WO2019066375A3 - 열가소성 수지 조성물 및 이로부터 제조된 열가소성 수지 성형품 - Google Patents

열가소성 수지 조성물 및 이로부터 제조된 열가소성 수지 성형품 Download PDF

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Publication number
WO2019066375A3
WO2019066375A3 PCT/KR2018/011107 KR2018011107W WO2019066375A3 WO 2019066375 A3 WO2019066375 A3 WO 2019066375A3 KR 2018011107 W KR2018011107 W KR 2018011107W WO 2019066375 A3 WO2019066375 A3 WO 2019066375A3
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WIPO (PCT)
Prior art keywords
thermoplastic resin
resin composition
layer
graft
copolymer
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PCT/KR2018/011107
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English (en)
French (fr)
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WO2019066375A2 (ko
Inventor
최정수
이원석
이루다
이종주
유근훈
장석구
박상후
옥혜정
김호훈
심형섭
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주식회사 엘지화학
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Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to EP18862507.3A priority Critical patent/EP3640297B1/en
Priority to CN201880045895.7A priority patent/CN110914361B/zh
Priority to US16/630,805 priority patent/US11267964B2/en
Publication of WO2019066375A2 publication Critical patent/WO2019066375A2/ko
Publication of WO2019066375A3 publication Critical patent/WO2019066375A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/53—Core-shell polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

본 발명은 우수한 투명성 및 내백화성을 나타내는 열가소성 수지 조성물에 관한 것으로, 본 발명의 열가소성 수지 조성물은 (A) 다층구조의 그래프트 공중합체 및 (B) 열가소성 공중합체를 포함하고, 상기 다층구조의 그래프트 공중합체(A)는 500 Å 내지 2,000 Å의 중량평균 입경을 가지는 공액 디엔계 고무 라텍스의 코어; 중간층; 및 그라프트 층을 포함하는 것으로, 상기 중간층의 유리전이온도는 40℃ 이하이고, 상기 그라프트 층의 유리전이온도는 80℃ 이상이며, 그래프트 공중합체(A) 및 열가소성 공중합체(B) 간의 굴절율의 차이는 0.01 미만인 것이다.
PCT/KR2018/011107 2017-09-29 2018-09-20 열가소성 수지 조성물 및 이로부터 제조된 열가소성 수지 성형품 WO2019066375A2 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP18862507.3A EP3640297B1 (en) 2017-09-29 2018-09-20 Thermoplastic resin composition and method for preparing the thermoplastic resin composition
CN201880045895.7A CN110914361B (zh) 2017-09-29 2018-09-20 热塑性树脂组合物以及使用其制备的热塑性树脂模制品
US16/630,805 US11267964B2 (en) 2017-09-29 2018-09-20 Thermoplastic resin composition and thermoplastic resin molded article prepared by using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2017-0127617 2017-09-29
KR20170127617 2017-09-29

Publications (2)

Publication Number Publication Date
WO2019066375A2 WO2019066375A2 (ko) 2019-04-04
WO2019066375A3 true WO2019066375A3 (ko) 2019-05-23

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PCT/KR2018/011107 WO2019066375A2 (ko) 2017-09-29 2018-09-20 열가소성 수지 조성물 및 이로부터 제조된 열가소성 수지 성형품

Country Status (5)

Country Link
US (1) US11267964B2 (ko)
EP (1) EP3640297B1 (ko)
KR (1) KR102161030B1 (ko)
CN (1) CN110914361B (ko)
WO (1) WO2019066375A2 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102044364B1 (ko) * 2016-11-11 2019-11-13 주식회사 엘지화학 열가소성 수지 및 열가소성 수지 조성물
CN113574111B (zh) * 2019-03-15 2022-06-21 东丽株式会社 苯乙烯系热塑性树脂组合物及其制造方法、成型品和成型品的制造方法
EP4019587A4 (en) * 2020-07-20 2022-12-07 LG Chem, Ltd. THERMOPLASTIC RESIN AND METHOD OF MANUFACTURE THEREOF
WO2022035071A1 (ko) * 2020-08-11 2022-02-17 (주) 엘지화학 투명 열가소성 수지 및 이의 제조방법
WO2022085899A1 (ko) * 2020-10-22 2022-04-28 (주) 엘지화학 열가소성 수지 조성물 및 이로부터 제조된 성형품
KR20230047908A (ko) * 2021-10-01 2023-04-10 주식회사 엘지화학 투명 수지 조성물 및 성형품

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070108008A (ko) * 2006-05-04 2007-11-08 제일모직주식회사 내스크래치성이 우수한 수지 조성물
KR20130046162A (ko) * 2011-10-27 2013-05-07 제일모직주식회사 열가소성 수지 조성물 및 이를 이용한 성형품
KR20130082221A (ko) * 2012-01-11 2013-07-19 주식회사 엘지화학 열가소성 투명수지 및 그 제조방법
KR20150137558A (ko) * 2014-05-30 2015-12-09 제일모직주식회사 내열성 및 내크래치성이 향상된 열가소성 수지 조성물
KR20170069456A (ko) * 2015-12-11 2017-06-21 주식회사 엘지화학 열가소성 수지 조성물 및 이를 포함하는 성형품

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6284109A (ja) 1985-10-09 1987-04-17 Japan Synthetic Rubber Co Ltd 熱可塑性樹脂組成物の製造方法
US5891962A (en) 1994-09-20 1999-04-06 Mitsui Chemicals, Inc. Transparent, rubber-modified styrene resin and production process thereof
JPH08199008A (ja) 1995-01-27 1996-08-06 Densen Sogo Gijutsu Center 低煙・低毒性難燃ポリオレフィンコンパゥンド
JP3879204B2 (ja) 1997-11-17 2007-02-07 石川島播磨重工業株式会社 排煙脱硫装置の吸収塔循環ポンプ起動・停止時における吸収剤スラリー流量制御方法及び装置
DE19958820B4 (de) 1999-12-07 2010-04-01 Vestolit Gmbh & Co. Kg Verfahren zur Herstellung thermoplastischer Formmassen, nach diesem Verfahren hergestellte Formmassen und deren Verwendung
DE19961894A1 (de) 1999-12-20 2001-06-21 Basf Ag Transparente, schlagzähe thermoplastische Formmassen
KR20030012155A (ko) 2001-07-30 2003-02-12 주식회사 엘지화학 압출쉬트용 아크릴로니트릴-부타디엔-스티렌(ａｂｓ)열가소성 투명수지의 제조방법
KR100442922B1 (ko) * 2001-10-29 2004-08-02 주식회사 엘지화학 내화학성 및 투명성이 우수한아크릴로니트릴-부타디엔-스티렌계 공중합 투명수지 및그의 제조방법
KR100626954B1 (ko) 2004-08-19 2006-09-20 주식회사 엘지화학 열가소성 투명수지 조성물 및 그 제조방법
JP4818635B2 (ja) 2005-04-28 2011-11-16 三菱レイヨン株式会社 衝撃強度改質剤および耐衝撃性樹脂組成物
PL2697267T3 (pl) * 2011-04-11 2016-04-29 Allnex Netherlands Bv Sposób wytwarzania wodnych dyspersji polimerów winylowych
KR20140087879A (ko) 2012-12-31 2014-07-09 제일모직주식회사 투명 열가소성 수지 조성물 및 이로부터 형성된 성형품
KR101442412B1 (ko) * 2013-05-03 2014-09-17 주식회사 엘지화학 고무 강화 그라프트 공중합체용 고무질 중합체 및 그 제조방법
KR101743326B1 (ko) 2013-06-28 2017-06-02 롯데첨단소재(주) 저온 내백화 특성이 개선되고 내충격성이 우수한 투명 열가소성 수지 조성물
US9034963B2 (en) 2013-06-28 2015-05-19 Cheil Industries Inc. Transparent thermoplastic resin composition having improved whitening resistance at low temperature and excellent impact strength
WO2016043424A1 (ko) * 2014-09-16 2016-03-24 주식회사 엘지화학 열가소성 수지 조성물 및 이로부터 제조된 열가소성 수지 성형품
CN105612214B (zh) * 2014-09-16 2018-04-06 Lg化学株式会社 热塑性树脂组合物以及由该组合物制备的热塑性树脂模制品
JP6757317B2 (ja) * 2014-10-16 2020-09-16 クィーンズ ユニバーシティー アット キングストン 汚れ防止および落書き防止組成物
KR20180075490A (ko) * 2015-10-28 2018-07-04 유엠지 에이비에스 가부시키가이샤 그래프트 공중합체, 가교 입자, 그래프트 가교 입자, 고무질 중합체, 및 그것을 사용한 열 가소성 수지 조성물
JP6831390B2 (ja) * 2016-03-01 2021-02-17 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ 多段階製造されたポリマーを含む水性分散体およびそれを含むコーティング材料組成物
KR101823576B1 (ko) 2016-05-12 2018-01-30 송윤우 비행 무게중심 조절장치 및 그를 포함하는 비행기 완구

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070108008A (ko) * 2006-05-04 2007-11-08 제일모직주식회사 내스크래치성이 우수한 수지 조성물
KR20130046162A (ko) * 2011-10-27 2013-05-07 제일모직주식회사 열가소성 수지 조성물 및 이를 이용한 성형품
KR20130082221A (ko) * 2012-01-11 2013-07-19 주식회사 엘지화학 열가소성 투명수지 및 그 제조방법
KR20150137558A (ko) * 2014-05-30 2015-12-09 제일모직주식회사 내열성 및 내크래치성이 향상된 열가소성 수지 조성물
KR20170069456A (ko) * 2015-12-11 2017-06-21 주식회사 엘지화학 열가소성 수지 조성물 및 이를 포함하는 성형품

Also Published As

Publication number Publication date
KR20190038347A (ko) 2019-04-08
US11267964B2 (en) 2022-03-08
EP3640297A4 (en) 2020-06-17
EP3640297B1 (en) 2023-01-11
US20200140672A1 (en) 2020-05-07
CN110914361B (zh) 2022-08-19
CN110914361A (zh) 2020-03-24
EP3640297A2 (en) 2020-04-22
WO2019066375A2 (ko) 2019-04-04
KR102161030B1 (ko) 2020-10-05

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