WO2019181851A1 - Ensemble d'agent adhésif et procédé de fabrication de structure - Google Patents

Ensemble d'agent adhésif et procédé de fabrication de structure Download PDF

Info

Publication number
WO2019181851A1
WO2019181851A1 PCT/JP2019/011178 JP2019011178W WO2019181851A1 WO 2019181851 A1 WO2019181851 A1 WO 2019181851A1 JP 2019011178 W JP2019011178 W JP 2019011178W WO 2019181851 A1 WO2019181851 A1 WO 2019181851A1
Authority
WO
WIPO (PCT)
Prior art keywords
meth
liquid
group
component
elastomer
Prior art date
Application number
PCT/JP2019/011178
Other languages
English (en)
Japanese (ja)
Inventor
亜季子 川口
藤本　大輔
Original Assignee
日立化成株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日立化成株式会社 filed Critical 日立化成株式会社
Priority to JP2020507785A priority Critical patent/JPWO2019181851A1/ja
Publication of WO2019181851A1 publication Critical patent/WO2019181851A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical

Definitions

  • the present invention relates to an adhesive set and a method of manufacturing a structure using the same.
  • (meth) acrylic adhesives have been used in various fields including the automobile field. Among them, a first liquid and a second liquid are provided, and by mixing them, the temperature is about room temperature (for example, 30 ° C.). ) Has been studied in various ways (so-called room temperature curable two-component adhesives). A rubber component such as polybutadiene may be added to such a two-pack type (meth) acrylic adhesive as disclosed in Patent Document 1, for example.
  • the present invention has been made in view of the above circumstances, an adhesive set capable of curing at room temperature, which has excellent adhesion to an adherend formed of different materials, and the adhesive. It aims at providing the manufacturing method of the structure using a set.
  • One aspect of the present invention includes a first liquid containing a polymerization initiator and a second liquid containing a reducing agent, and at least one of the first liquid and the second liquid has a monomer having an ethylenically unsaturated group. And at least one of the first liquid and the second liquid relates to an adhesive set containing a (meth) acryl elastomer having a weight average molecular weight of 250,000 or more.
  • the above-mentioned adhesive set is an adhesive set that can be cured at room temperature and has excellent adhesion even to an adherend formed of different kinds of materials. For this reason, by arranging the two liquids included in the adhesive set between the adherends, curing at room temperature, that is, adhesion between the adherends at room temperature is possible, and the adherends are different materials. Even if it is formed with, excellent adhesiveness is exhibited.
  • the glass transition temperature of the (meth) acryl elastomer may be 80 ° C. or less.
  • the (meth) acryl elastomer may have a weight average molecular weight of 300,000 or more, or 400,000 or more.
  • Another aspect of the present invention includes a step of bonding adherends to each other using the adhesive set, wherein the first liquid and the second liquid are disposed between the adherends in the step. It relates to a manufacturing method.
  • adherends can be bonded to each other at room temperature, and a structure in which adherends formed of different materials are suitably bonded to each other can be obtained.
  • the manufacturing method of the structure using the adhesive set which has the adhesiveness which was excellent also to the to-be-adhered body formed from a different material, and which can be cured at room temperature, and the said adhesive set is provided. Provided.
  • (meth) acryl means acryl and methacryl corresponding to it.
  • the adhesive set according to the present embodiment is an adhesive set (also referred to as a two-component adhesive) including a first liquid containing a polymerization initiator and a second liquid containing a reducing agent. At least one of the first liquid and the second liquid contains a monomer having an ethylenically unsaturated group (hereinafter also referred to as “component (A)”), and at least one of the first liquid and the second liquid is a (meth) acryl elastomer. (Hereinafter also referred to as “component (B)”).
  • component (A) monomer having an ethylenically unsaturated group
  • component (B) a (meth) acryl elastomer.
  • the adhesive set according to the present embodiment is an adhesive set that can be cured at room temperature and has excellent adhesion to an adherend formed of different materials.
  • the first liquid includes (A) component, (B) A component and a polymerization initiator are contained, and the 2nd liquid contains (A) component, (B) component, and a reducing agent.
  • the first liquid contains the component (A), the component (B) and the polymerization initiator, and the second liquid contains the reducing agent (the components (A) and (B). Not contained).
  • the first liquid contains a polymerization initiator (not containing (A) component and (B) component), and the second liquid contains (A) component, (B) component and reducing agent. Containing.
  • the first liquid contains the component (A) and the polymerization initiator (does not contain the component (B)), and the second liquid contains the component (B) and the reducing agent (( A) does not contain a component).
  • the first liquid contains the component (B) and the polymerization initiator (not containing the component (A)), and the second liquid contains the component (A) and the reducing agent (( B) Contains no component).
  • the first liquid contains the component (A), the component (B) and the polymerization initiator, and the second liquid contains the component (A) and the reducing agent (the component (B). Not contained).
  • the first liquid contains the component (A), the component (B) and the polymerization initiator, and the second liquid contains the component (B) and the reducing agent (the component (A). Not contained).
  • the first liquid contains the component (A) and the polymerization initiator (does not contain the component (B)), and the second liquid contains the component (A), the component (B), and the reducing agent. Containing.
  • the first liquid contains the component (B) and the polymerization initiator (not containing the component (A)), and the second liquid contains the component (A), the component (B), and the reducing agent. Containing.
  • the component (A) component has an ethylenically unsaturated group (CH 2 ⁇ CR—, R represents a hydrogen atom or a methyl group).
  • the component (A) may contain a carboxyl group, an ester group, an amide group, a cyano group, a phosphoric acid group, a phosphonic acid group, a triazine ring, a thiol group, and the like.
  • Component (A) is a monofunctional monomer having one ethylenically unsaturated group, a bifunctional monomer having two ethylenically unsaturated groups, or a trifunctional or higher polyfunctional monomer having three or more ethylenically unsaturated groups. Any of these may be used.
  • the component (A) preferably contains a (meth) acryl monomer having at least one (meth) acryloyl group from the viewpoint of excellent dispersibility in the (meth) acryl elastomer.
  • the component (A) may contain acrylonitrile and the like.
  • (Meth) acrylic monomer may be, for example, (meth) acrylic acid, alkyl (meth) acrylate, or the like.
  • the number of carbon atoms of the alkyl group in the alkyl (meth) acrylate may be, for example, 1 to 18, 1 to 12, or 1 to 8.
  • the alkyl group may be linear, branched or cyclic.
  • the alkyl (meth) acrylate may be, for example, methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, butyl (meth) acrylate, dicyclopentanyl (meth) acrylate, and the like (meth) From the viewpoint of further excellent dispersibility in the acrylic elastomer, methyl methacrylate is preferable.
  • (Meth) acrylic monomer may contain a phosphate group.
  • examples of such (meth) acrylic monomers include acid phosphooxyethyl (meth) acrylate, acid phosphooxypropyl (meth) acrylate, acid phosphooxypolyoxyethylene glycol mono (meth) acrylate, and acid phosphooxypolyoxypropylene.
  • examples include glycol mono (meth) acrylate, 2,2′-di (meth) acryloyloxydiethyl phosphate, EO (ethylene oxide) -modified di (meth) acrylate, and phosphoric acid-modified epoxy (meth) acrylate.
  • the (meth) acrylic monomer may be, for example, a (meth) acrylic monomer having a triazine ring such as isocyanuric acid-modified (meth) acrylate.
  • the (meth) acryl monomer may be, for example, a (meth) acryl monomer having an amino group such as acrylamide.
  • (Meth) acrylic monomer may contain two or more (meth) acryloyl groups.
  • examples of such (meth) acrylic monomers include bifunctional monomers such as diethylene glycol di (meth) acrylate and 1,6-hexanediol di (meth) acrylate, trimethylolpropane triacrylate, pentaerythritol tri (meth) ) Trifunctional monomers such as acrylate, or tetrafunctional monomers such as ditrimethylolpropane tetra (meth) acrylate.
  • the (meth) acryl monomer may be a (meth) acrylate containing 5 or more (meth) acryloyl groups.
  • component (A) components can be used singly or in combination of two or more.
  • the component (A) contained in the first liquid and the component (A) contained in the second liquid may be the same as each other. They may be different and are preferably the same as each other.
  • the total amount of the component (A) in the first liquid and the second liquid may be, for example, 5 parts by mass or more with respect to 100 parts by mass of the total amount of the component (A) and the component (B). From a viewpoint, Preferably it is 10 mass parts or more, More preferably, it is 20 mass parts or more.
  • the total amount of the content may be, for example, 99 parts by mass or less with respect to 100 parts by mass of the total amount of the component (A) and the component (B).
  • a (meth) acryl elastomer is an elastomer containing a structural unit represented by the following formula (1).
  • R 1 represents a hydrogen atom or a methyl group
  • R 2 represents a hydrogen atom or a monovalent organic group.
  • the organic group represented by R 2 may be, for example, a hydrocarbon group.
  • the hydrocarbon group may be a chain or a ring.
  • the chain hydrocarbon group may be linear or branched. These hydrocarbon groups may have, for example, 1 to 20, 1 to 15, or 1 to 10 carbon atoms.
  • the hydrocarbon group may be an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a cycloalkyl group, or the like.
  • alkyl group examples include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group and the like.
  • alkenyl group examples include a vinyl group, a propenyl group, and a butenyl group.
  • alkynyl group examples include ethynyl group, propargyl group, butynyl group, pentynyl group, hexynyl group and the like.
  • aryl group a phenyl group, a toluyl group, a naphthyl group etc.
  • cycloalkyl group examples include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclopentadienyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, a cyclononyl group, a cyclodecyl group, and a dicyclopentanyl group.
  • the organic group represented by R 2 may have a substituent other than a hydrocarbon group.
  • an optimum substituent can be selected from the viewpoint of adhesiveness according to the type of material used for the adherend.
  • the substituent may be, for example, a glycidyl group, a carboxyl group, a phosphate group, a sulfo group, a phosphonic acid group, a hydroxyl group, a nitro group, a cyano group, an amino group, an alkoxy group, an acyloxy group, etc., and is formed of a metal.
  • a glycidyl group, a hydroxyl group, a phosphoric acid group, a phosphonic acid group, a nitro group, a cyano group, an amino group, and the like are preferable.
  • the (meth) acryl elastomer may further contain a structural unit represented by the following formula (2) (a structural unit derived from acrylonitrile) in addition to the structural unit represented by the formula (1).
  • the (meth) acryl elastomer may further contain a structural unit (structural unit derived from acrylamide) represented by the following formula (3) in addition to the structural unit represented by the formula (1).
  • (Meth) acrylic elastomer contains one or more of the above-mentioned structural units so as to have rubber elasticity, and preferably contains two or more of the above-mentioned structural units.
  • the (meth) acryl elastomer may contain only one type or two or more types of the structural units described above as the structural unit.
  • the (meth) acrylic elastomer may be an elastomer that does not contain a structural unit other than the structural units described above (for example, a structural unit derived from an olefin such as ethylene, propylene, and butadiene).
  • the (meth) acryl elastomer may be composed of two or more structural units represented by the formula (1).
  • the (meth) acryl elastomer is represented by the formula (1)
  • the organic group represented by R 2 is represented by the formula (1) and one or more structural units of a hydrocarbon group.
  • the organic group represented by R 2 may consist of one or more structural units having a glycidyl group or a hydroxyl group.
  • the (meth) acryl elastomer may be composed of a structural unit represented by the formula (1) and a structural unit represented by the formula (2).
  • the (meth) acryl elastomer may contain two or more kinds of structural units as the structural unit represented by the formula (1).
  • the organic group represented by the formula (1) and represented by R 2 1 type or 2 types or more of structural units in which is a hydrocarbon group, and 1 type or 2 types or more of structural units represented by the formula (1), wherein the organic group represented by R 2 has a glycidyl group or a hydroxyl group And may be included.
  • the content of the structural unit represented by the formula (1) may be 1% by mass or more, 20% by mass or more, or 50% by mass or more based on the total amount of structural units of the (meth) acryl elastomer.
  • the content of the structural unit represented by the formula (1) and the organic group represented by R 2 is a hydrocarbon group is 1% by mass or more and 20% by mass based on the total amount of the structural unit of the (meth) acryl elastomer. It may be 30% by mass or more, or 99% by mass or less or 95% by mass or less.
  • the content of the structural unit represented by the formula (1) and the organic group represented by R 2 having a substituent other than the hydrocarbon group is 1% by mass or more based on the total amount of the structural unit of the (meth) acryl elastomer. Or it may be 2 mass% or more, and may be 60 mass% or less, 50 mass% or less, or 40 mass% or less.
  • the content of the structural unit represented by the formula (2) may be 60% by mass or less, 50% by mass or less, or 40% by mass or less based on the total amount of the structural unit of the (meth) acryl elastomer.
  • the elastic modulus of the (meth) acryl elastomer is preferably 3000 MPa or less, 2000 MPa or less, or 1500 MPa or less from the viewpoint of excellent suppression of warpage when different types of adherends are joined.
  • the elastic modulus of the (meth) acryl elastomer is calculated from the initial slope of the stress-strain curve by conducting a tensile test. The tensile test is performed using an autograph (“AGS-X” manufactured by Shimadzu Corporation) with a test piece cut into 5 mm ⁇ 0.5 mm (distance between chucks: 20 mm, tensile speed: 5 mm / min).
  • the glass transition temperature (Tg) of the (meth) acryl elastomer is preferably 130 ° C. or lower, 100 ° C. or lower, 80 ° C. or lower, 70 ° C. or lower, 60 ° C. or lower, from the viewpoint of further excellent adhesion to different types of adherends. 50 ° C or lower, 40 ° C or lower, 30 ° C or lower, 20 ° C or lower, 0 ° C or lower, or -10 ° C or lower.
  • the glass transition temperature (Tg) of the (meth) acryl elastomer may be, for example, ⁇ 50 ° C. or higher.
  • the (meth) acryl elastomer may have two or more glass transition temperatures (Tg). In this case, it is preferable that at least one of the two or more glass transition temperatures (Tg) is in the above range, and it is more preferable that all of the two or more glass transition temperatures (Tg) are in the above range. .
  • the glass transition temperature (Tg) of the (meth) acryl elastomer means an intermediate glass transition temperature value by differential scanning calorimetry using a differential scanning calorimeter (for example, “Thermo Plus 2” manufactured by Rigaku Corporation). Specifically, the glass transition temperature (Tg) of the (meth) acryl elastomer is measured in the measurement temperature range: ⁇ 50 to 300 ° C., and the temperature rise rate is 10 ° C./min. And means the midpoint glass transition temperature calculated by a method based on JIS K7121: 1987.
  • the weight average molecular weight (Mw) of the (meth) acryl elastomer is 250,000 or more, preferably 300,000 or more, more preferably 400,000 or more, 500,000 or more, 600,000 or more, or 700,000 or more. Also good.
  • the weight average molecular weight (Mw) of the (meth) acryl elastomer may be 1 million or less, for example. The greater the weight average molecular weight (Mw) of the (meth) acryl elastomer, the better the elongation, strength and rupture energy of the cured product of the mixture of the first liquid and the second liquid, and the adhesion (stress) between different types of adherends. There is a tendency to be excellent in relaxation.
  • the weight average molecular weight (Mw) of the (meth) acryl elastomer means a value determined by using a gel permeation chromatography (GPC) method under the following conditions and determining polystyrene as a standard substance.
  • GPC gel permeation chromatography
  • (Meth) acrylic elastomer can be used alone or in combination of two or more.
  • the (meth) acryl elastomer contained in the first liquid and the (meth) acryl elastomer contained in the second liquid are the same as each other. They may be different or different, and are preferably the same as each other.
  • the total amount of the component (B) in the first liquid and the second liquid may be, for example, 5 parts by mass or more with respect to 100 parts by mass of the total amount of the component (A) and the component (B). From a viewpoint, Preferably it is 10 mass parts or more, More preferably, it is 20 mass parts or more.
  • the total amount of the content is, for example, 99 parts by mass or less with respect to 100 parts by mass of the total amount of the component (A) and the component (B).
  • the polymerization initiator may be a radical polymerization initiator, for example.
  • the radical polymerization initiator may be, for example, an organic peroxide or an azo compound.
  • the organic peroxide may be, for example, hydroperoxide, peroxydicarbonate, peroxyester, peroxyketal, dialkyl peroxide, diacyl peroxide, and the like.
  • the azo compound may be AIBN (2,2′-azobisisobutyronitrile), V-65 (azobisdimethylvaleronitrile) or the like.
  • a polymerization initiator can be used individually by 1 type or in combination of 2 or more types.
  • hydroperoxide examples include diisopropylbenzene hydroperoxide and cumene hydroperoxide.
  • Peroxydicarbonates include di-n-propyl peroxydicarbonate, diisopropyl peroxydicarbonate, bis (4-tert-butylcyclohexyl) peroxydicarbonate, di-2-ethoxymethoxyperoxydicarbonate, di- (2-Ethylhexylperoxy) dicarbonate, dimethoxybutylperoxydicarbonate, di (3-methyl-3methoxybutylperoxy) dicarbonate and the like.
  • Peroxyesters include cumyl peroxyneodecanoate, 1,1,3,3-tetramethylbutylperoxyneodecanoate, 1-cyclohexyl-1-methylethylperoxyneodecanoate, t -Hexylperoxyneodecanoate, t-butylperoxypivalate, 1,1,3,3-tetramethylbutylperoxy-2-ethylhexanoate, 2,5-dimethyl-2,5-di ( 2-ethylhexanoylperoxy) hexane, 1-cyclohexyl-1-methylethylperoxy-2-ethylhexanate, t-hexylperoxy-2-ethylhexanoate, t-butylperoxy-2 -Ethylhexanoate, t-butylperoxyisobutyrate, 1,1-bis (t-butylperoxy) cyclohex
  • Peroxyketals include 1,1-bis (t-hexylperoxy) -3,3,5-trimethylcyclohexane, 1,1-bis (t-hexylperoxy) cyclohexane, 1,1- Bis (t-butylperoxy) -3,3,5-trimethylcyclohexane, 1,1-bis (t-butylperoxy) cyclododecane, 2,2-bis (t-butylperoxy) decane, etc. Can be mentioned.
  • Dialkyl peroxides include ⁇ , ⁇ '-bis (t-butylperoxy) diisopropylbenzene, dicumyl peroxide, 2,5-dimethyl-2,5-di (t-butylperoxy) hexane, t- Examples thereof include butyl cumyl peroxide.
  • Diacyl peroxides include isobutyl peroxide, 2,4-dichlorobenzoyl peroxide, 3,5,5-trimethylhexanoyl peroxide, octanoyl peroxide, lauroyl peroxide, stearoyl peroxide, succinic peroxide , Benzoylperoxytoluene, benzoyl peroxide and the like.
  • the radical polymerization initiator is preferably a peroxide, more preferably a hydroperoxide, and still more preferably cumene hydroperoxide from the viewpoint of storage stability.
  • the content of the polymerization initiator in the first liquid is, for example, 0.1 parts by mass or more with respect to 100 parts by mass of the total amount of the components (A) and (B) contained in the first liquid and the second liquid. It may be 20 parts by mass or less.
  • the reducing agent may be, for example, a tertiary amine, a thiourea derivative, a transition metal salt, or the like.
  • a tertiary amine include triethylamine, tripropylamine, tributylamine, N, N-dimethylparatoluidine and the like.
  • the thiourea derivative include 2-mercaptobenzimidazole, methylthiourea, dibutylthiourea, tetramethylthiourea, ethylenethiourea and the like.
  • transition metal salts include cobalt naphthenate, copper naphthenate, and vanadyl acetylacetonate.
  • a reducing agent can be used individually by 1 type or in combination of 2 or more types.
  • the reducing agent is preferably a thiourea derivative or a transition metal salt from the viewpoint of curing speed.
  • the thiourea derivative may be, for example, ethylene thiourea.
  • the transition metal salt is preferably vanadyl acetylacetonate.
  • the content of the reducing agent in the second liquid is, for example, 0.01 parts by mass or more with respect to 100 parts by mass of the total amount of the component (A) and the component (B) contained in the first liquid and the second liquid.
  • the said content is 10 mass parts or less with respect to 100 mass parts of total amounts of (A) component and (B) component contained in a 1st liquid and a 2nd liquid, for example.
  • the adhesive set may contain other components other than the component (A), the component (B), the polymerization initiator, and the reducing agent.
  • the other components may be contained in one or both of the first liquid and the second liquid, and may be contained in a third liquid different from the first liquid and the second liquid.
  • polymerization inhibitors for the purpose of improving storage stability.
  • examples of the polymerization inhibitor include hydroquinone, methyl hydroquinone, hydroquinone monomethyl ether, catechol, pyrogallol, and phenothiazine.
  • paraffins for the purpose of preventing polymerization inhibition by oxygen.
  • paraffins include paraffin wax, microcrystalline wax, carnauba wax, beeswax, lanolin, whale wax, ceresin, and candelilla wax.
  • the other components may be fillers for the purpose of preventing dripping, imparting thixotropy, and improving adhesive strength.
  • Examples of the shape of the filler include a fibrous filler and a spherical filler.
  • the filler component examples include metal fillers such as silver powder, gold powder, copper powder, and nickel powder, alumina, aluminum hydroxide, magnesium hydroxide, calcium carbonate, magnesium carbonate, calcium silicate, magnesium silicate, calcium oxide, and oxidation.
  • metal fillers such as silver powder, gold powder, copper powder, and nickel powder, alumina, aluminum hydroxide, magnesium hydroxide, calcium carbonate, magnesium carbonate, calcium silicate, magnesium silicate, calcium oxide, and oxidation.
  • metal fillers such as silver powder, gold powder, copper powder, and nickel powder, alumina, aluminum hydroxide, magnesium hydroxide, calcium carbonate, magnesium carbonate, calcium silicate, magnesium silicate, calcium oxide, and oxidation.
  • examples thereof include magnesium, aluminum oxide, aluminum nitride, crystalline silica, amorphous silica, boron nitride, titania, glass, iron oxide, inorganic fillers such as ceramics, and organic fillers such as carbon and rubber fillers.
  • the manufacturing method of the structure using the adhesive set according to the present embodiment includes a step (adhesion step) of bonding adherends to each other using the above-described adhesive set.
  • the first liquid and the second liquid are disposed between the adherends.
  • the adherend is formed of, for example, metal such as steel, iron, copper, tin, aluminum, and stainless steel, resin, carbon fiber reinforced plastic (CFRP), and the like.
  • the two adherends to be bonded may be made of the same kind of material, or may be made of different kinds of materials. Since the adhesive set used in this manufacturing method is excellent in adhesiveness to different types of adherends, even if one adherend and the other adherend are formed of different materials from each other, Thus, a structure in which adherends are suitably bonded to each other is obtained.
  • one adherend and another adherend are arranged with a predetermined gap therebetween, and the first liquid and the second liquid are placed in the gap using a device such as a mixing nozzle. Inject two liquids.
  • the first liquid and the second liquid may be mixed substantially simultaneously with the injection between the adherends, or the first liquid and the second liquid may be mixed immediately before the injection between the adherends. Good.
  • the mixture is cured and the adherends are bonded to each other.
  • the temperature at which the bonding step is performed may be, for example, 100 ° C. or lower, 80 ° C. or lower, or 50 ° C. or lower, and may be 5 ° C. or higher, 10 It may be higher than or equal to 20 ° C.
  • the bonding step may be performed while changing the temperature stepwise. For example, after the bonding is performed at a temperature of 50 ° C. or lower, after-curing may be performed at a temperature of 100 ° C. or lower.
  • the structure obtained by the above manufacturing method is provided with one adherend, another adherend, and an adhesion part that adheres the one adherend and the other adherend.
  • the adhesion part is a cured product of a mixture of liquids (for example, a mixture of the first liquid and the second liquid) constituting the above-described adhesive set.
  • (meth) acryl elastomer 1A a (meth) acryl elastomer (hereinafter referred to as (meth) acryl elastomer 1A).
  • Synthesis Example 1B Except having been changed to 0.6 g lauroyl peroxide as an initiator, it was synthesized under the same conditions as in Synthesis Example 1A, includes the same structural unit as (meth) acrylic elastomer 1A, and has Mw and Tg shown in Table 1 ( A (meth) acrylic elastomer (hereinafter referred to as (meth) acrylic elastomer 1B) was obtained.
  • Synthesis Example 1C Except having been changed to 0.75 g of lauroyl peroxide as an initiator, it was synthesized under the same conditions as in Synthesis Example 1A, includes the same structural unit as (meth) acrylic elastomer 1A, and has Mw and Tg shown in Table 1 ( A (meth) acrylic elastomer (hereinafter referred to as (meth) acrylic elastomer 1C) was obtained.
  • Synthesis Example 2A instead of the monomer used in Synthesis Example 1A, synthesis was performed under the same conditions as in Synthesis Example 1A except that BA 69.5 g, acrylonitrile (AN) 28 g, and GMA 2.5 g were used. A (meth) acrylic elastomer (hereinafter referred to as (meth) acrylic elastomer 2A) was obtained.
  • Synthesis Example 2B Except having been changed to 0.6 g lauroyl peroxide as an initiator, it was synthesized under the same conditions as in Synthesis Example 2A, includes the same structural unit as (meth) acrylic elastomer 2A, and has Mw and Tg shown in Table 1 ( A (meth) acrylic elastomer (hereinafter referred to as (meth) acrylic elastomer 2B) was obtained.
  • Synthesis Example 2C Except having been changed to 0.75 g of lauroyl peroxide as an initiator, it was synthesized under the same conditions as in Synthesis Example 2A, includes the same structural unit as (meth) acrylic elastomer 2A, and has Mw and Tg shown in Table 1 ( A (meth) acrylic elastomer (hereinafter referred to as (meth) acrylic elastomer 2C) was obtained.
  • (Synthesis Example 4) The same structural unit as (meth) acrylic elastomer 1A was synthesized under the same conditions as in Synthesis Example 1A, except that the initiator was changed to 0.75 g of lauroyl peroxide and the temperature in the flask was changed to 65 ° C.
  • ⁇ Preparation of evaluation sample> A 0.2 mm spacer was placed between an aluminum plate having a size of 5 mm ⁇ 100 mm and a thickness of 0.5 mm and a cold-rolled steel plate so that the thickness of the adhesive was 0.2 mm.
  • the first liquid and the second liquid were mixed between the aluminum plate and the cold-rolled steel plate while mixing using a mixing nozzle (manufactured by Tomita Engineering Co., Ltd.) to produce an evaluation sample 1.
  • Evaluation sample 2 in the same manner as evaluation sample 1 except that a CFRP plate having a size of 5 mm ⁇ 100 mm and a thickness of 2 mm was used instead of the aluminum plate having a size of 5 mm ⁇ 100 mm and a thickness of 0.5 mm. was made.
  • Evaluation samples 1 and 2 were heated at 170 ° C. for 20 minutes, then allowed to cool at room temperature (30 ° C.), and the presence or absence of warpage or peeling was visually confirmed. Of those that did not warp or peel over 5 mm, those with a warp of 1 mm or less were evaluated as A +, those with a warp of greater than 1 mm and less than 3 mm were evaluated as A, and those with a warp of 3 mm or more were evaluated as A-. . Moreover, the thing with the curvature or peeling of 5 mm or more was evaluated as B. The warpage was measured by measuring the distance between the other end and the base in a state where one end of the evaluation sample was fixed on a base parallel to the ground.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Selon un mode de réalisation, l'invention fournit un ensemble d'agent adhésif qui comporte: un premier liquide comprenant un initiateur de polymérisation, et un second liquide contenant un réducteur. Le premier et/ou le second liquide contient également un monomère possédant un groupe éthyléniquement insaturé. De plus, le premier et/ou le second liquide contient un élastomère (méth)acrylique de masse moléculaire moyenne en poids supérieure ou égale à 250000.
PCT/JP2019/011178 2018-03-19 2019-03-18 Ensemble d'agent adhésif et procédé de fabrication de structure WO2019181851A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2020507785A JPWO2019181851A1 (ja) 2018-03-19 2019-03-18 接着剤セット及び構造体の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JPPCT/JP2018/010887 2018-03-19
PCT/JP2018/010887 WO2019180791A1 (fr) 2018-03-19 2018-03-19 Ensemble d'agent adhésif et procédé de fabrication de structure

Publications (1)

Publication Number Publication Date
WO2019181851A1 true WO2019181851A1 (fr) 2019-09-26

Family

ID=67987229

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/JP2018/010887 WO2019180791A1 (fr) 2018-03-19 2018-03-19 Ensemble d'agent adhésif et procédé de fabrication de structure
PCT/JP2019/011178 WO2019181851A1 (fr) 2018-03-19 2019-03-18 Ensemble d'agent adhésif et procédé de fabrication de structure

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/JP2018/010887 WO2019180791A1 (fr) 2018-03-19 2018-03-19 Ensemble d'agent adhésif et procédé de fabrication de structure

Country Status (2)

Country Link
JP (1) JPWO2019181851A1 (fr)
WO (2) WO2019180791A1 (fr)

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5347434A (en) * 1976-10-12 1978-04-27 Toagosei Chem Ind Co Ltd Composition for acrylic adhesive
JPS58174476A (ja) * 1982-04-08 1983-10-13 Koatsu Gas Kogyo Kk 二液型アクリル系接着剤組成物
JPS59159867A (ja) * 1983-02-28 1984-09-10 Suriibondo:Kk 接着剤組成物
JPS6128568A (ja) * 1984-05-31 1986-02-08 Nippon Shokubai Kagaku Kogyo Co Ltd 接着剤組成物
JPS6151072A (ja) * 1984-08-17 1986-03-13 Nogawa Chem Kk 二液非混合型アクリル系接着剤組成物
JPS6281469A (ja) * 1985-10-03 1987-04-14 Koatsu Gas Kogyo Kk 二液型アクリル系接着剤組成物
JPS6372772A (ja) * 1986-09-16 1988-04-02 Nippon Zeon Co Ltd 接着剤組成物
JPS6411176A (en) * 1987-07-03 1989-01-13 Koatsu Gas Kogyo Two-pack type acrylic adhesive composition
JPH02178374A (ja) * 1988-12-29 1990-07-11 Kanebo N S C Kk 二液型アクリル系接着剤組成物
JPH0598216A (ja) * 1991-04-29 1993-04-20 Natl Starch & Chem Investment Holding Corp アクリル接着剤配合物
JPH09183950A (ja) * 1995-12-28 1997-07-15 Koatsu Gas Kogyo Co Ltd 二液型アクリル系接着剤組成物
JP2005317487A (ja) * 2004-03-29 2005-11-10 Nitto Denko Corp 蛍光体除去用粘着シート
JP2008239670A (ja) * 2007-03-26 2008-10-09 Tokai Rubber Ind Ltd 電歪型アクチュエータ用アクリルゴム、およびそれを用いた電歪型アクチュエータ
JP2010034537A (ja) * 2008-06-24 2010-02-12 Hitachi Chem Co Ltd 電波吸収シート用組成物、それを用いてなる電波吸収シート及び電波吸収体
JP2014088458A (ja) * 2012-10-29 2014-05-15 Mitsubishi Rayon Co Ltd アクリル系接着剤組成物

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440910A (en) * 1982-01-18 1984-04-03 Loctite Corporation Toughened cyanoacrylates containing elastomeric rubbers

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5347434A (en) * 1976-10-12 1978-04-27 Toagosei Chem Ind Co Ltd Composition for acrylic adhesive
JPS58174476A (ja) * 1982-04-08 1983-10-13 Koatsu Gas Kogyo Kk 二液型アクリル系接着剤組成物
JPS59159867A (ja) * 1983-02-28 1984-09-10 Suriibondo:Kk 接着剤組成物
JPS6128568A (ja) * 1984-05-31 1986-02-08 Nippon Shokubai Kagaku Kogyo Co Ltd 接着剤組成物
JPS6151072A (ja) * 1984-08-17 1986-03-13 Nogawa Chem Kk 二液非混合型アクリル系接着剤組成物
JPS6281469A (ja) * 1985-10-03 1987-04-14 Koatsu Gas Kogyo Kk 二液型アクリル系接着剤組成物
JPS6372772A (ja) * 1986-09-16 1988-04-02 Nippon Zeon Co Ltd 接着剤組成物
JPS6411176A (en) * 1987-07-03 1989-01-13 Koatsu Gas Kogyo Two-pack type acrylic adhesive composition
JPH02178374A (ja) * 1988-12-29 1990-07-11 Kanebo N S C Kk 二液型アクリル系接着剤組成物
JPH0598216A (ja) * 1991-04-29 1993-04-20 Natl Starch & Chem Investment Holding Corp アクリル接着剤配合物
JPH09183950A (ja) * 1995-12-28 1997-07-15 Koatsu Gas Kogyo Co Ltd 二液型アクリル系接着剤組成物
JP2005317487A (ja) * 2004-03-29 2005-11-10 Nitto Denko Corp 蛍光体除去用粘着シート
JP2008239670A (ja) * 2007-03-26 2008-10-09 Tokai Rubber Ind Ltd 電歪型アクチュエータ用アクリルゴム、およびそれを用いた電歪型アクチュエータ
JP2010034537A (ja) * 2008-06-24 2010-02-12 Hitachi Chem Co Ltd 電波吸収シート用組成物、それを用いてなる電波吸収シート及び電波吸収体
JP2014088458A (ja) * 2012-10-29 2014-05-15 Mitsubishi Rayon Co Ltd アクリル系接着剤組成物

Also Published As

Publication number Publication date
JPWO2019181851A1 (ja) 2021-03-25
WO2019180791A1 (fr) 2019-09-26

Similar Documents

Publication Publication Date Title
JP5419318B2 (ja) 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
WO2021106992A1 (fr) Ensemble composition durcissable et article
WO2019181851A1 (fr) Ensemble d'agent adhésif et procédé de fabrication de structure
WO2021106994A1 (fr) Ensemble composition contenant un compose possedant une chaîne polyoxyalkylene
JP5356763B2 (ja) 樹脂組成物および半導体装置
CN109072029B (zh) 自由基固化型粘接组合物、粘接剂
JP7318883B2 (ja) （メタ）アクリル系樹脂組成物
JP2014145030A (ja) 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
JP5510701B2 (ja) 接着剤組成物
WO2023223978A1 (fr) Composition qui contient un composé ayant une chaîne polyoxyalkylène et un agent à base d'ester conférant une thixotropie
JP2022035695A (ja) メソゲン骨格を有する（メタ）アクリレートを含有する組成物
JP2009221297A (ja) 接着剤組成物
CN111344374B (zh) 自由基固化型粘接组合物、粘接剂
WO2023223979A1 (fr) Composition qui contient un composé ayant une chaîne polyoxyalkylène et un copolymère acrylique
JP4929688B2 (ja) 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
WO2024009895A1 (fr) Composition comprenant un polymère (méth)acrylique et des particules métalliques
JP4400424B2 (ja) 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
JP2020055894A (ja) 接着剤セット及び構造体の製造方法
JP4830430B2 (ja) 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
JP7338303B2 (ja) 接着剤セット及び構造体の製造方法
JP4935026B2 (ja) 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
JP2021031508A (ja) 接着剤、接着剤セット及び構造体の製造方法
JP4539232B2 (ja) 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
JP5017772B2 (ja) 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
JP2014088458A (ja) アクリル系接着剤組成物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 19771719

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2020507785

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 19771719

Country of ref document: EP

Kind code of ref document: A1