WO2016021425A1 - Colorant capillaire oxydant, procédé de production pour mélange de colorants capillaires oxydants, et procédé de colorant capillaire oxydant - Google Patents

Colorant capillaire oxydant, procédé de production pour mélange de colorants capillaires oxydants, et procédé de colorant capillaire oxydant Download PDF

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Publication number
WO2016021425A1
WO2016021425A1 PCT/JP2015/071100 JP2015071100W WO2016021425A1 WO 2016021425 A1 WO2016021425 A1 WO 2016021425A1 JP 2015071100 W JP2015071100 W JP 2015071100W WO 2016021425 A1 WO2016021425 A1 WO 2016021425A1
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Prior art keywords
agent
component
mass
oxidative hair
mixture
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PCT/JP2015/071100
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English (en)
Japanese (ja)
Inventor
久美子 長尾
顕策 井口
真也 原
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株式会社マンダム
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Priority to CN201580013149.6A priority Critical patent/CN106102702B/zh
Priority to JP2016540154A priority patent/JP6359668B2/ja
Publication of WO2016021425A1 publication Critical patent/WO2016021425A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention comprises at least a first agent containing an alkali agent and an oxidative dye and a second agent containing hydrogen peroxide, and the oxidative hair dye used by mixing the first agent and the second agent. It relates to the agent.
  • the present invention also relates to a method for producing a mixture for oxidative hair using an oxidative hair dye and a method for oxidative hair dyeing.
  • multi-component decoloring agents and oxidative hair dyes comprising a first agent containing an alkaline agent and a second agent containing hydrogen peroxide are widely used (for example, patents).
  • Reference 1 Hair is dyed by a mixture of the first agent and the second agent.
  • the decolorizing agent described in Patent Document 1 has a problem that hair damage increases because the content of hydrogen peroxide in the mixture exceeds 3% by mass.
  • An object of the present invention is to provide a method for producing an oxidative hair dye and a oxidative hair dye mixture which can reduce damage to hair, exhibit excellent dyeing power, and also have excellent storage stability. And providing an oxidative hair dyeing method.
  • the present inventors have determined that the content of hydrogen peroxide by using a compound selected from the group consisting of carbonates and bicarbonates, dialkyl phosphates, and higher alcohols as the first agent. It has been found that an oxidative hair dye exhibiting excellent dyeing power can be obtained even when the amount is reduced.
  • the present situation is that an oxidative hair dye that has little hair damage, has excellent dyeing power, and also has good storage stability has not been obtained. I found a configuration that can solve the problem.
  • the oxidative hair dye according to the present invention comprises at least a first agent and a second agent, and the first agent and the second agent are mixed and used, and the first agent comprises the following component A, The following component B, the following component C, the following component D, and the following component E are included, the said 2nd agent contains the following component X, In said 1st agent, content of the said component D is 5.5. In the mixed agent of the first agent and the second agent, the content of the component X is 1.5% by mass or more and less than 2.7% by mass.
  • Component A Compound selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine
  • Component B Compound selected from the group consisting of carbonate and bicarbonate
  • Component C Dialkyl phosphate
  • Component D Higher alcohol
  • Component E Oxidative dye
  • Component X Hydrogen peroxide
  • the pH of the mixture of the first agent and the second agent at 25 ° C. is 8.8 or more and 10.0 or less.
  • the first agent preferably contains the following component A ′ as the component A.
  • the total content of ammonia and ammonium ions in the mixture of the first agent and the second agent is preferably 0.45 mmol / g or less in terms of ammonia.
  • the second agent further includes the following component Y.
  • Component Y Nonionic surfactant
  • the first agent is creamy and the second agent is creamy.
  • the first agent and the second agent are preferably in a mass ratio of 1: 1.5 to 1.5: 1.
  • the method for producing a mixture for oxidative hair dyeing comprises the component A, the component B, the component C, the component D, and the component E, and the component D is 5.5.
  • the content of the component X is 1.5 mass% or more and less than 2.7 mass%.
  • the oxidative hair dyeing method includes the component A, the component B, the component C, the component D, and the component E, and includes the component D at 5.5% by mass or less.
  • the pH at 25 ° C. is preferably 8.8 or more and 10.0 or less.
  • the total content of ammonia and ammonium ions is 0.45 mmol / g or less in terms of ammonia. It is preferable to do.
  • the first agent and the second agent are in a mass ratio of 1: 1. It is preferable to mix the first agent and the second agent so as to be 5 to 1.5: 1.
  • the manufacturing method of the mixture for oxidative hair which concerns on this invention, and the oxidative hair dyeing method which concerns on this invention the damage to hair is reduced by being provided with the structure of this invention. And developing sufficient dyeing power for hair. Moreover, the storage stability of the first agent is also excellent.
  • the oxidative hair dye according to the present invention includes at least a first agent and a second agent.
  • the oxidative hair dye used in the method for producing the oxidative hair dye mixture according to the present invention and the oxidative hair dyeing method according to the present invention comprises at least a first agent and a second agent.
  • the first agent and the second agent are mixed and used.
  • the first agent and the second agent are mixed at the time of use (that is, at the time of dyeing hair).
  • the first agent was selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine, and the group consisting of carbonate and bicarbonate.
  • a compound, a dialkyl phosphate, a higher alcohol, and an oxidation dye are included.
  • the second agent contains hydrogen peroxide.
  • the “compound selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine” may be referred to as “component (A)”.
  • the “compound selected from the group consisting of carbonates and bicarbonates” may be referred to as “component (B)”.
  • the “dialkyl phosphate” may be referred to as “component (C)”.
  • the above “higher alcohol” may be referred to as “component (D)”.
  • the “oxidative dye” may be referred to as “component (E)”.
  • the “hydrogen peroxide” may be referred to as “component (X)”.
  • the content of the component (D) is 5.5% by mass or less
  • Content of component (X) is 1.5 mass% or more and less than 2.7 mass%.
  • the mixed agent of the first agent and the second agent is a mixed agent obtained by mixing the first agent and the second agent.
  • the method for producing a mixture for oxidative hair according to the present invention comprises a mixing step of mixing the first agent and the second agent using the oxidative hair dye to obtain a mixture.
  • the oxidative hair dyeing method according to the present invention uses the oxidative hair dye to mix the first agent and the second agent to obtain a mixture, and uses the mixture to produce hair.
  • the content of component (X) in the obtained admixture is 1.5% by mass or more and 2.7% by mass. Less than.
  • the content of hydrogen peroxide is considerably small, so that damage to the hair can be reduced.
  • the hair can be sufficiently dyed by using the component (B), the component (C), and the component (D) in combination.
  • This is not particularly limited to the following estimation, but the effect of improving the dyeing power while keeping the pH low to some extent by component (B) and the combination of component (C) and component (D) allow the admixture to penetrate into the hair.
  • the content of the component (D) is in a specific range, an increase in viscosity of the first agent over time can be suppressed, and storage stability can be improved.
  • the inventors of the present invention 1) reduce damage to hair, 2) sufficiently dye hair, and 3) increase the viscosity stability of the first agent over time and increase storage stability. We have found the above configuration that can solve the extremely difficult problem of improving all three performances.
  • the component (B) since the component (B) exhibits decoloring power, when used for hair mixed with white hair and black hair, the color of white hair dyed after dyeing and dyed black hair Difference can be reduced, and so-called familiarity with white hair is improved.
  • the oxidative hair dye which concerns on this invention can be used also for the hair which is not mixed with the white hair. Furthermore, the irritating odor at the time of use is also reduced by the effect of a component (B), a component (C), and a component (D).
  • the second agent preferably contains a nonionic surfactant.
  • nonionic surfactant may be referred to as “component (Y)”.
  • the first agent includes at least a component (A), a component (B), a component (C), a component (D), and a component (E).
  • the first agent may contain other components.
  • the second agent contains at least component (X).
  • the second agent preferably contains a component (Y).
  • the second agent may contain other components. Only 1 type may be used for a component (A), a component (B), a component (D), a component (E), a component (Y), and another component, respectively, and 2 or more types may be used together. .
  • the total content of ammonia and ammonium ions is preferably 0.20 mmol / g or more, more preferably in terms of ammonia. Is 0.25 mmol / g or more, preferably 0.45 mmol / g or less.
  • the dyeing power is further increased.
  • the decolorization power is improved and the familiarity with gray hair is further improved.
  • the irritating odor and the irritating feeling during use are further reduced.
  • Component (A) is an alkaline agent.
  • Component (A) is a compound (at least one compound) selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine, and isopropanolamine.
  • the component (A) is preferably a compound (at least one amine compound) selected from the group consisting of monoethanolamine and isopropanolamine, and monoethanolamine (hereinafter referred to as the above). More preferably, “monoethanolamine” may be referred to as component (A ′).
  • the first agent preferably contains a component (A ′) as the component (A).
  • the content of the component (A) and the content of the component (A ′) are each preferably 0.5% by mass or more, more preferably 2.0% by mass or more, preferably 7 It is 0.0 mass% or less, More preferably, it is 6.0 mass% or less.
  • the content of each of the component (A) and the component (A ′) is not less than the above lower limit, the dyeing power is further increased.
  • the hair damage is further reduced.
  • Component (B) is an alkaline agent.
  • Component (B) is a compound (at least one compound) selected from the group consisting of carbonates and bicarbonates.
  • the component (B) plays a role of improving the dyeing power and compensating for the shortage of hair dyeing power accompanying the reduction of the component (X).
  • a component (B) improves depigmenting power, it improves the familiarity of gray hair when it is used for hair in which gray hair and black hair are mixed.
  • the pH of the admixture can be kept low, so that the irritating odor and the feeling of irritation are further suppressed.
  • component (B) examples include ammonium carbonate, ammonium bicarbonate, sodium carbonate, sodium bicarbonate, potassium carbonate, potassium bicarbonate, guanidine carbonate, guanidine bicarbonate, lithium carbonate, calcium carbonate, magnesium carbonate, and barium carbonate.
  • the component (B) is preferably a compound (at least one compound) selected from the group consisting of ammonium carbonate, ammonium bicarbonate, sodium carbonate and sodium bicarbonate. .
  • the component (B) is more preferably a compound (at least one compound) selected from the group consisting of ammonium hydrogen carbonate and sodium hydrogen carbonate.
  • the component (B) is more preferably ammonium hydrogen carbonate.
  • the first agent preferably contains ammonium hydrogen carbonate as the component (B).
  • the content of the component (B), the content of a compound selected from ammonium carbonate, ammonium hydrogen carbonate, sodium carbonate and sodium hydrogen carbonate, the content of a compound selected from ammonium hydrogen carbonate and sodium hydrogen carbonate, And ammonium hydrogen carbonate content is preferably 0.03 mmol / g or more, more preferably 0.20 mmol / g or more, still more preferably 0.25 mmol / g or more, preferably 0.70 mmol / g or less, more preferably Is 0.65 mmol / g or less.
  • the staining power is further increased.
  • familiarity with gray hair is improved, and the irritating odor and feeling during use are further reduced.
  • hair damage is further reduced.
  • the carbon number of the alkyl group of component (C) is preferably 12 or more, preferably 24 or less, more preferably 20 or less.
  • the component (C) is preferably dicetyl phosphate (hereinafter sometimes referred to as “component (C ′)”).
  • the first agent preferably contains a component (C ′) as the component (C).
  • the content of the component (C) and the content of the component (C ′) are preferably 0.2% by mass or more, more preferably 0.3% by mass or more, and still more preferably 0. 0.5% by mass or more, preferably 10.0% by mass or less, more preferably 5.0% by mass or less, still more preferably 2.0% by mass or less, and particularly preferably 1.5% by mass or less.
  • the content of each of the component (C) and the component (C ′) is not less than the above lower limit, the dyeing power is further increased. Moreover, the irritating odor at the time of use is further reduced.
  • the preparation stability is further enhanced.
  • Component (D) By using a component (D) by a predetermined quantity, the viscosity of a 1st agent and a mixing agent can be raised moderately, the adhesiveness to the hair of a mixing agent can be improved, and dyeing power can be improved. In addition, the storage stability of the first agent can be improved by suppressing the increase in viscosity of the first agent over time.
  • the carbon number of component (D) is preferably 12 or more, more preferably 14 or more, preferably 22 or less, more preferably 18 or less. From the viewpoint of further improving the storage stability of the first agent and controlling the viscosity of the mixture within a better range, the component (D) is preferably an aliphatic monovalent higher alcohol.
  • component (D) examples include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, behenyl alcohol, and batyl alcohol.
  • the content of the component (D) is 5.5% by mass or less in 100% by mass of the first agent.
  • the content of the component (D) in 100% by mass of the first agent is preferably 5.0% by mass or less, more preferably 4.5% by mass. It is as follows.
  • the content of component (D) is preferably 0.5 mass from the viewpoint of making the first agent creamy and further improving the adhesion of the mixture to the hair and further improving the dyeing power. % Or more, more preferably 2.0 mass% or more, still more preferably 3.0 mass% or more.
  • Oxidative dye means both an oxidative dye precursor that develops color by its own oxidative polymerization and a coupler that develops various colors by reacting with the oxidative dye precursor.
  • oxidative dye precursor that develops color by its own oxidative polymerization
  • coupler that develops various colors by reacting with the oxidative dye precursor.
  • the said oxidation dye precursor and the said coupler only 1 type may respectively be used and 2 or more types may be used together.
  • oxidation dye precursor examples include phenylenediamines, aminophenols and diaminopyridines, and salts thereof.
  • salts examples include hydrochloride and sulfate.
  • phenylenediamines examples include p-phenylenediamine, toluene-2,5-diamine, toluene-3,4-diamine, 2,5-diaminoanisole, N-phenyl-p-phenylenediamine, N-methyl-p- Phenylenediamine, N, N-dimethyl-p-phenylenediamine, 6-methoxy-3-methyl-p-phenylenediamine, N, N-diethyl-2-methyl-p-phenylenediamine, N-ethyl-N- (hydroxy Ethyl) -p-phenylenediamine, N- (2-hydroxypropyl) -p-phenylenediamine, 2-chloro-6-methyl-p-phenylenediamine, 2-chloro-p-phenylenediamine, N, N-bis- (2-Hydroxyethyl) -p-phenylenediamine, 2,6-dich
  • aminophenols examples include paraaminophenol, orthoaminophenol, paramethylaminophenol, 2,4-diaminophenol, 5-aminosalicylic acid, 2-methyl-4-aminophenol, 3-methyl-4-aminophenol, 2 , 6-Dimethyl-4-aminophenol, 3,5-dimethyl-4-aminophenol, 2,3-dimethyl-4-aminophenol, 2,5-dimethyl-4-aminophenol, 2-chloro-4-amino Examples include phenol and 3-chloro-4-aminophenol.
  • diaminopyridines examples include 2,5-diaminopyridine.
  • Examples of the coupler include resorcin, m-aminophenol, m-phenylenediamine, 2,4-diaminophenoxyethanol, 5-amino-o-cresol, 2-methyl-5-hydroxyethylaminophenol, 2,6-diamino.
  • Examples thereof include pyridine, catechol, pyrogallol, ⁇ -naphthol, gallic acid and tannic acid, and salts thereof.
  • the content of the component (E) is appropriately adjusted in consideration of the color tone to be dyed and the dyeing power.
  • the content of the oxidation dye is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, preferably 2.0% by mass.
  • it is more preferably 1.5% by mass or less, and still more preferably 1.0% by mass or less.
  • component (X) is used in a relatively small amount in order to reduce hair damage.
  • the content of hydrogen peroxide in the mixture is generally set to 2.7% by mass or more in order to develop the dyeing power that is the basic performance.
  • the content of component (X) is set to be quite low. That is, in the present invention, in the mixture, the content of component (X) is 1.5% by mass or more and less than 2.7% by mass. Content of component (X) becomes like this. Preferably it is 1.7 mass% or more, Preferably it is 2.5 mass% or less.
  • the content of component (X) is not less than the above lower limit, the dyeing power is further increased.
  • the content of component (X) is not more than the above upper limit, hair damage is further reduced.
  • component (X) is less than 2.7% by mass in the admixture, since the components (A) to (D) are used, the dyeing power becomes sufficiently high.
  • the second agent preferably contains a component (Y) that is a nonionic surfactant.
  • Y a component that is a nonionic surfactant.
  • polyoxyalkylene alkyl ether As the component (Y), it is preferable to use polyoxyalkylene alkyl ether, glycerin fatty acid ester, polyoxyalkylene fatty acid ester, polyoxyalkylene castor oil, polyoxyalkylene hydrogenated castor oil, alkyl polyglucoside, and polyoxyalkylene alkyl ether. It is more preferable to use Specific examples of the polyoxyalkylene alkyl ether include polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene behenyl ether and polyoxyethylene octyldodecyl ether. In addition mole number of the alkylene oxide of the said polyoxyalkylene alkyl ether is not specifically limited.
  • the content of the component (Y) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, preferably 10.0% by mass or less, more preferably 7%. 0.0 mass% or less.
  • the content of the component (Y) is not less than the above lower limit and not more than the above upper limit, the storage stability of the second agent is further enhanced, and the adhesiveness of the mixture to the hair is further enhanced.
  • the first agent and the second agent each contain water.
  • the water is not particularly limited, but purified water is preferable.
  • the content of water in 100% by mass of the first agent and the content of water in 100% by mass of the second agent are not particularly limited, but each is preferably 50% by mass or more.
  • the first agent may contain a direct dye.
  • the direct dye include paranitroorthophenylenediamine, nitroparaphenylenediamine, paranitrometaphenylenediamine sulfate, 2-amino-5-nitrophenol, and picramic acid.
  • the first agent preferably further contains a reducing agent.
  • the reducing agent suppresses the color development of the oxidation dye when the first agent is exposed to the atmosphere.
  • reducing agent examples include N-acetyl-L-cysteine, L-ascorbic acid, sodium L-ascorbate, sodium sulfite, sodium pyrosulfite and thioglycolic acid. These salts may be used. As for the said reducing agent, only 1 type may be used and 2 or more types may be used together.
  • the content of the reducing agent is preferably 0.01% by mass or more, more preferably 0.05% by mass in 100% by mass of the first agent. As mentioned above, Preferably it is 2.0 mass% or less, More preferably, it is 1.0 mass% or less.
  • the second agent preferably contains a higher alcohol.
  • the second agent only one kind of the higher alcohol may be used, or two or more kinds may be used in combination.
  • the carbon number of the higher alcohol is preferably 12 or more, more preferably 14 or more, preferably 22 or less, more preferably 18 or less. From the viewpoint of further improving the stability of the first agent and the second agent, the higher alcohol is preferably an aliphatic monovalent higher alcohol.
  • Examples of the higher alcohol that can be used in the second agent include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, behenyl alcohol, and batyl alcohol. Can be mentioned.
  • the content of the higher alcohol is preferably 0.5% by mass or more, more preferably 2.0% by mass or more, in 100% by mass of the second agent. More preferably, it is 3.0% by mass or more, preferably 10.0% by mass or less, more preferably 7.0% by mass or less.
  • the first agent preferably contains a surfactant other than the component (C).
  • the second agent may contain a surfactant other than the nonionic surfactant.
  • the surfactant include an anionic surfactant, a cationic surfactant, an amphoteric surfactant, and a nonionic surfactant. As for the said surfactant, only 1 type may be used and 2 or more types may be used together.
  • anionic surfactant examples include sulfate ester type anionic surfactant, phosphate ester type anionic surfactant, phosphate ether type anionic surfactant, sulfonic acid type anionic surfactant and carboxylic acid type An anionic surfactant etc. are mentioned.
  • amphoteric surfactant glycine type amphoteric surfactant, aminopropionic acid type amphoteric surfactant, aminoacetic acid betaine type amphoteric surfactant and sulfobetaine type amphoteric surfactant, imidazolinium type amphoteric surfactant, Examples thereof include amine oxide type amphoteric surfactants and phosphobetaine type amphoteric surfactants.
  • cationic surfactant examples include quaternary ammonium salt type cationic surfactants.
  • nonionic surfactant examples include polyoxyalkylene alkyl ether, glycerin fatty acid ester, polyoxyalkylene fatty acid ester, polyoxyalkylene castor oil, polyoxyalkylene hydrogenated castor oil, and alkylpolyglucoside. It is preferable to use polyoxyalkylene alkyl ether. Specific examples of the polyoxyalkylene alkyl ether include polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene behenyl ether and polyoxyethylene octyldodecyl ether. In addition mole number of the alkylene oxide of the said polyoxyalkylene alkyl ether is not specifically limited.
  • the content of the surfactant is preferably 0.1% by mass or more, more preferably 0.5% by mass or more. Preferably, it is 10.0 mass% or less, More preferably, it is 7.0 mass% or less.
  • At least one of the first agent and the second agent may contain a thickening polymer.
  • the thickening polymer include cationized cellulose, a cationic polymer, and an anionic polymer.
  • the said thickening polymer only 1 type may be used and 2 or more types may be used together.
  • Examples of the cationized cellulose include chloride-O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose and diallyldimethylammonium chloride / hydroxyethylcellulose.
  • Examples of the cationic polymer include cationic starch, cationized guar gum derivative, diallyl quaternary ammonium salt polymer, diallyl quaternary ammonium salt / acrylic acid copolymer, diallyl quaternary ammonium salt / acrylamide copolymer, and quaternary polyvinyl.
  • Examples include pyrrolidone derivatives.
  • Specific examples of the cationic polymer include chloride-O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum, dimethyldiallylammonium chloride / acrylic acid copolymer liquid, dimethyldiallylammonium chloride / acrylamide copolymer. And quaternized derivatives of vinyl pyrrolidone and dimethylamino methacrylate with dimethyl sulfate.
  • anionic polymer examples include xanthan gum, alkyl acrylate / alkyl methacrylate / polyoxyethylene stearyl ether copolymer, alkyl acrylate / methacrylic acid polyoxyethylene behenes ether copolymer, alkyl acrylate / itaconate poly Examples thereof include oxyethylene stearyl ether copolymers and alkyl acrylate / methacrylic acid polyoxyethylene stearyl ether crosspolymers.
  • At least one of the first agent and the second agent contains hydrocarbons.
  • Each of the first agent and the second agent preferably contains hydrocarbons.
  • the said hydrocarbons only 1 type may be used and 2 or more types may be used together.
  • hydrocarbons examples include paraffin, liquid paraffin, liquid isoparaffin, squalene, and squalane. As for the said hydrocarbons, only 1 type may be used and 2 or more types may be used together.
  • each content of the hydrocarbons is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably It is 5.0 mass% or less, More preferably, it is 3.0 mass% or less.
  • the content of the hydrocarbons is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5.0% by mass or less, more preferably 3.0%. It is below mass%.
  • At least one of the first agent and the second agent contains silicone oil.
  • Each of the first agent and the second agent preferably contains silicone oil.
  • silicone oil examples include methylpolysiloxane, methylphenylpolysiloxane, methylcyclopolysiloxane, octamethylcyclotetrasiloxane, octamethylcyclopentasiloxane, decamethylcyclopentasiloxane, methylhydrogenpolysiloxane, amino-modified silicone, and polyether.
  • modified silicone examples include modified silicone.
  • the said silicone oil only 1 type may be used and 2 or more types may be used together.
  • At least one of the first agent and the second agent contains a polyhydric alcohol.
  • Each of the first agent and the second agent preferably contains a polyhydric alcohol.
  • the said polyhydric alcohol only 1 type may be used and 2 or more types may be used together.
  • polyhydric alcohol examples include polyethylene glycol, glycerin, polyglycerin, propylene glycol, dipropylene glycol, 1,3-butylene glycol, 1,2-pentanediol, and 1,2-octanediol.
  • the second agent may contain a hydrogen peroxide stabilizer.
  • a hydrogen peroxide stabilizer As the hydrogen peroxide stabilizer, only one type may be used, or two or more types may be used in combination.
  • hydrogen peroxide stabilizer examples include phenoxyethanol, phenacetin, and hydroxyethanediphosphonic acid.
  • oxidation hair dye for example, sugar alcohols such as sorbitol, maltitol and trehalose; sequestering agents; antioxidants; plant extract extracts; pigments; A preservative; a solvent or the like may be used.
  • the oxidative hair dye comprises at least the first agent and the second agent. That is, the oxidative hair dye is an oxidative hair dye kit including at least the first agent and the second agent.
  • the oxidative hair dye may further include a third agent in addition to the first agent and the second agent. Examples of the third agent include a hair rinse agent, a hair treatment agent, and a hair conditioning agent.
  • the oxidative hair dye contains the third agent and the third agent is used by mixing with the first agent and the second agent, the mixture contains the third agent, and the mixture Is obtained by mixing the first agent, the second agent and the third agent.
  • the first agent and the second agent are mixed and used as a mixture.
  • the properties of the first agent, the second agent and the mixed agent include liquid, emulsion, gel and cream.
  • the first agent is preferably creamy
  • the second agent is preferably creamy
  • the mixing The agent is preferably creamy.
  • the viscosity of the above mixture at 25 ° C. is preferably 7000 mPa ⁇ s or more, more preferably 10,000 mPa ⁇ s or more, preferably 30000 mPa ⁇ s or less, more preferably 25000 mPa ⁇ s or less.
  • the viscosity of the mixture is not less than the above lower limit and not more than the above upper limit, 1) the irritating odor at the time of use is further reduced, 2) damage to the hair is further reduced, and 3) the hair is further effective. Stained.
  • the viscosity of the admixture was measured using a B-type viscometer (manufactured by Tokimec) at 25 ° C. and rotor No. It is measured at 4, 12 rpm and 1 minute.
  • the pH of the above mixture at 25 ° C. is preferably 8.8 or more, and preferably 10.0 or less.
  • the pH at the time of mixing is not less than the above lower limit and not more than the above upper limit, the three performances of 1) reduction of irritating odor during use, 2) reduction of damage to hair, and 3) hair dyeing can be improved in a balanced manner. it can.
  • the oxidative hair dye may be mixed in a mixing container, may be mixed on a comb, or may be mixed on hair.
  • the 1st agent and the 2nd agent may be discharged in the state mixed from a separate container, and may be discharged in the state where it is not mixed from a separate container.
  • Examples of the mixing container include a mixing container including a container body and a lid having a discharge nozzle.
  • Examples of the storage container include an aerosol container.
  • the first agent and the second agent are preferably used in a mass ratio (first agent: second agent) of 1: 5 to 5: 1, and 1: 3 to More preferably, it is used in a ratio of 3: 1, and more preferably 1: 2 to 2: 1. From the viewpoint of mixing the first agent and the second agent well, and 1) reducing the irritating odor during use, 2) reducing the damage to the hair, and 3) improving the hair dyeing performance in a well-balanced manner.
  • the first agent and the second agent are preferably used in a mass ratio of 1: 1.5 to 1.5: 1.
  • the mass ratio (first agent: second agent) of the first agent and the second agent in the oxidative hair dye kit is preferably 1: 5 to 5: 1, more preferably 1: 3 to 3 : 1, more preferably 1: 2 to 2: 1, particularly preferably 1: 1.5 to 1.5: 1. That is, the above-mentioned mixed agent (mixture of the first agent and the second agent) has a mass ratio of the first agent to the second agent (first agent: second agent) of 1: 5 to 5: 1 (more The mixture is preferably 1: 3 to 3: 1, more preferably 1: 2 to 2: 1, particularly preferably 1: 1.5 to 1.5: 1.
  • the above oxidative hair dye can be used for black hair, brown hair, yellow hair and gray hair. Since it has excellent hair dyeing power, the oxidative hair dye according to the present invention can be suitably used for hair containing gray hair.
  • Examples 1 to 14 and Comparative Examples 1 to 7 The components shown in Tables 1 to 4 below were blended in the contents shown in Tables 1 to 4 below to obtain a first agent and a second agent. Specific production methods of the first agent, the second agent, and the mixed agent are as follows.
  • the contact angle of water in the untreated black human hair bundle not subjected to the dyeing treatment was 125.2 °.
  • the contact angle value is 110 ° or more, it can be determined that there is little damage to the hair.
  • ⁇ E * ab the less the color difference between the evaluation hair bundle for staining the white human hair bundle and the evaluation hair bundle for staining the black human hair bundle is better.
  • the value of ⁇ E * ab is preferably 18 or less, and when it is 17 or less, familiarity with white hair was quite good.
  • composition and evaluation results are shown in Tables 1 to 7 below.
  • the blending unit of the content of each component in the following Tables 1 to 4 is “% by mass”.

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Abstract

L'invention concerne un colorant capillaire oxydant pouvant réduire des dommages causés aux cheveux, présentant une excellente puissance de coloration, et ayant une excellente stabilité de stockage. Ce colorant capillaire oxydant comprend : un premier agent comprenant un constituant A qui est un composé choisi dans le groupe constitué d'ammoniac, de monoéthanolamine, de diéthanolamine, de triéthanolamine et d'isopropanolamine, un constituant B qui est un composé choisi dans le groupe constitué de carbonate et de carbonate d'hydrogène, un constituant C qui est du phosphate de dialkyle, un constituant D qui est un alcool supérieur, et un constituant E qui est un colorant oxydant ; et un second agent comprenant un constituant X qui est du peroxyde d'hydrogène. La teneur en constituant D dans le premier agent n'est pas supérieure à 5,5 % en masse, et la teneur en constituant X dans un mélange du premier agent et du second agent est au moins 1,5 % en masse et inférieure à 2,7 % en masse.
PCT/JP2015/071100 2014-08-08 2015-07-24 Colorant capillaire oxydant, procédé de production pour mélange de colorants capillaires oxydants, et procédé de colorant capillaire oxydant WO2016021425A1 (fr)

Priority Applications (2)

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CN201580013149.6A CN106102702B (zh) 2014-08-08 2015-07-24 氧化染发剂、氧化染发用混合剂的制造方法以及氧化染发方法
JP2016540154A JP6359668B2 (ja) 2014-08-08 2015-07-24 酸化染毛剤、酸化染毛用混合剤の製造方法、及び酸化染毛方法

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PCT/JP2015/071100 WO2016021425A1 (fr) 2014-08-08 2015-07-24 Colorant capillaire oxydant, procédé de production pour mélange de colorants capillaires oxydants, et procédé de colorant capillaire oxydant

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JP2017160198A (ja) * 2016-03-08 2017-09-14 クローダジャパン株式会社 毛髪用染毛剤
JP2020132554A (ja) * 2019-02-18 2020-08-31 株式会社ダリヤ エアゾール型染毛剤または脱色剤組成物
JP2020132555A (ja) * 2019-02-18 2020-08-31 株式会社ダリヤ エアゾール型染毛剤または脱色剤組成物

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JP7146520B2 (ja) * 2017-09-20 2022-10-04 花王株式会社 粉末状組成物
SG11202003730WA (en) * 2017-10-27 2020-05-28 Amorepacific Corp Oxidation type hair dye composition
JP7396622B2 (ja) * 2019-09-06 2023-12-12 ホーユー株式会社 酸化染毛剤組成物及び染毛方法
CN111920695A (zh) * 2020-09-12 2020-11-13 四川大学 一种染发剂、其制备方法及使用方法

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JP2002370949A (ja) * 2001-06-12 2002-12-24 Hoyu Co Ltd 脱色剤組成物及び染毛剤組成物
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JP7033391B2 (ja) 2016-03-08 2022-03-10 クローダジャパン株式会社 毛髪用染毛剤
JP2020132554A (ja) * 2019-02-18 2020-08-31 株式会社ダリヤ エアゾール型染毛剤または脱色剤組成物
JP2020132555A (ja) * 2019-02-18 2020-08-31 株式会社ダリヤ エアゾール型染毛剤または脱色剤組成物
JP7164875B2 (ja) 2019-02-18 2022-11-02 株式会社ダリヤ エアゾール型染毛剤または脱色剤組成物
JP7164876B2 (ja) 2019-02-18 2022-11-02 株式会社ダリヤ エアゾール型染毛剤または脱色剤組成物

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JP6359668B2 (ja) 2018-07-18
CN106102702B (zh) 2019-09-17
CN106102702A (zh) 2016-11-09
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