WO2019058425A1 - 半導体装置製造用接着フィルム - Google Patents
半導体装置製造用接着フィルム Download PDFInfo
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- WO2019058425A1 WO2019058425A1 PCT/JP2017/033723 JP2017033723W WO2019058425A1 WO 2019058425 A1 WO2019058425 A1 WO 2019058425A1 JP 2017033723 W JP2017033723 W JP 2017033723W WO 2019058425 A1 WO2019058425 A1 WO 2019058425A1
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- CVQVSVBUMVSJES-UHFFFAOYSA-N dimethoxy-methyl-phenylsilane Chemical compound CO[Si](C)(OC)C1=CC=CC=C1 CVQVSVBUMVSJES-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
- HZGIOLNCNORPKR-UHFFFAOYSA-N n,n'-bis(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCNCCC[Si](OC)(OC)OC HZGIOLNCNORPKR-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 150000003553 thiiranes Chemical group 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- 238000009849 vacuum degassing Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L21/6836—Wafer tapes, e.g. grinding or dicing support tapes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
- B32B7/14—Interconnection of layers using interposed adhesives or interposed materials with bonding properties applied in spaced arrangements, e.g. in stripes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/50—Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the subgroups H01L21/06 - H01L21/326, e.g. sealing of a cap to a base of a container
- H01L21/52—Mounting semiconductor bodies in containers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
Definitions
- the present disclosure relates to an adhesive film used in a semiconductor device manufacturing process.
- Patent Document 1 discloses an adhesive sheet (dicing die bonding sheet) having a function of fixing a semiconductor wafer in a dicing step and a function of bonding a semiconductor chip to a substrate in a die bonding step.
- the present disclosure is useful for efficiently performing the bonding process in the manufacturing process of the semiconductor device, even if the area of the substrate to which the semiconductor chip is to be bonded is limited or the shape of the semiconductor chip is special. To provide an adhesive film.
- the present disclosure provides an adhesive film for manufacturing a semiconductor device.
- the adhesive film includes a belt-like carrier film having a width of 100 mm or less and a plurality of adhesive pieces arranged on the carrier film in the longitudinal direction of the carrier film.
- a plurality of adhesive pieces arranged to be aligned on the carrier film can be sequentially picked up, and then each adhesive piece can be arranged in a predetermined area of the substrate, and the substrate and the semiconductor chip Can be carried out efficiently.
- the bonding process can be performed more efficiently by the roll-to-roll method.
- the shape of the adhesive piece may be appropriately set according to the shape of the region of the substrate to which the semiconductor chip is to be bonded or the shape of the semiconductor chip.
- the size and the number of adhesive pieces disposed on the carrier film may be appropriately set according to the design of the semiconductor device to be manufactured.
- the area of one adhesive strip can range from 10 to 200 mm 2 .
- the percentage of the area of the surface of the carrier film covered by the plurality of adhesive pieces can be 10 to 60% based on the area of the carrier film.
- An array of one or more adhesive strips may be formed on the carrier film.
- the plurality of adhesive strips can be formed, for example, by stamping an adhesive layer formed to cover the surface of the carrier film.
- the adhesion between the carrier film and the adhesive piece is It is preferably 0.5 to 18 N / m.
- the adhesive film according to the present disclosure covers the second surface opposite to the first surface on the carrier film side of the adhesive strip, and may further include a protective member having the same shape as the adhesive strip. By covering the adhesive strip with the protective member, dust and the like can be prevented from adhering to the adhesive strip until the time of use.
- the adhesive strip and the protective member can be formed by die cutting an adhesive layer formed to cover the surface of the carrier film and a protective film disposed to cover the adhesive layer.
- the light transmittance of the protective member is preferably lower than the light transmittance of the carrier film.
- the adhesion between the adhesive piece and the protective member is preferably 16 N / m or less.
- the adhesion between the adhesive strip and the protective member is preferably 16 N / m or less after heat treatment at 100 ° C. for 10 minutes. .
- the bonding process in the manufacturing process of the semiconductor device is efficiently performed.
- Useful adhesive films are provided.
- FIG. 1 is a perspective view schematically showing an embodiment of an adhesive film according to the present disclosure.
- FIG. 2 is a cross-sectional view taken along the line II-II shown in FIG.
- FIG. 3: is sectional drawing which shows typically the laminated body on which the carrier film, the adhesive bond layer, and the protective film were laminated
- FIG. 4 is a perspective view showing how a plurality of adhesive pieces are formed on the carrier film by die cutting.
- FIG. 5 is a cross-sectional view schematically showing how the adhesive strip and the protective member covering the adhesive strip are picked up from the carrier film.
- (meth) acrylic means acrylic or methacrylic.
- FIG. 1 is a perspective view schematically showing an adhesive film according to the present embodiment.
- FIG. 2 is a cross-sectional view taken along the line II-II shown in FIG.
- Adhesive films 10 shown in these figures are a band-like carrier film 1 having a width of 100 mm or less, and a plurality of carrier films 1 arranged on the carrier film 1 in the longitudinal direction (direction of arrow X shown in FIG. 1).
- the adhesive strip 3p and the protective member 5p covering the surface F2 of the adhesive strip 3p and having the same shape as the adhesive strip 3p are provided.
- the surface F2 (second surface) of the adhesive piece 3p is a surface opposite to the surface F1 (first surface) of the adhesive piece 3p on the carrier film 1 side.
- the adhesive film 10 is applicable to various adhesion processes (for example, adhesion of a semiconductor chip and a substrate) in a manufacturing process of a semiconductor device.
- a plurality of adhesive pieces 3p arranged to line up on the carrier film 1 can be sequentially picked up, and then each adhesive piece 3p can be arranged in a predetermined area of the substrate, and the substrate
- the step of bonding the semiconductor chip to the semiconductor chip can be carried out efficiently.
- the adhesive strip 3p shaped like a thick T is illustrated, but the shape of the adhesive strip is the shape of the area of the substrate to which the semiconductor chip is to be bonded, or The setting may be made as appropriate according to the shape of the semiconductor chip.
- FIGS. 1 and 2 show the case where one row 3A of a plurality of adhesive pieces 3p is provided on the carrier film 1, two or more rows 3A are provided on the carrier film 1. It may be done.
- the adhesive strip 3p in this embodiment is assumed to have a sufficiently small size, and the area of one adhesive strip 3p is, for example, 10 to 200 mm 2 , 20 to 160 mm 2 or 25 to 100 mm 2 . It may be.
- the ratio of the area (area ratio of adhesive pieces) on the surface of the carrier film 1 and covered by the plurality of adhesive pieces 3p is, for example, 10 to 60% based on the area of the carrier film 1; It may be 10 to 35% or 15 to 33%.
- the carrier film 1 is band-like and has a width of 100 mm or less.
- the width of the carrier film 1 may be appropriately set in accordance with the size of the adhesive piece 3p disposed thereon and the number of rows 3A.
- the width of the carrier film 1 is preferably 10 to 50 mm, and may be 10 to 30 mm or 10 to 20 mm.
- the width of the carrier film 1 is 10 mm or more, when the roll-to-roll method is adopted, it is easy to prevent the deterioration in workability caused by the twisting of the carrier film 1.
- the material of the carrier film 1 is not particularly limited as long as it can sufficiently withstand the tension applied in the manufacturing process of the adhesive film 10 and the manufacturing process of the semiconductor device.
- the carrier film 1 is preferably transparent from the viewpoint of the visibility of the adhesive piece 3p and / or the protective member 5p disposed thereon.
- the carrier film 1 may be a polyester film such as polyethylene terephthalate film, polytetrafluoroethylene film, polyethylene film, polypropylene film, polymethylpentene film, polyvinyl acetate film, poly-4-methylpentene-1, ethylene-vinyl acetate co
- a polyolefin film such as a polymer, a homopolymer or copolymer such as ethylene-ethyl acrylate copolymer, or a mixture thereof, a plastic film such as a polyvinyl chloride film or a polyimide film, or the like can be used.
- the carrier film 1 may have a single layer structure or a multilayer structure.
- the thickness of the carrier film 1 may be appropriately selected within a range that does not impair the workability, and is, for example, 10 to 200 ⁇ m, and may be 20 to 100 ⁇ m or 25 to 80 ⁇ m. These thickness ranges are practically acceptable and economically effective.
- the carrier film 1 it is also possible to use a low surface energy film made of a fluorocarbon resin.
- a film for example, A-63 (release treatment agent: modified silicone type) manufactured by Teijin Film Solutions Ltd., and A-31 (release treatment agent: Pt type manufactured by Teijin Film Solutions Ltd.) There are silicone type etc.
- the surface of the carrier film 1 is separated from silicone release agent, fluorine release agent, long chain alkyl acrylate release agent, etc. You may form the release layer comprised from a mold agent.
- the adhesion between the carrier film 1 and the adhesive strip 3p is preferably 0.5 to 18 N / m, more preferably 2 to 10 N / m, 2 to 6 N / m or 2 to 4 N / m. It may be m.
- the adhesion is 0.5 N / m or more, careless peeling of the adhesive piece 3p from the carrier film 1 in the process of producing the adhesive film 10 can be easily prevented, and on the other hand, 18 N / m or less
- the adhesion of the adhesive strip 3p to the carrier film 1 means 90 ° peel strength.
- an adhesive layer of 20 mm in width made of the same composition as the adhesive strip 3p is formed on the carrier film 1
- the prepared sample is prepared, which means the peel strength measured when the adhesive layer is peeled from the carrier film at an angle of 90 ° and a peeling speed of 50 mm / min.
- the adhesive strip 3p is formed by simultaneously die-cutting the adhesive layer 3 formed to cover the surface of the carrier film 1 and the protective film 5 disposed to cover the adhesive layer 3 to form a protective member 5p. (See FIG. 4).
- the thickness of the adhesive piece 3p may be appropriately selected within a range that does not impair the workability, and is, for example, 3 to 50 ⁇ m, and may be 5 to 40 ⁇ m or 7 to 30 ⁇ m. Sufficient adhesion can be easily secured by the thickness of the adhesive strip 3p being 3 ⁇ m or more, and the adhesive composition constituting the adhesive strip 3p can be protruded from the protective member 5p by being 50 ⁇ m or less It is easy to control.
- the adhesive composition constituting the adhesive strip 3p only needs to have properties (for example, adhesiveness and heat resistance to heat of about 150 ° C.) that can be used without problems in the manufacturing process of the semiconductor device. What is used in the manufacturing process of the semiconductor device may be adopted appropriately.
- the adhesive strip 3p preferably contains a thermoplastic resin, a thermosetting resin, a curing accelerator, and a filler, and may contain a photoreactive monomer, a photopolymerization initiator, and the like as necessary.
- thermoplastic resin a resin having thermoplasticity or a resin having thermoplasticity at least in an uncured state and forming a crosslinked structure after heating can be used.
- a thermoplastic resin as a tape for processing a semiconductor, a (meth) acrylic copolymer (hereinafter referred to as “reactive group-containing (meth) acrylic copolymer”) having a reactive group from the viewpoint of being excellent in shrinkage, heat resistance and peelability. It may be called "polymer”) is preferable.
- the adhesive piece 3p may not include the thermosetting resin. That is, the aspect containing a reactive group containing (meth) acrylic copolymer, a hardening accelerator, and a filler may be sufficient.
- a thermoplastic resin can be used individually by 1 type or in combination of 2 or more types.
- Examples of the (meth) acrylic copolymer include (meth) acrylic acid ester copolymers such as acrylic resin and acrylic rubber, and acrylic rubber is preferable.
- the acrylic rubber preferably comprises an acrylic ester as a main component and is formed by copolymerization of a monomer selected from (meth) acrylic ester and acrylonitrile.
- (meth) acrylic acid esters methyl acrylate, ethyl acrylate, propyl acrylate, isopropyl acrylate, butyl acrylate, isobutyl acrylate, hexyl acrylate, cyclohexyl acrylate, 2-ethylhexyl acrylate, lauryl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, Examples thereof include isopropyl acrylate, butyl methacrylate, isobutyl methacrylate, hexyl methacrylate, cyclohexyl methacrylate, 2-ethylhexyl methacrylate, lauryl methacrylate and the like.
- (meth) acrylic acid ester copolymer a copolymer containing butyl acrylate and acrylonitrile as a copolymer component, and a copolymer containing ethyl acrylate and acrylonitrile as a copolymer component are preferable.
- the reactive group-containing (meth) acrylic copolymer is preferably a reactive group-containing (meth) acrylic copolymer containing a (meth) acrylic monomer having a reactive group as a copolymerization component.
- a reactive group-containing (meth) acrylic copolymer can be obtained by copolymerizing a monomer composition containing a (meth) acrylic monomer having a reactive group and the above-described monomer. .
- the reactive group is preferably an epoxy group, a carboxyl group, an acryloyl group, a methacryloyl group, a hydroxyl group or an episulfide group from the viewpoint of heat resistance improvement, and from the viewpoint of crosslinkability, an epoxy group and a carboxyl group are more preferable.
- the reactive group-containing (meth) acrylic copolymer is preferably an epoxy group-containing (meth) acrylic copolymer containing a (meth) acrylic monomer having an epoxy group as a copolymerization component.
- the (meth) acrylic monomer having an epoxy group glycidyl acrylate, 4-hydroxybutyl acrylate glycidyl ether, 3,4-epoxycyclohexyl methyl acrylate, glycidyl methacrylate, 4-hydroxybutyl methacrylate glycidyl ether, 3,4- Epoxy cyclohexyl methyl methacrylate and the like can be mentioned.
- the (meth) acrylic monomer having a reactive group is preferably glycidyl acrylate or glycidyl methacrylate from the viewpoint of heat resistance.
- the Tg of the thermoplastic resin is preferably ⁇ 50 ° C. to 50 ° C.
- the Tg of the thermoplastic resin is 50 ° C. or less, the flexibility of the adhesive piece 3 p can be easily secured.
- the unevenness is present when pasted to the adherend, it becomes easy to follow and has appropriate adhesiveness.
- the Tg of the thermoplastic resin is ⁇ 50 ° C. or higher, it is easy to suppress the flexibility of the adhesive piece 3 p from becoming too high, and excellent handleability, adhesiveness, and releasability can be achieved.
- the Tg of a thermoplastic resin is the midpoint glass transition temperature value obtained by differential scanning calorimetry (DSC). Specifically, the Tg of the thermoplastic resin is an intermediate value calculated by the method according to JIS K 7121: 1987, measuring the change in heat quantity under the conditions of a temperature rising rate of 10 ° C./min and a measuring temperature of -80 to 80 ° C. It is a point glass transition temperature.
- the weight average molecular weight of the thermoplastic resin is preferably 100,000 or more and 2,000,000 or less.
- the weight average molecular weight is 100,000 or more, heat resistance can be easily secured when used for temporary fixation.
- the weight average molecular weight of the thermoplastic resin is more preferably 500,000 or more and 2,000,000 or less, and still more preferably 1,000,000 or more and 2,000,000 or less.
- a weight average molecular weight is a polystyrene conversion value which used the calibration curve by standard polystyrene by the gel permeation chromatography method (GPC).
- the total content of these is 0.1 to 20% by mass based on the total amount of the copolymerization component.
- the content is preferably 0.5 to 15% by mass, and more preferably 1.0 to 10% by mass. If the content is within the above range, it is easy to achieve all of the flexibility, adhesiveness and releasability of the adhesive strip 3p to a higher level.
- the (meth) acrylic copolymer having a reactive group as described above one obtained by a polymerization method such as pearl polymerization or solution polymerization may be used.
- a polymerization method such as pearl polymerization or solution polymerization
- commercially available products such as HTR-860P-3CSP (trade name, manufactured by Nagase ChemteX Co., Ltd.) may be used.
- thermosetting resin Any thermosetting resin can be used without particular limitation as long as it can be cured by heat.
- thermosetting resin epoxy resin, acrylic resin, silicone resin, phenol resin, thermosetting polyimide resin, polyurethane resin, melamine resin, urea resin, etc. may be mentioned. These can be used singly or in combination of two or more.
- the epoxy resin is not particularly limited as long as it cures and has a heat-resistant function.
- a bifunctional epoxy resin such as bisphenol A epoxy, a novolac epoxy resin such as phenol novolac epoxy resin, and a cresol novolac epoxy resin can be used.
- the epoxy resin conventionally known ones such as polyfunctional epoxy resin, glycidyl amine type epoxy resin, heterocycle-containing epoxy resin, alicyclic epoxy resin and the like can be used.
- Examples of the phenol novolac epoxy resin include Epicoat 152, Epicoat 154 (all manufactured by Mitsubishi Chemical Co., Ltd.), EPPN-201 (manufactured by Nippon Kayaku Co., Ltd.), DEN-438 (manufactured by Dow Chemical Co.) and the like.
- o-cresol novolac type epoxy resin As o-cresol novolac type epoxy resin, YDCN-700-10 (manufactured by Nippon Steel & Sumikin Chemical Co., Ltd.), EOCN-102S, EOCN-103S, EOCN-104S, EOCN-1012, EOCN-1025, EOCN-1027 (all of them) Nippon Kayaku Co., Ltd., YDCN 701, YDCN 702, YDCN 703, YDCN 704 (all manufactured by Nippon Steel & Sumikin Chemical Co., Ltd.) and the like.
- Epon 1031S made by Mitsubishi Chemical Corporation
- araldite 0163 made by BASF Japan Ltd.
- Denacol EX-611, EX-614, EX-614B, EX-622, EX-512, EX-521 And EX-421, EX-411 and EX-321 all of which are manufactured by Nagase ChemteX Co., Ltd.
- an amine type epoxy resin Epicoat 604 (made by Mitsubishi Chemical Corporation), YH-434 (made by Nippon Steel & Sumikin Chemical Co., Ltd.), TETRAD-X, TETRAD-C (all are made by Mitsubishi Chemical Co., Ltd.), ELM-120 (both) And Sumitomo Chemical Co., Ltd.).
- heterocycle-containing epoxy resin examples include Araldite PT810 (manufactured by BASF Japan Ltd.), ERL 4234, ERL 4299, ERL 4221, and ERL 4206 (all manufactured by Union Carbide). These epoxy resins can be used singly or in combination of two or more.
- the epoxy resin curing agent which is a part of the thermosetting resin component
- a commonly used known resin can be used. Specifically, amines, polyamides, acid anhydrides, polysulfides, boron trifluoride, bisphenol A, bisphenol F, bisphenols having two or more phenolic hydroxyl groups in one molecule such as bisphenol S, phenol novolac resin And phenol resins such as bisphenol A novolac resin and cresol novolac resin.
- phenol resins such as phenol novolac resin, bisphenol A novolac resin, and cresol novolac resin are preferable from the viewpoint of being excellent in electrolytic corrosion resistance at the time of moisture absorption.
- the epoxy curing agent may be used simultaneously with the epoxy resin or may be used alone.
- Phenolite LF 4871, Phenolite TD-2090, Phenolite TD-2149, Phenolite VH-4150, Phenolite VH 4170 (all manufactured by DIC Corporation, trade names), H-1 (Meiwa) Made by Kasei Co., Ltd., trade name, Epicure MP402FPY, Epicure YL6065, Epicure YLH129B65, Mirex XL, Mirex XLC, Mirex XLC-LL, Mirex RN, Mirex RS, Mirex VR (all are manufactured by Mitsubishi Chemical Corporation, etc.), etc. It is preferable to use a material having the following structure.
- the content of the thermosetting resin in the adhesive piece 3p is preferably 10 to 500 parts by mass, more preferably 30 to 450 parts by mass, and still more preferably 50 to 400 parts by mass with respect to 100 parts by mass of the thermoplastic resin. It is easy to achieve the outstanding adhesiveness after thermosetting of adhesive piece 3p as content of a thermosetting resin is in a mentioned range.
- adhesive piece 3p contains the (meth) acrylic copolymer which has an epoxy group
- the hardening accelerator which promotes hardening of the epoxy group contained in the said acrylic copolymer.
- curing accelerators that promote curing of epoxy groups include phenolic curing agents, acid anhydride curing agents, amine curing agents, imidazole curing agents, imidazoline curing agents, triazine curing agents, and phosphine curing agents. It can be mentioned. Among these, from the viewpoint of rapid curing, heat resistance and releasability, an imidazole-based curing agent which can be expected to shorten the process time and improve the workability is preferable. These compounds can be used singly or in combination of two or more.
- the content of the curing accelerator in the adhesive strip 3p is preferably 0.01 to 50 parts by mass, more preferably 0.02 to 20 parts by mass, and more preferably 0.025 to 10 parts by mass with respect to 100 parts by mass of the thermoplastic resin. Parts are more preferred. It exists in the tendency which can fully suppress the fall of storage stability, improving the hardenability of adhesive agent piece 3p as content of a hardening accelerator is in the said range.
- the adhesive strip 3p preferably contains an inorganic filler.
- the inorganic filler include metal fillers such as silver powder, gold powder and copper powder, and nonmetallic inorganic fillers such as silica, alumina, boron nitride, titania, glass, iron oxide and ceramic.
- the inorganic filler can be selected according to the desired function.
- the inorganic filler preferably has an organic group on the surface.
- the surface of the inorganic filler is modified with an organic group, so that the dispersibility in an organic solvent when preparing a varnish for forming the adhesive strip 3p, and the high elastic modulus and the excellent peeling of the adhesive strip 3p It is easy to make
- the inorganic filler having an organic group on the surface can be obtained, for example, by mixing a silane coupling agent represented by the following formula (B-1) and an inorganic filler and stirring at a temperature of 30 ° C. or more. It can be confirmed by UV measurement, IR measurement, XPS measurement or the like that the surface of the inorganic filler has been modified by the organic group.
- X represents an organic group selected from the group consisting of phenyl group, glycidoxy group, acryloyl group, methacryloyl group, mercapto group, amino group, vinyl group, isocyanate group and methacryloxy group;
- Is an integer of 0 or 1 to 10.
- R 11 , R 12 and R 13 each independently represent an alkyl group having 1 to 10 carbon atoms.
- alkyl group having 1 to 10 carbon atoms examples include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, isopropyl group and isobutyl group.
- the alkyl group having 1 to 10 carbon atoms is preferably a methyl group, an ethyl group and a pentyl group from the viewpoint of easy availability.
- X is preferably an amino group, a glycidoxy group, a mercapto group and an isocyanate group, and more preferably a glycidoxy group and a mercapto group.
- s in the formula (B-1) is preferably 0 to 5, and more preferably 0 to 4.
- trimethoxyphenylsilane dimethyldimethoxyphenylsilane, triethoxyphenylsilane, dimethoxymethylphenylsilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris (2-methoxyethoxy) silane, N- (2 -Aminoethyl) -3-aminopropylmethyldimethoxysilane, N- (2-aminoethyl) -3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropyltrimethoxysilane, 3-glycide Xylpropyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 3-isocyanatopropyltrie
- 3-aminopropyltriethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-isocyanatopropyltriethoxysilane, 3-mercaptopropyltrimethoxysilane are preferable, trimethoxyphenylsilane, 3-glycidoxy Propyltrimethoxysilane and 3-mercaptopropyltrimethoxysilane are more preferred.
- the silane coupling agent can be used singly or in combination of two or more.
- the content of the coupling agent is preferably 0.01 to 50 parts by mass, and 0.05 to 20 parts by mass, with respect to 100 parts by mass of the inorganic filler, from the viewpoint of achieving a balance between heat resistance and storage stability.
- the amount is more preferably 0.5 to 10 parts by mass from the viewpoint of heat resistance improvement.
- the content of the inorganic filler in the adhesive piece 3p is preferably 600 parts by mass or less, more preferably 500 parts by mass or less, and 400 parts by mass or less with respect to 100 parts by mass of the thermoplastic resin. More preferable.
- the lower limit of the content of the inorganic filler is not particularly limited, but is preferably 5 parts by mass or more, and more preferably 8 parts by mass or more with respect to 100 parts by mass of the thermoplastic resin.
- Adhesive piece 3 p may contain an organic filler.
- the organic filler include carbon, rubber fillers, silicone particles, polyamide particles and polyimide particles. 300 mass parts or less are preferable with respect to 100 mass parts of thermoplastic resins, as for content of an organic filler, 200 mass parts or less are more preferable, and 100 mass parts or less are still more preferable.
- the lower limit of the content of the organic filler is not particularly limited, but is preferably 5 parts by mass or more with respect to 100 parts by mass of the thermoplastic resin.
- the adhesive strip 3p may be diluted with an organic solvent, if necessary.
- the organic solvent is not particularly limited, but can be determined in consideration of the volatility and the like at the time of film formation from the boiling point.
- relatively low boiling point solvents such as methanol, ethanol, 2-methoxyethanol, 2-ethoxyethanol, 2-butoxyethanol, methyl ethyl ketone, acetone, methyl isobutyl ketone, toluene, xylene, etc. It is preferable from the viewpoint of difficulty in curing.
- a solvent having a relatively high boiling point such as dimethylacetamide, dimethylformamide, N-methylpyrrolidone, cyclohexanone and the like. These solvents can be used singly or in combination of two or more.
- the protective member 5 p simultaneously cuts off the adhesive layer 3 formed so as to cover the surface of the carrier film 1 and the protective film 5 arranged so as to cover the adhesive layer 3 to form an adhesive piece 3 p. (See FIG. 4).
- the protective member 5p according to the present embodiment is formed at the same time as the adhesive piece 3p by die cutting, and thus has substantially the same shape as the adhesive piece 3p.
- the protective film 5 may be a film which can be punched out in the manufacturing process of the adhesive film 10 and can easily peel the protective member 5p from the adhesive piece 3p in the manufacturing process of the semiconductor device.
- the adhesion between the adhesive strip 3p and the protective member 5p is preferably 16 N / m or less, more preferably 10 N / m or less, and 5 N / m or less or 4.5 N / m or less It is also good.
- the adhesive strip 3p is made of a thermosetting resin composition, it is preferable that the adhesion of the protective member 5p to the adhesive strip 3p be in the above range after heat treatment at 100 ° C. for 10 minutes.
- the adhesion is 16 N / m or less, the adhesive strip 3p in a state of being covered with the protective member 5p is temporarily crimped to an adherend (for example, a substrate) under conditions of 100 ° C. for 3 seconds, for example.
- the adhesion of the protective member 5p to the adhesive strip 3p means 90 ° peel strength, and specifically, a protective film of the same width on a 20 mm wide adhesive layer made of the same composition as the adhesive strip 3p. Means a peel strength which is measured when the prepared sample is prepared and this protective film is peeled from the adhesive layer at an angle of 90 ° and a peeling speed of 300 mm / min.
- polyester-based films such as polyethylene terephthalate film, polytetrafluoroethylene film, polyethylene film, polypropylene film, polymethylpentene film, polyvinyl acetate film, poly-4-methylpentene-1, ethylene-vinyl acetate co
- a polyolefin film such as a polymer, a homopolymer or copolymer such as ethylene-ethyl acrylate copolymer, or a mixture thereof, a plastic film such as a polyvinyl chloride film or a polyimide film, or the like can be used.
- the protective film 5 may have a single layer structure or a multilayer structure.
- the thickness of the protective film 5 may be appropriately selected within a range that does not impair the workability, and is, for example, 10 to 200 ⁇ m, and may be 20 to 100 ⁇ m or 25 to 80 ⁇ m. These thickness ranges are practically acceptable and economically effective.
- the light transmittance of the protective member 5 p is preferably lower than the light transmittance of the carrier film 1.
- a device such as a camera
- the manufacturing method of the present embodiment includes the following steps.
- FIG. 3 is sectional drawing which shows typically the laminated body 20 prepared by (A) process.
- the laminate 20 can be produced as follows. First, the raw material resin composition of the adhesive layer 3 is dissolved in a solvent such as an organic solvent to prepare a varnished coating liquid. The coating liquid is applied onto the carrier film 1 and then the solvent is removed to form the adhesive layer 3.
- the coating method may, for example, be a knife coating method, a roll coating method, a spray coating method, a gravure coating method, a bar coating method or a curtain coating method. Next, the protective film 5 is attached to the surface of the adhesive layer 3 under the conditions of normal temperature to 60 ° C. Thereby, the laminated body 20 can be obtained.
- the laminated film is produced by bonding together the protective film 5 so that this may be covered, and this is cut
- FIG. 4 is a perspective view showing how a plurality of adhesive pieces 3p and a protective member 5p covering the adhesive pieces 3p are formed on the carrier film 1 by die cutting in the (B) step.
- the laminate 20 passes between the rotating body 51 having a plurality of blades 51 c for carrying out the die-cutting on the outer peripheral surface and the roll 52 paired with the rotating body 51.
- An adhesive piece 3p and a protection member 5p according to the shape of the blade 51c are continuously formed on the carrier film 1.
- the surface on the protective film 5 side of the laminate 20 faces the rotating body 51
- the surface on the carrier film 1 side faces the roll 52.
- the depth of the cut formed in the laminate 20 by the blade 51c by adjusting the distance between the rotation shaft 51a of the rotating body 51 and the rotation shaft 52a of the roll 52 or changing the height of the blade 51c Can be adjusted.
- the laminate 20 which has passed between the rotating body 51 and the roll 52 is separated into the adhesive film 10 and the unnecessary portion 30 as shown in FIG. 4 and wound around each reel (not shown).
- the unnecessary portion 30 includes the adhesive layer 3 and the protective film 5 in which the adhesive piece 3 p and the protective member 5 p are hollowed out.
- FIG. 5 is a cross-sectional view schematically showing how the adhesive strip 3p and the protective member 5p covering the adhesive strip 3p are picked up from the carrier film 1.
- FIG. 5 The adhesive film 10 is moved in the direction of the arrow shown in FIG. 5 while bringing the surface of the adhesive film 10 on the carrier film 1 side into contact with the wedge shaped member 60 in a state where a constant tension is applied to the adhesive film 10.
- the front of the adhesive agent piece 3p and the protection member 5p will be in the state which floated from the carrier film 1.
- FIG. 5 is a cross-sectional view schematically showing how the adhesive strip 3p and the protective member 5p covering the adhesive strip 3p are picked up from the carrier film 1.
- the adhesive strip 3p and the protective member 5p are picked up by the pickup device 65 having a suction force.
- the pickup device 65 having a suction force.
- the adhesive strip 3p in a state of being covered by the protective member 5p is disposed at a predetermined position and direction of the substrate (not shown).
- temporary pressure bonding of the adhesive piece 3p to the substrate is performed.
- the temporary pressure bonding may be performed, for example, at a temperature of 60 to 150 ° C. and a pressing force of 0.05 to 1 MPa for 0.1 to 10 seconds.
- the adhesive piece 3p is in close contact with the substrate to such an extent that the adhesive piece 3p is weak but does not peel off from the substrate.
- the protective member 5p is peeled off from the adhesive piece 3p using an adhesive tape or the like.
- the semiconductor chip After placing the semiconductor chip (not shown) on the surface of the adhesive piece 3p exposed by the peeling of the protective member 5p, the semiconductor chip is crimped to the substrate.
- the pressure bonding may be performed, for example, at a temperature of 60 to 150 ° C. under a pressure of 0.05 to 1 MPa for 0.1 to 10 seconds.
- this indication is not limited to the above-mentioned embodiment.
- the case where the colored protective film 5 is used is illustrated so that the presence or absence, the direction, etc. of the protective member 5p can be grasped by a camera or the like, but instead of this, a predetermined protective member 5p is used.
- the position of may be marked.
- it is set as the aspect by which the adhesive agent piece 3p was colored it is not necessary to provide the protection member 5p.
- the direction of the adhesive piece 3p does not matter (for example, when the shape of the adhesive piece 3p is circular), it is not necessary to identify the direction.
- Example 1 (Preparation of adhesive varnish) An adhesive varnish was obtained by mixing the following materials and vacuum degassing.
- Thermoplastic resin: HTR-860P-3 (trade name, manufactured by Nagase ChemteX Co., Ltd., glycidyl group-containing acrylic rubber, molecular weight 1,000,000, Tg-7 ° C.) 100 parts by mass
- Thermosetting resin: YDCN-700-10 (Trade name, manufactured by Nippon Steel & Sumikin Chemical Co., Ltd., o-cresol novolac epoxy resin, epoxy equivalent weight 210) 30 parts by mass
- Thermosetting resin: LF-4871 (trade name, manufactured by DIC, bisphenol A epoxy resin, Epoxy equivalent 118) 95 parts by mass
- Thermosetting resin: YDF-8170C (trade name, manufactured by Nippon Steel Sumikin Chemical Co., Ltd., bisphenol F type epoxy resin, epoxy equivalent 157) 100 parts by mass Curing accelerator: 2PZ-CN (com
- the adhesive varnish was coated on a surface release-treated polyethylene terephthalate film (manufactured by Teijin Film Solutions Co., Ltd., trade name: Teijin Tetron Film A-63) with a thickness of 50 ⁇ m. After the drying step, a film having a 25 ⁇ m-thick adhesive layer formed on one side of the polyethylene terephthalate film (carrier film) was obtained. A laminated film was obtained by laminating this film and a colored 50 ⁇ m-thick polyethylene film (manufactured by Tamapoly Co., Ltd., TDM-1). By slitting this laminated film to a width of 15 mm, a strip-like laminated body was obtained.
- the laminated film obtained as described above was die-cut using the device having the configuration shown in FIG. 4 to obtain an adhesive film according to this example.
- the shape of the adhesive piece was a shape (area: 29 mm 2 ) in which a corner of a part of a rectangle of about 7 mm in length ⁇ about 6 mm in width was missing.
- the pitch P was about 9 mm.
- the area ratio R of the adhesive piece was 23%.
- Example 2 An adhesive film was produced in the same manner as in Example 1 except that the size and pitch of the adhesive pieces were changed.
- Example 3 An adhesive film was produced in the same manner as in Example 2 except that a carrier film having a different surface treatment from that of the carrier film used in Example 2 was used and the shape of the adhesive piece was changed.
- a carrier film a surface release-treated polyethylene terephthalate film (manufactured by Teijin Film Solutions Co., Ltd., trade name: Teijin Tetron Film A-53) having a thickness of 50 ⁇ m was used.
- Example 4 An adhesive film was produced in the same manner as in Example 2 except that a protective film different from the protective film used in Example 2 was used.
- a protective film a non-colored polyethylene film (manufactured by Tamapoly Corporation, trade name: NF-13, thickness: 20 ⁇ m) was used.
- Example 5 An adhesive film was produced in the same manner as in Example 2 except that a protective film different from the protective film used in Example 2 was used.
- a protective film a non-colored polyethylene film (manufactured by Tamapoly Corporation, trade name: GF-3, thickness: 30 ⁇ m) was used.
- Example 6 An adhesive film was produced in the same manner as in Example 2 except that a carrier film different from the carrier film used in Example 2 was used.
- a carrier film a polyethylene terephthalate film (manufactured by Teijin Film Solutions Co., Ltd., trade name: Teijin Tetron Film G2, thickness: 50 ⁇ m) not subjected to surface release treatment was used.
- Example 7 An adhesive film was produced in the same manner as in Example 2 except that a carrier film different from the carrier film used in Example 2 was used.
- a carrier film a polyethylene terephthalate film (manufactured by Teijin Film Solutions Co., Ltd., trade name: Teijin Tetron Film G2, thickness: 38 ⁇ m) not subjected to surface release treatment was used.
- Example 8 An adhesive film was produced in the same manner as in Example 2 except that the size of the adhesive strip was changed.
- Example 9 An adhesive film was produced in the same manner as in Example 2 except that the size of the adhesive strip was changed.
- Light Transmittance V-570 (trade name) manufactured by JASCO Corporation is used to transmit light with a wavelength of 500 nm in a region where an adhesive strip and a protective member covering the adhesive film are provided on a carrier film. Measured.
- Adhesion of protective film (90 ° peel strength)
- a laminated film (carrier film / adhesive layer / protective film) not cut was cut into a width of 20 mm.
- the protective film is upward while maintaining the angle of the protective film to the adhesive layer at 90 °.
- the adhesive layer was peeled off from the protective film by pulling up. The pulling rate was 300 mm / min, and the measurement environment temperature was 23 ⁇ 2 ° C. The force required to pull it up was measured.
- the adhesion between the protective film and the adhesive layer was calculated by substituting the measured value (mN) and the width (20 mm) of the sample into the following equation.
- Adhesion (N / m) measured value (mN) / 20 (mm)
- the bonding process in the manufacturing process of the semiconductor device is efficiently performed.
- Useful adhesive films are provided.
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PCT/JP2018/034514 WO2019059189A1 (ja) | 2017-09-19 | 2018-09-18 | 半導体装置製造用接着フィルム、並びに、半導体装置及びその製造方法 |
SG11202002554XA SG11202002554XA (en) | 2017-09-19 | 2018-09-18 | Adhesive film for use in semiconductor device manufacture, semiconductor device, and manufacturing method of semiconductor device |
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JP2019543646A JP7338469B2 (ja) | 2017-09-19 | 2018-09-18 | 半導体装置製造用接着フィルム |
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- 2018-09-18 KR KR1020207010061A patent/KR102528135B1/ko active IP Right Grant
- 2018-09-18 WO PCT/JP2018/034514 patent/WO2019059189A1/ja active Application Filing
- 2018-09-18 JP JP2019543646A patent/JP7338469B2/ja active Active
- 2018-09-18 CN CN201880060553.2A patent/CN111133564B/zh active Active
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KR102528135B1 (ko) | 2023-05-02 |
WO2019059189A1 (ja) | 2019-03-28 |
CN111133564A (zh) | 2020-05-08 |
SG11202002554XA (en) | 2020-04-29 |
JPWO2019059189A1 (ja) | 2020-11-26 |
TWI827551B (zh) | 2024-01-01 |
TW201921524A (zh) | 2019-06-01 |
KR20200055012A (ko) | 2020-05-20 |
CN111133564B (zh) | 2024-02-13 |
JP7338469B2 (ja) | 2023-09-05 |
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