WO2018097698A1 - 글리세릴라우레이트를 포함하는 피부 미백용 화장료 조성물 - Google Patents
글리세릴라우레이트를 포함하는 피부 미백용 화장료 조성물 Download PDFInfo
- Publication number
- WO2018097698A1 WO2018097698A1 PCT/KR2017/013703 KR2017013703W WO2018097698A1 WO 2018097698 A1 WO2018097698 A1 WO 2018097698A1 KR 2017013703 W KR2017013703 W KR 2017013703W WO 2018097698 A1 WO2018097698 A1 WO 2018097698A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- skin
- cosmetic composition
- whitening
- skin whitening
- glyceryl laurate
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/68—Sphingolipids, e.g. ceramides, cerebrosides, gangliosides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Definitions
- Cosmetic composition for skin whitening comprising glyceryl laurate
- 'It is defined as a product that helps to burn skin finely or protect skin from UV rays.
- the industry is launching whitening products that improve skin tone.
- Whitening means to brighten and whiten the skin and to whiten the skin
- Whitening is aimed at improving skin whiteness, which basically suppresses melanin production and prevents skin from darkening; removes melanin that has already been produced to make it clear.
- 'Whitening in order to use the word in the product not apply Notification raw recognized food and drug safety destination of the Republic of Korea on the product or: to develop a new whitening ingredients and apply them to the products: go through the sikyak cheoui authentication whitening It can be labeled as a functional cosmetic.
- the whitening ingredients recognized by our country are:
- Brightening is meant to brighten dull and dark skin and is used when there is a whitening effect that brightens skin tone. It can be defined as a whitening effect, tone-up, or complexion improvement. have.
- Glyceryl laurate is a vegetable supplement emulsifier, binder,
- Skin Emulsifiers Surfactants-Emulsifiers, known to have low bactericidal properties. It is mainly used to supply oil to bath products.
- the present inventors have described a cosmetic composition comprising glyceryl laurate.
- the present invention was completed by confirming that the composition containing glyceryl laurate of the present invention exhibits a skin: whitening effect.
- Japanese Patent Application Laid-Open No. 2015-3888 discloses an external skin preparation containing a polyglycerol fatty acid ester, but it is a whitening ingredient.
- Glyceryl laurate (a type of polyglycerin fatty acid ester) for invention and skin whitening has different effects.
- No. 2011-0036683 describes glyceryl laurate as an antimicrobial agent, and the skin lightening effect of the present invention is not mentioned or described at all.
- the object of the present invention is a skin comprising glyceryl laurate
- the present invention relates to a skin whitening cosmetic composition
- a skin whitening cosmetic composition comprising glyceryl laurate as an active ingredient.
- the glomeroselaurate may be included in an amount of 0.0005-5% by weight based on the total weight of the cosmetic composition for skin whitening.
- the skin whitening cosmetic composition further comprises a cationic phospholipid surfactant
- the cationic phospholipid surfactant may be contained in an amount of 0.01 wt% based on the total amount of the cosmetic composition for skin whitening.
- the cationic phospholipid surfactant is an antibacterial product of skin whitening cosmetic herb.
- the cationic phospholipid surfactant may be selected from Cocofiji-dimonium chloride.
- the skin whitening cosmetic composition is glycerin, hexylene glycol, butylene: glycol, butyl glycol, propylene glycol, hexanediol and octanediol It may further include one or more selected from the group consisting of). :
- the cosmetic composition includes lotion, skin softener, skin toner, paragraph,
- the present invention for kkoebu containing glyceryl GW Wu rate as the active ingredient whitening relates to a cosmetic composition.
- the whitening refers to whitening the skin, and to whiten the skin.
- brightening is meant to lighten dark skin, and may also be defined as tone-up, complexion improvement, and the like.
- the glyceryl laurate is used for skin whitening, especially for improving skin brightness.
- the glyceryl laurate is glycerin and lauric
- the glyceryl laurate may be synthesized or synthesized according to a conventional method.
- Glyceryl laurate is more than 90% pure form
- the glyceryl laurate is based on the total weight of the cosmetic composition for skin whitening
- 0.0005-5% by weight may be included. Preferably it is 0.001-0.5% by weight. If the content of the glyceryl laurate is less than 0.0005% by weight or more than 5% by weight, the skin lightening effect is weak or hardly visible.
- the skin whitening cosmetic composition may further contain a cationic phospholipid surfactant to increase antibacterial activity, and the cationic phospholipid surfactant may be sodium: cocopiji-dimonium chloride phosphate, Linoleamidopropyl sebum-dimonium chloride phosphate,
- It may be at least one member selected from the group consisting of myristamidopropyl sebum-dimonium chloride phosphate.
- myristamidopropyl sebum-dimonium chloride phosphate Preferably, it is, but not limited to, sodium cocopiji-dimonium chloride phosphate.
- the cationic phospholipid surfactant may be included in an amount of 0.01 to 1 wt ⁇ 3 ⁇ 4 based on the total weight of the skin whitening cosmetic composition. If the content of the cationic phospholipid surfactant is less than 0.01 weight «3 ⁇ 4, the cosmetic composition for skin whitening The bactericidal power of this product does not meet the standard of use, and even if it exceeds 1% by weight, there is no big difference in antibacterial activity.
- the skin whitening cosmetic composition may be added at least one member selected from the group consisting of glycerin, nuxylene glycol, butylene glycol, propylene; glycol, dinucleic acid and octane diol.
- the above glycerin, nuylene glycol, butylene glycol, propylene glycol, dinucleic acid diol and octane diol can be used to increase the solubility of glyceryl laurate.
- the skin whitening cosmetic composition may be prepared as a concentrate.
- At least one selected from the group consisting of propylene glycol, dinucleic acid diol and octane diol could be used as a solvent instead of purified water, and may be used in combination with tablets.
- the skin and whitening cosmetic composition prepared by using glycoserine, nuxylene glycol, butylene glycol, propylene glycol, dinucleic acid diol and octane diol as a solvent instead of purified water does not irritate the skin.
- the concentrate can be used by diluting with purified water.
- the dilution may be diluted 1 to 1000 times based on the total amount of dilution, but this may depend on the judgment of the person in charge.
- the skin whitening cosmetic composition may be prepared by including an additional additive.
- the additive may be a moisturizer, a functional material, a thickener, a softener, an emulsifier, a surfactant, and a pH adjuster.
- the moisturizing agent may include, but is not limited to, glycerol, propylene glycol, butylene glycol, pentylene glycol, propane, dipropane, hyaluronic acid, and ceramide.
- the thickener may be a polymer, xanthan gum or guar gum, but is not limited thereto.
- the softener may include, but is not limited to, mineral oil, shea butter, and paraffin.
- the emulsifier may be dimethicone, beeswax, or the like.
- the skin lightening composition may be used in combination with the whitening material.
- the whitening raw material is the extract of the bark, arbutin, ethyl ascorbyl ether, solubility: licorice extract, ascorbyl glucoside, niacinamide, cx-visabo ( ⁇ -bisabolol) and
- the cosmetic composition includes lotion, skin softener, skin toner, paragraph,
- the pack may be a mask pack, and the sheets used in the mask pack may be cotton, rayon, polyester, viscose rayon, nylon, poly 3 ⁇ 4 lofolene, polyester, tencel, acrylic, vinylon, and casein.
- One or more fibers selected from the group consisting of glass fibers, filfils, hydrogels and virocells can be used.
- Impregnated in the sheet When manufacturing the mask pack: Impregnated in the sheet .
- the amount of saturation in the composition can be from 20 g to 40 g. ::
- the present invention is for skin whitening containing glyceryl laurate.
- glyceryl laurate of the present invention is excellent in whitening effect.
- FIG. 1 shows the results of confirming the effect of increasing the skin brightness of the skin whitening cosmetic composition of the present invention.
- FIG. 2 shows the results of confirming the change in skin brightness according to the present invention and the skin whitening cosmetic composition over time.
- glycol glycol
- Example 2-1 50 48
- Example 2-2 50 48
- Example 2-3 50
- Example 2-4 50
- Example 2 ⁇ 5 50 48
- Example 2-6 50
- Example 2-7 50
- Example 2-8 50
- Example 2-9 50
- Example 2-10 50
- Example 2 ⁇ U 50 Example 2-12 50
- Example 2-i3 50 40 Example 2 One M 50 49
- Comparative Example 1-1 0.0005 99.9995 Comparative Example ' 1-2 0,000 5 99.9995 Comparative Example 1-3 1 99 Comparative Example 1-4. 0.1 99.9 Comparative Example 1-5 0.1 99.9 Comparative Example 1-6 0,1 99.9 Comparison Example 1-7 0.1 99.9 Verification Example 1-8. .0.0005 0.1 99.8995 Comparative Example 1—9 1 0.1 98.9 Ratio: Comparative Example 1-10 1 0.1 98.9 Ratio: Comparative Example 1-1.1 .0.0005 0.1 99.8995 Comparative Example 1-12 1 0.1 98.9 Ratio ⁇ : Example.
- the solubility of each component of the cosmetic composition is important:
- Example 1 of the present invention the skin composition of the skin whitening cosmetic composition of Example 1, excepting Examples 1-45, was prepared It was confirmed that all were dissolved and transparent, and no precipitate was formed.
- Examples 1-3, 1-9, 1-10, 1-12, 1-14, 2-1, and 2-2 are glyceryl laurate or glycerol. It was observed that the yl monolaurate did not completely dissolve and became opaque and precipitated out over time.
- Example 1-45 Comparative Example 1-3, 1-9, 1-10, 1-12, 1-14, using purified water as a solvent in a cosmetic composition containing 1% by weight or more of glyceryl monolaurate 2-1 and In the case of 2-2, it was observed that the glyceryl laurate or glyceryl monolaurate was not completely dissolved but opaque and precipitated out over time. On the other hand, the content of glyceryl laurate or glyceryl monolaurate was observed. In the cosmetic composition of Examples 2-1 to 2-16 using glycols in the cosmetic composition containing 1% by weight or more, both glyceryl laurate or glyceryl monolaurate is dissolved. It was confirmed that it was transparent without being precipitated.
- Glyceryl monolaurate was observed to dissolve and no skin irritation was observed. . .
- Glycols can be used to increase the solubility of glyceryl laurate or glyceryl monolaurate without irritating the skin when preparing cosmetic compositions containing
- Example 1 A skin whitening cosmetic composition of Example 1 and Comparative Example 1 as rayon
- Mask packs were prepared by impregnating the configured mask pack sheets.
- Example 1 In order to confirm the effect of the skin whitening composition of Example 1 and Comparative Example 1 on the skin whitening cosmetic composition, the degree of skin braning, that is, the improvement of skin brightness was checked.
- the skin lightness improvement was measured using Konica miolita before and after the mask pack manufactured in Experimental Example 2-1 using Konica miolita, and using Equation 1 below: Before and after mask pack sheet was attached. Skin lightness increase rate was calculated.
- Skin Brightness Growth Rate ((Skin Brightness after Pack / Skin Brightness before Pack) xlOO OO [84] The skin brightness of the investigator's arm was measured before attaching the mask pack impregnated with the whitening cosmetic composition. The mask pack was attached and removed for 15 minutes.
- compositions for skin whitening of the present invention such as the cut shown in £ 1 (Examples 1-1, 1-9, 2-10), negative control, positive control and comparative example 1- Contrast with 19: the skin brightness was remarkably increased. :
- the skin whitening cosmetic material of the present invention composition (Examples 1-2, 1-5, 1-9) in the case of the impregnated mask pack, the skin brightness increase rate gradually increased and then increased to about 10 minutes.
- the skin whitening cosmetic composition Comparative Examples 1-4, Comparative Examples 1-16
- the purified water negative control
- the application of a mask pack impregnated with the skin whitening cosmetic composition of the present invention resulted in an increase in the brightness of the skin compared to the currently available whitening mask packs used as a positive control.
- the skin whitening cosmetic composition of the present invention is impregnated with the glyceryl laurate which is included as an active ingredient in the skinmer bag cosmetic composition of the present invention.
- the mask pack it was confirmed that there was no significant difference in the skin brightness increase before and after the mask pack was attached or lower than the positive control group, which can show the effect of increasing the brightness of the skin when the glycerin content is low.
- Example 2-1 to Example 2-16 and Comparative Example 2-1 to Comparative Example 2-25 were passed through 100% of purified water passed through an exchange resin.
- Table 7 the results are shown in Table 7 below.
- the dilution used had a high skin brightness increase because it was included in the appropriate range having a significant skin whitening effect and the glyceryl laurate content.
- the skin brightening effect of the whitening cosmetic composition was very good.
- the effect of the whitening cosmetic composition was affected by the content and solubility of glycerol rilaurate. ;
- the anti-microbial activity of the cosmetics is important as well as the skin improvement effect of the cosmetics, and the cosmetic products further include antimicrobial agents.
- the skin whitening cosmetic composition of Examples 1 and 1 The antibacterial activity was confirmed. :. ::
- the antibacterial activity test was performed according to the American Cosmetic Industry Association Sl (CTFA): Standard. Specifically, experiments were carried out by a plate culture method to confirm the reduction and mortality of the bacteria. As bacteria: antibacterial activity was confirmed by dividing bacteria and fungi.
- bacteria bacteria 10 6 CFU /, fungi 10 5 CFU / m £
- Examples 1-1 to Examples 1-46 and Comparative Examples 1-1 to Comparative Examples 1- 25 is the cosmetic composition, and the cosmetic composition of Examples 2-1 to 2-2 and Comparative Examples 2-25 to Comparative Example 2-25 was used 100 times of distilled water in the purified water passed through the ion exchange resin.
- Skin whitening cosmetic composition untreated bacterial mixture: The solution was used. After each culture was incubated, the plated medium was counted and the colony number of the produced bacteria was counted. The mortality of the bacteria was calculated using the results, as shown in Table 8.
- the criteria for the killing rate of bacteria for use in cosmetic compositions is 99.9% or more, and less than 99.9% is not suitable for application to cosmetic compositions.
- glyceryl laurate or the like of Examples 1-1, i-1, 1-4 and 1-5 in the skin whitening cosmetic composition of the present invention As shown in Table 8, glyceryl laurate or the like of Examples 1-1, i-1, 1-4 and 1-5 in the skin whitening cosmetic composition of the present invention.
- glyceryl monolaurate is Hwajeong "medical composition, which is also respectively 0.001% by weight or 0.02% by weight saturable, the antibacterial activity against fungi and bacteria did not have a death rate based on the bacterium for use as a cosmetic composition, carried out As in Example 1-3 and Example 1-6, when 0.5 weight% of glyceryl laurate or glyceryl monolaurate was contained, it was confirmed that antibacterial activity is 99.9% or more.
- Example 1-45 which contains 1% by weight of glyceryl laurate
- the killing of bacteria for use as a cosmetic composition for antibacterial activity against bacteria and fungi It was confirmed that it does not meet the rate standard, and it is expected that 1% by weight of glyceryl laurate did not dissolve properly in purified water, thereby affecting antibacterial activity.
- a cationic phospholipid surfactant in a cosmetic composition containing only glyceryl laurate or glyceryl monolaurate as in the cosmetic composition of Examples 1-6
- the antibacterial activity of the skin whitening cosmetic composition of 1-7 to Examples 1-44 and Examples 1-46 was 99.9% or more.
- the amount of cationic phospholipid surfactant was less than 0.
- the antibacterial activity was less than 99.9% and there was no significant difference in the antibacterial activity even if it exceeds 1% by weight.
- the skin whitening cosmetic composition containing the glyceryl laurate of the present invention has not only a whitening effect but also an antibacterial activity, so that it is not only applicable to the whitening cosmetic product but also added for the preservation of the cosmetic product. It was found that the amount of antimicrobial agents included could be reduced.
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Abstract
Description
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Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201780045569.1A CN109496148B (zh) | 2016-11-28 | 2017-11-28 | 含有甘油月桂酸酯的皮肤美白化妆品组合物 |
JP2019524107A JP2019525959A (ja) | 2016-11-28 | 2017-11-28 | ラウリン酸グリセリルを含む皮膚美白用化粧料組成物 |
Applications Claiming Priority (4)
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KR20160159144 | 2016-11-28 | ||
KR10-2016-0159144 | 2016-11-28 | ||
KR1020170058638A KR101824424B1 (ko) | 2016-11-28 | 2017-05-11 | 글리세릴라우레이트를 포함하는 피부 미백용 화장료 조성물 |
KR10-2017-0058638 | 2017-05-11 |
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WO2018097698A1 true WO2018097698A1 (ko) | 2018-05-31 |
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PCT/KR2017/013703 WO2018097698A1 (ko) | 2016-11-28 | 2017-11-28 | 글리세릴라우레이트를 포함하는 피부 미백용 화장료 조성물 |
Country Status (4)
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JP (1) | JP2019525959A (ko) |
KR (1) | KR101824424B1 (ko) |
CN (1) | CN109496148B (ko) |
WO (1) | WO2018097698A1 (ko) |
Families Citing this family (2)
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KR102026364B1 (ko) | 2018-05-11 | 2019-11-04 | 주식회사 네이처인랩 | 꽃봉오리 추출물을 포함하는 화장료 조성물 및 이의 제조방법 |
CN110623853B (zh) * | 2019-07-29 | 2022-09-09 | 德亚生物科技有限公司 | 一种清洁护理组合物及其制备方法 |
Citations (5)
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JP2004331592A (ja) * | 2003-05-08 | 2004-11-25 | National Institute Of Advanced Industrial & Technology | 美白剤を配合した皮膚外用剤、石鹸、入浴剤、繊維処理剤、繊維 |
WO2007091694A1 (en) * | 2006-02-06 | 2007-08-16 | Showa Denko K.K. | Whitening dermatological preparations |
CN103705391A (zh) * | 2013-12-16 | 2014-04-09 | 浙江赞宇科技股份有限公司 | 一种天然去痘印去黑头美白嫩肤温和洗面膏及其制备方法 |
JP2015003888A (ja) * | 2013-06-24 | 2015-01-08 | ポーラ化成工業株式会社 | 皮膚外用剤 |
JP2016150900A (ja) * | 2015-02-16 | 2016-08-22 | アサヒフードアンドヘルスケア株式会社 | メラニン産生抑制用の皮膚外用剤 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004026657A (ja) * | 2002-06-21 | 2004-01-29 | Pola Chem Ind Inc | 美白用の化粧料 |
JP2007056009A (ja) * | 2005-07-27 | 2007-03-08 | Showa Denko Kk | 乳化皮膚外用剤および該皮膚外用剤の安定化方法 |
JP4326512B2 (ja) * | 2005-08-29 | 2009-09-09 | 日光ケミカルズ株式会社 | 美白剤及びこれを含有する美白化粧料 |
CN104940118A (zh) * | 2015-06-20 | 2015-09-30 | 青岛克立克信息技术有限公司 | 一种祛斑晚霜 |
-
2017
- 2017-05-11 KR KR1020170058638A patent/KR101824424B1/ko active IP Right Grant
- 2017-11-28 WO PCT/KR2017/013703 patent/WO2018097698A1/ko active Application Filing
- 2017-11-28 JP JP2019524107A patent/JP2019525959A/ja active Pending
- 2017-11-28 CN CN201780045569.1A patent/CN109496148B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004331592A (ja) * | 2003-05-08 | 2004-11-25 | National Institute Of Advanced Industrial & Technology | 美白剤を配合した皮膚外用剤、石鹸、入浴剤、繊維処理剤、繊維 |
WO2007091694A1 (en) * | 2006-02-06 | 2007-08-16 | Showa Denko K.K. | Whitening dermatological preparations |
JP2015003888A (ja) * | 2013-06-24 | 2015-01-08 | ポーラ化成工業株式会社 | 皮膚外用剤 |
CN103705391A (zh) * | 2013-12-16 | 2014-04-09 | 浙江赞宇科技股份有限公司 | 一种天然去痘印去黑头美白嫩肤温和洗面膏及其制备方法 |
JP2016150900A (ja) * | 2015-02-16 | 2016-08-22 | アサヒフードアンドヘルスケア株式会社 | メラニン産生抑制用の皮膚外用剤 |
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Publication number | Publication date |
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KR101824424B1 (ko) | 2018-02-01 |
CN109496148B (zh) | 2021-09-17 |
JP2019525959A (ja) | 2019-09-12 |
CN109496148A (zh) | 2019-03-19 |
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