WO2016129679A1 - 化合物、樹脂、リソグラフィー用下層膜形成材料、リソグラフィー用下層膜形成用組成物、リソグラフィー用下層膜、レジストパターン形成方法、回路パターン形成方法及び化合物又は樹脂の精製方法 - Google Patents
化合物、樹脂、リソグラフィー用下層膜形成材料、リソグラフィー用下層膜形成用組成物、リソグラフィー用下層膜、レジストパターン形成方法、回路パターン形成方法及び化合物又は樹脂の精製方法 Download PDFInfo
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- 0 C[N+](c(c(C(c(cc1)ccc1-c1ccccc1)c1c(*N)ccc(-c2ccc(*N)cc2)c1)c1)ccc1-c(cc1)ccc1N=O)[O-] Chemical compound C[N+](c(c(C(c(cc1)ccc1-c1ccccc1)c1c(*N)ccc(-c2ccc(*N)cc2)c1)c1)ccc1-c(cc1)ccc1N=O)[O-] 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N c(cc1)cc2c1cccc2 Chemical compound c(cc1)cc2c1cccc2 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 3
- UMRZSTCPUPJPOJ-UHFFFAOYSA-N C(C1)C2CC1CC2 Chemical compound C(C1)C2CC1CC2 UMRZSTCPUPJPOJ-UHFFFAOYSA-N 0.000 description 1
- BWRRUOFLSXVDGW-UHFFFAOYSA-N C(C1)CC2(CC3)C1CC3C2 Chemical compound C(C1)CC2(CC3)C1CC3C2 BWRRUOFLSXVDGW-UHFFFAOYSA-N 0.000 description 1
- KHXRDBYDEUWHPC-FIOFKEMQSA-N C/C=C\C(\c1ccccc1)=C/C=C Chemical compound C/C=C\C(\c1ccccc1)=C/C=C KHXRDBYDEUWHPC-FIOFKEMQSA-N 0.000 description 1
Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
- G03F7/094—Multilayer resist systems, e.g. planarising layers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
- C07C43/275—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings having all ether-oxygen atoms bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/34—Separation; Purification; Stabilisation; Use of additives
- C07C41/38—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
- C07C43/205—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring the aromatic ring being a non-condensed ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/235—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring and to a carbon atom of a ring other than a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
- G03F7/11—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having cover layers or intermediate layers, e.g. subbing layers
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/16—Coating processes; Apparatus therefor
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/30—Imagewise removal using liquid means
Definitions
- the present invention relates to a compound or resin having a specific structure.
- the present invention also relates to a material for forming a lower layer film for lithography containing these, a composition containing the material, a lower layer film for lithography obtained from the composition, and a resist or circuit pattern forming method using the composition. Furthermore, it is related with the purification method of the said compound or resin.
- the light source for lithography used for resist pattern formation is shortened from KrF excimer laser (248 nm) to ArF excimer laser (193 nm).
- KrF excimer laser 248 nm
- ArF excimer laser (193 nm)
- simply thinning the resist makes it difficult to obtain a resist pattern film thickness sufficient for substrate processing. Therefore, not only a resist pattern but also a process in which a resist underlayer film is formed between the resist and a semiconductor substrate to be processed and the resist underlayer film also has a function as a mask during substrate processing has become necessary.
- a material for forming an underlayer film for a multilayer resist process contains at least a resin component having a substituent that generates a sulfonic acid residue and a solvent (see Japanese Patent Application Laid-Open No. 2004-177668).
- a resist underlayer film material including a polymer having a specific repeating unit has been proposed as a material for realizing a resist underlayer film for lithography having a lower dry etching rate selection ratio than that of a resist (Patent Document 2 below).
- Patent Document 2 Japanese Patent Application Laid-Open No. 2004-271838).
- a repeating unit of acenaphthylenes and a repeating unit having a substituted or unsubstituted hydroxy group are copolymerized.
- a resist underlayer film material containing a polymer is proposed (see Patent Document 3 below: Japanese Patent Laid-Open No. 2005-250434).
- an amorphous carbon underlayer film formed by CVD using methane gas, ethane gas, acetylene gas or the like as a raw material is well known.
- a resist underlayer film material capable of forming a resist underlayer film by a wet process such as spin coating or screen printing is required.
- the inventors of the present invention provide a lithographic lower layer containing a naphthalene formaldehyde polymer containing a specific structural unit and an organic solvent as a material that is excellent in optical characteristics and etching resistance and is soluble in a solvent and applicable to a wet process.
- a film-forming composition (see Patent Document 4: International Publication No. 2009/072465 and Patent Document 5: International Publication No. 2011/034062) is proposed.
- a silicon nitride film formation method for example, a silicon nitride film formation method (see Patent Document 6 below: Japanese Patent Laid-Open No. 2002-334869), a silicon nitride film The following CVD formation method (see Patent Document 7: International Publication No. 2004/066377) is known.
- a material containing a silsesquioxane-based silicon compound is known (Patent Document 8: JP 2007-226170 A and Patent Document 9 below: -226204).
- the present invention has been made in view of the above-mentioned problems, and its purpose is to form a photoresist underlayer film that is applicable to a compound or resin having a specific structure, a wet process, and excellent in heat resistance and etching resistance.
- a composition containing the material, a lower layer film for lithography obtained from the composition a method for forming a resist or circuit pattern using the composition, and the compound or resin It is to provide a purification method.
- a compound represented by the following formula (1) (In the formula (1), R 1 is a 2n-valent group having 1 to 30 carbon atoms, and R 2 to R 5 are each independently an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms.
- An alkoxy group, m 2 and m 3 are each independently an integer of 0 to 8, and m 4 and m 5 are each independently an integer of 0 to 9, provided that m 4 and m 5 are (At the same time, it is not 0, n is an integer of 1 to 4, and p 2 to p 5 are each independently an integer of 0 to 2.)
- [2] The compound according to [1], wherein at least one of R 2 and / or at least one of R 3 is an alkoxy group having 1 to 30 carbon atoms.
- the compound according to [1] or [2], wherein the compound represented by the formula (1) is a compound represented by the following formula (1a).
- R 1 to R 5 and n are as defined in the formula (1), m 2 ′ and m 3 ′ are each independently an integer of 0 to 4, m 4 ′ and m 5 ′ are each independently an integer of 0 to 5, provided that m 4 ′ and m 5 ′ are not 0 at the same time.
- [4] The compound according to [3], wherein the compound represented by the formula (1a) is a compound represented by the following formula (1b).
- R 1 has the same meaning as that described in Formula (1) above, and R 6 and R 7 are each independently an alkyl group having 1 to 10 carbon atoms, or 6 to 10 carbon atoms.
- An aryl group, an alkenyl group having 2 to 10 carbon atoms, a thiol group, or a hydroxyl group, and R 8 to R 11 are each independently an alkyl group having 1 to 30 carbon atoms or a hydrogen atom, provided that R 8 At least one of —R 11 is an alkyl group having 1 to 30 carbon atoms, and m 6 and m 7 are each independently an integer of 0 to 7.) [5]
- the compound according to [4], wherein the compound represented by the formula (1b) is represented by the following formula (BiF-1-CH).
- each R 12 is independently a cyclohexyl group or a hydrogen atom, provided that at least one of R 12 is a cyclohexyl group.
- the crosslinkable compound is at least one selected from the group consisting of aldehydes, ketones, carboxylic acids, carboxylic acid halides, halogen-containing compounds, amino compounds, imino compounds, isocyanates, and unsaturated hydrocarbon group-containing compounds.
- the resin as described in [7] above.
- the resin according to [6] which has a structure represented by the following formula (2).
- R 1 is a 2n-valent group having 1 to 30 carbon atoms
- R 2 to R 5 are each independently an alkyl group having 1 to 10 carbon atoms, 6 to 10 carbon atoms, An aryl group, an alkenyl group having 2 to 10 carbon atoms, an alkoxy group having 1 to 30 carbon atoms, a thiol group, or a hydroxyl group, provided that at least one of R 4 and / or at least one of R 5 has 1 carbon atom Is an alkoxy group having 1 to 30;
- L is a linear or branched alkylene group having 1 to 20 carbon atoms or a single bond; and
- m 2 and m 3 are each independently an integer of 0 to 8.
- a material for forming an underlayer film for lithography comprising the compound according to any one of [1] to [5] and / or the resin according to any one of [6] to [9].
- a composition for forming an underlayer film for lithography comprising the material for forming an underlayer film for lithography as described in [10] above and a solvent.
- composition for forming a lower layer film for lithography as described in [11] or [12], further including an acid generator.
- a lithography lower layer film formed from the composition for forming a lithography lower layer film according to any one of [11] to [13].
- a lower layer film is formed on the substrate using the lower layer film forming composition according to any one of [11] to [13], and at least one photoresist layer is formed on the lower layer film.
- a resist pattern forming method in which, after formation, a predetermined region of the photoresist layer is irradiated with radiation and developed.
- a lower layer film is formed on the substrate using the lower layer film forming composition according to any one of [11] to [13], and a resist intermediate layer containing silicon atoms is formed on the lower layer film
- An intermediate layer film is formed by using a film material, and at least one photoresist layer is formed on the intermediate layer film, and then a predetermined region of the photoresist layer is irradiated with radiation and developed to form a resist pattern. Then, the intermediate layer film is etched using the resist pattern as a mask, the lower layer film is etched using the obtained intermediate layer film pattern as an etching mask, and the substrate is formed using the obtained lower layer film pattern as an etching mask.
- the acidic aqueous solution is one or more mineral acid aqueous solutions selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid and phosphoric acid, or acetic acid, propionic acid, succinic acid, malonic acid, succinic acid, fumaric acid, maleic acid
- the purification method according to the above [17] which is one or more organic acid aqueous solutions selected from the group consisting of tartaric acid, citric acid, methanesulfonic acid, phenolsulfonic acid, p-toluenesulfonic acid and trifluoroacetic acid.
- a compound or resin having a specific structure, a wet process can be applied, and it is useful for forming a photoresist underlayer film having excellent heat resistance and etching resistance. It is possible to provide a composition containing materials, an underlayer film for lithography obtained from the composition, a method for forming a resist or circuit pattern using the composition, and a method for purifying the compound or resin.
- the compound of the present invention is represented by the following formula (1). Since the compound of the present invention is thus configured, it has high heat resistance, a relatively high carbon concentration, a relatively low oxygen concentration, and a high solvent solubility.
- R 1 is a 2n-valent group having 1 to 30 carbon atoms, and each aromatic ring is bonded through this R 1 .
- Examples of the 2n-valent group include those having a linear hydrocarbon group, a branched hydrocarbon group, or an alicyclic hydrocarbon group.
- the alicyclic hydrocarbon group includes a bridged alicyclic hydrocarbon group.
- the 2n-valent group may have a double bond, a hetero atom, or an aromatic group having 6 to 30 carbon atoms.
- R 2 to R 5 each independently represents an alkyl group having 1 to 10 carbon atoms; an aryl group having 6 to 10 carbon atoms; an alkenyl group having 2 to 10 carbon atoms; 1 to 30 carbon atoms
- at least one of R 4 and / or at least one of R 5 is an alkoxy group having 1 to 30 carbon atoms.
- n is an integer of 1 to 4.
- p 2 to p 5 are each independently an integer of 0 to 2. Incidentally, for example, if p 2 is 0, the corresponding aromatic ring becomes a benzene ring, the corresponding aromatic ring is a naphthalene ring when p2 is 1. Further, when p2 is 3, the corresponding aromatic ring is a three-membered aromatic ring such as anthracene.
- the alkyl group having 1 to 10 carbon atoms and the alkenyl group having 2 to 10 carbon atoms include linear, branched or cyclic alkyl groups or alkenyl groups.
- the alkoxy group having 1 to 30 carbon atoms is selected from a linear hydrocarbon group, a branched hydrocarbon group, an alicyclic hydrocarbon group, an aromatic hydrocarbon group, and a group consisting of a combination of two or more thereof.
- the alicyclic hydrocarbon group includes a bridged alicyclic hydrocarbon group.
- the alkoxy group may have a double bond, a hetero atom, or a halogen atom.
- the alkoxy group having 1 to 30 carbon atoms is preferably a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentyloxy group, a hexyloxy group, a cyclobutyloxy group, a cyclopentyloxy group, a cyclohexyloxy group, or a cyclohexenyloxy group.
- the compound represented by the formula (1) has a relatively low molecular weight, but has high heat resistance due to the rigidity of its structure, and therefore can be used under high temperature baking conditions.
- the substrate has a relatively low molecular weight and low viscosity, it is easy to uniformly fill every corner of a step even on a substrate having a step (particularly, a fine space or a hole pattern).
- the material for forming a lower layer film for lithography using the same can be relatively advantageously enhanced in embedding characteristics and planarization characteristics.
- it is a compound having a relatively high carbon concentration, high etching resistance is also imparted.
- it since it has an alkoxy group having 1 to 30 carbon atoms, further solvent solubility and quality stabilization are achieved.
- the compound represented by the formula (1) is an alkoxy group in which at least one of R 2 and / or at least one of R 3 has 1 to 30 carbon atoms from the viewpoint of easy crosslinking and solubility in an organic solvent. It is preferable that In addition, when R 2 and R 3 are an aryl group having 6 to 10 carbon atoms having a substituent, the substituent is preferably a substituent not containing an oxygen atom.
- the compound represented by the formula (1) is more preferably a compound represented by the following formula (1a) from the viewpoint of raw material supply.
- R 1 to R 5 and n have the same meaning as described in the formula (1).
- m 2 ′ and m 3 ′ are each independently an integer of 0 to 4
- m 4 ′ and m 5 ′ are each independently an integer of 0 to 5.
- m 4 ′ and m 5 ′ are not 0 at the same time.
- the compound represented by the formula (1a) is more preferably a compound represented by the following formula (1b) from the viewpoint of solubility in an organic solvent.
- R 6 and R 7 are each independently an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, a thiol group, or a hydroxyl group.
- R 8 to R 11 are each independently an alkyl group having 1 to 30 carbon atoms or a hydrogen atom.
- R 8 to R 11 is an alkyl group having 1 to 30 carbon atoms.
- the above alkyl group and alkenyl group may be linear, branched or cyclic.
- m 6 and m 7 are each independently an integer of 0 to 7.
- the compound represented by the formula (1b) is particularly preferably a compound represented by the following formula (BiF-1-CH) from the viewpoint of further solubility in an organic solvent.
- R 12 are each independently a cyclohexyl group or a hydrogen atom from the viewpoint of quality stabilization. However, at least one of R 12 is a cyclohexyl group.
- R 2 to R 5 have the same meanings as described in the formula (1), m 8 and m 9 are each independently an integer of 0 to 6, m 10 and m 11 Are each independently an integer of 0 to 7. However, m 10 and m 11 are not 0 at the same time.
- R 2 to R 5 have the same meanings as described in the formula (1).
- m 2 ′ and m 3 ′ are each independently an integer of 0 to 4
- m 4 ′ and m 5 ′ are each independently an integer of 0 to 5.
- m 4 ′ and m 5 ′ are not 0 at the same time.
- R 2 to R 5 have the same meanings as described in the formula (1), m 8 and m 9 are each independently an integer of 0 to 6, and m 10 and m 11 are Each independently represents an integer of 0 to 7. However, m 10 and m 11 are not 0 at the same time.
- R 2 to R 5 have the same meanings as described in the formula (1).
- m 2 ′ and m 3 ′ are each independently an integer of 0 to 4
- m 4 ′ and m 5 ′ are each independently an integer of 0 to 5.
- m 4 ′ and m 5 ′ are not 0 at the same time.
- R 12 has the same meaning as described for the formula (BiF-1-CH).
- the compound represented by the formula (1) used in the present invention can be appropriately synthesized by applying a known technique, and the synthesis technique is not particularly limited.
- the above-mentioned formula can be obtained by subjecting biphenols, bithiophenols, binaphthols, bithionaphthols or bianthraceneol and a corresponding aldehyde or ketone to a polycondensation reaction under an acid catalyst under normal pressure.
- a compound that is a precursor of the compound represented by (1) (a compound in which at least one of R 4 and / or at least one of R 5 that is an alkoxy group having 1 to 30 carbon atoms is a hydroxyl group in the formula (1) ) Can be obtained. Moreover, it can also carry out under pressure as needed.
- biphenols examples include, but are not limited to, biphenol, methyl biphenol, methoxy binaphthol, and the like. These can be used individually by 1 type or in combination of 2 or more types. Among these, it is more preferable to use biphenol from the viewpoint of stable supply of raw materials.
- bithiophenols examples include, but are not limited to, bithiophenol, methylbithiophenol, methoxybithiophenol, and the like. These can be used individually by 1 type or in combination of 2 or more types. Among these, it is more preferable to use bithiophenol from the viewpoint of stable supply of raw materials.
- binaphthols examples include, but are not limited to, binaphthol, methyl binaphthol, methoxy binaphthol, and the like. These can be used alone or in combination of two or more. Among these, it is more preferable to use binaphthol in terms of increasing the carbon atom concentration and improving heat resistance.
- bithionaphthols examples include, but are not limited to, bithionaphthol, methylbithionaphthol, methoxybithionaphthol, and the like. These can be used alone or in combination of two or more. Among these, it is more preferable to use bithionaphthol in terms of increasing the carbon atom concentration and improving heat resistance.
- aldehydes examples include formaldehyde, trioxane, paraformaldehyde, acetaldehyde, propylaldehyde, butyraldehyde, hexylaldehyde, decylaldehyde, undecylaldehyde, phenylacetaldehyde, phenylpropylaldehyde, furfural, benzaldehyde, hydroxybenzaldehyde, fluorobenzaldehyde, Chlorobenzaldehyde, Nitrobenzaldehyde, Methylbenzaldehyde, Dimethylbenzaldehyde, Ethylbenzaldehyde, Propylbenzaldehyde, Butylbenzaldehyde, Cyclohexylbenzaldehyde, Benzaldehyde, Hydroxybenzaldehyde, Fluorobenzaldehyde, Chlorobenzaldehyde
- ketones examples include acetone, methyl ethyl ketone, cyclobutanone, cyclopentanone, cyclohexanone, norbornanone, tricyclohexanone, tricyclodecanone, adamantanone, fluorenone, benzofluorenone, acenaphthenequinone, acenaphthenone, anthraquinone, and the like. However, it is not particularly limited to these. These can be used alone or in combination of two or more.
- cyclopentanone cyclohexanone, norbornanone, tricyclohexanone, tricyclodecanone, adamantanone, fluorenone, benzofluorenone, acenaphthenequinone, acenaphthenone and anthraquinone from the viewpoint of giving high heat resistance.
- the acid catalyst used in the reaction can be appropriately selected from known ones and is not particularly limited.
- inorganic acids and organic acids are widely known.
- inorganic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, hydrobromic acid, hydrofluoric acid, oxalic acid, malonic acid, and succinic acid.
- Adipic acid sebacic acid, citric acid, fumaric acid, maleic acid, formic acid, p-toluenesulfonic acid, methanesulfonic acid, trifluoroacetic acid, dichloroacetic acid, trichloroacetic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, naphthalenesulfonic acid Organic acids such as naphthalenedisulfonic acid, Lewis acids such as zinc chloride, aluminum chloride, iron chloride, boron trifluoride, or solid acids such as silicotungstic acid, phosphotungstic acid, silicomolybdic acid or phosphomolybdic acid Although it is mentioned, it is not specifically limited to these.
- an organic acid and a solid acid are preferable from the viewpoint of production, and hydrochloric acid or sulfuric acid is preferably used from the viewpoint of production such as availability and ease of handling.
- an acid catalyst 1 type can be used individually or in combination of 2 or more types.
- the amount of the acid catalyst used can be appropriately set according to the raw material used, the type of catalyst used, and the reaction conditions, and is not particularly limited, but is 0.01 to 100 per 100 parts by mass of the reactive raw material. It is preferable that it is a mass part.
- a reaction solvent may be used.
- the reaction solvent is not particularly limited as long as the reaction of aldehydes or ketones to be used with biphenols, bithiophenols, binaphthols, bithionaphthols, or bianthracenediol proceeds. It can be appropriately selected from those used. Examples thereof include water, methanol, ethanol, propanol, butanol, tetrahydrofuran, dioxane, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, or a mixed solvent thereof.
- a solvent can be used individually by 1 type or in combination of 2 or more types.
- the amount of these solvents used can be appropriately set according to the raw material used, the type of catalyst used, and the reaction conditions, and is not particularly limited, but is 0 to 2000 parts by mass with respect to 100 parts by mass of the reaction raw material. It is preferable that it is the range of these.
- the reaction temperature in the reaction can be appropriately selected according to the reactivity of the reaction raw material, and is not particularly limited, but is usually in the range of 10 to 200 ° C.
- the reaction temperature is preferably high, and specifically, a range of 60 to 200 ° C. is preferable.
- the reaction method can be appropriately selected from known methods, and is not particularly limited. However, biphenols, bithiophenols, binaphthols, bithionaphthols or bianthracenediol, aldehydes or ketones, There are a method in which the catalyst is charged all at once, and a method in which biphenols, bithiophenols, binaphthols, bithionaphthols, bianthracenediol, aldehydes, or ketones are dropped in the presence of the catalyst.
- the obtained compound can be isolated according to a conventional method, and is not particularly limited.
- a general method is adopted such as raising the temperature of the reaction vessel to 130-230 ° C. and removing volatile matter at about 1-50 mmHg.
- the target compound can be obtained.
- Preferable reaction conditions are 1.0 mol to excess of biphenols, bithiophenols, binaphthols, bithionaphthols or bianthracenediol, and 0.
- the reaction proceeds by using 001 to 1 mol and reacting at 50 to 150 ° C. for 20 minutes to 100 hours at normal pressure.
- the target product can be isolated by a known method.
- the reaction solution is concentrated, pure water is added to precipitate the reaction product, cooled to room temperature, filtered and separated, and the resulting solid is filtered and dried, followed by column chromatography.
- the compound which becomes the precursor of the compound represented by the formula (1), which is the target product can be obtained by separating and purifying from the by-product, and performing solvent distillation, filtration and drying.
- the obtained precursor compound is represented by the above formula (1).
- the method for replacing the hydrogen atom of the phenolic hydroxyl group with a monovalent group having 1 to 30 carbon atoms is not particularly limited.
- the precursor compound is reacted with a halogenated hydrocarbon compound in the presence of a base catalyst. Can be obtained by dehydrohalogenation reaction.
- the halogenated hydrocarbon compound is not particularly limited, but a halogenated hydrocarbon compound having 1 to 30 carbon atoms is preferably used.
- the halogenated hydrocarbon compound is composed of a linear hydrocarbon group, a branched hydrocarbon group, an alicyclic hydrocarbon group, an aromatic hydrocarbon group, a group composed of two or more thereof, and a halogen atom.
- the alicyclic hydrocarbon group includes a bridged alicyclic hydrocarbon group.
- the halogenated hydrocarbon compound may have a double bond, a hetero atom, or another type of halogen atom.
- Halogenated hydrocarbon compounds include, for example, methyl chloride, methyl bromide, methyl iodide, propyl chloride, propyl bromide, propyl iodide, butyl chloride, butyl bromide, butyl iodide, heptyl chloride, heptyl bromide, iodine
- Examples include heptyl chloride, hexyl chloride, hexyl bromide, hexyl iodide, decyl chloride, decyl bromide, decyl iodide, and a compound selected from the group represented by the following formula (5), but are not particularly limited thereto. . These can be used individually by 1 type or in combination of 2 or more types.
- Y shows a chlorine atom, a bromine atom, or an iodine atom.
- a base catalyst sodium carbonate, potassium carbonate, triethylamine, ammonia, sodium hydroxide, etc.
- 0.1 to 10 mol of the halogenated hydrocarbon compound can be reacted at 0 to 150 ° C. for about 0.5 to 20 hours with respect to 1 mol of the precursor compound.
- the compound represented by the formula (1) can be obtained by filtration, washing with alcohols such as methanol, washing with water, separation by filtration, and drying.
- the compound represented by the formula (1) used in the present embodiment can also be obtained by introducing an alkoxy group into biphenols and the like and then reacting with aldehydes and ketones. There is no particular limitation.
- the compound represented by the formula (1) can be used as it is as a material for forming a lower layer film for lithography. Moreover, it can be used also as resin obtained by using the compound represented by said Formula (1) as a monomer. For example, it can also be used as a resin obtained by reacting a compound represented by the formula (1) with a compound having crosslinking reactivity. Examples of the resin obtained using the compound represented by the formula (1) as a monomer include those having a structure represented by the following formula (2). That is, the lower layer film forming material for lithography of the present embodiment may contain a resin having a structure represented by the following formula (2).
- R 1 to R 5 are m 2 to m 5 , n, and p 2 to p 5 are the same as those described in formula (1).
- L is a linear or branched alkylene group having 1 to 20 carbon atoms or a single bond.
- the compound having crosslinking reactivity a known compound can be used without particular limitation as long as the compound represented by the formula (1) can be oligomerized or polymerized.
- Specific examples of the compound having crosslinking reactivity include aldehyde, ketone, carboxylic acid, carboxylic acid halide, halogen-containing compound, amino compound, imino compound, isocyanate, unsaturated hydrocarbon group-containing compound, and the like. It is not specifically limited to these.
- the compound represented by the formula (1) is novolakized by a condensation reaction with an aldehyde that is a crosslinking-reactive compound. Resin.
- aldehyde for example, formaldehyde, trioxane, paraformaldehyde, benzaldehyde, acetaldehyde, propylaldehyde, phenylacetaldehyde, phenylpropylaldehyde, hydroxybenzaldehyde
- examples thereof include, but are not limited to, chlorobenzaldehyde, nitrobenzaldehyde, methylbenzaldehyde, ethylbenzaldehyde, butylbenzaldehyde, biphenylaldehyde, naphthaldehyde, anthracenecarbaldehyde, phenanthrenecarbaldehyde, pyrenecarbaldehyde, and furfural.
- aldehydes can be used individually by 1 type or in combination of 2 or more types.
- the amount of the aldehyde used is not particularly limited, but is preferably 0.2 to 5 mol, more preferably 0.5 to 2 mol with respect to 1 mol of the compound represented by the formula (1). is there.
- a catalyst may be used.
- the acid catalyst used here can be appropriately selected from known ones and is not particularly limited.
- inorganic acids and organic acids are widely known.
- inorganic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, hydrobromic acid, hydrofluoric acid, oxalic acid, malonic acid, and succinic acid.
- Adipic acid sebacic acid, citric acid, fumaric acid, maleic acid, formic acid, p-toluenesulfonic acid, methanesulfonic acid, trifluoroacetic acid, dichloroacetic acid, trichloroacetic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, naphthalenesulfonic acid Organic acids such as naphthalenedisulfonic acid, Lewis acids such as zinc chloride, aluminum chloride, iron chloride, boron trifluoride, or solid acids such as silicotungstic acid, phosphotungstic acid, silicomolybdic acid or phosphomolybdic acid Although it is mentioned, it is not specifically limited to these.
- organic acids and solid acids are preferable from the viewpoint of production, and hydrochloric acid or sulfuric acid is preferable from the viewpoint of production such as availability and ease of handling.
- an acid catalyst 1 type can be used individually or in combination of 2 or more types.
- the amount of the acid catalyst used can be appropriately set according to the raw material used, the type of catalyst used, and the reaction conditions, and is not particularly limited, but is 0.01 to 100 per 100 parts by mass of the reactive raw material. It is preferable that it is a mass part.
- indene hydroxyindene, benzofuran, hydroxyanthracene, acenaphthylene, biphenyl, bisphenol, trisphenol, dicyclopentadiene, tetrahydroindene, 4-vinylcyclohexene, norbornadiene, 5-vinylnorborna-2-ene, ⁇ -pinene, ⁇ -pinene
- aldehydes are not necessarily required.
- a reaction solvent can also be used.
- the reaction solvent in this polycondensation can be appropriately selected from known solvents and is not particularly limited. Examples thereof include water, methanol, ethanol, propanol, butanol, tetrahydrofuran, dioxane, and mixed solvents thereof. Illustrated.
- a solvent can be used individually by 1 type or in combination of 2 or more types.
- the amount of these solvents used can be appropriately set according to the raw material used, the type of catalyst used, and the reaction conditions, and is not particularly limited, but is 0 to 2000 parts by mass with respect to 100 parts by mass of the reaction raw material. It is preferable that it is the range of these.
- the reaction temperature can be appropriately selected according to the reactivity of the reaction raw material, and is not particularly limited, but is usually in the range of 10 to 200 ° C.
- reaction method can select and use a well-known method suitably, although it does not specifically limit,
- the method of charging the compound represented by said Formula (1), aldehydes, and a catalyst collectively, said Formula (1) There is a method in which a compound or an aldehyde represented by (2) is dropped in the presence of a catalyst.
- the obtained compound can be isolated according to a conventional method, and is not particularly limited.
- a general method is adopted such as raising the temperature of the reaction vessel to 130-230 ° C. and removing volatile matter at about 1-50 mmHg.
- a novolak resin as the target product can be obtained.
- the resin having the structure represented by the formula (2) may be a homopolymer of the compound represented by the formula (1), but is a copolymer with other phenols. May be.
- the copolymerizable phenols include phenol, cresol, dimethylphenol, trimethylphenol, butylphenol, phenylphenol, diphenylphenol, naphthylphenol, resorcinol, methylresorcinol, catechol, butylcatechol, methoxyphenol, methoxyphenol, Although propylphenol, pyrogallol, thymol, etc. are mentioned, it is not specifically limited to these.
- the resin having the structure represented by the formula (2) may be copolymerized with a polymerizable monomer in addition to the other phenols described above.
- the copolymerization monomer include naphthol, methylnaphthol, methoxynaphthol, dihydroxynaphthalene, indene, hydroxyindene, benzofuran, hydroxyanthracene, acenaphthylene, biphenyl, bisphenol, trisphenol, dicyclopentadiene, tetrahydroindene, 4-vinylcyclohexene.
- the resin having the structure represented by the above formula (2) is a binary or more (for example, 2-4 quaternary) copolymer of the compound represented by the above formula (1) and the above-described phenols. Even if it is a binary or more (for example, 2-4 quaternary) copolymer of the compound represented by the formula (1) and the above-mentioned copolymerization monomer, it is represented by the formula (1). It may be a ternary or more (for example, ternary to quaternary) copolymer of the above compound, the above-mentioned phenols, and the above-mentioned copolymerization monomer.
- the molecular weight of the resin having the structure represented by the formula (2) is not particularly limited, but the polystyrene equivalent weight average molecular weight (Mw) is preferably 500 to 30,000, more preferably 750 to 20,000. Further, from the viewpoint of increasing the crosslinking efficiency and suppressing the volatile components in the baking, the resin having the structure represented by the formula (2) has a dispersity (weight average molecular weight Mw / number average molecular weight Mn) of 1.2. Those within the range of ⁇ 7 are preferred. The Mn can be obtained by the method described in Examples described later.
- the resin obtained by using the compound having the structure represented by the formula (1) and the compound such as the resin having the structure represented by the formula (2) as a monomer makes it easier to apply a wet process.
- the solvent has high solubility. More specifically, when these compounds and / or resins use 1-methoxy-2-propanol (PGME) and / or propylene glycol monomethyl ether acetate (PGMEA) as a solvent, the solubility in the solvent is 10% by mass or more. It is preferable that Here, the solubility in PGMEA and / or PGMEA is defined as “mass of compound or resin ⁇ (mass of compound or resin + mass of solvent) ⁇ 100 (mass%)”. For example, when 10 g of the compound or resin is dissolved in 90 g of PGMEA, the solubility of the resin in PGMEA is “10% by mass or more”, and when it is not dissolved, it is “less than 10% by mass”.
- the material for forming an underlayer film for lithography contains at least one substance selected from the group consisting of the compound represented by the formula (1) and the resin obtained using the compound as a monomer.
- the substance is preferably 25 to 100% by mass, more preferably 50 to 100% by mass, and further preferably 75 to 100% by mass in the lower layer film forming material for lithography. It is especially preferable that it is 100 mass%.
- the lower layer film forming material for lithography of the present embodiment may include a known lower layer film forming material for lithography and the like as long as the effects of the present invention are not impaired.
- composition for forming underlayer film for lithography contains the material for forming a lower layer film for lithography and a solvent.
- solvent As the solvent used in the present embodiment, a known solvent can be appropriately used as long as the lower layer film forming material for lithography is at least soluble.
- the solvent include, for example, ketone solvents such as acetone, methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone, cellosolv solvents such as propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate (PGMEA), ethyl lactate, methyl acetate, and acetic acid.
- ketone solvents such as acetone, methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone
- cellosolv solvents such as propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate (PGMEA), ethyl lactate, methyl acetate, and acetic acid.
- Ester solvents such as ethyl, butyl acetate, isoamyl acetate, ethyl lactate, methyl methoxypropionate, methyl hydroxyisobutyrate, alcohol solvents such as methanol, ethanol, isopropanol, 1-ethoxy-2-propanol (PGME), toluene, Although aromatic hydrocarbons, such as xylene and anisole, etc. are mentioned, It does not specifically limit to these. These solvents can be used alone or in combination of two or more.
- cyclohexanone propylene glycol monomethyl ether
- propylene glycol monomethyl ether acetate propylene glycol monomethyl ether acetate
- ethyl lactate propylene glycol monomethyl ether acetate
- ethyl lactate methyl hydroxyisobutyrate
- 1-methoxy-2-propanol and anisole are particularly preferable from the viewpoint of safety.
- the content of the solvent is not particularly limited, but from the viewpoint of solubility and film formation, it is preferably 100 to 10,000 parts by mass with respect to 100 parts by mass of the lower layer film-forming material, and 200 to 5, The amount is more preferably 000 parts by mass, and still more preferably 300 to 1,000 parts by mass.
- composition for forming a lower layer film for lithography of the present embodiment may contain components such as a crosslinking agent and an acid generator, if necessary.
- these optional components will be described.
- the composition for forming a lower layer film for lithography of the present embodiment may contain a crosslinking agent as necessary from the viewpoint of suppressing intermixing.
- a crosslinking agent that can be used in the present embodiment include double bonds such as melamine compounds, guanamine compounds, glycoluril compounds or urea compounds, epoxy compounds, thioepoxy compounds, isocyanate compounds, azide compounds, alkenyl ether groups, and the like.
- these crosslinking agents can be used individually by 1 type or in combination of 2 or more types. These may be used as additives, but these crosslinkable groups may be introduced as pendant groups in the polymer side chain.
- a compound containing a hydroxy group can also be used as a crosslinking agent.
- the melamine compound include, for example, hexamethylol melamine, hexamethoxymethyl melamine, a compound in which 1 to 6 methylol groups of hexamethylol melamine are methoxymethylated or a mixture thereof, hexamethoxyethyl melamine, hexaacyloxymethyl melamine And a compound in which 1 to 6 methylol groups of hexamethylolmelamine are acyloxymethylated, or a mixture thereof.
- epoxy compound examples include tris (2,3-epoxypropyl) isocyanurate, trimethylolmethane triglycidyl ether, trimethylolpropane triglycidyl ether, triethylolethane triglycidyl ether, and the like.
- the guanamine compound include, for example, tetramethylolguanamine, tetramethoxymethylguanamine, a compound in which 1 to 4 methylol groups of tetramethylolguanamine are methoxymethylated, or a mixture thereof, tetramethoxyethylguanamine, tetraacyloxyguanamine, Examples thereof include compounds in which 1 to 4 methylol groups of tetramethylolguanamine are acyloxymethylated, or mixtures thereof.
- glycoluril compound examples include, for example, tetramethylol glycoluril, tetramethoxyglycoluril, tetramethoxymethylglycoluril, a compound in which 1 to 4 methylol groups of tetramethylolglycoluril are methoxymethylated, or a mixture thereof, Examples thereof include compounds in which 1 to 4 methylol groups of methylol glycoluril are acyloxymethylated, or mixtures thereof.
- urea compound examples include, for example, tetramethylol urea, tetramethoxymethyl urea, a compound in which 1 to 4 methylol groups of tetramethylol urea are methoxymethylated or a mixture thereof, tetramethoxyethyl urea, and the like.
- the compound containing an alkenyl ether group include, for example, ethylene glycol divinyl ether, triethylene glycol divinyl ether, 1,2-propanediol divinyl ether, 1,4-butanediol divinyl ether, tetramethylene glycol divinyl ether, neo Pentyl glycol divinyl ether, trimethylolpropane trivinyl ether, hexanediol divinyl ether, 1,4-cyclohexanediol divinyl ether, pentaerythritol trivinyl ether, pentaerythritol tetravinyl ether, sorbitol tetravinyl ether, sorbitol pentavinyl ether, trimethylolpropane trivinyl ether, etc. Can be mentioned.
- the content of the crosslinking agent is not particularly limited, but is preferably 5 to 50 parts by weight with respect to 100 parts by weight of the material for forming a lower layer film for lithography.
- the amount is more preferably 10 to 40 parts by mass, and further preferably 15 to 35 parts by mass.
- the composition for forming a lower layer film for lithography of the present embodiment may contain an acid generator as necessary from the viewpoint of further promoting a crosslinking reaction by heat.
- an acid generator those that generate acid by thermal decomposition and those that generate acid by light irradiation are known, and any of them can be used.
- R 101a , R 101b and R 101c are each independently a linear, branched or cyclic alkyl group having 1 to 12 carbon atoms, an alkenyl group, an oxoalkyl group or an oxoalkenyl group, and 6 to 6 carbon atoms.
- 20 aryl groups, aralkyl groups having 7 to 12 carbon atoms, or aryloxoalkyl groups, part or all of hydrogen atoms of these groups may be substituted with alkoxy groups or the like.
- R 101b and R 101c may form a ring. When a ring is formed, R 101b and R 101c each independently represent an alkylene group having 1 to 6 carbon atoms.
- K ⁇ represents a non-nucleophilic counter ion.
- R 101d , R 101e , R 101f and R 101g are each independently represented by adding a hydrogen atom to R 101a , R 101b and R 101c .
- R 101d and R 101e , R 101d and R 101e and R 101f may form a ring, and in the case of forming a ring, R 101d and R 101e and R 101d , R 101e and R 101f have 3 carbon atoms.
- R 101a , R 101b , R 101c , R 101d , R 101e , R 101f and R 101g may be the same as or different from each other.
- examples of the alkyl group include methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, pentyl, hexyl, heptyl, octyl, and cyclopentyl.
- alkenyl group examples include a vinyl group, an allyl group, a propenyl group, a butenyl group, a hexenyl group, and a cyclohexenyl group.
- oxoalkyl group examples include a 2-oxocyclopentyl group, a 2-oxocyclohexyl group, and the like.
- a 2-oxopropyl group, a 2-cyclopentyl-2-oxoethyl group, a 2-cyclohexyl-2-oxoethyl group, 2- (4 -Methylcyclohexyl) -2-oxoethyl group and the like can be mentioned.
- Examples of the oxoalkenyl group include a 2-oxo-4-cyclohexenyl group and a 2-oxo-4-propenyl group.
- Examples of the aryl group include a phenyl group, a naphthyl group, a p-methoxyphenyl group, an m-methoxyphenyl group, an o-methoxyphenyl group, an ethoxyphenyl group, a p-tert-butoxyphenyl group, and an m-tert-butoxyphenyl group.
- Alkylphenyl groups such as alkoxyphenyl groups, 2-methylphenyl groups, 3-methylphenyl groups, 4-methylphenyl groups, ethylphenyl groups, 4-tert-butylphenyl groups, 4-butylphenyl groups, dimethylphenyl groups, etc.
- Alkyl naphthyl groups such as methyl naphthyl group and ethyl naphthyl group, alkoxy naphthyl groups such as methoxy naphthyl group and ethoxy naphthyl group, dialkyl naphthyl groups such as dimethyl naphthyl group and diethyl naphthyl group, dimethoxy naphthyl group and diethoxy naphthyl group Dialkoxynaphthyl group And the like.
- the aralkyl group include a benzyl group, a phenylethyl group, and a phenethyl group.
- 2-aryl-2-oxoethyl group such as 2-phenyl-2-oxoethyl group, 2- (1-naphthyl) -2-oxoethyl group, 2- (2-naphthyl) -2-oxoethyl group, etc. Groups and the like.
- Non-nucleophilic counter ions of K 2 ⁇ include halide ions such as chloride ions and bromide ions, triflate, fluoroalkyl sulfonates such as 1,1,1-trifluoroethanesulfonate, nonafluorobutanesulfonate, tosylate, and benzenesulfonate.
- Aryl sulfonates such as 4-fluorobenzene sulfonate and 1,2,3,4,5-pentafluorobenzene sulfonate, and alkyl sulfonates such as mesylate and butane sulfonate.
- the heteroaromatic ring may be an imidazole derivative (for example, imidazole, 4-methyl Imidazole, 4-methyl-2-phenylimidazole, etc.), pyrazole derivatives, furazane derivatives, pyrroline derivatives (eg pyrroline, 2-methyl-1-pyrroline etc.), pyrrolidine derivatives (eg pyrrolidine, N-methylpyrrolidine, pyrrolidinone, N- Methylpyrrolidone etc.), imidazoline derivatives, imidazolidine derivatives, pyridine derivatives (eg pyridine, methylpyridine, ethylpyridine, propylpyridine, butylpyridine, 4- (1-butylpentyl) pyridine, dimethylpyridine, trimethylpyridine, triethylpyridine, phenylpyri
- imidazole derivative for example, imidazole, 4-methyl Imidazole, 4-methyl-2-phenylimidazole, etc.
- the formula (P1a-1) and the formula (P1a-2) are effective as both a photoacid generator and a thermal acid generator, but the formula (P1a-3) acts as a thermal acid generator.
- R 102a and R 102b each independently represent a linear, branched or cyclic alkyl group having 1 to 8 carbon atoms.
- R 103 represents a linear, branched or cyclic alkylene group having 1 to 10 carbon atoms.
- R 104a and R 104b each independently represent a 3-oxoalkyl group having 3 to 7 carbon atoms.
- K ⁇ represents a non-nucleophilic counter ion.
- R 102a and R 102b include a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, a hexyl group, a heptyl group, and an octyl group.
- R 103 includes methylene group, ethylene group, propylene group, butylene group, pentylene group, hexylene group, heptylene group, octylene group, nonylene group, 1,4-cyclohexylene group, 1,2-cyclohexylene. Group, 1,3-cyclopentylene group, 1,4-cyclooctylene group, 1,4-cyclohexanedimethylene group and the like.
- R 104a and R 104b include a 2-oxopropyl group, a 2-oxocyclopentyl group, a 2-oxocyclohexyl group, and a 2-oxocycloheptyl group.
- K - is the formula (P1a-1), can be exemplified the same ones as described in (P1a-2) and (P1a-3).
- R 105 and R 106 are each independently a linear, branched or cyclic alkyl group or halogenated alkyl group having 1 to 12 carbon atoms, an aryl group having 6 to 20 carbon atoms or halogen. An aryl group or an aralkyl group having 7 to 12 carbon atoms.
- Examples of the alkyl group for R 105 and R 106 include a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, Examples include amyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, norbornyl group, adamantyl group and the like.
- halogenated alkyl group examples include a trifluoromethyl group, 1,1,1-trifluoroethyl group, 1,1,1-trichloroethyl group, nonafluorobutyl group, and the like.
- aryl group an alkoxyphenyl group such as a phenyl group, a p-methoxyphenyl group, an m-methoxyphenyl group, an o-methoxyphenyl group, an ethoxyphenyl group, a p-tert-butoxyphenyl group, or an m-tert-butoxyphenyl group
- alkylphenyl groups such as 2-methylphenyl group, 3-methylphenyl group, 4-methylphenyl group, ethylphenyl group, 4-tert-butylphenyl group, 4-butylphenyl group and dimethylphenyl group.
- halogenated aryl group examples include a fluorophenyl group, a chlorophenyl group, and 1,2,3,4,5-pentafluorophenyl group.
- aralkyl group examples include a benzyl group and a phenethyl group.
- R 107 , R 108 and R 109 are each independently a linear, branched or cyclic alkyl group or halogenated alkyl group having 1 to 12 carbon atoms, or aryl having 6 to 20 carbon atoms.
- R 108 and R 109 may be bonded to each other to form a cyclic structure.
- R 108 and R 109 each represent a linear or branched alkylene group having 1 to 6 carbon atoms. .
- Examples of the alkyl group, halogenated alkyl group, aryl group, halogenated aryl group, and aralkyl group of R 107 , R 108 , and R 109 include the same groups as those described for R 105 and R 106 .
- Examples of the alkylene group for R 108 and R 109 include a methylene group, an ethylene group, a propylene group, a butylene group, and a hexylene group.
- R 101a and R 101b are the same as described above.
- R 110 represents an arylene group having 6 to 10 carbon atoms, an alkylene group having 1 to 6 carbon atoms, or an alkenylene group having 2 to 6 carbon atoms, and part or all of the hydrogen atoms of these groups May further be substituted with a linear or branched alkyl group or alkoxy group having 1 to 4 carbon atoms, a nitro group, an acetyl group, or a phenyl group.
- R 111 represents a linear, branched or substituted alkyl group, alkenyl group, alkoxyalkyl group, phenyl group, or naphthyl group having 1 to 8 carbon atoms, and some or all of the hydrogen atoms of these groups are further An alkyl group or alkoxy group having 1 to 4 carbon atoms; a phenyl group optionally substituted with an alkyl group, alkoxy group, nitro group or acetyl group having 1 to 4 carbon atoms; a heteroaromatic group having 3 to 5 carbon atoms; Alternatively, it may be substituted with a chlorine atom or a fluorine atom.
- examples of the arylene group of R 110 include a 1,2-phenylene group and a 1,8-naphthylene group.
- examples of the alkylene group include methylene group, ethylene group, trimethylene group, tetramethylene group, phenylethylene group, norbornane-2,3-diyl group and the like.
- examples of the alkenylene group include a 1,2-vinylene group, a 1-phenyl-1,2-vinylene group, and a 5-norbornene-2,3-diyl group.
- Examples of the alkyl group for R 111 include the same groups as R 101a to R 101c .
- alkenyl groups include vinyl, 1-propenyl, allyl, 1-butenyl, 3-butenyl, isoprenyl, 1-pentenyl, 3-pentenyl, 4-pentenyl, dimethylallyl, Examples include a hexenyl group, a 3-hexenyl group, a 5-hexenyl group, a 1-heptenyl group, a 3-heptenyl group, a 6-heptenyl group, and a 7-octenyl group.
- alkoxyalkyl group examples include methoxymethyl group, ethoxymethyl group, propoxymethyl group, butoxymethyl group, pentyloxymethyl group, hexyloxymethyl group, heptyloxymethyl group, methoxyethyl group, ethoxyethyl group, propoxyethyl group, Butoxyethyl group, pentyloxyethyl group, hexyloxyethyl group, methoxypropyl group, ethoxypropyl group, propoxypropyl group, butoxypropyl group, methoxybutyl group, ethoxybutyl group, propoxybutyl group, methoxypentyl group, ethoxypentyl group, A methoxyhexyl group, a methoxyheptyl group, etc. are mentioned.
- examples of the optionally substituted alkyl group having 1 to 4 carbon atoms include a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, an isobutyl group, and a tert-butyl group.
- examples of the alkoxy group having 1 to 4 carbon atoms include methoxy group, ethoxy group, propoxy group, isopropoxy group, n-butoxy group, isobutoxy group, tert-butoxy group and the like.
- Examples of the phenyl group which may be substituted with an alkyl group having 1 to 4 carbon atoms, an alkoxy group, a nitro group or an acetyl group include a phenyl group, a tolyl group, a p-tert-butoxyphenyl group, a p-acetylphenyl group, p -Nitrophenyl group and the like.
- Examples of the heteroaromatic group having 3 to 5 carbon atoms include a pyridyl group and a furyl group.
- tetramethylammonium trifluoromethanesulfonate tetramethylammonium nonafluorobutanesulfonate, triethylammonium nonafluorobutanesulfonate, pyridinium nonafluorobutanesulfonate, triethylammonium camphorsulfonate, pyridinium camphorsulfonate, nona Tetra n-butylammonium fluorobutanesulfonate, tetraphenylammonium nonafluorobutanesulfonate, tetramethylammonium p-toluenesulfonate, diphenyliodonium trifluoromethanesulfonate, phenyliodonium trifluoromethanesulfonate (p-tert-butoxyphenyl) phenyliodonium, p-Toluenesulf
- triphenylsulfonium trifluoromethanesulfonate trifluoromethanesulfonic acid (p-tert-butoxyphenyl) diphenylsulfonium, trifluoromethanesulfonic acid tris (p-tert-butoxyphenyl) sulfonium, p-toluenesulfonic acid Triphenylsulfonium, p-toluenesulfonic acid (p-tert-butoxyphenyl) diphenylsulfonium, p-toluenesulfonic acid tris (p-tert-butoxyphenyl) sulfonium, trifluoromethanesulfonic acid trinaphthylsulfonium, trifluoromethanesulfonic acid cyclohexylmethyl (2-oxo
- the content of the acid generator is not particularly limited, but is 0.1 to 50 parts by weight with respect to 100 parts by weight of the material for forming a lower layer film for lithography. It is preferably 0.5 to 40 parts by mass, more preferably 1.0 to 30 parts by mass. When the amount is within the above range, the acid generation amount tends to increase and the crosslinking reaction tends to be enhanced, and the occurrence of a mixing phenomenon with the resist layer tends to be suppressed.
- composition for forming a lower layer film for lithography of the present embodiment may contain a basic compound from the viewpoint of improving storage stability.
- the basic compound serves as a quencher for the acid to prevent the acid generated in a trace amount from the acid generator from causing the crosslinking reaction to proceed.
- Examples of such basic compounds include primary, secondary, and tertiary aliphatic amines, hybrid amines, aromatic amines, heterocyclic amines, nitrogen-containing compounds having a carboxy group, and sulfonyl groups. Nitrogen-containing compounds having a hydroxyl group, nitrogen-containing compounds having a hydroxyl group, nitrogen-containing compounds having a hydroxyphenyl group, alcoholic nitrogen-containing compounds, amide derivatives, imide derivatives, and the like, but are not particularly limited thereto.
- the primary aliphatic amines include ammonia, methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylamine, sec-butylamine, tert-butylamine, pentyl.
- Examples include amine, tert-amylamine, cyclopentylamine, hexylamine, cyclohexylamine, heptylamine, octylamine, nonylamine, decylamine, dodecylamine, cetylamine, methylenediamine, ethylenediamine, tetraethylenepentamine and the like.
- secondary aliphatic amines include dimethylamine, diethylamine, di-n-propylamine, diisopropylamine, di-n-butylamine, diisobutylamine, di-sec-butylamine, dipentylamine, dicyclopentylamine.
- tertiary aliphatic amines include trimethylamine, triethylamine, tri-n-propylamine, triisopropylamine, tri-n-butylamine, triisobutylamine, tri-sec-butylamine, tripentylamine, tripentylamine, Cyclopentylamine, trihexylamine, tricyclohexylamine, triheptylamine, trioctylamine, trinonylamine, tridecylamine, tridodecylamine, tricetylamine, N, N, N ′, N′-tetramethylmethylenediamine, Examples thereof include N, N, N ′, N′-tetramethylethylenediamine, N, N, N ′, N′-tetramethyltetraethylenepentamine and the like.
- the mixed amines include dimethylethylamine, methylethylpropylamine, benzylamine, phenethylamine, benzyldimethylamine and the like.
- aromatic amines and heterocyclic amines include aniline derivatives (for example, aniline, N-methylaniline, N-ethylaniline, N-propylaniline, N, N-dimethylaniline, 2-methylaniline, 3- Methylaniline, 4-methylaniline, ethylaniline, propylaniline, trimethylaniline, 2-nitroaniline, 3-nitroaniline, 4-nitroaniline, 2,4-dinitroaniline, 2,6-dinitroaniline, 3,5- Dinitroaniline, N, N-dimethyltoluidine, etc.), diphenyl (p-tolyl) amine, methyldiphenylamine, triphenylamine, phenylenediamine, naphthylamine, diaminona
- nitrogen-containing compound having a carboxy group examples include aminobenzoic acid, indolecarboxylic acid, amino acid derivatives (for example, nicotinic acid, alanine, arginine, aspartic acid, glutamic acid, glycine, histidine, isoleucine, glycylleucine, Leucine, methionine, phenylalanine, threonine, lysine, 3-aminopyrazine-2-carboxylic acid, methoxyalanine) and the like.
- aminobenzoic acid for example, nicotinic acid, alanine, arginine, aspartic acid, glutamic acid, glycine, histidine, isoleucine, glycylleucine, Leucine, methionine, phenylalanine, threonine, lysine, 3-aminopyrazine-2-carboxylic acid, methoxyalan
- nitrogen-containing compound having a sulfonyl group examples include 3-pyridinesulfonic acid and pyridinium p-toluenesulfonate.
- nitrogen-containing compounds having a hydroxyl group, nitrogen-containing compounds having a hydroxyphenyl group, and alcoholic nitrogen-containing compounds include 2-hydroxypyridine, aminocresol, 2,4-quinolinediol, 3-indolemethanol hydrate, mono Ethanolamine, diethanolamine, triethanolamine, N-ethyldiethanolamine, N, N-diethylethanolamine, triisopropanolamine, 2,2'-iminodiethanol, 2-aminoethanol, 3-amino-1-propanol, 4- Amino-1-butanol, 4- (2-hydroxyethyl) morpholine, 2- (2-hydroxyethyl) pyridine, 1- (2-hydroxyethyl) piperazine, 1- [2- (2-hydroxyethoxy) ethyl]
- amide derivative examples include formamide, N-methylformamide, N, N-dimethylformamide, acetamide, N-methylacetamide, N, N-dimethylacetamide, propionamide, benzamide and the like.
- imide derivative examples include phthalimide, succinimide, maleimide and the like.
- the content of the basic compound is not particularly limited, but is 0.001 to 2 parts by mass with respect to 100 parts by mass of the material for forming the lower layer film for lithography. More preferably, it is more preferably 0.01 to 1 part by mass, and even more preferably 0.05 to 0.5 part by mass. By setting it in the above range, the storage stability tends to be enhanced without excessively impairing the crosslinking reaction.
- the composition for forming a lower layer film for lithography of the present embodiment may contain other resins and / or compounds for the purpose of imparting thermosetting properties and controlling absorbance.
- other resins and / or compounds include naphthol resins, xylene resins, naphthol-modified resins, phenol-modified resins of naphthalene resins, polyhydroxystyrene, dicyclopentadiene resins, (meth) acrylates, dimethacrylates, trimethacrylates, tetra Resins containing no heterocyclic ring or aromatic ring such as methacrylate, vinyl naphthalene, polyacenaphthylene and other naphthalene rings, phenanthrenequinone, biphenyl rings such as fluorene, hetero rings having hetero atoms such as thiophene and indene; rosin resins; Examples thereof include resins or compounds containing an alicyclic
- the underlayer film for lithography of this embodiment is formed using the above-described composition for forming an underlayer film for lithography.
- the multilayer resist pattern forming method of the present embodiment includes forming a lower layer film on the substrate using the above-described composition for forming a lower layer film for lithography, and at least one photoresist layer on the lower layer film. After forming the film, a desired region of the photoresist layer can be irradiated with radiation and developed.
- the multilayer resist pattern forming method of the present embodiment includes forming a lower layer film on the substrate using the above-described lithography lower layer film forming material, and a resist intermediate layer film containing silicon atoms on the lower layer film
- An intermediate layer film is formed using a material, and at least one photoresist layer is formed on the intermediate layer film, and then a desired region of the photoresist layer is irradiated with radiation and developed to form a resist pattern.
- the intermediate layer film is etched using the resist pattern as a mask, the lower layer film is etched using the obtained intermediate layer film pattern as an etching mask, and the substrate is etched using the obtained lower layer film pattern as an etching mask.
- a pattern can be formed on the substrate.
- the formation method of the underlayer film for lithography of the present embodiment is not particularly limited as long as it is formed from the above-described composition for forming an underlayer film for lithography, and a technique known in the art can be applied. .
- a technique known in the art can be applied.
- the organic solvent is volatilized and removed to remove the lower layer.
- a film can be formed.
- the baking temperature is not particularly limited, but is preferably in the range of 80 to 450 ° C., more preferably 200 to 400 ° C.
- the baking time is not particularly limited, but is preferably within the range of 10 to 300 seconds.
- the thickness of the lower layer film can be appropriately selected according to the required performance and is not particularly limited, but is usually preferably about 30 to 20,000 nm, more preferably 50 to 15,000 nm. It is preferable.
- a silicon-containing resist layer is formed thereon, or a single-layer resist made of ordinary hydrocarbons.
- a silicon-containing intermediate layer is formed thereon, and further thereon.
- a single-layer resist layer not containing silicon is produced. In this case, a well-known thing can be used as a photoresist material for forming this resist layer.
- a silicon-containing resist layer or a single layer resist made of normal hydrocarbon is formed on the lower layer film, and in the case of a three-layer process, a silicon-containing layer is formed on the lower layer film.
- a single-layer resist layer not containing silicon can be produced on the intermediate layer and further on the silicon-containing intermediate layer.
- the photoresist material for forming the resist layer can be appropriately selected from known materials and is not particularly limited.
- a silicon-containing resist material for a two-layer process from the point of resistance to oxygen gas etching, a silicon atom-containing polymer such as a polysilsesquioxane derivative or a vinylsilane derivative is used as a base polymer, and an organic solvent, an acid generator, If necessary, a positive photoresist material containing a basic compound or the like is preferably used.
- a silicon atom-containing polymer a known polymer used in this type of resist material can be used.
- a polysilsesquioxane-based intermediate layer is preferably used as the silicon-containing intermediate layer for the three-layer process.
- the intermediate layer With an effect as an antireflection film, reflection can be suppressed.
- the k value increases and the substrate reflection tends to increase, but by suppressing the reflection in the intermediate layer, The substrate reflection can be reduced to 0.5% or less.
- polysilsesquioxane crosslinked with acid or heat into which a light absorbing group having a phenyl group or a silicon-silicon bond is introduced is preferably used for 193 nm exposure.
- an intermediate layer formed by a Chemical-Vapor-deposition (CVD) method can be used.
- a SiON film is known as an intermediate layer having a high effect as an antireflection film manufactured by a CVD method.
- the formation of the intermediate layer by a wet process such as spin coating or screen printing has a simpler and more cost-effective advantage than the CVD method.
- the upper layer resist in the three-layer process may be either a positive type or a negative type, and the same one as a commonly used single layer resist can be used.
- the lower layer film of this embodiment can also be used as an antireflection film for a normal single layer resist or a base material for suppressing pattern collapse. Since the lower layer film of this embodiment is excellent in etching resistance for the base processing, it can be expected to function as a hard mask for the base processing.
- a wet process such as spin coating or screen printing is preferably used as in the case of forming the lower layer film.
- prebaking is usually performed, but this prebaking is preferably performed at 80 to 180 ° C. for 10 to 300 seconds.
- a resist pattern can be obtained by performing exposure, post-exposure baking (PEB), and development.
- the thickness of the resist film is not particularly limited, but is generally preferably 30 to 500 nm, more preferably 50 to 400 nm.
- the exposure light may be appropriately selected and used according to the photoresist material to be used.
- high energy rays having a wavelength of 300 nm or less, specifically, 248 nm, 193 nm, 157 nm excimer laser, 3 to 20 nm soft X-ray, electron beam, X-ray and the like can be mentioned.
- the resist pattern formed by the above method is one in which pattern collapse is suppressed by the lower layer film of this embodiment. Therefore, by using the lower layer film of this embodiment, a finer pattern can be obtained, and the exposure amount necessary for obtaining the resist pattern can be reduced.
- gas etching is preferably used as the etching of the lower layer film in the two-layer process.
- gas etching etching using oxygen gas is suitable.
- an inert gas such as He or Ar, or CO, CO 2 , NH 3 , SO 2 , N 2 , NO 2 or H 2 gas may be added.
- gas etching can be performed only with CO, CO 2 , NH 3 , N 2 , NO 2, and H 2 gas without using oxygen gas.
- the latter gas is used for side wall protection for preventing undercut of the pattern side wall.
- gas etching is also preferably used in the etching of the intermediate layer in the three-layer process.
- the gas etching the same gas etching as that described in the above two-layer process can be applied.
- the processing of the intermediate layer in the three-layer process is preferably performed using a fluorocarbon gas and a resist pattern as a mask.
- the lower layer film can be processed by, for example, oxygen gas etching using the intermediate layer pattern as a mask.
- a silicon oxide film, a silicon nitride film, or a silicon oxynitride film is formed by a CVD method, an ALD method, or the like.
- the method for forming the nitride film is described in, for example, Japanese Patent Application Laid-Open No. 2002-334869 (Patent Document 6) and WO 2004/066377 (Patent Document 7).
- a photoresist film can be formed directly on such an intermediate film, but an organic antireflection film (BARC) is formed on the intermediate film by spin coating, and a photoresist film is formed thereon. May be.
- an intermediate layer based on polysilsesquioxane is also preferably used.
- the resist intermediate layer film is an antireflection film.
- reflection can be suppressed.
- Specific examples of the material for the polysilsesquioxane-based intermediate layer are described in, for example, Japanese Patent Application Laid-Open No. 2007-226170 (the above-mentioned Patent Document 8) and Japanese Patent Application Laid-Open No. 2007-226204 (the above-mentioned Patent Document 9). Has been.
- the next substrate can be etched by a conventional method.
- the etching is mainly made of a chlorofluorocarbon gas, and if p-Si, Al, or W is used, a chlorine or bromine gas is used. Etching mainly composed of can be performed.
- the substrate processing is etched with chlorofluorocarbon gas, the silicon-containing resist of the two-layer resist process and the silicon-containing intermediate layer of the three-layer process are peeled off simultaneously with the substrate processing.
- the silicon-containing resist layer or the silicon-containing intermediate layer is separately peeled, and generally, dry etching peeling with a chlorofluorocarbon-based gas is performed after the substrate is processed. .
- the lower layer film of this embodiment is excellent in the etching resistance of these substrates.
- a substrate known in the art can be appropriately selected and used, and is not particularly limited, but Si, ⁇ -Si, p-Si, SiO 2 , SiN, SiON, W, TiN, Al, etc. Is mentioned.
- the substrate may be a laminate having a film to be processed (substrate to be processed) on a base material (support). Examples of such processed films include various low-k films such as Si, SiO 2 , SiON, SiN, p-Si, ⁇ -Si, W, W-Si, Al, Cu, and Al-Si, and their stopper films. In general, a material different from the base material (support) is used.
- the thickness of the substrate to be processed or the film to be processed is not particularly limited, but is usually preferably about 50 to 10,000 nm, more preferably 75 to 5,000 nm.
- the method for purifying a compound or resin in the present embodiment includes an organic solvent which is not arbitrarily miscible with water and a solution containing a compound represented by the formula (1) or a resin obtained using the compound as a monomer (hereinafter referred to as solution (A). And an acidic aqueous solution are contacted and extracted.
- solution (A) a solution containing a compound represented by the formula (1) or a resin obtained using the compound as a monomer
- solution (A) a solution containing a compound represented by the formula (1) or a resin obtained using the compound as a monomer
- solution (A) a solution containing a compound represented by the formula (1) or a resin obtained using the compound as a monomer
- solution (A) a solution containing a compound represented by the formula (1) or a resin obtained using the compound as a monomer
- acidic aqueous solution are contacted and extracted.
- the content of various metals that can be contained as impurities in the compound or the resin can be reduced.
- the compound or resin used in the present embodiment may be used alone or in combination of two or more.
- the compound or the resin may contain various surfactants, various crosslinking agents, various acid generators, various stabilizers, and the like.
- the organic solvent that is arbitrarily immiscible with water used in the present invention is not particularly limited, but an organic solvent that can be safely applied to a semiconductor manufacturing process is preferable.
- the amount of the organic solvent used is usually about 1 to 100 times by mass with respect to the compound or the resin.
- solvent used examples include ethers such as diethyl ether and diisopropyl ether, esters such as ethyl acetate, n-butyl acetate and isoamyl acetate, methyl ethyl ketone, methyl isobutyl ketone, ethyl isobutyl ketone, cyclohexanone and cyclopentanone.
- ethers such as diethyl ether and diisopropyl ether
- esters such as ethyl acetate, n-butyl acetate and isoamyl acetate, methyl ethyl ketone, methyl isobutyl ketone, ethyl isobutyl ketone, cyclohexanone and cyclopentanone.
- Ketones such as 2-heptanone and 2-pentanone, glycol ether acetates such as ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate (PGMEA), propylene glycol monoethyl ether acetate, n- Aliphatic hydrocarbons such as hexane and n-heptane, aromatic hydrocarbons such as toluene and xylene, halogenation such as methylene chloride and chloroform Hydrogen, etc. can be mentioned.
- glycol ether acetates such as ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate (PGMEA), propylene glycol monoethyl ether acetate
- n- Aliphatic hydrocarbons such as hexane and n-heptane
- toluene, 2-heptanone, cyclohexanone, cyclopentanone, methyl isobutyl ketone, propylene glycol monomethyl ether acetate, ethyl acetate and the like are preferable, methyl isobutyl ketone, ethyl acetate, cyclohexanone, propylene glycol monomethyl ether acetate are more preferable, More preferred are methyl isobutyl ketone and ethyl acetate.
- Methyl isobutyl ketone, ethyl acetate, and the like have a relatively high saturation solubility and a relatively low boiling point of the compound or the resin, thereby reducing the load in the process of removing the solvent industrially or by drying. It becomes possible.
- These solvents can be used alone or in combination of two or more.
- the acidic aqueous solution used in the present invention is appropriately selected from aqueous solutions in which generally known organic and inorganic compounds are dissolved in water.
- aqueous solutions in which generally known organic and inorganic compounds are dissolved in water.
- an aqueous solution in which a mineral acid such as hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid is dissolved in water, or acetic acid, propionic acid, succinic acid, malonic acid, succinic acid, fumaric acid, maleic acid, tartaric acid
- Examples thereof include an aqueous solution (organic acid aqueous solution) in which an organic acid such as citric acid, methanesulfonic acid, phenolsulfonic acid, p-toluenesulfonic acid, trifluoroacetic acid and the like is dissolved in water.
- acidic aqueous solutions can be used alone or in combination of two or more.
- aqueous solutions of sulfuric acid, nitric acid, and carboxylic acids such as acetic acid, succinic acid, tartaric acid, and citric acid are preferable, and aqueous solutions of sulfuric acid, succinic acid, tartaric acid, and citric acid are preferable, and an aqueous solution of succinic acid is particularly preferable.
- polyvalent carboxylic acids such as succinic acid, tartaric acid, and citric acid are coordinated to metal ions to produce a chelate effect, it is considered that the metal can be removed more.
- the water used here is preferably one having a low metal content, such as ion-exchanged water, for the purpose of the present invention.
- the pH of the acidic aqueous solution used in the present invention is not particularly limited. However, if the acidity of the aqueous solution is too large, the compound or the resin may be adversely affected. Usually, the pH range is about 0 to 5, more preferably about pH 0 to 3.
- the amount of the acidic aqueous solution used in the present invention is not particularly limited, but if the amount is too small, it is necessary to increase the number of extractions for removing the metal, and conversely if the amount of the aqueous solution is too large, the total amount of liquid is required. May increase operational problems.
- the amount of the aqueous solution used is usually 10 to 200% by mass, preferably 20 to 100% by mass, based on the solution of the compound or resin dissolved in an organic solvent.
- the metal component is extracted by bringing the acidic aqueous solution as described above into contact with the compound or the resin and a solution (A) containing an organic solvent which is not arbitrarily miscible with water.
- the solution (A) further contains an organic solvent arbitrarily mixed with water.
- the solution (A) contains an organic solvent arbitrarily mixed with water, whereby the amount of the compound or the resin charged can be increased, the liquid separation property is improved, and the high pot Purification can be performed efficiently.
- a method for adding an organic solvent arbitrarily mixed with water to the solution (A) is not particularly limited.
- a method of adding an organic solvent arbitrarily mixed with water to a solution containing an organic solvent not arbitrarily mixed with water a method of adding an organic solvent arbitrarily mixed with water to water or an acidic aqueous solution; Any method of adding an organic solvent miscible with water after contacting a solution containing an organic solvent immiscible with water and an acidic aqueous solution can be employed.
- a method of adding an organic solvent to be mixed to a solution containing an organic solvent that is not arbitrarily miscible with water is preferable from the viewpoint of the workability of the operation and the ease of management of the charged amount.
- the “organic solvent arbitrarily mixed with water” is not particularly limited, but an organic solvent that is arbitrarily mixed with water and can be safely applied to a semiconductor manufacturing process is preferable.
- the content of the “organic solvent arbitrarily mixed with water” is not particularly limited as long as the solution phase and the aqueous phase are separated, but the compound represented by the formula (1) or the formula (2) used. In general, it can be used in an amount of about 0.1 to 100 mass times the total amount of the resin having the structure represented by
- organic solvent arbitrarily mixed with water examples include, for example, ethers such as tetrahydrofuran and 1,3-dioxolane; alcohols such as methanol, ethanol and isopropanol; ketones such as acetone and N-methylpyrrolidone; ethylene Aliphatic hydrocarbons such as glycol ethers such as glycol monoethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether (PGME), and propylene glycol monoethyl ether.
- ethers such as tetrahydrofuran and 1,3-dioxolane
- alcohols such as methanol, ethanol and isopropanol
- ketones such as acetone and N-methylpyrrolidone
- ethylene Aliphatic hydrocarbons such as glycol ethers such as glycol monoethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether (PGME), and
- N-methylpyrrolidone, propylene glycol monomethyl ether and the like are preferable, and N-methylpyrrolidone and propylene glycol monomethyl ether are particularly preferable.
- These solvents can be used alone or in combination of two or more.
- the temperature at the time of contacting the solution (A) with the acidic aqueous solution is usually 20 to 90 ° C., and preferably 30 to 80 ° C.
- extraction operation is not specifically limited, For example, after mixing well by stirring etc., it is performed by leaving still. Thereby, the metal content contained in the solution containing the compound or the resin and the organic solvent is transferred to the aqueous phase. Moreover, the acidity of a solution falls by this operation, and the quality change of the said compound or the said resin can be suppressed.
- the solution containing the compound or the resin and the organic solvent is recovered by decantation or the like.
- the standing time is not particularly limited, but it is preferable to adjust the standing time from the viewpoint of improving the separation between the solution phase containing the organic solvent and the aqueous phase.
- the time for standing is 1 minute or longer, preferably 10 minutes or longer, more preferably 30 minutes or longer.
- the extraction process may be performed only once, but it is also effective to repeat the operations of mixing, standing, and separation a plurality of times.
- the solution containing the compound or the resin and the organic solvent extracted and recovered from the aqueous solution is further subjected to an extraction treatment with water.
- the extraction treatment with water is not particularly limited, and can be performed by, for example, stirring well and then allowing to stand. Since the solution obtained after the standing is separated into a solution phase containing the compound or the resin and an organic solvent and an aqueous phase, the solution phase containing the compound or the resin and the organic solvent can be recovered by decantation or the like.
- the water used here is a thing with little metal content, for example, ion-exchange water etc. according to the objective of this embodiment.
- the extraction process may be performed only once, but it is also effective to repeat the operations of mixing, standing, and separation a plurality of times. Further, the use ratio of both in the extraction process, conditions such as temperature and time are not particularly limited, but they may be the same as those in the contact process with the acidic aqueous solution.
- the water that can be mixed in the solution containing the compound or the resin and the organic solvent thus obtained can be easily removed by performing an operation such as vacuum distillation. Further, if necessary, an organic solvent can be added to adjust the concentration of the compound or the resin to an arbitrary concentration.
- a method for isolating the compound or the resin from the obtained compound or a solution containing the resin and an organic solvent is not particularly limited, and known methods such as removal under reduced pressure, separation by reprecipitation, and combinations thereof. Can be done. If necessary, known processes such as a concentration operation, a filtration operation, a centrifugal separation operation, and a drying operation can be performed.
- Evaluation A Thermal decomposition temperature is ⁇ 150 ° C.
- Evaluation C Thermal decomposition temperature ⁇ 150 ° C (Evaluation of solvent solubility) At 23 ° C., the compound was dissolved in propylene glycol monomethyl ether (PGME) so as to be a 5 mass% solution, then allowed to stand at 5 ° C. for 30 days, and the results were evaluated according to the following criteria.
- Evaluation C Visually confirmed presence of deposit
- the obtained solid was filtered and dried, followed by separation and purification by column chromatography to obtain 5.0 g of the target compound (BisF-1-CH4) represented by the following formula.
- the target compound (BisF-1-CH4) represented by the following formula.
- the following peaks were found and it confirmed that it had a chemical structure of a following formula.
- the molecular weight of the obtained BisF-1-CH4 was 865.
- the carbon concentration was 84.7% by mass, and the oxygen concentration was 7.4% by mass.
- a four-necked flask having an internal volume of 0.5 L equipped with a Dimroth condenser, a thermometer, and a stirring blade was prepared.
- 100 g (0.51 mol) of the dimethylnaphthalene formaldehyde resin obtained as described above and 0.05 g of paratoluenesulfonic acid were charged in a nitrogen stream, and the temperature was raised to 190 ° C. Stir after heating for hours. Thereafter, 52.0 g (0.36 mol) of 1-naphthol was further added, and the temperature was further raised to 220 ° C. to react for 2 hours.
- the obtained resin (CR-1) was Mn: 885, Mw: 2220, and Mw / Mn: 4.17.
- the carbon concentration was 89.1% by mass, and the oxygen concentration was 4.5% by mass.
- Acid generator Ditertiary butyl diphenyliodonium nonafluoromethanesulfonate (DTDPI) manufactured by Midori Chemical Co., Ltd.
- Cross-linking agent Nikalac MX270 (Nikalac) manufactured by Sanwa Chemical Co., Ltd.
- Organic solvent Propylene glycol monomethyl ether acetate acetate (PGMEA)
- Novolak PSM4357 manufactured by Gunei Chemical Co., Ltd.
- Etching device RIE-10NR manufactured by Samco International Output: 50W Pressure: 20Pa Time: 2min Etching gas
- Ar gas flow rate: CF 4 gas flow rate: O 2 gas flow rate 50: 5: 5 (sccm)
- the etching resistance was evaluated according to the following procedure. First, a novolac underlayer film was produced under the same conditions as in Example 1 except that novolak (PSM4357 manufactured by Gunei Chemical Co., Ltd.) was used instead of the compound (BisF-1-CH4) used in Example 1. . And the said etching test was done for the lower layer film of this novolak, and the etching rate at that time was measured.
- novolak PSM4357 manufactured by Gunei Chemical Co., Ltd.
- a compound of the following formula (11) 5 parts by mass, triphenylsulfonium nonafluoromethanesulfonate: 1 part by mass, tributylamine: 2 parts by mass, and PGMEA: 92 parts by mass are blended.
- the prepared one was used.
- the compound of the formula (11) is 4.15 g of 2-methyl-2-methacryloyloxyadamantane, 3.00 g of methacryloyloxy- ⁇ -butyrolactone, 2.08 g of 3-hydroxy-1-adamantyl methacrylate, azobisisobutyronitrile. 0.38 g was dissolved in 80 mL of tetrahydrofuran to obtain a reaction solution.
- This reaction solution was polymerized for 22 hours under a nitrogen atmosphere while maintaining the reaction temperature at 63 ° C., and then the reaction solution was dropped into 400 mL of n-hexane.
- the product resin thus obtained was coagulated and purified, and the resulting white powder was filtered and obtained by drying overnight at 40 ° C. under reduced pressure.
- 40, 40 and 20 indicate the ratio of each structural unit, and do not indicate a block copolymer.
- the photoresist layer was exposed using an electron beam drawing apparatus (ELIONX, ELS-7500, 50 keV), baked at 115 ° C. for 90 seconds (PEB), and 2.38 mass% tetramethylammonium hydroxide (A positive resist pattern was obtained by developing with an aqueous solution of TMAH for 60 seconds.
- ELIONX electron beam drawing apparatus
- ELS-7500 ELS-7500, 50 keV
- PEB baked at 115 ° C. for 90 seconds
- TMAH 2.38 mass% tetramethylammonium hydroxide
- the shape of the obtained resist pattern was observed using an electron microscope (S-4800) manufactured by Hitachi, Ltd.
- S-4800 electron microscope
- the resist pattern having no pattern collapse and having good rectangularity was evaluated as “good”, and the resist pattern was evaluated as “defective”.
- the minimum line width with no pattern collapse and good rectangularity was used as an evaluation index as the resolution.
- the minimum amount of electron beam energy that can draw a good pattern shape is used as an evaluation index as sensitivity. The results are shown in Table 1.
- Example 1 using BisF-1-CH4, which is a compound of the present invention was good in any of heat resistance, solvent solubility and etching resistance.
- Comparative Example 1 using the polyphenol compound BisF-1 although the heat resistance and the etching resistance were good, the solvent solubility was poor.
- Comparative Example 2 using CR-1 (phenol-modified dimethylnaphthalene formaldehyde resin) all of heat resistance, solvent solubility, and etching resistance were poor, and resist performance evaluation was not performed.
- Example 1 it was confirmed that the resist pattern shape after development was good and no defects were observed.
- Comparative Example 1 it was confirmed that the resist pattern shape after development was poor and there were many defects.
- Example 1 was significantly superior in both resolution and sensitivity as compared with Comparative Example 3 in which the formation of the lower layer film was omitted. From the difference in the resist pattern shape after development, it was shown that the lower layer film forming material for lithography of Example 1 had good adhesion to the resist material.
- Example 6 The underlayer film forming composition for lithography used in Example 1 was applied onto a 300 nm-thick SiO 2 substrate and baked at 240 ° C. for 60 seconds and further at 400 ° C. for 120 seconds, thereby forming a lower layer having a thickness of 80 nm. A film was formed. On this lower layer film, a silicon-containing intermediate layer material was applied and baked at 200 ° C. for 60 seconds to form an intermediate layer film having a thickness of 35 nm. Further, the ArF resist solution was applied on this intermediate layer film and baked at 130 ° C. for 60 seconds to form a 150 nm-thick photoresist layer.
- the silicon-containing intermediate layer material a silicon atom-containing polymer described in ⁇ Synthesis Example 1> of JP-A-2007-226170 was used.
- the photoresist layer was subjected to mask exposure using an electron beam lithography apparatus (ELIONX, ELS-7500, 50 keV), baked at 115 ° C. for 90 seconds (PEB), and 2.38 mass% tetramethylammonium hydroxide.
- TMAH aqueous solution for 60 seconds
- a positive resist pattern of 55 nm L / S (1: 1) was obtained.
- Each etching condition is as shown below.
- Output: 50W Pressure: 20Pa Time: 2min Etching gas Ar gas flow rate: CF 4 gas flow rate: O 2 gas flow rate 50: 5: 5 (sccm) (Etching conditions for resist underlayer film pattern to SiO 2 film)
- Output: 50W Pressure: 20Pa Time: 2min Etching gas Ar gas flow rate: C 5 F 12 gas flow rate: C 2 F 6 gas flow rate: O 2 gas flow rate 50: 4: 3: 1 (sccm)
- Example 7 Purification of BisF-1-CH4 A solution (10% by mass) of BisF-1-CH4 used in Example 1 dissolved in PGMEA was added to a 1000 mL four-necked flask (bottomed type). 150 g was charged and heated to 80 ° C. with stirring. Next, 37.5 g of an aqueous oxalic acid solution (pH 1.3) was added, and the mixture was stirred for 5 minutes and allowed to stand for 30 minutes. Thereby, it isolate
- an aqueous oxalic acid solution pH 1.3
- the compounds and resins of the present invention have a relatively high carbon concentration, a relatively low oxygen concentration, a relatively high heat resistance, a relatively high solvent solubility, and can be applied to a wet process. Since this lower layer film forming material for lithography uses a compound or resin having a specific structure, which has high heat resistance, relatively high carbon concentration, relatively low oxygen concentration, and high solvent solubility. Deterioration of the film during high temperature baking is suppressed, and a lower layer film having excellent etching resistance against oxygen plasma etching or the like can be formed. Furthermore, since the adhesiveness with the resist layer is also excellent, an excellent resist pattern can be formed.
- the underlayer film forming material for lithography containing the compound or resin of the present invention and the underlayer film forming composition containing the material can be widely and effectively used in various applications requiring these performances.
- the present invention provides, for example, an electrical insulating material, a resist resin, a semiconductor sealing resin, an adhesive for a printed wiring board, an electrical laminate mounted on an electrical device / electronic device / industrial device, etc. ⁇ Matrix resin for prepregs, built-up laminate materials, resin for fiber reinforced plastics, sealing resin for liquid crystal display panels, paints, various coating agents, adhesives, and coatings for semiconductors installed in electronic equipment and industrial equipment It can be used widely and effectively in an agent, a resist resin for a semiconductor, a resin for forming a lower layer film, and the like. In particular, the present invention can be used particularly effectively in the field of lithography lower layer films and multilayer resist lower layer films.
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Abstract
Description
[1]下記式(1)で表される化合物。
[2]R2の少なくとも1つ及び/又はR3の少なくとも1つが、炭素数1~30のアルコキシ基である前記[1]に記載の化合物。
[3]前記式(1)で表される化合物が、下記式(1a)で表される化合物である前記[1]又は[2]に記載の化合物。
[4]前記式(1a)で表される化合物が、下記式(1b)で表される化合物である前記[3]に記載の化合物。
[5]前記式(1b)で表される化合物が、下記式(BiF-1-CH)で表される前記[4]に記載の化合物。
[6]前記[1]~[5]のいずれか一つに記載の化合物をモノマーとして得られる樹脂。
[7]前記[1]~[5]のいずれか一つに記載の化合物と架橋反応性のある化合物との反応によって得られる前記[6]に記載の樹脂。
[8]前記架橋反応性のある化合物が、アルデヒド、ケトン、カルボン酸、カルボン酸ハライド、ハロゲン含有化合物、アミノ化合物、イミノ化合物、イソシアネート及び不飽和炭化水素基含有化合物からなる群より選ばれる少なくとも1つである前記[7]に記載の樹脂。
[9]下記式(2)で表される構造を有する前記[6]に記載の樹脂。
[10]前記[1]~[5]のいずれか一つに記載の化合物及び/又は前記[6]~[9]のいずれか一つに記載の樹脂を含有するリソグラフィー用下層膜形成材料。
[11]前記[10]に記載のリソグラフィー用下層膜形成材料と溶媒とを含有するリソグラフィー用下層膜形成用組成物。
[12]架橋剤をさらに含有する前記[11]に記載のリソグラフィー用下層膜形成用組成物。
[13]酸発生剤をさらに含有する前記[11]又は[12]に記載のリソグラフィー用下層膜形成用組成物。
[14]前記[11]~[13]のいずれかに記載のリソグラフィー用下層膜形成用組成物から形成されるリソグラフィー用下層膜。
[15]基板上に、前記[11]~[13]のいずれかに記載の下層膜形成用組成物を用いて下層膜を形成し、該下層膜上に、少なくとも1層のフォトレジスト層を形成した後、該フォトレジスト層の所要の領域に放射線を照射し、現像を行うレジストパターン形成方法。
[16]基板上に、前記[11]~[13]のいずれかに記載の下層膜形成用組成物を用いて下層膜を形成し、前記下層膜上に、珪素原子を含有するレジスト中間層膜材料を用いて中間層膜を形成し、前記中間層膜上に、少なくとも1層のフォトレジスト層を形成した後、前記フォトレジスト層の所要の領域に放射線を照射し、現像してレジストパターンを形成し、その後、前記レジストパターンをマスクとして前記中間層膜をエッチングし、得られた中間層膜パターンをエッチングマスクとして前記下層膜をエッチングし、得られた下層膜パターンをエッチングマスクとして基板をエッチングすることで基板にパターンを形成する回路パターン形成方法。
[17]前記[1]~[5]のいずれか一つに記載の化合物又は前記[6]~[9]のいずれか一つに記載の樹脂と、水と任意に混和しない有機溶媒を含む溶液と、酸性の水溶液と、を接触させ抽出する工程を含む、化合物又は樹脂の精製方法。
[18]前記酸性の水溶液が、塩酸、硫酸、硝酸及びリン酸からなる群より選ばれる1種以上の鉱酸水溶液、又は酢酸、プロピオン酸、蓚酸、マロン酸、コハク酸、フマル酸、マレイン酸、酒石酸、クエン酸、メタンスルホン酸、フェノールスルホン酸、p-トルエンスルホン酸及びトリフルオロ酢酸からなる群より選ばれる1種以上の有機酸水溶液である前記[17]に記載の精製方法。
[19]前記水と任意に混和しない有機溶媒が、トルエン、2-ヘプタノン、シクロヘキサノン、シクロペンタノン、メチルイソブチルケトン、プロピレングリコールモノメチルエーテルアセテート又は酢酸エチルである前記[17]又は[18]に記載の精製方法。
[20]前記溶液と酸性の水溶液とを接触させ抽出処理を行ったのち、さらに水による抽出処理を行う工程を含む前記[17]~[19]のいずれか一つに記載の精製方法。
本発明の化合物は、下記式(1)で表される。本発明の化合物は、このように構成されているため、耐熱性が高く、炭素濃度が比較的に高く、酸素濃度が比較的に低く、溶媒溶解性も高い。
式(1)中、R2~R5は、各々独立して、炭素数1~10のアルキル基;炭素数6~10のアリール基;炭素数2~10のアルケニル基;炭素数1~30のアルコキシ基;チオール基及び水酸基からなる群より選択される1価の基である。但し、R4の少なくとも1つ及び/又はR5の少なくとも1つは炭素数1~30のアルコキシ基である。
式(1)中、m2及びm3は、各々独立して0~8の整数であり、m4及びm5は、各々独立して0~9の整数であるが、m4及びm5は、同時に0となることはない。
式(1)中、nは、1~4の整数である。
式(1)中、p2~p5は各々独立して0~2の整数である。尚、例えばp2が0の場合、対応する芳香環はベンゼン環となり、p2が1の場合には対応する芳香環がナフタレン環となる。更に、p2が3の場合には対応する芳香環がアントラセン等の三員環の芳香環となる。
また炭素数1~30のアルコキシ基とは、直鎖状炭化水素基、分岐状炭化水素基又は脂環式炭化水素基、芳香族炭化水素基およびそれらの二以上の組み合わせからなる基より選ばれる基と、酸素原子とから構成される基である。ここで、前記脂環式炭化水素基については、有橋脂環式炭化水素基も含まれる。また、該アルコキシ基は、二重結合、ヘテロ原子、ハロゲン原子を有していてもよい。
m2’及びm3’は各々独立して0~4の整数であり、m4’及びm5’は各々独立して0~5の整数である。但し、m4’及びm5’は同時に0となることはない。
式(1b)中、R6及びR7は、各々独立して、炭素数1~10アルキル基、炭素数6~10のアリール基、炭素数2~10のアルケニル基、チオール基又は水酸基であり、R8~R11は、各々独立して、炭素数1~30のアルキル基又は水素原子である。但し、R8~R11の少なくとも1つは炭素数1~30のアルキル基である。上述のアルキル基及びアルケニル基は、直鎖状、分岐状又は環状のいずれであってもよい。
m6及びm7は、各々独立して0~7の整数である。
m2’及びm3’は各々独立して0~4の整数であり、m4’及びm5’は各々独立して0~5の整数である。但し、m4’及びm5’は同時に0となることはない。
式(2)中、Lは、炭素数1~20の直鎖状若しくは分岐状のアルキレン基又は単結合である。
本実施形態のリソグラフィー用下層膜形成材料は、前記式(1)で表される化合物及び該化合物をモノマーとして得られる前記樹脂からなる群より選ばれる物質を少なくとも1つ含有するものである。
本実施形態において前記物質はリソグラフィー用下層膜形成材料中、25~100質量%であることが好ましく、50~100質量%であることがより好ましく、75~100質量%であることがさらに好ましく、100質量%であることが特に好ましい。
なお、本実施形態のリソグラフィー用下層膜形成材料は、本発明の効果が損なわれない範囲において、既に知られているリソグラフィー用下層膜形成材料等を含んでいてもよい。
本実施形態においてリソグラフィー用下層膜形成用組成物は、前記リソグラフィー用下層膜形成材料と溶媒とを含有する。
本実施形態において用いる溶媒としては、前記リソグラフィー用下層膜形成材料が、少なくとも溶解するものであれば公知のものを適宜用いることができる。溶媒の具体例としては、例えば、アセトン、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノン等のケトン系溶媒、プロピレングリコールモノメチルエーテル、プロピレングリコールモノメチルエーテルアセテート(PGMEA)等のセロソルブ系溶媒、乳酸エチル、酢酸メチル、酢酸エチル、酢酸ブチル、酢酸イソアミル、乳酸エチル、メトキシプロピオン酸メチル、ヒドロキシイソ酪酸メチル等のエステル系溶媒、メタノール、エタノール、イソプロパノール、1-エトキシ-2-プロパノール(PGME)等のアルコール系溶媒、トルエン、キシレン、アニソール等の芳香族系炭化水素等が挙げられるが、これらに特に限定されない。これらの溶媒は、1種を単独で、或いは2種以上を組み合わせて用いることができる。
本実施形態のリソグラフィー用下層膜形成用組成物は、インターミキシングを抑制する等の観点から、必要に応じて架橋剤を含有していてもよい。本実施形態で使用可能な架橋剤の具体例としては、例えば、メラミン化合物、グアナミン化合物、グリコールウリル化合物又はウレア化合物、エポキシ化合物、チオエポキシ化合物、イソシアネート化合物、アジド化合物、アルケニルエーテル基などの2重結合を含む化合物であって、メチロール基、アルコキシメチル基、アシロキシメチル基から選ばれる少なくとも一つの基で置換されたものなどが挙げるが、これらに特に限定されない。なお、これらの架橋剤は、1種を単独で、或いは2種以上を組み合わせて用いることができる。また、これらは添加剤として用いてもよいが、これら架橋性基をポリマー側鎖にペンダント基として導入してもよい。また、ヒドロキシ基を含む化合物も架橋剤として用いることができる。
本実施形態のリソグラフィー用下層膜形成用組成物は、熱による架橋反応をさらに促進させるなどの観点から、必要に応じて酸発生剤を含有していてもよい。当業界において酸発生剤としては、熱分解によって酸を発生するもの、光照射によって酸を発生するものなどが知られているが、いずれのものも使用することができる。
1)下記一般式(P1a-1)、(P1a-2)、(P1a-3)又は(P1b)のオニウム塩、
2)下記一般式(P2)のジアゾメタン誘導体、
3)下記一般式(P3)のグリオキシム誘導体、
4)下記一般式(P4)のビススルホン誘導体、
5)下記一般式(P5)のN-ヒドロキシイミド化合物のスルホン酸エステル、
6)β-ケトスルホン酸誘導体、
7)ジスルホン誘導体、
8)ニトロベンジルスルホネート誘導体、
9)スルホン酸エステル誘導体
等が挙げられるが、これらに特に限定されない。なお、これらの酸発生剤は、1種を単独で、或いは2種以上を組み合わせて用いることができる。
これらのなかでも、特に、トリフルオロメタンスルホン酸トリフェニルスルホニウム、トリフルオロメタンスルホン酸(p-tert-ブトキシフェニル)ジフェニルスルホニウム、トリフルオロメタンスルホン酸トリス(p-tert-ブトキシフェニル)スルホニウム、p-トルエンスルホン酸トリフェニルスルホニウム、p-トルエンスルホン酸(p-tert-ブトキシフェニル)ジフェニルスルホニウム、p-トルエンスルホン酸トリス(p-tert-ブトキシフェニル)スルホニウム、トリフルオロメタンスルホン酸トリナフチルスルホニウム、トリフルオロメタンスルホン酸シクロヘキシルメチル(2-オキソシクロヘキシル)スルホニウム、トリフルオロメタンスルホン酸(2-ノルボニル)メチル(2-オキソシクロヘキシル)スルホニウム、1,2’-ナフチルカルボニルメチルテトラヒドロチオフェニウムトリフレート等のオニウム塩、ビス(ベンゼンスルホニル)ジアゾメタン、ビス(p-トルエンスルホニル)ジアゾメタン、ビス(シクロヘキシルスルホニル)ジアゾメタン、ビス(n-ブチルスルホニル)ジアゾメタン、ビス(イソブチルスルホニル)ジアゾメタン、ビス(sec-ブチルスルホニル)ジアゾメタン、ビス(n-プロピルスルホニル)ジアゾメタン、ビス(イソプロピルスルホニル)ジアゾメタン、ビス(tert-ブチルスルホニル)ジアゾメタン等のジアゾメタン誘導体、ビス-(p-トルエンスルホニル)-α-ジメチルグリオキシム、ビス-(n-ブタンスルホニル)-α-ジメチルグリオキシム等のグリオキシム誘導体、ビスナフチルスルホニルメタン等のビススルホン誘導体、N-ヒドロキシスクシンイミドメタンスルホン酸エステル、N-ヒドロキシスクシンイミドトリフルオロメタンスルホン酸エステル、N-ヒドロキシスクシンイミド1-プロパンスルホン酸エステル、N-ヒドロキシスクシンイミド2-プロパンスルホン酸エステル、N-ヒドロキシスクシンイミド1-ペンタンスルホン酸エステル、N-ヒドロキシスクシンイミドp-トルエンスルホン酸エステル、N-ヒドロキシナフタルイミドメタンスルホン酸エステル、N-ヒドロキシナフタルイミドベンゼンスルホン酸エステル等のN-ヒドロキシイミド化合物のスルホン酸エステル誘導体が好ましく用いられる。
塩基性化合物は、酸発生剤より微量に発生した酸が架橋反応を進行させるのを防ぐための、酸に対するクエンチャーの役割を果たす。このような塩基性化合物としては、第一級、第二級、第三級の脂肪族アミン類、混成アミン類、芳香族アミン類、複素環アミン類、カルボキシ基を有する含窒素化合物、スルホニル基を有する含窒素化合物、水酸基を有する含窒素化合物、ヒドロキシフェニル基を有する含窒素化合物、アルコール性含窒素化合物、アミド誘導体、イミド誘導体等が挙げられるが、これらに特に限定されない。
また、本実施形態のリソグラフィー用下層膜形成用組成物は、熱硬化性の付与や吸光度をコントロールする目的で、他の樹脂及び/又は化合物を含有していてもよい。このような他の樹脂及び/又は化合物としては、ナフトール樹脂、キシレン樹脂ナフトール変性樹脂、ナフタレン樹脂のフェノール変性樹脂、ポリヒドロキシスチレン、ジシクロペンタジエン樹脂、(メタ)アクリレート、ジメタクリレート、トリメタクリレート、テトラメタクリレート、ビニルナフタレン、ポリアセナフチレンなどのナフタレン環、フェナントレンキノン、フルオレンなどのビフェニル環、チオフェン、インデンなどのヘテロ原子を有する複素環を含む樹脂や芳香族環を含まない樹脂;ロジン系樹脂、シクロデキストリン、アダマンタン(ポリ)オール、トリシクロデカン(ポリ)オール及びそれらの誘導体等の脂環構造を含む樹脂又は化合物等が挙げられるが、これらに特に限定されない。さらに、本実施形態のリソグラフィー用下層膜形成用組成物は、当業界で公知の添加剤、例えば、紫外線吸収剤、界面活性剤、着色剤、ノニオン系界面活性剤等を含有していてもよい。
本実施形態のリソグラフィー用下層膜は、前述のリソグラフィー用下層膜形成用組成物を用いて形成されるものである。
このような中間層膜の上に直接フォトレジスト膜を形成することができるが、中間層膜の上に有機反射防止膜(BARC)をスピンコートで形成して、その上にフォトレジスト膜を形成してもよい。
なお、基板は、当業界で公知のものを適宜選択して使用することができ、特に限定されないが、Si、α-Si、p-Si、SiO2、SiN、SiON、W、TiN、Al等が挙げられる。また、基板は、基材(支持体)上に被加工膜(被加工基板)を有する積層体であってもよい。このような被加工膜としては、Si、SiO2、SiON、SiN、p-Si、α-Si、W、W-Si、Al、Cu、Al-Si等種々のLow-k膜及びそのストッパー膜等が挙げられ、通常、基材(支持体)とは異なる材質のものが用いられる。なお、加工対象となる基板或いは被加工膜の厚さは、特に限定されないが、通常、50~10,000nm程度であることが好ましく、より好ましくは75~5,000nmである。
本実施形態における化合物又は樹脂の精製方法は、水と任意に混和しない有機溶媒及び前記式(1)で表される化合物又は該化合物をモノマーとして得られる樹脂を含む溶液(以下、溶液(A)と称することがある)と、酸性の水溶液と、を接触させ抽出する工程を含む。本実施形態の精製方法によれば、前記化合物又は前記樹脂に不純物として含まれうる種々の金属の含有量を低減することができる。
より詳細には、本実施形態においては、前記化合物又は前記樹脂を水と任意に混和しない有機溶媒に溶解させ、さらにその溶液を酸性水溶液と接触させて抽出処理を行うものとすることができる。これにより、前記化合物又は前記樹脂を含む溶液(A)に含まれる金属分を水相に移行させたのち、有機相と水相とを分離して金属含有量の低減された前記化合物又は前記樹脂を得ることができる。
これらの溶媒はそれぞれ単独で用いることもできるし、また2種以上を混合して用いることもできる。
また、ここで用いる水は、本実施形態の目的に沿って、金属含有量の少ないもの、例えばイオン交換水等であることが好ましい。抽出処理は1回だけでもかまわないが、混合、静置、分離という操作を複数回繰り返して行うのも有効である。また、抽出処理における両者の使用割合や、温度、時間等の条件は特に限定されないが、先の酸性の水溶液との接触処理の場合と同様で構わない。
有機元素分析により炭素濃度及び酸素濃度(質量%)を測定した。
装置:CHNコーダーMT-6(ヤナコ分析工業(株)製)
(分子量)
LC-MS分析により、Water社製Acquity UPLC/MALDI-Synapt HDMSを用いて測定した。
(分子量の測定)
ゲル浸透クロマトグラフィー(GPC)分析により、ポリスチレン換算の重量平均分子量(Mw)、数平均分子量(Mn)を求め、分散度(Mw/Mn)を求めた。
装置:Shodex GPC-101型(昭和電工(株)製)
カラム:KF-80M×3
溶離液:THF 1ml/min
温度:40℃
(耐熱性の評価)
エスアイアイ・ナノテクノロジー社製EXSTAR6000DSC装置を使用し、試料約5mgをアルミニウム製非密封容器に入れ、窒素ガス(30ml/min)気流中昇温速度10℃/minで500℃まで昇温した。その際、ベースラインに減少部分が現れる温度を熱分解温度(Tg)とし、以下の基準で耐熱性を評価した。
評価A:熱分解温度が≧150℃
評価C:熱分解温度が<150℃
(溶媒溶解性の評価)
23℃にて、化合物をプロピレングリコールモノメチルエーテル(PGME)に対して5質量%溶液になるよう溶解させ、その後、5℃にて30日間静置し、結果を以下の基準で評価した。
評価A:目視にて析出物なしを確認
評価C:目視にて析出物ありを確認
攪拌機、冷却管及びビュレットを備えた内容積200mLの容器を準備した。この容器に、4,4’-ビフェノール(東京化成社製試薬)30g(161mmol)と、4-ビフェニルアルデヒド(三菱瓦斯化学社製)15g(82mmol)と、酢酸ブチル100mLと、を仕込み、p-トルエンスルホン酸(関東化学社製試薬)3.9g(21mmol)を加えて、反応液を調製した。この反応液を90℃で3時間撹拌して反応を行った。次に、反応液を濃縮し、ヘプタン50gを加えて反応生成物を析出させ、室温まで冷却した後、濾過を行って分離した。濾過により得られた固形物を乾燥させた後、カラムクロマトによる分離精製を行うことにより、下記式で表される目的化合物(BisF-1)5.8gを得た。
なお、400MHz-1H-NMRにより以下のピークが見出され、下記式の化学構造を有することを確認した。
1H-NMR:(d-DMSO、内部標準TMS)
δ(ppm)9.4(4H,O-H)、6.8~7.8(22H,Ph-H)、6.2(1H,C-H)
得られた化合物について、前記方法により分子量を測定した結果、536であった。
4,4’-ビフェノールを2,2’-ビフェノールに変更した以外は、製造例1と同様にし、下記式で表される目的混合物(BisF-2)を3.0g得た。
なお、400MHz-1H-NMRにより以下のピークが見出され、下記式の化学構造を有することを確認した。
1H-NMR:(d-DMSO、内部標準TMS)
δ(ppm)9.3(4H,O-H)、6.8~7.8(22H,Ph-H)、6.3(1H,C-H)
得られた化合物について、前記方法により分子量を測定した結果、536であった。
攪拌機、冷却管及びビュレットを備えた内容積1000mLの容器に、前記で得られたBisF-1を6.7g(12.5mmol)と、炭酸カリウムを108g(810mmol)と、ジメチルホルムアミド200mLとを仕込み、ブロモシクロヘキサン250g(1.53mol)を加えて、反応液を110℃で24時間撹拌して反応を行った。次に、反応液を濃縮し、純水500gを加えて反応生成物を析出させ、室温まで冷却した後、濾過を行って分離した。得られた固形物を濾過し、乾燥させた後、カラムクロマトによる分離精製を行うことにより、下記式で表される目的化合物(BisF-1-CH4)を5.0g得た。
得られた化合物について、前記測定条件でNMR測定を行ったところ、以下のピークが見出され、下記式の化学構造を有することを確認した。
1H-NMR:(d-DMSO、内部標準TMS)
δ(ppm)6.8~7.8(22H,Ph-H)、6.2(1H,C-H)、1.4~4.5(44H,Cy-H)/Cy-H
得られたBisF-1-CH4の分子量は、865であった。また、炭素濃度は84.7質量%、酸素濃度は7.4質量%であった。
炭酸カリウムを54g(405mmol)、ブロモシクロヘキサンを125g(0.77mol)に変更した以外は、合成実施例1と同様にし、下記式で表される目的混合物(BisF-1-CH2)を2.0g得た。
得られた化合物について、前記測定条件でNMR測定を行ったところ、以下のピークが見出され、下記式の化学構造を有することを確認した。
1H-NMR:(d-DMSO、内部標準TMS)
δ(ppm)9.4(2H,O-H)、6.8~7.8(22H,Ph-H)、6.2(1H,C-H)、1.4~4.5(22H,Cy-H)/Cy-H
ブロモシクロヘキサンをヨウ化メチル217g(1.53mol)に変更した以外は、合成実施例1と同様にし、下記式で表される目的化合物(BisF-1-ME4)を2.0g得た。
得られた化合物について、前記測定条件でNMR測定を行ったところ、以下のピークが見出され、下記式の化学構造を有することを確認した。
1H-NMR:(d-DMSO、内部標準TMS)
δ(ppm)6.8~7.8(22H,Ph-H)、6.2(1H,C-H)、3.8(12H,CH3)
得られたBisF-2-ME4の分子量は、592であった。また、炭素濃度は83.1質量%、酸素濃度は10.8質量%であった。
攪拌機、冷却管及びビュレットを備えた内容積1000mLの容器に、上述で得られたBisF-1:3.4g(6.3mmol)と、炭酸セシウム26g(80mmol)と、ヨウ化銅0.8g(4mmol)と、ジメチルグリシン塩酸塩1.7g(12mmol)と、ジオキサン80mLとを仕込み、ヨウ化ベンゼン8.2g(40mmol)を加えて、反応液を90℃で96時間撹拌して反応を行った。次に、酢酸エチル500mLを加えて反応生成物を析出させ、室温まで冷却した後、濾過を行って分離した。得られた固形物を濾過し、乾燥させた後、カラムクロマトによる分離精製を行うことにより、下記式で表される目的化合物(BisF-1-PH4)1.9gを得た。
得られた化合物について、前記測定条件でNMR測定を行ったところ、以下のピークが見出され、下記式の化学構造を有することを確認した。
1H-NMR:(d-DMSO、内部標準TMS)
δ(ppm)6.8~7.8(42H,Ph-H)、6.2(1H,C-H)
得られたBisF-1-PH4の分子量は、840であった。また、炭素濃度は87.1質量%、酸素濃度は7.6質量%であった。
BisF-1をBisF-2に変更した以外は、合成実施例1と同様にし、下記式で表される目的物(BisF-2-CH4)を2.0g得た。
得られた化合物について、前記測定条件でNMR測定を行ったところ、以下のピークが見出され、下記式の化学構造を有することを確認した。
1H-NMR:(d-DMSO、内部標準TMS)
δ(ppm)6.8~7.8(22H,Ph-H)、6.3(1H,C-H)、1.4~4.5(44H,Cy-H)/Cy-H
得られたBisF-2-CH4の分子量は、865であった。また、炭素濃度は84.7質量%、酸素濃度は7.4質量%であった。
ジムロート冷却管、温度計及び攪拌翼を備えた、底抜きが可能な内容積10Lの四つ口フラスコを準備した。この四つ口フラスコに、窒素気流中、1,5-ジメチルナフタレン1.09kg(7mol、三菱ガス化学(株)製)、40質量%ホルマリン水溶液2.1kg(ホルムアルデヒドとして28mol、三菱ガス化学(株)製)及び98質量%硫酸(関東化学(株)製)0.97mLを仕込み、常圧下、100℃で還流させながら7時間反応させた。その後、希釈溶媒としてエチルベンゼン(和光純薬工業(株)製試薬特級)1.8kgを反応液に加え、静置後、下相の水相を除去した。さらに、中和及び水洗を行い、エチルベンゼン及び未反応の1,5-ジメチルナフタレンを減圧下で留去することにより、淡褐色固体のジメチルナフタレンホルムアルデヒド樹脂1.25kgを得た。
得られたジメチルナフタレンホルムアルデヒド樹脂の分子量は、Mn:562、Mw:1168、Mw/Mn:2.08であった。また、炭素濃度は84.2質量%、酸素濃度は8.3質量%であった。
得られた樹脂(CR-1)は、Mn:885、Mw:2220、Mw/Mn:4.17であった。また、炭素濃度は89.1質量%、酸素濃度は4.5質量%であった。
前記BisF-1-CH4,BisF-1-CH2,BisF-1-ME4,BisF-1-PH4,BisF-2-CH4,BisF-1及びCR-1を用いて耐熱性の評価及び溶媒溶解性の評価を行った。結果を第1表に示す。
また、第1表に示す組成のリソグラフィー用下層膜形成用組成物を各々調製した。次に、これらの下層膜形成用組成物をシリコン基板上に回転塗布し、その後、240℃で60秒間、さらに400℃で120秒間ベークして、膜厚200nmの下層膜を各々作製した。酸発生剤、架橋剤及び有機溶媒については次のものを用いた。
架橋剤:三和ケミカル社製 ニカラックMX270(ニカラック)
有機溶媒:プロピレングリコールモノメチルエーテルアセテートアセテート(PGMEA)
ノボラック:群栄化学社製 PSM4357
エッチング装置:サムコインターナショナル社製 RIE-10NR
出力:50W
圧力:20Pa
時間:2min
エッチングガス
Arガス流量:CF4ガス流量:O2ガス流量=50:5:5(sccm)
[エッチング耐性評価]
エッチング耐性評価は、以下の手順で行った。
まず、実施例1において用いる化合物(BisF-1-CH4)に代えてノボラック(群栄化学社製:PSM4357)を用いること以外は、実施例1と同様の条件で、ノボラックの下層膜を作製した。そして、このノボラックの下層膜を対象として、前記のエッチング試験を行い、そのときのエッチングレートを測定した。
次に、実施例1~5及び比較例1~2の下層膜を対象として、前記エッチング試験を同様に行い、そのときのエッチングレートを測定した。
そして、ノボラックの下層膜のエッチングレートを基準として、以下の評価基準でエッチング耐性を評価した。
[評価基準]
A:ノボラックの下層膜に比べてエッチングレートが、-10%未満
B:ノボラックの下層膜に比べてエッチングレートが、-10%~+5%
C:ノボラックの下層膜に比べてエッチングレートが、+5%超
式(11)の化合物は、2-メチル-2-メタクリロイルオキシアダマンタン4.15g、メタクリルロイルオキシ-γ-ブチロラクトン3.00g、3-ヒドロキシ-1-アダマンチルメタクリレート2.08g、アゾビスイソブチロニトリル0.38gを、テトラヒドロフラン80mLに溶解させて反応溶液とした。この反応溶液を、窒素雰囲気下、反応温度を63℃に保持して、22時間重合させた後、反応溶液を400mLのn-ヘキサン中に滴下した。このようにして得られる生成樹脂を凝固精製させ、生成した白色粉末をろ過し、減圧下40℃で一晩乾燥させて得た。
下層膜の形成を行わないこと以外は、実施例1と同様にして、フォトレジスト層をSiO2基板上に直接形成し、ポジ型のレジストパターンを得て同様の評価を行った。結果を第1表に示す。
また、実施例1では、現像後のレジストパターン形状が良好であり、欠陥も見られないことが確認された。一方、比較例1は、現像後のレジストパターン形状が不良であり、欠陥も多いことが確認された。これは、比較例1で用いたBisF-1が塗布溶媒に対して低溶解性である為と推察される。
さらに、実施例1は、下層膜の形成を省略した比較例3に比して、解像性及び感度ともに有意に優れていることが確認された。
現像後のレジストパターン形状の相違から、実施例1のリソグラフィー用下層膜形成材料は、レジスト材料との密着性が良いことが示された。
実施例1において用いたリソグラフィー用下層膜形成用組成物を膜厚300nmのSiO2基板上に塗布して、240℃で60秒間、さらに400℃で120秒間ベークすることにより、膜厚80nmの下層膜を形成した。この下層膜上に、珪素含有中間層材料を塗布し、200℃で60秒間ベークすることにより、膜厚35nmの中間層膜を形成した。さらに、この中間層膜上に、前記ArF用レジスト溶液を塗布し、130℃で60秒間ベークすることにより、膜厚150nmのフォトレジスト層を形成した。なお、珪素含有中間層材料としては、特開2007-226170号公報の<合成例1>に記載の珪素原子含有ポリマーを用いた。
次いで、電子線描画装置(エリオニクス社製;ELS-7500,50keV)を用いて、フォトレジスト層をマスク露光し、115℃で90秒間ベーク(PEB)し、2.38質量%テトラメチルアンモニウムヒドロキシド(TMAH)水溶液で60秒間現像することにより、55nmL/S(1:1)のポジ型のレジストパターンを得た。
その後、サムコインターナショナル社製のRIE-10NRを用いて、得られたレジストパターンをマスクにして珪素含有中間層膜(SOG)のドライエッチング加工を行い、続いて、得られた珪素含有中間層膜パターンをマスクにした下層膜のドライエッチング加工と、得られた下層膜パターンをマスクにしたSiO2膜のドライエッチング加工とを順次行った。
(レジストパターンのレジスト中間層膜へのエッチング条件)
出力:50W
圧力:20Pa
時間:1min
エッチングガス
Arガス流量:CF4ガス流量:O2ガス流量=50:8:2(sccm)
(レジスト中間膜パターンのレジスト下層膜へのエッチング条件)
出力:50W
圧力:20Pa
時間:2min
エッチングガス
Arガス流量:CF4ガス流量:O2ガス流量=50:5:5(sccm)
(レジスト下層膜パターンのSiO2膜へのエッチング条件)
出力:50W
圧力:20Pa
時間:2min
エッチングガス
Arガス流量:C5F12ガス流量:C2F6ガス流量:O2ガス流量
=50:4:3:1(sccm)
前記のようにして得られた実施例6のパターン断面(エッチング後のSiO2膜の形状)を、(株)日立製作所製電子顕微鏡(S-4800)を用いて観察したところ、本発明の下層膜を用いた実施例は、多層レジスト加工におけるエッチング後のSiO2膜の形状は矩形であり、欠陥も認められず良好であることが確認された。
1000mL容量の四つ口フラスコ(底抜き型)に、実施例1で用いたBisF-1-CH4をPGMEAに溶解させた溶液(10質量%)を150g仕込み、攪拌しながら80℃まで加熱した。次いで、蓚酸水溶液(pH1.3)37.5gを加え、5分間攪拌後、30分静置した。これにより油相と水相とに分離し、水相を除去した。この操作を1回繰り返した後、得られた油相に、超純水37.5gを仕込み、5分間攪拌後、30分間静置し、水相を除去した。この操作を3回繰り返した後、80℃に加熱しながらフラスコ内を200hPa以下に減圧することで、残留水分及びPGMEAを濃縮留去した。その後、ELグレードのPGMEA(関東化学社製試薬)を希釈し、10質量%に濃度調整を行うことにより、金属含有量の低減されたBisF-1-CH4のPGMEA溶液を得た。
イオン交換樹脂(三菱化学ダイヤイオン:SMT100-ミックス樹脂)25gをシクロヘキサノンで膨潤後、テフロン(登録商標)カラムに充填し、1,3-ジオキソランを500mL通液することで溶媒置換した。次いで、実施例1で得られたBisP-1-CH4を1,3-ジオキソランに溶解させた溶液(10質量%)500gを通液することでBisF-1-CH4のジオキソラン溶液を得た。
また、明細書に記載された全ての文献、特許出願、及び技術規格は、個々の文献、特許出願、及び技術規格が参照により取り込まれることが具体的かつ個々に記された場合と同程度に、本明細書中に参照により取り込まれる。
そのため、本発明の化合物又は樹脂を含むリソグラフィー用下層膜形成材料及び該材料を含む下層膜形成用組成物はこれらの性能が要求される各種用途において、広く且つ有効に利用可能である。したがって、本発明は、例えば、電気用絶縁材料、レジスト用樹脂、半導体用封止樹脂、プリント配線板用接着剤、電気機器・電子機器・産業機器等に搭載される電気用積層板、電気機器・電子機器・産業機器等に搭載されるプリプレグのマトリックス樹脂、ビルドアップ積層板材料、繊維強化プラスチック用樹脂、液晶表示パネルの封止用樹脂、塗料、各種コーティング剤、接着剤、半導体用のコーティング剤、半導体用のレジスト用樹脂、下層膜形成用樹脂等において、広く且つ有効に利用可能である。特に、本発明は、リソグラフィー用下層膜及び多層レジスト用下層膜の分野において、特に有効に利用可能である。
Claims (20)
- R2の少なくとも1つ及び/又はR3の少なくとも1つが、炭素数1~30のアルコキシ基である請求項1に記載の化合物。
- 請求項1~5のいずれか1項に記載の化合物をモノマーとして得られる樹脂。
- 請求項1~5のいずれか1項に記載の化合物と架橋反応性のある化合物との反応によって得られる請求項6に記載の樹脂。
- 前記架橋反応性のある化合物が、アルデヒド、ケトン、カルボン酸、カルボン酸ハライド、ハロゲン含有化合物、アミノ化合物、イミノ化合物、イソシアネート及び不飽和炭化水素基含有化合物からなる群より選ばれる少なくとも1つである請求項7に記載の樹脂。
- 下記式(2)で表される構造を有する請求項6に記載の樹脂。
(式(2)中、R1は、炭素数1~30の2n価の基であり、R2~R5は、各々独立して、炭素数1~10のアルキル基、炭素数6~10のアリール基、炭素数2~10のアルケニル基、炭素数1~30のアルコキシ基、チオール基又は水酸基であり、但し、R4の少なくとも1つ及び/又はR5の少なくとも1つは炭素数1~30のアルコキシ基であり、Lは、炭素数1~20の直鎖状若しくは分岐状のアルキレン基又は単結合であり、m2及びm3は、各々独立して0~8の整数であり、m4及びm5は、各々独立して0~9の整数であり、但し、m4とm5とは同時に0となることはなく、nは、1~4の整数であり、p2~p5は各々独立して0~2の整数である。) - 請求項1~5のいずれか1項に記載の化合物及び/又は請求項6~9のいずれかに記載の樹脂を含有するリソグラフィー用下層膜形成材料。
- 請求項10に記載のリソグラフィー用下層膜形成材料と溶媒とを含有するリソグラフィー用下層膜形成用組成物。
- 架橋剤をさらに含有する請求項11に記載のリソグラフィー用下層膜形成用組成物。
- 酸発生剤をさらに含有する請求項11又は12に記載のリソグラフィー用下層膜形成用組成物。
- 請求項11~13のいずれか1項に記載のリソグラフィー用下層膜形成用組成物から形成されるリソグラフィー用下層膜。
- 基板上に、請求項11~13のいずれか1項に記載の下層膜形成用組成物を用いて下層膜を形成し、前記下層膜上に、少なくとも1層のフォトレジスト層を形成した後、前記フォトレジスト層の所要の領域に放射線を照射し、現像を行うレジストパターン形成方法。
- 基板上に、請求項11~13のいずれか1項に記載の下層膜形成用組成物を用いて下層膜を形成し、前記下層膜上に、珪素原子を含有するレジスト中間層膜材料を用いて中間層膜を形成し、前記中間層膜上に、少なくとも1層のフォトレジスト層を形成した後、前記フォトレジスト層の所要の領域に放射線を照射し、現像してレジストパターンを形成し、その後、前記レジストパターンをマスクとして前記中間層膜をエッチングし、得られた中間層膜パターンをエッチングマスクとして前記下層膜をエッチングし、得られた下層膜パターンをエッチングマスクとして基板をエッチングすることで基板にパターンを形成する回路パターン形成方法。
- 請求項1~5のいずれか1項に記載の化合物又は請求項6~9のいずれか1項に記載の樹脂と、水と任意に混和しない有機溶媒を含む溶液と、酸性の水溶液とを接触させ抽出する工程を含む、化合物又は樹脂の精製方法。
- 前記酸性の水溶液が、塩酸、硫酸、硝酸及びリン酸からなる群より選ばれる1種以上の鉱酸水溶液、又は酢酸、プロピオン酸、蓚酸、マロン酸、コハク酸、フマル酸、マレイン酸、酒石酸、クエン酸、メタンスルホン酸、フェノールスルホン酸、p-トルエンスルホン酸及びトリフルオロ酢酸からなる群より選ばれる1種以上の有機酸水溶液である請求項17に記載の精製方法。
- 前記水と任意に混和しない有機溶媒が、トルエン、2-ヘプタノン、シクロヘキサノン、シクロペンタノン、メチルイソブチルケトン、プロピレングリコールモノメチルエーテルアセテート又は酢酸エチルである請求項17又は18に記載の精製方法。
- 前記溶液と前記酸性の水溶液とを接触させ抽出処理を行ったのち、さらに水による抽出処理を行う工程を含む請求項17~19のいずれか1項に記載の精製方法。
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EP16749322.0A EP3257835A4 (en) | 2015-02-12 | 2016-02-12 | Compound, resin, lithography underlayer film forming material, lithography underlayer film forming composition, lithography underlayer film, method for forming resist pattern, method for forming circuit pattern, and method for purifying compound or resin |
KR1020177022588A KR20170116044A (ko) | 2015-02-12 | 2016-02-12 | 화합물, 수지, 리소그래피용 하층막 형성재료, 리소그래피용 하층막 형성용 조성물, 리소그래피용 하층막, 레지스트패턴 형성방법, 회로패턴 형성방법 및 화합물 또는 수지의 정제방법 |
US15/550,207 US20180029968A1 (en) | 2015-02-12 | 2016-02-12 | Compound, resin, material for forming underlayer film for lithography, composition for forming underlayer film for lithography, underlayer film for lithography, resist pattern forming method, circuit pattern forming method, and purification method of compound or resin |
SG11201706304YA SG11201706304YA (en) | 2015-02-12 | 2016-02-12 | Compound, resin, material for forming underlayer film for lithography, composition for forming underlayer film for lithography, underlayer film for lithography, resist pattern forming method, circuit pattern forming method, and purification method of compound or resin |
CN201680009964.XA CN107250089A (zh) | 2015-02-12 | 2016-02-12 | 化合物、树脂、光刻用下层膜形成材料、光刻用下层膜形成用组合物、光刻用下层膜、抗蚀图案形成方法、电路图案形成方法和化合物或树脂的纯化方法 |
IL253822A IL253822A0 (en) | 2015-02-12 | 2017-08-03 | Compound, resin, material for the production of an underlayer of film for lithography, preparation for the production of an underlayer of film for lithography, an underlayer for lithography, a protective material for the production method and a cleaning agent for the compound or resin |
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JP7336078B2 (ja) | 2018-06-26 | 2023-08-31 | 三菱瓦斯化学株式会社 | リソグラフィー用膜形成材料、リソグラフィー用膜形成用組成物、リソグラフィー用下層膜及びパターン形成方法 |
JPWO2020004316A1 (ja) * | 2018-06-26 | 2021-08-02 | 三菱瓦斯化学株式会社 | リソグラフィー用膜形成材料、リソグラフィー用膜形成用組成物、リソグラフィー用下層膜及びパターン形成方法 |
US20210294214A1 (en) * | 2018-07-31 | 2021-09-23 | Mitsubishi Gas Chemical Company, Inc. | Underlayer film forming composition |
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KR20170116044A (ko) | 2017-10-18 |
CN107250089A (zh) | 2017-10-13 |
EP3257835A1 (en) | 2017-12-20 |
US20180029968A1 (en) | 2018-02-01 |
JP6670453B2 (ja) | 2020-03-25 |
JPWO2016129679A1 (ja) | 2017-11-24 |
IL253822A0 (en) | 2017-09-28 |
EP3257835A4 (en) | 2018-10-03 |
TW201702740A (zh) | 2017-01-16 |
SG11201706304YA (en) | 2017-09-28 |
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