WO2016141911A8 - Verfahren zur herstellung von polyharnstoff-verdickten schmierfetten auf basis von lignin-derivaten, derartige schmierfette und deren verwendung - Google Patents

Verfahren zur herstellung von polyharnstoff-verdickten schmierfetten auf basis von lignin-derivaten, derartige schmierfette und deren verwendung Download PDF

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Publication number
WO2016141911A8
WO2016141911A8 PCT/DE2016/000100 DE2016000100W WO2016141911A8 WO 2016141911 A8 WO2016141911 A8 WO 2016141911A8 DE 2016000100 W DE2016000100 W DE 2016000100W WO 2016141911 A8 WO2016141911 A8 WO 2016141911A8
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WO
WIPO (PCT)
Prior art keywords
greases
preparation
thickened
polyurea
lignin derivative
Prior art date
Application number
PCT/DE2016/000100
Other languages
English (en)
French (fr)
Other versions
WO2016141911A1 (de
WO2016141911A9 (de
Inventor
Thomas Litters
Florian Hahn
Torsten Goerz
Hans Jürgen ERKEL
Original Assignee
Fuchs Petrolub Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES16717236T priority Critical patent/ES2765670T3/es
Priority to KR1020177028506A priority patent/KR20170133374A/ko
Application filed by Fuchs Petrolub Se filed Critical Fuchs Petrolub Se
Priority to RU2017133625A priority patent/RU2712238C2/ru
Priority to BR112017019392-2A priority patent/BR112017019392B1/pt
Priority to PL16717236T priority patent/PL3268455T3/pl
Priority to CN201680015119.3A priority patent/CN107429192B/zh
Priority to EP16717236.0A priority patent/EP3268455B1/de
Priority to CA2978121A priority patent/CA2978121C/en
Priority to MX2017011566A priority patent/MX2017011566A/es
Priority to JP2017547577A priority patent/JP6710698B2/ja
Priority to AU2016228615A priority patent/AU2016228615B2/en
Priority to US15/556,602 priority patent/US10604721B2/en
Publication of WO2016141911A1 publication Critical patent/WO2016141911A1/de
Publication of WO2016141911A8 publication Critical patent/WO2016141911A8/de
Publication of WO2016141911A9 publication Critical patent/WO2016141911A9/de
Priority to HK18106523.3A priority patent/HK1246821A1/zh

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/06Mixtures of thickeners and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M115/00Lubricating compositions characterised by the thickener being a non-macromolecular organic compound other than a carboxylic acid or salt thereof
    • C10M115/08Lubricating compositions characterised by the thickener being a non-macromolecular organic compound other than a carboxylic acid or salt thereof containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M119/00Lubricating compositions characterised by the thickener being a macromolecular compound
    • C10M119/24Lubricating compositions characterised by the thickener being a macromolecular compound containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M151/00Lubricating compositions characterised by the additive being a macromolecular compound containing sulfur, selenium or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M151/00Lubricating compositions characterised by the additive being a macromolecular compound containing sulfur, selenium or tellurium
    • C10M151/04Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/02Mixtures of base-materials and thickeners
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • C10M2203/1025Aliphatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12Polysaccharides, e.g. cellulose, biopolymers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/10Amides of carbonic or haloformic acids
    • C10M2215/102Ureas; Semicarbazides; Allophanates
    • C10M2215/1023Ureas; Semicarbazides; Allophanates used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/10Amides of carbonic or haloformic acids
    • C10M2215/102Ureas; Semicarbazides; Allophanates
    • C10M2215/1026Ureas; Semicarbazides; Allophanates used as thickening material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045Polyureas; Polyurethanes
    • C10M2217/0456Polyureas; Polyurethanes used as thickening agents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/04Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2221/041Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving sulfurisation of macromolecular compounds, e.g. polyolefins
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/02Viscosity; Viscosity index
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/02Bearings
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2070/00Specific manufacturing methods for lubricant compositions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur Herstellung von Schmierfetten auf Basis von Lignin-Derivaten verdickt durch einen Polyharnstoffverdicker, so hergestellte Schmierfette und die Verwendung solcher Schmierfette u.a. in Getrieben, Gleichlaufgelenkwellen und gedichteten Wälzlagern.
PCT/DE2016/000100 2015-03-09 2016-03-09 Verfahren zur herstellung von polyharnstoff-verdickten schmierfetten auf basis von lignin-derivaten, derartige schmierfette und deren verwendung WO2016141911A1 (de)

Priority Applications (13)

Application Number Priority Date Filing Date Title
MX2017011566A MX2017011566A (es) 2015-03-09 2016-03-09 Metodo para la preparacion de grasas lubricantes espesadas con poliurea, a base de derivados de lignina, esas grasas lubricantes y usos de las mismas.
CA2978121A CA2978121C (en) 2015-03-09 2016-03-09 Method for preparing lignin derivative-based, polyurea-thickened lubricating greases, such lubricant greases and use thereof
RU2017133625A RU2712238C2 (ru) 2015-03-09 2016-03-09 Способ получения загущенных полимочевиной консистентных смазок на основе производных лигнина, консистентные смазки и их применение
KR1020177028506A KR20170133374A (ko) 2015-03-09 2016-03-09 폴리우레아-농후화된 리그닌 유도체-유래의 윤활 그리스의 제조 방법, 그러한 윤활 그리스 및 그의 사용
PL16717236T PL3268455T3 (pl) 2015-03-09 2016-03-09 Sposób wytwarzania zagęszczonych polimocznikiem smarów stałych na bazie pochodnych ligniny, takie smary stałe i ich zastosowanie
CN201680015119.3A CN107429192B (zh) 2015-03-09 2016-03-09 木质素衍生聚脲增稠润滑油脂的生产方法、该润滑油脂及其应用
JP2017547577A JP6710698B2 (ja) 2015-03-09 2016-03-09 ポリ尿素により増粘され、リグニン誘導体を基材とする潤滑グリースの調製方法、その潤滑グリース、及びその使用
ES16717236T ES2765670T3 (es) 2015-03-09 2016-03-09 Método para la preparación de grasas lubricantes espesadas con poliurea, a base de derivados de lignina, esas grasas lubricantes y usos de las mismas
BR112017019392-2A BR112017019392B1 (pt) 2015-03-09 2016-03-09 Método para preparar uma graxa lubrificante contendo derivado de lignina, graxa lubrificante e uso da graxa lubrificante
EP16717236.0A EP3268455B1 (de) 2015-03-09 2016-03-09 Verfahren zur herstellung von polyharnstoff-verdickten schmierfetten auf basis von lignin-derivaten, derartige schmierfette und deren verwendung
AU2016228615A AU2016228615B2 (en) 2015-03-09 2016-03-09 Process for the preparation of polyurea-thickened lignin derivative-based lubricating greases, such lubricant greases and use thereof
US15/556,602 US10604721B2 (en) 2015-03-09 2016-03-09 Process for the preparation of polyurea-thickened lignin derivative-based lubricating greases, such lubricant greases and use thereof
HK18106523.3A HK1246821A1 (zh) 2015-03-09 2018-05-18 木質素衍生聚脲增稠潤滑油脂的生產方法、該潤滑油脂及其應用

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102015103440.9 2015-03-09
DE102015103440.9A DE102015103440A1 (de) 2015-03-09 2015-03-09 Verfahren zur Herstellung von Polyharnstoff-verdickten Schmierfetten auf Basis von Lignin-Derivaten, derartige Schmierfette und deren Verwendung

Publications (3)

Publication Number Publication Date
WO2016141911A1 WO2016141911A1 (de) 2016-09-15
WO2016141911A8 true WO2016141911A8 (de) 2016-11-03
WO2016141911A9 WO2016141911A9 (de) 2016-12-29

Family

ID=55794829

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2016/000100 WO2016141911A1 (de) 2015-03-09 2016-03-09 Verfahren zur herstellung von polyharnstoff-verdickten schmierfetten auf basis von lignin-derivaten, derartige schmierfette und deren verwendung

Country Status (16)

Country Link
US (1) US10604721B2 (de)
EP (1) EP3268455B1 (de)
JP (1) JP6710698B2 (de)
KR (1) KR20170133374A (de)
CN (1) CN107429192B (de)
AU (1) AU2016228615B2 (de)
BR (1) BR112017019392B1 (de)
CA (1) CA2978121C (de)
DE (1) DE102015103440A1 (de)
ES (1) ES2765670T3 (de)
HK (1) HK1246821A1 (de)
MX (1) MX2017011566A (de)
PL (1) PL3268455T3 (de)
PT (1) PT3268455T (de)
RU (1) RU2712238C2 (de)
WO (1) WO2016141911A1 (de)

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US20200199481A1 (en) * 2018-12-19 2020-06-25 Exxonmobil Research And Engineering Company Grease compositions having calcium sulfonate and polyurea thickeners
RU2713451C1 (ru) * 2019-10-11 2020-02-05 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Низкотемпературная экологичная пластичная смазка и способ ее получения
WO2021133583A1 (en) * 2019-12-23 2021-07-01 Exxonmobil Research And Engineering Company Method and apparatus for the continuous production of polyurea grease
CN112375607B (zh) * 2020-11-25 2022-09-23 青岛中科润美润滑材料技术有限公司 一种四脲润滑脂组合物及其制备方法
CN113355148B (zh) * 2021-05-28 2022-12-20 中国石油化工股份有限公司 一种用于汽车驱动轴轮毂轴承结合面的润滑剂及其制法
CN113563944A (zh) * 2021-07-27 2021-10-29 新协同(宁波)油脂有限公司 一种蜗轮蜗杆专用润滑脂及其制备方法
US20230097718A1 (en) * 2021-09-15 2023-03-30 Ingevity South Carolina, Llc Biobased extreme pressure additive for lubricating compositions and associated methods

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BR112017019392A2 (pt) 2018-04-24
US20180258368A1 (en) 2018-09-13
US10604721B2 (en) 2020-03-31
EP3268455A1 (de) 2018-01-17
CA2978121A1 (en) 2016-09-15
ES2765670T3 (es) 2020-06-10
AU2016228615B2 (en) 2020-09-03
WO2016141911A1 (de) 2016-09-15
HK1246821A1 (zh) 2018-09-14
MX2017011566A (es) 2018-05-11
RU2712238C2 (ru) 2020-01-27
EP3268455B1 (de) 2019-10-16
CA2978121C (en) 2023-03-14
KR20170133374A (ko) 2017-12-05
CN107429192A (zh) 2017-12-01
RU2017133625A3 (de) 2019-07-17
WO2016141911A9 (de) 2016-12-29
RU2017133625A (ru) 2019-04-09
PL3268455T3 (pl) 2020-06-01
JP6710698B2 (ja) 2020-06-17
PT3268455T (pt) 2020-01-22
AU2016228615A1 (en) 2017-10-26
CN107429192B (zh) 2020-10-16
BR112017019392B1 (pt) 2021-12-14

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