WO2021145202A1 - 塗工機、フィルムの製造システム、および、フィルムの製造方法 - Google Patents

塗工機、フィルムの製造システム、および、フィルムの製造方法 Download PDF

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Publication number
WO2021145202A1
WO2021145202A1 PCT/JP2020/048879 JP2020048879W WO2021145202A1 WO 2021145202 A1 WO2021145202 A1 WO 2021145202A1 JP 2020048879 W JP2020048879 W JP 2020048879W WO 2021145202 A1 WO2021145202 A1 WO 2021145202A1
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WIPO (PCT)
Prior art keywords
coating
manifold
base material
coating liquid
discharge port
Prior art date
Application number
PCT/JP2020/048879
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English (en)
French (fr)
Japanese (ja)
Inventor
山下　裕司
大前　通宏
雅 品川
Original Assignee
日東電工株式会社
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Application filed by 日東電工株式会社 filed Critical 日東電工株式会社
Priority to CN202080091168.1A priority Critical patent/CN114901401A/zh
Priority to KR1020227022808A priority patent/KR102475550B1/ko
Publication of WO2021145202A1 publication Critical patent/WO2021145202A1/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/04—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
    • B05C1/08—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/12—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic

Definitions

  • the present invention relates to a coating machine, a film manufacturing system, and a film manufacturing method.
  • a bar coater is known as a coating machine that applies a coating liquid to the surface of a resin base material (see, for example, Patent Document 1).
  • a coating liquid containing air bubbles may be applied to the base material.
  • the present invention provides a coating machine capable of suppressing the application of a coating liquid containing air bubbles to a base material, a film manufacturing system, and a film manufacturing method.
  • the present invention is a coating member for applying a coating liquid to a base material, wherein the coating member extending in an axial direction orthogonal to the flow direction of the base material and the coating liquid are collected.
  • a manifold block having one manifold and supporting the coating member is provided, and the manifold block is arranged on the upstream side of the coating member in the flow direction and has a first discharge port for discharging the coating liquid.
  • a second discharge port which is arranged on the downstream side of the coating member in the flow direction and discharges the coating liquid, a first flow path connecting the first manifold and the first discharge port, and the above. Includes a coating machine having a second flow path that branches off from the first flow path and connects to the second discharge port.
  • the air on the surface of the coating member can be removed by the coating liquid discharged from the second discharge port.
  • first manifold leads to the first discharge port via the first flow path and also leads to the second discharge port via the second flow path branched from the first flow path.
  • the size of the manifold leading to the first discharge port and the manifold leading to the second discharge port can be reduced as compared with the case where the manifold is provided independently.
  • the manifold block is arranged on the upstream side with respect to the coating member in the flow direction, and faces the coating member at a distance from the first lip in the flow direction. It has a second lip that is arranged on the downstream side of the coating member and faces the coating member at a distance, and the space between the first lip and the coating member is the first discharge.
  • the second outlet is between the second lip and the coating member, and the second lip is orthogonal to both the flow direction and the axial direction.
  • the coating machine according to the above [1] is included, which is arranged more away from the base material than one lip.
  • the second lip is arranged farther from the base material than the first lip in the orthogonal direction.
  • the coating liquid discharged from the first discharge port can be applied to the base material
  • the coating liquid that has come into contact with the coating member in the second discharge port gets over the second lip so as not to come into contact with the base material. It can be discharged (overflowing from the second discharge port).
  • the manifold block is an inclined surface that connects to the second lip, and is an inclined surface that inclines in a direction away from the base material as the second lip moves toward the downstream side in the flow direction.
  • the coating machine of the above [2] is included.
  • the coating liquid that has passed over the second lip can be smoothly discharged along the inclined surface connected to the second lip so as not to come into contact with the base material.
  • the first flow path is a second manifold in which the coating liquid is collected, and includes the first discharge port and the second manifold communicating with the second flow path.
  • the first flow path is a second manifold in which the coating liquid is collected, and includes the first discharge port and the second manifold communicating with the second flow path.
  • the amount of coating liquid discharged from the first discharge port is increased in the axial direction due to the influence of the coating liquid flowing from the first flow path to the second flow path. May be non-uniform.
  • the influence of the flow of the coating liquid from the first flow path to the second flow path can be buffered by the second manifold.
  • the coating liquid can be uniformly discharged from the first discharge port in the axial direction.
  • the width of the first discharge port in a direction orthogonal to the axial direction is the direction in which the coating liquid flows in the second manifold and is orthogonal to both the axial direction.
  • the coating machine of the above [4], which is narrower than the width of the second manifold, is included.
  • the width of the second discharge port in a direction orthogonal to the axial direction is a direction orthogonal to both the direction in which the coating liquid flows in the second flow path and the axial direction.
  • the coating machine according to the above [4] or [5], which is wider than the width of the second flow path, is included.
  • the coating liquid that has passed through the second flow path can be stored in the second discharge port.
  • a baffle portion is provided in which the second manifold is arranged away from the first manifold and the first flow path is arranged between the first manifold and the second manifold. Further included, the above-mentioned coating machines [4] to [6] are included.
  • the present invention [8] includes any one of the above [1] to [7], wherein at least a part of the inner surface of the first manifold is a curved surface.
  • the manifold block is a main body block having the first manifold and a support block that can be attached to and detached from the main body block to support the coating member and provide the second flow path.
  • the coating machine according to any one of the above [1] to [8] is included, which comprises a support block having the support block.
  • the present invention includes a coating machine according to any one of the above [1] to [9], wherein the coating member is a bar.
  • the present invention is a film manufacturing system, which comprises an extrusion molding machine for extrusion molding the base material and a coating machine according to any one of the above [1] to [10].
  • a film manufacturing system comprising a coating machine for applying the coating liquid and a stretching machine for stretching the base material to which the coating liquid is applied.
  • the yield of the film can be improved.
  • the present invention [12] is an easy-adhesion film in which the film includes the base material and an easy-adhesion layer arranged on the base material, and the coating liquid forms the easy-adhesion layer.
  • the yield of the easy-adhesive film can be improved.
  • the present invention is a method for producing a film, which is extruded by an extrusion molding step of extrusion molding the base material and an extrusion molding step of any one of the above [1] to [10].
  • the film manufacturing method includes a coating step of applying the coating liquid to the molded base material and a stretching step of stretching the base material to which the coating liquid has been applied by the coating step.
  • the coating liquid can be applied to the base material by the above-mentioned coating machine, it is possible to suppress the coating liquid containing air bubbles from being applied to the base material.
  • the yield of the film can be improved.
  • the present invention [14] is an easy-adhesion film in which the film includes the base material and an easy-adhesion layer arranged on the base material, and the coating liquid forms the easy-adhesion layer.
  • the film is an easy-adhesion composition for the above, and includes the method for producing a film according to the above [13], which contains a resin component and fine particles.
  • the yield of the easy-adhesive film can be improved.
  • the film manufacturing system According to the coating machine of the present invention, the film manufacturing system, and the film manufacturing method, it is possible to prevent the coating liquid containing bubbles from being applied to the base material.
  • FIG. 1 is a cross-sectional view of a film manufactured by a film manufacturing system as an embodiment of the present invention.
  • FIG. 2 is a schematic configuration diagram of a film manufacturing system.
  • FIG. 3 is a side view of the bar coater seen from the upstream side in the flow direction.
  • FIG. 4 is a cross-sectional view taken along the line AA of the bar coater shown in FIG.
  • FIG. 5 is an enlarged view of a part of the bar coater shown in FIG.
  • FIG. 6 is a side view of the second main body block shown in FIG. 4 as viewed from the upstream side in the flow direction.
  • FIG. 7 is a plan view of the baffle plate.
  • FIG. 8 is a cross-sectional view taken along the line BB of the support block shown in FIG.
  • the film F includes a base material S and a film C.
  • the base material S has a first surface S1 and a second surface S2 in the thickness direction of the base material S.
  • the coating film C is arranged on the first surface S1 of the base material S.
  • the coating film C covers the first surface S1 of the base material S.
  • the coating film C may be an easy-adhesion layer.
  • the film F is an easy-adhesive film.
  • the easy-adhesive film is used, for example, as a polarizing plate of an image display device such as a mobile device, a car navigation device, a monitor for a personal computer, or a television.
  • the easy-adhesive film is used as a protective film that protects the polarizer of the polarizing plate.
  • the easy-adhesive film is bonded to the polarizer via an adhesive layer.
  • the easy-adhesive film is an easy-adhesive layer and is bonded to a polarizer.
  • the film F manufacturing system 1 includes an extrusion molding machine 2, a first stretching machine 4A, a bar coater 3 as an example of a coating machine, and a second stretching machine as an example of a stretching machine. It includes 4B, a slit processing machine 5, a knurling processing machine 6, and a winding machine 7.
  • the extrusion molding machine 2 extrudes the base material S (extrusion molding step).
  • the base material S extruded from the extrusion molding machine 2 has a sheet shape.
  • the base material S is made of a thermoplastic resin.
  • the thermoplastic resin include cellulose-based polymers such as acrylic resin, polyolefin resin, cyclic polyolefin resin, polyester resin, polycarbonate resin, polystyrene resin, polyamide resin, polyimide resin, and acetate resin (diacetyl cellulose, triacetyl cellulose, etc.). Can be mentioned.
  • the material of the base material S is preferably an acrylic resin.
  • the acrylic resin may be an acrylic resin having a glutaric anhydride structure or an acrylic resin having a lactone ring structure.
  • An acrylic resin having a glutaric anhydride structure and an acrylic resin having a lactone ring structure have high heat resistance, high transparency, and high mechanical strength, so that the polarizing plate has a high degree of polarization and excellent durability. Suitable for manufacturing.
  • Acrylic resins having a glutaric anhydride structure are described in JP-A-2006-283013, JP-A-2006-335902, and JP-A-2006-274118.
  • Acrylic resins having a lactone ring structure are described in JP-A-2000-230016, JP-A-2001-151814, JP-A-2002-120326, JP-A-2002-254544, and JP-A-2005-146084. Has been done.
  • the base material S may contain a thermoplastic resin other than the acrylic resin in addition to the acrylic resin.
  • a thermoplastic resin By containing another thermoplastic resin, it is possible to cancel the birefringence of the acrylic resin and obtain an easily adhesive film having excellent optical isotropic properties. It is also possible to improve the mechanical strength of the easy-adhesive film.
  • the base material S may contain additives such as antioxidants, stabilizers, reinforcing materials, ultraviolet absorbers, flame retardants, antistatic agents, colorants, fillers, plasticizers, lubricants, and fillers. ..
  • the first stretching machine 4A heats the base material S obtained by the extrusion molding step and then stretches the base material S in the flow direction MD of the base material S (first stretching step).
  • the bar coater 3 applies a coating liquid to the first surface S1 of the base material S extruded by the extrusion molding step (coating step).
  • the first surface S1 of the base material S may be subjected to surface treatment such as corona treatment and plasma treatment after the extrusion molding step and before the coating step.
  • the coating liquid is an easy-adhesive composition for forming an easy-adhesive layer.
  • the easy-adhesion layer contains a binder resin and fine particles.
  • the binder resin examples include thermosetting resins such as urethane resin and epoxy resin, and thermoplastic resins such as acrylic resin and polyester resin.
  • the binder resin is preferably a thermosetting resin.
  • a plurality of types of binder resins can be used in combination.
  • the fine particles include oxides such as silicon oxide (silica), titanium oxide (titania), aluminum oxide (alumina), and zirconium oxide (zirconia), and carbonates such as calcium carbonate, such as calcium silicate and calcium silicate.
  • oxides such as silicon oxide (silica), titanium oxide (titania), aluminum oxide (alumina), and zirconium oxide (zirconia)
  • carbonates such as calcium carbonate, such as calcium silicate and calcium silicate.
  • examples thereof include silicates such as aluminum acetate and magnesium silicate, for example, silicate minerals such as talc and kaolin, for example, phosphates such as calcium phosphate.
  • the fine particles are preferably oxides, more preferably silicon oxide. A plurality of types of fine particles can be used in combination.
  • the coating liquid (easy-adhesion composition) contains a resin component, the above-mentioned fine particles, and a dispersion medium.
  • the resin component forms the above-mentioned binder resin film (easy-adhesive layer) by the stretching step described later.
  • the binder resin is a urethane resin
  • examples of the resin component include an aqueous urethane resin.
  • examples of the aqueous urethane resin include a non-reactive aqueous urethane resin which is an emulsion of a urethane resin, and a reactive aqueous urethane resin which is an emulsion of a urethane resin in which an isocyanate group is protected with a blocking agent.
  • the coating liquid may contain a urethane curing catalyst (triethylamine or the like) and an isocyanate monomer.
  • dispersion medium examples include water, alcohols such as methanol and ethanol, and ketones such as acetone and methyl ethyl ketone.
  • the second stretching machine 4B dries the coating liquid applied by the coating process. As a result, the coating liquid becomes the above-mentioned film C. Further, the second stretching machine 4B heats the base material S on which the coating film C is formed and then stretches the base material S in the width direction TD of the base material S (second stretching step). The width direction TD is orthogonal to the flow direction MD. By the second stretching step, the base material S on which the coating film C is formed is stretched to obtain the above-mentioned film F.
  • the slit processing machine 5 cuts the film F stretched by the stretching step into a predetermined width (slit step).
  • Knurling machine 6 forms knurling at both ends in the width direction of the film F cut to a predetermined width by the slitting process (knurling process).
  • Knar is formed by a laser.
  • Knar may be formed by heated embossed rolls.
  • Winding machine 7 winds up the film F on which knurling is formed by the knurling process (winding process). When the winding process is completed, a roll of film F can be obtained.
  • the bar coater 3 includes a bar 11 as an example of a coating member and a manifold block 12.
  • the bar bar 11 applies a coating liquid to the base material S in the above-mentioned coating process.
  • the bar 11 extends axially.
  • the axial direction is the same as the width direction TD of the base material S. That is, the axial direction is orthogonal to the flow direction MD of the base material S.
  • the bar 11 is arranged at the upper end of the bar coater 3. In other words, the bar 11 is arranged at one end of the bar coater 3 in the orthogonal direction orthogonal to both the axial direction and the flow direction MD.
  • the bar 11 has a cylindrical shape.
  • the bar 11 has one end E1 and the other end E2 in the axial direction.
  • the length of the bar 11 in the axial direction is longer than the length of the manifold block 12 in the axial direction.
  • the one end portion E1 is arranged on one side of the manifold block 12 in the axial direction.
  • One end E1 of the bar 11 is attached to a base (not shown) via a bearing such as a ball bearing B.
  • One end E1 is connected to a motor (not shown).
  • the other end E2 is arranged on the other side of the manifold block 12 in the axial direction. In other words, the other end E2 is arranged on the opposite side of the one end E1 with respect to the manifold block 12 in the axial direction.
  • the other end E2 is attached to a base (not shown) via a bearing such as a ball bearing B.
  • the bar 11 rotates forward in the flow direction (see the arrow in FIG. 4) by power from a motor (not shown).
  • Examples of the bar 11 include a wire bar in which a wire is wound around a shaft, for example, a wireless bar in which a concave groove is formed in the shaft.
  • a groove is formed between the wires in the axial direction.
  • the bar 11 may be subjected to surface treatment such as chrome plating or diamond-like carbon coating.
  • surface treatment such as chrome plating or diamond-like carbon coating.
  • the bar 11 is preferably diamond-like carbon coated from the viewpoint of improving wear resistance.
  • the manifold block 12 is arranged between one end E1 and the other end E2 of the bar 11 in the axial direction.
  • the manifold block 12 is mounted on a base (not shown).
  • the manifold block 12 extends in the axial and orthogonal directions.
  • the manifold block 12 supports the bar 11.
  • the manifold block 12 includes a supply port 121, a first manifold 122, a first discharge port 123, a first flow path 124, a second discharge port 125, and a second flow path 126.
  • the supply port 121 is arranged at the center of the manifold block 12 in the axial direction.
  • the supply port 121 is connected to the pump via a pipe. Piping and pumps are not shown.
  • the coating liquid is supplied to the supply port 121 by a pump.
  • the supply port 121 leads to the first manifold 122 (see FIG. 4).
  • the first manifold 122 is arranged away from the bar 11 in the orthogonal direction.
  • the first manifold 122 is arranged at the center of the manifold block 12 in the orthogonal direction.
  • the first manifold 122 extends in the axial direction.
  • the first manifold 122 communicates with the supply port 121.
  • the coating liquid supplied to the supply port 121 collects in the first manifold 122.
  • the first manifold 122 has a substantially semicircular shape in cross-sectional view. Specifically, the first manifold 122 has an inner surface 122A and an inner surface 122B.
  • the inner surface 122A is a flat surface.
  • the inner surface 122A extends in the orthogonal direction.
  • the inner surface 122B is arranged on the opposite side of the supply port 121 with respect to the inner surface 122A.
  • the inner surface 122B is a curved surface. That is, at least a part of the inner surface of the first manifold 122 is a curved surface. Since the inner surface 122B has a curved surface, it is possible to prevent the coating liquid from staying in the first manifold 122 for a long period of time.
  • the first discharge port 123 is arranged at one end of the manifold block 12 in the orthogonal direction.
  • the first discharge port 123 is arranged on the upstream side of the bar 11 in the flow direction MD.
  • the first discharge port 123 discharges the coating liquid.
  • the coating liquid discharged from the first discharge port 123 is applied to the base material S by the rotation of the bar 11.
  • the coating liquid L1 that was not applied to the base material S flows on the surface of the manifold block 12. Collected in a coating liquid tank (not shown).
  • the first discharge port 123 extends in the axial direction.
  • the first flow path 124 is arranged between the first manifold 122 and the first discharge port 123 in the orthogonal direction.
  • the first flow path 124 connects the first manifold 122 and the first discharge port 123.
  • the coating liquid in the first manifold 122 is discharged from the first discharge port 123 through the first flow path 124.
  • the first flow path 124 has a second manifold 124A and a baffle portion 124B.
  • the second manifold 124A is arranged between the first manifold 122 and the first discharge port 123 in the orthogonal direction.
  • the second manifold 124A is arranged away from the first manifold 122 in the orthogonal direction.
  • the second manifold 124A extends in the orthogonal direction.
  • the second manifold 124A extends in the axial direction.
  • the length of the second manifold 124A in the axial direction is substantially the same as the length of the first discharge port 123 in the axial direction.
  • the coating liquid in the first manifold 122 flows into the second manifold 124A through the baffle portion 124B.
  • the coating liquid that has flowed into the second manifold 124A collects in the second manifold 124A.
  • the second manifold 124A communicates with the first discharge port 123.
  • the coating liquid in the second manifold 124A is discharged from the first discharge port 123.
  • the width W1 of the first discharge port 123 in the direction orthogonal to the axial direction is the second manifold in the direction orthogonal to both the direction in which the coating liquid flows in the second manifold 124A and the axial direction. It is narrower than the width W2 of 124A. Therefore, it is possible to prevent the coating liquid in the second manifold 124A from being excessively discharged from the first discharge port 123.
  • the baffle portion 124B is arranged between the first manifold 122 and the second manifold 124A.
  • the baffle portion 124B extends in the orthogonal direction.
  • a baffle plate 13C (see FIG. 7), which will be described later, is arranged in the baffle portion 124B. Due to the pressure loss in the baffle portion 124B, the influence of the pulsation of the pump on the discharge amount of the coating liquid from the first discharge port 123 and the second discharge port 125 can be suppressed.
  • the second discharge port 125 is arranged at one end of the manifold block 12 in the orthogonal direction.
  • the second discharge port 125 is arranged on the downstream side of the bar 11 in the flow direction MD.
  • the second discharge port 125 is arranged on the opposite side of the first discharge port 123 with respect to the bar 11 in the flow direction MD.
  • the bar 11 is arranged between the first discharge port 123 and the second discharge port 125 in the flow direction MD.
  • the coating liquid collects in the second discharge port 125.
  • the coating liquid in the second discharge port 125 comes into contact with the bar 11.
  • the coating liquid discharged from the first discharge port 123 by the bar 11 is applied to the base material S, the coating liquid in the groove of the bar 11 is lost. At this time, air enters the groove of the bar 11 instead of the coating liquid.
  • the bar 11 rotates while the air is in the groove of the bar 11, the air is mixed with the coating liquid in the first flow path 124 (in the present embodiment, the coating liquid in the second manifold 124A). Bubbles in the coating liquid. Then, the coating liquid containing air bubbles may be discharged from the first discharge port 123 and coated on the base material S.
  • the coating liquid in the second discharge port 125 comes into contact with the bar 11
  • the coating liquid in the second discharge port 125 enters the groove of the bar 11 instead of the air. Therefore, the air that has entered the groove of the bar 11 can be removed, and it is possible to suppress the inclusion of air bubbles in the coating liquid in the first flow path 124. As a result, it is possible to prevent the coating liquid containing air bubbles from being applied to the base material S.
  • the coating liquid in the second discharge port 125 in contact with the bar 11 overflows from the second discharge port 125.
  • the second discharge port 125 discharges the coating liquid.
  • the coating liquid L2 discharged from the second discharge port 125 is not applied to the base material S, but is on the surface of the manifold block 12 (see the inclined surface 142 and FIG. 5 described later). Is collected in a coating liquid tank (not shown).
  • the second discharge port 125 extends in the axial direction.
  • Second flow path 126 branches from the first flow path 124 and connects to the second discharge port 125. That is, the first manifold 122 leads to the first discharge port 123 via the first flow path 124, and also leads to the second discharge port 125 via the second flow path 126 branched from the first flow path 124. .. Therefore, the size of the manifold leading to the first discharge port 123 and the manifold leading to the second discharge port 125 can be reduced as compared with the case where the manifold is provided independently.
  • the second flow path 126 communicates with the second manifold 124A of the first flow path 124.
  • the second manifold 124A is discharged from the second discharge port 125 through the second flow path 126.
  • the width W3 of the second discharge port 125 in the direction orthogonal to the axial direction is the second in the direction orthogonal to both the direction in which the coating liquid flows in the second flow path 126 and the axial direction. It is wider than the width W4 of the flow path 126. Therefore, the coating liquid that has passed through the second flow path 126 can be stored in the second discharge port 125.
  • the manifold block 12 includes a main body block 13 and a support block 14.
  • the main body block 13 has the above-mentioned first manifold 122 and the above-mentioned baffle portion 124B.
  • the main body block 13 includes a first main body block 13A, a second main body block 13B, and a baffle plate 13C.
  • the first main body block 13A is arranged on the upstream side with respect to the bar 11 in the flow direction MD.
  • the first main body block 13A extends in the orthogonal direction and the axial direction.
  • the first main body block 13A has an outer surface S11 and an inner surface S12 in the flow direction MD.
  • the inner surface S12 comes into contact with the second main body block 13B.
  • the inner surface S12 is arranged between the outer surface S11 and the second main body block 13B in the flow direction MD.
  • the first main body block 13A has a first lip 131 and a recess 132.
  • the first lip 131 is arranged at one end of the first main body block 13A in the orthogonal direction.
  • the first lip 131 is arranged on the upstream side with respect to the bar 11 in the flow direction MD.
  • the first lip 131 faces the bar 11 at a distance.
  • the space between the first lip 131 and the bar 11 is the first discharge port 123 described above.
  • the recess 132 is arranged on the inner surface 122A2 of the first main body block 13A.
  • the recess 132 is arranged on the other side of the first lip 131 in the orthogonal direction.
  • the recess 132 faces the support block 14.
  • the second manifold 124A is between the recess 132 and the support block 14.
  • the second main body block 13B is arranged on the downstream side of the first main body block 13A in the flow direction MD.
  • the second main body block 13B is arranged on the other side of the bar 11 at intervals in the orthogonal direction.
  • the second main body block 13B extends in the orthogonal direction and the axial direction.
  • the second main body block 13B has an outer surface S21 and an inner surface S22 in the flow direction MD.
  • the inner surface S22 comes into contact with the first main body block 13A.
  • the inner surface S22 is arranged between the outer surface S21 and the first main body block 13A in the flow direction MD.
  • the second main body block 13B has a recess 133.
  • the recess 133 is arranged on the inner surface S22 of the second main body block 13B.
  • the recess 133 has a substantially semicircular shape in cross-sectional view. Since the recess 133 has a substantially semicircular shape, the inner surface 122B of the first manifold 122 can be curved as described above, and the coating liquid can be prevented from staying in the first manifold 122 for a long period of time.
  • the recess 133 extends in the axial direction.
  • Each of both ends of the recess 133 in the axial direction has an arc shape. Since each of both ends of the recess 133 in the axial direction has an arc shape, it is possible to prevent the coating liquid from staying at each of both ends of the first manifold 122 in the axial direction.
  • the recess 133 has no corners.
  • the recess 133 faces the inner surface S12 of the first main body block 13A.
  • the first manifold 122 is between the recess 133 and the inner surface S12 of the first main body block 13A.
  • the baffle plate 13C is arranged between the first manifold 122 and the second manifold 124A in the orthogonal direction.
  • the baffle plate 13C is arranged between the first main body block 13A and the second main body block 13B.
  • the baffle plate 13C extends in the axial direction.
  • the baffle plate 13C has one end E11 and the other end E12 in the orthogonal direction.
  • the other end E12 is arranged between the one end E11 and the first manifold 122 in the orthogonal direction.
  • the baffle plate 13C has a notch 135.
  • the notch 135 is arranged at the other end E12 of the baffle plate 13C in the orthogonal direction.
  • the notch 135 extends axially.
  • the length of the notch 135 in the axial direction is substantially the same as the length of the first manifold 122 in the axial direction.
  • the support block 14 is arranged between the bar 11 and the second main body block 13B in the orthogonal direction.
  • the support block 14 has a first support block 14A and a second support block 14B.
  • the first support block 14A supports the second support block 14B.
  • the first support block 14A is removable from the second main body block 13B.
  • the support block 14 can be attached to and detached from the main body block 13.
  • the ratio of can be easily changed.
  • the support block 14 since the support block 14 is removable from the main body block 13, the amount of the coating liquid discharged from the first discharge port 123 and the first number can be obtained by exchanging the minimum configuration (support block 14 only). 2
  • the ratio to the amount of coating liquid discharged from the discharge port 125 can be changed.
  • the first support block 14A extends in the axial direction.
  • the first support block 14A has an outer surface S31 and an inner surface S32 in the flow direction MD.
  • the inner surface S32 is arranged between the outer surface S31 and the first main body block 13A in the flow direction MD.
  • the first support block 14A has a substantially L-shape in cross-sectional view.
  • the first support block 14A has a second lip 141, an inclined surface 142, and a recess 143.
  • the second lip 141 is arranged at one end of the first support block 14A in the orthogonal direction.
  • the second lip 141 is arranged on the downstream side of the bar 11 in the flow direction MD.
  • the second lip 141 faces the bar 11 at a distance.
  • the space between the second lip 141 and the bar 11 is the second discharge port 125 described above.
  • the second lip 141 is arranged on the opposite side of the first lip 131 in the orthogonal direction. As a result, the second lip 141 is arranged farther from the base material S than the first lip 131 in the orthogonal direction.
  • the coating liquid L1 (see FIG. 4) discharged from the first discharge port 123 can be applied to the base material S, while the coating liquid L2 (see FIG. 4) in contact with the bar 11 in the second discharge port 125. ) Can be discharged by overcoming the second lip 141 (overflowing from the second discharge port 125) so as not to come into contact with the base material S.
  • the coating liquid L2 from which air has been removed from the surface of the bar 11 from being mixed into the second manifold 124A of the first flow path 124.
  • the inclined surface 142 is one end surface of the first support block 14A in the orthogonal direction.
  • the inclined surface 142 is connected to the second lip 141.
  • the inclined surface 142 is inclined away from the base material S from the second lip 141 toward the downstream side of the flow direction MD.
  • the coating liquid L2 (see FIG. 4) discharged from the second discharge port 125 flows on the inclined surface 142 in a direction away from the base material S.
  • the coating liquid L2 (discharged from the second discharge port 125) that has passed over the second lip 141 can be smoothly discharged along the inclined surface 142 so as not to come into contact with the base material S. ..
  • the recess 143 is arranged on the inner surface S32 of the first support block 14A.
  • the recess 143 is arranged on the other side of the second lip 141 in the orthogonal direction.
  • the recess 143 faces the recess 132 of the first main body block 13A.
  • the second support block 14B is arranged in the recess 143 of the first support block 14A.
  • the second support block 14B is supported by the first support block 14A.
  • the second support block 14B is arranged on the other side of the bar 11 in the orthogonal direction.
  • the second support block 14B comes into contact with the bar 11.
  • the bar 11 is mounted on the second support block 14B.
  • the support block 14 supports the bar 11.
  • the manifold block 12 supports the bar 11.
  • the bar 11 is not attached to the manifold block 12.
  • the second support block 14B extends in the axial direction.
  • the second support block 14B includes a plurality of protrusions 144 and a plurality of protrusions 145 (see FIG. 5).
  • Each of the plurality of protrusions 144 is arranged on the other end surface of the second support block 14B in the orthogonal direction. Each of the plurality of protrusions 144 extends in the orthogonal direction. Each of the plurality of protrusions 144 contacts the inner surface of the recess 143 of the first support block 14A in the orthogonal direction. As a result, a part of the second flow path 126 is formed between the other end surface of the second support block 14B in the orthogonal direction and the inner surface of the recess 143. Further, the plurality of protrusions 144 are arranged in the axial direction. Each of the plurality of protrusions 144 is arranged at a distance from each other. Between each of the plurality of protrusions 144 is also a part of the second flow path 126.
  • each of the plurality of protrusions 145 is arranged on the downstream end face of the second support block 14B in the flow direction MD.
  • Each of the plurality of protrusions 145 extends in the flow direction MD.
  • Each of the plurality of protrusions 145 comes into contact with the inner surface of the recess 143 of the first support block 14A in the flow direction MD.
  • a part of the second flow path 126 is formed between the other end surface of the second support block 14B in the flow direction MD and the inner surface of the recess 143.
  • the plurality of protrusions 145 are arranged in the axial direction in the same manner as the plurality of protrusions 144.
  • Each of the plurality of protrusions 145 is arranged at a distance from each other. Between each of the plurality of protrusions 145 is also a part of the second flow path 126. That is, the support block 14 has a second flow path 126.
  • the second support block 14B is removable from the first support block 14A.
  • the plurality of protrusions 144 and the plurality of protrusions 145 are arranged in the middle of the second flow path 126, a portion in which the plurality of protrusions 144 and the plurality of protrusions 145 are arranged and a plurality of protrusions 145 are arranged in the axial direction.
  • the pressure loss of the portion where the plurality of protrusions 144 and the plurality of protrusions 145 are arranged is larger than the pressure loss of the portion where the plurality of protrusions 144 and the plurality of protrusions 145 are not arranged.
  • the amount of the coating liquid flowing from the first flow path 124 to the second flow path 126 becomes non-uniform in the axial direction.
  • the amount of coating liquid flowing from the first flow path 124 to the second flow path 126 is "non-uniform" and is discharged from the first discharge port 123. It affects the amount of liquid, and the amount of coating liquid discharged from the first discharge port 123 may become non-uniform in the axial direction.
  • the influence of "non-uniformity" of the amount of the coating liquid flowing from the first flow path 124 to the second flow path 126 can be buffered by the second manifold 124A.
  • the coating liquid can be uniformly discharged from the first discharge port 123 in the axial direction.
  • the buffering action of the second manifold 124A suppresses the fluctuation of the ratio between the amount of the coating liquid discharged from the first discharge port 123 and the amount of the coating liquid discharged from the second discharge port 125. can.
  • the bar coater 3 does not have to have the second manifold 124A.
  • the bar coater 3 has a flow path leading to the first discharge port 123 instead of the second manifold 124A.
  • the width of the flow path in the direction orthogonal to both the direction in which the coating liquid flows in the flow path and the axial direction may be the same as the width W1 of the first discharge port 123 in the direction orthogonal to the axial direction.
  • the bar coater 3 does not have to have the support block 14.
  • the second main body block 13B may have a second lip 141 and a second flow path 126.
  • At least one of the plurality of protrusions 144 and the plurality of protrusions 145 may be provided on the first support block 14A.
  • the use of the bar coater 3 is not limited to extrusion molding.
  • the base material S may be fed out from the roll of the base material S, and the coating liquid may be applied to the fed base material S with the bar coater 3.
  • the coating machine is not limited to the bar coater 3.
  • examples of the coating machine include a gravure coater and a kiss coater.
  • the film F manufacturing system 1 does not have to include the first stretching machine 4A.
  • the base material S may be stretched (biaxially simultaneously stretched) in the flow direction MD and the width direction TD by the second stretching machine 4B.
  • the film F manufacturing system 1 may include a masking film feeding machine that feeds out the masking film and a laminating machine that attaches the fed out masking film to the film F, instead of the narling processing machine 6.
  • the coating machine, film manufacturing system, and film manufacturing method of the present invention are used for manufacturing films such as easy-adhesive films.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Coating Apparatus (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Paints Or Removers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
PCT/JP2020/048879 2020-01-14 2020-12-25 塗工機、フィルムの製造システム、および、フィルムの製造方法 WO2021145202A1 (ja)

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KR1020227022808A KR102475550B1 (ko) 2020-01-14 2020-12-25 도공기, 필름의 제조 시스템, 및, 필름의 제조 방법

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WO2022107478A1 (ja) * 2020-11-20 2022-05-27 日東電工株式会社 フィルムの製造方法

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JPH06269715A (ja) * 1993-03-17 1994-09-27 Fuji Photo Film Co Ltd 塗布方法及び装置
JP2003033702A (ja) * 2001-07-26 2003-02-04 Fuji Photo Film Co Ltd 塗布方法及び塗布装置
JP2005034729A (ja) * 2003-07-14 2005-02-10 Tomoegawa Paper Co Ltd グラビア塗布装置
JP2013071099A (ja) * 2011-09-29 2013-04-22 Toray Ind Inc 塗液塗布方法、塗布フィルムの製造方法および塗液塗布装置
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CN105451894B (zh) * 2013-07-04 2018-05-25 三键精密化学有限公司 涂敷装置及涂敷装置的控制方法
JP6309407B2 (ja) * 2014-09-17 2018-04-11 東レ株式会社 塗布器、塗布装置、及び塗布方法
JP6269715B2 (ja) 2016-04-08 2018-01-31 株式会社デンソー 監視装置
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JPS627467A (ja) * 1985-07-04 1987-01-14 Fuji Photo Film Co Ltd 塗布方法及び装置
JPH06269715A (ja) * 1993-03-17 1994-09-27 Fuji Photo Film Co Ltd 塗布方法及び装置
JP2003033702A (ja) * 2001-07-26 2003-02-04 Fuji Photo Film Co Ltd 塗布方法及び塗布装置
JP2005034729A (ja) * 2003-07-14 2005-02-10 Tomoegawa Paper Co Ltd グラビア塗布装置
JP2013071099A (ja) * 2011-09-29 2013-04-22 Toray Ind Inc 塗液塗布方法、塗布フィルムの製造方法および塗液塗布装置
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WO2022107478A1 (ja) * 2020-11-20 2022-05-27 日東電工株式会社 フィルムの製造方法
JP2022082375A (ja) * 2020-11-20 2022-06-01 日東電工株式会社 フィルムの製造方法
JP7249985B2 (ja) 2020-11-20 2023-03-31 日東電工株式会社 フィルムの製造方法

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