WO2016121750A1 - 難燃性エポキシ樹脂組成物、それを用いてなるプリプレグ及び積層板 - Google Patents
難燃性エポキシ樹脂組成物、それを用いてなるプリプレグ及び積層板 Download PDFInfo
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- WO2016121750A1 WO2016121750A1 PCT/JP2016/052160 JP2016052160W WO2016121750A1 WO 2016121750 A1 WO2016121750 A1 WO 2016121750A1 JP 2016052160 W JP2016052160 W JP 2016052160W WO 2016121750 A1 WO2016121750 A1 WO 2016121750A1
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- epoxy resin
- group
- resin composition
- atom
- alkyl group
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- BQPNUOYXSVUVMY-UHFFFAOYSA-N CC(C)(c(cc1)ccc1OP(Oc1ccccc1)(Oc1ccccc1)=O)c(cc1)ccc1OP(Oc1ccccc1)(Oc1ccccc1)=O Chemical compound CC(C)(c(cc1)ccc1OP(Oc1ccccc1)(Oc1ccccc1)=O)c(cc1)ccc1OP(Oc1ccccc1)(Oc1ccccc1)=O BQPNUOYXSVUVMY-UHFFFAOYSA-N 0.000 description 1
- 0 Cc(c(*)c1)c(*)cc1-c1cc(S)c(C)c(*)c1 Chemical compound Cc(c(*)c1)c(*)cc1-c1cc(S)c(C)c(*)c1 0.000 description 1
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- C08K5/49—Phosphorus-containing compounds
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- B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids R2P(=O)(OH); Thiophosphinic acids, i.e. R2P(=X)(XH) (X = S, Se)
- C07F9/32—Esters thereof
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Definitions
- the present invention relates to a flame retardant epoxy resin composition, and in particular, contains a phosphorus-based reactive flame retardant and has excellent environmental compatibility, and the flame retardant epoxy resin composition
- the present invention relates to an epoxy resin laminate using
- Epoxy resins have been used in a wide range of industrial applications, but the performance required for epoxy resins has become increasingly sophisticated in recent years with the development of the industry. For example, epoxy resins have been used for copper-clad laminates and casting materials used in electronic components and electronic devices, but these epoxy resins are safe for fire prevention and delay of fire spread. From the standpoint of safety, brominated epoxy resins that provide flame retardant effects have been used. However, from the viewpoint of environmental problems, in recent years, materials that exhibit a flame retardant effect in place of halogen have been actively developed.
- Patent Document 2 a method for producing an epoxy resin composition having flame retardancy using a phosphorus-containing compound that reacts with an epoxy resin is also known (for example, Patent Document 2).
- the phosphorus-containing compound reacts with the epoxy resin to solve the above bleed phenomenon problem.
- the epoxy resin is heated. When cured, the physical properties and heat resistance of the cured product were disadvantageous.
- the phosphorus-containing compound used has high crystallinity, there is also a disadvantage that workability when the composition is used is poor.
- the present inventors have found that a reactive phosphorus-containing compound that does not cause a bleed phenomenon of a flame retardant during curing, does not deteriorate the physical properties of the cured product, and is excellent in workability.
- the present inventors have found a flame retardant epoxy resin composition comprising the above, and have reached the present invention.
- a first object of the present invention is to provide a flame retardant epoxy resin composition excellent in workability and physical properties of a cured product, comprising a phosphorus-based reactive flame retardant excellent in environmental suitability. is there.
- the second object of the present invention is to provide a laminate having excellent environmental suitability and excellent physical properties and heat resistance of a cured product.
- the present invention contains an epoxy resin (A), a curing agent (B), and a phosphorus compound represented by the following general formula (1) (hereinafter simply referred to as “phosphorus-containing compound”) (C). It is a flame retardant epoxy resin composition.
- m in the above formula (1) represents an integer of 2 to 10
- R 1 and R 2 each independently represents an alkyl group or an aryl group
- R 3 represents an oxygen atom, a sulfur atom, or a nitrogen atom.
- X represents an oxygen atom or a sulfur atom
- Y represents an oxygen atom, a sulfur atom, or —NR 4 —, wherein R 4 represents a hydrogen atom, an alkyl group, or an aryl group .
- a flame-retardant epoxy resin composition having excellent environmental suitability and excellent workability, and excellent cured material properties and heat resistance can be obtained. Moreover, by using the epoxy resin composition, it is possible to obtain a laminated board excellent not only in heat resistance and flame retardancy but also in environmental suitability.
- curing agent (B), and phosphorus containing compound (C) which are used by this invention are demonstrated.
- the use of the epoxy resin composition of the present invention is not particularly limited.
- the epoxy resin (A) used in the present invention is not particularly limited in molecular structure, molecular weight, etc. as long as it has two or more epoxy groups in the molecule, and can be appropriately selected from known epoxy resins. Although it is possible, it is preferable to use them properly depending on the intended use.
- epoxy resin examples include bisphenol type epoxy resins such as bisphenol A type epoxy resin and bisphenol F type epoxy resin; biphenyl type epoxy resins such as biphenyl type epoxy resin and tetramethylbiphenyl type epoxy resin; and dicyclopentadiene type epoxy resin.
- Naphthalene type epoxy resin alicyclic epoxy resin obtained from cyclohexanedimethanol, hydrogenated bisphenol A, etc .
- phenol novolac type epoxy resin cresol novolac type epoxy resin, bisphenol A novolac type epoxy resin, phenols and phenolic hydroxyl group Epoxy compounds that are condensates with aromatic aldehydes, and novolac epoxy resins such as biphenyl novolac epoxy resins; triphenylmethane epoxy Fats; tetraphenyl ethane epoxy resin; dicyclopentadiene - phenol addition reaction type epoxy resin; and a phenol aralkyl type epoxy resins.
- epoxy resins may be used alone or in combination of two or more.
- a novolac type epoxy resin and / or a bisphenol type epoxy resin should be used. Is preferred.
- the epoxy resin composition used for the sealant is at least one selected from bisphenol-type epoxy resins, dicyclopentadiene-type epoxy resins, novolac-type epoxy resins, and naphthalene-type epoxy resins.
- the epoxy resin is preferably used, and bisphenol type epoxy resins and / or alicyclic epoxy resins are preferable for the epoxy resin composition used for the casting material.
- a reactive diluent can be used in combination in order to adjust to a desired viscosity.
- a diluent having at least one epoxy group is used from the viewpoint of suppressing a decrease in heat resistance and glass transition temperature of the cured product when the epoxy resin composition is cured. To do.
- the number of epoxy groups contained in the reactive diluent may be one or more, and is not particularly limited.
- the reactive diluent having one epoxy group include n-butyl glycidyl ether, C 12 to C 14 alkyl glycidyl ether, allyl glycidyl ether, 2-ethylhexyl glycidyl ether, styrene oxide, phenyl glycidyl ether, Examples include glycidyl ether, p-sec-butylphenyl glycidyl ether, t-butylphenyl glycidyl ether, glycidyl methacrylate, and tertiary carboxylic acid glycidyl ester.
- Examples of the reactive diluent having two epoxy groups include ethylene glycol diglycidyl ether, propylene glycol diglycidyl ether, butanediol diglycidyl ether, 1,6-hexanediol diglycidyl ether, and neopentyl glycol diester. A glycidyl ether etc. are mentioned. Examples of the reactive diluent having 3 epoxy groups include trimethylolpropane triglycidyl ether and glycerin triglycidyl ether.
- the blending amount of the reactive diluent with respect to the epoxy resin is not particularly limited, but it is preferable to properly use it depending on the intended use.
- the epoxy resin composition used for the laminate it is preferable not to use a reactive diluent from the viewpoint of avoiding a decrease in the glass transition temperature of the product.
- the epoxy resin composition used for the sealant it is preferably blended in an amount of 3 to 50 parts by mass, more preferably 5 to 30 parts by mass with respect to 100 parts by mass of the epoxy resin.
- an epoxy resin composition used for a casting material it is preferably blended in an amount of 3 to 50 parts by mass, more preferably 5 to 30 parts by mass with respect to 100 parts by mass of the epoxy resin.
- examples of the curing agent (B) used in the present invention include phenol resins, aliphatic amines, aromatic amines, latent curing agents, and acid anhydrides.
- these curing agents it is preferable to use these curing agents properly depending on applications.
- the use of the laminate it is preferable to use phenol resins or latent curing agents, and it is more preferable to use phenol novolac resins, cresol novolac resins, or dicyandiamide type latent curing agents.
- the sealant it is preferable to use latent curing agents or acid anhydrides, and for the use of the casting material, it is preferable to use aliphatic amines, aromatic amines, or acid anhydrides.
- These curing agents may be used alone or in combination of two or more.
- phenol resins examples include phenol novolac resin, cresol novolac resin, aromatic hydrocarbon formaldehyde resin-modified phenol resin, dicyclopentadiene phenol addition resin, phenol aralkyl resin (Zylok resin), naphthol aralkyl resin, trisphenylol methane resin.
- Tetraphenylolethane resin naphthol novolak resin, naphthol-phenol co-condensation novolak resin, naphthol-cresol co-condensation novolak resin, biphenyl-modified phenol resin (polyhydric phenol compound in which phenol nucleus is linked by bismethylene group), biphenyl-modified naphthol Resin (polyvalent naphthol compound in which phenol nucleus is linked by bismethylene group), aminotriazine modified phenolic resin (phenol skeleton, Compounds having an azine ring and a primary amino group in the molecular structure) and polyvalent compounds such as alkoxy group-containing aromatic ring-modified novolak resins (polyhydric phenol compounds in which a phenol nucleus and an alkoxy group-containing aromatic ring are linked with formaldehyde).
- a phenol compound is mentioned.
- curing agent (B) which consists of the said phenol resin is not specifically limited,
- the hydroxyl group in a phenol resin is 0 with respect to one epoxy group in an epoxy resin.
- the blending is preferably 3 to 1.5, and more preferably 0.8 to 1.2.
- Examples of the aliphatic amines include ethylenediamine, hexamethylenediamine, 1,4-diaminocyclohexane, 1,3-diaminocyclohexane, 4,4′-diaminodicyclohexylmethane, 1,3-bis (aminomethyl) cyclohexane, 1,4-bis (aminomethyl) cyclohexane, 4,4′-diaminodicyclohexylpropane, bis (4-aminocyclohexyl) sulfone, 4,4′-diaminodicyclohexyl ether, 2,2′-dimethyl-4,4 Examples include '-diaminodicyclohexane, 4,4'-diaminodicyclohexane, isophorone diamine, norbornene diamine, and meta-xylene diamine. These can be used singly or as an appropriately mixed mixture.
- the active hydrogen in an aliphatic amine with respect to one epoxy group in an epoxy resin Is preferably blended so as to be 0.6 to 1.5, more preferably 0.8 to 1.2.
- aromatic amines examples include diethyltoluenediamine, 1-methyl-3,5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6-diaminobenzene, 1,3,3 Examples include 5-triethyl-2,6-diaminobenzene, 3,3′-diethyl-4,4′-diaminodiphenylmethane, and 3,5,3 ′, 5′-tetramethyl-4,4′-diaminodiphenylmethane. These can be used alone or in a mixture of any proportions.
- the active hydrogen in an aliphatic amine with respect to one epoxy group in an epoxy resin Is preferably blended so as to be 0.6 to 1.5, more preferably 0.8 to 1.2.
- latent curing agent examples include latent curing agents such as dicyandiamide type, imidazole type, and polyamine type compounds that have a small viscosity change and property change when mixed with an epoxy resin at room temperature.
- latent curing agents such as dicyandiamide type, imidazole type, and polyamine type compounds that have a small viscosity change and property change when mixed with an epoxy resin at room temperature.
- Adeka Hardener EH-3636AS manufactured by ADEKA Corporation, dicyandiamide type latent curing agent
- Adeka Hardener EH-4351S manufactured by ADEKA Corporation, dicyandiamide type latent curing agent
- Adeka Hardener EH-5011S (manufactured by ADEKA Corporation, imidazole type latent curing agent), Adeka Hardener EH-5046S (manufactured by ADEKA Corporation, imidazole type latent curing agent), Adeka Hardener EH-4357S (manufactured by ADEKA Corporation) , Polyamine type latent curing agent), ADEKA HARDNER EH-5057P (manufactured by ADEKA, polyamine type latent curing agent), and ADEKA HARDNER EH-5057PK (manufactured by ADEKA, polyamine type latent curing) ) And the like, can be used as these mixtures alone or mixed appropriately.
- the blending amount of the curing agent (B) composed of the latent curing agent with respect to the epoxy resin (A) is not particularly limited, but is preferably 1 to 70 parts by mass with respect to 100 parts by mass of the epoxy resin. More preferably, it is 3 to 60 parts by mass.
- Examples of the acid anhydrides include hymic anhydride, phthalic anhydride, maleic anhydride, methyl hymic anhydride, succinic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, methyltetrahydrophthalic anhydride, methylhexahydroanhydride.
- Examples thereof include phthalic acid, trialkyltetrahydrophthalic anhydride-maleic anhydride adduct, benzophenone tetracarboxylic anhydride, trimellitic anhydride, pyromellitic anhydride, and hydrogenated methylnadic acid anhydride.
- the acid in acid anhydrides with respect to one epoxy group in an epoxy resin is preferably 0.7 to 1.6, and more preferably 0.9 to 1.2.
- a known epoxy resin curing accelerator can be used in combination with the curing agent (B) as necessary.
- these curing accelerators include phosphine compounds such as triphenylphosphine; phosphonium salts such as tetraphenylphosphonium bromide; 2-methylimidazole, 2-phenylimidazole, 2-ethyl-4-methylimidazole, 2 Imidazoles such as undecylimidazole and 1-cyanoethyl-2-methylimidazole; imidazole salts which are salts of the imidazoles with trimellitic acid, isocyanuric acid, boron and the like; benzyldimethylamine, 2,4,6- Examples include amines such as tris (dimethylaminomethyl) phenol; quaternary ammonium salts such as trimethylammonium chloride; and complex compounds of boron trifluoride with amines and ether compounds.
- These curing accelerators may be used alone
- m in the above formula (1) represents an integer of 2 to 10
- R 1 and R 2 each independently represents an alkyl group or an aryl group
- R 3 represents an oxygen atom, a sulfur atom, or nitrogen
- X represents an oxygen atom or a sulfur atom
- Y represents an oxygen atom, a sulfur atom, or —NR 4 —
- R 4 represents a hydrogen atom, an alkyl group, or an aryl group.
- the phosphorus-containing compound of component (C) used in the present invention is a compound that reacts with an epoxy group according to the reaction formula shown in the following general formula (3).
- m in the above formula (3) represents an integer of 2 to 10
- R 1 and R 2 each independently represents an alkyl group or an aryl group
- R 3 represents an oxygen atom, a sulfur atom, or a nitrogen atom.
- R 8 is an alkyl group or an aryl group
- X is an oxygen atom or a sulfur atom
- Y is an oxygen atom, a sulfur atom, or —NR 4 —
- R 4 is a hydrogen atom Represents an alkyl group or an aryl group.
- M in the above formula (1) is preferably 2 to 7, and more preferably 2 to 5.
- m 1, the number of functional groups that react with the epoxy group is one, and the glass transition temperature and strength of the cured product when the epoxy resin is cured are significantly reduced, which is not preferable.
- m is a number larger than 10, it is not preferable since the viscosity becomes high and the production becomes difficult when the phosphorus-containing compound is produced.
- Examples of the alkyl group represented by R 1 or R 2 in the above formula (1) include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a tertiary butyl group, an amyl group, and an isoamyl group.
- R 1 or R 2 examples include a phenyl group and a naphthyl group.
- R 1 and / or R 2 is preferably an alkyl group having 1 to 6 carbon atoms, more preferably an alkyl group having 2 to 5 carbon atoms, and an ethyl group Or it is most preferable that it is a propyl group.
- Examples of the hydrocarbon group represented by R 3 in the formula (1) include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a tertiary butyl group, an amyl group, an isoamyl group, Tertiary amyl group, hexyl group, isohexyl group, octyl group, 2-ethylhexyl group, tertiary octyl group, nonyl group, decyl group and other alkyl groups; phenyl group, naphthyl group and other aryl groups; methylene group, ethylene group, Alkanediyl groups such as propylene group, ethanediyl group and octanediyl group; Alkanetriyl groups such as methylenetriyl and 1,1,3-ethylenetriyl group; Alkanes such
- the phosphorus-containing compound of the component (C) used in the present invention is preferably a compound containing at least one aromatic ring in the skeleton, Particularly preferred are compounds containing groups represented by the following general formulas (2-1) to (2-6). However, R 5 in the above formula (2-1) represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.
- n represents an integer of 0 to 3
- o represents an integer of 0 to 50
- R 6 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms
- R 7 represents oxygen.
- Z represents a hydroxyl group or a functional group represented by the following general formula (2-3).
- R 1 and R 2 in the above formula (2-3) each independently represent an alkyl group or an aryl group.
- R 3 in the formula (1) is a group represented by the above (2-1) to (2-6)
- R 3 is the above (2-1) or (2-2
- R 1 and R 2 are each independently an ethyl group or a propyl group
- R 5 is a hydrogen atom or a methyl group.
- n is 0 or 1
- o is an integer of 1 to 5
- R 1 and R 2 are each independently an ethyl group or a propyl group
- R 6 is methyl.
- R 7 is preferably a methylene group, an ethanediyl group, or a propanediyl group. Examples of such compounds include compounds represented by the following formulas (4-1) to (4-4).
- p in the above formula (4-4) is an integer of 1 to 5.
- the compounding quantity of the said phosphorus-containing compound in the epoxy resin composition of this invention is not specifically limited,
- the phosphorus content resulting from the said phosphorus-containing compound in the total solid of an epoxy resin composition is 0.
- the amount is preferably 1 to 5% by mass, and more preferably 0.5 to 3% by mass. If the phosphorus content is less than 0.1% by mass, the flame retardancy of the epoxy resin composition may be significantly reduced. On the other hand, when there is more phosphorus content than the quantity used as 5 mass%, the water resistance of an epoxy resin composition may fall remarkably.
- the phosphorus-containing compound used in the present invention can be produced by a method represented by the following general formula (5).
- m is an integer of 2 to 10
- R 1 and R 2 each independently represents an alkyl group or an aryl group
- R 3 may contain an oxygen atom, a sulfur atom, or a nitrogen atom.
- Hydrocarbon group X represents an oxygen atom or a sulfur atom
- Y represents an oxygen atom, a sulfur atom, or —NR 4 —
- R 4 represents a hydrogen atom, an alkyl group, or an aryl group.
- Examples of the base used in the general formula (5) include tertiary amines such as triethylamine, tributylamine, diazabicycloundecene, diazabicyclononene, and 1,4-diazabicyclo [2.2.2] octane.
- Pyridines such as pyridine and N, N-dimethylaminopyridine; imidazoles such as 1-methylimidazole; phosphines such as triphenylphosphine, tributylphosphine and tricyclohexylphosphine;
- a tertiary amine is preferably used, and triethylamine is most preferably used.
- Examples of the solvent used in the general formula (5) include ketones such as methyl ethyl ketone, methyl amyl ketone, diethyl ketone, acetone, methyl isopropyl ketone, propylene glycol monomethyl ether acetate, and cyclohexanone; tetrahydrofuran, 1,2-dimethoxy Ethers such as ethane, 1,2-diethoxyethane, propylene glycol monomethyl ether; esters such as ethyl acetate and n-butyl acetate; aromatic hydrocarbons such as benzene, toluene and xylene; carbon tetrachloride, chloroform, trichloroethylene And halogenated aliphatic hydrocarbons such as methylene chloride; halogenated aromatic hydrocarbons such as chlorobenzene.
- ketones such as methyl ethyl ketone, methyl amyl ketone, diethy
- ethers or halogenated aliphatic hydrocarbons are preferable, and ethers are particularly preferable.
- the above reaction can be carried out at ⁇ 80 to 100 ° C., preferably at room temperature to 50 ° C., for 0.5 hour to 72 hours, preferably 1 hour to 24 hours.
- an organic solvent can be used as a viscosity modifier.
- the organic solvent include amides such as N, N-dimethylformamide, ethers such as ethylene glycol monomethyl ether, ketones such as acetone and methyl ethyl ketone, alcohols such as methanol and ethanol, and aromatics such as benzene and toluene. Group hydrocarbons and the like.
- at least one of these solvents can be mixed and blended so as to be in the range of 30 to 80% by mass with respect to the total mass of the epoxy resin composition.
- An inorganic filler may be added to the epoxy resin composition of the present invention as necessary.
- examples of such inorganic filler include silica such as fused silica and crystalline silica, magnesium hydroxide, aluminum hydroxide, zinc borate, zinc molybdate, calcium carbonate, silicon nitride, silicon carbide, boron nitride, calcium silicate, Examples thereof include powders such as potassium titanate, aluminum nitride, beryllia, zirconia, zircon, fosterite, steatite, spinel, mullite, titania, beads formed by spheroidizing these, and glass fibers. These inorganic fillers may be used alone or in combination of two or more.
- the above-mentioned inorganic filler it is preferable to use the above-mentioned inorganic filler properly depending on the intended use.
- the use of the laminate it is preferable to use fused silica, aluminum hydroxide or the like, and for the use of the sealant, it is preferable to use fused silica, crystalline silica or the like, and particularly to use fused silica.
- the use of the casting material it is preferable to use fused silica, crystalline silica, aluminum hydroxide or the like, and it is particularly preferable to use fused silica.
- the blending amount of the inorganic filler is preferably 20 to 90% by mass and more preferably 25 to 80% by mass with respect to the total solid content of the epoxy resin composition. If the blending amount of the inorganic filler is less than 20% by mass, the effect of reducing the thermal expansion coefficient of the cured product tends to be low, and if it exceeds 90% by mass, the viscosity of the epoxy resin composition increases and the workability is remarkably lowered. Tend to.
- an additive other than the inorganic filler may be used in combination with the epoxy resin composition of the present invention, if necessary.
- the additive include non-reactive diluents (plasticizers) such as dioctyl phthalate, dibutyl phthalate, benzyl alcohol, and coal tar; fibrous fillers such as glass fiber, pulp fiber, synthetic fiber, and ceramic fiber; Reinforcing materials such as glass cloth, aramid cloth, carbon fiber; pigment; ⁇ -aminopropyltriethoxysilane, N- ⁇ - (aminoethyl) - ⁇ -aminopropyltriethoxysilane, N- ⁇ - (aminoethyl) -N '- ⁇ - (Aminoethyl) - ⁇ -aminopropyltriethoxysilane, ⁇ -anilinopropyltriethoxysilane, ⁇ -glycidoxypropyltriethoxysilane,
- the epoxy resin composition of the present invention includes a laminate used for an electronic circuit board, a sealant used for an electronic component, a casting material, a film material, an adhesive, an electrical insulating paint, a composite material that requires flame retardancy, and It can be used for powder coatings and the like, and among them, it is preferable to use it for laminates used for electronic circuit boards, sealants used for electronic components, and casting materials.
- a prepreg using the epoxy resin composition of the present invention is laminated in a predetermined number, for example, 1 to 20 sheets, and a metal foil such as copper or aluminum is disposed on one side or both sides and laminated. Thereafter, it can be manufactured by thermocompression bonding at a predetermined temperature, for example, 100 to 250 ° C., using a multistage press, a multistage vacuum press or the like.
- the prepreg using the epoxy resin composition of the present invention can be produced by impregnating or applying the epoxy resin composition of the present invention to a substrate and semi-curing (B-stage) by heating or the like.
- the base material of the prepreg known materials such as inorganic fibers such as glass fibers and carbon fibers, organic fibers such as polyimide, polyester and tetrafluoroethylene, and mixtures thereof can be used.
- Examples of the shape of these base materials include sheet-like base materials such as woven fabrics, non-woven fabrics, robinks, chopped strand mats, and surfacing mats.
- the material and shape of these base materials are selected according to the intended use and performance of the molded product. If necessary, it can be used alone or in combination of two or more kinds of materials and shapes.
- the sealing agent of the present invention used for electronic parts can be produced by stirring, melting, mixing, and dispersing the epoxy resin composition of the present invention as necessary with heat treatment.
- the apparatus used for stirring, melting, mixing, and dispersion is not particularly limited.
- a lykai machine equipped with a stirring and heating apparatus, a three-roll mill, a ball mill, a planetary mixer, a bead mill. Etc. can be used. Moreover, you may use combining these apparatuses suitably.
- the casting material using the epoxy resin composition of the present invention can be manufactured using, for example, a mold after mixing the epoxy resin composition of the present invention using a mixer or the like and vacuum degassing.
- UL Underwriters Laboratories
- Test for Flammability of Plastic Materials UL 94 is used for test pieces that have been processed to have a length of 127 mm and a width of 12.7 mm by removing the copper foil of the double-sided copper-clad laminate by etching.
- the test was conducted in accordance with the above and judged as follows. ⁇ Judgment method> The test piece was kept vertical, a burner was fired at the lower end indirectly for 10 seconds, the flame was removed, and the time until the fire that ignited the test piece disappeared was measured.
- the second flame contact was performed for 10 seconds, and the time until the ignited fire was extinguished was measured in the same manner as the first time.
- the combustion rank was evaluated according to the UL-94V standard from the first and second combustion times, the presence or absence of cotton ignition, and the like. The combustion rank is V-0, and the flame retardance decreases as V-1 and V-2 are reached. However, those not corresponding to any of the ranks V-0 to V-2 were determined as NR.
- the glass transition temperature of the cured product was measured using TMA (thermal mechanical analyzer, manufactured by Hitachi High-Tech Science Co., Ltd., EXSTAR TMA / SS-6100).
- the peel strength of the copper foil was measured according to JIS C 6481 5.7.
- reaction solution was transferred to a separatory funnel, and 500 mL of chloroform and 300 mL of a saturated aqueous sodium hydrogen carbonate solution were added and stirred well. After oil-water separation, the aqueous layer was removed. The organic layer was washed twice with 200 mL of distilled water and dried over anhydrous magnesium sulfate, and then the solvent was removed with an evaporator to obtain 60.6 g of phosphorus-containing compound (I-1) (yield 96.1%).
- ⁇ Production Example 2 Synthesis of phosphorus-containing compound (I-2)> A 500 mL five-necked flask equipped with a stirring blade, a reflux tube, a thermometer, a dropping funnel and a septum was thoroughly dried and purged with nitrogen, and HF-1M (phenol novolac resin, manufactured by Meiwa Kasei Co., Ltd.) 34.2 g (0 .16 mol), 34.4 g (0.34 mol) of triethylamine, and 300 mL of ultra-dehydrated tetrahydrofuran were charged.
- HF-1M phenol novolac resin, manufactured by Meiwa Kasei Co., Ltd.
- reaction solution was transferred to a separatory funnel, and 500 mL of chloroform and 300 mL of a saturated aqueous sodium hydrogen carbonate solution were added and stirred well. After oil-water separation, the aqueous layer was removed. The organic layer was washed twice with 200 mL of distilled water and dried over anhydrous magnesium sulfate, and then the solvent was removed with an evaporator to obtain 78.1 g of phosphorus-containing compound (I-3) (yield 89.4%).
- reaction solution was transferred to a separatory funnel, and 500 mL of chloroform and 300 mL of saturated aqueous sodium hydrogen carbonate solution were added and stirred well. After oil-water separation, the aqueous layer was removed. The organic layer was washed twice with 200 mL of distilled water and dried over anhydrous magnesium sulfate, and then the solvent was removed with an evaporator to obtain 60.9 g of phosphorus-containing compound (I-4) (yield 93.2%).
- Example 1 EOCN-104S (cresol novolac type epoxy resin, Nippon Kayaku Co., Ltd.) 49.1 g, HP-350 (aluminum hydroxide, Showa Denko Co., Ltd.) 60.1 g and SFP-130MC (spherical silica, Denki Kagaku Kogyo Co., Ltd.) 60.1 g (manufactured by company) was added to 100 g of methyl ethyl ketone and dispersed with three rolls. Next, 15.3 g of the phosphorus-containing compound (I-1) obtained in Production Example 1 was dissolved in 3 g of methanol and added.
- the obtained resin varnish was impregnated into glass cloth (manufactured by Nitto Boseki Co., Ltd., # 7628) and dried by heating in a hot air circulating furnace at 120 ° C. for 10 minutes to prepare a prepreg.
- the amount of resin in the prepreg at this time was 40 to 50% by mass of the entire prepreg.
- 4 sheets of the prepared prepregs were stacked, and 35 ⁇ m thick copper foil (made by Fukuda Metal Foil Powder Co., Ltd.) was placed on both sides of the prepreg, and thermocompression bonding was performed at a temperature of 190 ° C. and a pressure condition of 10 kg / cm 2 for 120 minutes.
- Table 1 shows the physical properties of the double-sided copper-clad laminate obtained as described above.
- reaction solution was transferred to a separatory funnel, and 500 mL of chloroform and 300 mL of a saturated aqueous sodium hydrogen carbonate solution were added and stirred well. After oil-water separation, the aqueous layer was removed. The organic layer was washed twice with 200 mL of distilled water, the organic layer was dried over anhydrous magnesium sulfate, and then the solvent was removed with an evaporator to obtain 50.7 g of phosphorus-containing compound (I-5) (yield 85.3%). It was.
- Examples 2 to 4 and Comparative Examples 1 to 4> A double-sided copper-clad laminate was prepared in the same manner as in Example 1 except that the compositions described in Table 1 were blended, and various evaluations were performed. The results are as shown in Table 1.
- * 1 HCA-HQ Compound represented by the following structural formula (6), manufactured by Sanko Co., Ltd.
- * 2 FP-600 Compound represented by the following structural formula (7), manufactured by ADEKA Corporation
- Comparative Example 1 since the phosphorus-containing compound used was crystallized at the time of preparing the prepreg, a uniform prepreg could not be obtained and the subsequent evaluation could not be performed.
- Comparative Example 2 a component considered to be FP-600 partially separated at the time of pressure curing at the time of producing a double-sided copper-clad laminate, and a uniform laminate could not be obtained. From the result of Table 1, it was confirmed that the laminated board using the flame-retardant epoxy resin composition of the present invention exhibits good flame retardancy.
- the flame-retardant epoxy resin composition of the present invention does not use halogen, it is not only excellent in environmental suitability, but also uses a phosphorus-based flame retardant having two or more reactive points with the epoxy group of the epoxy resin. In addition to excellent workability, the flame retardant bleed phenomenon does not occur during curing, and the physical properties of the cured product do not deteriorate.
- the laminates produced using the flame retardant epoxy resin composition of the present invention are not only excellent in flame retardancy, but also excellent in manufacturing, environmental suitability and physical properties. It is extremely useful in industry.
Abstract
Description
本発明の第二の目的は、環境適正に優れると共に硬化物の物性や耐熱性にも優れた、積層板を提供することにある。
本発明のエポキシ樹脂組成物の使用用途は特に限定されるものではなく、例えば、電子回路基板に用いられる積層板、電子部品に用いられる封止剤、注型材、フィルム材、接着剤、電気絶縁塗料、難燃性の必要な複合材、及び粉体塗料等に使用することができる。本発明においては、特に電子回路基板に用いられる積層板、電子部品に用いられる封止剤、及び注型材等に使用することが好ましく、積層板に使用することが最も好ましい。
具体的には、積層板の用途に関しては、フェノール樹脂類又は潜在性硬化剤を使用することが好ましく、フェノールノボラック樹脂、クレゾールノボラック樹脂、又はジシアンジアミド型潜在性硬化剤を使用することがより好ましい。封止剤に関しては、潜在性硬化剤又は酸無水物類を使用することが好ましく、注型材の用途に関しては、脂肪族アミン、芳香族アミン、又は酸無水物類を使用することが好ましい。これらの硬化剤は単独で使用してもよく、2種以上を併用しても良い
但し、上記式(1)中のmは2~10の整数を表し、R1及びR2はそれぞれ独立に、アルキル基、又はアリール基を表し、R3は、酸素原子、硫黄原子、又は窒素原子を含んでも良い炭化水素基、Xは酸素原子又は硫黄原子、Yは、酸素原子、硫黄原子、又は―NR4―を表し、ここでR4は、水素原子、アルキル基、又はアリール基を表す。
但し、上記式(3)中のmは2~10の整数を表し、R1及びR2はそれぞれ独立に、アルキル基又はアリール基を表し、R3は、酸素原子、硫黄原子、又は窒素原子を含んでも良い炭化水素基、R8はアルキル基又はアリール基、Xは酸素原子又は硫黄原子、Yは、酸素原子、硫黄原子、又は―NR4―を表し、ここでR4は、水素原子、アルキル基、又はアリール基を表す。
本発明においては、これらの中でも、R1及び/又はR2が、炭素数1~6のアルキル基であることが好ましく、炭素数が2~5のアルキル基であることがより好ましく、エチル基又はプロピル基であることが最も好ましい。
但し、上記式(2-1)中のR5は、水素原子又は炭素数が1~4のアルキル基を表す。
但し、上記式(2-3)中のR1及びR2は、それぞれ独立に、アルキル基又はアリール基を表す。
一方、前記(2-2)の構造の場合には、nが0又は1、oが1~5の整数であり、R1、R2がそれぞれ独立にエチル基又はプロピル基、R6がメチル基であり、R7がメチレン基、エタンジイル基、又はプロパンジイル基であることが好ましい。
このような化合物としては、例えば、下記式(4-1)~(4-4)で表される化合物が挙げられる。
本発明においては、上記の反応を、-80~100℃、好ましくは室温~50℃で、0.5時間~72時間、好ましくは1時間~24時間かけて行わせることができる。
上記プリプレグの基材としては、例えば、ガラス繊維や炭素繊維等の無機繊維、ポリイミド、ポリエステル及びテトラフルオロエチレン等の有機繊維、並びにそれらの混合物等の、公知のものを使用することができる。
尚、以下の実施例等における%は、特に記載がない限り質量基準である。また、プリプレグの外観は、目視観察した場合に、均一な外観のものを良好と評価し、外観が不均一な物を不良とした。同様に、プリプレグを用いて加圧硬化させ、両面銅張積層板を作製した後の外観の評価を目視で観察し、均一に硬化しているものを良好とし、不均一に硬化しているものを不良とした。難燃性は、両面銅張積層板の銅箔をエッチングによって除去し、長さ127mm、幅12.7mmに加工した試験片について、UL(Underwriters Laboratories)の“Test for Flammability of Plastic Materials UL 94”に準じて試験をし、下記の様にして判定した。
<判定方法>
試験片を垂直に保ち、下端にバーナーの火を10秒間接炎させた後、炎を取り除き、試験片に着火した火が消える迄の時間を測定した。次に、火が消えると同時に2回目の接炎を10秒間行ない、1回目と同様にして、着火した火が消える迄の時間を測定した。また、落下する火種により、試験片の下に置いた綿が着火するか否かについても同時に評価した。
1回目と2回目の燃焼時間、綿着火の有無等からUL-94V規格にしたがって燃焼ランクを評価した。燃焼ランクはV-0が最高であり、V-1、V-2となるにしたがって難燃性は低下する。但し、V-0~V-2のランクの何れにも該当しないものはNRとした。
撹拌羽、還流管、温度計、滴下漏斗及びセプタムを備えた500mLの五口フラスコを、十分に乾燥・窒素置換し、4,4’-ビフェノール29.8g(0.16mol)、トリエチルアミン34.4g(0.34mol)、及び超脱水テトラヒドロフラン300mLを仕込んだ。滴下漏斗にジエチルホスフィン酸クロリド47.8g(0.34mol)を仕込み、反応温度が50℃を超えないように滴下した。滴下終了後、一晩攪拌した。反応溶液を分液漏斗に移し、クロロホルム500mL及び飽和炭酸水素ナトリウム水溶液300mLを加えて良く撹拌し、油水分離した後、水層を除去した。有機層を蒸留水200mLで二回水洗し、無水硫酸マグネシウムで乾燥した後、エバポレーターで溶媒を除去し、含リン化合物(I‐1)60.6g(収率96.1%)を得た。
撹拌羽、還流管、温度計、滴下漏斗及びセプタムを備えた500mLの五口フラスコを、十分に乾燥・窒素置換し、HF‐1M(フェノールノボラック樹脂、明和化成株式会社製)34.2g(0.16mol)、トリエチルアミン34.4g(0.34mol)、及び超脱水テトラヒドロフラン300mLを仕込んだ。滴下漏斗にジエチルホスフィン酸クロリド47.8g(0.34mol)を仕込み、反応温度が50℃を超えないように滴下した。滴下終了後、一晩攪拌した。反応溶液を分液漏斗に移し、クロロホルム500mL及び飽和炭酸水素ナトリウム水溶液300mLを加えて良く撹拌し、油水分離した後、水層を除去した。有機層を蒸留水200mLで二回水洗し、無水硫酸マグネシウムで乾燥した後、エバポレーターで溶媒を除去し、含リン化合物(I‐2)66.4g(収率98.3%)を得た。
撹拌羽、還流管、温度計、滴下漏斗及びセプタムを備えた500mLの五口フラスコを、十分に乾燥・窒素置換し、ビスフェノールA45.7g(0.20mol)、トリエチルアミン42.5g(0.42mol)、及び超脱水テトラヒドロフラン300mLを仕込んだ。滴下漏斗にジエチルホスフィン酸クロリド59.0g(0.42mol)を仕込み、反応温度が50℃を超えないように滴下した。滴下終了後、一晩攪拌した。反応溶液を分液漏斗に移し、クロロホルム500mL及び飽和炭酸水素ナトリウム水溶液300mLを加えて良く撹拌し、油水分離した後、水層を除去した。有機層を蒸留水200mLで二回水洗し、無水硫酸マグネシウムで乾燥した後、エバポレーターで溶媒を除去し、含リン化合物(I‐3)78.1g(収率89.4%)を得た。
撹拌羽、還流管、温度計、滴下漏斗及びセプタムを備えた500mLの五口フラスコを、十分に乾燥・窒素置換し、ビスフェノールF32.0g(0.16mol)、トリエチルアミン34.4g(0.34mol)、及び超脱水テトラヒドロフラン300mLを仕込んだ。滴下漏斗にジエチルホスフィン酸クロリド47.8g(0.34mol)を仕込み、反応温度が50℃を超えないように滴下した。滴下終了後、一晩攪拌した。反応溶液を分液漏斗に移し、クロロホルム500mL及び飽和炭酸水素ナトリウム水溶液300mLを加えて良く撹拌し、油水分離した後水層を除去した。有機層を蒸留水200mLで二回水洗し、無水硫酸マグネシウムで乾燥した後、エバポレーターで溶媒を除去し、含リン化合物(I‐4)60.9g(収率93.2%)を得た。
EOCN-104S(クレゾールノボラック型エポキシ樹脂、日本化薬株式会社製)49.1g、HP-350(水酸化アルミニウム、昭和電工株式会社製)60.1g及びSFP-130MC(球状シリカ、電気化学工業株式会社製)60.1gをメチルエチルケトン100gに加え、三本ロールで分散させた。次いで、製造例1で得られた含リン化合物(I-1)15.3gを、メタノール3gに溶解して加えた。更に、EOCN-104S 50.9g、アデカハードナー EH-3636AS(ジシアンジアミド型潜在性硬化剤、株式会社ADEKA製)5g(5phr)、及びメチルエチルケトン100gを追加してディスパーで分散し、樹脂ワニスを作製した。
回転子、還流管、セプタムを備えた100mL三口フラスコを十分に乾燥、窒素置換し、フェノール28.2g(0.30mol)、トリエチルアミン32.4g(0.32mol)、超脱水テトラヒドロフラン300mLを仕込んだ。滴下漏斗にジエチルホスフィン酸クロリド45.0g(0.32mol)を仕込み、反応温度が50℃を超えないように滴下した。滴下終了後、一晩攪拌した。反応溶液を分液漏斗に移し、クロロホルム500mL及び飽和炭酸水素ナトリウム水溶液300mL を加えて良く撹拌し、油水分離後、水層を除去した。有機層を蒸留水200mL で二回水洗し、有機層を無水硫酸マグネシウムで乾燥した後エバポレーターで溶媒を除去し、含リン化合物(I-5)50.7g(収率85.3%)を得た。
表1に記載した組成で配合したこと以外は、実施例1と同様にして両面銅張積層板を作製して各種評価を行った。結果は表1に示した通りである。
*2 FP-600:下記構造式(7)で表される化合物、株式会社ADEKA製
表1の結果から、本発明の難燃性エポキシ樹脂組成物を使用した積層板は、良好な難燃性を示すことが確認された。
Claims (6)
- 前記式(1)中のR3が、芳香環を少なくとも1個有する炭化水素基である、請求項1に記載されたエポキシ樹脂組成物。
- 前記式(1)中のX及びYが共に酸素原子であり、R1及びR2が、それぞれ独立に炭素数1~4のアルキル基であり、R3が下記一般式(2-1)~(2-6)から選択される何れかの構造を有する基である、請求項1又は2に記載されたエポキシ樹脂組成物;
但し、上記式(2-1)中のR5は、水素原子又は炭素数が1~4のアルキル基を表す;
但し、上記式(2-2)中のnは0~3の整数、oは0~50の整数を表し、R6は、水素原子又は炭素数が1~4のアルキル基、R7は、酸素原子又は硫黄原子を含んでもよい炭化水素基を表し、Zは水酸基又は下記一般式(2-3)で表される官能基である;
但し、上記式(2-3)中のR1及びR2は、それぞれ独立に、アルキル基又は下記のアリール基を表す;
- 無機繊維及び有機繊維から選択され得た少なくとも1種の繊維からなるシート状基材と、請求項1に記載されたエポキシ樹脂組成物とからなることを特徴とするプリプレグ。
- 請求項4に記載されたプリプレグ又は2以上の該プリプレグを積層してなる積層体の少なくとも一方の表面に金属箔を配置して積層し、熱圧着することを特徴とするエポキシ樹脂積層板の製造方法。
- 請求項5に記載された方法によって製造されてなるエポキシ樹脂積層板。
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106366567A (zh) * | 2016-08-27 | 2017-02-01 | 安徽天瞳智能科技有限公司 | 一种力学性能好印刷线路板用环氧树脂组合物 |
JP2018044069A (ja) * | 2016-09-14 | 2018-03-22 | 株式会社Adeka | 難燃性エポキシ樹脂組成物、並びにそれを用いてなるプリプレグ及び積層板 |
JP2019038988A (ja) * | 2017-08-23 | 2019-03-14 | 株式会社Adeka | 難燃性エポキシ樹脂組成物 |
WO2020009001A1 (ja) | 2018-07-04 | 2020-01-09 | 株式会社Adeka | 樹脂組成物、その硬化物、繊維強化プラスチック及び繊維強化プラスチックの難燃化方法 |
WO2020196819A1 (ja) * | 2019-03-27 | 2020-10-01 | 株式会社Adeka | 硬化性樹脂組成物 |
WO2021106963A1 (ja) * | 2019-11-26 | 2021-06-03 | 株式会社Adeka | 樹脂組成物、及び硬化物の発泡抑制方法 |
EP4141059A1 (en) | 2021-08-31 | 2023-03-01 | Clariant International Ltd | Diorganylphosphinic salts having exceptional surface structure |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI679242B (zh) * | 2015-03-23 | 2019-12-11 | 日商Adeka股份有限公司 | 環氧樹脂組成物 |
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EP4301586A1 (en) * | 2021-03-03 | 2024-01-10 | Mallinda | Vitrimers containing additives |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3371046A (en) * | 1963-12-30 | 1968-02-27 | Douglas Aircraft Co Inc | Inhibition of corrosion of hydraulic fluids |
GB1121462A (en) * | 1964-07-29 | 1968-07-31 | Monsanto Co | Synthesis of phosphinic and thiophosphinic esters |
US3527850A (en) * | 1965-03-31 | 1970-09-08 | Monsanto Co | Phenyl dialkyl phosphinates |
SU584008A1 (ru) * | 1976-07-07 | 1977-12-15 | Казанский Химико-Технологический Институт Имени С.М.Кирова | Способ получени фениловых эфиров фосфиновых кислот |
DD251134A1 (de) * | 1986-07-09 | 1987-11-04 | Univ Halle Wittenberg | Verfahren zur herstellung von organosilylmethylphosphinsaeureestern |
WO2009119789A1 (ja) * | 2008-03-28 | 2009-10-01 | 日本化薬株式会社 | 有機リン系化合物の水性分散液とそれを用いる防炎加工方法 |
JP2012512196A (ja) * | 2008-12-18 | 2012-05-31 | クラリアント・ファイナンス・(ビーブイアイ)・リミテッド | 混合置換ジアルキルホスフィン酸、混合置換ジアルキルホスフィン酸エステル、および混合置換ジアルキルホスフィン酸塩の調製方法、およびそれらの使用 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE251134C (ja) | ||||
DE3700208A1 (de) * | 1987-01-07 | 1988-07-21 | Bayer Ag | Phosphorhaltige oligomere und polymere mit polyphenylenetherbloecken sowie mischungen anderer kunststoffe mit ihnen |
JPH09235449A (ja) | 1995-12-28 | 1997-09-09 | Toray Ind Inc | エポキシ樹脂組成物 |
JPH10265487A (ja) * | 1997-03-21 | 1998-10-06 | Kanagawa Univ | ホスホン酸エステル類並びにポリホスホネートの 製造方法と硬化性組成物 |
JP3613724B2 (ja) | 1997-09-09 | 2005-01-26 | 東都化成株式会社 | リン含有エポキシ樹脂組成物 |
JP3482149B2 (ja) | 1999-02-16 | 2003-12-22 | 住友ベークライト株式会社 | 難燃性樹脂組成物、これを用いたプリプレグ及び積層板 |
JP2006160789A (ja) * | 2004-12-02 | 2006-06-22 | Toyobo Co Ltd | リン含有ハイパーブランチポリマーおよび難燃性樹脂組成物 |
JP4672505B2 (ja) * | 2005-04-13 | 2011-04-20 | 信越化学工業株式会社 | 難燃性接着剤組成物、ならびにそれを用いた接着シート、カバーレイフィルムおよびフレキシブル銅張積層板 |
US20090326111A1 (en) * | 2008-06-30 | 2009-12-31 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
WO2010109957A1 (ja) * | 2009-03-25 | 2010-09-30 | 東レ株式会社 | エポキシ樹脂組成物、プリプレグ、炭素繊維強化複合材料および電子電気部品筐体 |
EP2456817B1 (en) * | 2009-07-24 | 2013-05-29 | Basf Se | Derivatives of diphosphines as flame retardants in aromatic and/or heteroaromatic epoxy resins |
WO2011083009A1 (de) * | 2009-12-16 | 2011-07-14 | Basf Se | Flammschutzmittel |
JP2011219531A (ja) * | 2010-04-05 | 2011-11-04 | Asahi Kasei Chemicals Corp | 柔軟性難燃樹脂組成物 |
CN104119639B (zh) * | 2013-04-24 | 2016-08-03 | 台光电子材料(昆山)有限公司 | 无卤素树脂组合物及应用其的铜箔基板及印刷电路板 |
BR112016000802B1 (pt) * | 2013-08-22 | 2021-05-18 | Adeka Corporation | composto contendo fósforo, e, composição de resina epóxi curável |
-
2016
- 2016-01-26 EP EP16743353.1A patent/EP3252102B1/en active Active
- 2016-01-26 BR BR112017016180-0A patent/BR112017016180B1/pt active IP Right Grant
- 2016-01-26 WO PCT/JP2016/052160 patent/WO2016121750A1/ja active Application Filing
- 2016-01-26 KR KR1020177021231A patent/KR102346197B1/ko active IP Right Grant
- 2016-01-26 CN CN201680015284.9A patent/CN107343380B/zh active Active
- 2016-01-26 US US15/547,090 patent/US10421261B2/en active Active
- 2016-01-26 JP JP2016572053A patent/JP6666857B2/ja active Active
- 2016-01-29 TW TW105102838A patent/TWI683851B/zh active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3371046A (en) * | 1963-12-30 | 1968-02-27 | Douglas Aircraft Co Inc | Inhibition of corrosion of hydraulic fluids |
GB1121462A (en) * | 1964-07-29 | 1968-07-31 | Monsanto Co | Synthesis of phosphinic and thiophosphinic esters |
US3527850A (en) * | 1965-03-31 | 1970-09-08 | Monsanto Co | Phenyl dialkyl phosphinates |
SU584008A1 (ru) * | 1976-07-07 | 1977-12-15 | Казанский Химико-Технологический Институт Имени С.М.Кирова | Способ получени фениловых эфиров фосфиновых кислот |
DD251134A1 (de) * | 1986-07-09 | 1987-11-04 | Univ Halle Wittenberg | Verfahren zur herstellung von organosilylmethylphosphinsaeureestern |
WO2009119789A1 (ja) * | 2008-03-28 | 2009-10-01 | 日本化薬株式会社 | 有機リン系化合物の水性分散液とそれを用いる防炎加工方法 |
JP2012512196A (ja) * | 2008-12-18 | 2012-05-31 | クラリアント・ファイナンス・(ビーブイアイ)・リミテッド | 混合置換ジアルキルホスフィン酸、混合置換ジアルキルホスフィン酸エステル、および混合置換ジアルキルホスフィン酸塩の調製方法、およびそれらの使用 |
Non-Patent Citations (1)
Title |
---|
JON J.LONGLET ET AL.: "Synthesis, Structure, and Reactivity of Some N-Phosphorylphosphoranimines", INORGANIC CHEMISTRY, vol. 41, no. 24, 2002, pages 6507 - 6513, XP055319322 * |
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JP2018044069A (ja) * | 2016-09-14 | 2018-03-22 | 株式会社Adeka | 難燃性エポキシ樹脂組成物、並びにそれを用いてなるプリプレグ及び積層板 |
JP7066268B2 (ja) | 2017-08-23 | 2022-05-13 | 株式会社Adeka | 難燃性エポキシ樹脂組成物 |
JP2019038988A (ja) * | 2017-08-23 | 2019-03-14 | 株式会社Adeka | 難燃性エポキシ樹脂組成物 |
WO2020009001A1 (ja) | 2018-07-04 | 2020-01-09 | 株式会社Adeka | 樹脂組成物、その硬化物、繊維強化プラスチック及び繊維強化プラスチックの難燃化方法 |
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WO2020196819A1 (ja) * | 2019-03-27 | 2020-10-01 | 株式会社Adeka | 硬化性樹脂組成物 |
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EP4141059A1 (en) | 2021-08-31 | 2023-03-01 | Clariant International Ltd | Diorganylphosphinic salts having exceptional surface structure |
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BR112017016180B1 (pt) | 2022-02-01 |
CN107343380A (zh) | 2017-11-10 |
BR112017016180A2 (ja) | 2018-04-17 |
JP6666857B2 (ja) | 2020-03-18 |
TW201631024A (zh) | 2016-09-01 |
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