WO2016098291A1 - 円筒形電池 - Google Patents
円筒形電池 Download PDFInfo
- Publication number
- WO2016098291A1 WO2016098291A1 PCT/JP2015/005887 JP2015005887W WO2016098291A1 WO 2016098291 A1 WO2016098291 A1 WO 2016098291A1 JP 2015005887 W JP2015005887 W JP 2015005887W WO 2016098291 A1 WO2016098291 A1 WO 2016098291A1
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- WO
- WIPO (PCT)
- Prior art keywords
- plate
- positive electrode
- current collector
- upper insulating
- lead
- Prior art date
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0422—Cells or battery with cylindrical casing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0431—Cells with wound or folded electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/528—Fixed electrical connections, i.e. not intended for disconnection
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/534—Electrode connections inside a battery casing characterised by the material of the leads or tabs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/148—Lids or covers characterised by their shape
- H01M50/152—Lids or covers characterised by their shape for cells having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/166—Lids or covers characterised by the methods of assembling casings with lids
- H01M50/171—Lids or covers characterised by the methods of assembling casings with lids using adhesives or sealing agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a cylindrical battery having a positive electrode plate to which a plurality of positive electrode leads are connected.
- Non-aqueous electrolyte secondary batteries having high energy density have been widely used as drive power sources for high output applications such as electric tools, electric assist bicycles, and hybrid electric vehicles.
- Non-aqueous electrolyte secondary batteries are roughly classified into cylindrical batteries, square batteries, and pouch-type batteries according to the outer shape and the exterior body. Cylindrical batteries are suitable for the above applications because they are resistant to external impacts and can be easily processed into assembled batteries using a large number of batteries.
- a cylindrical battery is manufactured by inserting an electrode body, in which a negative electrode plate and a positive electrode plate are wound, through a separator, into an outer can, and sealing the opening with a sealing body.
- the sealing body functions as a positive electrode external terminal, it is necessary to electrically connect the positive electrode plate and the sealing body.
- a method of connecting a lead connected to a positive electrode plate to a sealing body is mainly employed.
- Patent Documents 1 to 3 are cited as prior art documents relating to a battery having a positive electrode plate to which a plurality of leads are connected.
- Patent Document 1 discloses a secondary battery in which a plurality of leads derived from an electrode body are overlapped at one point, and the overlapping portion is connected to a sealing body.
- Patent Document 2 discloses an electrode winding type battery in which a plurality of leads led out from an electrode body are collected by a conductive member arranged on the electrode body.
- the conductive member is composed of a bolt having a nut and a flange portion, and a lead led out from the electrode body is bent on the flange portion of the bolt, and the lead is sandwiched and fixed by the bolt and the nut.
- Patent Document 3 discloses a nickel cadmium battery in which a plurality of electrode plate tabs derived from a spiral electrode group are connected to a relay plate as a current collector plate.
- An insulating plate is disposed between the electrode group and the relay plate, and the relay plate and the insulating plate are provided with a large number of arc-shaped openings for inserting electrode plate tabs.
- the electrode plate tab inserted in the arc-shaped opening is bent and connected on the relay plate.
- Patent Document 2 since a bolt and a nut sandwiching a plurality of leads are used as external terminals, the step of connecting the leads to the sealing body is omitted.
- the bolts and nuts that do not contribute to charging / discharging occupy a lot of space inside the battery, the battery capacity is reduced. In particular, such a problem becomes conspicuous when the technique described in Patent Document 2 is applied to a small battery.
- a cylindrical battery according to the present invention includes an electrode body in which a negative electrode plate and a positive electrode plate to which a plurality of positive electrode leads are connected are wound through a separator, and an upper portion disposed on the electrode body An insulating plate, a current collector plate disposed on the upper insulating plate, a sealing body, and an outer can are provided.
- the upper insulating plate has at least one through hole, and the plurality of positive leads are at least one first positive lead disposed on the inner peripheral side of the upper insulating plate, and at least disposed on the outer peripheral side of the upper insulating plate. It consists of one second positive electrode lead.
- the first positive electrode lead passes through the through hole of the upper insulating plate, passes between the upper insulating plate and the current collector plate, is bent from the outer peripheral portion of the current collecting plate onto the current collecting plate, and the second positive electrode lead is the outer peripheral portion of the upper insulating plate. It is bent on the current collector plate from the outer periphery of the current collector plate.
- the first positive electrode lead and the second positive electrode lead are connected to a current collector plate, and the current collector plate is electrically connected to the sealing body.
- FIG. 1 is a cross-sectional view of a cylindrical nonaqueous electrolyte secondary battery according to an embodiment.
- FIG. 2A is a plan view of the negative electrode plate according to the embodiment, and FIG. 2B is a plan view of the positive electrode plate according to the embodiment.
- FIG. 3A to FIG. 3F are perspective views showing a method of connecting the positive electrode lead led out from the electrode body according to the embodiment to the current collector in the order of steps.
- FIG. 4A is a plan view showing the upper insulating plate according to the embodiment arranged on the electrode body, and FIG. 4B shows the upper insulating plate according to the modification of the embodiment arranged on the electrode body.
- FIG. 4A is a plan view showing the upper insulating plate according to the embodiment arranged on the electrode body
- FIG. 4B shows the upper insulating plate according to the modification of the embodiment arranged on the electrode body.
- the cylindrical nonaqueous electrolyte secondary battery 10 includes a bottomed cylindrical outer can 24, an electrode body 16 inserted into the outer can 24, and an opening of the outer can 24. It has the sealing body 23 which seals.
- the battery includes a nonaqueous electrolyte in which an electrolyte salt is dissolved in a nonaqueous solvent.
- the sealing body 23 includes an external terminal cap 23 a, an explosion-proof valve 23 b, and a terminal plate 23 d, and is caulked and fixed to the opening of the outer can 24 via the gasket 22.
- the external terminal cap 23a has a flange portion, and the flange portion is electrically connected to the explosion-proof valve 23b.
- the explosion-proof valve 23b and the terminal plate 23d are connected to each other through the annular insulating plate 23c.
- the connecting portion breaks when the pressure inside the battery rises and reaches a predetermined value, and interrupts the current path inside the battery. When the pressure inside the battery further increases, the explosion-proof valve 23b breaks and releases the gas inside the battery.
- the electrode body 16 is composed of a negative electrode plate 11, a positive electrode plate 13 and a separator 15, and is produced by winding the negative electrode plate 11 and the positive electrode plate 13 with the separator 15 interposed therebetween. As shown in FIG. 2, two negative leads 12 and two positive leads 14 are connected to the negative plate 11 and the positive plate 13, respectively. Inside the battery, the negative electrode lead 12 is bent so as to be parallel to the bottom surface of the outer can 24. Of the two negative leads 12, the negative lead on the outer peripheral side of the electrode body 16 is connected to the bottom of the outer can 24, and the negative lead on the inner peripheral side of the electrode body 16 is connected to the connecting portion.
- the two positive electrode leads 14 are connected to the current collector plate 18, and the current collector plate 18 is electrically connected to the terminal plate 23 d of the sealing body 23 through the current collector lead portion 18 a.
- An upper insulating plate 17 and a lower insulating plate 21 are disposed on the upper and lower portions of the electrode body 16, respectively.
- a ring-shaped insulating plate 20 is further disposed on the current collecting plate 18.
- the first positive electrode lead 14a and the second positive electrode lead 14b are led out from the electrode body 16 immediately after fabrication (FIG. 3A).
- the first positive electrode lead 14a is inserted into the through hole 17a, and the upper insulating plate 17 is disposed on the electrode body 16 (FIG. 3B).
- the first positive electrode lead 14a and the second positive electrode lead 14b are bent to the outside of the electrode body 16 (FIG. 3C), and the current collector plate 18 provided with the insulating member 19 at the lower portion is placed on the upper insulating plate 17. Arrange (Fig. 3 (d)).
- the first positive electrode lead 14 a and the second positive electrode lead 14 b By bending the first positive electrode lead 14 a and the second positive electrode lead 14 b in the direction of the outer peripheral side of the electrode body 16, a space for arranging the current collector plate 18 can be secured. Then, the first positive electrode lead 14a and the second positive electrode lead 14b are bent on the current collector plate 18 and connected to the current collector plate 18 (FIG. 3E). Laser welding can be used as a connection method. Finally, in order to insert the electrode body 16 into the outer can 24, the current collecting lead portion 18a of the current collecting plate 18 is bent at an angle of 90 ° (FIG. 3 (f)).
- the positive electrode lead can be connected to the current collector plate as long as the positive electrode lead does not overlap with the current collector lead portion of the current collector plate. Therefore, the allowable range of the position variation on the current collector of the positive electrode lead can be expanded.
- the upper insulating plate 17 having the planar shape shown in FIG. 4A is used.
- the second positive electrode lead 14b is passed through at least a part of the outer periphery.
- the upper insulating plate 27 provided with the notch 27b can also be used. If this notch 27b is used as a reference for positioning the upper insulating plate 27, it is not necessary to use the through hole 27a as a reference for positioning, so that the area of the through hole 27a can be increased. This increases the degree of freedom of the planar shape of the upper insulating plate that can be taken, so that the number of positive electrode leads can be easily increased.
- the material of the upper insulating plate any material having electrical insulation properties such as polyethylene can be used without limitation as long as the battery characteristics are not affected.
- an insulating member 19 is provided below the current collector plate 18. Protrusions are formed on the edge of the insulating member 19, so that the current collector 18 can be prevented from being displaced on the insulating member 19. Furthermore, the current collecting plate 18 and the insulating member 19 can be configured as an integrated member by matching the region surrounded by the convex portion with the shape of the current collecting plate.
- the edge of the insulating member 19 includes not only the outer peripheral edge of the insulating member 19 but also the edge of the opening of the insulating member 19. It is not necessary to form the convex portions on all the edges of the insulating member 19, and it is sufficient that the convex portions are formed on the insulating member 19 as long as the movement of the current collector plate 18 can be prevented.
- the insulating member is not an indispensable member, but the insulating member can be more effectively prevented from affecting the electrode body such as spatter generated when the positive electrode lead and the current collecting member are connected. Is preferably used. As long as the material of the insulating member is an electrically insulating material such as polyethylene, it can be used without limitation as long as the battery characteristics are not affected.
- the ring-shaped insulating plate 20 is disposed on the current collector plate 18.
- the cross-sectional shape of the ring-shaped insulating plate may be L-shaped with the outer peripheral side protruding toward the electrode body side. Both the outer peripheral portion and the inner peripheral portion of the planar shape of the ring-shaped insulating plate can be circular and a polygon inscribed in the circle, but at least the outer peripheral portion is preferably circular.
- the current collecting plate 18 has a current collecting lead portion 18a integrally formed as a part of the current collecting plate 18.
- a current collector plate can be produced by connecting leads of different parts to a metal plate. According to such a manufacturing method, the thickness of the metal plate portion of the current collector can be made larger than the thickness of the current collector lead portion, and the degree of freedom in designing the current collector plate can be increased.
- the material of the current collector plate is preferably the same as that of the positive electrode lead, and examples of the material of the positive electrode lead and the current collector plate include aluminum and aluminum alloys.
- the current collector lead portion of the current collector plate and the sealing body can be connected under the same conditions as those of a conventional cylindrical battery having a positive electrode plate to which one positive electrode lead is connected. Therefore, according to this embodiment, it is possible to provide a cylindrical battery having excellent productivity while having a positive electrode plate to which a plurality of positive electrode leads are connected.
- the negative electrode plate 11 has a negative electrode current collector and a negative electrode mixture layer 11a formed on both surfaces of the negative electrode current collector.
- the negative electrode lead 12 is connected to each of the negative electrode current collector exposed portions 11b provided at both ends of the negative electrode plate 11, but the negative electrode lead 12 may be connected to only one of them.
- a copper foil is preferably used as the negative electrode current collector.
- the negative electrode mixture layer 11a can be formed by applying and drying a negative electrode mixture slurry containing a negative electrode active material on a negative electrode current collector. In addition to the negative electrode active material, a binder or a conductive agent can be added to the negative electrode mixture slurry. The formed negative electrode mixture layer 11a is compressed with a roller and cut into a predetermined size, whereby the negative electrode plate 11 is obtained.
- a carbon material or metal oxide that can occlude and release lithium ions, or a metal material that can be alloyed with lithium can be used.
- the carbon material include graphite such as natural graphite and artificial graphite.
- the metal oxide and metal material include silicon and tin, and oxides thereof.
- the carbon material, the metal oxide, and the metal material can be used alone or in combination of two or more, and graphite and silicon oxide can also be used in combination.
- the positive electrode plate 13 has a positive electrode current collector and a positive electrode mixture layer 13a formed on both surfaces of the positive electrode current collector.
- the first positive electrode lead 14a and the second positive electrode lead 14b are connected to the two positive electrode current collector exposed portions 13b provided on the positive electrode plate 13, respectively. It is not limited to this, and three or more positive electrode leads can also be used.
- the positive lead arranged on the inner peripheral side of the upper insulating plate is the first positive lead
- the positive lead arranged on the outer peripheral side of the upper insulating plate is the second positive lead. are categorized.
- the positive electrode mixture layer 13a can be formed by applying and drying a positive electrode mixture slurry containing a positive electrode active material on a positive electrode current collector. In addition to the positive electrode active material, a binder or a conductive agent can be added to the positive electrode mixture slurry. The formed positive electrode mixture layer 13a is compressed with a roller and cut into a predetermined size, whereby the positive electrode plate 13 is obtained.
- a lithium transition metal composite oxide capable of inserting and extracting lithium ions can be used.
- the lithium transition metal composite oxide include general formula LiMO 2 (M is at least one of Co, Ni, and Mn), LiMn 2 O 4, and LiFePO 4 . These may be used alone or in admixture of two or more. At least one selected from the group consisting of Al, Ti, Mg, and Zr can be added to or substituted for these transition metal elements.
- a microporous film mainly composed of polyolefin such as polyethylene (PE) or polypropylene (PP) can be used as the separator.
- the microporous membrane can be used as a single layer or as a laminate of two or more layers.
- a layer mainly composed of polyethylene (PE) having a low melting point is used as an intermediate layer and polypropylene (PP) having excellent oxidation resistance is used as a surface layer.
- inorganic particles such as aluminum oxide (Al 2 O 3 ), titanium oxide (TiO 2 ), and silicon oxide (SiO 2 ) can be added to the separator. Such inorganic particles can be carried in the separator and can be applied together with a binder on the separator surface.
- non-aqueous electrolyte a solution obtained by dissolving a lithium salt as an electrolyte salt in a non-aqueous solvent as a solvent can be used. Moreover, it can replace with a non-aqueous solvent and can also use the non-aqueous electrolyte using the gel-like polymer.
- a cyclic carbonate ester As the non-aqueous solvent, a cyclic carbonate ester, a chain carbonate ester, a cyclic carboxylic acid ester and a chain carboxylic acid ester can be used, and these are preferably used in combination of two or more.
- the cyclic carbonate include ethylene carbonate (EC), propylene carbonate (PC), and butylene carbonate (BC).
- a cyclic carbonate in which part of hydrogen is substituted with fluorine such as fluoroethylene carbonate (FEC)
- the chain carbonate include dimethyl carbonate (DMC), ethyl methyl carbonate (EMC), diethyl carbonate (DEC), and methyl propyl carbonate (MPC).
- Examples of cyclic carboxylic acid esters include ⁇ -butyrolactone ( ⁇ -BL) and ⁇ -valerolactone ( ⁇ -VL).
- Examples of chain carboxylic acid esters include methyl pivalate, ethyl pivalate, methyl isobutyrate and methyl Pionate is exemplified.
- lithium salts examples include LiPF 6 , LiBF 4 , LiCF 3 SO 3 , LiN (CF 3 SO 2 ) 2 , LiN (C 2 F 5 SO 2 ) 2 , LiN (CF 3 SO 2 ) (C 4 F 9 SO 2 ), LiC (CF 3 SO 2 ) 3 , LiC (C 2 F 5 SO 2 ) 3 , LiAsF 6 , LiClO 4 , Li 2 B 10 Cl 10 and Li 2 B 12 Cl 12 .
- LiPF 6 is particularly preferable, and the concentration in the nonaqueous electrolyte is preferably 0.5 to 2.0 mol / L.
- Other lithium salts such as LiBF 4 may be mixed with LiPF 6 .
- the present invention it is possible to provide a cylindrical battery having excellent productivity while having a positive electrode plate to which a plurality of positive electrode leads are connected.
- a cylindrical battery having a positive electrode plate to which a plurality of positive electrode leads are connected is excellent in electrochemical characteristics such as load characteristics.
- the present invention since it is not necessary to form a through hole for inserting the positive electrode lead into the current collector, it is possible to provide a current collector plate with low electrical resistance. That is, the present invention can contribute to the improvement of the productivity of a cylindrical battery as a drive power source for applications that require high output such as electric tools, assist bicycles, and hybrid electric vehicles, and thus has great industrial applicability. .
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Connection Of Batteries Or Terminals (AREA)
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- Secondary Cells (AREA)
Abstract
Description
11 負極板
12 負極リード
13 正極板
14 正極リード
14a 第1正極リード
14b 第2正極リード
15 セパレータ
16 電極体
17 上部絶縁板
17a 貫通孔
18 集電板
19 絶縁部材
20 リング状絶縁板
21 下部絶縁板
22 ガスケット
23 封口体
24 外装缶
Claims (6)
- 負極板及び複数の正極リードが接続された正極板がセパレータを介して巻回された電極体と、前記電極体上に配置された上部絶縁板と、前記上部絶縁板上に配置された集電板と、封口体と、外装缶と、を備える円筒形電池であって、
前記上部絶縁板は少なくとも一つの貫通孔を有し、
前記複数の正極リードは、前記上部絶縁板の内周側に配置された少なくとも1つの第1正極リードと、前記上部絶縁板の外周側に配置された少なくとも1つの第2正極リードからなり、
前記第1正極リードは前記上部絶縁板の前記貫通孔を通り前記上部絶縁板と前記集電板の間を経由して前記集電板の外周部から前記集電板上に折り曲げられ、
前記第2正極リードは前記上部絶縁板の外周部の外側を通り前記集電板の外周部から前記集電板上に折り曲げられており、
前記第1正極リード及び前記第2正極リードが前記集電板に接続され、
前記集電板は前記封口体と電気的に接続されている円筒形電池。 - 前記上部絶縁板の外周部に切り欠き部が設けられている請求項1記載の円筒形電池。
- 前記集電板の下部に、縁部の少なくとも一部に凸部を有する絶縁部材が配置されている請求項1又は2に記載の円筒形電池。
- 前記複数の正極リードは前記集電板の上面にレーザー溶接されている請求項1から3のいずれかに記載の円筒形電池。
- 前記正極リードはアルミニウム又はアルミニウム合金からなる請求項1から4のいずれかに記載の円筒形電池。
- 前記第1正極リード及び前記第2正極リードの数はそれぞれ1本である請求項1から5のいずれかに記載の円筒形電池。
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018180828A1 (ja) * | 2017-03-29 | 2018-10-04 | 三洋電機株式会社 | 円筒形電池 |
JP2019149251A (ja) * | 2018-02-26 | 2019-09-05 | パナソニック株式会社 | 電池の製造方法及び電池 |
CN110226244A (zh) * | 2017-06-02 | 2019-09-10 | 株式会社Lg化学 | 二次电池 |
JPWO2019054312A1 (ja) * | 2017-09-15 | 2020-10-15 | 三洋電機株式会社 | 円筒形非水電解質二次電池 |
WO2020262437A1 (ja) * | 2019-06-28 | 2020-12-30 | 三洋電機株式会社 | 円筒形非水電解質二次電池 |
WO2022270280A1 (ja) * | 2021-06-25 | 2022-12-29 | 三洋電機株式会社 | 円筒形電池 |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016174811A1 (ja) * | 2015-04-27 | 2016-11-03 | 三洋電機株式会社 | 円筒形電池、並びにそれに用いる集電部材及びその製造方法 |
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US20230246317A1 (en) * | 2020-04-02 | 2023-08-03 | Stryker Corporation | Electrochemical Cell Design And Structure |
CN115472970A (zh) * | 2022-10-13 | 2022-12-13 | 中创新航科技股份有限公司 | 圆柱电池 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54149839A (en) * | 1978-05-16 | 1979-11-24 | Matsushita Electric Ind Co Ltd | Method of producing cylindrical storage battery |
JP2010534916A (ja) * | 2007-07-24 | 2010-11-11 | エイ 123 システムズ,インク. | 電池セル設計およびその組立方法 |
JP2012023011A (ja) * | 2010-07-12 | 2012-02-02 | Samsung Sdi Co Ltd | 電極組立体およびこれを含む二次電池 |
WO2012105362A1 (ja) * | 2011-02-03 | 2012-08-09 | 三洋電機株式会社 | 非水電解液二次電池 |
WO2013038677A1 (ja) * | 2011-09-14 | 2013-03-21 | パナソニック株式会社 | 非水電解質二次電池 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS571402Y2 (ja) | 1976-03-10 | 1982-01-09 | ||
JPH11312509A (ja) | 1998-04-28 | 1999-11-09 | Toyota Central Res & Dev Lab Inc | 電極巻回型電池 |
US7041413B2 (en) * | 2000-02-02 | 2006-05-09 | Quallion Llc | Bipolar electronics package |
US7853788B2 (en) * | 2002-10-08 | 2010-12-14 | Koolspan, Inc. | Localized network authentication and security using tamper-resistant keys |
KR101304125B1 (ko) * | 2005-09-02 | 2013-09-05 | 에이일이삼 시스템즈 인코포레이티드 | 전지 셀의 구조와 그 구성 방법 |
JP2007335232A (ja) | 2006-06-15 | 2007-12-27 | Matsushita Electric Ind Co Ltd | 二次電池およびその製造方法 |
JP4539658B2 (ja) * | 2007-01-23 | 2010-09-08 | ソニー株式会社 | 電池 |
US8119280B2 (en) | 2007-06-07 | 2012-02-21 | A123 Systems, Inc. | Cap assembly for a high current capacity energy delivery device |
CN102549811B (zh) * | 2009-12-04 | 2014-11-05 | 松下电器产业株式会社 | 密闭型二次电池 |
DK2782181T3 (en) * | 2011-12-19 | 2019-03-11 | Exergy Power Systems Inc | Layered Cell and Total Battery Including Layered Cell |
-
2015
- 2015-11-27 WO PCT/JP2015/005887 patent/WO2016098291A1/ja active Application Filing
- 2015-11-27 JP JP2016564668A patent/JP6593344B2/ja active Active
- 2015-11-27 CN CN201580068729.5A patent/CN107112487B/zh active Active
- 2015-11-27 US US15/531,648 patent/US10461304B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54149839A (en) * | 1978-05-16 | 1979-11-24 | Matsushita Electric Ind Co Ltd | Method of producing cylindrical storage battery |
JP2010534916A (ja) * | 2007-07-24 | 2010-11-11 | エイ 123 システムズ,インク. | 電池セル設計およびその組立方法 |
JP2012023011A (ja) * | 2010-07-12 | 2012-02-02 | Samsung Sdi Co Ltd | 電極組立体およびこれを含む二次電池 |
WO2012105362A1 (ja) * | 2011-02-03 | 2012-08-09 | 三洋電機株式会社 | 非水電解液二次電池 |
WO2013038677A1 (ja) * | 2011-09-14 | 2013-03-21 | パナソニック株式会社 | 非水電解質二次電池 |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110419124A (zh) * | 2017-03-29 | 2019-11-05 | 三洋电机株式会社 | 圆筒形电池 |
JPWO2018180828A1 (ja) * | 2017-03-29 | 2020-05-14 | 三洋電機株式会社 | 円筒形電池 |
WO2018180828A1 (ja) * | 2017-03-29 | 2018-10-04 | 三洋電機株式会社 | 円筒形電池 |
US11011806B2 (en) | 2017-03-29 | 2021-05-18 | Sanyo Electric Co., Ltd. | Cylindrical battery |
JP7006683B2 (ja) | 2017-03-29 | 2022-01-24 | 三洋電機株式会社 | 円筒形電池 |
CN110226244A (zh) * | 2017-06-02 | 2019-09-10 | 株式会社Lg化学 | 二次电池 |
EP3534426B1 (en) * | 2017-06-02 | 2024-02-28 | LG Energy Solution, Ltd. | Secondary battery |
CN110226244B (zh) * | 2017-06-02 | 2022-08-16 | 株式会社Lg新能源 | 二次电池 |
JP7171585B2 (ja) | 2017-09-15 | 2022-11-15 | 三洋電機株式会社 | 円筒形非水電解質二次電池 |
JPWO2019054312A1 (ja) * | 2017-09-15 | 2020-10-15 | 三洋電機株式会社 | 円筒形非水電解質二次電池 |
JP2019149251A (ja) * | 2018-02-26 | 2019-09-05 | パナソニック株式会社 | 電池の製造方法及び電池 |
WO2020262437A1 (ja) * | 2019-06-28 | 2020-12-30 | 三洋電機株式会社 | 円筒形非水電解質二次電池 |
CN114026725A (zh) * | 2019-06-28 | 2022-02-08 | 三洋电机株式会社 | 圆筒形非水电解质二次电池 |
WO2022270280A1 (ja) * | 2021-06-25 | 2022-12-29 | 三洋電機株式会社 | 円筒形電池 |
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