WO2015166944A1 - 角型蓄電デバイス、および角型蓄電デバイスの製造方法 - Google Patents
角型蓄電デバイス、および角型蓄電デバイスの製造方法 Download PDFInfo
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- WO2015166944A1 WO2015166944A1 PCT/JP2015/062815 JP2015062815W WO2015166944A1 WO 2015166944 A1 WO2015166944 A1 WO 2015166944A1 JP 2015062815 W JP2015062815 W JP 2015062815W WO 2015166944 A1 WO2015166944 A1 WO 2015166944A1
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- insulating sheet
- electrode group
- case
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- negative electrode
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
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- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/103—Primary casings; Jackets or wrappings characterised by their shape or physical structure prismatic or rectangular
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M50/10—Primary casings; Jackets or wrappings
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/463—Separators, membranes or diaphragms characterised by their shape
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/528—Fixed electrical connections, i.e. not intended for disconnection
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/584—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
- H01M50/586—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries inside the batteries, e.g. incorrect connections of electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/584—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
- H01M50/59—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries characterised by the protection means
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a rectangular electricity storage device in which an electrode group is a laminate in which sheet-like positive electrodes and negative electrodes are alternately laminated, or a wound body in which sheet-like positive electrodes and negative electrodes are overlapped and wound. It relates to a manufacturing method.
- Conventional square electricity storage devices are, for example, a laminate in which a sheet-like positive electrode and a negative electrode are alternately stacked with a separator between them, and a positive electrode and a negative electrode are stacked with a separator between them. It has the electrode group which consists of the wound body wound together.
- the “rectangular power storage device” includes a power storage device having a prismatic shape close to a rectangular parallelepiped, and a power storage device having a flat prismatic shape with rounded sides and corners.
- the shape of the case of the square electricity storage device generally corresponds to the shape of the electrode group. If the electrode group is a laminate, the shape of the electrode group is a prismatic shape close to a rectangular parallelepiped. Therefore, the outer shape of the square electricity storage device is also close to a rectangular parallelepiped. If the electrode group is a wound body, the shape of the electrode group is a prismatic shape having curved surfaces on both sides. For this reason, the external shape of the square electricity storage device also has a shape having curved surfaces on both sides.
- the electrode group is inserted into a rectangular case having an opening. After the electrode group is inserted into the case, a sealing plate is attached to the opening of the case. Thereafter, an electrolyte is injected into the case from the hole provided in the sealing plate. Thereafter, through a process such as deaeration, the hole of the sealing plate is closed, and the square electricity storage device is sealed.
- the case is usually made of metal and has electrical conductivity.
- the conductive case may have either a positive polarity or a negative polarity or may not have any polarity.
- the insulating sheet can be formed into a bag shape so as to accommodate the electrode group. At this time, for example, one insulating sheet is folded in half, and the peripheral portions of the overlapping portions are joined together by heat welding to form a bag shape. Alternatively, two insulating sheets are overlapped and their peripheral portions are joined together by heat welding to form a bag.
- the joining method is not limited to thermal welding.
- the four side surfaces of the prismatic electrode group are covered with a heat-shrinkable tube, and a bottom insulating plate is disposed between the lower surface (bottom surface) of the electrode group and the bottom of the case. Thereby, it is also generally performed to prevent an internal short circuit of the electricity storage device.
- an electrode group and a case are insulated by forming a bag from an insulating sheet by thermal welding and accommodating the electrode group therein.
- the electrode group and the case are insulated using a heat shrinkable tube and a bottom insulating plate.
- One aspect of the present invention includes a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode, and a prismatic electrode group having an upper surface, a lower surface, and four side surfaces, Electrolyte, A case having an opening and containing the electrode group and the electrolyte; A sealing plate for sealing the opening of the case; An insulating sheet that is interposed between the electrode group and the case and electrically insulates the electrode group and the case;
- the present invention relates to a rectangular electricity storage device in which the insulating sheet is folded so as to surround the lower surface and the four side surfaces of the electrode group.
- a prismatic electrode group including (a) a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode, and having an upper surface, a lower surface, and four side surfaces. And a process of (B) preparing an electrolyte; (C) providing an opening and preparing a case for accommodating the electrode group and the electrolyte; (D) preparing a sealing plate for sealing the opening of the case; (E) preparing an insulating sheet interposed between the electrode group and the case to electrically insulate the electrode group and the case; (F) folding the insulating sheet so as to surround the lower surface and the four side surfaces of the electrode group; (G) installing the electrode group and the folded insulating sheet inside the case in a state where the insulating sheet is interposed between the electrode group and the case.
- the present invention relates to a device manufacturing method.
- FIG. 2 is an arrow cross-sectional view of a subgroup of an electrode group taken along line I1-I1 of FIG. It is a top view of the state which developed the insulating sheet. It is a perspective view which shows the 1st process of the process which folds an insulating sheet so that the lower surface and four side surfaces of an electrode group may be surrounded by an insulating sheet. It is a perspective view which shows the 2nd process of the process which folds an insulating sheet so that the lower surface and four side surfaces of an electrode group may be surrounded by an insulating sheet.
- a prismatic power storage device includes a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode, and a prismatic electrode group having an upper surface, a lower surface, and four side surfaces.
- the insulating sheet is folded so as to surround the lower surface and the four side surfaces of the electrode group. Two or more insulating sheets may be used.
- rectangular column shape includes a rectangular parallelepiped shape, a shape close to a rectangular parallelepiped with rounded sides and corners, and the like. If the electrode group is prismatic, the electrode group has an upper surface, a lower surface, and four side surfaces. The electrode group can be inserted through the opening of the case. The opening of the case can be closed by a lid-like sealing plate, for example.
- the insulating sheet for insulating the electrode group and the case is not formed in a bag for housing the electrode group by thermal welding or the like.
- the insulating sheet is simply folded so as to cover the lower surface and the four side surfaces of the electrode group.
- Such a process can be easily incorporated into the assembly line of the square electricity storage device. Therefore, according to the present embodiment, it is possible to simplify the manufacture of the rectangular electricity storage device. In addition, it is possible to suppress an increase in the size of the manufacturing facility for the rectangular electricity storage device and the complexity of the manufacturing process. Therefore, it becomes easy to reduce the manufacturing cost of the rectangular electricity storage device.
- the number of insulating sheets for covering the lower surface and the four side surfaces of the electrode group is preferably one from the viewpoint of reducing the number of parts of the power storage device and simplifying the production.
- one of them covers a part (for example, half) of the electrode group to be covered, and the other one covers the remaining part of the electrode group to be covered. it can.
- the part which should cover the electrode group can also be divided and covered using three or more insulating sheets.
- the insulating sheet is not limited to a single layer structure, and may be a multilayer structure in which two or more layers of materials are stacked. Two or more insulating sheets may be used in an overlapping manner.
- all four side surfaces of the electrode group are covered with an insulating sheet. However, portions that are not directly facing the case on the four side surfaces of the electrode group may not be covered with the insulating sheet.
- the insulating sheet can also cover at least a part of the upper surface of the electrode group.
- the lower surface of the electrode group is preferably covered with an insulating sheet.
- the electrode group is, for example, a laminate in which a sheet-like positive electrode and a negative electrode are stacked with a separator interposed therebetween, or a wound body in which a positive electrode and a negative electrode are wound with a separator interposed therebetween. It can be. If the electrode group is a laminate, the shape thereof is typically a prismatic shape close to a rectangular parallelepiped (see FIG. 1).
- the insulating sheet is basically only folded, and does not have a welded portion that joins a part of the insulating sheet and the other part. Moreover, when using two or more insulating sheets, it does not have the welding part which joins the said insulating sheet and another insulating sheet. However, you may make it keep the shape of the folded insulating sheet, for example using an adhesive tape.
- the material of the insulating sheet is not particularly limited, but it is preferable to use an insulating resin.
- resins include polyolefins such as polyethylene (PE), polypropylene (PP), and ethylene-propylene copolymers; polyester resins such as polyethylene terephthalate (PET), polybutylene terephthalate (PBT), and polycarbonate (PC); polysulfone (PS), polyethersulfone (PES), polyphenylene ether (PPE) and other polyether resins, polyphenylene sulfide (PPS), polyphenylene sulfide ketone and other polyphenylene sulfide resins; aromatic polyamide resins (aramid resins, etc.) and other polyamide resins Polyimide resin; cellulose resin, etc. can be used. These may be used alone or in combination of two or more.
- the insulating sheet can be formed of a fluororesin.
- the prismatic power storage device when the prismatic power storage device is a molten salt battery, the prismatic power storage device can be used in a relatively high temperature range (eg, 0 to 90 ° C.). Fluororesin has high heat resistance. For this reason, also when a square electrical storage device is used in a comparatively high temperature range, it can prevent that an insulating sheet softens with a heat
- the rectangular electricity storage device when used in a temperature range of, for example, 80 ° C. or less, it is not necessary to use a material having a particularly high heat resistance for the insulating sheet. It can be formed from PE.
- an insulating sheet formed of a fluororesin into a bag shape by welding.
- the insulating sheet is not formed into a bag shape by welding, but is simply folded so as to surround the electrode group. Therefore, according to this embodiment, since the welding is difficult, the fluororesin that has been difficult to use in this application can be easily used as the material for the insulating sheet.
- the fluororesin may be a homopolymer or copolymer having a fluorine-containing monomer unit.
- a fluororesin examples include polytetrafluoroethylene (PTFE), tetrafluoroethylene-hexafluoropropylene copolymer, tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA), and tetrafluoroethylene-ethylene copolymer.
- PTFE polytetrafluoroethylene
- PFA tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer
- PVDF polyvinylidene fluoride
- PVF polyvinyl fluoride
- the melting point of the fluororesin is preferably 200 ° C. or higher.
- the type of power storage device to which the present invention is applied is not particularly limited.
- the present invention can be applied to an electricity storage device using a nonaqueous electrolyte such as an alkali metal ion secondary battery and an alkali metal ion capacitor, and an electricity storage device using an aqueous electrolyte such as an alkaline storage battery, a lead storage battery, and an electric double layer capacitor.
- the present invention is preferably applied to sodium ion secondary batteries, lithium ion secondary batteries, sodium ion capacitors, lithium ion capacitors, and the like.
- a Faraday reaction involving alkali metal ions proceeds at the positive electrode and the negative electrode of an alkali metal ion secondary battery.
- alkali metal ion capacitor a non-Faraday reaction in which an anion in the electrolyte is adsorbed proceeds at the positive electrode, and a Faraday reaction in which an alkali metal ion participates proceeds at the negative electrode.
- the electrolyte can contain an organic electrolyte, a molten salt, and / or an additive.
- the organic electrolyte includes an organic solvent and an alkali metal salt that dissolves in the organic solvent.
- a molten salt is synonymous with a salt in a molten state, and is also referred to as an ionic liquid.
- An ionic liquid is a liquid ionic substance composed of an anion and a cation. When the electricity storage device is used at a relatively high temperature, 90% by mass or more of the electrolyte is preferably a molten salt.
- the electricity storage device when used mainly in a normal temperature range (for example, ⁇ 5 to 40 ° C.), 80% by mass or more of the electrolyte is preferably an organic electrolyte, and 50% by mass or more of the electrolyte is an organic solvent. It is preferable.
- a lithium ion secondary battery and / or a lithium ion capacitor in which the main component of the electrolyte is an organic solvent is used in a normal temperature range (for example, ⁇ 5 to 40 ° C.).
- a normal temperature range for example, ⁇ 5 to 40 ° C.
- polyolefins such as PE and PP can be suitably used as the material for the insulating sheet.
- PE or PP can be suitably used as a material for the insulating sheet.
- the thickness DT1 of the insulating sheet is preferably 0.05 to 0.2 mm.
- the thickness DT2 of the insulating sheet is preferably 0.05 to 0.5 mm.
- resin sheet as described above, cellulose, paper, and the like can be used for the insulating sheet.
- a rectangular (including square) sheet can be preferably used as the insulating sheet. At this time, it is also conceivable to cut off a surplus portion (for example, a triangular portion between the region A3 and the region A5 in FIG. 3) when folded. However, from the viewpoint of maintaining sufficient strength of the insulating sheet, it is preferable to leave such a part without cutting.
- the insulating sheet When the insulating sheet is a rectangle having a first side and a second side orthogonal to the first side, the insulating sheet includes a central portion of the insulating sheet and covers the lower surface of the electrode group, and the lower surface of the insulating sheet faces the lower side. Folded at each of the two sides and folded at the boundary between the second region covering two of the four side surfaces of the electrode group and the other two opposite sides and the four side surfaces of the bottom surface of the electrode group, A third region covering the other two of the side surfaces.
- the positive electrode external terminal and the negative electrode external terminal can be disposed on the sealing plate in a state of being electrically insulated from each other.
- the positive electrode and the positive electrode external terminal can be electrically connected by a positive electrode lead piece.
- the negative electrode and the negative electrode external terminal can be electrically connected by a negative electrode lead piece.
- the partition member is preferably three-dimensional.
- the partition member includes a bottom plate disposed so as to face the electrode group, and at least one vertical plate provided continuously with a peripheral portion of the bottom plate.
- the bottom plate includes a first hole through which the positive electrode lead piece is inserted and a second hole through which the negative electrode lead piece is inserted.
- At least one vertical plate is interposed between the positive electrode lead piece and / or the negative electrode lead piece and the case.
- a method for manufacturing a rectangular electricity storage device includes (a) a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode, and includes an upper surface, a lower surface, and four side surfaces.
- a step of preparing a prismatic electrode group having: (b) a step of preparing an electrolyte; (c) a step of preparing a case having an opening and containing the electrode group and the electrolyte; and (d) a case A step of preparing a sealing plate for sealing the opening of the electrode, and (e) a step of preparing an insulating sheet interposed between the electrode group and the case to insulate the electrode group and the case; and (f) an insulating sheet.
- steps (a) to (g) can all be incorporated in the assembly line of the conventional square electricity storage device. Therefore, it is not necessary to greatly modify the line for manufacturing the rectangular electricity storage device.
- the insulating sheet is typically a rectangle (a broad rectangle, including a square) having a first side and a second side orthogonal to the first side.
- the lower surface of the electrode group is a rectangle having a long side and a short side (a narrow rectangle)
- the length of the first side of the insulating sheet is set to the length of the long side of the lower surface of the electrode group (electrode group).
- the maximum width That is, at least one of the two orthogonal sides of the insulating sheet is made larger than the maximum width of the electrode group.
- the insulating sheet is a narrow rectangle, at least the long side is made larger than the maximum width of the electrode group.
- the insulating sheet is square, the length of all sides of the insulating sheet is made larger than the maximum width of the electrode group.
- the length of the short side (X1, see FIG. 3) of the insulating sheet is made longer than the maximum width of the electrode group (long side of the lower surface). Enlarge.
- the square electricity storage device is an electricity storage device 110 having a horizontally long case 14A as shown in FIG. 8 and the width W1 of the electrode group 12A exceeds twice the height H1
- the maximum width (W1) of the electrode group becomes larger than the length of the short side of the insulating sheet.
- the length of the long side of the insulating sheet is made larger than the maximum width of the electrode group.
- step (f) the long side of the lower surface of the electrode group and the second side Y1 of the insulating sheet are orthogonal to each other (see FIG. 3), and the center of the lower surface is positioned at the center of the insulating sheet.
- the bottom surface of the electrode group and the insulating sheet are brought into contact with each other, (f2) the insulating sheet is folded back at the two long sides of the bottom surface, (f3) the insulating sheet is folded at the two short sides of the bottom surface, (f4) )
- Each procedure of folding the insulating sheet at each of the four side boundaries is performed.
- the procedure (f3) and the procedure (f4) the procedure (f3) can be performed first or the procedure (f4) can be performed first.
- the procedure (f3) is performed first.
- the angle formed by the long side of the lower surface of the electrode group and the second side of the insulating sheet is strictly 90 degrees. If the angle is an angle close to 90 degrees (for example, 80 to 100 degrees), it can be considered that the long side of the lower surface of the electrode group and the second side of the insulating sheet are orthogonal to each other. Further, “the center of the lower surface of the electrode group is located at the center of the insulating sheet” does not mean that the positions of the two are completely coincident. If the deviation between the two is small (for example, 5 mm or less), it can be considered that the center of the lower surface of the electrode group is located at the center of the insulating sheet.
- FIG. 1 is an exploded perspective view showing a schematic configuration of a rectangular electricity storage device according to an embodiment of the present invention.
- the prismatic electricity storage device 10 in the illustrated example is a prismatic sodium ion secondary battery or a lithium ion capacitor, and includes a prismatic electrode group 12, a prismatic case 14 having an opening, and an opening of the case 14. And a sealing plate 16 for sealing.
- the case 14 and the sealing plate 16 are made of metal and have conductivity.
- An insulating partition member 18 is disposed between the upper surface of the electrode group 12 and the sealing plate 16.
- An insulating sheet 20 is disposed between the electrode group 12 and the case 14.
- a part of the insulating sheet 20 is notched and the upper portions of the four side surfaces of the electrode group 12 are exposed from the insulating sheet 20. Yes.
- the four side surfaces of the electrode group 12 are actually covered with the insulating sheet 20 up to the upper end portion.
- the sealing plate 16 can be provided with a positive external terminal 40 and a negative external terminal 42.
- the positive external terminal 40 is disposed at a position near one end in the longitudinal direction (Y-axis direction) of the sealing plate 16, and the negative external terminal 42 is disposed at a position near the other end. Those external terminals are electrically insulated from the sealing plate 16.
- a degassing valve 44 (for example, a break valve) for releasing the gas inside the case when the internal pressure of the case 14 abnormally rises can be installed at the center of the sealing plate 16.
- a pressure regulating valve 46 and a liquid injection hole 48 can be provided in the vicinity of the gas vent valve 44.
- the liquid injection hole 48 is a hole for injecting the electrolyte into the case 14 after the sealing plate 16 is attached to the opening of the case 14.
- the liquid injection hole 48 is closed by a liquid stopper (not shown).
- the electrode group 12 is formed from a laminate in which positive and negative electrodes are alternately stacked, and has an upper surface, a lower surface, and four flat side surfaces.
- the positive electrode and the negative electrode constituting the electrode group 12 will be described in detail later.
- the outer shape of the electrode group 12 is a prismatic shape close to a rectangular parallelepiped.
- the electrode group 12 includes a plurality (four in the illustrated example) of subgroups 12a, 12b, 12c, and 12d.
- FIG. 2 is a sectional view showing one subgroup of the electrode group.
- This cross-sectional view is a cross-sectional view when the subgroup 12a is cut along a plane including the line I1-I1 of FIG. 1 and perpendicular to the Y-axis. Note that the number of electrodes (positive electrode, negative electrode) shown in the figure does not necessarily match the number of electrodes actually included in the subgroup 12a.
- the configurations of the other subgroups 12b to 12d are the same as the configuration of the subgroup 12a.
- the subgroup 12a of the electrode group 12 is configured by alternately laminating a plurality of positive electrodes 22 and a plurality of negative electrodes 24 housed in, for example, a bag-shaped separator 21.
- the positive electrode 22 includes a positive electrode current collector and a positive electrode active material.
- the negative electrode 24 includes a negative electrode current collector and a negative electrode active material. In FIG. 2, the positive electrode current collector, the negative electrode current collector, the positive electrode active material, and the negative electrode active material are not shown separately from the electrodes.
- a lead piece (positive electrode lead piece) 26 is attached to the upper end of each of the plurality of positive electrodes 22 (or positive electrode current collectors).
- the positive electrode lead piece 26 may be formed integrally with the positive electrode 22 or the positive electrode current collector.
- the lead pieces of the plurality of positive electrodes 22 of the subgroup 12a are bundled and welded together, for example, so that the positive electrodes 22 are connected in parallel.
- a portion 26A in which the positive electrode lead pieces 26 are bundled (hereinafter referred to as a positive electrode lead piece bundle portion) 26A is connected to a conductive positive electrode connecting member 30 (see FIG. 1), and is connected to the positive electrode external terminal 40 via the positive electrode connecting member 30. Electrically connected.
- Each of the other subgroups 12b to 12d also has a positive lead piece bundle portion 26A.
- These positive electrode lead piece bundle portions 26 ⁇ / b> A are also connected to the positive electrode connecting member 30 and connected to the positive electrode external terminal 40 through the positive electrode connecting member 30.
- a lead piece (negative electrode lead piece) 28 is attached to each upper end portion of the plurality of negative electrodes 24 (or negative electrode current collectors).
- the negative electrode lead piece 28 may be formed integrally with the negative electrode 24 at the upper end of the negative electrode 24 or the negative electrode current collector.
- the plurality of negative electrodes 24 are connected in parallel by bundling the lead pieces of the plurality of negative electrodes 24 of the subgroup 12a and, for example, welding them together.
- a portion in which the negative electrode lead pieces 28 are bundled (hereinafter referred to as a negative electrode lead piece bundle portion) 28A is connected to a conductive negative electrode connecting member 32 (see FIG. 1), and is connected to the negative electrode external terminal 42 via the negative electrode connecting member 32. Electrically connected.
- the other subgroups 12b to 12d each have a negative electrode lead piece bundle portion 28A.
- the negative electrode lead piece bundle portion 28 ⁇ / b> A is also connected to the negative electrode connecting member 32 and connected to the negative electrode external terminal 42 via the negative electrode connecting member 32.
- the partition wall member 18 includes a positive electrode lead piece bundle portion 26A, a negative electrode lead piece bundle portion 28A, a positive electrode connection member 30 and a negative electrode connection member 32, and an upper surface of the electrode group 12 so as to prevent contact with the conductive case 14. Between the sealing plate 16 and the sealing plate 16.
- the partition wall member 18 includes a bottom plate 18a having a substantially rectangular outer shape, and four vertical plates 18b erected perpendicularly to the bottom plate 18a from four sides of the bottom plate 18a.
- the bottom plate 18a and the four vertical plates 18b can be integrally formed.
- the boundary between the bottom plate 18a and the vertical plate 18b is preferably formed in a groove-like thin portion so that it can be easily bent. Thereby, the three-dimensional partition member 18 can be easily formed from one board
- the bottom plate 18a has a first hole 18c through which each positive electrode lead piece bundle portion 26A of the subgroups 12a to 12d is inserted, and a second hole through which each negative electrode lead piece bundle portion 28A of the subgroups 12a to 12d is inserted. 18d. Since the four vertical plates 18b surround the positive electrode lead piece bundle portion 26A, the negative electrode lead piece bundle portion 28A, the positive electrode connection member 30, and the negative electrode connection member 32, contact between these conductive members and the case 14 is prevented.
- FIG. 3 is a plan view showing the insulating sheet in a developed state.
- the insulating sheet 20 has, for example, a rectangular shape.
- the insulating sheet 20 includes four regions, an area A1 (which is a first area) covering the lower surface of the prismatic electrode group 12 and a prismatic electrode group 12.
- a region A2 (a second region) covering two opposing side surfaces of the side surfaces, a region A3, a region A4 covering the other two side surfaces of the four side surfaces of the prismatic electrode group 12, and
- an area A5 (the three areas A3 to A5 are the third area).
- the region A1 includes the central portion of the insulating sheet 20.
- the insulating sheet 20 is formed with a first fold F1 corresponding to each of two opposing sides of the lower surface of the electrode group 12, and a second fold F2 corresponding to each of the other two opposing sides of the lower surface. .
- a region surrounded by the two first folds F1 and the two second folds F2 is a region A1.
- the two first folds F1 are perpendicular to the second side Y1 (long side in the illustrated example) of the insulating sheet 20.
- the two second folds F2 are perpendicular to the first side X1 (short side in the illustrated example) of the insulating sheet 20.
- third folds F3 are formed on the insulating sheet 20 along an extension line extending the two first folds F1 toward the second side Y1.
- a region surrounded by one second fold line F2 and two third fold lines F3 adjacent thereto is a region A3.
- fourth folds F4 are formed in the insulating sheet 20 along a line segment that forms an angle of 45 degrees with the third fold F3.
- fifth folds F5 respectively corresponding to the boundary lines of the four side surfaces of the electrode group 12 are formed on the insulating sheet 20.
- FIGS. 4A to 4E are perspective views showing an example of the process of folding the insulating sheet so as to surround the lower surface and the four side surfaces of the electrode group. Note that the process of folding the insulating sheet is not limited to the process shown in FIGS. 4A to 4E.
- an intermediate product 34 including an electrode group 12, a sealing plate 16, and a partition member 18 on a rectangular insulating sheet 20 unwound from a roll and cut to a predetermined length, for example. Put. At this time, the intermediate product 34 is placed on the insulating sheet 20 so that the entire lower surface of the electrode group 12 faces the region A1 of the insulating sheet 20.
- the plurality of positive electrode lead piece bundle portions 26 ⁇ / b> A and the positive electrode connection member 30 are joined, and all the positive electrodes of the electrode group 12 are electrically connected to the positive electrode external terminal 40.
- the plurality of negative electrode lead piece bundle portions 28 ⁇ / b> A and the negative electrode connection member 32 are joined, and all the negative electrodes of the electrode group 12 are electrically connected to the negative electrode external terminal 42.
- the electrode group 12 has a pair of opposing side surfaces SF1 having a relatively large area and another pair of opposing side surfaces SF2 having a small area.
- the insulating sheet 20 is folded back at each of the two first folds F1. Thereby, the two side surfaces SF ⁇ b> 1 of the electrode group 12 are covered with the two regions A ⁇ b> 2 of the insulating sheet 20.
- the insulating sheet 20 is folded back at two second folds F2. Accordingly, the lower portions of the two side surfaces SF2 are covered with the two regions A3 of the insulating sheet 20. At this time, the insulating sheet 20 is creased by four third folds F3 and creased by four fourth folds F4.
- the insulating sheet 20 is folded at two fifth folds F5 (F5A) around one area A2. Thereby, most of the remaining part which is not covered with area
- F5A fifth folds
- the insulating sheet 20 is folded at two fifth folds F5 (F5B) around the other region A2 (not visible in the figure). Thereby, the remaining part which is not covered with area
- FIG. 4E Through the above insulating sheet folding step, the lower surface and the four side surfaces of the electrode group 12 constituting the intermediate product 34 are all covered with the insulating sheet 20. Note that the procedure shown in FIGS. 4D and 4E can be performed prior to the procedure shown in FIG. 4C. In this case, contrary to the state shown in FIG. 4E, the region A3 is overlaid on the lower portions of the regions A4 and A5.
- FIG. 6 shows a state in which the electrode group constituting the intermediate product and the partition member are housed in the case.
- the sealing plate 16 is attached to the opening of the case 14 by, for example, welding the outer peripheral portion of the sealing plate 16 to the opening of the case 14.
- an electrolyte is injected into the case 14 through the injection hole 48. After the injection of the electrolyte is completed, the injection hole 48 is closed and the case 14 is sealed.
- FIG. 7 shows an example of the outer shape of the electrode group when the electrode group is a wound body in which a positive electrode and a negative electrode are wound with a separator interposed therebetween.
- a wound body 100 shown in the figure includes an upper surface 101, a lower surface 102, two parallel and flat side surfaces 103 and 104, and a pair of side surfaces 105 and 106 whose surfaces are curved.
- the electrode group may be composed of one wound body 100, or the plurality of subgroups may be composed of one wound body 100, and the electrode group may be composed of a plurality of subgroups. Good.
- the positive electrode 22 or the negative electrode 24 is formed by, for example, applying or filling an electrode mixture on a current collector made of a metal foil or a metal porous body, and compressing the current collector and the electrode mixture in the thickness direction as necessary. Is done.
- the electrode mixture includes an active material as an essential component, and may include a conductive additive and / or a binder as an optional component.
- a negative electrode active material of a sodium ion secondary battery a material that reversibly absorbs and releases sodium ions can be used.
- examples of such materials include carbon materials, spinel type lithium titanium oxide, spinel type sodium titanium oxide, silicon oxide, silicon alloy, tin oxide, and tin alloy.
- the carbon material non-graphitizable carbon (hard carbon) is preferable.
- the negative electrode active material of the lithium ion capacitor a material that reversibly absorbs and releases lithium ions can be used. Examples of such materials include carbon materials, spinel type lithium titanium oxide, silicon oxide, silicon alloy, tin oxide, and tin alloy.
- As the carbon material graphite, non-graphitizable carbon, graphitizable carbon and the like are preferable.
- a transition metal compound that reversibly absorbs and releases sodium ions is preferably used.
- a sodium-containing transition metal oxide for example, NaCrO 2
- a porous material for example, activated carbon
- the electrolyte used for the sodium ion secondary battery preferably contains a molten salt.
- the molten salt includes a salt of sodium ion and anion (first anion).
- first anion examples include a fluorine-containing acid anion (PF 6 ⁇ , BF 4 ⁇ and the like), a chlorine-containing acid anion (ClO 4 ⁇ ), a bissulfonylamide anion, a trifluoromethanesulfonic acid anion (CF 3 SO 3 ⁇ ) and the like.
- PF 6 ⁇ fluorine-containing acid anion
- ClO 4 ⁇ chlorine-containing acid anion
- CF 3 SO 3 ⁇ trifluoromethanesulfonic acid anion
- the electrolyte used for the sodium ion secondary battery can contain an organic solvent and / or an additive in addition to the molten salt. From the viewpoint of improving heat resistance, the electrolyte is 90% by mass or more, and further 100% by mass. It is preferably occupied by a molten salt (an ionic substance composed of an anion and a cation).
- a molten salt an ionic substance composed of an anion and a cation
- the molten salt preferably contains an organic cation in addition to sodium ions as a cation.
- organic cations include nitrogen-containing cations, sulfur-containing cations, and phosphorus-containing cations.
- the counter anion (second anion) of the organic cation is preferably a bissulfonylamide anion.
- bissulfonylamide anion examples include bis (fluorosulfonyl) amide anion ((N (SO 2 F) 2 ⁇ ) (FSA ⁇ : bis (fluorosulfonyl) amide anion)); bis (trifluoromethylsulfonyl) amide anion (N ( SO 2 CF 3 ) 2 ⁇ ) (TFSA ⁇ : bis (trifluoromethylsulfonyl) amide anion), (fluorosulfonyl) (trifluoromethylsulfonyl) amide anion (N (SO 2 F) (SO 2 CF 3 ) ⁇ ) ((fluorosulfonyl) ) (trifluoromethylsulfonyl) amide anion).
- nitrogen-containing cations examples include quaternary ammonium cations, pyrrolidinium cations, imidazolium cations, and the like.
- Examples of the quaternary ammonium cation include tetraalkylammonium cations such as tetraethylammonium cation (TEA + : tetraethylammonium cation) and triethylmethylammonium cation (TEMA + : methyltriethylammonium cation) (particularly tetra-C 1-5 alkylammonium cation). Etc. can be exemplified.
- Examples of the pyrrolidinium cation include 1-methyl-1-propylpyrrolidinium cation (Py13 + ), 1-butyl-1-methylpyrrolidinium cation (Py14 + : 1-butyl).
- imidazolium cation examples include 1-ethyl-3-methylimidazolium cation (EMI + ), 1-butyl-3-methylimidazolium cation (BMI + : 1-buthyl-3-cation). methylimidazolium cation).
- the proportion of sodium ions in the total of sodium ions and organic cations contained in the molten salt is preferably 10 mol% or more, and more preferably 30 mol% or more. Moreover, it is preferable that it is 90 mol% or less, and it is still more preferable that it is 80 mol% or less.
- the organic electrolyte includes an organic solvent and a lithium salt that dissolves in the organic solvent.
- the lithium salt include LiPF 6 , LiBF 4 , LiClO 4 , lithium bissulfonylamide (LiFSA), lithium trifluoromethanesulfonate (LiCF 3 SO 3 ), and the like.
- the organic solvent cyclic carbonate (ethylene carbonate, propylene carbonate, etc.), chain carbonate (diethyl carbonate, dimethyl carbonate, ethyl methyl carbonate, etc.), cyclic carboxylic acid ester, chain carboxylic acid ester, etc. are used.
- the electrolyte used for the lithium ion capacitor can contain a molten salt and / or an additive in addition to the organic solvent and the lithium salt.
- a molten salt and / or an additive in addition to the organic solvent and the lithium salt.
- the insulating sheet disposed between the electrode group and the conductive case is not formed on the bag by thermal welding or the like, but simply the lower surface of the electrode group. And fold to surround the four sides. Therefore, it becomes easy to simplify the manufacturing process and manufacturing facility of the prismatic power storage device.
- the present invention is not limited to the above contents, but is shown by the scope of claims and is intended to include all modifications within the meaning and scope equivalent to the scope of claims.
- the rectangular electricity storage device is a sodium ion secondary battery or a lithium ion capacitor.
- the present invention is not limited to this, and the lithium ion secondary battery, the sodium ion capacitor, and the like. It can be applied to various prismatic electricity storage devices.
- the prismatic power storage device and the method for manufacturing the same according to the present invention are useful as, for example, a large power storage device for home use or industrial use, and a power source mounted in an electric vehicle or a hybrid vehicle.
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Abstract
Description
電解質と、
開口部を有し、前記電極群および前記電解質を収容するケースと、
前記ケースの前記開口部を封口する封口板と、
前記電極群と前記ケースとの間に介在され、前記電極群と前記ケースとを電気的に絶縁する絶縁シートと、を備え、
前記絶縁シートが、前記電極群の前記下面および前記4つの側面を包囲するように折りたたまれている、角型蓄電デバイスに関する。
(b)電解質を準備する工程と、
(c)開口部を有し、前記電極群および前記電解質を収容するケースを準備する工程と、
(d)前記ケースの前記開口部を封口する封口板を準備する工程と、
(e)前記電極群と前記ケースとの間に介在され、前記電極群と前記ケースとを電気的に絶縁する絶縁シートを準備する工程と、
(f)前記絶縁シートを、前記電極群の前記下面および前記4つの側面を包囲するように折りたたむ工程と、
(g)前記電極群および前記折りたたまれた絶縁シートを、前記ケースの内部に、前記絶縁シートが前記電極群と前記ケースとの間に介在された状態で設置する工程と、を含む角型蓄電デバイスの製造方法に関する。
図1に、本発明の一実施形態に係る角型蓄電デバイスの概略構成を分解斜視図により示す。図示例の角型蓄電デバイス10は、角型のナトリウムイオン二次電池もしくはリチウムイオンキャパシタであり、角柱状の電極群12と、開口部を有する角型のケース14と、ケース14の開口部を封口する封口板16とを備えている。ケース14および封口板16は金属から形成されており、導電性を有している。
図4A~4Eに、電極群の下面と4つの側面とを包囲するように絶縁シートを折りたたむ工程の一例を斜視図により示す。なお、そのように絶縁シートを折りたたむ工程は、図4A~4Eにより示した工程に限定されない。
Claims (6)
- 正極と、負極と、前記正極と前記負極との間に介在されるセパレータとを含み、上面、下面および4つの側面を有する角柱状の電極群と、
電解質と、
開口部を有し、前記電極群および前記電解質を収容するケースと、
前記ケースの前記開口部を封口する封口板と、
前記電極群と前記ケースとの間に介在され、前記電極群と前記ケースとを電気的に絶縁する絶縁シートと、を備え、
前記絶縁シートが、前記電極群の前記下面および前記4つの側面を包囲するように折りたたまれている、角型蓄電デバイス。 - 前記絶縁シートが、前記絶縁シートの一部分と他の一部分とを接合する溶着部を有していない、請求項1に記載の角型蓄電デバイス。
- 前記絶縁シートは、展開された状態で長方形であり、かつ
前記長方形の中央部を含むとともに前記電極群の前記下面を覆う第1領域と、
前記下面の対向する2つの辺でそれぞれ折り返され、前記4つの側面のうちの2つを覆う第2領域と、
前記下面の他の対向する2つの辺および前記4つの側面の境界で折り返され、前記4つの側面のうちの他の2つを覆う第3領域と、を含む、請求項1または2に記載の角型蓄電デバイス。 - 相互に電気的に絶縁された状態で前記封口板に配設された正極外部端子および負極外部端子と、
前記正極と前記正極外部端子とを電気的に接続する正極リード片と、
前記負極と前記負極外部端子とを電気的に接続する負極リード片と、
前記電極群と前記封口板との間に配設される絶縁性の隔壁部材とを備え、
前記隔壁部材は、前記電極群と対向するように配置される底板と、前記底板の周縁部に連設された少なくとも1つの縦板とを有し、
前記底板が、前記正極リード片が挿通される第1孔と、前記負極リード片が挿通される第2孔とを含み、
前記少なくとも1つの縦板が、前記正極リード片および前記負極リード片の少なくとも一方のリード片と、前記電池ケースとの間に介在している、請求項1~3のいずれか1項に記載の角型蓄電デバイス。 - (a)正極と、負極と、前記正極と前記負極との間に介在されるセパレータとを含み、上面、下面および4つの側面を有する角柱状の電極群を準備する工程と、
(b)電解質を準備する工程と、
(c)開口部を有し、前記電極群および前記電解質を収容するケースを準備する工程と、
(d)前記ケースの前記開口部を封口する封口板を準備する工程と、
(e)前記電極群と前記ケースとの間に介在され、前記電極群と前記ケースとを電気的に絶縁する絶縁シートを準備する工程と、
(f)前記絶縁シートを、前記電極群の前記下面および前記4つの側面を包囲するように折りたたむ工程と、
(g)前記電極群および前記折りたたまれた絶縁シートを、前記ケースの内部に、前記絶縁シートが前記電極群と前記ケースとの間に介在された状態で設置する工程と、を含む角型蓄電デバイスの製造方法。 - 前記絶縁シートが、第1の辺および前記第1の辺と直交する第2の辺を有する長方形であり、
前記電極群の前記下面が、長辺と短辺とを有する長方形であり、
前記絶縁シートの前記第1の辺が、前記下面の前記長辺よりも長く、
前記工程(f)が、
前記下面の前記長辺と前記絶縁シートの前記第2の辺とが直交し、かつ前記下面の中心が前記絶縁シートの中心に位置するように、前記下面と前記絶縁シートとを接触させることと、
前記絶縁シートを前記下面の2つの長辺でそれぞれ折り返すことと、
前記絶縁シートを前記下面の2つの短辺でそれぞれ折り返すことと、
前記絶縁シートを前記4つの側面の境界で折り返すことと、を含む、請求項5に記載の角型蓄電デバイスの製造方法。
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