WO2021033657A1 - 塩化マグネシウムを含む粉末調味料 - Google Patents
塩化マグネシウムを含む粉末調味料 Download PDFInfo
- Publication number
- WO2021033657A1 WO2021033657A1 PCT/JP2020/030945 JP2020030945W WO2021033657A1 WO 2021033657 A1 WO2021033657 A1 WO 2021033657A1 JP 2020030945 W JP2020030945 W JP 2020030945W WO 2021033657 A1 WO2021033657 A1 WO 2021033657A1
- Authority
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- WIPO (PCT)
- Prior art keywords
- magnesium chloride
- starch
- deliquescent
- seasoning
- powder
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/212—Starch; Modified starch; Starch derivatives, e.g. esters or ethers
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/40—Table salts; Dietetic salt substitutes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/212—Starch; Modified starch; Starch derivatives, e.g. esters or ethers
- A23L29/219—Chemically modified starch; Reaction or complexation products of starch with other chemicals
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
- A23L29/35—Degradation products of starch, e.g. hydrolysates, dextrins; Enzymatically modified starches
Definitions
- the present invention relates to a powder seasoning composed of magnesium chloride and starch.
- the daily salt intake target value was less than 9 g for adult men and less than 7.5 g for adult women, whereas in the 2015 edition, one day Since the daily salt intake target value is less than 8 g for adult males and less than 7 g for adult females, the daily salt intake target value is decreasing, and it is considered that the tendency toward salt reduction will continue to increase in the future.
- Patent Documents 1 and 2 disclose instant noodles having both a good texture and a salty taste by adhering magnesium chloride to the noodles.
- Patent Document 3 discloses a method of covering magnesium chloride with fats and oils to suppress deliquescent, but there is a problem that flavor and melting in the mouth are lowered because fats and oils having a relatively high melting point are used. In addition, since it cannot be stored at a temperature exceeding the melting point of fats and oils, its use is limited.
- JP-A-2019-103454 Japanese Unexamined Patent Publication No. 2019-10833 Japanese Unexamined Patent Publication No. 2001-017093
- An object of the present invention is to obtain a powdered seasoning containing magnesium chloride that can be stored for a long time by suppressing deliquescent.
- the present inventors have found that by covering magnesium chloride with a certain amount or more of starch, deliquescent of magnesium chloride can be suppressed and the powder can be stored for a long time. Furthermore, it has been found that by using oxidized starch as starch, a powder seasoning that can be used for a wider range of purposes can be obtained without affecting the viscosity and taste of powdered soup.
- the present invention is a powder seasoning containing at least magnesium chloride and starch, which is characterized by containing 5 parts by weight or more and 40 parts by weight or less of starch with respect to 1 part by weight of magnesium chloride. It is a seasoning. This will be described in detail below.
- Powdered seasoning in the present invention refers to a solid seasoning that dissolves quickly when boiling water is poured. Specifically, even if it is lumpy, it is included in the powder seasoning in the present invention as long as it dissolves quickly in boiling water (about 10 seconds). On the other hand, even if it is in powder form, those that do not dissolve quickly in boiling water are not included in the powder seasoning.
- Magnesium chloride is a material with a salty taste and a strong bitterness, but when used in combination with sodium chloride or potassium chloride, the bitterness is alleviated and the salty taste is emphasized. For this reason, the inventors have long studied methods of using magnesium chloride as a substitute for sodium chloride.
- the issue when using magnesium chloride as a substitute for sodium chloride is the deliquescent property of magnesium chloride.
- deliquescent can be suppressed by covering magnesium chloride with a certain amount or more of starch.
- Magnesium chloride is not limited to high-purity magnesium chloride, and additives containing magnesium chloride as a main component such as bittern can be used. Since magnesium chloride is extremely unstable by itself, it can be generally obtained as magnesium chloride hexahydrate incorporating bound water.
- the starch in the present invention refers to untreated starch (raw starch), phosphoric acid cross-linked starch, processed starch such as oxidized starch, and dextrin having a dextrose equivalent (hereinafter “DE”) of 12 or less. These starches may be used in combination.
- DE dextrose equivalent
- dextrose, oxidized starch, or phosphoric acid-crosslinked starch having an excellent deliquescent suppression equivalent of 9 or less is preferable, and oxidized starch is most preferable.
- the powder seasoning in the present invention needs to contain starch in a range of 5 parts by weight or more and 40 parts by weight or less with respect to 1 part by weight of magnesium chloride, and is in a range of 12 parts by weight or more and 40 parts by weight or less. It is more preferable to include in. If the amount of starch is too small, the deliquescent of magnesium chloride cannot be suppressed and the powder state cannot be maintained. Further, if the amount of starch is too large, the salty taste of magnesium chloride is masked, so that the function as a salty seasoning cannot be achieved.
- the components other than magnesium chloride and starch may be contained.
- salty components such as sodium chloride and potassium chloride
- sweet components such as glucose, sucrose, and oligosaccharides
- umami components such as glutamic acid and inosic acid
- sour components such as acetic acid and citric acid
- spices are used as flavors. It can be added as appropriate as long as the storage stability is not deteriorated.
- Magnesium chloride hexahydrate (MgCl 2 ⁇ 6H 2 O) , and was prepared Table 1 starch (all manufactured by Matsutani Chemical Co., Ltd.).
- Deliquescent test 100 g of the starch shown in Table 1 was placed in a 225 ml beaker, and the opening of the beaker was covered with a non-woven fabric to prevent water droplets and dust from being mixed. This test piece was allowed to stand in a thermostat (temperature 40 ° C., humidity 75% RH), and the sample weight was measured every hour.
- the "weight increase rate (%)" shown in Table 2 indicates the rate of increase in the sample weight after the start of the test with respect to the sample weight before the start of the test (0 hours).
- Test Example 1 10 parts of magnesium chloride hexahydrate and 10 parts of oxidized starch were put into a closed container and mixed by stirring. After stirring and mixing, 100 g of the sample was transferred to a 225 ml beaker. Until the start of the test, the sample was stored tightly closed with a lid so that it would not come into contact with the outside air.
- Test Examples 2 to 20 A deliquescent test was conducted by changing the type of starch and the blending ratio. The test results are shown in Tables 3 and 4.
- magnesium chloride hexahydrate (molar mass 203.31 g / mol) is used. Therefore, in Test Example 1, starch is added about twice (weight ratio) of magnesium chloride (molar mass 95.211 g / mol), and in Test Example 2, starch is added about 6 times (weight ratio) of magnesium chloride. ) It means that it is added.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Seasonings (AREA)
Abstract
Description
本発明における粉末調味料とは、熱湯を注ぐことで速やかに溶解する固形の調味料を指す。具体的には、塊状であっても、熱湯に速やかに(概ね10秒程度)溶解するものであれば本発明における粉末調味料に含まれる。一方、粉末状であっても、熱湯に速やかに溶解しないものは粉末調味料には含まれない。
1-1.塩化マグネシウム
塩化マグネシウムは、塩味と強い苦味のある素材であるが、塩化ナトリウムや塩化カリウムと併用することで苦味が緩和されて塩味が強調される。このため、本発明者らは、塩化マグネシウムを塩化ナトリウムの代替物として使用する方法を長年検討してきた。
本発明における澱粉とは、何の処理もしていない澱粉(生澱粉)、リン酸架橋澱粉、及び酸化澱粉等の加工澱粉、並びにデキストロース当量(以下「DE」)12以下のデキストリン等を指し、これらの澱粉を組み合わせて用いてもよい。塩化マグネシウムを一定量以上の澱粉で覆うことで、塩化マグネシウムの潮解を抑制し、粉末状態のまま安定して保存することができる。
本発明では、塩化マグネシウム及び澱粉以外のその成分を含んでもよい。具体的には、塩化ナトリウム、塩化カリウム等の塩味成分、グルコース、スクロース、オリゴ糖などの甘味成分、グルタミン酸やイノシン酸等の旨味成分、酢酸、クエン酸等の酸味成分、および香辛料などを風味や保存性が低下しない範囲で適宜加えることができる。ただし、塩化マグネシウムと澱粉を混合攪拌した後に、その他成分を添加することが好ましい。塩化マグネシウムが澱粉で覆われる前にその他成分を加えてしまうと、塩化マグネシウムの潮解を抑えられなくなる可能性がある。
調味料の製造方法については特に制限はなく、既存の方法を用いることができる。なお、前記の通り、塩化マグネシウムと澱粉を混合攪拌した後に、その他成分を添加することが好ましい。
澱粉に沸騰したお湯を加えてよく攪拌して固形分3%の混合液を調整する。
次に、混合液を70℃で保温しながら、B型粘度計(東京計器、B8L)を用いて粘度を測定した。
(比較試験例)
表1記載の澱粉100gを225mlビーカーに入れて、水滴やゴミが混入しないようにビーカーの開口部を不織布で覆った。この試験体を恒温機(温度40℃、湿度75%RH)に静置し、1時間ごとに試料重量を測定した。なお、表2記載の「重量増加率(%)」とは、試験開始前(0時間)の試料重量に対する試験開始後の試料重量の増加率を示したものである。
塩化マグネシウム六水和物10部と、酸化澱粉10部を密閉容器に投入し攪拌混合した。攪拌混合後に試料100gを225mlビーカーに移し替えた。なお、試験開始までは試料が外気に触れないように蓋で密閉して保管した。
澱粉の種類、及び配合比率を変更して潮解性試験を実施した。試験結果は表3、4の通りである。
Claims (3)
- 少なくとも塩化マグネシウムと、澱粉とを含む粉末調味料であって、
塩化マグネシウム1重量部に対して、澱粉を5重量部以上、40重量部以下の範囲で含むことを特徴とする粉末調味料。 - 澱粉として、デキストロース当量9以下のデキストロース、酸化澱粉、又はリン酸架橋澱粉を含むことを特徴とする請求項1記載の粉末調味料。
- 澱粉として、酸化澱粉を含むことを特徴とする請求項1記載の粉末調味料。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17/432,035 US20220160007A1 (en) | 2019-08-22 | 2020-08-17 | Powdered seasoning containing magnesium chloride |
EP20854595.4A EP4018842B1 (en) | 2019-08-22 | 2020-08-17 | Powdered seasoning containing magnesium chloride |
CN202080022469.9A CN113645853A (zh) | 2019-08-22 | 2020-08-17 | 含有氯化镁的粉末调味料 |
BR112021018464A BR112021018464A2 (pt) | 2019-08-22 | 2020-08-17 | Tempero em pó contendo cloreto de magnésio |
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JP2019-152070 | 2019-08-22 | ||
JP2019152070 | 2019-08-22 | ||
JP2020134310A JP2021035354A (ja) | 2019-08-22 | 2020-08-07 | 塩化マグネシウムを含む粉末調味料 |
JP2020-134310 | 2020-08-07 |
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WO2021033657A1 true WO2021033657A1 (ja) | 2021-02-25 |
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PCT/JP2020/030945 WO2021033657A1 (ja) | 2019-08-22 | 2020-08-17 | 塩化マグネシウムを含む粉末調味料 |
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US (1) | US20220160007A1 (ja) |
EP (1) | EP4018842B1 (ja) |
BR (1) | BR112021018464A2 (ja) |
WO (1) | WO2021033657A1 (ja) |
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JPS61265067A (ja) * | 1985-05-17 | 1986-11-22 | Showa Denko Kk | アミノ酸一糖類合剤組成物 |
JPH04356164A (ja) * | 1990-12-04 | 1992-12-09 | Hidemi Tagome | 蛋白質変性遅延剤、および該蛋白質変性遅延剤を利用した蛋白食品の製造方法 |
JP2001017093A (ja) | 1999-07-01 | 2001-01-23 | Nof Corp | 油脂被覆組成物及びその製造方法 |
JP2001226401A (ja) * | 2000-02-16 | 2001-08-21 | Snow Brand Milk Prod Co Ltd | カルシウム・リン酸化澱粉複合体及びその製造方法 |
JP2006274100A (ja) * | 2005-03-30 | 2006-10-12 | Sanwa Denpun Kogyo Kk | 水溶性澱粉粉末およびその製造方法 |
JP2008031225A (ja) * | 2006-07-26 | 2008-02-14 | Bio Marine Kk | 海水からの金属イオン化合物の混合物とシクロデキストリンとの包接体 |
US20110229607A1 (en) * | 2010-03-18 | 2011-09-22 | S K Patil & Associates, Inc. | Low-Sodium Salt Compositions |
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JP2019103454A (ja) | 2017-12-13 | 2019-06-27 | 日清食品ホールディングス株式会社 | 塩化マグネシウムを含む即席麺の製造方法 |
JP2019110833A (ja) | 2017-12-25 | 2019-07-11 | 日清食品ホールディングス株式会社 | 塩化マグネシウム及び乳酸カリウムを含有する即席麺 |
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2020
- 2020-08-17 BR BR112021018464A patent/BR112021018464A2/pt unknown
- 2020-08-17 EP EP20854595.4A patent/EP4018842B1/en active Active
- 2020-08-17 US US17/432,035 patent/US20220160007A1/en active Pending
- 2020-08-17 WO PCT/JP2020/030945 patent/WO2021033657A1/ja unknown
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See also references of EP4018842A4 |
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Publication number | Publication date |
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BR112021018464A2 (pt) | 2022-03-03 |
EP4018842A4 (en) | 2023-05-10 |
EP4018842A1 (en) | 2022-06-29 |
EP4018842B1 (en) | 2024-03-20 |
US20220160007A1 (en) | 2022-05-26 |
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