WO2020130631A1 - 전기 저항 점용접성이 우수한 고강도 아연도금강판 및 그 제조방법 - Google Patents

전기 저항 점용접성이 우수한 고강도 아연도금강판 및 그 제조방법 Download PDF

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Publication number
WO2020130631A1
WO2020130631A1 PCT/KR2019/018005 KR2019018005W WO2020130631A1 WO 2020130631 A1 WO2020130631 A1 WO 2020130631A1 KR 2019018005 W KR2019018005 W KR 2019018005W WO 2020130631 A1 WO2020130631 A1 WO 2020130631A1
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Prior art keywords
steel sheet
less
hot
surface layer
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2019/018005
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English (en)
French (fr)
Korean (ko)
Inventor
강기철
엄상호
지창운
정연채
민광태
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Posco Holdings Inc
Original Assignee
Posco Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Posco Co Ltd filed Critical Posco Co Ltd
Priority to JP2021534943A priority Critical patent/JP7680354B2/ja
Priority to CN201980085280.1A priority patent/CN113227434B/zh
Priority to US17/414,231 priority patent/US20220042155A1/en
Priority to EP19898057.5A priority patent/EP3901318A4/en
Priority to CN202410736826.8A priority patent/CN118726884A/zh
Publication of WO2020130631A1 publication Critical patent/WO2020130631A1/ko
Anticipated expiration legal-status Critical
Priority to JP2023192741A priority patent/JP2024020359A/ja
Priority to US18/622,583 priority patent/US12221701B2/en
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
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    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/76—Adjusting the composition of the atmosphere
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    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
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    • C21D8/0257—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment with diffusion of elements, e.g. decarburising, nitriding
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    • C21D8/0263—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
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    • C21D8/0247—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273—Final recrystallisation annealing
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    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C18/04—Alloys based on zinc with aluminium as the next major constituent
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    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36—Elongated material
    • C23C2/40—Plates; Strips
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2221/00—Treating localised areas of an article
    • C21D2221/02—Edge parts

Definitions

  • the present invention relates to a galvanized steel sheet excellent in electric resistance spot weldability and a method for manufacturing the same.
  • High-strength steel usually means a steel having a strength of 490 MPa or more, but is not limited thereto, transformation induced plasticity (TRIP) steel, twin induced plasticity (TWIP) steel, and abnormal structure ( This may include dual phase (DP) steel, complex phase (CP) steel, and the like.
  • TRIP transformation induced plasticity
  • TWIP twin induced plasticity
  • DP dual phase
  • CP complex phase
  • automotive steel is supplied in the form of a plated steel plate that has been plated on the surface to ensure corrosion resistance.
  • zinc plated steel plate GI steel plate
  • alloyed galvanized steel plate GA uses zinc sacrificial corrosion resistance to provide high corrosion resistance. Because it has, it is often used as a material for automobiles.
  • alloy components such as Mn, Al, and Si contained in the steel sheet react with the atmosphere to form oxides on the surface of the steel sheet.
  • a galvanized steel sheet excellent in spot weldability and a method of manufacturing the same are provided.
  • the galvanized steel sheet according to one aspect of the present invention is a galvanized steel sheet including a steel sheet and a zinc-based plated layer formed on the steel sheet, and the decarburization rate of the surface layer portion of the steel sheet represented by Formula 1 may be 30% or more.
  • the surface layer part means an area from the surface of the steel sheet to a depth of 35 ⁇ m.
  • a method of manufacturing a galvanized steel sheet according to another aspect of the present invention includes hot rolling a steel slab to obtain a hot rolled steel sheet; Winding the hot rolled steel sheet at a temperature of 590 to 750° C. to obtain a hot rolled steel sheet; Heating the edge portion of the coiled hot-rolled steel sheet at 600 to 800° C.
  • the present invention can produce a galvanized steel sheet having excellent surface quality and excellent resistance to spot welding LME by forming a decarburization layer on the surface layer of the base layer directly under the plating layer.
  • FIG. 1 is a graph showing a section for integrating a carbon concentration profile to measure decarburization.
  • galvanized steel sheet in the present invention is a concept including not only galvanized steel sheet (GI steel sheet) but also alloyed galvanized steel sheet (GA) as well as galvanized steel sheet mainly containing zinc.
  • Mainly containing zinc means that the proportion of zinc among the elements included in the plating layer is the highest.
  • the proportion of iron may be higher than that of zinc, and among the remaining components except iron, the proportion of zinc may be the highest.
  • the inventors of the present invention have focused on the fact that the liquid metal embrittlement (LME) generated during welding is caused by micro-cracks generated from the surface of the steel sheet, and research the means for suppressing the micro-cracks on the surface. It has been found that it is necessary to soften the material and the present invention has been reached.
  • LME liquid metal embrittlement
  • a large amount of elements such as C, Mn, Si, Cr, Mo, and V may be included in order to secure hardenability or austenite stability of the steel, and these elements serve to increase the susceptibility to cracks in steel Do it. Therefore, the steel containing a large amount of these elements easily causes micro-cracks, which ultimately causes the embrittlement of liquid metal during welding. According to the results of the research by the present inventors, the behavior of such microcracks is closely related to the carbon concentration, and since the cracks are generated from the surface and propagate to the inside, the possibility of microcracks is increased when the carbon concentration of the surface is high. do.
  • the overall composition of the steel is to have a high carbon concentration for high strength, but the carbon concentration in the surface layer portion at which the crack occurs is low carbon concentration, that is, high decarburization so as to have resistance to cracking. Have a rate.
  • the surface layer part means a point within 35 ⁇ m in the depth direction from the surface of the steel sheet, and the decarburization rate of the surface layer part can be represented by the following equation [1].
  • the carbon concentration in the surface layer means the average value of the carbon concentration in the surface layer
  • the GDS profile of carbon as shown in FIG. 1 is a depth of 35 in the surface layer of the steel sheet.
  • the value integrated up to ⁇ m can be set as the value divided by the depth (35 ⁇ m).
  • the bulk carbon concentration means the carbon concentration when there is no longer a change in the carbon concentration even when moving in the depth direction on the GDS profile, and usually means a carbon concentration of 1/4 of the thickness of the steel sheet. At this time, the carbon concentration of 1/4 of the thickness of the steel sheet can be obtained by removing a part of the steel sheet in the depth direction and then performing GDS analysis.
  • the surface layer decarburization rate may be based on a value measured at the center in the width direction.
  • the decarburization rate of the edge portion in the width direction is often higher than that of the center portion in the width direction of the steel sheet, the spot weldability can be further improved when the decarburization rate at the edge portion satisfies a value defined in the present invention. have.
  • the edge portion in the width direction refers to both end points of the cross-section in which the steel sheet is cut in the width direction, but when there is a problem in the integrity of the specimen, such as contamination occurring at the point, 1 mm inside the width direction from the end point Can mean the point of
  • the decarburization rate may be 30% or more in order to secure sufficient spot weldability through prevention of LME generation.
  • the decarburization rate may be 40% or more, and in another embodiment, the decarburization rate may be 50% or more.
  • the upper limit of the decarburization rate is not particularly limited. However, according to one embodiment of the present invention, the upper limit of the decarburization rate may be set to 90%, in another embodiment, the upper limit of the decarburization rate may be set to 80%, and in another embodiment, the upper limit of the decarburization rate. Can be set to 70%.
  • an inner oxide may be present in the surface layer portion of the steel sheet.
  • the internal oxide may include at least one or more of Si, Mn, Al, and Fe, and may further include additional elements derived from the composition of the steel sheet.
  • the steel sheet to be targeted in the present invention is not limited as long as it is a high-strength steel sheet having a strength of 490 MPa or more.
  • the steel sheet targeted in the present invention is in a weight ratio, C: 0.05 to 1.5%, Si: 2.0% or less, Mn: 1.0 to 30%, S-Al (acid soluble aluminum): 3% or less, Cr: 2.5% or less, Mo: 1% or less, B: 0.005% or less, Nb: 0.2% or less, Ti: 0.2% or less, V: 0.2% or less, Sb+Sn+Bi: 0.1% or less, N: It may have a composition containing 0.01% or less.
  • the rest of the components are iron and other impurities, and other elements not listed above, but are not excluded until they further contain elements that can be included in the steel in a total range of 1.0% or less.
  • the content of each component element is indicated by weight unless otherwise specified.
  • the above-mentioned composition means the bulk composition of the steel sheet, that is, the composition at a quarter of the thickness of the steel sheet (hereinafter, the same).
  • the high-strength steel sheet may be targeted to TRIP steel or the like.
  • Each steel can have the following composition.
  • Steel composition 1 C: 0.05 to 0.30% (preferably 0.10 to 0.25%), Si: 0.5 to 2.5% (preferably 1.0 to 1.8%), Mn: 1.5 to 4.0% (preferably 2.0 to 3.0%) ), S-Al: 1.0% or less (preferably 0.05% or less), Cr: 2.0% or less (preferably 1.0% or less), Mo: 0.2% or less (preferably 0.1% or less), B: 0.005% Or less (preferably 0.004% or less), Nb: 0.1% or less (preferably 0.05% or less), Ti: 0.1% or less (preferably 0.001 to 0.05%), Sb+Sn+Bi: 0.05% or less, N : 0.01% or less, including residual Fe and unavoidable impurities.
  • the elements that are not listed above but can be included in the steel may further contain a total of 1.0% or less.
  • Steel composition 2 C: 0.05 to 0.30% (preferably 0.10 to 0.2%), Si: 0.5% or less (preferably 0.3% or less), Mn: 4.0 to 10.0% (preferably 5.0 to 9.0%), S-Al: 0.05% or less (preferably 0.001 to 0.04%), Cr: 2.0% or less (preferably 1.0% or less), Mo: 0.5% or less (preferably 0.1 to 0.35%), B: 0.005% Or less (preferably 0.004% or less), Nb: 0.1% or less (preferably 0.05% or less), Ti: 0.15% or less (preferably 0.001 to 0.1%), Sb+Sn+Bi: 0.05% or less, N : 0.01% or less, including residual Fe and unavoidable impurities.
  • the elements that are not listed above but can be included in the steel may further contain a total of 1.0% or less.
  • each of the above-mentioned component elements is not limited, it means that they may be regarded as arbitrary elements and the content may be 0%.
  • the surface of the steel sheet may include one or more plating layers, and the plating layer may be a zinc-based plating layer including GI (Galvanized) or GA (Galva-annealed).
  • the Ceq ratio is appropriately controlled as described above, even if a zinc-based plating layer is formed on the surface of the steel sheet, the problem of liquid metal embrittlement occurring during spot welding can be suppressed.
  • the alloying degree (meaning the content of Fe in the plating layer) can be controlled to 8 to 13% by weight, preferably 10 to 12% by weight. If the degree of alloying is not sufficient, there is a possibility that the zinc in the zinc-based plating layer penetrates into the micro-cracks and causes a problem of embrittlement of the liquid metal. On the contrary, when the degree of alloying is too high, problems such as powdering may occur. .
  • the plating amount of the zinc-based plating layer may be 30 to 70 g/m 2 . If the plating adhesion amount is too small, it is difficult to obtain sufficient corrosion resistance. On the other hand, when the plating adhesion amount is too large, problems in manufacturing cost increase and liquid metal embrittlement may occur, so that the plating is controlled within the above range.
  • a more preferable range of the plating adhesion amount may be 40 to 60 g/m 2 .
  • This plating adhesion amount refers to the amount of the plating layer attached to the final product. When the plating layer is a GA layer, the weight of plating adhesion increases due to alloying, so its weight may decrease slightly before alloying, depending on the degree of alloying. Therefore, although not necessarily limited to this, the amount of adhesion before alloying (that is, the amount of plating attached from the plating bath) may be reduced by about 10%.
  • a hot rolled steel sheet can be produced by hot rolling a steel slab of the above-described composition and then winding it up.
  • Conditions for heating the slab (temperature control in the case of direct rolling) or hot rolling are not particularly limited, but in one embodiment of the present invention, the winding temperature may be limited as follows.
  • Winding temperature 590 ⁇ 750°C
  • the hot rolled steel sheet is then wound up and stored in a coil form, and the wound steel sheet undergoes a slow cooling process.
  • Oxidizing elements included in the surface layer portion of the steel sheet are removed by the above process.
  • the coiling temperature of the slab is too low, the coil is annealed at a temperature lower than the temperature required for the oxidation removal of these elements, so it is difficult to obtain a sufficient effect.
  • the coiling temperature is too high, the temperature deviation between the center portion and the edge portion in the width direction becomes large and the material deviation increases accordingly. In this case, the cold rolling property is inferior, and the strength of the final product is not only lowered, but also the moldability may be deteriorated.
  • the upper limit of the coiling temperature may be set to 750°C.
  • Heated edge of hot-rolled coil 5 to 24 hours at 600 to 800°C
  • the hot-rolled coil edge is heated to increase the decarburization rate of the edge.
  • the heating of the hot-rolled coil edge portion means heating both ends of the coiled coil in the width direction, that is, the edge portion, whereby the edge portion is first heated to a temperature suitable for oxidation by heating the edge portion. That is, the coiled coil is maintained at a high temperature inside, but the edge portion is cooled relatively quickly, thereby shortening the time to be maintained at a temperature suitable for internal oxidation at the edge portion. Therefore, the removal of the oxidizing element at the edge portion becomes less active than the center portion in the width direction.
  • Edge heating may be used as one method for removing oxidizing elements at the edge.
  • the edge portion in the case of heating the edge portion, as opposed to the case of cooling after winding, the edge portion is first heated, and accordingly, the temperature of the edge portion in the width direction is appropriately maintained for internal oxidation. As a result, the thickness of the inner oxide layer of the edge portion increases. To this end, the heating temperature of the edge portion needs to be 600°C or higher (based on the temperature of the edge portion of the steel sheet). However, if the temperature is too high, the surface may be deteriorated after pickling due to excessive scale formation on the edge portion during heating or formation of porous high oxidation scale (hematite), so the edge portion temperature may be 800°C or less. A more preferable edge heating temperature is 600 to 750°C.
  • the edge portion heating time needs to be 5 hours or more.
  • the edge portion heating time may be 24 hours or less.
  • the edge heating may be performed by a combustion heating method through air-fuel ratio control. That is, the oxygen fraction in the atmosphere may be changed by adjusting the air-fuel ratio. The higher the oxygen partial pressure, the greater the concentration of oxygen in contact with the surface layer of the steel sheet may increase decarburization and internal oxidation.
  • the present invention can be controlled to a nitrogen atmosphere containing 0.5 to 2% by volume of oxygen by adjusting the air-fuel ratio in one embodiment. Those skilled in the art to which the present invention pertains may control the oxygen fraction by adjusting the air-fuel ratio without particular difficulty, so this will not be described separately.
  • the hot rolled steel sheet subjected to the above-described process may be subjected to pickling as necessary, and then cold rolled. After the cold rolling process described above, the process of annealing the steel sheet may be followed.
  • the decarburization rate of the surface layer part may be greatly changed, so in one embodiment of the present invention, the annealing process can be controlled under conditions to properly control the decarburization rate of the surface layer part. It can be controlled under the same conditions.
  • the sheet speed of the cold rolled steel sheet needs to be 40MPm or more.
  • the upper limit of the mail order speed may be set to 130 mpm.
  • the plate speed affects the thickness of the inner oxide layer, the thickness of the inner oxide increases and the carbon content tends to decrease as the plate speed decreases, so an excessively fast plate speed is sufficient for the thickness of the inner oxide layer. It can be a factor that prevents formation.
  • the inner oxide layer may be formed to a thickness of 3 ⁇ m or less at a plate speed of more than 130 mpm.
  • Annealing conditions 650 ⁇ 900°C, -10 ⁇ 30°C dew point atmosphere
  • the temperature at which annealing is performed may be 650° C. or higher, which is a temperature at which a sufficient internal oxidation effect is exhibited.
  • the temperature controlling the dew point may be 900° C. or less because it may be reduced and may also cause a problem of shortening equipment life and increasing process cost by generating an annealing furnace load.
  • the temperature at which annealing is performed means the temperature of the crack zone.
  • the dew point of the atmosphere in the annealing furnace it is advantageous to control the dew point of the atmosphere in the annealing furnace in order to form a sufficient and uniform internal oxide layer.
  • the dew point is too low, there is a possibility that oxide such as Si or Mn is generated on the surface due to surface oxidation rather than internal oxidation. Therefore, it is necessary to control the dew point to -10°C or higher.
  • the dew point is too high, there is a possibility that oxidation of Fe occurs, so the dew point needs to be controlled to 30°C or less.
  • the dew point can be adjusted by adding wet nitrogen (N 2 +H 2 O) containing 1 to 10% by volume of hydrogen into an annealing furnace.
  • the steel sheet annealed by this process is immediately immersed in a plating bath to perform hot dip galvanization.
  • the steel sheet annealed by this process is reheated to a plating bath temperature or higher (460 to 500°C) and then immersed in a plating bath to perform hot dip galvanization.
  • a plating bath temperature or higher 460 to 500°C
  • the thickness of the annealed steel sheet immersed in the plating bath may be adjusted to 1.0 to 2.0 mm.
  • the plating bath may include 50% by weight or more of Zn as a zinc-based plating bath.
  • the alloying temperature is set in the above-described range.
  • the alloying heat treatment time may be 1 second or more.
  • the alloying degree may exceed the range specified in the present invention, so the upper limit of the alloying heat treatment time may be set to 5 seconds.
  • the hot-dip galvanized steel sheet was obtained without alloying
  • the cold-rolled steel sheet was annealed in an annealing furnace and reheated, followed by plating by dipping in a zinc-based plating bath containing 0.24% by weight of Al. After the nipping, the steel sheet was cooled to finally obtain a hot dip galvanized (GI) steel sheet.
  • GI hot dip galvanized
  • the rolling reduction during cold rolling was 52%
  • the crack zone temperature during annealing was set to 830°C
  • the proportion of hydrogen contained in wet nitrogen in the annealing furnace was set to 5.0% by volume.
  • the conditions for each other example are as described in Table 2 (B and N in the table are expressed in ppm units, and the remaining components are expressed in weight percent).
  • Table 3 shows the results of measuring the properties of the alloyed hot-dip galvanized (GA) steel sheet manufactured by the above-described process, and observing whether liquid metal embrittlement (LME occurred) during spot welding. It was cut along the edges of each cut, and the spot welding current was applied twice and the hold time of 1 cycle was maintained after energization. The spot welding was carried out in 3 layers of 2 types. Evaluation Materials-Evaluation Materials-GA 980DP Spot welding was performed by laminating in the order of 1.4 t. During spot welding, a new electrode was welded 15 times to a soft material, and after the electrode was worn, the upper limit current at which expulsion occurred as a target material for spot welding was measured.
  • G alloyed hot-dip galvanized
  • spot welding is performed 8 times per welding current at currents 0.5 and 1.0 kA lower than the upper limit current, and the end face of the spot welding part is precisely processed by electric discharge machining, then polished by epoxy mounting, and the crack length is measured by an optical microscope.
  • magnification was designated as 100 times, and if no crack was found at the magnification, it was determined that liquid metal embrittlement did not occur, and when cracks were found, the length was measured by image analysis software.
  • the generated B-type crack was 100 ⁇ m or less, and the C-type crack was judged to be good when not observed.
  • the decarburization rate was calculated using concentration values for each depth using GDOES.
  • the surface layer decarburization rate was calculated according to Equation 1 as described above.
  • Tensile strength was measured through a tensile test by making a C-direction sample of JIS-5 standard.
  • the alloying degree and plating adhesion amount were measured using a wet dissolution method using a hydrochloric acid solution.
  • the sealer adhesion was confirmed by attaching the structural adhesive D-type for automobiles to the plating surface, and then bending the steel plate 90 degrees to see if the plating fell off. After powdering, the plated material was bent to 90 degrees, and the tape was adhered to the bent portion, and then peeled off to confirm how many millimeters of the plated layer dropped off the tape. Flaking was checked in the form of'U' and then the plated layer was removed from the processed part.
  • ⁇ 1/4t Ceq means the Ceq at the point of 1/4 of the thickness of the steel sheet.
  • the unit of each Ceq in the table is% by weight.
  • Comparative Example 1 is a case in which the alloying temperature in the GA alloying process is controlled to be lower than the range suggested by the present invention. As a result, the alloying degree is formed lower than the reference, and the surface is too bright, resulting in poor surface quality and flaking, resulting in plating surface quality. This was inferior.
  • Comparative Example 2 is a case in which the heating time during the heat treatment of the edge portion exceeds the range specified in the present invention, and peroxidation occurs at the edge portion during the heat treatment process to form a hematite-based scale with a red surface scale, The thickness of the scale became excessively thick.
  • the edge portion was excessively pickled during the pickling process after hot rolling, the surface roughness was increased, resulting in uneven surface shape after plating, and color nonuniformity defects in which the surface color was different from the central portion.
  • Comparative Example 3 the coiling temperature during the hot rolling process was higher than the range suggested by the present invention. Therefore, sufficient decarburization occurs during the hot rolling process, and the dew point during the annealing is high, so that the surface layer decarburization rate is formed at 40% or higher, and even if the plating surface quality and LME resistance are excellent, the width direction material deviation occurs and the cold rolling property It was inferior and the tensile strength was inferior.
  • Comparative Example 4 is a case where the heat treatment furnace temperature exceeds the range suggested in the present invention, peroxidation occurs at the edge portion during the heat treatment process to form a red hematite-based scale on the surface, and The thickness was excessively thick.
  • the edge portion was excessively pickled during the pickling process after hot rolling, the surface roughness was increased, resulting in uneven surface shape after plating, and color nonuniformity defects in which the surface color was different from the central portion.
  • Comparative Example 5 is a case in which the coiling temperature during the hot rolling process was controlled to be lower than the range suggested by the present invention. Therefore, LME characteristics were inferior because decarbonization occurring during the hot rolling process did not occur sufficiently.
  • Comparative Examples 6 and 13 are cases in which the dew point in the furnace during annealing was lower than the range suggested by the present invention. Even if a sufficient decarburization layer was generated in the entire width during the heating process by the hot rolling and heat treatment, after the cold rolling, the dew point was not sufficiently high during the annealing process, and the homogenization of the carbon occurred, so that a sufficient decarburization level could not be formed, resulting in a poorly welded LME crack length. In the case of GI material, since the dew point was low and sufficient internal oxidation was not generated, the surface oxide was excessively generated, resulting in poor plating adhesion.
  • Comparative Example 7 is a case in which the sheet speed of the steel sheet in the annealing was lower than the range suggested by the present invention. Although sufficient time was given for the decarburization reaction in which the water vapor and the steel plate reacted in the annealing furnace met the criteria in the evaluation of the spot welding LME crack, the production time was long and the productivity was inferior, making it unsuitable as a manufacturing condition.
  • Comparative Example 9 is a case in which the heating temperature of the heat treatment furnace at the edge heat treatment was lower than that of the present invention. As the sufficient decarburization layer was not formed during hot rolling, it was poor because it did not satisfy the criteria when evaluating cracks in spot welding LME.
  • the heating temperature and time of the heat treatment satisfied the range suggested by the present invention, but the oxygen fraction exceeded the range.
  • peroxidation occurred at the edge portion, and the surface scale formed a red hematite-based scale, and the thickness of the scale became excessively thick.
  • the edge portion was excessively pickled during the pickling process after hot rolling, the surface roughness was increased, resulting in uneven surface shape after plating, and color nonuniformity defects in which the surface color was different from the central portion.
  • Comparative Example 12 is a case in which the sheet speed of the steel sheet during annealing heat treatment was controlled higher than the range suggested by the present invention. Since sufficient time was not given for the decarburization reaction in which water vapor and the steel sheet reacted in the annealing furnace, the decarburization rate of the surface layer portion of the steel sheet after annealing was not sufficient, resulting in spot welding LME crack exceeding the standard.
  • Comparative Example 14 is a case where the heat treatment furnace heating temperature and time satisfy the range suggested by the present invention, but the oxygen fraction is lower than the range.
  • the hot-rolled decarburization layer was not sufficiently formed, and thus it was poor because it did not satisfy the criteria in the evaluation of spot welding LME cracks.
  • Comparative Example 17 is a case where the heat treatment furnace heating temperature satisfies the scope of the present invention, but the heat treatment furnace heating time is shorter than the range suggested by the present invention. A sufficient hot-rolled decarburization layer was not formed, and thus it was poor because it did not satisfy the criteria in the evaluation of spot welding LME cracks.

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PCT/KR2019/018005 2018-12-19 2019-12-18 전기 저항 점용접성이 우수한 고강도 아연도금강판 및 그 제조방법 Ceased WO2020130631A1 (ko)

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JP2021534943A JP7680354B2 (ja) 2018-12-19 2019-12-18 電気抵抗スポット溶接性に優れた高強度亜鉛めっき鋼板及びその製造方法
CN201980085280.1A CN113227434B (zh) 2018-12-19 2019-12-18 电阻点焊性优异的高强度镀锌钢板及其制造方法
US17/414,231 US20220042155A1 (en) 2018-12-19 2019-12-18 High-strength galvanized steel sheet having excellent electrical resistance spot weldability, and method for producing same
EP19898057.5A EP3901318A4 (en) 2018-12-19 2019-12-18 HIGH STRENGTH GALVANIZED STEEL SHEET WITH EXCELLENT ELECTRICAL RESISTANCE SPOT WELDING AND PROCESS FOR ITS PRODUCTION
CN202410736826.8A CN118726884A (zh) 2018-12-19 2019-12-18 电阻点焊性优异的高强度镀锌钢板及其制造方法
JP2023192741A JP2024020359A (ja) 2018-12-19 2023-11-13 電気抵抗スポット溶接性に優れた高強度亜鉛めっき鋼板及びその製造方法
US18/622,583 US12221701B2 (en) 2018-12-19 2024-03-29 Welded member of galvanized steel sheets

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Cited By (12)

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JPWO2022149502A1 (https=) * 2021-01-07 2022-07-14
JP2024500721A (ja) * 2020-12-18 2024-01-10 ポスコ カンパニー リミテッド めっき密着性及び溶接性に優れた高強度溶融亜鉛めっき鋼板及びその製造方法
WO2024053669A1 (ja) * 2022-09-06 2024-03-14 日本製鉄株式会社 溶接継手
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