WO2017163449A1 - 触媒反応器及びこれを備えた船舶 - Google Patents
触媒反応器及びこれを備えた船舶 Download PDFInfo
- Publication number
- WO2017163449A1 WO2017163449A1 PCT/JP2016/074512 JP2016074512W WO2017163449A1 WO 2017163449 A1 WO2017163449 A1 WO 2017163449A1 JP 2016074512 W JP2016074512 W JP 2016074512W WO 2017163449 A1 WO2017163449 A1 WO 2017163449A1
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- WIPO (PCT)
- Prior art keywords
- catalyst
- opening
- frame
- cassette
- cassettes
- Prior art date
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/88—Handling or mounting catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8631—Processes characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9431—Processes characterised by a specific device
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/011—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more purifying devices arranged in parallel
- F01N13/017—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more purifying devices arranged in parallel the purifying devices are arranged in a single housing
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2842—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2878—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration by using non-elastic means for retaining catalyst body in the housing, e.g. a metal chamfer, or by corrugation or deformation of the metal housing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2067—Urea
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4566—Gas separation or purification devices adapted for specific applications for use in transportation means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/02—Fitting monolithic blocks into the housing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/30—Removable or rechangeable blocks or cartridges, e.g. for filters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2590/00—Exhaust or silencing apparatus adapted to particular use, e.g. for military applications, airplanes, submarines
- F01N2590/02—Exhaust or silencing apparatus adapted to particular use, e.g. for military applications, airplanes, submarines for marine vessels or naval applications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the present invention relates to a catalytic reactor and a ship equipped with the same.
- a wedge-shaped member is inserted into the gap between the catalyst cassette and the catalyst cassette inserted so as to be adjacent to each other from the opening of the catalyst reactor.
- Some catalyst cassettes are fixed inside a catalyst reactor by energizing a catalyst cassette inserted by a lid member that closes the portion (see Patent Document 1).
- the wedge-shaped member is supported by the housing via a connecting member provided at the other end.
- the connecting member is a substantially rod-like member and is configured to be extendable and contractable by a screw mechanism. By operating the screw mechanism of the connecting member, the wedge effect of the wedge-shaped member is increased and each catalyst cassette is firmly fixed.
- an object of the present invention is to provide a catalyst reactor capable of easily fixing a plurality of catalyst cassettes to the catalyst reactor in the catalyst reactor of the present invention and a ship equipped with the catalyst reactor.
- the catalyst reactor of the present invention is a catalyst reactor comprising an opening provided on one side surface and a plurality of catalyst cassettes charged in a state adjacent to each other toward the side surface facing from the opening.
- a fixing member that is biased by a lid member that closes the opening and presses the upper surfaces of the plurality of catalyst cassettes is provided, and the fixing member is disposed along a side surface facing the opening. is there.
- the catalyst cassette includes a catalyst part that reduces NOx in the exhaust, and an outer peripheral part configured by a frame that covers a side surface of the catalyst part, and the fixing member is It is preferable that it is disposed between adjacent catalyst cassettes among the plurality of catalyst cassettes and on the outer peripheral portion.
- a filler is provided between the adjacent catalyst cassettes along the side surface facing from the opening.
- the ship of the present invention includes the catalytic reactor.
- a plurality of catalyst cassettes can be easily fixed to the catalyst reactor.
- (B) It is a partial enlarged view which shows adjustment of the protrusion part of a pressing member. It is a perspective view which shows arrangement
- (A) It is a perspective view of the lattice frame comprised so that division
- (b) It is a side view of the lattice frame comprised so that division
- upstream side indicates the upstream side in the exhaust flow direction
- downstream side indicates the downstream side in the exhaust flow direction
- width direction refers to the catalyst reactor 12 in the left-right direction as viewed from one side where the opening is provided
- depth direction refers to the catalyst reactor 12 provided with the opening. This refers to the front-rear direction when viewed from one side.
- the ship 100 includes a hull 101, a cabin 102 provided on the stern side of the hull 101, a funnel 103 disposed at the rear of the cabin 102, and a propeller 104 and a rudder 105 provided at the lower rear of the hull 101.
- a skeg 107 is integrally formed on the stern side ship bottom 106.
- a propeller shaft 108 that rotationally drives the propeller 104 is supported on the skeg 107.
- a hold 109 is provided on the bow side and in the center of the hull 101.
- An engine room 110 is provided on the stern side in the hull 101.
- a main engine 111 diesel engine in this embodiment
- a speed reducer 112 which are driving sources of the propeller 104
- a power generator 113 for supplying electric power to the electrical system in the hull 101 are arranged.
- the propeller 104 is rotationally driven by the rotational power from the main engine 111 via the speed reducer 112.
- the interior of the engine room 110 is divided up and down by an upper deck 114, a second deck 115, a third deck 116, and an inner bottom plate 117.
- the main engine 111 and the speed reducer 112 are installed on the inner bottom plate 117 at the lowest stage of the engine room 110, and the power generator is installed on the third deck 116 at the middle stage of the engine room 110.
- the power generation apparatus is configured by combining an engine 31 and a generator 33 that generates power by driving the engine 31.
- the exhaust emission control device 1 will be described with reference to FIGS. 3 and 4.
- the exhaust purification device 1 purifies exhaust exhausted from the engine 31 that is a power source of the generator 33 and the like.
- the exhaust purification device 1 is provided in an exhaust pipe 11 connected to the engine 31.
- the exhaust pipe 11 extends to the funnel 103 and communicates directly with the outside.
- the exhaust purification device 1 includes a urea water injection nozzle 2, a urea supply channel 3, an air supply channel 4, a pressurized air valve 5, an air tank 6, a pressurized air supply pump (compressor) 7, a switching valve 8, and urea water supply.
- a pump 9, a urea water tank 10, a catalytic reactor 12, a control device 30 and the like are provided.
- the urea water injection nozzle 2 supplies urea water into the exhaust pipe 11 or the catalytic reactor 12.
- the urea water injection nozzle 2 is formed of a tubular member, and is provided so that one side (downstream side) thereof is inserted from the outside of the exhaust pipe 11 or the catalytic reactor 12 into the inside.
- a urea supply flow path 3 that is a flow path of urea water is connected to the urea water injection nozzle 2.
- the urea water injection nozzle 2 is connected to an air supply flow path 4 that is a flow path of pressurized air.
- the pressurized air valve 5 communicates or blocks the flow path of the pressurized air.
- the pressurized air valve 5 is provided in the air supply flow path 4.
- the pressurized air valve 5 is composed of an electromagnetic valve, and a solenoid is connected to the control device 30.
- the pressurized air valve 5 is configured to be able to supply pressurized air pressurized to the air tank 6 by a pressurized air supply pump (compressor) 7 to the urea water injection nozzle 2 by sliding a spool (not shown).
- the switching valve 8 switches the urea water flow path.
- the switching valve 8 is provided on the downstream side of the urea water supply pump 9 in the air supply flow path 4.
- the switching valve 8 is configured such that the urea water in the urea water tank 10 can be supplied to the urea water injection nozzle 2 by the urea water supply pump 9 by sliding a spool (not shown).
- the catalytic reactor 12 is for reducing exhaust (NOx in the exhaust) by a NOx catalyst arranged inside.
- the catalytic reactor 12 is provided in the middle of the exhaust pipe 11 connected to the engine 31 and downstream of the urea water injection nozzle 2.
- a plurality of catalyst cassettes in which a NOx catalyst is incorporated in a metal frame are arranged inside the casing 13 of the catalyst reactor 12.
- Control device 30 controls pressurized air valve 5, switching valve 8, urea water supply pump 9, and the like.
- the control device 30 stores various programs and data for controlling the pressurized air valve 5, the switching valve 8, the urea water supply pump 9, and the like.
- the control device 30 may be configured such that a CPU, a ROM, a RAM, an HDD, and the like are connected by a bus, or may be configured by a one-chip LSI or the like.
- the control device 30 can also be configured integrally with an ECU that controls the engine 31.
- the control device 30 controls the pressurized air valve 5, the switching valve 8, the urea water supply pump 9, and the like to inject urea water into the exhaust pipe 11.
- Ammonia is generated from the urea water injected by the heat of the exhaust.
- the exhaust purification apparatus 1 reduces NOx to nitrogen and water by the NOx catalyst incorporated in each catalyst cassette of the ammonia and catalytic reactor 12.
- the catalyst reactor 12 includes a housing 13, a catalyst cassette that reduces exhaust from the engine 31, a support frame that supports the catalyst cassette in the housing 13, a fixing member 34 that fixes the catalyst cassette, and the like.
- the housing 13 is made of a heat-resistant metal material and is formed in a substantially cylindrical shape (in this embodiment, a rectangular tube shape).
- An exhaust pipe 11 is connected to one end of the casing 13, and the other end of the casing 13 is open to the outside through the exhaust pipe 11. That is, the housing 13 is configured as an exhaust passage through which exhaust from the engine 31 flows from one side (upstream side) to the other side (downstream side) (see the black arrow in FIG. 4).
- the exhaust pipe 11 is provided with exhaust pipe switching valves 42 and 43 for switching the branch pipe 41 and the exhaust passage route upstream of the urea water injection nozzle 2.
- the branch pipe 41 is connected to the exhaust pipe 11.
- the exhaust gas switching valve 42 is disposed inside the exhaust pipe 11 upstream of the urea water injection nozzle 2 and downstream of the branch pipe 41.
- the exhaust gas switching valve 43 is disposed inside the branch pipe 41.
- the exhaust gas switching valves 42 and 43 are configured to be able to open and close in conjunction with each other. Specifically, the exhaust gas switching valves 42 and 43 close the exhaust gas switching valve 43 when the exhaust gas switching valve 42 is open, and open the exhaust gas switching valve 43 when the exhaust gas switching valve 42 is closed. It is configured to be. Thereby, when the exhaust gas switching valve 42 is in the open state and the exhaust gas switching valve 43 is in the closed state, the exhaust pipe 11 forms a path through which the exhaust gas is supplied to the main flow path 32a described later. On the other hand, when the exhaust gas switching valve 42 is closed and the exhaust gas switching valve 43 is open, the exhaust pipe 11 forms a path through which exhaust gas is supplied to a bypass flow path 32b described later.
- the exhaust flow path of the housing 13 is formed as a main flow path 32a for purifying the exhaust gas by reducing NOx in the exhaust gas by a partition plate 13c extending along the exhaust movement direction, and an exhaust passage path. And a bypass channel 32b that exhausts the exhaust gas without purifying the exhaust gas.
- the partition plate 13c is provided so as to face a lid member that closes an opening described later.
- an opening used for installation, replacement, repair, etc. of the catalyst cassette is provided on one side of the housing 13, an opening used for installation, replacement, repair, etc. of the catalyst cassette is provided.
- a first opening 13a and a second opening 13b are formed in order from the upstream side on one side surface of the housing 13 constituting the main flow path 32a.
- the opening is configured to be closed by a lid member.
- the first opening 13 a is configured to be closed by the first lid member 26, and the second opening 13 b is configured to be closed by the second lid member 27.
- the catalyst cassette is constituted by a catalyst part constituted by a NOx catalyst that reduces exhaust gas, and a metal frame that covers side faces other than the side face through which the through hole of the NOx catalyst is open And an outer peripheral portion.
- the NOx catalyst is formed by producing a material containing a metal such as alumina, zirconia, vanadia / titania or zeolite into a substantially rectangular parallelepiped having a large number of lattice-shaped through holes.
- the catalyst cassette includes a plurality of first catalyst cassettes 14 that are inserted through the first openings 13a and a plurality of second catalyst cassettes 15 that are inserted through the second openings 13b.
- the first catalyst cassette 14 includes a catalyst part 14a constituted by a NOx catalyst and an outer peripheral part 14b constituted by a metal frame covering a side face other than the side face where the through hole of the NOx catalyst is opened.
- the second catalyst cassette 15 is configured by a catalyst portion 15a configured by a NOx catalyst and an outer peripheral portion 15b configured by a metal frame that covers a side surface other than the side surface where the through hole of the NOx catalyst is open.
- the catalyst portions 14a and 15a are formed in a substantially rectangular parallelepiped shape, and the outer peripheral portions 14b and 15b are formed in a substantially rectangular tube shape so as to surround the catalyst portions 14a and 15a.
- Each catalyst cassette is arranged so that the axial direction of the through hole of the NOx catalyst coincides with the flow direction of the exhaust (see the black arrows in FIGS. 5 and 6). That is, each catalyst cassette is arranged so that the side surface not covered with the frame faces the flow of exhaust gas. Therefore, after the exhaust gas passes through the first catalyst cassette 14 mounted on the first grid frame 18 described later, the catalyst reactor 12 passes the second catalyst cassette 15 mounted on the second grid frame 21 described later on. It is configured to pass through and be discharged from the housing 13.
- a support frame for supporting the catalyst cassette is provided in the main flow path 32 a of the housing 13.
- the support frame is provided in a space surrounded by the housing 13 and the partition plate 13c.
- the support frame is disposed in the vicinity of the lower edge of the opening, and has a lattice frame on which a plurality of catalyst cassettes inserted through the opening are placed, and a wall that extends downstream from the outer frame of the lattice frame. It is comprised by.
- the wall portion is fixed in close contact with the inner surface of the housing 13 and the partition plate 13c.
- the lattice frame is fixed to the housing 13 via the stay 16.
- the support frame includes a first support frame 17 that supports the plurality of first catalyst cassettes 14 that are inserted through the first opening 13a, and a plurality of second catalysts that are inserted through the second opening 13b. And a second support frame 20 that supports the cassette 15.
- the first support frame 17 is configured by a first lattice frame 18 on which a plurality of first catalyst cassettes 14 are placed, and a first wall portion 19 extending from the outer frame of the first lattice frame 18 toward the downstream side.
- the second support frame 20 includes a second lattice frame 21 on which the plurality of second catalyst cassettes 15 are placed, and a second wall portion 22 that extends from the outer frame of the second lattice frame 21 toward the downstream side.
- the lattice frame is formed in a lattice shape by a plurality of inflow holes through which exhaust flows into the catalyst portions of the catalyst cassettes and frame portions constituting the inflow holes.
- the first lattice frame 18 includes a plurality of first inflow holes 18a and a first frame portion 18b.
- the second lattice frame 21 includes a plurality of second inflow holes 21a and a second frame portion 21b.
- the 1st inflow hole 18a and the 2nd inflow hole 21a are formed in a substantially rectangular shape according to the shape of catalyst part 14a * 15a.
- the first frame portion 18b and the second frame portion 21b are formed as a substantially rectangular frame so as to surround the first inflow hole 18a and the second inflow hole 21a formed in a substantially rectangular shape.
- the outer peripheral portion of the catalyst cassette is configured to fit in the frame portion constituting the lattice frame as viewed from the exhaust flow direction. That is, each catalyst cassette can be arranged in each frame portion.
- the outer peripheral portions 14b and 15b are formed in a substantially square shape when viewed from the flow direction of the exhaust gas.
- the first frame portion 18b and the second frame portion 21b are also formed in a substantially square shape when viewed from the exhaust flow direction.
- the maximum length of the outer peripheral portions 14b and 15b of the catalyst cassette is formed to be smaller than the maximum length of the first frame portion 18b and the second frame portion 21b, so that the outer peripheral portion of the catalyst cassette fits in the frame portion. Composed.
- the maximum length of the outer peripheral portions 14b and 15b here refers to the longest side among the sides constituting the opening surface of the outer peripheral portion. When the cross section of the outer peripheral portion in the flow direction of the exhaust is circular, it indicates the major axis. Similarly, the maximum length of the first frame portion 18b and the second frame portion 21b refers to the longest side among the sides constituting the frame portion. When the cross section of the frame portion in the exhaust flow direction is circular, it indicates the major axis.
- the plurality of catalyst cassettes are charged so as to be adjacent to the opposite side surface from the opening.
- a total of nine catalyst cassettes with three rows in the width direction and three rows in the depth direction as viewed from the opening side are arranged in the lattice frame.
- a total of nine inflow holes are formed in the lattice frame, with three rows in the width direction and three rows in the depth direction.
- the number of catalyst cassettes is not limited to this, and is configured based on the size of the exhaust purification device 1. For example, it is possible to arrange four rows in the width direction and four rows in the depth direction.
- Each catalyst cassette is arranged with the side surfaces covered with the frame next to each other.
- the catalyst cassettes adjacent in the width direction are provided with a predetermined interval A (see FIG. 5).
- a filler 23 (see FIG. 10) is provided along the side surface facing from the opening.
- the filler 23 is a plate-like member made of a heat insulating material such as glass wool, and is provided so as to close the predetermined interval A, thereby preventing the exhaust gas from flowing into the downstream side via the predetermined interval A. .
- the movement of the adjacent catalyst cassettes in the width direction with respect to the support frame is restricted by closing the gap between the adjacent catalyst cassettes.
- the catalyst cassettes adjacent in the depth direction are provided with a predetermined interval B (see FIG. 5).
- a filler 24 (see FIG. 10) is provided along the width direction when viewed from the opening side.
- the filler 24 is a plate-like member made of a heat insulating material such as glass wool, and is provided across a plurality of catalyst cassettes adjacent in the width direction.
- each catalyst cassette can be arranged in each frame so that a heavy catalyst cassette can be loaded, replaced, repaired, etc. in the catalyst reactor 12. It is not necessary to move the catalyst cassettes simultaneously, and the catalyst cassettes can be arranged individually. Therefore, the catalyst cassette can be easily arranged, and the installation workability of the catalyst cassette is improved.
- the number of lattice frames provided in the catalyst reactor 12 and the number of catalyst cassettes placed on the lattice frames are not limited to the present embodiment.
- the arrangement of the catalyst cassette can be easily changed according to the degree of deterioration of the catalyst cassette that changes depending on the arrangement position of the catalyst cassette on the lattice frame. Therefore, it can be expected to extend the life of the catalyst portion of the catalyst cassette.
- the strength of the housing 13 can be increased by providing a separate support frame in the housing 13. Therefore, by providing the support frame having the lattice frame, it is possible to increase the strength of the housing 13 and improve the installation workability of the catalyst cassette.
- support frames that support a plurality of catalyst cassettes are provided at least on the upstream side and the downstream side inside the casing 13 that constitutes the catalyst reactor 12.
- the first catalyst cassette 14 provided on the first support frame 17 (first grid frame 18) on the side is compared with the second catalyst cassette 15 provided on the second support frame 20 (second grid frame 21) on the downstream side.
- the support frame is configured by a first support frame 17 provided on the upstream side and a second support frame 20 provided on the downstream side.
- the weight of each catalyst cassette can be reduced, so that the installation workability of the catalyst cassette is improved.
- the first catalyst cassette 14 provided on the upstream side is easily deteriorated and the replacement frequency is high because the exhaust gas containing a large amount of NOx passes through the first catalyst cassette 14 provided on the downstream side. Therefore, the first catalyst cassette 14 provided on the upstream side is configured to be shorter in the exhaust flow direction than the second catalyst cassette 15 provided on the downstream side, so that the first catalyst cassette 14 that is easily deteriorated is configured at low cost. And the replacement cost can be reduced.
- the fixing member 34 will be described with reference to FIGS. As shown in FIGS. 8 and 9, the fixing member 34 is disposed along the side surface facing the opening, and is energized by a lid member that closes the opening, so that a plurality of catalyst cassettes are placed on the upper surface thereof. It is what is pressed from.
- the fixing member 34 is energized by a plate-like member 35 extending along the side surface facing the opening from the upper surface of the plurality of catalyst cassettes, and the plate-like member 35 by being biased by a lid member that closes the opening. And a pressing member 36 that presses one end.
- a plate-like member 35 extending along the side surface facing the opening from the upper surface of the plurality of catalyst cassettes, and the plate-like member 35 by being biased by a lid member that closes the opening.
- a pressing member 36 that presses one end.
- the plate member 35 is a substantially rectangular parallelepiped member extending from one side to the other side.
- the upper surface (downstream side surface) on one side and the other side of the plate-like member 35 is provided with a gradient portion 35a that is inclined toward the end portion.
- the length in the longitudinal direction of the plate-like member 35 is set approximately as the length from the first opening 13a to the opposing side surface (partition plate 13c).
- the gradient portion 35a at the end of the plate-like member 35 on the partition plate 13c side is provided so as to be fitted to a receiving portion 37 provided on the partition plate 13c.
- the plate-like member 35 is disposed so as to cover the space between the first catalyst cassettes 14 adjacent in the width direction among the first catalyst cassettes 14 inserted through the first opening 13a. Specifically, a plate is placed between the adjacent first catalyst cassettes 14 and not overlapping the catalyst part 14a of the first catalyst cassette 14 when viewed from the exhaust flow direction, that is, on the outer peripheral part 14b of the first catalyst cassette 14.
- the shaped member 35 is disposed (see FIG. 10).
- the pressing member 36 is provided at one end of the plate-like member 35 on the first opening 13a side.
- the pressing member 36 is pressed from the first opening 13a side by attaching the first lid member to the first opening 13a.
- the pressing member 36 is formed in a substantially rectangular parallelepiped shape, and the lower surface (upstream side surface) thereof has a gradient portion 36a.
- the gradient portion 36 a of the pressing member 36 is configured to be in contact with the gradient portion 35 a of the plate member 35 by being configured at substantially the same inclination angle as the gradient portion 35 a of the plate member 35.
- the gradient portion 36a of the pressing member 36 is set so that an appropriate pressing force is generated on the gradient portion 35a of the plate-like member 35 by contacting the gradient portion 35a of the plate-like member 35 at an appropriate position.
- the pressing member 36 is provided with a protruding portion toward the first opening 13 a.
- the protruding portion is constituted by a pin 36b and a washer 36c attached to the pressing member 36.
- the pin 36b has a head formed in a disk shape.
- a hole is provided in the side surface of the first opening 13a of the pressing member 36, and the protrusion is configured by attaching a pin 36b to the hole via a washer 36c.
- the protrusion length of the protrusion can be adjusted by adjusting the number of washers 36c.
- the slope portion 36a of the pressing member 36 can be brought into contact with the slope portion 35a of the plate-like member 35 at an appropriate position.
- the pressing member 36 is restricted from moving in the downstream direction with respect to the gradient portion 35a of the plate-like member 35 by the upper wall constituting the first opening 13a. Therefore, even if it is urged by the first lid member 26, the pressing member 36 does not exceed an appropriate position with the gradient portion 35 a of the plate-like member 35, and can abut at an appropriate position.
- the head of the pin 36 b that constitutes the protruding portion of the pressing member 36 is pressed by the first lid member 26.
- a pressing force is generated on the contact surface of the plate-like member 35 by the pressed pressing member 36.
- a component force in a direction parallel to the longitudinal direction of the plate member 35 and a component force in a direction perpendicular to the plate member 35 are applied to the contact surface of the plate member 35.
- the plurality of first catalyst cassettes 14 provided across the fixing member 34 are pressed against the first support frame 17 by the applied component force, thereby being fixed to the first support frame 17.
- the catalyst cassette and the catalyst cassette adjacent in the width direction can be fixed to the catalyst reactor 12 by the fixing member 34.
- the procedure for loading the first catalyst cassette 14 into the first support frame 17 will be described with reference to FIG. Note that the procedure for loading the second catalyst cassette 15 into the second support frame 21 is the same, and is omitted.
- the first catalyst cassette 14 is placed in the farthest row as viewed from the first opening 13a side by crane or human power.
- Fillers 23 are inserted into the upper and lower ends of the gap between the first catalyst cassette 14 and the first catalyst cassette 14, respectively.
- a guide 23 a is attached to the filler 23 to facilitate insertion into the gap between the first catalyst cassette 14 and the first catalyst cassette 14.
- Two fillers 24 are attached by adhesive spray so as to straddle a plurality of adjacent first catalyst cassettes 14 on the side surface of the first opening 13a of the arranged first catalyst cassette 14.
- the filler 24 is attached avoiding the upper end and the lower end so as not to hit the guide portion 23a of the filler 23 inserted in the gap between the first catalyst cassette 14 and the first catalyst cassette 14 adjacent in the width direction. It is done.
- the filler material 23 is inserted and the filler material 24 is attached.
- a plurality of plate-like members 35 are arranged in the gap between the first catalyst cassette 14 and the first catalyst cassette 14 adjacent in the width direction and along the side surface (partition plate 13c) facing the first opening 13a. To do. The end of each plate-like member 35 on the partition plate 13c side is fitted to each receiving portion 37 attached to the partition plate 13c. At the end of each plate-like member 35 on the first opening 13a side, a pressing member 36 that adjusts the protruding length of the protruding portion is disposed, and the first lid member 26 is attached to the first opening 13a.
- the first catalyst cassette 14 can be fixed to the catalyst reactor 12.
- the plate-like member 35 constituting the fixing member 34 is located between the catalyst cassettes adjacent in the width direction and at a position that does not overlap the catalyst portion of the catalyst cassette as viewed from the exhaust flow direction, that is, on the outer peripheral portion of the catalyst cassette. By being arranged in, it can be fixed without hindering the flow of exhaust. Further, even if the number of catalyst cassettes to be charged into the catalyst reactor 12 is increased, the fixing member 34 may be disposed between the catalyst cassettes adjacent in the width direction. Therefore, the catalyst cassette can be easily fixed to the catalyst reactor 12.
- the exhaust gas flowing into the main flow path 32a constituting the catalyst reactor 12 is exhausted through the gap between the catalyst cassette and the catalyst cassette. This can be prevented, and exhaust gas can be sufficiently purified by reducing NOx by the catalyst unit.
- the lattice frame is configured to be divided into an opening portion side frame and a facing portion side frame facing the opening portion, and the opening portion frame is detachably provided on the facing portion side frame. be able to.
- segmentation structure is demonstrated using the 1st lattice frame 18 which mounts the some 1st catalyst cassette 14 inserted from the 1st opening part 13a.
- the first lattice frame 18 is configured to be divided into an opening-side frame 18c and an opposing-portion frame 18d that faces the opening. Only the first catalyst cassette 14 in the innermost row as viewed from the first opening 13a side can be placed on the facing portion side frame 18d. That is, the opening side frame 18c can mount the first catalyst cassettes 14 in the middle row and the foremost row when viewed from the first opening portion 13a side.
- the facing portion side frame 18 d is fixed to the housing 13 via the stay 16.
- the contact surfaces of the facing portion side frame 18d and the opening portion side frame 18c are configured to be engageable.
- a pin protruding to the facing portion side is formed on the contact surface of the opening portion side frame 18c, and an engagement hole for engaging the pin is formed on the contact surface of the facing portion side frame 18d. It may be configured.
- a slope 38 is formed at the end of the opening side frame 18c on the first opening 13a side.
- a pressing member 39 configured to be able to press the gradient portion 38 is provided on the gradient portion 38 of the opening side frame 18c.
- the pressing member 39 is configured in the same manner as the pressing member 36 constituting the fixing member 34.
- the pressing member 39 is configured to be pressed from the first opening 13a side by attaching the first lid member 26 to the first opening 13a.
- the pressing member 39 is provided on a slope portion 39a that can contact the slope portion 38 of the opening side frame 18c.
- the pressing member 39 is provided with a protruding portion that protrudes toward the first opening 13a, and the protruding length of the protruding portion is configured to be adjustable.
- the pressing member 39 is restricted from moving in the downstream direction with respect to the gradient portion 38 of the opening side frame 18c by a stopper (not shown) provided on the first lid member.
- the contact surface of the pressing member 39 has a component force in a direction parallel to the depth direction, a component force in a vertical direction, Will be added.
- the opening side frame 18c is pressed against the opposed side frame 18d by the applied component force, and is fixed to the housing 13.
- the lattice frame is configured to be divided into the opening portion side frame and the facing portion side frame, and the opening portion side frame is detachably provided on the facing portion side frame, so that the opening portion side is provided.
- the lattice frame may be configured to be slidable in the depth direction.
- Rail portions 40 that slidably support the first lattice frame 18 are provided at both ends in the width direction of the housing 13 (wall portion 19).
- the rail portion 40 includes a support shaft 40a that protrudes inward from the inner surface of the housing 13, and a roller 40b that is rotatably supported by the support shaft 40a.
- a pair of support shafts 40a are provided on the upstream side and the downstream side of the first lattice frame 18, respectively.
- a plurality of the pair of support shafts 40a are arranged side by side along the depth direction.
- a roller 40b that clamps the widthwise end of the first lattice frame 18 is provided at the inner end of each support shaft 40a.
- the roller 40b constituting the rail portion 40 rotates and the first lattice frame 18 is slid. Therefore, for example, when installing the first catalyst cassette 14 in the innermost row of the first grid frame 18, the first opening is achieved by sliding the first grid frame 18 toward the front side along the rail portion 40.
- the first catalyst cassette 14 can be easily installed without getting out of the portion 13a and performing the installation work, and the installation workability of the catalyst cassette is improved.
- the present invention can be used for a catalytic reactor.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Toxicology (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
排気浄化装置1は、発電機33等の動力源であるエンジン31から排出される排気を浄化するものである。排気浄化装置1は、エンジン31に接続される排気管11に設けられる。排気管11は、ファンネル103まで延びていて外部に直接連通される。排気浄化装置1は、尿素水噴射ノズル2、尿素供給流路3、空気供給流路4、加圧空気弁5、エアタンク6、加圧空気供給ポンプ(コンプレッサ)7、切替弁8、尿素水供給ポンプ9、尿素水タンク10、触媒反応器12、制御装置30等を具備する。
触媒反応器12は、筐体13、エンジン31からの排気を還元する触媒カセット、触媒カセットを筐体13内において支持する支持枠、触媒カセットを固定する固定部材34等を具備する。
図8及び図9に示すように、固定部材34は、開口部から対向する側面に沿って配置され、開口部を閉塞する蓋部材によって付勢されることで、複数の触媒カセットを、その上面から押圧するものである。
12 触媒反応器
13a 第一開口部
13b 第二開口部
14 第一触媒カセット
14a 触媒部
14b 外周部
15 第二触媒カセット
15a 触媒部
15b 外周部
18 第一格子枠
18a 第一流入孔
18b 第一枠部
18c 開口部側フレーム
18d 対向部側フレーム
21 第二格子枠
21a 第二流入孔
21b 第二枠部
23 充填材
24 充填材
26 第一蓋部材
27 第二蓋部材
34 固定部材
100 船舶
Claims (4)
- 一側面に設けられる開口部と、前記開口部から対向する側面に向けて互いに隣接した状態で装入される複数の触媒カセットと、を備える触媒反応器であって、
前記開口部を閉塞する蓋部材によって付勢され、前記複数の触媒カセットの上面を押圧する固定部材が設けられ、
前記固定部材は、前記開口部から対向する側面に沿って配置される、触媒反応器。 - 請求項1に記載の触媒反応器であって、
前記触媒カセットは、排気中のNOxを還元する触媒部と、前記触媒部の側面を覆う枠体によって構成される外周部と、を備え、
前記固定部材は、前記複数の触媒カセットのうちの隣接する触媒カセットの間であって、かつ、前記外周部上に配置される、触媒反応器。 - 請求項1又は2に記載の触媒反応器であって、
前記隣接する触媒カセットの間には、前記開口部から対向する側面に沿って充填材が設けられる、触媒反応器。 - 請求項1から3の何れか一項に記載の触媒反応器を備えた船舶。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201680082551.4A CN109069998B (zh) | 2016-03-24 | 2016-08-23 | 催化反应器以及具有该催化反应器的船舶 |
EP16895474.1A EP3434355A4 (en) | 2016-03-24 | 2016-08-23 | CATALYTIC REACTOR AND SHIP THEREOF |
KR1020187029357A KR102101110B1 (ko) | 2016-03-24 | 2016-08-23 | 촉매 반응기 및 이를 구비한 선박 |
US16/087,541 US10814274B2 (en) | 2016-03-24 | 2016-08-23 | Catalytic reactor and ship provided with same |
Applications Claiming Priority (2)
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JP2016060983A JP6444329B2 (ja) | 2016-03-24 | 2016-03-24 | 触媒反応器及びこれを備えた船舶。 |
JP2016-060983 | 2016-03-24 |
Publications (1)
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WO2017163449A1 true WO2017163449A1 (ja) | 2017-09-28 |
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PCT/JP2016/074512 WO2017163449A1 (ja) | 2016-03-24 | 2016-08-23 | 触媒反応器及びこれを備えた船舶 |
Country Status (6)
Country | Link |
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US (1) | US10814274B2 (ja) |
EP (1) | EP3434355A4 (ja) |
JP (1) | JP6444329B2 (ja) |
KR (1) | KR102101110B1 (ja) |
CN (1) | CN109069998B (ja) |
WO (1) | WO2017163449A1 (ja) |
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EP3260187A1 (en) * | 2016-06-23 | 2017-12-27 | Yara Marine Technologies AS | System and method for reducing the amount of sulfur oxides in exhaust gas |
JP7356367B2 (ja) * | 2020-02-06 | 2023-10-04 | 三菱重工業株式会社 | 灰堆積防止機能付き触媒反応器 |
KR102369507B1 (ko) * | 2020-06-03 | 2022-03-04 | 주식회사 국일인토트 | 촉매 모듈 제조 장치 및 제조 방법 및 이를 이용해 제조된 촉매 모듈 |
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Also Published As
Publication number | Publication date |
---|---|
CN109069998A (zh) | 2018-12-21 |
KR20180120761A (ko) | 2018-11-06 |
JP2017172517A (ja) | 2017-09-28 |
KR102101110B1 (ko) | 2020-04-14 |
EP3434355A1 (en) | 2019-01-30 |
US20190232222A1 (en) | 2019-08-01 |
US10814274B2 (en) | 2020-10-27 |
EP3434355A4 (en) | 2019-02-20 |
JP6444329B2 (ja) | 2018-12-26 |
CN109069998B (zh) | 2021-06-08 |
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