatus and method for determining sparkle |
| US20150174625A1 (en) * | 2011-11-30 | 2015-06-25 | Corning Incorporated | Articles with monolithic, structured surfaces and methods for making and using same |
| US20180128957A1 (en) * | 2015-05-15 | 2018-05-10 | Corning Incorporated | Glass article comprising light extraction features and methods for making the same |
| WO2020013012A1 (en) * | 2018-07-09 | 2020-01-16 | 日本板硝子株式会社 | Glass plate suitable for image display device |
| EP3822234A1 (en) * | 2018-07-09 | 2021-05-19 | Nippon Sheet Glass Company, Limited | Glass plate suitable for image display device |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12195384B2 (en) | 2013-05-07 | 2025-01-14 | Corning Incorporated | Scratch-resistant laminates with retained optical properties |
| US12019209B2 (en) | 2018-01-09 | 2024-06-25 | Corning Incorporated | Coated articles with light-altering features and methods for the production thereof |
| US11940593B2 (en) | 2020-07-09 | 2024-03-26 | Corning Incorporated | Display articles with diffractive, antiglare surfaces and methods of making the same |
| US12147009B2 (en) | 2020-07-09 | 2024-11-19 | Corning Incorporated | Textured region to reduce specular reflectance including a low refractive index substrate with higher elevated surfaces and lower elevated surfaces and a high refractive index material disposed on the lower elevated surfaces |
| US12352924B2 (en) | 2020-07-09 | 2025-07-08 | Corning Incorporated | Display articles with diffractive, antiglare surfaces and methods of making the same |
| US12360290B2 (en) | 2020-07-09 | 2025-07-15 | Corning Incorporated | Display articles with antiglare surfaces and thin, durable antireflection coatings |
| US12386101B2 (en) | 2020-07-09 | 2025-08-12 | Corning Incorporated | Textured region of a substrate to reduce specular reflectance incorporating surface features with an elliptical perimeter or segments thereof, and method of making the same |
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