WO2017056339A1 - Tube de résine synthétique - Google Patents
Tube de résine synthétique Download PDFInfo
- Publication number
- WO2017056339A1 WO2017056339A1 PCT/JP2015/083193 JP2015083193W WO2017056339A1 WO 2017056339 A1 WO2017056339 A1 WO 2017056339A1 JP 2015083193 W JP2015083193 W JP 2015083193W WO 2017056339 A1 WO2017056339 A1 WO 2017056339A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- ant
- tube
- synthetic resin
- outer layer
- Prior art date
Links
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 49
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 claims description 40
- 241000607479 Yersinia pestis Species 0.000 claims description 28
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 239000004677 Nylon Substances 0.000 claims description 12
- 239000000314 lubricant Substances 0.000 claims description 12
- 229920001778 nylon Polymers 0.000 claims description 12
- 229920005672 polyolefin resin Polymers 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 241000256602 Isoptera Species 0.000 abstract 2
- 239000010410 layer Substances 0.000 description 274
- 241000257303 Hymenoptera Species 0.000 description 33
- 230000004224 protection Effects 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 4
- 230000003628 erosive effect Effects 0.000 description 4
- 229940121375 antifungal agent Drugs 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920013716 polyethylene resin Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000003429 antifungal agent Substances 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000005888 Clothianidin Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 235000017663 capsaicin Nutrition 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
Definitions
- This invention relates to a tube made of synthetic resin that can prevent damage caused by pests.
- corrugated tube made of synthetic resin mixed with an anti-bacterial agent as a control agent for controlling pests (see, for example, Patent Document 1).
- This corrugated tube had a single-layer structure or a two-layer structure of an outer layer and an inner layer.
- an organophosphorus compound or an organic acid metal salt as an antifungal agent was mixed into the synthetic resin having a single layer structure or the outer layer synthetic resin having a two-layer structure.
- the present invention has been made to solve the above-described conventional drawbacks, and the object of the present invention is to reduce the manufacturing cost and to control pests inside and outside the pipe.
- the object is to provide a tube made of synthetic resin.
- a synthetic resin tube according to an embodiment of the present invention is a synthetic resin tube including a tube wall having an outer layer, an inner layer, and an intermediate layer, and only the outer layer and the inner layer excluding the intermediate layer, It consists of a control layer that controls pests.
- the outer layer and the inner layer are composed of a control layer for controlling pests, whereby pests can be controlled inside and outside the tube. And since an intermediate
- the outer layer and the inner layer are formed of an ant barrier layer as the control layer, and the ant barrier layer may be formed of a nylon resin.
- the outer layer and the inner layer formed of nylon resin are hard, and white ants cannot easily break through the outer layer and the inner layer.
- the outer layer and the inner layer are formed of an ant barrier layer as the control layer, and the ant barrier layer is formed by adding a lubricant to the polyolefin resin. May be formed.
- the surface of the outer layer and the inner layer formed by adding the lubricant to the polyolefin resin is slippery, and white ants cannot easily break through the outer layer and the inner layer.
- the outer layer and the inner layer are formed of an ant-proof layer as the control layer, and these ant-proof layers are formed by containing an ant-proof agent. May be.
- the outer layer and the inner layer are formed by containing the ant-proofing agent, so that the white ants progress along the outer surface or the inner surface of the tube and enter a house or the like, and eat and break the outer layer and the inner layer of the tube. Can be prevented.
- the outer layer and the inner layer are formed of an ant-proof layer as the control layer, and the ant-proof layer serving as the outer layer is formed of a nylon resin.
- the ant-proof layer serving as the outer layer may be formed by adding a lubricant to a polyolefin-based resin, and the ant-proof layer serving as the inner layer may be formed containing an ant-proof agent.
- the outer layer is hard, and white ants cannot easily break through the outer layer.
- an outer layer formed by adding a lubricant to a polyolefin-based resin The surface of the outer layer is slippery, and white ants cannot easily break through the outer layer.
- the inner layer is formed to contain an ant-proofing agent, it is possible to prevent white ants from propagating along the inner surface of the pipe and entering a house or the like, or eroding the inner layer of the pipe. .
- the thickness of the outer layer and the thickness of the inner layer may be the same as or thinner than the thickness of the intermediate layer, respectively.
- the inner layer has a wall thickness equal to or less than that of the intermediate layer
- the outer layer has a wall thickness of the inner layer. It may be the same as or thinner than that. In this way, by limiting the thickness of the outer layer and the inner layer made of the control layer, it is possible to reliably reduce the region of the control layer that increases the cost in the pipe.
- the intermediate layer may be composed of a plurality of layers.
- the outer layer may contain carbon.
- the tube has improved UV resistance, and even when the tube is placed under external light, the tube is prevented from deteriorating and the control effect of controlling pests in the outer layer is reduced. Can be prevented.
- the synthetic resin pipe according to the present invention only the outer layer and the inner layer excluding the intermediate layer are formed of the control layer for controlling pests, thereby reducing the area of the control layer that increases the cost of the pipe and the manufacturing cost. And can control pests inside and outside the tube.
- FIG. 1 shows an embodiment of a synthetic resin pipe according to the present invention.
- Reference numeral 1 in the figure denotes a synthetic resin tube having a controllability for controlling pests.
- the pipe 1 is, for example, a pipe that accommodates and protects wiring / piping material (wiring material or piping material), and is buried in the ground, buried in a concrete structure, or exposed.
- the tube 1 includes a tube wall having an outer layer 2, an inner layer 3 and an intermediate layer 4.
- tube 1 consists of a control layer which only the outer layer 2 and the inner layer 3 except the intermediate
- the thickness of the outer layer 2 and the thickness of the inner layer 3 are the same as or thinner than the thickness of the intermediate layer 4, respectively.
- the thickness of the inner layer 3 is equal to or less than the thickness of the intermediate layer 4, and the thickness of the outer layer 2 is equal to or less than the thickness of the inner layer 3. That is, the inner layer 3 only needs to have a thickness such that the depth of scratches on the inner surface when the wiring / pipe material is inserted into the tube 1 does not reach the intermediate layer 4. It may be the same as or thinner than the thickness of 4.
- the outer surface of the tube 1 (the surface of the outer layer 2) is not damaged as much as the inner surface (the surface of the inner layer 3). For this reason, the thickness of the outer layer 2 is the same as or thinner than that of the inner layer 3. It doesn't matter.
- the tube 1 is a corrugated tube having flexibility.
- tube 1 consists of three layers, the outer wall 2, the inner layer 3, and the intermediate
- the outer layer 2 and the inner layer 3 are formed by containing a control agent for controlling pests.
- the outer layer 2 and the inner layer 3 are each molded with a control agent for controlling pests, for example, enclosed in microcapsules and kneaded with a synthetic resin material such as vinyl chloride resin or polyethylene resin as a base. Is done.
- the outer layer 2 contains carbon.
- the intermediate layer 4 is formed of a synthetic resin material such as a vinyl chloride resin or a polyethylene resin without containing a control agent for controlling pests.
- the control agent in the outer layer 2 and the inner layer 3 is an insect repellent for preventing white ants from being damaged, that is, an ant repellent
- the component of the ant repellent is, for example, a neonicotinoid compound such as clothianidin. Or a pyrethroid compound, an organic phosphorus agent, a carbamate agent, a boron compound, a fluorine compound, or the like. That is, the outer layer 2 and the inner layer 3 are made of an ant-proof layer as a control layer, and these ant-proof layers are formed containing an ant-proof agent.
- the outer layer 2 and the inner layer 3 are formed of a control layer for controlling pests, whereby pests can be controlled inside and outside the tube 1.
- middle layer 4 is not a control layer, the area
- the white ants progress along the outer surface or the inner surface of the tube 1 and enter the house or the like. It is possible to prevent the outer layer 2 and the inner layer 3 from being broken.
- the thickness of the outer layer 2 and the inner layer 3 is the same as or thinner than the thickness of the intermediate layer 4, or the thickness of the inner layer 3 is the same as or thinner than the thickness of the intermediate layer 4,
- the thickness of the outer layer 2 is the same as or thinner than the thickness of the inner layer 3. In this way, by limiting the thickness of the outer layer 2 and the inner layer 3 made of the ant-proof layer (control layer), the area of the ant-control layer (control layer) that increases the cost in the pipe 1 can be surely reduced.
- the outer layer 2 contains carbon.
- the tube 1 has improved anti-ultraviolet characteristics, and even when the tube 1 is disposed under external light, the tube 1 prevents deterioration of the tube 1 and controls white ants in the outer layer 2. Decrease in effect (control effect for controlling pests) can be prevented.
- control agent in the outer layer 2 and the inner layer 3 may be anything that controls pests, and is not limited to an anti-anticide, but is an insecticide, for example, an antifungal agent containing capsaicins, etc. It may be a drug. That is, the insect control layer may be an insect repellent layer or an antifungal layer, etc., instead of the ant preventive layer.
- the outer layer 2 and the inner layer 3 are formed by kneading a control agent for controlling pests together with a synthetic resin material as a base. Both or either one may be formed by applying a coating solution containing a control agent to the outer surface or the inner surface of the intermediate layer 4 and curing the coating solution to form a film.
- the coating liquid is, for example, a mixture of a control agent in a synthetic resin or the like, and specifically includes a binder resin, a volatile solvent, and a control agent, and the volatile solvent is volatilized after application. The coating solution is cured to form a film.
- the pipe body including the intermediate layer 4 is formed by blow molding, and at the time of the blow molding, the coating liquid is sprayed to the outside or the inside to thereby apply the coating liquid.
- the outer layer 2 or the inner layer 3 can be formed by applying to the outer surface or inner surface of the tube body.
- the outer layer 2 and the inner layer 3 are made of ant-proof layers as control layers, but these ant-proof layers may be formed of nylon resin. That is, the outer layer 2 and the inner layer 3 made of nylon resin are hard, and white ants cannot easily break through the outer layer 2 and the inner layer 3.
- the inner layer 3 on the inner side is an ant-proof layer, so that further erosion by the white ants would occur. I can stop.
- the white ants can be controlled inside and outside the pipe 1 by the outer layer 2 and the inner layer 3 being made of ant protection layers (control layers) that control the white ants (pests).
- middle layer 4 is not an ant-proof layer (control layer)
- tube 1 can be reduced. That is, according to the tube 1 made of synthetic resin, only the outer layer 2 and the inner layer 3 except the intermediate layer 4 are formed of an ant protection layer (control layer) that controls white ants (pests), thereby reducing the cost of the tube 1. It is possible to reduce the manufacturing cost by reducing the area of the high ant protection layer, and to control white ants inside and outside the pipe 1. In addition, since only the outer layer 2 and the inner layer 3 are formed of nylon resin, the flexibility of the tube 1 can be improved as compared with the case where the entire tube 1 is formed of nylon resin. Moreover, if the ant-proof layer (control layer) used as the outer layer 2 does not contain an ant-control agent (control agent), there is no possibility that the ant-control agent (control agent) will melt into soil or the like.
- the ant-proof layer which becomes the outer layer 2 and the inner layer 3 may be formed by adding a lubricant to a polyolefin resin. That is, the surface of the outer layer 2 and the inner layer 3 formed by adding a lubricant to the polyolefin resin is slippery, and white ants cannot easily break through the outer layer 2 and the inner layer 3.
- the inner layer 3 on the inner side is an ant-proof layer, so that further erosion by the white ants would occur. I can stop.
- the white ants can be controlled inside and outside the pipe 1 by the outer layer 2 and the inner layer 3 being made of ant protection layers (control layers) that control the white ants (pests).
- middle layer 4 is not an ant-proof layer (control layer)
- tube 1 can be reduced. That is, according to the tube 1 made of synthetic resin, only the outer layer 2 and the inner layer 3 except the intermediate layer 4 are formed of an ant protection layer (control layer) that controls white ants (pests), thereby reducing the cost of the tube 1. It is possible to reduce the manufacturing cost by reducing the area of the high ant protection layer, and to control white ants inside and outside the pipe 1.
- the ant-proof layer (control layer) used as the outer layer 2 does not contain an ant-control agent (control agent), there is no possibility that the ant-control agent (control agent) will melt into soil or the like.
- the polyolefin-based resin include polyethylene resin and polypropylene resin, but are not limited thereto.
- the lubricant include, but are not limited to, fluorine-based, silicone-based, or fatty acid amide-based lubricants.
- the ant-proof layer used as the outer layer 2 is formed of a nylon resin, or is formed by adding a lubricant to a polyolefin resin, and the ant-proof layer used as the inner layer 3 is formed containing an ant-proof agent. Also good.
- the outer layer 2 formed of a nylon resin the outer layer 2 is hard, and white ants cannot easily break through the outer layer 2, and the outer layer 2 is formed by adding a lubricant to the polyolefin resin.
- the surface of the outer layer 2 is slippery, and white ants cannot easily break through the outer layer 2.
- the white ants advance along the inner surface of the tube 1 to enter a house or the like, or eat away the inner layer 3 of the tube 1. Can be prevented.
- the inner layer 3 on the inner side is an ant-proof layer, so that further erosion by the white ants would occur. I can stop.
- the white ants can be controlled inside and outside the pipe 1 by the outer layer 2 and the inner layer 3 being made of ant protection layers (control layers) that control the white ants (pests).
- middle layer 4 is not an ant-proof layer (control layer)
- tube 1 can be reduced. That is, according to the tube 1 made of synthetic resin, only the outer layer 2 and the inner layer 3 except the intermediate layer 4 are formed of an ant protection layer (control layer) that controls white ants (pests), thereby reducing the cost of the tube 1. It is possible to reduce the manufacturing cost by reducing the area of the high ant protection layer, and to control white ants inside and outside the pipe 1. Moreover, although the inner layer 3 contains an ant preventive agent (control agent), the ant preventive agent is blocked by the intermediate layer 4 and is not likely to be dissolved into the external soil or the like. That is, the intermediate layer 4 serves as an outflow prevention layer that prevents outflow of the termite-proofing agent (controlling agent).
- the various ant protection layers (control layers) described above in the outer layer 2 and the inner layer 3 can be arbitrarily combined, and are not limited to the combinations described above.
- the thickness of the outer layer 2 and the inner layer 3 is not limited to the above-described range.
- outer layer 2 contains carbon, but this carbon may not be contained.
- the intermediate layer 4 may not be a single layer but may be composed of a plurality of layers made of different materials.
- the pipe 1 may be a drain hose or the like that allows water to flow into the pipe, instead of accommodating and protecting the wiring / pipe material.
- tube 1 consists of a corrugated pipe
- tube may be formed in a helical form other than the recessed part and convex part which comprise the wave being formed in a ring shape.
- the tube 1 may be a smooth tube instead of a corrugated tube.
- tube 1 is provided with flexibility, it is not necessary to provide this flexibility.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Laminated Bodies (AREA)
- Building Environments (AREA)
- Sewage (AREA)
Abstract
L'invention concerne un tube de résine synthétique, lequel tube est conçu de telle sorte que le coût de fabrication peut être réduit et de telle sorte que des organismes nuisibles peuvent être régulés sur l'intérieur et l'extérieur du tube. Un tube (1) est constitué par une résine synthétique et comporte une paroi de tube ayant une couche externe (2), une couche interne (3), et une couche intermédiaire (4). Seules la couche externe (2) et la couche interne (3) du tube (1), à l'exclusion de la couche intermédiaire (4) du tube (1), comprennent des couches de régulation (par exemple, des couches de régulation de termites pour lutter contre les termites) pour lutter contre des organismes nuisibles. La région des couches de contrôle du tube (1), qui augmente le coût, peut être réduite en raison du fait que la couche intermédiaire (4) n'est pas une couche de régulation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201580001878.XA CN107530999A (zh) | 2015-10-02 | 2015-11-26 | 合成树脂制的管 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015196752A JP6797518B2 (ja) | 2015-10-02 | 2015-10-02 | 合成樹脂製の管の製造方法 |
JP2015-196752 | 2015-10-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2017056339A1 true WO2017056339A1 (fr) | 2017-04-06 |
Family
ID=58422847
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2015/083193 WO2017056339A1 (fr) | 2015-10-02 | 2015-11-26 | Tube de résine synthétique |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP6797518B2 (fr) |
CN (2) | CN113352714A (fr) |
TW (1) | TWI721963B (fr) |
WO (1) | WO2017056339A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6329004B2 (ja) * | 2014-06-02 | 2018-05-23 | 未来工業株式会社 | 流体管 |
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2015
- 2015-10-02 JP JP2015196752A patent/JP6797518B2/ja active Active
- 2015-11-26 CN CN202110630273.4A patent/CN113352714A/zh active Pending
- 2015-11-26 WO PCT/JP2015/083193 patent/WO2017056339A1/fr active Application Filing
- 2015-11-26 CN CN201580001878.XA patent/CN107530999A/zh active Pending
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2016
- 2016-01-19 TW TW105101527A patent/TWI721963B/zh active
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JPS5682382U (fr) * | 1979-11-28 | 1981-07-03 | ||
JPH05174635A (ja) * | 1991-12-20 | 1993-07-13 | Fujikura Ltd | 防蟻電線・ケーブル |
JPH09213137A (ja) * | 1996-01-30 | 1997-08-15 | Showa Electric Wire & Cable Co Ltd | 防蟻電線・ケーブル |
JPH1182862A (ja) * | 1997-08-29 | 1999-03-26 | Inoac Corp | 可撓性ホース |
JP2015113959A (ja) * | 2013-12-13 | 2015-06-22 | 未来工業株式会社 | 合成樹脂製の管 |
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TW201713498A (zh) | 2017-04-16 |
CN107530999A (zh) | 2018-01-02 |
JP6797518B2 (ja) | 2020-12-09 |
CN113352714A (zh) | 2021-09-07 |
JP2017067263A (ja) | 2017-04-06 |
TWI721963B (zh) | 2021-03-21 |
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