WO2018221388A1 - 車両ドア用トリムボード及びドアトリム - Google Patents
車両ドア用トリムボード及びドアトリム Download PDFInfo
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- WO2018221388A1 WO2018221388A1 PCT/JP2018/020069 JP2018020069W WO2018221388A1 WO 2018221388 A1 WO2018221388 A1 WO 2018221388A1 JP 2018020069 W JP2018020069 W JP 2018020069W WO 2018221388 A1 WO2018221388 A1 WO 2018221388A1
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- board
- resin
- door trim
- vehicle door
- mass
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J5/00—Doors
- B60J5/04—Doors arranged at the vehicle sides
- B60J5/042—Reinforcement elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J5/00—Doors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J5/00—Doors
- B60J5/04—Doors arranged at the vehicle sides
- B60J5/048—Doors arranged at the vehicle sides characterised by the material
- B60J5/0481—Doors arranged at the vehicle sides characterised by the material plastic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3005—Body finishings
- B29L2031/3014—Door linings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/0257—Polyamide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/0271—Epoxy resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
- B60R13/0237—Side or rear panels
- B60R13/0243—Doors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
Definitions
- the present invention relates to a vehicle door trim board and a door trim. More specifically, the present invention relates to a door panel mounted on a door panel of a vehicle and a vehicle door trim board constituting the door panel.
- Patent Document 1 discloses a technology that uses a high-impact core material as a trim board for a vehicle door.
- Patent Documents 2 and 3 below disclose impact-resistant resins including polyolefin resins and polyamide resins.
- Patent Document 1 discloses a technique of using a high impact core material as a vehicle door trim board, and a polypropylene resin mixed with a rubber component is disclosed as a material of the high impact core material. .
- Patent Document 2 discloses that a modified elastomer can be used as a compatibilizer in a resin composition containing a polyamide resin and a polyolefin resin.
- Patent Document 3 discloses that a resin composition containing a polyamide resin and a polyolefin resin can exhibit a phase structure having a continuous phase, a dispersed phase, and a finely dispersed phase.
- Patent Documents 2-3 disclose that these resin compositions can be used for door trims, the merits of the resin compositions can be specifically used for vehicle doors in any form. No consideration has been given to whether the trim board can be enjoyed.
- the present invention has been made in view of the above circumstances, and an object of the present invention is to provide a vehicle door trim board that is difficult to break by using a predetermined impact-resistant resin in part. Furthermore, it aims at providing the door trim using the said trim board for vehicle doors.
- the vehicle door trim board according to claim 1 includes a polyolefin resin, a polyamide resin, and a compatibilizer,
- the gist is that the compatibilizing agent has a reinforcing portion made of an impact-resistant resin that is a modified elastomer having a reactive group for the polyamide resin.
- the vehicle door trim board according to claim 2 is the vehicle door trim board according to claim 1, wherein the upper board portion and the lower board portion are divided into upper and lower parts, The gist of the invention is to have the reinforcing portion interposed between the upper board portion and the lower board portion.
- the vehicle door trim board according to claim 3 is the vehicle door trim board according to claim 2, wherein each of the upper board portion and the lower board portion is made of another thermoplastic resin different from the impact resistant resin. It consists of the foamed resin board used,
- the gist of the invention is that the upper board part, the lower board part, and the reinforcing part are made of an integral multicolor molded product using the other thermoplastic resin and the impact resistant resin.
- a vehicle door trim board according to a fourth aspect of the present invention is the vehicle door trim board according to the second aspect, wherein the upper board portion and the lower board portion are respectively bonded to plant fibers and the plant fibers.
- a fiber reinforced board containing The gist of the present invention is that the upper board part, the lower board part, and the reinforcing part are made of an integral insert molding using the fiber reinforced board as an insert body.
- the vehicle door trim board according to claim 5 is the vehicle door trim board according to claim 1, wherein the upper board part and the lower board part adjacent to each other in the vertical direction;
- the gist of the present invention is to include at least the reinforcing portion that covers the surface of the boundary region straddling the upper board portion and the lower board portion.
- the vehicle door trim board according to claim 6 is the vehicle door trim board according to claim 5, wherein the upper board portion and the lower board portion are made of another thermoplastic resin different from the impact resistant resin.
- the gist of the invention is that the upper board part, the lower board part, and the reinforcing part are made of an integral multicolor molded product using the other thermoplastic resin and the impact resistant resin.
- the vehicle door trim board according to claim 7 is the vehicle door trim board according to claim 5, wherein the upper board portion and the lower board portion are plant fibers and a binder resin that binds the plant fibers.
- a monolithic fiber reinforced board containing The gist of the present invention is that the upper board part, the lower board part, and the reinforcing part are made of an integral insert molding using the fiber reinforced board as an insert body.
- the vehicle door trim board according to claim 8 is the vehicle door trim board according to any one of claims 1 to 7, wherein the reinforcing portion has a belt shape and the vehicle door extends in the front-rear direction of the vehicle. Is arranged to penetrate the trim board for The lower board portion has another reinforcing portion having at least one strip shape different from the reinforcing portion, The other reinforcing portion is made of the impact-resistant resin and is arranged substantially parallel to the reinforcing portion.
- the vehicle door trim board according to claim 9 is the vehicle door trim board according to any one of claims 1 to 8, wherein the impact-resistant resin includes the polyolefin resin.
- the gist is to have a dispersed phase dispersed in the continuous phase (A), the dispersed phase (B) containing the polyamide resin and the modified elastomer.
- the vehicle door trim board according to claim 10 is the vehicle door trim board according to claim 9, wherein the dispersed phase (B) includes a continuous phase (B 1 ) containing the polyamide resin, And a finely dispersed phase (B 2 ) containing the modified elastomer dispersed in the continuous phase (B 1 ).
- the vehicle door trim board according to claim 11 is the vehicle door trim board according to claim 9 or 10, wherein the modified elastomer is a copolymer of ethylene or propylene and an ⁇ -olefin having 3 to 8 carbon atoms.
- a door trim according to a twelfth aspect includes the vehicle door trim board according to any one of the first to eleventh aspects, and a skin layer laid on the design surface side of the vehicle door trim board. Is the gist.
- the vehicle door trim board and the door trim it is possible to provide a vehicle door trim board and a door trim which are hard to break.
- the vehicle door trim board when the upper board part and the lower board part which are divided into upper and lower parts and the reinforcing part interposed therebetween are provided, it is possible to suppress breakage due to the difference in rigidity between the upper board part and the lower board part. .
- the upper board portion and the lower board portion have different rigidity. Therefore, it can be assumed that the vehicle door trim board is cracked when an impact is applied due to the difference in rigidity.
- each of the upper board portion and the lower board portion is made of a foamed resin board
- the foamed resin board is formed using another thermoplastic resin
- the reinforcing portion is formed using an impact resistant resin.
- the trim board for vehicle doors which provided the outstanding impact resistance and cannot be broken easily can be provided.
- the upper board portion and the lower board portion are each made of a fiber reinforced board
- the fiber reinforced board is used as an insert body
- the reinforcing portion is formed by injection molding
- the upper board portion, the lower board portion and the reinforcing portion are integrated.
- the foamed resin board is formed using another thermoplastic resin
- the reinforcing part is formed using an impact resistant resin.
- the trim board for vehicle doors which provided the outstanding impact resistance and cannot be broken easily can be provided.
- the upper board part and the lower board part are made of an integral fiber reinforced board
- the upper board part, the lower board, and the reinforcing part are integrated by forming the reinforcing part by injection molding using the fiber reinforced board as an insert body. By using the insert molded product, it is possible to provide a trim board for a vehicle door that is provided with excellent impact resistance and is difficult to crack.
- the reinforcing portion has a belt shape and is arranged so as to penetrate the vehicle door trim board in the longitudinal direction of the vehicle, and the lower board portion has at least one belt shape made of impact-resistant resin.
- an impact band for example, a chest protective band
- the reinforcing portion is arranged substantially in parallel with the reinforcing portion, an impact band (for example, a chest protective band) necessary for occupant protection using the reinforcing portion and the other reinforcing portion. Abdominal protection band, waist protection band, etc.).
- FIGS. 4 to 7 are cross-sectional views taken along the line AA ′ of the perspective view. It is a perspective view explaining a vehicle door and a door trim. It is the perspective view and sectional drawing explaining an example of the trim board for vehicle doors. It is explanatory drawing explaining the connection form of a reinforcement part. It is the perspective view and sectional drawing explaining the other example of the trim board for vehicle doors. It is the perspective view and sectional drawing explaining the other example of the trim board for vehicle doors. It is the perspective view and sectional drawing explaining the other example of the trim board for vehicle doors. It is the perspective view and sectional drawing explaining the other example of the trim board for vehicle doors. It is the perspective view and sectional drawing explaining the other example of the trim board for vehicle doors.
- Vehicle door trim board The vehicle door trim board (20) of the present invention includes a polyolefin resin, a polyamide resin, and a compatibilizer, and the compatibilizer has a reactive group for the polyamide resin. It has the reinforcement part (23) which consists of impact-resistant resin which is a modified elastomer.
- the conventional vehicle door trim board 29 is divided into a plurality of parts. Specifically, for example, it is composed of three parts: an upper board 291, an armrest board 292, and a lower board 293.
- the upper board 291 and the lower board 293 are different in shape and size and have different rigidity. Therefore, there is a risk of cracking at the boundary between the upper board 291 and the lower board 293.
- the armrest board 292 is generally weakened at the position where the upper board 291 and the lower board 293 are engaged. For these reasons, the number of components tends to increase, and a mechanism for weakening is required.
- the vehicle door trim board 20 includes the reinforcing portion 23, so that the vehicle door trim board 20 can be integrally formed as illustrated in FIGS. And by forming integrally, the characteristic of the impact-resistant resin which comprises the reinforcement part 23 can be enjoyed effectively, and the trim board for vehicle doors which cannot be broken easily can be provided.
- the vehicle door trim board 20 can be used.
- the upper board part 21 and the lower board part 25 are divided vertically, that is, when the upper board part 21 and the lower board part 25 are separate boards, the upper board part 21 and the lower board part 25
- the vehicle door trim board 20 can be integrated with the reinforcing portion 23 interposed therebetween (see FIG. 2).
- the reinforcing portion 23 can be disposed across the vehicle door trim board 20 in the longitudinal direction of the vehicle. That is, it can be provided in a belt-like shape at the center of the vehicle door trim board 20 (in a form that penetrates forward and backward).
- the reinforcing portion 23 interposed between the upper board portion 21 and the lower board portion 25 is flexible so as to absorb the rigidity difference between the upper board portion 21 and the lower board portion 25. Since the shock can be absorbed, the shock can be absorbed without being broken even if they are integrated.
- the joint portion between the reinforcing portion 23 and the upper board portion 21, or the reinforcing portion there are no particular limitations on the joining form of the joining portion between the lower board part 25 and the lower board part 25.
- the joining forms shown in FIGS. 3 (a) to 3 (c) are exemplified. That is, in FIG. 3A, by forming the cross sections of the reinforcing portion 23 and the other portion that is the bonding partner so as to be oblique to each other, the bonding area can be increased and the bonding strength can be improved. Further, as shown in FIG.
- the thickness of the joint portion between the reinforcing portion 23 and the other portion is reduced so that the total thickness becomes the thickness of one trim board 20 for the vehicle door.
- the joint area can be increased and the joint strength can be improved.
- the bonding area can be increased and the bonding strength can be improved.
- each corner portion is generally avoided in order to avoid stress concentration at each corner portion.
- Chamfering is required.
- the apex angle of the convex portion (corresponding to the tip angle of the tenon in the tenon joint) and the base angle of the concave part (corresponding to the bottom angle of the mortise hole in the tenon joint). ) Can be eliminated.
- FIG. 7 it can also be set as the form provided with the extended contact part 231 extended from the reinforcement part 23 which covers the whole surface of the upper board part 21 and the lower board part 25. As shown in FIG. In this form, better bonding strength can be obtained.
- another reinforcing portion 24 can be used in combination.
- the band portion is similarly formed.
- the other reinforcing part 24 made can be used in combination.
- reinforcing portion 24 may be provided, or two or more reinforcing portions 24 may be provided.
- another reinforcing portion 24 can be provided on the lower board portion 25.
- the other reinforcement part 24 can provide two strips as the other reinforcement part 241 and the other reinforcement part 242, for example. Similar to the reinforcing portion 23, these other reinforcing portions 24 can also be formed from the above-described impact resistant resin.
- the reinforcement part 23 and the other reinforcement part 24 can be arrange
- the reinforcing portion 23 is placed on the passenger chest.
- the other reinforcing portions 241 are arranged corresponding to the occupant abdomen and the other reinforcing portions 242 are arranged corresponding to the occupant waist.
- the reinforcing part 23 can function as a chest protective band, the other reinforcing part 241 as an abdominal protective band, and the other reinforcing part 242 as a waist protective band.
- the other reinforcing portion 24 can be arranged to be replaced as a part of the lower board portion 25, or as shown in FIG. It can also be attached to one side).
- the armrest board portion 27 is also formed integrally with the reinforcing portion 23.
- the armrest board portion 27 may be made of other materials ( For example, it may be composed of a material common to the upper board part 21 and the lower board part 25), and may be integrated using the reinforcing part 23 at the time of molding.
- Each of the upper board portion 21 and the lower board portion 25 may be formed of any material.
- a fiber reinforced board including a reinforcing fiber and a binding resin for binding the reinforcing fiber can be formed as In this case, it can be set as the vehicle door trim board 20 which consists of an integral molded article by using a fiber reinforced board (the upper board part 21 and the lower board part 25) as an insert body. That is, the upper board part 21 and the lower board part 25, which are fiber reinforced boards, are used as insert bodies, and an impact-resistant resin is injection-formed between them, so that the upper board part 21, the lower board part 25 and the reinforcing part 23 are integrated. Thus, the vehicle door trim board 20 can be obtained.
- the kind of the reinforcing fiber constituting the fiber reinforced board is not limited, and inorganic fibers (glass fibers and the like) and organic fibers (natural fibers such as plant fibers and animal fibers) can be used. These may use only 1 type and may use 2 or more types together. Of these, organic fibers are preferable, natural fibers are more preferable, and plant fibers are particularly preferable.
- Plant fiber is a fiber derived from a plant, and includes a fiber taken out from a plant and a fiber obtained by processing the fiber.
- Plant fibers are collected from leaf vein plant fibers (abaca, sisal, agave, etc.), bast plant fibers (flux, jute, hemp, kenaf, ramie, etc.), woody plant fibers (broadleaf trees, conifers, etc.) Plant fibers), other plant fibers (coconut shell fibers, oil palm empty fruit bunch fibers, rice straw fibers, straw straw fibers, bamboo fibers, cotton, etc.)
- the type of the binder resin is not limited and can be selected according to the reinforcing fiber to be used, but a thermoplastic resin is particularly preferable.
- a thermoplastic resin is particularly preferable.
- Specific examples include polyolefin resins, polyester resins, polystyrene resins, acrylic resins, polyamide resins, polycarbonate resins, polyacetal resins, and ABS resins. These may use only 1 type and may use 2 or more types together.
- polyolefin resin is preferable.
- Polyolefin resins include polyethylene resins such as ethylene homopolymers, ethylene / 1-butene copolymers, ethylene / 1-hexene copolymers, ethylene / 4-methyl-1-pentene copolymers (total number of structural units).
- polypropylene resins such as propylene homopolymers, propylene / ethylene copolymers (propylene / ethylene random copolymers, etc.), propylene / 1-butene copolymers (50% or more of the total number of structural units are propylene-derived units) Is).
- the binder resin may be only a non-modified thermoplastic resin or may include a thermoplastic resin modified by introducing a polar group.
- polar groups include carboxylic anhydride groups (—CO—O—OC—), carboxylic acid groups (—COOH), carbonyl groups (—CO—), hydroxyl groups (—OH), amino groups (—NH 2 ), Examples thereof include a nitro group (—NO 2 ) and a nitrile group (—CN). These may use only 1 type and may use 2 or more types together.
- the ratio of the reinforcing fiber and the binder resin is not limited. However, when the total of these is 100% by mass, the reinforcing fiber is 10% by mass to 90% by mass (more preferably 15% by mass to 85% by mass, 25 mass% or more and 75 mass% or less, and further 35 mass% or more and 65 mass% or less).
- the reinforcing portion 23 of the vehicle door trim board 20 includes a polyolefin resin and a modified elastomer that is a compatibilizer. And the olefin type thermoplastic elastomer mentioned later can be utilized as this modified elastomer. Therefore, when a polyolefin resin is used as the above-mentioned binder resin, and a modified polyolefin resin modified by introducing a polar group into a part of the polyolefin resin constituting the binder resin is used, For the reinforcing portion 23, it is preferable to use a polyolefin resin and an olefin-based thermoplastic elastomer. By combining these, it is possible to provide a vehicle door trim board that is particularly difficult to crack.
- each of the upper board portion 21 and the lower board portion 25 may be formed from any material.
- each may be formed as a foamed resin board.
- the foamed resin board (upper board portion 21 and lower board portion 25) is formed from a predetermined resin material, the reinforcing portion 23 is formed from impact-resistant resin, and these are performed in one mold, thereby the upper board.
- the trim board 20 for vehicle doors which consists of a multicolor molded product with which the part 21, the lower board part 25, and the reinforcement part 23 were united can be obtained.
- the resin material constituting the foamed resin board is not limited, but another thermoplastic resin different from the impact resistant resin constituting the reinforcing portion 23 can be used (that is, a multicolor molded product can be used).
- the same olefin resin as the binder resin of Embodiment 2 described above can be used together with the foaming agent.
- a polyolefin resin can be used as another thermoplastic resin constituting the foamed resin board.
- a polyolefin resin can be used as another thermoplastic resin constituting the foamed resin board.
- the vehicle board trim board 20 that is hard to break by covering the surfaces of the upper board portion 21 and the lower board portion 25 with the reinforcing portion 23. be able to.
- the reinforcing portion 23 it is preferable to provide the reinforcing portion 23 so as to cover at least the surface of the boundary region straddling the upper board portion 21 and the lower board portion 25 (see FIG. 4).
- the reinforcing portion 23 can be provided so as to cover the entire upper board portion 21 and the lower board portion 25 while covering the surface straddling the boundary region with the reinforcing portion 23 (see FIG. 5).
- the reinforcing portion 23 covering the surface may be provided on the design surface 20a side (vehicle interior side) of the vehicle door trim board 20 as shown in FIG. 5, or as shown in FIG. You may provide in the non-design surface 20b side (vehicle compartment outer side) of the trim board 20.
- the other reinforcing portion 24 as shown in FIGS. 8 and 9 described in the first embodiment can be provided in the same manner even when the reinforcing portion 23 having the form shown in FIG. 4 is provided.
- Each of the upper board portion 21 and the lower board portion 25 may be formed of any material, but each of the upper board portion 21 and the lower board portion 25 includes a reinforcing fiber and a binding resin for binding the reinforcing fiber, as in the second embodiment. It can be formed as a contained fiber reinforced board. In this case, it can be set as the vehicle door trim board 20 which consists of an integral molded article by using a fiber reinforced board (the upper board part 21 and the lower board part 25) as an insert body. That is, the upper board part 21 and the lower board part 25, which are fiber reinforced boards, are used as inserts, and an impact-resistant resin is injected and formed on these surfaces (at least the surfaces straddling these boundary regions). The vehicle door trim board 20 in which the portion 25 and the reinforcing portion 23 are integrated can be obtained. Also in this case, as in the second embodiment, plant fibers can be used as the reinforcing fibers, and the same applies to the preferred binder resin.
- each of the upper board portion 21 and the lower board portion 25 may be formed from any material, but each may be formed as a foamed resin board as in the third embodiment.
- the foamed resin board (upper board portion 21 and lower board portion 25) is formed from a predetermined resin material, the reinforcing portion 23 is formed from impact-resistant resin, and these are performed in one mold, thereby the upper board.
- the trim board 20 for vehicle doors which consists of a multicolor molded product with which the part 21, the lower board part 25, and the reinforcement part 23 were united can be obtained.
- a polyolefin resin and a modified polyolefin resin into which a polar group is introduced can be used as another thermoplastic resin constituting the foamed resin board.
- the impact-resistant resin that forms the reinforcing portion 23 includes a polyolefin resin, a polyamide resin, and a compatibilizing agent. Further, among these, the compatibilizer is a modified elastomer having a reactive group for the polyamide resin.
- polyolefin resin for the polyolefin resin constituting the impact resistant resin, an olefin homopolymer and / or an olefin copolymer can be used.
- the olefin is not particularly limited, and examples thereof include ethylene, propylene, and ⁇ -olefin having 4 to 8 carbon atoms.
- Examples of the ⁇ -olefin having 4 to 8 carbon atoms include 1-butene, 3-methyl-1-butene, 1-pentene, 3-methyl-1-pentene, 4-methyl-1-pentene, 1-hexene, 1-hexene, Examples include octene. These may use only 1 type and may use 2 or more types together.
- examples of the polyolefin resin include polyethylene resin, polypropylene resin, poly 1-butene, poly 1-hexene, poly 4-methyl-1-pentene, and the like. These polymers may be used alone or in combination of two or more. That is, the polyolefin resin may be a mixture of the above polymers.
- polyethylene resin examples include ethylene homopolymers and copolymers of ethylene and other olefins (other olefins do not contain ethylene).
- examples of the latter include ethylene / 1-butene copolymer, ethylene / 1-hexene copolymer, ethylene / 1-octene copolymer, ethylene / 4-methyl-1-pentene copolymer, etc. 50% or more of the total number of structural units is derived from ethylene).
- polypropylene resin examples include propylene homopolymers and copolymers of propylene and other olefins (other olefins do not contain propylene). Examples of the latter include propylene / ethylene copolymers and propylene / 1-butene copolymers (provided that 50% or more of the total number of structural units is propylene-derived units).
- the copolymer of propylene and other olefins may be a random copolymer or a block copolymer, but a block copolymer is preferred. In particular, a propylene / ethylene block copolymer in which the other olefin is ethylene is preferable.
- This propylene / ethylene block copolymer is also referred to as, for example, an impact copolymer, a polypropylene impact copolymer, a heterophasic polypropylene, a heterophasic block polypropylene, or the like.
- the weight average molecular weight (standard polystyrene conversion) by the gel permeation chromatography (GPC) of polyolefin resin is also not specifically limited, For example, it can be 10,000 or more and 500,000 or less, and is 100,000 or more and 450,000 or less. Preferably, 200,000 or more and 400,000 or less are more preferable.
- the polyolefin resin is a polyolefin that does not have an affinity for a polyamide resin, which will be described later, and does not have a reactive group that can react with the polyamide resin. In this respect, it differs from the olefinic component as the modified elastomer described later.
- the polyamide resin constituting the impact resistant resin is a polymer obtained by polymerizing a plurality of monomers via amide bonds (—NH—CO—).
- Monomers constituting the polyamide resin include amino acids such as 6-aminocaproic acid, 11-aminoundecanoic acid, 12-aminododecanoic acid and paraaminomethylbenzoic acid, and lactams such as ⁇ -caprolactam, undecane lactam, and ⁇ -lauryllactam. Etc. These may use only 1 type and may use 2 or more types together.
- the polyamide resin can also be obtained by copolymerization of a diamine and a dicarboxylic acid.
- the diamine as a monomer includes ethylenediamine, 1,3-diaminopropane, 1,4-diaminobutane, 1,6-diaminohexane, 1,7-diaminoheptane, 1,8-diaminooctane, , 9-diaminononane, 1,10-diaminodecane, 1,11-diaminoundecane, 1,12-diaminododecane, 1,13-diaminotridecane, 1,14-diaminotetradecane, 1,15-diaminopentadecane, 1, 16-diaminohexadecane, 1,17-diaminoheptadecane, 1,18-diaminooctadecane, 1,19-dia
- dicarboxylic acids as monomers include oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, brassic acid, Aliphatic dicarboxylic acids such as tetradecanedioic acid, pentadecanedioic acid, octadecanedioic acid, alicyclic dicarboxylic acids such as cyclohexanedicarboxylic acid, aromatic dicarboxylic acids such as phthalic acid, terephthalic acid, isophthalic acid, naphthalenedicarboxylic acid Etc. These may use only 1 type and may use 2 or more types together.
- polyamide resin polyamide 6, polyamide 66, polyamide 11, polyamide 610, polyamide 612, polyamide 614, polyamide 12, polyamide 6T, polyamide 6I, polyamide 9T, polyamide M5T, polyamide 1010, polyamide 1012, polyamide 10T, polyamide MXD6, polyamide 6T / 66, polyamide 6T / 6I, polyamide 6T / 6I / 66, polyamide 6T / 2M-5T, polyamide 9T / 2M-8T, and the like.
- These polyamides may be used alone or in combination of two or more.
- the straight chain carbon number of the hydrocarbon group sandwiched between adjacent amide bonds in the main chain is 6 or more (usually 16 or less).
- a polyamide resin having a certain structure in the present invention, simply referred to as “long chain structure” can be used.
- long chain structure it is preferable to have 50% or more of the long chain structure among all the structural units of the polyamide resin, and may be 100%.
- Specific examples include polyamide 11, polyamide 610, polyamide 612, polyamide 614, polyamide 12, polyamide 6T, polyamide 6I, polyamide 9T, polyamide 1010, polyamide 1012, polyamide 10T, polyamide 9T / 2M-8T. These polyamides may be used alone or in combination of two or more.
- plant-derived polyamide resin can be used among the above-mentioned various polyamide resins.
- the plant-derived polyamide resin is a resin that uses a monomer obtained from a plant-derived component such as vegetable oil, and is therefore desirable from the viewpoint of environmental protection (particularly from the viewpoint of carbon neutral).
- Examples of plant-derived polyamide resins include polyamide 11 (hereinafter also simply referred to as “PA11”), polyamide 610 (hereinafter also simply referred to as “PA610”), polyamide 612 (hereinafter also simply referred to as “PA612”), polyamide 614 (hereinafter referred to as “PA612”).
- PA614 Polyamide 1010
- PA1012 polyamide 1012
- PA10T polyamide 10T
- the weight average molecular weight (standard polystyrene conversion) by the gel permeation chromatography (GPC) of a polyamide resin is not specifically limited, For example, it can be 5,000 or more and 100,000 or less, and is 7,500 or more and 50,000 or less. Preferably, it is 10,000 or more and 50,000 or less.
- the modified elastomer constituting the impact resistant resin is an elastomer having a reactive group for the polyamide resin.
- This modified elastomer is preferably a component having affinity for the polyolefin resin. That is, it is preferably a component having a compatibilizing effect on the polyamide resin and the polyolefin resin. In other words, it is preferably a compatibilizer between a polyamide resin and a polyolefin resin.
- the reactive group includes an acid anhydride group (—CO—O—OC—), a carboxyl group (—COOH), and an epoxy group ⁇ —C 2 O (a three-membered ring comprising two carbon atoms and one oxygen atom). Structure) ⁇ , an oxazoline group (—C 3 H 4 NO), an isocyanate group (—NCO), and the like. These may use only 1 type and may use 2 or more types together.
- the amount of modification of the modified elastomer is not limited, and the modified elastomer may have one or more reactive groups in one molecule. Further, the modified elastomer preferably has 1 or more and 50 or less reactive groups in one molecule, more preferably 3 or more and 30 or less, and particularly preferably 5 or more and 20 or less.
- modified elastomers polymers using various monomers capable of introducing reactive groups (modified elastomers obtained by polymerization using monomers capable of introducing reactive groups), and oxidative degradation products of various polymers (oxidation)
- Modified elastomers in which reactive groups have been formed by decomposition) and graft polymers of organic acids to various polymers Modified elastomers in which reactive groups have been introduced by graft polymerization of organic acids.
- These may use only 1 type and may use 2 or more types together. These may use only 1 type and may use 2 or more types together.
- Examples of the monomer capable of introducing a reactive group include a monomer having a polymerizable unsaturated bond and an acid anhydride group, a monomer having a polymerizable unsaturated bond and a carboxyl group, and a polymerizable unsaturated bond.
- Examples thereof include monomers having an epoxy group.
- acid anhydrides such as maleic anhydride, itaconic anhydride, succinic anhydride, glutaric anhydride, adipic anhydride, citraconic anhydride, tetrahydrophthalic anhydride, butenyl succinic anhydride, and maleic acid, itaconic acid And carboxylic acids such as fumaric acid, acrylic acid and methacrylic acid. These may be used alone or in combination of two or more. Of these compounds, acid anhydrides are preferred, maleic anhydride and itaconic anhydride are more preferred, and maleic anhydride is particularly preferred.
- skeleton resin the type of resin constituting the skeleton of the modified elastomer
- various thermoplastic resins can be used.
- this skeleton resin one kind or two or more kinds of various resins exemplified above as the polyolefin resin can be used.
- an olefin-based thermoplastic elastomer and a styrene-based thermoplastic elastomer can be used as the skeleton resin. These may use only 1 type and may use 2 or more types together.
- the olefin-based thermoplastic elastomer examples include a copolymer obtained by copolymerizing two or more olefins.
- the olefin one or more of the various olefins exemplified above as the olefin constituting the polyolefin resin can be used.
- the olefin-based thermoplastic elastomer a copolymer of ethylene and an ⁇ -olefin having 3 to 8 carbon atoms and a copolymer of propylene and an ⁇ -olefin having 4 to 8 carbon atoms are preferable.
- copolymers of ethylene and ⁇ -olefin having 3 to 8 carbon atoms include ethylene / propylene copolymer (EPR), ethylene / 1-butene copolymer (EBR), ethylene / 1-pentene copolymer. And ethylene / 1-octene copolymer (EOR).
- EPR ethylene / propylene copolymer
- EBR ethylene / 1-butene copolymer
- EOR ethylene / 1-octene copolymer
- Examples of the copolymer of propylene and ⁇ -olefin having 4 to 8 carbon atoms include propylene / 1-butene copolymer (PBR), propylene / 1-pentene copolymer, propylene / 1-octene copolymer. (POR). These may use only 1 type and may use 2 or more types together.
- examples of the styrenic thermoplastic elastomer include a block copolymer of a styrene compound and a conjugated diene compound, and a hydrogenated product thereof.
- examples of the styrene compound include styrene, ⁇ -methyl styrene, p-methyl styrene, alkyl styrene such as pt-butyl styrene, p-methoxy styrene, vinyl naphthalene, and the like. These may use only 1 type and may use 2 or more types together.
- conjugated diene compound examples include butadiene, isoprene, piperylene, methylpentadiene, phenylbutadiene, 3,4-dimethyl-1,3-hexadiene, 4,5-diethyl-1,3-octadiene, and the like. These may use only 1 type and may use 2 or more types together.
- styrene-based thermoplastic elastomers include styrene-butadiene-styrene copolymer (SBS), styrene-isoprene-styrene copolymer (SIS), styrene-ethylene / butylene-styrene copolymer (SEBS), styrene- And ethylene / propylene-styrene copolymer (SEPS). These may use only 1 type and may use 2 or more types together. Of these, SEBS is preferred.
- the weight average molecular weight (standard polystyrene conversion) by the gel permeation chromatography (GPC) of a modified elastomer is not specifically limited, For example, it can be 10,000 or more and 500,000 or less, for example, 35,000 or more and 500,000 or less. Preferably, 35,000 or more and 300,000 or less are more preferable.
- Other components can be blended in the impact resistant resin.
- Other components include fillers (reinforcing fillers), nucleating agents, antioxidants, heat stabilizers, weathering agents, light stabilizers, plasticizers, UV absorbers, antistatic agents, flame retardants, and flame retardant aids. , Slip agent, anti-blocking agent, anti-fogging agent, lubricant, antibacterial agent, colorant (pigment, dye), dispersant, copper damage inhibitor, neutralizer, anti-bubble agent, weld strength improver, natural oil, synthetic An oil, a wax, etc. are mentioned. These may use only 1 type and may use 2 or more types together.
- thermoplastic resins examples include polyester resins (polybutylene terephthalate, polyethylene terephthalate, polycarbonate, polybutylene succinate, polyethylene succinate, polylactic acid) and the like. These may use only 1 type and may use 2 or more types together.
- Fillers include glass components (glass fibers, glass beads, glass flakes, etc.), silica, inorganic fibers (glass fibers, alumina fibers, carbon fibers), graphite, silicate compounds (calcium silicate, aluminum silicate, montmorillonite, kaolin, talc) , Clay, etc.), metal oxides (iron oxide, titanium oxide, zinc oxide, antimony oxide, alumina, etc.), carbonates and sulfates of metals such as lithium, calcium, magnesium, zinc, metals (aluminum, iron, silver, Copper, etc.), hydroxides (aluminum hydroxide, magnesium hydroxide, etc.), sulfides (barium sulfate, etc.), carbides (charcoal, bamboo charcoal, etc.), titanates (potassium titanate, barium titanate, etc.), organic fibers ( Aromatic polyester fiber, aromatic polyamide fiber, fluororesin fiber, polyimide fiber, vegetable fiber, etc. , Celluloses (cellulose microfibril
- Phase structure The phase structure exhibited by the impact-resistant resin is not limited, but can have the following phase structures (1) to (3).
- Phase structure (1) Phase structure having a continuous phase (A) containing a polyolefin resin and a dispersed phase (B) containing a polyamide resin and a modified elastomer dispersed in the continuous phase (A) (FIG. 10). However, other phase structures having a continuous phase containing a polyamide resin and a dispersed phase dispersed in the continuous phase do not coexist.
- Phase structure (2) A phase structure having a continuous phase containing a polyamide resin and a dispersed phase containing a polyolefin resin dispersed in the continuous phase.
- Phase structure (3) a continuous phase (A 1 ) containing a polyolefin resin, a dispersed phase (B A1 ) containing a polyamide resin and a modified elastomer dispersed in the continuous phase (A 1 ), and a polyamide resin and inclusive continuous phase (a 2), the continuous phase (a 2) are dispersed in the dispersed phase containing the modified elastomer (B A2) and a phase structure having a (see FIG. 11).
- the phase structure (1) or the phase structure (3) is preferable, and the phase structure (1) is more preferable.
- the dispersed phase (B) in the phase structure (1) is a continuous phase in the dispersed phase (B), and a continuous phase (B 1 ) containing a polyamide resin, A finely dispersed phase dispersed in the continuous phase (B 1 ) and containing a modified elastomer (B 2 ) (see FIG. 10).
- the phase structure (1) exhibits a multiphase structure having a finely dispersed phase (B 1 ) in the dispersed phase (B).
- the modified elastomer may be an unreacted modified elastomer, a reaction product with a polyamide resin, or a mixture thereof.
- the phase structure (3) can exhibit a co-continuous phase structure in which two continuous phases of the continuous phase (A 1 ) and the continuous phase (A 2 ) coexist.
- the dispersed phase in the continuous phase (A 1) (B A1) is a continuous phase within the dispersed phase (B A1), the continuous phase comprising a polyamide resin and (B A11), the continuous phase (B A11 ) and a finely dispersed phase (B A12 ) containing a modified elastomer.
- the phase structure (3) exhibits a multiphase structure having a finely dispersed phase (B A12 ) in the dispersed phase (B A1 ).
- the modified elastomer may be an unreacted modified elastomer, a reaction product with a polyamide resin, or a mixture thereof.
- the continuous phase (A) contains a polyolefin resin.
- the polyolefin resin is a main component of the continuous phase (A) (generally 70% by mass or more and may be 100% by mass with respect to the entire continuous phase A).
- the dispersed phase (B) contains a polyamide resin and a modified elastomer.
- the polyamide resin (when the dispersed phase (B) contains a modified elastomer, the polyamide resin and the modified elastomer) is the main component of the dispersed phase (B) (generally 70% by mass or more with respect to the entire dispersed phase B, and 100% by mass). %).
- the continuous phase (B 1 ) contains a polyamide resin.
- the polyamide resin is a main component of the continuous phase (B 1 ) (typically 70% by mass or more and may be 100% by mass with respect to the entire continuous phase B 1 ).
- the finely dispersed phase (B 2 ) contains a modified elastomer.
- the modified elastomer is a main component of the finely dispersed phase (B 2 ) (typically 70% by mass or more and may be 100% by mass with respect to the entire finely dispersed phase B 2 ).
- the continuous phase (A 1 ) contains a polyolefin resin.
- the polyolefin resin is a main component of the continuous phase (A 1 ) (typically 70% by mass or more and may be 100% by mass with respect to the entire continuous phase A 1 ).
- the dispersed phase (B A1 ) contains a polyamide resin and a modified elastomer.
- the polyamide resin and the modified elastomer are the main components of the dispersed phase (B A1 ) (generally 70% by mass or more and may be 100% by mass with respect to the entire dispersed phase B A1 ).
- the continuous phase (B A11 ) contains a polyamide resin.
- the polyamide resin is the main component of the continuous phase (B A11 ) (typically 70% by mass or more and may be 100% by mass with respect to the entire continuous phase B A11 ).
- the finely dispersed phase (B A12 ) contains a modified elastomer.
- the modified elastomer is a main component of the finely dispersed phase (B A12 ) (generally 70% by mass or more and may be 100% by mass with respect to the entire finely dispersed phase B A12 ).
- the continuous phase (A 2 ) includes a polyamide resin.
- the polyamide resin is a main component of the continuous phase (A 2 ) (typically 70% by mass or more and may be 100% by mass with respect to the entire continuous phase A 2 ).
- the dispersed phase (B A2 ) with respect to the continuous phase (A 2 ) contains a modified elastomer.
- the modified elastomer is a main component of the dispersed phase (B A2 ) (typically 70% by mass or more and may be 100% by mass with respect to the entire dispersed phase B A2 ).
- phase structures can be obtained more reliably by melt-kneading a melt-kneaded product of a polyamide resin and a modified elastomer and a polyolefin resin.
- the reactive group of the modified elastomer can be a reaction product obtained by reacting the polyamide resin.
- the reactant is, for example, an interface between the continuous phase (A) and the dispersed phase (B) and / or a continuous phase (B 1 ) and a finely dispersed phase (B 2 ). Can exist at the interface.
- phase structure (3) for example, the interface between the continuous phase (A 1 ) and the continuous phase (A 2 ), the interface between the continuous phase (A 1 ) and the dispersed phase (B A1 ), the continuous phase (B A11 ) and the finely dispersed phase (B A12 ), etc.
- the various phase structures can be observed with a field emission scanning electron microscope (FE-SEM) after the oxygen plasma etching treatment and the treated surface of the osmium-coated test piece.
- FE-SEM field emission scanning electron microscope
- the dispersed phase and the finely dispersed phase can be observed by an image magnified 1000 times or more (usually 10,000 times or less) in this method.
- the components constituting each phase can be specified by performing energy dispersive X-ray analysis (EDS) during observation using a field emission scanning electron microscope (FE-SEM).
- the size of the dispersed phase of the impact resistant resin is not particularly limited, but the dispersed diameter (average dispersed diameter) is preferably 10,000 nm or less, more Preferably they are 50 nm or more and 8000 nm or less, More preferably, they are 100 nm or more and 4000 nm or less.
- the dispersion diameter of the dispersed phase can be measured in an enlarged image of 1000 times or more obtained using an electron microscope. That is, the longest diameter of each of the 20 dispersed phases randomly selected from a predetermined region in the image is measured, and the average value of the longest diameters obtained is set as the first average value. And the further average value of the 1st average value measured in five different area
- the size is not particularly limited, but the dispersion diameter (average dispersion diameter) is preferably 5 nm to 1000 nm, more preferably 5 nm to 600 nm, still more preferably 10 nm to 400 nm, and particularly preferably 15 nm to 350 nm. It is as follows. The dispersion diameter of the finely dispersed phase can be measured in an enlarged image of 1000 times or more obtained using an electron microscope.
- the longest diameter of each of the 20 finely dispersed phases randomly selected from a predetermined region in the image is measured, and the average value of the obtained longest diameters is set as the first average value.
- regions in an image is the average dispersion diameter (major axis average dispersion diameter) of a fine dispersion phase.
- the ratio of the polyolefin resin can be 2% by mass or more and 90% by mass or less. This proportion is preferably 5% by mass to 85% by mass, more preferably 10% by mass to 83% by mass, further preferably 15% by mass to 80% by mass, and further preferably 20% by mass to 78% by mass. Furthermore, 25 mass% or more and 75 mass% or less are preferable, 30 mass% or more and 73 mass% or less are more preferable, and 35 mass% or more and 70 mass% or less are more preferable.
- the ratio of the polyamide resin and the modified elastomer (some or all of these may be mutually reacted) It can be 10 mass% or more and 98 mass% or less. This ratio is preferably 15% by mass to 95% by mass, more preferably 17% by mass to 90% by mass, further preferably 20% by mass to 85% by mass, and further preferably 22% by mass to 80% by mass. Furthermore, 25 mass% or more and 75 mass% or less are preferable, 27 mass% or more and 70 mass% or less are more preferable, and 30 mass% or more and 65 mass% or less are more preferable.
- the ratio of the polyamide resin can be 1% by mass to 75% by mass. This proportion is preferably 2% by mass or more and 70% by mass or less, more preferably 4% by mass or more and 65% by mass or less, further preferably 6% by mass or more and 60% by mass or less, and further preferably 8% by mass or more and 55% by mass or less. Furthermore, 10 mass% or more and 50 mass% or less are preferable, 12 mass% or more and 45 mass% or less are more preferable, and 15 mass% or more and 40 mass% or less are more preferable.
- the ratio of the modified elastomer can be 1% by mass to 60% by mass. This proportion is preferably 2% to 55% by mass, more preferably 4% to 45% by mass, further preferably 6% to 40% by mass, and further preferably 8% to 38% by mass. Furthermore, 10 mass% or more and 37 mass% or less are preferable, 12 mass% or more and 36 mass% or less are preferable, and 15 mass% or more and 35 mass% or less are more preferable.
- the ratio of the polyamide resin can be 1.5% by mass or more and 88% by mass or less. This ratio is preferably 3% by mass or more and 75% by mass or less, more preferably 5% by mass or more and 70% by mass or less, further preferably 10% by mass or more and 65% by mass or less, and further preferably 15% by mass or more and 60% by mass or less. Furthermore, 18 mass% or more and 55 mass% or less are preferable, 20 mass% or more and 50 mass% or less are more preferable, and 25 mass% or more and 45 mass% or less are more preferable.
- the ratio of the modified elastomer can be 20% by mass or more and 90% by mass or less. This ratio is preferably 22% by mass or more and 88% by mass or less, more preferably 25% by mass or more and 86% by mass or less, further preferably 27% by mass or more and 75% by mass or less, and preferably 29% by mass or more and 70% by mass or less. Furthermore, 32 mass% or more and 66 mass% or less are preferable, and also 36 mass% or more and 60 mass% or less are preferable.
- the proportion of the polyolefin resin when the total of the above-mentioned polyolefin resin, polyamide resin and modified elastomer is 100% by mass is usually the whole phase. Is equal to the proportion of the continuous phase (A) in the case of 100 mass%.
- the phase structure (3) it is usually equal to the ratio of the continuous phase (A 1 ) when the entire phase is 100% by mass.
- the ratio here is a volume ratio, but is usually equal to an area ratio in which the volume ratio is reflected (the same applies hereinafter).
- the ratio of the polyamide resin and the modified elastomer is usually in the case of the above-described phase structure (1) (see FIG. 10). It is equal to the proportion of the dispersed phase (B) when the total phase is 100% by mass.
- the phase structure (3) in the case of the phase structure (3) (see FIG. 11), normally, the dispersed phase (B A1 ), the continuous phase (A 2 ), and the dispersed phase (B A2 ) when the entire phase is 100% by mass. And equal to the total percentage.
- the ratio of the polyamide resin when the total of the above-mentioned polyolefin resin, polyamide resin and modified elastomer is 100% by mass is usually 100 for the entire phase. It is equal to the ratio of the continuous phase (B 1 ) in the case of mass%.
- the total ratio of the continuous phase (A 2 ) and the continuous phase in the dispersed phase (B A11 ) when the entire phase is 100% by mass be equivalent to.
- the ratio of the modified elastomer when the total of the above-mentioned polyolefin resin, polyamide resin and modified elastomer is 100% by mass is usually 100 for the entire phase. It is equal to the proportion of the finely dispersed phase (B 2 ) in the case of mass%.
- the phase structure (3) in the case of the phase structure (3) (see FIG. 11), it is usually equal to the total proportion of the finely dispersed phase (B A12 ) and the dispersed phase (B A2 ) when the entire phase is 100% by mass. .
- the Charpy impact strength can be 5 kJ / m 2 or more and 150 kJ / m 2 or less.
- the flexural modulus can be set to 430 MPa or more and 1500 MPa or less.
- the Charpy impact strength can be 50 kJ / m 2 or more and 140 kJ / m 2 or less.
- the flexural modulus can be 440 MPa to 1300 MPa.
- the Charpy impact strength can be 60 kJ / m 2 or more and 135 kJ / m 2 or less.
- the flexural modulus can be 450 MPa or more and 1250 MPa or less. Furthermore, the Charpy impact strength can be set to 70 kJ / m 2 or more and 130 kJ / m 2 or less. The flexural modulus can be 460 MPa or more and 1200 MPa or less. Further, Charpy impact strength can be reduced to 80 kJ / m 2 or more 125kJ / m 2 or less. The flexural modulus can be 470 MPa or more and 1100 MPa or less. The value of the Charpy impact strength is a value when measured according to JIS K7111-1 (type A notch, temperature 23 ° C., edgewise test method).
- the value of the flexural modulus was measured in accordance with JIS K7171 (supported by two fulcrums with a distance between fulcrums of 64 mm and a radius of curvature of 5 mm, using an action point with a radius of curvature of 5 mm, load load speed of 2 mm / min). Is the case value.
- the method for preparing the impact resistant resin is not limited, but can be obtained, for example, by melt-kneading a melt-kneaded product of a polyamide resin and a modified elastomer and a polyolefin resin.
- any melt-kneading apparatus may be used for the preparation of the above-mentioned melt-kneaded product and the melt-kneading of the melt-kneaded product and the polyolefin resin.
- an extruder single screw extruder, twin screw kneading extruder, etc.
- a kneader a mixer (high-speed flow mixer, paddle mixer, ribbon mixer, etc.), etc.
- the melt kneading temperature of the polyamide resin and the modified elastomer is not limited, but can be, for example, 190 ° C. or higher and 350 ° C. or lower, preferably 200 ° C. or higher and 330 ° C. or lower, more preferably 205 ° C. or higher and 310 ° C. or lower.
- the melt kneading temperature of the obtained melt-kneaded product and the polyolefin resin is not limited, but can be, for example, 190 ° C or higher and 350 ° C or lower, preferably 200 ° C or higher and 300 ° C or lower, and 205 ° C or higher and 260 ° C or lower. Is more preferable.
- the one part or all part can be made into a foam as needed. That is, the reinforcing part can be a foamed reinforcing part. Further, the other reinforcing part can be a foamed reinforcing part (hereinafter, the foamed reinforcing part and the other reinforcing part are also simply referred to as “foamed part”).
- the foamed reinforcing part and the other reinforcing part are foam-molded, it is possible to provide a vehicle door trim board having excellent heat resistance while being lightweight while having excellent impact resistance.
- This foamed part can be obtained by foaming an impact resistant resin.
- the impact resistant resin has a phase structure including the continuous phase (A) and the dispersed phase (B) as described above, the bubbles are included in the continuous phase (A) and the dispersed phase (B) It is preferable that it is not contained in.
- the door trim (10) (see FIG. 1) of the present invention includes a vehicle door trim board (20) and a skin layer (15) laid on the design surface side of the vehicle door trim board (20). ). That is, the skin layer (15) can be provided so as to constitute the design surface (10a) of the door trim (10). And this door trim (10) is functioned as a vehicle door (1) as a whole by being fitted by the door panel (30).
- the skin layer 15 is a layer that forms the design surface of the door trim 10. Specifically, various fabrics (including woven fabrics, knitted fabrics, non-woven fabrics, etc.), resin skins (for example, resin skin materials provided with a pattern by embossing), and the like can be used. Moreover, the structure of the skin layer 15 is not limited, It may consist of only one layer and may consist of two or more layers. In the case of two or more layers, for example, a laminate comprising a surface layer having a design surface (for example, synthetic leather or woven fabric) and a cushion layer (arranged on the non-design surface side of the skin layer 15) is used as a skin layer. 15 can be set.
- the door trim 10 of the present invention includes the skin layer 28 as described above, it can of course be used as the door trim 10 even if it is not provided. That is, the vehicle door trim board 20 can be used as it is as the door trim 10 as long as the design surface is directly embossed on the design surface of the vehicle door trim board 20.
- the vehicle door trim board and door trim of the present invention are used as interior materials for automobiles and railway vehicles. Similarly, it can be diverted to other automobile interior materials. Specific examples include instrument panels, door trims, quarter trims, roof linings, pillar garnishes, deck trims, tonneau boards, package trays, dashboards, console boxes, and seat back boards.
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Abstract
Description
下記特許文献1には、車両ドア用トリムボードとして高衝撃性芯材を利用する技術が開示されている。また、下記特許文献2及び3には、ポリオレフィン樹脂及びポリアミド樹脂を含んだ耐衝撃樹脂が開示されている。
上記特許文献2には、ポリアミド樹脂とポリオレフィン樹脂とを含んだ樹脂組成物において、相容化剤として変性エラストマーを利用できることが開示されている。また、上記特許文献3には、ポリアミド樹脂とポリオレフィン樹脂とを含んだ樹脂組成物において、連続相と分散相と微分散相とを有する相構造を呈し得ることが開示されている。
しかしながら、上記特許文献2-3には、これらの樹脂組成物をドアトリムに利用できるという開示はあるものの、具体的に、どのような形態で利用することで当該樹脂組成物のメリットを車両ドア用トリムボードにおいて享受できるかについての検討はなされていない。
請求項1に記載の車両ドア用トリムボードは、ポリオレフィン樹脂とポリアミド樹脂と相容化剤と、を含み、
前記相容化剤が、前記ポリアミド樹脂に対する反応性基を有する変性エラストマーである耐衝撃樹脂からなる補強部を有することを要旨とする。
請求項2に記載の車両ドア用トリムボードは、請求項1に記載の車両ドア用トリムボードにおいて、上下に分割されたアッパーボード部及びロアボード部と、
前記アッパーボード部と前記ロアボード部との間に介在された前記補強部と、を有することを要旨とする。
請求項3に記載の車両ドア用トリムボードは、請求項2に記載の車両ドア用トリムボードにおいて、前記アッパーボード部及び前記ロアボード部は、各々、前記耐衝撃樹脂と異なる他の熱可塑性樹脂を用いた発泡樹脂ボードからなり、
前記アッパーボード部、前記ロアボード部及び前記補強部は、前記他の熱可塑性樹脂と前記耐衝撃樹脂とを用いた一体の多色成形物からなることを要旨とする。
請求項4に記載の車両ドア用トリムボードは、請求項2に記載の車両ドア用トリムボードにおいて、前記アッパーボード部及び前記ロアボード部は、各々、植物繊維と、前記植物繊維を結着する結着樹脂と、を含んだ繊維補強ボードからなり、
前記アッパーボード部、前記ロアボード部及び前記補強部は、前記繊維補強ボードをインサート体とした一体のインサート成形物からなることを要旨とする。
請求項5に記載の車両ドア用トリムボードは、請求項1に記載の車両ドア用トリムボードにおいて、上下に隣り合ったアッパーボード部及びロアボード部と、
少なくとも前記アッパーボード部及び前記ロアボード部を跨いだ境界域の表面を覆う前記補強部と、を有することを要旨とする。
請求項6に記載の車両ドア用トリムボードは、請求項5に記載の車両ドア用トリムボードにおいて、前記アッパーボード部及び前記ロアボード部は、前記耐衝撃樹脂と異なる他の熱可塑性樹脂を用いた一体の発泡樹脂ボードからなり、
前記アッパーボード部、前記ロアボード部及び前記補強部は、前記他の熱可塑性樹脂と前記耐衝撃樹脂とを用いた一体の多色成形物からなることを要旨とする。
請求項7に記載の車両ドア用トリムボードは、請求項5に記載の車両ドア用トリムボードにおいて、前記アッパーボード部及び前記ロアボード部は、植物繊維と、前記植物繊維を結着する結着樹脂と、を含んだ一体の繊維補強ボードからなり、
前記アッパーボード部、前記ロアボード部及び前記補強部は、前記繊維補強ボードをインサート体とした一体のインサート成形物からなることを要旨とする。
請求項8に記載の車両ドア用トリムボードは、請求項1乃至7のうちのいずれかに記載の車両ドア用トリムボードにおいて、前記補強部は、帯状をなし、車両の前後方向に本車両ドア用トリムボードを貫通するように配置されており、
前記ロアボード部は、前記補強部とは異なる少なくとも1条の帯状をなした他補強部を有し、
前記他補強部は、前記耐衝撃樹脂からなるとともに、前記補強部と略平行に配置されることを要旨とする。
請求項9に記載の車両ドア用トリムボードは、請求項1乃至8のうちのいずれかに記載の車両ドア用トリムボードにおいて、前記耐衝撃樹脂は、前記ポリオレフィン樹脂を含んだ連続相(A)と、
前記連続相(A)中に分散された分散相であって、前記ポリアミド樹脂及び前記変性エラストマーを含んだ分散相(B)と、を有することを要旨とする。
請求項10に記載の車両ドア用トリムボードは、請求項9に記載の車両ドア用トリムボードにおいて、前記分散相(B)が、前記ポリアミド樹脂を含んだ連続相(B1)と、
前記連続相(B1)中に分散された前記変性エラストマーを含んだ微分散相(B2)と、を有することを要旨とする。
請求項11に記載の車両ドア用トリムボードは、請求項9又は10に記載の車両ドア用トリムボードにおいて、前記変性エラストマーは、エチレン若しくはプロピレンと炭素数3~8のα-オレフィンとの共重合体を骨格としたオレフィン系熱可塑性エラストマーであることを要旨とする。
請求項12に記載のドアトリムは、請求項1乃至11のうちのいずれかに記載の車両ドア用トリムボードと、前記車両ドア用トリムボードの意匠面側に敷設された表皮層と、を有することを要旨とする。
本車両ドア用トリムボードにおいて、上下分割されたアッパーボード部及びロアボード部とこれらの間に介在された補強部を有する場合は、アッパーボード部とロアボード部との剛性差に起因する破壊を抑制できる。即ち、車両ドア用トリムボードでは、アッパーボード部とロアボード部とで剛性が異なるため、この剛性差に起因して、衝撃負荷時に車両ドア用トリムボードが割れることも想定され得る。この点、アッパーボード部とロアボード部との間に耐衝撃樹脂で形成された補強部が介在された車両ドア用トリムボードでは、アッパーボード部とロアボード部との間の剛性差が緩和され、上述の破壊を抑制できる。
また、アッパーボード部及びロアボード部が、各々、繊維補強ボードからなる場合には、繊維補強ボードをインサート体として、補強部を射出形成により形成し、アッパーボード部、ロアボード部及び補強部を一体のインサート成形物にすることにより、優れた耐衝撃性を付与した割れ難い車両ドア用トリムボードを提供できる。
また、アッパーボード部及びロアボード部が、一体の繊維補強ボードからなる場合には、繊維補強ボードをインサート体として、補強部を射出形成により形成することで、アッパーボード部、ロアボード及び補強部を一体のインサート成形物にすることにより、優れた耐衝撃性を付与した割れ難い車両ドア用トリムボードを提供できる。
本発明の車両ドア用トリムボード(20)は、ポリオレフィン樹脂とポリアミド樹脂と相容化剤と、を含み、相容化剤が、ポリアミド樹脂に対する反応性基を有する変性エラストマーである耐衝撃樹脂からなる補強部(23)を有することを特徴とする。
これに対し、本車両ドア用トリムボード20では、補強部23を有することにより、図2~図7に例示されるように、本車両ドア用トリムボード20を一体に形成することができる。そして、一体に形成することで、補強部23を構成する耐衝撃樹脂の特性を効果的に享受でき、割れ難い車両ドア用トリムボードを提供できる。
[実施形態1]
アッパーボード部21とロアボード部25とが上下に分割されている場合、即ち、アッパーボード部21とロアボード部25とが、別体のボードである場合には、アッパーボード部21とロアボード部25との間に、補強部23を介在させて一体化した車両ドア用トリムボード20とすることができる(図2参照)。また、この場合、補強部23は、車両の前後方向に、車両ドア用トリムボード20を横断させて配置することができる。即ち、車両ドア用トリムボード20の中央部に帯状に設けることができる(前後に貫通する形態となる)。
このような構成とすることにより、アッパーボード部21とロアボード部25との間に介在された補強部23が、アッパーボード部21とロアボード部25との間の剛性差を吸収するように柔軟に衝撃吸収できるため、一体化されていても割れることなく衝撃を吸収させることができる。
また、本発明では、補強部23以外にも他補強部24を併用できる。特に、前述のように、補強部23が帯状をなし、車両の前後方向に、車両ドア用トリムボード20を貫通するように配置(横断して配置)されている場合、更に、同様に帯状をなした他補強部24を併用することができる。この他補強部24は、1つのみを設けてもよいし、2つ以上を設けてもよい。
具体的には、図8及び図9に示すように、ロアボード部25に、他補強部24を設けることができる。他補強部24は、例えば、他補強部241及び他補強部242として2条を設けることができる。これらの他補強部24も、補強部23と同様に、前述した耐衝撃樹脂から形成できる。
更に、他補強部24は、図8に示すように、ロアボード部25の一部として置換するように配置することもできるし、図9に示すように、ロアボード部25の表裏いずれかの(又は両面でもよい)の一面に付設することもできる。
アッパーボード部21及びロアボード部25は、各々、どのような材料から形成してもよいが、例えば、各々を補強繊維と、この補強繊維を結着する結着樹脂と、を含んだ繊維補強ボードとして形成することができる。
この場合、繊維補強ボード(アッパーボード部21及びロアボード部25)をインサート体として一体のインサート成形物からなる車両ドア用トリムボード20とすることができる。即ち、繊維補強ボードであるアッパーボード部21及びロアボード部25をインサート体とし、これらの間に耐衝撃樹脂を射出形成することで、アッパーボード部21、ロアボード部25及び補強部23が一体となった車両ドア用トリムボード20を得ることができる。
これらのうちでは、有機繊維が好ましく、更には天然繊維が好ましく、特に植物繊維が好ましい。植物繊維は、植物に由来する繊維であり、植物から取り出した繊維や、これを加工した繊維が含まれる。植物性繊維には、葉脈系植物繊維(アバカ、サイザル、アガベ等)、靭皮系植物繊維(フラックス、ジュート、ヘンプ、ケナフ、ラミー等)、木質系植物繊維(広葉樹及び針葉樹等から採取された植物繊維)、その他の植物繊維(ココヤシ殻繊維、オイルパーム空果房繊維、稲わら繊維、麦わら繊維、タケ繊維、綿等)
これらのなかでも、ポリオレフィン樹脂が好ましい。ポリオレフィン樹脂としては、エチレン単独重合体、エチレン・1-ブテン共重合体、エチレン・1-へキセン共重合体、エチレン・4-メチル-1-ペンテン共重合体等のポリエチレン樹脂(全構成単位数のうちの50%以上がエチレン由来単位である)が挙げられる。また、プロピレン単独重合体、プロピレン・エチレン共重合体(プロピレン・エチレンランダム共重合体等)、プロピレン・1-ブテン共重合体等のポリプロピレン樹脂(全構成単位数のうち50%以上がプロピレン由来単位である)が挙げられる。
前述のように、アッパーボード部21及びロアボード部25は、各々、どのような材料から形成してもよいが、例えば、各々を発泡樹脂ボードとして形成することができる。
この場合、発泡樹脂ボード(アッパーボード部21及びロアボード部25)を所定の樹脂材料から形成し、補強部23を耐衝撃樹脂から形成し、これらを1つの金型内で行うことで、アッパーボード部21、ロアボード部25及び補強部23が一体となった多色成形物からなる車両ドア用トリムボード20を得ることができる。
アッパーボード部21とロアボード部25とが、上下に隣り合っている場合には、アッパーボード部21及びロアボード部25の表面を、補強部23で覆うことで割れ難い車両ドア用トリムボード20とすることができる。この場合、少なくともアッパーボード部21及びロアボード部25を跨いだ境界域の表面を覆うように補強部23を備えることが好ましい(図4参照)。当然ながら、図5に示すように、境界域を跨いだ表面を補強部23で覆いながら、アッパーボード部21及びロアボード部25の全面を覆うように補強部23を備えることができる(図5参照)。
更に、表面を覆う補強部23は、図5に示すように、車両ドア用トリムボード20の意匠面20a側(車室内側)に設けてもよいし、図6に示すように、車両ドア用トリムボード20の非意匠面20b側(車室外側)に設けてもよい。このうち、車両ドア用トリムボード20の意匠面20a側(車室内側)が好ましい。
更に、当然ながら、実施形態1において説明した図8及び図9に示すような他補強部24は、上述の図4に示す形態の補強部23を有する場合にも、同様に設けることができる。
アッパーボード部21及びロアボード部25は、各々、どのような材料から形成してもよいが、実施形態2と同様に、各々を補強繊維と、この補強繊維を結着する結着樹脂と、を含んだ繊維補強ボードとして形成することができる。
この場合、繊維補強ボード(アッパーボード部21及びロアボード部25)をインサート体として一体のインサート成形物からなる車両ドア用トリムボード20とすることができる。即ち、繊維補強ボードであるアッパーボード部21及びロアボード部25をインサート体とし、これらの表面(少なくともこれらの境界域を跨ぐ表面)に耐衝撃樹脂を射出形成することで、アッパーボード部21、ロアボード部25及び補強部23が一体となった車両ドア用トリムボード20を得ることができる。この場合にも、実施形態2と同様に、補強繊維として植物繊維を利用でき、また、好ましい結着樹脂の態様についても同様である。
更に、前述のように、アッパーボード部21及びロアボード部25は、各々、どのような材料から形成してもよいが、実施形態3と同様に、各々を発泡樹脂ボードとして形成することができる。
この場合、発泡樹脂ボード(アッパーボード部21及びロアボード部25)を所定の樹脂材料から形成し、補強部23を耐衝撃樹脂から形成し、これらを1つの金型内で行うことで、アッパーボード部21、ロアボード部25及び補強部23が一体となった多色成形物からなる車両ドア用トリムボード20を得ることができる。この場合、発泡樹脂ボードを構成する他の熱可塑性樹脂として、ポリオレフィン樹脂及び極性基が導入された変性ポリオレフィン樹脂を用いることができることについても、実施形態3と同様である。
補強部23をなす耐衝撃樹脂は、ポリオレフィン樹脂とポリアミド樹脂と相容化剤と、を含む。更には、このうち、相容化剤は、ポリアミド樹脂に対する反応性基を有する変性エラストマーである。
耐衝撃樹脂を構成するポリオレフィン樹脂には、オレフィンの単独重合体、及び/又は、オレフィンの共重合体を用いることができる。
上記オレフィンは特に限定されないが、エチレン、プロピレン及び炭素数4~8のα-オレフィン等が挙げられる。炭素数4~8のα-オレフィンとしては、1-ブテン、3-メチル-1-ブテン、1-ペンテン、3-メチル-1-ペンテン、4-メチル-1-ペンテン、1-ヘキセン、1-オクテン等が挙げられる。これらは1種のみを用いてもよく2種以上を併用してもよい。
具体的には、ポリオレフィン樹脂としては、ポリエチレン樹脂、ポリプロピレン樹脂、ポリ1-ブテン、ポリ1-ヘキセン、ポリ4-メチル-1-ペンテン等が挙げられる。これら重合体は1種のみで用いてもよく、2種以上を併用してもよい。即ち、ポリオレフィン樹脂は上記重合体の混合物であっても良い。
また、プロピレンと他のオレフィンとの共重合体は、ランダム共重合体であってもよく、ブロック共重合体であってもよいが、ブロック共重合体が好ましい。とりわけ、他のオレフィンがエチレンであるプロピレン・エチレンブロック共重合体が好ましい。このプロピレン・エチレンブロック共重合体は、例えば、インパクトコポリマー、ポリプロピレンインパクトコポリマー、ヘテロファジックポリプロピレン、ヘテロファジックブロックポリプロピレン等とも称される。
耐衝撃樹脂を構成するポリアミド樹脂は、アミド結合(-NH-CO-)を介して複数の単量体が重合されてなる重合体である。
ポリアミド樹脂を構成する単量体としては、6-アミノカプロン酸、11-アミノウンデカン酸、12-アミノドデカン酸、パラアミノメチル安息香酸等のアミノ酸、ε-カプロラクタム、ウンデカンラクタム、ω-ラウリルラクタム等のラクタムなどが挙げられる。これらは1種のみを用いてもよく2種以上を併用してもよい。
植物由来ポリアミド樹脂としては、ポリアミド11(以下、単に「PA11」ともいう)、ポリアミド610(以下、単に「PA610」ともいう)、ポリアミド612(以下、単に「PA612」ともいう)、ポリアミド614(以下、単に「PA614」ともいう)、ポリアミド1010(以下、単に「PA1010」ともいう)、ポリアミド1012(以下、単に「PA1012」ともいう)、ポリアミド10T(以下、単に「PA10T」ともいう)等が挙げられる。これらは1種のみを用いてもよく2種以上を併用してもよい。
耐衝撃樹脂を構成する変性エラストマーは、ポリアミド樹脂に対する反応性基を有するエラストマーである。この変性エラストマーは、ポリオレフィン樹脂に対して親和性を有する成分であることが好ましい。即ち、ポリアミド樹脂とポリオレフィン樹脂とに対する相容化作用を有する成分であることが好ましい。更に換言すれば、ポリアミド樹脂とポリオレフィン樹脂との相容化剤であることが好ましい。
変性エラストマーの変性量は限定されず、変性エラストマーは1分子中に1以上の反応性基を有すればよい。更に、変性エラストマーは1分子中に1以上50以下の反応性基を有することが好ましく、3以上30以下がより好ましく、5以上20以下が特に好ましい。
具体的には、無水マレイン酸、無水イタコン酸、無水コハク酸、無水グルタル酸、無水アジピン酸、無水シトラコン酸、テトラヒドロ無水フタル酸、ブテニル無水コハク酸等の酸無水物、及びマレイン酸、イタコン酸、フマル酸、アクリル酸、メタクリル酸等のカルボン酸が挙げられる。これらは1種のみ用いてもよく2種以上を併用してもよい。これらの化合物のうちでは、酸無水物が好ましく、無水マレイン酸及び無水イタコン酸がより好ましく、無水マレイン酸が特に好ましい。
オレフィンとしては、ポリオレフィン樹脂を構成するオレフィンとして先に例示した各種のオレフィンの1種又は2種以上を用いることができる。このなかでも、オレフィン系熱可塑性エラストマーとしては、エチレンと炭素数3~8のα-オレフィンとの共重合体、及び、プロピレンと炭素数4~8のα-オレフィンとの共重合体が好ましい。
また、プロピレンと炭素数4~8のα-オレフィンとの共重合体としては、プロピレン・1-ブテン共重合体(PBR)、プロピレン・1-ペンテン共重合体、プロピレン・1-オクテン共重合体(POR)等が挙げられる。これらは1種のみを用いてもよく2種以上を併用してもよい。
上記スチレン系化合物としては、例えば、スチレン、α-メチルスチレン、p-メチルスチレン、p-t-ブチルスチレン等のアルキルスチレン、p-メトキシスチレン、ビニルナフタレン等が挙げられる。これらは1種のみを用いてもよく2種以上を併用してもよい。
上記共役ジエン化合物としては、ブタジエン、イソプレン、ピペリレン、メチルペンタジエン、フェニルブタジエン、3,4-ジメチル-1,3-ヘキサジエン、4,5-ジエチル-1,3-オクタジエン等が挙げられる。これらは1種のみを用いてもよく2種以上を併用してもよい。
耐衝撃樹脂には、ポリオレフィン樹脂、ポリアミド樹脂及び変性エラストマー以外に、他の成分を配合できる。他の成分としては、充填剤(補強フィラー)、造核剤、酸化防止剤、熱安定剤、耐候剤、光安定剤、可塑剤、紫外線吸収剤、帯電防止剤、難燃剤、難燃助剤、スリップ剤、アンチブロッキング剤、防曇剤、滑剤、抗菌剤、着色剤(顔料、染料)、分散剤、銅害防止剤、中和剤、気泡防止剤、ウェルド強度改良剤、天然油、合成油、ワックス等が挙げられる。これらは1種のみを用いてもよく2種以上を併用してもよい。
充填剤としては、ガラス成分(ガラス繊維、ガラスビーズ、ガラスフレーク等)、シリカ、無機繊維(ガラス繊維、アルミナ繊維、カーボン繊維)、黒鉛、珪酸化合物(珪酸カルシウム、珪酸アルミニウム、モンモリロナイト、カオリン、タルク、クレー等)、金属酸化物(酸化鉄、酸化チタン、酸化亜鉛、酸化アンチモン、アルミナ等)、リチウム、カルシウム、マグネシウム、亜鉛等の金属の炭酸塩及び硫酸塩、金属(アルミニウム、鉄、銀、銅等)、水酸化物(水酸化アルミニウム、水酸化マグネシウム等)、硫化物(硫酸バリウム等)、炭化物(木炭、竹炭等)、チタン化物(チタン酸カリウム、チタン酸バリウム等)、有機繊維(芳香族ポリエステル繊維、芳香族ポリアミド繊維、フッ素樹脂繊維、ポリイミド繊維、植物性繊維等)、セルロース類(セルロースミクロフィブリル、酢酸セルロース等)などが挙げられる。これらは1種のみを用いてもよく2種以上を併用してもよい。これらは、造核剤としても利用できる。
耐衝撃樹脂の呈する相構造は限定されないが、下記相構造(1)~(3)を取り得る。
相構造(1):ポリオレフィン樹脂を含んだ連続相(A)と、連続相(A)中に分散された、ポリアミド樹脂及び変性エラストマーを含んだ分散相(B)と、を有する相構造(図10参照)。但し、ポリアミド樹脂を含んだ連続相、及び、この連続相中に分散された分散相、を有する他の相構造は共存されない。
相構造(2):ポリアミド樹脂を含んだ連続相と、この連続相中に分散された、ポリオレフィン樹脂を含んだ分散相と、を有する相構造。但し、ポリオレフィン樹脂を含んだ連続相、及び、この連続相中に分散された分散相、を有する他の相構造は共存されない。
相構造(3):ポリオレフィン樹脂を含んだ連続相(A1)と、連続相(A1)中に分散された、ポリアミド樹脂及び変性エラストマーを含んだ分散相(BA1)と、ポリアミド樹脂を含んだ連続相(A2)と、連続相(A2)中に分散された、変性エラストマーを含んだ分散相(BA2)と、を有する相構造(図11参照)。
これらの相構造のなかでは、相構造(1)又は相構造(3)が好ましく、相構造(1)がより好ましい。
尚、相構造(1)において変性エラストマーは、未反応の変性エラストマーであってもよく、ポリアミド樹脂との反応物であってもよく、これらの混合物であってもよい。
尚、相構造(3)において変性エラストマーは、未反応の変性エラストマーであってもよく、ポリアミド樹脂との反応物であってもよく、これらの混合物であってもよい。
更に、相構造(1)において前述の多重相構造を呈する場合、連続相(B1)は、ポリアミド樹脂を含む。ポリアミド樹脂は連続相(B1)の主成分(連続相B1全体に対し、通常70質量%以上であり、100質量%であってもよい)である。また、微分散相(B2)は、変性エラストマーを含む。変性エラストマーは微分散相(B2)の主成分(微分散相B2全体に対し、通常70質量%以上であり、100質量%であってもよい)である。
更に、相構造(3)において前述の多重相構造を呈する場合、連続相(BA11)は、ポリアミド樹脂を含む。ポリアミド樹脂は連続相(BA11)の主成分(連続相BA11全体に対し、通常70質量%以上であり、100質量%であってもよい)である。また、微分散相(BA12)は、変性エラストマーを含む。変性エラストマーは微分散相(BA12)の主成分(微分散相BA12全体に対し、通常70質量%以上であり、100質量%であってもよい)である。
また、連続相(A2)は、ポリアミド樹脂を含む。ポリアミド樹脂は連続相(A2)の主成分(連続相A2全体に対し、通常70質量%以上であり、100質量%であってもよい)である。また、連続相(A2)に対する分散相(BA2)は、変性エラストマーを含む。変性エラストマーは分散相(BA2)の主成分(分散相BA2全体に対し、通常70質量%以上であり、100質量%であってもよい)である。
尚、耐衝撃樹脂では、変性エラストマーが有する反応性基がポリアミド樹脂に対して反応された反応物となることができる。この場合、反応物は、相構造(1)では、例えば、連続相(A)と分散相(B)との界面、及び/又は、連続相(B1)と微分散相(B2)との界面、に存在できる。同様に、相構造(3)では、例えば、連続相(A1)と連続相(A2)との界面、連続相(A1)と分散相(BA1)との界面、連続相(BA11)と微分散相(BA12)との界面、等に存在できる。
この分散相の分散径は、電子顕微鏡を用いて得られる1000倍以上の拡大画像において測定できる。即ち、画像内の所定の領域内から無作為に選択された20個の分散相の各々の最長径を測定し、得られた最長径の平均値を第1平均値とする。そして、画像内の異なる5つの領域において測定された第1平均値の更なる平均値が、分散相の平均分散径(長軸平均分散径)である。
この微分散相の分散径は、電子顕微鏡を用いて得られる1000倍以上の拡大画像において測定できる。即ち、画像内の所定の領域内から無作為に選択された20個の微分散相の各々の最長径を測定し、得られた最長径の平均値を第1平均値とする。そして、画像内の異なる5つの領域において測定された第1平均値の更なる平均値が、微分散相の平均分散径(長軸平均分散径)である。
耐衝撃樹脂において、ポリオレフィン樹脂とポリアミド樹脂と変性エラストマーとの合計を100質量%とした場合に、ポリオレフィン樹脂の割合は、2質量%以上90質量%以下とすることができる。この割合は、5質量%以上85質量%以下が好ましく、更に10質量%以上83質量%以下が好ましく、更に15質量%以上80質量%以下が好ましく、更に20質量%以上78質量%以下が好ましく、更に25質量%以上75質量%以下が好ましく、更に30質量%以上73質量%以下が好ましく、更に35質量%以上70質量%以下が好ましい。
この耐衝撃樹脂では、高い耐衝撃性又は高い曲げ弾性率を得たり、これらの特性を両立させたりすることができる。例えば、シャルピー衝撃強度は5kJ/m2以上150kJ/m2以下にできる。曲げ弾性率は430MPa以上1500MPa以下にできる。更に、シャルピー衝撃強度は50kJ/m2以上140kJ/m2以下にできる。曲げ弾性率は440MPa以上1300MPa以下にできる。更に、シャルピー衝撃強度は60kJ/m2以上135kJ/m2以下にできる。曲げ弾性率は450MPa以上1250MPa以下にできる。更に、シャルピー衝撃強度は70kJ/m2以上130kJ/m2以下にできる。曲げ弾性率は460MPa以上1200MPa以下にできる。更に、シャルピー衝撃強度は80kJ/m2以上125kJ/m2以下にできる。曲げ弾性率は470MPa以上1100MPa以下にできる。
尚、上記シャルピー衝撃強度の値は、JIS K7111-1に準拠して測定(タイプAノッチ、温度23℃、エッジワイズ試験法)した場合の値である。また、上記曲げ弾性率の値は、JIS K7171に準拠して測定(支点間距離64mm、曲率半径5mmの支点2つで支持、曲率半径5mmの作用点を使用、荷重負荷速度2mm/分)した場合の値である。
また、ポリアミド樹脂と変性エラストマーとの溶融混練温度は限定されないが、例えば、190℃以上350℃以下とすることができ、200℃以上330℃以下が好ましく、205℃以上310℃以下がより好ましい。また、得られた溶融混練物とポリオレフィン樹脂との溶融混練温度は限定されないが、例えば、190℃以上350℃以下とすることができ、200℃以上300℃以下が好ましく、205℃以上260℃以下がより好ましい。
この発泡部は、耐衝撃樹脂を発泡させて得ることができる。そして、耐衝撃樹脂が、前述のように、連続相(A)と分散相(B)とを含んだ相構造を有する場合、気泡は連続相(A)に含まれ、分散相(B)内に含まれないことが好ましい。
本発明のドアトリム(10)(図1参照)は、前述の車両ドア用トリムボード(20)と、車両ドア用トリムボード(20)の意匠面側に敷設された表皮層(15)と、を有することを特徴とする。即ち、ドアトリム(10)の意匠面(10a)を構成するように表皮層(15)を備えることができる。
そして、このドアトリム(10)は、ドアパネル(30)に嵌め込まれることで、全体として車両ドア(1)として機能される。
10;ドアトリム、10a;意匠面、
15;表皮層、
20;車両ドア用トリムボード、20a;意匠面、20b;非意匠面、
21;アッパーボード部、
23;補強部、
24、241、242;他補強部、
25;ロアボード部、
27;アームレストボード部、
30;ドアパネル、
A;連続相、
B;分散相、
B1;連続相(分散相B内の連続相)、
B2;微分散相(分散相B内の分散相)、
A1、A2;連続相、
BA1、BA2;分散相、
BA11;連続相(分散相BA1内の連続相)、
BA12;微分散相(分散相BA1内の分散相)。
Claims (12)
- ポリオレフィン樹脂とポリアミド樹脂と相容化剤と、を含み、
前記相容化剤が、前記ポリアミド樹脂に対する反応性基を有する変性エラストマーである耐衝撃樹脂からなる補強部を有することを特徴とする車両ドア用トリムボード。 - 上下に分割されたアッパーボード部及びロアボード部と、
前記アッパーボード部と前記ロアボード部との間に介在された前記補強部と、を有する請求項1に記載の車両ドア用トリムボード。 - 前記アッパーボード部及び前記ロアボード部は、各々、前記耐衝撃樹脂と異なる他の熱可塑性樹脂を用いた発泡樹脂ボードからなり、
前記アッパーボード部、前記ロアボード部及び前記補強部は、前記他の熱可塑性樹脂と前記耐衝撃樹脂とを用いた一体の多色成形物からなる請求項2に記載の車両ドア用トリムボード。 - 前記アッパーボード部及び前記ロアボード部は、各々、植物繊維と、前記植物繊維を結着する結着樹脂と、を含んだ繊維補強ボードからなり、
前記アッパーボード部、前記ロアボード部及び前記補強部は、前記繊維補強ボードをインサート体とした一体のインサート成形物からなる請求項2に記載の車両ドア用トリムボード。 - 上下に隣り合ったアッパーボード部及びロアボード部と、
少なくとも前記アッパーボード部及び前記ロアボード部を跨いだ境界域の表面を覆う前記補強部と、を有する請求項1に記載の車両ドア用トリムボード。 - 前記アッパーボード部及び前記ロアボード部は、前記耐衝撃樹脂と異なる他の熱可塑性樹脂を用いた一体の発泡樹脂ボードからなり、
前記アッパーボード部、前記ロアボード部及び前記補強部は、前記他の熱可塑性樹脂と前記耐衝撃樹脂とを用いた一体の多色成形物からなる請求項5に記載の車両ドア用トリムボード。 - 前記アッパーボード部及び前記ロアボード部は、植物繊維と、前記植物繊維を結着する結着樹脂と、を含んだ一体の繊維補強ボードからなり、
前記アッパーボード部、前記ロアボード部及び前記補強部は、前記繊維補強ボードをインサート体とした一体のインサート成形物からなる請求項5に記載の車両ドア用トリムボード。 - 前記補強部は、帯状をなし、車両の前後方向に本車両ドア用トリムボードを貫通するように配置されており、
前記ロアボード部は、前記補強部とは異なる少なくとも1条の帯状をなした他補強部を有し、
前記他補強部は、前記耐衝撃樹脂からなるとともに、前記補強部と略平行に配置される請求項1乃至7のうちのいずれかに記載の車両ドア用トリムボード。 - 前記耐衝撃樹脂は、前記ポリオレフィン樹脂を含んだ連続相(A)と、
前記連続相(A)中に分散された分散相であって、前記ポリアミド樹脂及び前記変性エラストマーを含んだ分散相(B)と、を有する請求項1乃至8のうちのいずれかに記載の車両ドア用トリムボード。 - 前記分散相(B)が、前記ポリアミド樹脂を含んだ連続相(B1)と、
前記連続相(B1)中に分散された前記変性エラストマーを含んだ微分散相(B2)と、を有する請求項9に記載の車両ドア用トリムボード。 - 前記変性エラストマーは、エチレン若しくはプロピレンと炭素数3~8のα-オレフィンとの共重合体を骨格としたオレフィン系熱可塑性エラストマーである請求項9又は10に記載の車両ドア用トリムボード。
- 請求項1乃至11のうちのいずれかに記載の車両ドア用トリムボードと、前記車両ドア用トリムボードの意匠面側に敷設された表皮層と、を有することを特徴とするドアトリム。
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Also Published As
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EP3632727A1 (en) | 2020-04-08 |
US11413942B2 (en) | 2022-08-16 |
KR20190130034A (ko) | 2019-11-20 |
EP3632727A4 (en) | 2021-03-10 |
CN110612226B (zh) | 2023-07-28 |
RU2744258C1 (ru) | 2021-03-04 |
CN110612226A (zh) | 2019-12-24 |
US20200079189A1 (en) | 2020-03-12 |
BR112019023787A2 (pt) | 2020-06-02 |
JP7095694B2 (ja) | 2022-07-05 |
SG11201909515SA (en) | 2019-11-28 |
EP3632727B1 (en) | 2023-01-25 |
JPWO2018221388A1 (ja) | 2020-05-21 |
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