WO2018198564A1 - Composition d'agent coiffant - Google Patents

Composition d'agent coiffant Download PDF

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Publication number
WO2018198564A1
WO2018198564A1 PCT/JP2018/010102 JP2018010102W WO2018198564A1 WO 2018198564 A1 WO2018198564 A1 WO 2018198564A1 JP 2018010102 W JP2018010102 W JP 2018010102W WO 2018198564 A1 WO2018198564 A1 WO 2018198564A1
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WO
WIPO (PCT)
Prior art keywords
component
mass
alkyl
monomer
copolymer
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PCT/JP2018/010102
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English (en)
Japanese (ja)
Inventor
藤田範子
橋本佳和
Original Assignee
株式会社マンダム
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Application filed by 株式会社マンダム filed Critical 株式会社マンダム
Priority to KR1020197019179A priority Critical patent/KR102256328B1/ko
Priority to JP2019515141A priority patent/JP6793820B2/ja
Priority to CN201880005895.4A priority patent/CN110167520B/zh
Publication of WO2018198564A1 publication Critical patent/WO2018198564A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A61K8/678—Tocopherol, i.e. vitamin E
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the present invention relates to a hairdressing composition.
  • This application claims the priority of Japanese Patent Application No. 2017-088806 and Japanese Patent Application No. 2017-088807 for which it applied to Japan on April 27, 2017, and uses the content here.
  • a film-forming polymer is generally used as a hair styling main functional base material.
  • a film forming polymer an anionic film forming polymer, a cationic film forming polymer, an amphoteric film forming polymer, a nonionic film forming polymer, or the like is used.
  • various thickeners such as a carboxy vinyl polymer, are mix
  • acrylic anionic film-forming polymers are useful in terms of improving hair styling retention because they have moisture resistance and moderate hardness.
  • a thickener particularly anionic thickener
  • an object of the present invention is to provide a hair styling composition in which a decrease in viscosity over time is suppressed while an acrylic film-forming polymer and a thickener are blended.
  • this invention provides the hairdressing composition containing the following component A, the following component B, the following component C, and the following component D.
  • Component A Phytic acid
  • Component B Acrylic polymer obtained by using the following monomer component B1 and the following monomer component B2 as monomer components
  • Monomer component B1 (meth) acrylic acid alkyl ester
  • Monomer component B2 alkyl acrylamide and / or diacetone acrylamide
  • Component C Thickener
  • D Water
  • Component B includes (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP, and (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP. And (Acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide / hydroxyethyl acrylate) copolymer, preferably at least one selected from the group consisting of AMPs.
  • the component C preferably contains at least one selected from the group consisting of the following component C1, the following component C2, and the following component C3.
  • Component C1 Polymer obtained using at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as the monomer component
  • Component C2 (meth) acrylic acid as the monomer component
  • at least one monomer selected from the group consisting of (meth) acrylic acid alkyl esters and a group selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether, and vinyl neodecanoate
  • Component C3 Carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer
  • the content of component A is 0.01 to 2.0% by mass
  • the content of component B is 0.1 to 15.0% by mass
  • the content of component C is 0.05 to 3%. It is preferably 0.0% by mass.
  • the hairdressing composition of the present invention preferably further contains the following component E.
  • Component E sulfite and / or etidronic acid or a salt thereof
  • the hairdressing composition of the present invention preferably further contains the following component F.
  • Component F Nonionic surfactant
  • the hairdressing composition of the present invention preferably further contains the following component G.
  • Component G Tocopherol acetate and / or edetate
  • the hair styling composition of the present invention has the above-described configuration, thereby suppressing a decrease in viscosity over time. For this reason, it is excellent in formulation stability. Therefore, since the initial viscosity is hardly changed in the container from the time of manufacture to the end of use, a stable quality hairdressing composition can be provided.
  • the hairdressing composition of the present invention contains at least an acrylic polymer obtained by using phytic acid, (meth) acrylic acid alkyl ester, and alkylacrylamide and / or diacetoneacrylamide as monomer components, a thickener, and water.
  • an acrylic polymer obtained by using the above phytic acid as “component A”, the above (meth) acrylic acid alkyl ester, and alkyl acrylamide and / or diacetone acrylamide as monomer components is referred to as “component B”.
  • the thickener may be referred to as “component C”, and the water may be referred to as “component D”.
  • the (meth) acrylic acid alkyl ester may be referred to as “monomer component B1”
  • the alkylacrylamide and / or diacetone acrylamide may be referred to as “monomer component B2”.
  • the hairdressing composition of the present invention preferably contains sulfite and / or etidronic acid or a salt thereof. Moreover, it is preferable that the hairdressing composition of this invention contains a nonionic surfactant. Moreover, it is preferable that the hairdressing composition of this invention contains tocopherol acetate and / or edetate.
  • component E the above sulfite and / or etidronic acid or a salt thereof
  • component F nonionic surfactant
  • the tocopherol acetate and / or edetate is referred to as “component G”.
  • the hairdressing composition of the present invention includes at least Component A, Component B, Component C, and Component D.
  • the hairdressing composition of the present invention preferably further contains Component E, Component F, and Component G. Other components may be included.
  • each component contained in the hairdressing composition of the present invention for example, component A, component B, component C, component D, component E, component F, component G, and other components, each has only one type. It may be used and 2 or more types may be used.
  • Component A is phytic acid, which is a compound represented by “Physic Acid” under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 16th edition, Volume 2, 2016, p. 2724).
  • Component A can be a commercially available product.
  • the brand name "Phytic acid” by the Tsukino Rice Fine Chemicals company is mentioned, for example.
  • the content of component A in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.01 to 2.0% by mass, more preferably 0.02 to 1.0% by mass. is there. It is preferable for the content to be 0.01% by mass or more because the effect of suppressing a decrease in viscosity over time is further improved. On the other hand, when the content exceeds 2.0% by mass, component A may inhibit the thickening effect of component C.
  • Component B Acrylic polymer obtained using monomer component B1 and monomer component B2 as monomer components
  • Component B is an acrylic polymer obtained using (meth) acrylic acid alkyl ester (monomer component B1) and alkyl acrylamide and / or diacetone acrylamide (monomer component B2) as monomer components. That is, Component B is a polymer containing a structural unit derived from (meth) acrylic acid alkyl ester (monomer component B1) and a structural unit derived from alkylacrylamide and / or diacetone acrylamide (monomer component B2).
  • Component B functions as a component that forms a film and imparts hair-styling power.
  • (meth) acrylic acid means one or both of acrylic acid and methacrylic acid.
  • component B only 1 type may be used and 2 or more types may be used.
  • sodium salt of component B hereinafter abbreviated as Na
  • ammonium salt triethanolamine salt
  • 2-amino-2-methyl-1-propanol salt hereinafter abbreviated as AMP
  • 2-amino-2-methyl-1,3-propanediol salt hereinafter abbreviated as AMPD.
  • component B examples include (alkyl acrylate / diacetone acrylamide) copolymer [INCI name: AMP-ACRYLATES / DIACETONACRYLAMIDE COPOLYMER], (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP.
  • Component B can be a commercially available product.
  • Commercially available products of (alkyl acrylate / diacetone acrylamide) copolymers include, for example, trade name “Plus Size L-6345U”, trade name “Plus Size L-53”, (Acrylates / alkyl acrylate (C1-18) /
  • Commercially available products of alkyl (C1-8) acrylamide) copolymer AMP include, for example, trade names “Plus Size L-9909U”, “Plus Size L-9909B”, Trade Name “Plus Size L-9715”, Trade Name “Plus”.
  • Size L-6740B alkyl acrylate / diacetone acrylamide copolymer AMP
  • Commercially available products of “Size L-6740B” (alkyl acrylate / diacetone acrylamide) copolymer AMP include, for example, trade name “Plus Size L-6330”, trade name “Plus Size L-6466”, (Acrylates / Acrylic Acid Alkyl (C1-18) / alkyl (C1-8) acrylic Examples of commercially available phagemid / hydroxyethyl acrylate) copolymer AMP, for example, trade name "Plus Size L-9700” (GOO CHEMICAL none Co., Ltd.).
  • the content of component B in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.1 to 15.0% by mass, more preferably 0.2 to 5.0% by mass. is there. It is preferable that the content is 0.1% by mass or more because the hair styling power is further improved. If the content exceeds 15.0% by mass, the stability of the preparation may be lowered, or flaking may occur after hair styling.
  • Content of the said component B is content of the sum total of all the components B in the hairdressing composition of this invention.
  • Component C is a thickener and has an effect of mainly thickening the system. For this reason, the hairdressing composition of the present invention is thickened, for example, when it is used by picking up the composition, it has a gel-like or grease-like property / dosage form that is difficult to sag and has excellent handleability. be able to. As for component C, only 1 type may be used and 2 or more types may be used.
  • Component C is not particularly limited as long as it is usually used in hairdressing composition, but for example, natural polymer thickeners such as xanthan gum, guar gum, carrageenan, locust bean gum; methylcellulose, ethylcellulose, hydroxymethylcellulose, hydroxy Examples thereof include cellulose thickeners such as ethyl cellulose, hydroxypropylmethylcellulose, carboxymethylcellulose; acrylic thickeners such as carboxyvinyl polymer. Among these, acrylic thickeners are preferable from the viewpoint of transparency and low luster.
  • Component C contains at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters as monomer components from the viewpoint of improving formulation stability and spreadability on hair.
  • Polymer (component C1) obtained by using, as a monomer component, at least one monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, and polyoxyethylene alkyl (meth) acrylate
  • a polymer (component C2) obtained using at least one monomer selected from the group consisting of ether, polyoxyethylene alkyl ethers of itaconic acid, and vinyl neodecanoate, and a carboxyvinyl polymer and / or an alkyl-modified carboxyvinyl polymer Selected from the group consisting of (component C3) Preferably contains at least one.
  • the monomer component used to obtain the polymer of component C1 includes at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters. That is, the component C1 is a polymer including at least two or more structural units selected from the group consisting of a structural unit derived from (meth) acrylic acid and a structural unit derived from (meth) acrylic acid alkyl ester. In the present specification, the polymer that can correspond to both the component C1 and the component C2 is not the component C1 but the component C2.
  • the component C1 may be a commercially available product.
  • commercially available products of component C1 include trade name “Aculin 33”, trade name “Aculin 33A” (both manufactured by Dow Chemical Co.); trade name “SepiMAX ZEN” (manufactured by SEPPIC).
  • the monomer component used to obtain the polymer of component C2 is at least one monomer component C2a selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, and (meth) acrylic acid poly And at least one monomer component C2b selected from the group consisting of oxyethylene alkyl ether, polyoxyethylene alkyl ether itaconic acid, and vinyl neodecanoate. That is, the component C2 is a polymer including at least a structural unit derived from the monomer component C2a and a structural unit derived from the monomer component C2b. As for the monomer component C2a and the monomer component C2b, only one type may be used, or two or more types may be used.
  • INCI name International Cosmetic Ingredient Dictionary and Handbook, the 16th edition, the 1st volume, 2016, p.76
  • CIRYLATES / STEARETH-20 METHACRYLATEC International Cosmetic Ingredient Dictionary and Handbook, 16th Edition, Volume 1, 2016, p.76
  • Accel Relay / ACRYLATES / BEHENETH-25 METHACLA under the INCI name International Cosmetic Ingredient Dictionary and Handbook, 16th edition, Volume 1, 2016, p. 65.
  • Component C2 may be a commercially available product.
  • Commercially available products of component C2 include, for example, trade name “Aculin 22”, trade name “Aculin 88”, trade name “Aculin 28”, trade name “Aculin 38” (all manufactured by Dow Chemical Co., Ltd.); trade name “STRUCTURE” 2001 ”, trade name“ STRUCTURE 3001 ”(all manufactured by Axon Nobel Co., Ltd.), and the like.
  • Component C3 is a carboxyvinyl polymer and / or an alkyl-modified carboxyvinyl polymer.
  • the carboxyvinyl polymer is mainly a polymer of acrylic acid
  • the alkyl-modified carboxyvinyl polymer is a copolymer of mainly acrylic acid and alkyl methacrylate (preferably alkyl has 10 to 30 carbon atoms).
  • Examples of the alkyl-modified carboxyvinyl polymer include (acrylates / alkyl acrylate (C10-30)) crosspolymer.
  • component C3 only 1 type may be used and 2 or more types may be used.
  • Component C3 may be a commercially available product.
  • Examples of commercially available products of carboxyvinyl polymer include a trade name “Carbopol 934”, a trade name “Carbopol 940”, a trade name “Carbopol 941”, a trade name “Carbopol 980”, and a trade name “Carbopol 981”.
  • alkyl-modified carboxyvinyl polymer examples include, for example, trade name “PEMULEN TR-1”, trade name “PEMULEN TR-2”, trade name “Carbopol ETD 2020”, trade name “Carbopol ULTREZ 20” (any As well as Nippon Lubrizol Co., Ltd.).
  • the component C is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance.
  • the basic substance include alkanolamines such as triethanolamine and monoethanolamine; inorganic basic compounds such as ammonia, sodium hydroxide and potassium hydroxide; basic amino acids such as arginine.
  • the addition amount of the basic substance is an amount that becomes a sufficiently neutralized component C, or an amount sufficient to neutralize the component C, and the component C and the basic substance are added. What is necessary is just to mix
  • the content of Component C in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.05 to 3.0% by mass, more preferably 0.1 to 2.0% by mass. is there. It is preferable for the content to be 0.05% by mass or more because the hairdressing composition is sufficiently thickened and the storage stability and coatability are further improved. It is preferable for the content to be 3.0% by mass or less because the formulation stability and the stickiness-inhibiting effect are further improved.
  • Content of the said component C is content of the sum total of all the components C in the hairdressing composition of this invention.
  • Component D Water
  • the component D is water.
  • Component D is not particularly limited, but purified water is preferred.
  • Ingredient D has the effect of providing a refreshing feel with no oiliness when using the hairdressing composition of the present invention as an aqueous composition such as a gel or a grease, and improving the spreadability.
  • the content of component D in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 20.0 to 95.0% by mass, more preferably 50.0 to 90.0% by mass. .
  • Component E Sulfite and / or Etidronic acid or salt thereof
  • the component E is sulfite and / or etidronic acid or a salt thereof.
  • Component E exhibits the effect of further improving the decrease in viscosity over time of the hairdressing composition. Furthermore, the effect of further suppressing changes in color tone and odor over time is exhibited. In particular, it is preferable because the effect of suppressing color tone change is high.
  • the sulfite include sodium sulfite, sodium hydrogen sulfite, and anhydrous sodium sulfite.
  • the salt of etidronic acid include sodium salt.
  • the content of component E in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.005 to 1.0% by mass, more preferably 0.01 to 0.5% by mass. is there. It is preferable for the content to be 0.005% by mass or more because the effect of suppressing the decrease in viscosity over time is further improved. Moreover, since the change of the color tone and odor of the hairdressing composition of this invention is suppressed further, it is preferable. When the said content exceeds 1.0 mass%, formulation stability may fall or an odor may arise.
  • Content of the said component E is content of the sum total of all the components E in the hairdressing composition of this invention.
  • Component F Nonionic surfactant
  • the component F is a nonionic surfactant.
  • Component F functions as a hair styling component of the hair styling composition. It has been found that hairdressing composition containing component F generally tends to cause a decrease in viscosity over time. On the other hand, since the component A acts and suppresses the decrease in the viscosity, the effect of the present invention is more easily exhibited in the system including the component F.
  • the arranging power of the hairdressing composition force to bend the hair in an arbitrary direction
  • wash-off properties are improved.
  • component F only 1 type may be used and 2 or more types may be used.
  • component F examples include glycerin fatty acid ester, polyglycerin fatty acid ester, ethylene oxide condensate of glycerin fatty acid ester, polyethylene glycol fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, ethylene oxide condensate of sorbitan fatty acid ester, polyoxy Examples include alkylene alkyl ethers, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene lanolin and the like.
  • glyceryl monocaprylate glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate
  • Glyceryl fatty acid esters such as glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl diarachiate
  • diglyceryl monocaprylate decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, Hexaglyceryl monolaurate, decaglyceryl monolaurate, poly (4-10) glyceryl monolaurate, monomyris Decaglyceryl acid, decag
  • Component F is preferably polyoxyethylene hydrogenated castor oil or polyoxyalkylene alkyl ether (particularly polyoxyethylene alkyl ether) from the viewpoint of excellent effect of imparting hair-styling power. Particularly preferred is polyoxyethylene hydrogenated castor oil.
  • the hairdressing composition containing the component F is not particularly limited, and examples thereof include a polyoxyethylene hydrogenated castor oil component having an average addition mole number of oxyethylene of 45 to 65 (sometimes referred to as “component F1”) and A hair styling composition comprising polyoxyethylene hydrogenated castor oil (sometimes referred to as “component F2”) having an average addition mole number of oxyethylene of 75 to 125 (sometimes referred to as “hair conditioning composition of specific embodiment 1”). There is).
  • the hair styling composition of the specific aspect 1 has the property of forming a hair bundle by the above-described configuration, raising the hair bundle from the roots while being able to be sufficiently eliminated, and maintaining the hairstyle for a long time.
  • Component F preferably contains polyoxyethylene hydrogenated castor oil (may be referred to as “Component F3”) having an average addition mole number of oxyethylene of 5 or more and less than 45, in addition to Component F1 and Component F2.
  • Component F3 polyoxyethylene hydrogenated castor oil
  • the hairdressing composition of the present invention contains the component F3 in addition to the components F1 and F2 as the component F, it is more excellent in facilitating the fading. Note that only one type of each of the components F1 to F3 may be used, or two or more types may be used.
  • the average number of moles of oxyethylene added in the component F1 is 45 to 65, preferably 50 to 60. Further, the average number of moles of oxyethylene added in the component F2 is 75 to 125, preferably 80 to 120. In addition, the average added mole number of oxyethylene in the component F3 is 5 or more and less than 45, preferably 10 to 40.
  • component F1 Commercially available products of component F1, for example, trade name “Brownon RCW-50”, trade name “Brownon RCW-60” (all manufactured by Aoki Oil & Fat Co., Ltd.), trade name “EMALEX HC-50”, trade name “EMALEX HC-60”, trade name “EMALEX RWIS-150”, trade name “EMALEX RWIS-350”, trade name “EMALEX RWIS-360” (all manufactured by Nippon Emulsion Co., Ltd.), and the like.
  • component F2 Commercially available products of component F2 include, for example, trade name “Brownon RCW-80”, trade name “Brownon RCW-100”, trade name “Brownon CW-100” (all manufactured by Aoki Oil & Fat Co., Ltd.), trade name “EMALEX HC-80”, trade name “EMALEX HC-100” (all manufactured by Nippon Emulsion Co., Ltd.) and the like can be mentioned.
  • component F3 Commercially available products of component F3 include, for example, trade name “Brownon RCW-20”, trade name “Brownon RCW-40”, trade name “Brownon CW-10”, trade name “Brownon CW-25”, trade name “Brownon”.
  • the mass ratio of the content of the component F1 to the total content of the component F1 and the component F2 [F1 / (F1 + F2)] From the viewpoint of the characteristics of starting up from the root, the formability of the hair bundle, and the characteristics of maintaining the hairstyle for a long time, 0.1 to 0.9 is preferable, more preferably 0.2 to 0.8, and still more preferably 0. .25 to 0.5.
  • the content of the component F1 is the total content of all the components F1 in the hairdressing composition of the present invention
  • the content of the component F2 is the hairdressing composition of the present invention. It is the total content of all the components F2 in the product.
  • the total content of the component F1 and the component F2 in the component F is not particularly limited, but it is easy to wear, the property of starting up the hair bundle from the root, the formability of the hair bundle, and maintaining the hairstyle for a long time. From the viewpoint of characteristics and the like, 50.0% by mass or more (for example, 50.0 to 100% by mass) is preferable with respect to 100% by mass of Component F, more preferably 70.0% by mass or more, and further preferably 80.0% by mass. % Or more.
  • the total content of the component F1 and the component F2 in the hairdressing composition of the present invention is not particularly limited, but is easy to apply, characteristics of starting up the hair bundle from the root, formability of the hair bundle, and hairstyle From the standpoint of the property of maintaining the hair for a long time, the amount is preferably 3.0 to 25.0% by weight, more preferably 5.0 to 20.0% by weight with respect to 100% by weight of the hairdressing composition of the present invention. More preferably, it is 6.0 to 15.0% by mass. When the content is within the above range, it is excellent in ease of squeezing, the property of raising the hair bundle from the root, the formability of a fine hair bundle, and the property of maintaining the hairstyle for a long time.
  • the total content of component F3 in the hairdressing composition of the present invention is not particularly limited, but from the viewpoint of further improving the ease of squeezing, it is based on 100% by mass of the hairdressing composition of the present invention. 0.5 to 10.0 mass% is preferable, and 0.8 to 5.0 mass% is more preferable. .
  • the content of component F in the hairdressing composition of the present invention is not particularly limited, but it is easy to wear, the property of starting up the hair bundle from the root, the formability of the hair bundle, and the hairstyle is maintained for a long time. From the viewpoint of properties and the like, the amount is preferably 3.0 to 30.0% by mass, more preferably 4.0 to 25.0% by mass, and still more preferably 6. It is 0 to 20.0% by mass.
  • Content of the said component F is content of the sum total of all the components F in the hairdressing composition of this invention.
  • Component G Tocopherol acetate and / or edetate
  • the component G is tocopherol acetate and / or edetate.
  • Component G exerts an effect of further suppressing the decrease in viscosity over time of the hairdressing composition. In addition, it exhibits the effect of further suppressing changes in color tone and odor over time.
  • the edetate include disodium edetate and tetrasodium edetate.
  • the content of component G in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.01 to 2.0% by mass, more preferably 0.05 to 1.0% by mass. is there. It is preferable for the content to be 0.01% by mass or more because the effect of suppressing a decrease in viscosity over time is further improved. Moreover, since the change of the color tone and odor of the hairdressing composition of this invention is suppressed further, it is preferable. When the content exceeds 2.0% by mass, the solubility may be lowered, or the thickening effect of Component C may be inhibited.
  • Content of the said component G is content of the sum total of all the components E in the hairdressing composition of this invention.
  • the hairdressing composition of the present invention may contain components other than components A to G (other components) within a range not impairing the effects of the present invention.
  • the other components are not particularly limited, and examples include components usually used for cosmetics and quasi drugs.
  • surfactants other than component F anionic surfactants, cationic surfactants, amphoteric surfactants
  • lower alcohols such as ethanol
  • Oil components such as oils, waxes, vegetable oils, hydrocarbon waxes, hydrocarbon oils, fats and oils, higher fatty acids, fragrances, ultraviolet absorbers, antioxidants, sequestering agents, powders such as silica, pigments, pigments, dyes; Vitamins; Amino acids; Astringents; Whitening agents; Animal and plant extracts; pH adjusters; Preservatives; Solvents;
  • the properties of the hairdressing composition of the present invention are not particularly limited, but gels and greases are preferred from the viewpoint of being easy to sag from the hand and excellent in handleability when picked up by hand and applied to hair. That is, the hair styling composition of the present invention is preferably a gel-like hair styling composition or a grease-like hair styling composition (referred to as hair grease, water grease, water-soluble pomade, etc.).
  • the method for producing the hairdressing composition of the present invention is not particularly limited, and a known method for producing a hairdressing composition can be used.
  • Examples of the method for producing the hairdressing composition of the present invention include a method of stirring and homogenizing each component with a disper mixer, a paddle mixer or the like.
  • the hair styling composition of the present invention is not particularly limited, but can be used, for example, in a form filled in a container.
  • the container include a bottle container, a jar container, and a tube container.
  • a bottle container, a tube container or a jar container is preferred, and when the hairdressing composition of the present invention is in a grease form A jar is preferred.
  • the viscosity and consistency of the hairdressing composition of the present invention are not particularly limited, for example, in the case of the hairdressing composition of the specific embodiment 1, when it is picked up and applied to the hair, it is difficult to sag from the hand.
  • the viscosity (25 ° C.) is preferably 5000 mPa ⁇ s or more.
  • the “viscosity (25 ° C.)” can be measured at 25 ° C. using a Brookfield rotary viscometer, for example.
  • the consistency (25 ° C.) is preferably 50 gf or less, more preferably 30 gf or less, from the viewpoint of easy scooping and easy handling when the container is scooped with a finger.
  • the “consistency (25 ° C.)” can be measured, for example, using a consistency meter equipped with a 17 ⁇ flat adapter at 25 ° C., a speed of 60 mm / min, and a stroke of 20 mm.
  • Examples of the consistency meter include trade name “RHEO METER” manufactured by Sun Kagaku Co., Ltd.
  • the hairdressing composition of the present invention contains at least Component A, Component B, Component C, and Component D.
  • the hair styling composition of the present invention is an aqueous hair styling composition containing component D, and solves the problem of a decrease in viscosity over time due to blending of both component B and component C by blending of component A. In addition, a stable viscosity is maintained. That is, formulation stabilization of a hairdressing composition containing component B, component C, and component D that could not be sufficiently suppressed with conventional sodium edetate alone can be achieved by blending component A. .
  • the hair-styling composition of this invention is an aqueous hair-styling composition containing the component D, compared with an oil-based hair-styling composition, there is no oily feeling and the refreshing feeling of use is obtained.
  • the hair styling composition of the present invention preferably further contains Component E, Component F, and Component G.
  • component E and component G exhibits the effect of further improving the action of component A to suppress a decrease in viscosity over time.
  • action which suppresses the change of a color tone or an odor is exhibited.
  • the hairdressing composition of the present invention can provide a stable quality hairdressing composition with excellent usability because the initial viscosity is hardly lowered in the container from the time of manufacture to the end of use. .
  • the compounding amount shown in the table is the compounding amount of each component (that is, the compounding amount of the active ingredient (so-called pure component) in the raw material), and is expressed in “mass%” unless otherwise specified.
  • Component A Phytic acid: Product name “Phytic acid” manufactured by Tsukino Rice Fine Chemicals Co., Ltd.
  • [Component B] (Alkyl acrylate / diacetone acrylamide) copolymer: manufactured by Kyoyo Chemical Industry Co., Ltd., trade name “Plus Size L-6345U” (Acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP: manufactured by Kyoyo Chemical Industry Co., Ltd., trade name “Plus Size L-9909B” (Acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide / hydroxyethyl acrylate) copolymer AMP: manufactured by Kyoyo Chemical Industry Co., Ltd., trade name “Plus Size L-9700”
  • Carboxy vinyl polymer Nippon Lubrizol Co., Ltd., trade name “Carbopol 940” Alkyl-modified carboxyvinyl polymer: manufactured by Nippon Lubrizol Co., Ltd., trade name “Carbopol ETD 2020”, (acrylates / alkyl acrylate (C10-30)) crosspolymer (acrylates / Beheneth methacrylate-25) Copolymer: Dow Chemical Product name "Aculin 28" (Acrylates / Stearless Methacrylate-20) Copolymer: manufactured by Dow Chemical Company, trade name “Aculin 22” Hydroxypropyl methylcellulose: Shin-Etsu Chemical Co., Ltd., trade name “Metrozu 60SH-4000” Xanthan gum: DSP Gokyo Food & Chemical Co., Ltd., trade name "Echo Gum T”
  • each hairdressing composition was prepared.
  • the properties of the hairdressing composition obtained in Examples 1 to 12 and Comparative Examples 1 to 3 were all gel-like.
  • Consistency (25 ° C.) was measured using a consistency meter equipped with a 17 ⁇ flat adapter [trade name “RHEO METER” manufactured by Sun Kagaku Co., Ltd.] under the conditions of 25 ° C., speed 60 mm / min, and stroke 20 mm. did.
  • the hair conditioner compositions of Examples 1 to 12 had a [Consistency at 40 ° C. storage sample (25 ° C.) / 5 ° C. storage sample consistency (25 ° C.)] of 0.87 or more.
  • the hairdressing composition of Comparative Examples 1 to 3 had a [Consistency at 40 ° C. storage sample (25 ° C.) / 5 ° C.
  • the hair styling composition containing component A (Examples 1 to 12) sufficiently suppressed the decrease in viscosity over time, whereas the hair styling composition containing no component A (Comparative Example) In 1 to 3), a decrease in viscosity was observed.
  • component G and component E were blended instead of component A, but these components alone may not be sufficient to suppress the decrease in viscosity over time of the hairdressing composition of the present invention. Indicated.
  • the following is a formulation example of the hairdressing composition of the present invention.
  • the present invention relates to a hair styling composition used for a hair styling agent for shaping hair.
  • the hair styling composition of the present invention is preferably a gel-like hair styling composition or a grease-like hair styling composition (referred to as hair grease, water grease, water-soluble pomade, etc.).

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  • Inorganic Chemistry (AREA)
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Abstract

La présente invention concerne une composition d'agent coiffant dans laquelle une réduction de la viscosité dans le temps est inhibée tout en contenant un polymère filmogène acrylique et un agent épaississant. Ladite composition d'agent coiffant contient les composants A, B, C et D suivants : composant A, acide phytique ; composant B, un polymère acrylique obtenu à l'aide des composants monomères B1 et B2 en tant que composants monomères (composant monomère B1, un ester d'alkyl(méth)acrylate, et composant monomère B2, un alkylacrylamide et/ou un diacétone acrylamide) ; composant C, un agent épaississant ; et composant D, de l'eau.
PCT/JP2018/010102 2017-04-27 2018-03-15 Composition d'agent coiffant WO2018198564A1 (fr)

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CN201880005895.4A CN110167520B (zh) 2017-04-27 2018-03-15 整发剂组合物

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021186993A1 (fr) * 2020-03-19 2021-09-23 株式会社マンダム Composition d'agent de coiffure

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010111594A (ja) * 2008-11-04 2010-05-20 Shiseido Co Ltd 整髪化粧料
JP2011251930A (ja) * 2010-06-01 2011-12-15 Nakano Seiyaku Kk スタイリング化粧料
JP2014114264A (ja) * 2012-12-12 2014-06-26 Kao Corp 毛髪化粧料

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0348611A (ja) 1989-07-14 1991-03-01 Sunstar Inc 透明ゲル状整髪化粧料
US5384061A (en) * 1993-12-23 1995-01-24 The Procter & Gamble Co. Stable thickened aqueous cleaning composition containing a chlorine bleach and phytic acid
JP3453645B2 (ja) 1996-09-13 2003-10-06 株式会社コーセー 透明ゲル状整髪料
JP3917352B2 (ja) * 2000-02-25 2007-05-23 株式会社資生堂 整髪料
JP2002087943A (ja) * 2000-09-12 2002-03-27 Arimino Kagaku Kk 頭髪化粧料及び頭髪処理法
JP5112928B2 (ja) * 2008-03-28 2013-01-09 株式会社コーセー 整髪料組成物
JP5363761B2 (ja) 2008-05-30 2013-12-11 中野製薬株式会社 毛髪化粧料
JP5536356B2 (ja) * 2009-03-26 2014-07-02 株式会社コーセー 油性固形状毛髪化粧料
JPWO2014065303A1 (ja) * 2012-10-23 2016-09-08 ロート製薬株式会社 皮膚外用組成物
CN105007887B (zh) * 2013-03-29 2018-08-31 株式会社漫丹 整发剂组合物
CN105792803A (zh) * 2014-03-28 2016-07-20 株式会社漫丹 整发剂组合物
WO2015174130A1 (fr) * 2014-05-16 2015-11-19 株式会社マンダム Composition de coiffure
JP6530237B2 (ja) * 2015-05-22 2019-06-12 株式会社マンダム 整髪剤組成物
JP6518152B2 (ja) * 2015-07-07 2019-05-22 株式会社マンダム 整髪剤組成物及び整髪剤組成物の製造方法
JP6662547B2 (ja) * 2016-05-20 2020-03-11 株式会社マンダム 整髪剤組成物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010111594A (ja) * 2008-11-04 2010-05-20 Shiseido Co Ltd 整髪化粧料
JP2011251930A (ja) * 2010-06-01 2011-12-15 Nakano Seiyaku Kk スタイリング化粧料
JP2014114264A (ja) * 2012-12-12 2014-06-26 Kao Corp 毛髪化粧料

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021186993A1 (fr) * 2020-03-19 2021-09-23 株式会社マンダム Composition d'agent de coiffure
JPWO2021186993A1 (fr) * 2020-03-19 2021-09-23

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KR102226577B1 (ko) 2021-03-11
KR20190091498A (ko) 2019-08-06
JP6793820B2 (ja) 2020-12-02
CN110167520B (zh) 2022-05-03
CN110177538A (zh) 2019-08-27
WO2018198563A1 (fr) 2018-11-01
JP6784834B2 (ja) 2020-11-11
CN110167520A (zh) 2019-08-23
KR102256328B1 (ko) 2021-05-26
KR20190091315A (ko) 2019-08-05
CN110177538B (zh) 2022-08-26
JPWO2018198563A1 (ja) 2019-11-07
JPWO2018198564A1 (ja) 2019-11-07

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