WO2017104338A1 - 面ファスナーおよび繊維製品 - Google Patents
面ファスナーおよび繊維製品 Download PDFInfo
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- WO2017104338A1 WO2017104338A1 PCT/JP2016/083893 JP2016083893W WO2017104338A1 WO 2017104338 A1 WO2017104338 A1 WO 2017104338A1 JP 2016083893 W JP2016083893 W JP 2016083893W WO 2017104338 A1 WO2017104338 A1 WO 2017104338A1
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- fabric
- hook
- loop fastener
- raised
- fastener according
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- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
- A44B18/0003—Fastener constructions
- A44B18/0011—Female or loop elements
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- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
- A44B18/0069—Details
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- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
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- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
- A44B18/0023—Woven or knitted fasteners
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/004—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft with weave pattern being non-standard or providing special effects
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/292—Conjugate, i.e. bi- or multicomponent, fibres or filaments
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/30—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
- D03D15/33—Ultrafine fibres, e.g. microfibres or nanofibres
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D27/00—Woven pile fabrics
- D03D27/02—Woven pile fabrics wherein the pile is formed by warp or weft
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/02—Pile fabrics or articles having similar surface features
- D04B1/04—Pile fabrics or articles having similar surface features characterised by thread material
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/02—Pile fabrics or articles having similar surface features
- D04B21/04—Pile fabrics or articles having similar surface features characterised by thread material
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D10/00—Pyjamas; Nightdresses
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2300/00—Details of garments
- A41D2300/30—Closures
- A41D2300/32—Closures using hook and loop-type fasteners
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/041—Polyacrylic
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/06—Details of garments
- D10B2501/063—Fasteners
- D10B2501/0632—Fasteners of the touch-and-close type
Definitions
- the present invention is a hook-and-loop fastener composed of a female material and a male material, which not only has excellent engagement, but is flexible and does not generate much peeling noise when separating the female material and the male material.
- the present invention relates to a hook-and-loop fastener excellent in stitchability to fabric and the like and excellent in durability, and a textile product including the hook-and-loop fastener.
- the hook-and-loop fastener is usually composed of a female material having a loop-shaped or arch-shaped engaging element and a male material having a hook-shaped or mushroom-shaped hook portion.
- a hook-and-loop fastener engages a product with a hook-and-loop fastener, and is easy to attach and detach. Therefore, the hook-and-loop fastener is generally widely used as a fastener for clothes, shoes, bags, gloves, and the like (for example, Patent Document 1). , Patent Document 2 and Patent Document 3).
- the hook-and-loop fastener has an engaging function as described above, but has a problem that a large peeling noise is generated when the female material and the male material of the hook-and-loop fastener are separated. Furthermore, since the base fabric part and the hook part of the hook-and-loop fastener are hard, there is a problem that it is difficult to sew to clothes or the like, and the skin is damaged.
- a flexible surface fastener has been proposed in which a fabric containing ultrafine fibers is used as a female material, and a napped fabric is used as a male material to suppress peeling noise when separating the female material and the male material.
- a fabric containing ultrafine fibers is used as a female material
- a napped fabric is used as a male material to suppress peeling noise when separating the female material and the male material.
- JP 2004-173819 A Japanese Patent No. 4354232 gazette Japanese Patent Laid-Open No. 2007-7124 Japanese Patent No. 569958
- the present invention has been made in view of the above-mentioned background, and its purpose is not only to have excellent engagement, but also to be flexible, and does not generate much peeling sound when separating a female material and a male material.
- the present inventor has laminated a resin layer on the back surface of the female material and the male material (the side opposite to the joint surface) of the female material and the male material. As a result, it was found that the durability of the bonding force is improved by increasing the rigidity, and the present invention has been completed by further intensive studies.
- a hook-and-loop fastener comprising a fabric A and a raised fabric B including a raised portion and a ground tissue portion, and both the fabric A and the raised fabric B have a resin layer.
- a hook-and-loop fastener characterized by the above is provided.
- the said resin layer is a resin coating layer or a laminate layer.
- the fabric A preferably has a knitted structure. Further, it is preferable that the fabric A includes a filament yarn having a single fiber diameter of 1000 nm or less.
- the filament yarn is preferably made of polyester and is a multifilament having 1000 or more filaments.
- the filament yarn has a loop shape and is exposed on the fabric surface.
- the thickness is preferably in the range of 0.3 to 3.0 mm.
- the elongation in either the vertical direction or the horizontal direction is in the range of 1 to 20%.
- the bending resistance of either the vertical direction or the horizontal direction is 25 mm or more.
- the napped portion is made of polyester and napped yarn having a single fiber fineness of 2.5 dtex or more.
- the raised length of the raised portion is preferably in the range of 0.1 to 3.0 mm.
- the elongation percentage in either the vertical direction or the horizontal direction is in the range of 1 to 20%.
- the bending resistance of either the vertical direction or the horizontal direction is 25 mm or more.
- the tensile shear strength defined below is 50 cN / cm 2 or more.
- F1 S / (L ⁇ W) Where F1 is the tensile shear strength (cN / cm 2 ), S is the maximum tensile shear load (cN), L is the overlap length (cm), and W is the sample width (cm).
- care clothing medical clothing, sportswear, outerwear, innerwear, pajamas, men's clothing, women's clothing, yukata, work clothing, protective clothing, combat clothing, including the surface fastener.
- Any fiber product selected from the group consisting of a skin care tool and a cosmetic tool is provided.
- the present invention not only has excellent engagement, but is flexible, does not generate much peeling sound when separating a female material and a male material, and is excellent in stitchability to a fabric or the like and durable.
- a surface fastener excellent in properties and a fiber product including the surface fastener can be obtained.
- the hook-and-loop fastener of the present invention is a hook-and-loop fastener composed of a fabric A (female material) and a raised fabric B (male material) including a raised portion and a ground tissue portion, and the fabric A and the raised fabric B are both
- the resin layer is provided on the back surface (that is, the surface opposite to the joint surface of both). Such a resin layer is also called back coating.
- the resin layer is preferably a resin coating layer, a laminate layer laminated with a film, or the like.
- the resin for forming the resin coating layer is not particularly limited, but includes acrylic ester copolymer resin, urethane resin, vinyl chloride resin, vinyl acetate resin, styrene-butadiene resin, polyester resin, natural rubber, isoprene rubber, silicone rubber, and the like. Is exemplified. Especially, since the said resin is resin containing acrylic acid ester copolymer resin, since it has adhesiveness, it does not require another binder and is preferable.
- polyester resin polyethylene resin, polypropylene resin, nylon resin, polystyrene resin, polyvinyl chloride resin, polyvinylidene chloride resin, and the like are preferable.
- the types of resins forming the resin layer may be the same or different.
- the method for forming the resin layer may be a known method, and may be appropriately subjected to heat treatment or drying treatment after resin coating by a conventional method such as knife coater or laminating a film.
- the viscosity of the resin is preferably in the range of 500 to 1500 cps.
- the adhesion amount is preferably in the range of 10 to 100 g / m 2 in terms of solid content.
- the resin layer is preferably formed on the entire surface of the fabric, but may be formed in a pattern such as a dot shape, a lattice shape, a grain pattern, a grain pattern, a geometric figure, a character, a logo, or an abstract pattern.
- the fabric structure is not particularly limited, and may be a woven fabric, a knitted fabric, or a nonwoven fabric obtained by a normal method. Of these, a woven fabric or a knitted fabric is preferable, and a knitted fabric is particularly preferable for improving stretchability.
- a knitted fabric it is preferable that the napped yarn of the male material can be firmly engaged by the loop of the knitted fabric.
- the needle surface of the knitted fabric is used as a surface (joint surface) that engages with the male material, excellent engagement is obtained, which is preferable.
- the fabric A contains a filament yarn having a single fiber diameter of 1000 nm or less because excellent engagement is obtained.
- the single fiber diameter (diameter of the single fiber) is more preferably in the range of 100 to 900 nm (more preferably 550 to 900 nm). .
- the single fiber diameter is larger than 1000 nm, sufficient engagement may not be obtained.
- the cross-sectional shape of the single fiber is an atypical cross section other than the round cross section, the diameter of the circumscribed circle is defined as the single fiber diameter.
- the single fiber diameter can be measured by photographing the cross section of the fiber with a transmission electron microscope. Further, it is preferable that the variation of the single fiber fineness is within a range of ⁇ 20% to + 20%.
- the number of filaments is not particularly limited, but is preferably 1000 or more (more preferably 2000 to 10,000) in order to obtain excellent engagement.
- the total fineness of the filament yarn is preferably in the range of 5 to 150 dtex.
- the fiber form of the filament yarn is not particularly limited, but is preferably a long fiber (multifilament yarn).
- the cross-sectional shape of the single fiber is not particularly limited, and may be a known cross-sectional shape such as round, triangular, flat, hollow. In addition, normal air processing and false twist crimping may be applied.
- the type of polymer forming the filament yarn is not particularly limited, but a polyester polymer is preferable.
- a polyester polymer is preferable.
- polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, stereocomplex polylactic acid, polyester obtained by copolymerizing the third component, and the like are preferably exemplified.
- Such polyester may be material recycled or chemically recycled polyester.
- it may be a polyester obtained by using a catalyst containing a specific phosphorus compound and a titanium compound as described in JP-A-2004-270097 and JP-A-2004-212268.
- a fine pore forming agent a cationic dye dyeing agent, an anti-coloring agent, a heat stabilizer, a fluorescent whitening agent, a matting agent, a coloring agent may be added as necessary within the range not impairing the object of the present invention.
- 1 type (s) or 2 or more types of an agent, a hygroscopic agent, and inorganic fine particles may be contained.
- the fabric A serving as a female material is preferably composed of only the filament yarn, but one or more types of other yarns may be included. In that case, it is preferable that the weight ratio of another thread
- Such other yarns are preferably polyester yarns and elastic fiber yarns having a single fiber diameter of more than 1000 nm.
- the polyester yarn is preferably made of polyester as described above.
- polybutylene terephthalate is a hard segment
- polyoxyethylene glycol is a soft segment
- polybutylene terephthalate is a hard segment
- Non-water-absorbing polyether ester elastic fiber yarn made of polyether ester elastomer with tetramethylene oxide glycol as soft segment polyurethane elastic fiber yarn, polytrimethylene terephthalate yarn, synthetic rubber elastic fiber yarn, natural rubber elastic fiber yarn, etc. Is preferably exemplified.
- the total fineness of the elastic fiber yarn is preferably in the range of 5 to 100 dtex (more preferably 10 to 40 dtex).
- the fabric A serving as a female material can be manufactured by, for example, the following manufacturing method.
- a sea-island composite fiber fiber for nanofiber
- a sea-island type composite fiber a sea-island type composite fiber multifilament (100 to 1500 islands) disclosed in Japanese Patent Application Laid-Open No. 2007-2364 is preferably used.
- the sea component polymer polyester, polyamide, polystyrene, polyethylene and the like having good fiber forming properties are preferable.
- polylactic acid, ultrahigh molecular weight polyalkylene oxide condensation polymer, polyethylene glycol compound copolymer polyester, polyethylene glycol compound copolymer polyester with 5-sodium sulfonic acid isophthalic acid are available. Is preferred.
- a polyethylene terephthalate copolymer polyester having an intrinsic viscosity of 0.4 to 0.6 obtained by copolymerizing 6 to 12 mol% of 5-sodium sulfoisophthalic acid and 3 to 10% by weight of polyethylene glycol having a molecular weight of 4000 to 12000. Is preferred.
- the island component polymer is preferably a polyester such as a fiber-forming polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, or a polyester obtained by copolymerizing a third component.
- a fine pore forming agent, a cationic dye dyeing agent, an anti-coloring agent, a heat stabilizer, a fluorescent whitening agent, a matting agent, a coloring agent may be added as necessary within the range not impairing the object of the present invention.
- 1 type (s) or 2 or more types of an agent, a hygroscopic agent, and inorganic fine particles may be contained.
- the sea-island type composite fiber multifilament composed of the sea component polymer and the island component polymer preferably has a sea component melt viscosity higher than that of the island component polymer during melt spinning.
- the diameter of the island component is preferably in the range of 10 to 1000 nm. At this time, if the diameter is not a perfect circle, the diameter of the circumscribed circle is obtained.
- the sea-island composite weight ratio (sea: island) is preferably in the range of 40:60 to 5:95, particularly preferably in the range of 30:70 to 10:90.
- Such a sea-island type composite fiber multifilament can be easily manufactured, for example, by the following method. That is, melt spinning is performed using the sea component polymer and the island component polymer. As the spinneret used for melt spinning, any one such as a hollow pin group for forming an island component or a group having a fine hole group can be used.
- the discharged sea-island type cross-section composite fiber multifilament is solidified by cooling air, preferably melt-spun at 400 to 6000 m / min, and wound up.
- the obtained undrawn yarn is made into a composite fiber having desired strength, elongation, and heat shrinkage properties through a separate drawing process, or is taken up by a roller at a constant speed without being wound once, and subsequently drawn.
- the single yarn fiber fineness, the number of filaments, and the total fineness are respectively single yarn fiber fineness of 0.5 to 10.0 dtex, number of filaments of 5 to 75, and total fineness of 30 to 170 dtex (preferably 30 Preferably in the range of ⁇ 100 dtex).
- the sea-island type composite fiber multifilament is used alone or, if necessary, used together with other yarns having a single fiber diameter larger than 1000 nm (for example, elastic fiber yarns) to knitting or weaving the fabric A To do.
- the structure of the fabric A is not particularly limited, and may be a woven fabric, a knitted fabric, or a nonwoven fabric obtained by a usual method. Of these, a woven fabric or a knitted fabric is preferable, and a knitted fabric is particularly preferable.
- the raised yarn of the male material can be firmly engaged by the loop of the knitted fabric.
- the needle surface of the knitted fabric is used as a surface that engages with the male material because excellent engagement is obtained.
- the woven structure of the woven fabric is a three-fold structure such as plain weave, oblique weave, satin weave, etc., altered structure such as altered weave, altered weave weave, single double structure such as vertical double weave, weft double weave, etc. Examples include vertical pile weaves such as fresh velvet, towels and velours, bevel pile weaves such as benjin, weft velvet, velvet and call heaven.
- the textile fabric which has these woven structures can be woven by a normal method using normal looms, such as a rapier loom and an air jet loom.
- the number of layers is not particularly limited and may be a single layer or a woven fabric having a multilayer structure of two or more layers.
- the type of knitting may be a weft knitting or a fresh knitting.
- the weft knitting structure include tenshi, rubber knitting, double-sided knitting, pearl knitting, tuck knitting, float knitting, one-side knitting, lace knitting, and bristle knitting.
- Preferred examples include a platen sheet in which a composite loop is formed by two types of yarns in a knitted structure of a sheet, and a bare sheet having one fiber as an elastic fiber yarn.
- Preferred examples of the warp knitting structure include a single denby knitting, a single atlas knitting, a double cord knitting, a half knitting, a back knitting, a jacquard knitting and the like.
- the knitting can be knitted by a normal method using a normal knitting machine such as a circular knitting machine, a flat knitting machine, a tricot knitting machine, and a Raschel knitting machine.
- a normal knitting machine such as a circular knitting machine, a flat knitting machine, a tricot knitting machine, and a Raschel knitting machine.
- the number of layers is not particularly limited and may be a single layer or a knitted fabric having a multilayer structure of two or more layers.
- the fabric is subjected to an alkaline aqueous solution treatment, and sea components of the sea-island type composite fiber multifilament are dissolved and removed with an alkaline aqueous solution, whereby the sea-island type composite fiber multifilament is converted into a filament yarn (nanofiber diameter of 10 to 1000 nm). Fiber).
- an alkaline aqueous solution treatment a NaOH aqueous solution having a concentration of 1 to 4% is used and the treatment is preferably performed at a temperature of 55 to 70 ° C.
- the fabric A can be obtained by forming the resin layer as described above.
- the fabric A thus obtained has a resin layer on the side surface opposite to the bonding surface, so that the rigidity is high and the durability of the bonding force is improved. Moreover, when the said filament yarn A which is a super extra fine fiber is contained, it can use suitably as a female material of a hook_and_loop
- the filament yarn is exposed on at least one of the front surface and the back surface.
- the filament yarn is not exposed on either the front surface or the back surface, there is a possibility that the male raised yarn cannot be engaged.
- the fabric A preferably has a thickness in the range of 0.3 to 3.0 mm.
- the fabric weight is preferably in the range of 30 to 500 g / m 2 .
- the elongation percentage of at least one of the vertical direction and the horizontal direction is in the range of 1 to 20%.
- the bending resistance of at least one of the vertical direction and the horizontal direction is 25 mm or more (preferably 25 to 80 mm).
- the female material may be composed of the fabric A only by appropriately cutting the fabric A, or may be sewn so that the periphery of the fabric A will not fray. No problem.
- the fabric A since the fabric A has a resin layer and high rigidity, it has an excellent effect that wrinkles are hardly generated in the cut portion.
- the surface fastener of the present invention includes a raised fabric B that is a male material.
- the napped fabric B has a ground tissue portion having a knitted fabric structure composed of organic fiber yarns, and is knitted or woven into the ground tissue portion, and extends from the ground texture portion to at least one surface side thereof. And a raised portion composed of a plurality of raised yarns.
- the napped yarn may be a loop pile, but is preferably a cut pile in order to obtain strong engagement.
- the napped yarn preferably has a single fiber fineness of 0.5 dtex or more (preferably 0.5 to 5.0 dtex). If the single fiber fineness is less than 0.5 dtex, it is difficult to maintain a raised state, and there is a possibility that firm engagement cannot be obtained when the raised fabric B is used as a male material and engaged with a female material. is there.
- the raised length of the raised yarn is preferably in the range of 0.1 to 10 mm. If the napped length is less than 0.1 mm, the napped length is too small, and there is a possibility that firm engagement cannot be obtained when the napped fabric B is used as a male material and engaged with a female material. On the contrary, if the length of the raised hair is larger than 10 mm, it is difficult to keep the raised state, and there is a possibility that firm engagement cannot be obtained when the raised fabric B is used as a male material and engaged with a female material. is there.
- the nap length is the height of L shown in FIG.
- the raised yarn density of the raised portion formed by such raised yarn is preferably 3000 dtex / cm 2 or more (preferably 5000 to 100,000 dtex / cm 2 ).
- the napped yarn density is less than 3000 dtex / cm 2 , the napped yarn is liable to fall down, so that it is difficult to maintain the napped state, and when the napped fabric B is used as a male material and is engaged with a female material, it is strong. There is a possibility that the engagement cannot be obtained.
- polyester fibers made of polyester as described above are particularly preferable in terms of recyclability and rigidity.
- a matting agent titanium dioxide
- a fine pore forming agent organic sulfonic acid metal salt
- an anti-coloring agent e.g., titanium dioxide
- a heat stabilizer e.g., aluminum oxide
- a flame retardant e.g., sodium bicarbonate
- a fluorescent brightening agent, a coloring pigment, an antistatic agent (sulfonic acid metal salt), a hygroscopic agent (polyoxyalkylene glycol), an antibacterial agent, and other inorganic particles may be contained.
- the shape of the raised yarn may be a non-crimped raised yarn, a false twist crimping method, a mechanical crimping method, or a crimped standing obtained by heat-treating a Cybyside type latent crimpable composite fiber.
- a wool yarn may be used and is not particularly limited, but a non-crimped yarn is preferable in order to obtain strong engagement.
- the single fiber cross-sectional shape of the raised yarn is not particularly limited, and may be a triangular shape, a flat shape, a flat shape with a constriction, a cross shape, a hexagonal shape, or a hollow shape in addition to a normal circular cross section.
- the ground texture portion is composed of organic fiber yarns and has a knitted texture.
- a fiber which comprises this organic fiber yarn the thing similar to the fiber illustrated as an example for the above-mentioned napped yarn may be sufficient.
- polyester fiber is preferable in terms of recyclability.
- the form of the organic fiber yarn constituting the ground texture portion is not particularly limited, it is preferably a long fiber (multifilament yarn).
- the single fiber fineness and total fineness of the organic fiber yarn are preferably a single fiber fineness of 0.5 to 5.0 dtex and a total fineness of 30 to 300 dtex without impairing the texture of the fabric.
- the cross-sectional shape of the single fiber is not limited, and may be a triangular, flat, constricted flat, cross, hexagonal, or hollow cross-sectional shape in addition to a normal circular cross section.
- organic fiber yarns include false twisted crimped yarns, composite yarns obtained by subjecting two or more types of constituent yarns to air-mixing processing or composite false twisting processing, an elastic yarn in the core portion, and a non-woven fabric in the sheath portion. It may be a covering yarn on which an elastic yarn is located.
- the raised fabric B can be easily obtained by the following production method, for example.
- the ground structure is knitted, and a loop pile structure such as a sinker pile, a pole tricot pile, and a double raschel pile extending thereon is formed.
- a method of shearing the loop pile is used.
- the pole tricot pile is obtained by forming a pile knitted portion of a tricot knitted structure into a loop pile using a raising machine.
- the napped fabric B thus obtained has a conventional dyeing process, water-repellent process, water-absorbing process, buffing process, ultraviolet shielding or antistatic agent, antibacterial agent, deodorant, insect repellent, luminous agent, recursion
- Various processings that impart functions such as a reflective agent and a negative ion generator may be additionally applied.
- the raised fabric B can be obtained by forming the resin layer as described above.
- the male material may be appropriately cut from the raised fabric B and may be composed of the raised fabric B alone, or may be sewn so that the periphery of the raised fabric B is not frayed, or appropriately decorated. Can be added.
- the fabric B since the fabric B has a resin layer and has high rigidity, it has an excellent effect that wrinkles are hardly generated in the cut portion.
- the raised length of the raised portion is preferably in the range of 0.1 to 3.0 mm.
- the elongation in either the vertical or horizontal direction is in the range of 1 to 20%.
- the bending resistance of either the vertical or horizontal direction is 25 mm or more (preferably 25 to 80 mm).
- the hook-and-loop fastener of the present invention is composed of a female material including the fabric A and a male material including the raised fabric B, and is excellent when used so that the raised portions of the fabric A and the raised fabric B are engaged. Has engagement.
- the tensile shear strength defined below is preferably 50 cN / cm 2 or more (preferably 50 to 300 cN / cm 2 ).
- F1 S / (L ⁇ W) Where F1 is the tensile shear strength (cN / cm 2 ), S is the maximum tensile shear load (cN), L is the overlap length (cm), and W is the sample width (cm).
- the surface fastener of the present invention includes the fabric A and the raised fabric B, the surface fastener is flexible and does not generate much peeling sound when the female material and the male material are separated. Moreover, it is excellent also in the sewing property to other fabrics. In addition, the durability of the bonding force is also excellent.
- the textile product of the present invention includes the above-mentioned hook-and-loop fastener, sportswear, outerwear, innerwear, men's clothing, women's clothing, medical clothing, nursing clothing, yukata, work clothing, protective clothing, footwear, It is a textile product selected from the group consisting of bags, hats, gloves, socks, bedding, support bands, base fabrics, car seats, supporters, wiping tools, skin care tools, and cosmetic tools. Since such a fiber product uses the above-mentioned hook-and-loop fastener, it not only has excellent engagement, but is flexible, and does not generate much peeling sound when separating the female material from the male material. It also has excellent seamability. In addition, the durability of the bonding force is also excellent.
- each measurement item in an Example was measured with the following method.
- ⁇ Melt viscosity> The polymer after the drying treatment is set in an orifice set to a ruder melting temperature at the time of spinning and melted and held for 5 minutes, and then extruded by applying a load of several levels, and the shear rate and melt viscosity at that time are plotted. The plot was gently connected to create a shear rate-melt viscosity curve, and the melt viscosity was observed when the shear rate was 1000 sec- 1 .
- ⁇ Dissolution rate> The sea and island components are each wound with a diameter of 0.3 ⁇ -0.6L ⁇ 24H at a spinning speed of 1000-2000m / min and further stretched so that the residual elongation is in the range of 30-60%. Thus, a multifilament having a total fineness of 84 dtex / 24 fil was produced. The weight loss rate was calculated from the dissolution time and the dissolution amount at a bath ratio of 100 at a temperature at which the solvent was dissolved in each solvent. ⁇ Single fiber diameter> After the fabric was photographed with a scanning electron microscope SEM, the single fiber diameter was measured with an n number of 5, and the average value was obtained. ⁇ Elongation> Measured according to JIS L 1096 8.12.
- F1 S / (L ⁇ W)
- F1 is the tensile shear strength (cN / cm 2 )
- S is the maximum tensile shear load (cN)
- L is the overlap length (cm)
- W is the sample width (cm).
- the obtained undrawn yarn was roller-drawn at a drawing temperature of 80 ° C. and a draw ratio of 2.5 times, and then heat-set at 150 ° C. and wound up.
- the obtained sea-island composite fiber multifilament (nanofiber fiber, drawn yarn) has a total fineness of 56 dtex / 10 fil, and when the cross section of the fiber is observed with a transmission electron microscope TEM, the shape of the island is round and the island The diameter was 700 nm.
- the sea island type composite fiber multifilament (nanofiber fiber) and polyester false twisted crimped yarn manufactured by Teijin Ltd., 56 dtex / 72fil
- polyester false twisted crimped yarn A circular knitting machine (fabric) with a sinker pile structure using a 24G, 26-inch circular knitting machine (Fukuhara Seiki Seisakusho Co., Ltd.) using Teijin's 167 dtex / 48 fil)
- a production machine for A) was knitted. Thereafter, the knitted fabric was subjected to alkali reduction by 8.3% at 70 ° C.
- the knitted fabric contained filament yarn having an average single fiber diameter of 700 nm in a loop shape in the pile portion on the surface. It was confirmed that the fibers were spread evenly. Further, the thickness of the knitted fabric (fabric A) was 0.85 mm, the elongation in the warp direction was 4.5%, and the bending resistance in the warp direction was 50 mm.
- normal polyester filament yarn manufactured by Teijin Ltd., 33 dtex / 12 fil
- normal polyester filament yarn manufactured by Teijin Ltd., 84 dtex / 24 fil
- the obtained warp knitting machine was used as a preset to perform dry heat setting at 160 ° C. and high pressure dyeing at 130 ° C. Then, shearing was performed, dry heat setting at 170 ° C.
- the napped fabric was composed of a napped portion made of a cut pile and a ground tissue portion, and a single fiber of napped yarn
- the fineness was 3.5 dtex
- the napped length was 1.2 mm
- the elongation in the vertical direction was 2.5%
- the bending resistance in the vertical direction was 48 mm.
- Example 2 Using only the sea-island type composite fiber multifilament 56 dtex / 10 fil (fiber for nanofiber) obtained in Example 1, using a 28G warp knitting machine (manufactured by KARL MAYER Co., Ltd.), a half structure (front: 10 / 23, middle: 23/10, back: 10/12) warp knitting machine (fabric machine for fabric A) was obtained. Thereafter, the knitted fabric was subjected to alkali reduction by 31% at 70 ° C. with a 3.5% NaOH aqueous solution in order to remove sea components of the sea island type composite fiber multifilament of the obtained warp knitting machine.
- the knitted fabric (fabric A) and the napped knitted fabric (napped fabric B) obtained in Example 1 are engaged with each other so that the napped surface of the napped fabric B is in contact with the fabric A.
- the tensile shear strength F1 97 cN / cm 2 and excellent engagement was obtained.
- the knitted fabric (fabric A) and the napped knitted fabric (napped fabric B) were sewn to a pajamas as a hook-and-loop fastener, the sewing work was also good. Furthermore, engagement did not decrease even after washing.
- Example 3 In the same manner as in Example 1, a sea-island composite fiber multifilament 56 dtex / 10 fil (nanofiber fiber) was obtained. Next, a multifilament (33 dtex / 12 file) made of the two drawn yarns and ordinary polyethylene terephthalate and interlaced were used to obtain a mixed yarn. The blended yarn is twisted at 300 times / m (S direction), and all the warp yarns are arranged. On the other hand, two multifilament false twisted crimped yarns (56 dtex / 144 fil) made of ordinary polyethylene terephthalate are aligned.
- Example 2 An acrylic resin was coated on the back surface in the same manner as in Example 1 and dried to obtain a fabric A.
- the thickness of the woven fabric (fabric A) was 0.33 mm, the elongation in the vertical direction was 1.8%, and the bending resistance in the vertical direction was 32 mm.
- the woven fabric (fabric A) and the napped knitted fabric (napped fabric B) obtained in Example 1 were engaged with each other so that the napped surface of the napped fabric B was in contact with the fabric A, and then pulled.
- the female material (fabric A) and the male material (rafted fabric B) no peeling noise was produced and the texture was soft.
- the woven fabric (fabric A) and the napped knitted fabric (napped fabric B) were sewn into a pajamas as a hook-and-loop fastener, the sewing work was also good. Furthermore, engagement did not decrease even after washing.
- Example 4 A knitted fabric (fabric A) was obtained in the same manner as in Example 1.
- a normal polyester crimped yarn (44 dtex / 48 fil, manufactured by Teijin Ltd.) is arranged on the warp of the ground texture as a yarn for ground texture
- a normal polyester false twisted crimped yarn (Teijin Ltd.) Manufactured, 56 dtex / 24 fil) is arranged on the weft of the ground structure
- normal polyester filament yarn (manufactured by Teijin Ltd., 84 dtex / 24 fil) is used as a yarn for napping yarn, warp density 165 / 2.54 cm
- a woven fabric machine (pile machine for standing fabric B) having a pile structure was obtained by a velvet weaving machine at a weaving density of 200 weft density / 2.54 cm.
- the thickness of the knitted fabric (fabric A) was 0.83 mm, the elongation ratio in the warp direction / width direction was 21.5% / 62%, and the bending resistance in the warp direction / width direction was 22 mm / 18 mm.
- a warp knitting machine (a standing machine for standing fabric B) was knitted in the same manner as in Example 1. Thereafter, the obtained warp knitting machine was used as a preset to perform dry heat setting at 160 ° C. and high-pressure dyeing at 130 ° C. Thereafter, shearing was performed, and a dry heat set at 170 ° C. was performed as a final set to obtain a raised fabric B (no back coating).
- the elongation ratio in the warp direction / width direction of the raised fabric (the raised fabric B) was 6.4% / 4.0%, and the bending resistance in the warp direction / width direction was 20 mm / 21 mm.
- the knitted fabric (fabric A) and the napped fabric (napped fabric B) are engaged so that the napped surface of the napped fabric B is in contact with the fabric A, and the tensile shear strength F1 is measured.
- the tensile shear strength F1 44 cN / cm 2 and the engagement was insufficient.
- the present invention not only has excellent engagement, but is flexible, does not generate much peeling sound when separating a female material and a male material, and is excellent in stitchability to a fabric or the like and durable.
- a hook-and-loop fastener excellent in performance and a fiber product including the hook-and-loop fastener are provided, and its industrial value is extremely large.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Knitting Of Fabric (AREA)
- Woven Fabrics (AREA)
- Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/781,772 US20180360169A1 (en) | 2015-12-14 | 2016-11-16 | Hook and loop fastener and textile products |
AU2016370986A AU2016370986A1 (en) | 2015-12-14 | 2016-11-16 | Hook and loop fastener and textile products |
KR1020187015920A KR20180093911A (ko) | 2015-12-14 | 2016-11-16 | 면 패스너 및 섬유 제품 |
EP16875322.6A EP3391768A4 (en) | 2015-12-14 | 2016-11-16 | Velcro fastener and textile products |
CN201680073508.1A CN108697207A (zh) | 2015-12-14 | 2016-11-16 | 粘扣带及纤维制品 |
CA3008209A CA3008209A1 (en) | 2015-12-14 | 2016-11-16 | Hook and loop fastener and textile products |
JP2017556430A JP6775526B2 (ja) | 2015-12-14 | 2016-11-16 | 面ファスナーおよび繊維製品 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2015-243254 | 2015-12-14 | ||
JP2015243254 | 2015-12-14 |
Publications (1)
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WO2017104338A1 true WO2017104338A1 (ja) | 2017-06-22 |
Family
ID=59056089
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2016/083893 WO2017104338A1 (ja) | 2015-12-14 | 2016-11-16 | 面ファスナーおよび繊維製品 |
Country Status (9)
Country | Link |
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US (1) | US20180360169A1 (ko) |
EP (1) | EP3391768A4 (ko) |
JP (1) | JP6775526B2 (ko) |
KR (1) | KR20180093911A (ko) |
CN (1) | CN108697207A (ko) |
AU (1) | AU2016370986A1 (ko) |
CA (1) | CA3008209A1 (ko) |
TW (1) | TWI731000B (ko) |
WO (1) | WO2017104338A1 (ko) |
Cited By (3)
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CN109989164A (zh) * | 2017-12-29 | 2019-07-09 | 上海嘉麟杰纺织品股份有限公司 | 可生物降解纸尿裤用前腰贴的制备工艺 |
JP2019187601A (ja) * | 2018-04-20 | 2019-10-31 | 帝人フロンティア株式会社 | 面ファスナーおよび血圧測定用カフ |
EP3715113A4 (en) * | 2017-11-22 | 2021-08-04 | Teijin Frontier Co., Ltd. | FABRIC WITH MULTI-LAYER STRUCTURE AND METHOD OF MANUFACTURING ITEM AND FIBER PRODUCT |
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CN107815778A (zh) * | 2016-09-14 | 2018-03-20 | 周朝木 | 自体黏扣织物(二) |
CN113613900A (zh) * | 2019-03-18 | 2021-11-05 | 积水化学工业株式会社 | 复合结构体及双面粘合带 |
US20230167589A1 (en) * | 2020-04-21 | 2023-06-01 | Teijin Frontier Co., Ltd. | Water-repelling fabric, and textile product |
CN111793890A (zh) * | 2020-07-20 | 2020-10-20 | 江苏百优达生命科技有限公司 | 一种外科手术用线带及其生产方法 |
JP7420697B2 (ja) * | 2020-11-13 | 2024-01-23 | 林テレンプ株式会社 | 車両内装材向けスエード調表皮材 |
US20220183400A1 (en) * | 2020-12-15 | 2022-06-16 | Shefit, Inc. | Brassiere assembly |
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Also Published As
Publication number | Publication date |
---|---|
AU2016370986A1 (en) | 2018-06-21 |
EP3391768A1 (en) | 2018-10-24 |
TW201731412A (zh) | 2017-09-16 |
KR20180093911A (ko) | 2018-08-22 |
EP3391768A4 (en) | 2020-07-15 |
JPWO2017104338A1 (ja) | 2018-09-27 |
CN108697207A (zh) | 2018-10-23 |
US20180360169A1 (en) | 2018-12-20 |
JP6775526B2 (ja) | 2020-10-28 |
TWI731000B (zh) | 2021-06-21 |
CA3008209A1 (en) | 2017-06-22 |
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