WO2016068299A1 - 水中油型乳化日焼け止め化粧料 - Google Patents
水中油型乳化日焼け止め化粧料 Download PDFInfo
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- WO2016068299A1 WO2016068299A1 PCT/JP2015/080765 JP2015080765W WO2016068299A1 WO 2016068299 A1 WO2016068299 A1 WO 2016068299A1 JP 2015080765 W JP2015080765 W JP 2015080765W WO 2016068299 A1 WO2016068299 A1 WO 2016068299A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/522—Antioxidants; Radical scavengers
Definitions
- the present invention relates to an oil-in-water emulsified sunscreen cosmetic. More specifically, the present invention relates to an oil-in-water emulsified sunscreen cosmetic that has an unprecedented property in that the UV protection effect is improved more than immediately after application by contact with water or sweat.
- UV care cosmetics a type of UV care cosmetics, contain UV absorbers and UV scattering agents to block UVA and UVB from reaching the skin and protect the skin from UV damage.
- Protect Non-Patent Document 1. Recently, it is considered that it is important to protect the skin from ultraviolet rays in daily life as well as the harsh UV conditions in outdoor activities such as summer swimming and swimming in the sea and winter skiing. Cosmetics having an ultraviolet protection effect are desired.
- Patent Document 1 As dosage forms of sunscreen cosmetics, preparations in an emulsified form are often used, and instability of emulsification may lead to a decrease in UV protection ability.
- Patent Document 1 it is described that storage stability is improved by blending free fatty acids having 14 to 24 carbon atoms, and a decrease in UV protection ability due to long-term storage is suppressed.
- sunscreen cosmetics applied to the skin come into contact with water or sweat, UV absorbers or UV scattering agents will flow out from the applied cosmetics, and UV rays It is inevitable that the protective effect will decline. Therefore, various attempts have been made to improve the water resistance and film strength of sunscreen cosmetics in order to prevent the outflow of UV protection agents.
- Patent Document 2 includes a water-swellable clay mineral, a quaternary ammonium salt type cationic surfactant, a polyoxyalkylene-modified organopolysiloxane, an aqueous phase, and a general formula R n SiO (4-n) / 2 .
- a water-in-oil emulsified composition containing an organosilicone resin which improves the water resistance and water repellency by incorporating an organosilicone resin and keeps the UV absorber on the skin for a long time. It has been proposed to do.
- Patent Document 3 discloses a water-in-oil emulsified cosmetic containing an ultraviolet light inhibitor, an organically modified clay mineral, a volatile component, a spherical resin powder, and a coating agent. It has been proposed to prevent powder rub-off and secondary adhesion to clothing.
- oil-in-water emulsions are widely used as sunscreen cosmetics because they provide a fresh feeling to use.
- oil-in-water emulsified cosmetics are often inferior in water resistance as compared to water-in-oil type, and the UV protection ability is likely to decrease due to the outflow of UV absorbers and UV scattering agents. Therefore, attempts have been made to improve water resistance by blending a film agent (Patent Document 4) and to enhance the ultraviolet protection effect by blending a high amount of ultraviolet absorber (Patent Document 5).
- the present invention has found a phenomenon that the UV protection effect does not decrease by contact with water, sweat, etc., but the effect is improved. Based on the above, it is an object to provide a sunscreen cosmetic having an unprecedented innovative property that an ultraviolet protection effect is improved by contact with moisture.
- the present inventors have blended an ultraviolet absorber and / or an ultraviolet scattering agent and a fatty acid, and by setting the neutralization rate of the fatty acid to a predetermined value or less.
- the present inventors have found that sunscreen cosmetics having the above-described novel characteristics can be obtained, and have completed the present invention.
- the present invention provides an oil-in-water emulsified sunscreen cosmetic containing (A) an ultraviolet protective agent and (B) a solid fatty acid at normal temperature, and the neutralization rate of the fatty acid is 51% or less. Is.
- the ultraviolet protection effect after contact with water, sweat, or the like is remarkably improved as compared with that immediately after the cosmetic is applied to the skin. That is, the oil-in-water emulsified sunscreen cosmetic according to the present invention is opposite to the conventional common sense that the UV protection effect is improved by contact with moisture, which has been the cause of deterioration in conventional sunscreen cosmetics.
- An innovative sunscreen cosmetic with properties are provided.
- the sunscreen cosmetic of the present invention exhibits an excellent UV protection effect without adding a high amount of a silicone resin or a coating agent in order to improve water resistance. good.
- it retains the original characteristics of oil-in-water emulsified cosmetics and not only gives a fresh feel when applied, but also has excellent usability without stickiness or oiliness, It can also be easily removed with soap.
- the mechanism of action that the sunscreen cosmetic of the present invention exhibits the unique property that the UV protection effect is improved by contact with moisture is not necessarily elucidated at present, but is considered as follows. be able to.
- the sunscreen cosmetic of the present invention having the above-described configuration is applied to the skin, it is considered that there is non-uniformity in the coating film containing the UV protection agent.
- this coating film comes into contact with water such as tap water, seawater, sweat, etc.
- minerals such as calcium ions and magnesium ions contained in these waters interact with fatty acid components, thereby increasing the water repellency of the coating film.
- the uniformity of the coating film is improved. It is known that the uniformity of the coating film of sunscreen cosmetics is important for the UV protection effect.
- a UV protection effect higher than that immediately after the application is realized, and at the same time, UV protection by the outflow of UV protection agent. Performance degradation is prevented.
- the uniformity of the coating film (denseness of the surface and the uniformity of the film itself) is greater after contact with moisture than immediately after application of the sunscreen cosmetic of the present invention. ) Has been confirmed to improve.
- the uniformity of the film decreases when it comes into contact with moisture.
- a uniform coating film as a whole is more ultraviolet than a non-uniform coating film.
- Defensive ability is much better. This is considered to be due to the fact that the UV protection ability is not improved additively with the increase of the film thickness but synergistically increases in proportion to the film thickness.
- the (A) UV protection agent (hereinafter sometimes simply referred to as “component (A)”) blended in the oil-in-water emulsified sunscreen cosmetic according to the present invention comprises a UV absorber and / or a UV scattering agent. Meaning, what is usually blended in sunscreen cosmetics can be used.
- the ultraviolet absorber used in the present invention is not particularly limited, but specific examples thereof include ethylhexyl methoxycinnamate, octocrylene, dimethicodiethylbenzalmalonate, polysilicon-15, t-butylmethoxydibenzoyl.
- Organics such as methane, ethylhexyltriazone, hexyl diethylaminohydroxybenzoylbenzoate, bisethylhexyloxyphenol methoxyphenyltriazine, oxybenzone-3, methylenebisbenzotriazolyltetramethylbutylphenol, phenylbenzimidazolesulfonic acid, homosalate, ethylhexyl salicylate, etc.
- An ultraviolet absorber can be mentioned.
- the ultraviolet scattering agent used in the present invention is not particularly limited, specific examples thereof include fine particle metal oxides such as zinc oxide, titanium oxide, iron oxide, cerium oxide, tungsten oxide and the like. be able to.
- the UV scattering agent may be one that has not been surface-treated or one that has been surface-treated, and examples of the surface treating agent include those commonly used in the cosmetics field, for example, alkoxysilanes such as octyltriethoxysilane, dextrin palmitate Dextrin fatty acid esters such as stearic acid and the like can be used.
- the amount of the component (A) is preferably 5% by mass or more, more preferably 5 to 40% by mass, and further preferably 6 to 20% by mass with respect to the total amount of the oil-in-water type emulsion sunscreen cosmetic. If the blending amount of component (A) is less than 5% by mass, it is difficult to obtain a sufficient UV protection effect, and even if blended in excess of 40% by mass, an increase in UV protection effect commensurate with the blending amount cannot be expected, and stability. There is a tendency for usability to deteriorate.
- the ultraviolet protective agent ((A) component) of this invention includes the aspect which consists only of an ultraviolet absorber, the aspect which consists only of an ultraviolet scattering agent, and the aspect containing both an ultraviolet absorber and an ultraviolet scattering agent.
- the (B) fatty acid (hereinafter sometimes simply referred to as “component (B)”) used in the present invention is not particularly limited as long as it can be used for cosmetics and the like, and is linear or branched. It can be selected from fatty acids having a chain saturated or unsaturated hydrocarbon group. In particular, linear higher fatty acids having a solid number of 8 to 22 carbon atoms such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid (behenic acid), oleic acid and the like can be mentioned. . Among these, it is particularly preferable to use one or more selected from stearic acid, palmitic acid and behenic acid.
- the fatty acid used in the present invention is partially neutralized (neutralization rate is 51% or less) by a counter ion (cation).
- “Neutralization rate of (fatty acid)” in this specification means “Ea ′” as the total number of equivalents of fatty acids blended in an oil-in-water emulsion cosmetic, and a substance obtained by removing fatty acids from acidic substances in cosmetics.
- Ea the total number of equivalents
- Eb the total number of equivalents of the basic substances blended in the cosmetic
- the basic substance used as a neutralizing agent for the fatty acid is a substance that can supply a counter ion (cation) that neutralizes the fatty acid anion, and is incorporated into cosmetics and the like.
- a counter ion (cation) that neutralizes the fatty acid anion
- Any inorganic base, organic base, cationic polymer, and the like that can be used may be used, and the invention is not particularly limited.
- Typical examples of the inorganic base include sodium hydroxide, potassium hydroxide, ammonium chloride and the like.
- the organic base include amines such as monoethanolamine, diethanolamine, triethanolamine, aminomethylpropanediol, 2-amino-2-methylpropanol (AMP), triisopropanolamine (TIPA), tris [(2-hydroxy) -1-propyl] amine, 2-amino-2-methyl-1,3-propanediol (AMPD), 2-amino-2-hydroxymethyl-1,3-propanediol, N-methylglucamine, etc. Mention may be made of amino acids such as arginine and lysine.
- the cationic polymer is not particularly limited as long as it is a cationic polymer that can be used in cosmetics and skin external preparations.
- Specific examples include cationized cellulose derivatives [for example, quaternary nitrogen-containing cellulose ether (“Polymer JR-400”, “Polymer JR-125”, “Polymer JR-300M” (all manufactured by Union Carbide, USA), etc.) )], Cationized guar gum, cationized locust bean gum, cationized tara gum, diallyl quaternary ammonium salt homopolymer, diallyl quaternary ammonium salt / acrylamide copolymer [for example, dimethyldiallylammonium chloride / acrylamide copolymer (" MERQUAT 2200 "(manufactured by Nalco Co., Ltd.)], quaternized polyvinylpyrrolidone derivative, polyglycol polyamine condensate, vinylimidazolium trichloride
- the neutralization rate of the fatty acid in the present invention is 0 to 51%, and all numerical values included in this range, for example, 0.001, 0.01, 0.1, 0.5, 1 Any value such as 5, 10, 15, 20, 25, 30, 35, 40, 45, or 50%, or all numerical ranges having these values as the lower limit value or the upper limit value can be adopted.
- the blending amount of the component (B) in the cosmetic of the present invention is only required to satisfy the following blending ratio based on the blending amount of the UV protective agent blended together, and is usually about 1 to 40% by weight. It is blended in the range.
- the blending amount is preferably more than 5% by mass and 40% by mass or less. It goes without saying that this blending amount range can take all values within the above range.
- “more than 5% by mass” does not include 5% by mass as the lower limit of the compounding amount, but more than that, for example, 5.1% by mass or more, 5.5% by mass or more, 6 It means that it can be made into mass% or more, 7 mass% or more, 8 mass% or more, 9 mass% or more, or 10 mass% or more.
- the upper limit of the blending amount can be set to 40% by mass or less, 35% by mass or less, 30% by mass or less, 28% by mass or less, 25% by mass or less, 22% by mass or less, or 20% by mass or less. It is.
- the amount of the basic substance (neutralizing agent) blended to neutralize the fatty acid is such that the fatty acid neutralization rate is 51% based on the blended amount of the fatty acid and the blended amount of other acidic substances. It can be calculated based on the above formula (A) as follows.
- the blending ratio of the ultraviolet absorber and / or ultraviolet scattering agent (component (A)) and component (B) ((A) / ( B)) must be 0.1 or more and less than 10.0.
- this ratio is 10.0 or more, there may be a case where the effect peculiar to the present invention that the ultraviolet ray protection effect is improved upon contact with moisture cannot be obtained.
- less than 10.0 is a concept that includes all values smaller than 10.0 but not 10.0.
- This blending amount ratio includes all numerical values and all numerical ranges (for example, 0.1 to 9.0, 0.2 to 8.0, or 0.3 to 7.0) included in the range from 0.1 to less than 10.0. Etc.).
- the upper limit of the blending ratio is set to 9.9, 9.8, 9.7, 9.6, 9.5, 9.0, 8.0, 7.0, 6.0, or the like.
- the lower limit can be set to 0.1, 0.15, 0.2, 0.3, 0.4, or the like.
- the IOB value is a ratio (Inorganic Organic Balance) of the inorganic value (IV) to the organic value (OV) in the organic conceptual diagram, and means “inorganic value (IV) / organic value (OV)”.
- An organic conceptual diagram is based on methane (CH 4 ) as the source of all organic compounds, and all other compounds as derivatives of methane. Set and add the scores to obtain the organic and inorganic values, and plot them on a diagram with the organic value on the X axis and the inorganic value on the Y axis ("Organic Conceptual Diagram” -Fundamentals and applications "(see Yoshio Koda, Sankyo Publishing, 1984)).
- component (C) IOB used in the present invention has an oil content of 0.5 or more (hereinafter sometimes simply referred to as “component (C)”) as esters such as diethoxyethyl succinate, alkylene polyglycol of dineopentanoic acid, etc.
- Oils, polyethylene glycol (PEG), polypropylene glycol (PPG), and alkylene oxide derivatives containing polyalkylene glycols such as polybutylene glycol (PBG) may be those conventionally used in cosmetics.
- an alkylene oxide derivative particularly a random alkylene oxide derivative represented by the following formula (I).
- AO is an oxyalkylene group having 3 to 4 carbon atoms
- EO is an oxyethylene group
- m and n are average addition moles of the oxyalkylene group and oxyethylene group, respectively, 1 ⁇ m ⁇ 70, 1 ⁇ n ⁇ 70
- the ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is 20 to 80 mass%
- the oxyalkylene group and oxyethylene group having 3 to 4 carbon atoms is also be added in a block form a hydrocarbon group or a hydrogen atom of a random good .
- R 1 and R 2 also be added to form the same or different carbon atoms and optionally 1 ⁇ 4, R 1 and (The ratio of
- AO is an oxyalkylene group having 3 to 4 carbon atoms, and specifically includes an oxypropylene group, an oxybutylene group, an oxyisobutylene group, an oxytrimethylene group, and an oxytetramethylene group. Etc. Preferably, an oxypropylene group and an oxybutylene group are mentioned.
- EO is an oxyethylene group.
- m is the average number of added moles of the oxyalkylene group having 3 to 4 carbon atoms, and 1 ⁇ m ⁇ 70, preferably 2 ⁇ m ⁇ 50.
- n is the average number of added moles of oxyethylene groups, and 1 ⁇ n ⁇ 70, preferably 5 ⁇ n ⁇ 55.
- the ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is preferably 20 to 80% by mass.
- the order of adding ethylene oxide and alkylene oxide having 3 to 4 carbon atoms is not particularly specified.
- the oxyethylene group and the oxyalkylene group having 3 to 4 carbon atoms may be added in a block form or randomly. Preferably, those added randomly are listed.
- R 1 and R 2 are a hydrocarbon group having 1 to 4 carbon atoms or a hydrogen atom, and examples of the hydrocarbon group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, Examples thereof include alkyl groups such as tert-butyl group. A methyl group and an ethyl group are preferred. When the hydrocarbon group has 5 or more carbon atoms, the effect of the present invention tends to decrease.
- R 1 and R 2 may be the same or different.
- Each of R 1 and R 2 may be used alone, or a hydrocarbon group having 1 to 4 carbon atoms and a hydrogen atom may be mixed, or a hydrocarbon group having 1 to 4 carbon atoms may be mixed.
- the abundance ratio of hydrocarbon groups and hydrogen atoms is such that the ratio Y / X of the number of hydrogen atoms (Y) to the number of hydrocarbon groups (X) is 0.15.
- it is preferably 0.06 or less.
- the alkylene oxide derivative of the formula (I) can be produced by a known method. For example, it can be obtained by addition-polymerizing ethylene oxide and an alkylene oxide having 3 to 4 carbon atoms to a compound having a hydroxyl group and then ether-reacting an alkyl halide in the presence of an alkali catalyst.
- alkylene oxide derivative of the formula (I) examples include POE (9) POP (2) dimethyl ether, POE (14) POP (7) dimethyl ether, POE (10) POP (10) dimethyl ether, POE (6) POP ( 14) dimethyl ether, POE (15) POP (5) dimethyl ether, POE (25) POP (25) dimethyl ether, POE (7) POP (12) dimethyl ether, POE (22) POP (40) dimethyl ether, POE (35) POP ( 40) dimethyl ether, POE (50) POP (40) dimethyl ether, POE (55) POP (30) dimethyl ether, POE (30) POP (34) dimethyl ether, POE (25) POP (30) dimethyl ether, POE (27) POP ( 14) Methyl ether, POE (55) POP (28) dimethyl ether, POE (36) POP (41) dimethyl ether, POE (7) POP (12) dimethyl ether, POE (17) POP (4) dimethyl
- polyoxyethylene (POE) / polyoxypropylene (POP) dimethyl ether is preferably used, but is not limited thereto.
- POE, POP, and POB are abbreviations for polyoxyethylene, polyoxypropylene, and polyoxybutylene, respectively.
- the alkylene oxide derivatives in the present invention include polyalkylene glycols such as polyethylene glycol (PEG), polypropylene glycol (PPG), and polybutylene glycol (PBG).
- PEG polyethylene glycol
- PPG polypropylene glycol
- PBG polybutylene glycol
- the polyalkylene glycol in the present invention includes polyoxybutylene polyoxypropylene glycol such as polyoxybutylene (9) polyoxypropylene (1) glycol, polyoxyethylene polyoxypropylene glycol and the like, and is used as a skin external preparation such as cosmetics. It is appropriately selected from those that can be used, but those having a molecular weight of 300 or more are preferred, and those having a molecular weight of 1000 or more are more preferred. Although the upper limit of molecular weight is not specifically limited, For example, the thing of molecular weight 20000 or less, 5000 or less, or 2500 or less is used suitably.
- the alkylene oxide derivative in the present invention can be used by arbitrarily selecting one or two or more types, and is polyoxyethylene / polyoxypropylene dimethyl ether which is an alkylene oxide derivative of the formula (I), among them, polyoxyethylene ( 14) It is particularly preferred to include polyoxypropylene (7) dimethyl ether.
- the amount of component (C) to be blended is not particularly limited. For example, it is blended in the range of 0.005 to 20% by mass, 0.5 to 10% by mass, or 0.1 to 5% by mass. As a result, the time from the contact with moisture until the effect of improving the UV protection ability is exhibited is shortened.
- the oil-in-water emulsified sunscreen cosmetics of the present invention are usually used in cosmetics, such as humectants, thickeners, powders, alcohols, natural polymers, synthetic polymers, sugars, Antioxidants, buffers, various extracts, stabilizers, preservatives, pigments, fragrances, and the like can be appropriately blended within a range that does not impair the effects of the present invention.
- cosmetics such as humectants, thickeners, powders, alcohols, natural polymers, synthetic polymers, sugars, Antioxidants, buffers, various extracts, stabilizers, preservatives, pigments, fragrances, and the like can be appropriately blended within a range that does not impair the effects of the present invention.
- the surfactant is added in an amount exceeding 5.0% by mass, the coating film itself may flow when it comes into contact with water. Therefore, the amount of the surfactant is 5.0% by mass or less.
- the present invention also includes an embodiment that does not contain a surfactant.
- the method for producing the oil-in-water emulsified sunscreen cosmetic of the present invention is not particularly limited.
- the component constituting the oil phase and the component constituting the water phase are separately mixed, and the oil phase is mixed with the water phase. And can be prepared by stirring and emulsifying.
- composition of the present invention has a fresh feeling of use and excellent detergency inherent to an oil-in-water emulsion, and exhibits a unique effect of improving the UV protection ability when in contact with water. It is particularly suitable for use as a type of oil-in-water emulsified sunscreen cosmetic.
- the oil-in-water emulsified sunscreen cosmetics of the present invention can be provided as, for example, sunscreen creams, sunscreen emulsions, sunscreen lotions, as well as foundations, makeup bases, makeup cosmetics, hair cosmetics that have been provided with sunscreen effects Etc. can also be used.
- a compounding quantity represents the mass% with respect to the whole quantity.
- Examples and Comparative Examples The oil-in-water emulsified sunscreen cosmetics shown in the Examples and Comparative Examples are prepared by adding an oil phase in which an oily component is separately heated to a water phase in which an aqueous component is heated and dissolved as necessary. It was prepared by emulsifying by stirring treatment.
- Example 3 A cosmetic having the composition listed in Table 2 below was prepared, and the Abs integrated value before and after bathing and the rate of change thereof were determined.
- Examples 5 to 15, Comparative Example 6 The cosmetics having the compositions listed in Table 3 and Table 4 below were prepared, and the Abs integrated value before and after the water bath and the rate of change thereof were determined.
- Examples 16 to 23 A cosmetic having the composition listed in Table 5 below was prepared, and the absorbance change rate before and after the water bath when the water bath time was 30 seconds, 1 minute, and 5 minutes was determined. The results are shown in Table 5.
- Example 16 which does not contain an oil component having an IOB of 0.5 or more, the change rate exceeded 100% after 5 minutes of water bathing, whereas the IOB was 0.1%.
- Example 17 containing 0.1% by mass of 5 or more oil, the rate of change exceeded 100% in a 1-minute water bath.
- Examples 18 to 23 in which the blending amounts of oils having an IOB of 0.5 or more were 1% by mass and 5% by mass, the rate of change exceeded 100% in a water bath for only 30 seconds. That is, it was confirmed that by adding an oil component having an IOB of 0.5 or more, the expression rate of the ultraviolet ray protection ability improving effect by the water bath is increased.
- Example 24 A cosmetic having the composition listed in Table 6 below was prepared, and the absorbance change rate before and after the water bath when the water bath time was 30 minutes was determined. The results are shown in Table 6.
- FIG. 1 shows micrographs of a cross section of the cosmetic coating film immediately after applying the cosmetic material of Example 19 to a pseudo skin substrate (uneven PMMA substrate) and after 30 minutes of water bathing.
- a pseudo skin substrate uneven PMMA substrate
- the film Immediately after application to the skin ((a) and (b)) and immediately after application to the crevice ((c)), the film has large irregularities and the coating thickness is non-uniform for 30 minutes. It can be confirmed that the coating film became dense and uniform after the water bathing (skin: (d) and (e); skin groove: (f)).
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Abstract
Description
しかし、たとえ使用直前まで紫外線防御能が維持されていたとしても、皮膚に塗布した日焼け止め化粧料が水や汗と接触すると、塗布した化粧料から紫外線吸収剤や紫外線散乱剤が流出し、紫外線防御効果が低下することが避けられない。そこで、紫外線防御剤の流出を阻止するために、日焼け止め化粧料の耐水性や被膜強度を改善する等の様々な試みがなされてきた。
また、特許文献3には、紫外線防止剤、有機変性粘土鉱物、揮発性成分、球状樹脂粉末および被膜剤を含有する油中水型乳化化粧料が開示されており、被膜剤を配合することにより、粉末のこすれ落ちや、衣服への二次付着を防止することが提案されている。
<(A)紫外線防御剤>
本発明に係る水中油型乳化日焼け止め化粧料に配合される(A)紫外線防御剤(以下、単に「(A)成分」と称する場合がある)は、紫外線吸収剤及び/又は紫外線散乱剤を意味し、日焼け止め化粧料に通常配合されるものを使用することができる。
なお、本発明の紫外線防御剤((A)成分)は、紫外線吸収剤のみからなる態様、紫外線散乱剤のみからなる態様、及び紫外線吸収剤と紫外線散乱剤の両方を含む態様を包含する。
本発明で用いられる(B)脂肪酸(以下、単に「(B)成分」と称する場合がある)は、化粧料等に使用できるものであれば特に限定されるものではなく、直鎖状または分岐鎖状の飽和または不飽和の炭化水素基を有する脂肪酸から選択できる。
特に、常温で固体であり、かつ、炭素数8~22の直鎖状の高級脂肪酸、たとえば、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸(ベヘン酸)、オレイン酸等が挙げられる。中でも、ステアリン酸、パルミチン酸およびベヘニン酸から選択される一種または二種以上を用いるのが特に好ましい。
本明細書における「(脂肪酸の)中和率」とは、水中油型乳化化粧料に配合される脂肪酸の合計当量数を「Ea’」、化粧料中の酸性物質から脂肪酸を除いた物質の合計当量数を「Ea”」、化粧料に配合される塩基性物質の合計当量数を「Eb」としたとき、以下の式(A)で表される数値と定義する。
[(Eb-Ea”)/(Ea’)]×100(%) (A)
有機塩基としては、アミン類、例えばモノエタノールアミン、ジエタノールアミン、トリエタノールアミン、アミノメチルプロパンジオール、2-アミノ-2-メチルプロパノール(AMP)、トリイソプロパノールアミン(TIPA)、トリス[(2-ヒドロキシ)-1-プロピル]アミン、2-アミノ-2-メチル-1,3-プロパンジオール(AMPD)及び2-アミノ-2-ヒドロキシメチル-1,3-プロパンジオール、N-メチルグルカミン等、塩基性アミノ酸、例えばアルギニンおよびリジンを挙げることができる。
本発明の水中油型乳化日焼け止め化粧料では、上記必須成分に加え、(C)IOBが0.5以上の油分をさらに配合することにより、水分と接する前の紫外線防御能(以下、初期の紫外線防御能)を高め、なおかつ水浴前後の紫外線防御能の向上幅及び向上速度を更に高めることができる。
R1O-[(AO)m(EO)n]-R2 (I)
(式中、AOは炭素数3~4のオキシアルキレン基、EOはオキシエチレン基、mおよびnはそれぞれ前記オキシアルキレン基、オキシエチレン基の平均付加モル数で、1≦m≦70、1≦n≦70である。炭素数3~4のオキシアルキレン基とオキシエチレン基の合計に対するオキシエチレン基の割合が、20~80質量%である。炭素数3~4のオキシアルキレン基とオキシエチレン基はブロック状に付加していてもランダム状に付加していてもよい。R1およびR2は同一もしくは異なっていてもよい炭素数1~4の炭化水素基または水素原子であり、R1およびR2の炭化水素基数に対する水素原子数の割合が0.15以下である。)
なお、上記POE、POP、POBは、それぞれポリオキシエチレン、ポリオキシプロピレン、ポリオキシブチレンの略である。
(C)成分を配合する場合の配合量は、特に限定されないが、例えば、0.005~20質量%、0.5~10質量%、又は0.1~5質量%の範囲で配合することにより、水分と接触してから紫外線防御能向上効果を発揮するまでの時間が短縮される。
ただし、界面活性剤を5.0質量%を超えて配合すると水に接触した場合に塗布膜自体が流れてしまう場合があるため、界面活性剤の配合量は5.0質量%以下とするのが好ましく、本発明は界面活性剤を含まない態様も包含する。
実施例および比較例に示す水中油型乳化日焼け止め化粧料は、水性成分を必要に応じて加温して溶解した水相に、別途油性成分を適宜加温して溶解した油相を添加し、攪拌処理にて乳化することにより調製した。
測定プレート(Sプレート)(5×5cmのV溝PMMA板、SPFMASTER-PA01)に各例の化粧料(サンプル)を2mg/cm2の量で滴下し、60秒間指で塗布し、15分間乾燥した後、その吸光度を株式会社日立製作所製U-3500型自記録分光光度計にて測定した。紫外線吸収のないグリセリンをコントロールとし、吸光度(Abs)を以下の式で算出した。
Abs=-log(T/To)
T:サンプルの透過率、To:グリセリンの透過率
測定したプレートを硬度50~500の水に十分に浸し、30分間そのまま水中で撹拌した(3-1モーターで300rpm)。その後、表面の水滴がなくなるまで15~30分程度乾燥させ、再び吸光度を測定し、水浴前後の吸光度(Abs)積算値からAbs変化率(以下の式)を紫外線防御能向上効果として算出した。
紫外線防御能向上効果:
Abs変化率(%)=(水浴後のAbs積算値)/(水浴前のAbs積算値)×100
下記の表1に掲げた組成を有する化粧料を調整し、水浴前後のAbs積算値およびその変化率を求めた。
下記の表2に掲げた組成を有する化粧料を調整し、水浴前後のAbs積算値およびその変化率を求めた。
下記の表3および表4に掲げた組成を有する化粧料を調整し、水浴前後のAbs積算値およびその変化率を求めた。
下記の表5に掲げた組成を有する化粧料を調整し、水浴時間を30秒間、1分間、5分間とした場合の、水浴前後の吸光度変化率を求めた。結果を表5に示す。
下記の表6に掲げた組成を有する化粧料を調製し、水浴時間を30分間とした場合の、水浴前後の吸光度変化率を求めた。結果を表6に示す。
Claims (6)
- (A)紫外線防御剤、及び
(B)常温で固形の脂肪酸を含有し、
前記脂肪酸の中和率が51%以下であって、
(A)紫外線防御剤と(B)常温で固形の脂肪酸との配合量比率((A)/(B))が、0.1以上10.0未満の範囲内である水中油型乳化日焼け止め化粧料。 - (C)IOBが0.5以上の油分をさらに含有する、請求項1に記載の化粧料。
- 前記(C)IOBが0.5以上の油分が、アルキレンオキシド誘導体から選択される一種又は二種以上である、請求項2に記載の化粧料。
- 前記アルキレンオキシド誘導体が、ポリオキシエチレン/ポリオキシプロピレンジメチルエーテル及びポリアルキレングリコールから選択される一種又は二種以上である、請求項3に記載の化粧料。
- 前記アルキレンオキシド誘導体が、ポリオキシエチレン(14)ポリオキシプロピレン(7)ジメチルエーテル及び/又はポリエチレングリコール及び/又はポリプロピレングリコール及び/又はポリオキシブチレンポリオキシプロピレングリコールを含む、請求項4に記載の化粧料。
- 前記(B)脂肪酸が、ステアリン酸、パルミチン酸、ミリスチン酸およびベヘニン酸から選択される一種または二種以上の直鎖脂肪酸である、請求項1から5のいずれか一項に記載の化粧料。
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US15/521,490 US11806412B2 (en) | 2014-10-31 | 2015-10-30 | Oil-in-water emulsion sunscreen cosmetic |
AU2015337532A AU2015337532A1 (en) | 2014-10-31 | 2015-10-30 | Oil-in-water emulsified sunblock cosmetic |
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WO2020032242A1 (ja) | 2018-08-10 | 2020-02-13 | 株式会社 資生堂 | 油性化粧料 |
WO2020032243A1 (ja) * | 2018-08-10 | 2020-02-13 | 株式会社 資生堂 | 乳化化粧料 |
JP7482775B2 (ja) * | 2018-08-10 | 2024-05-14 | 株式会社 資生堂 | 乳化化粧料 |
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RU2017116814A (ru) | 2018-11-30 |
AU2015337532A1 (en) | 2017-04-20 |
EP3213741B1 (en) | 2024-01-17 |
JP6789817B2 (ja) | 2020-11-25 |
KR102535495B1 (ko) | 2023-05-23 |
CN107072901A (zh) | 2017-08-18 |
RU2017116814A3 (ja) | 2019-02-12 |
TWI680769B (zh) | 2020-01-01 |
EP3213741A1 (en) | 2017-09-06 |
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US11806412B2 (en) | 2023-11-07 |
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