WO2015083365A1 - 発光装置およびその製造方法 - Google Patents
発光装置およびその製造方法 Download PDFInfo
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- WO2015083365A1 WO2015083365A1 PCT/JP2014/005999 JP2014005999W WO2015083365A1 WO 2015083365 A1 WO2015083365 A1 WO 2015083365A1 JP 2014005999 W JP2014005999 W JP 2014005999W WO 2015083365 A1 WO2015083365 A1 WO 2015083365A1
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- translucent
- light emitting
- circuit layer
- support base
- conductive circuit
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- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/62—Arrangements for conducting electric current to or from the semiconductor body, e.g. lead-frames, wire-bonds or solder balls
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- H01L24/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L24/81—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a bump connector
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- H01L25/00—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof
- H01L25/03—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof all the devices being of a type provided for in the same subgroup of groups H01L27/00 - H01L33/00, or in a single subclass of H10K, H10N, e.g. assemblies of rectifier diodes
- H01L25/04—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof all the devices being of a type provided for in the same subgroup of groups H01L27/00 - H01L33/00, or in a single subclass of H10K, H10N, e.g. assemblies of rectifier diodes the devices not having separate containers
- H01L25/075—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof all the devices being of a type provided for in the same subgroup of groups H01L27/00 - H01L33/00, or in a single subclass of H10K, H10N, e.g. assemblies of rectifier diodes the devices not having separate containers the devices being of a type provided for in group H01L33/00
- H01L25/0753—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof all the devices being of a type provided for in the same subgroup of groups H01L27/00 - H01L33/00, or in a single subclass of H10K, H10N, e.g. assemblies of rectifier diodes the devices not having separate containers the devices being of a type provided for in group H01L33/00 the devices being arranged next to each other
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
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Definitions
- Embodiments described herein relate generally to a light emitting device and a method for manufacturing the same.
- LEDs light emitting diodes
- optical devices such as indoor, outdoor, stationary, and mobile display devices, display lamps, various switches, signal devices, and general lighting. Yes.
- a plurality of LEDs are arranged between two transparent substrates as a device suitable for a display device or a display lamp for displaying various character strings, geometrical figures or patterns.
- Such transparent light emitting devices are known.
- the transparent substrate By using a flexible substrate made of transparent resin as the transparent substrate, restrictions on the mounting surface of the light emitting device as a display device, a display lamp, etc. are reduced, so the convenience and availability of the transparent light emitting device are improved. To do.
- the transparent light emitting device has a structure in which a plurality of LED chips are arranged between a first transparent insulating substrate having a first conductive circuit layer and a second transparent insulating substrate having a second conductive circuit layer.
- Each of the plurality of LED chips has a pair of electrodes, and these electrodes are electrically connected to the first and second conductive circuit layers, respectively.
- the space between the first transparent insulating substrate and the second transparent insulating substrate, which is generated by arranging a plurality of LED chips with a certain distance, is made of a transparent resin having electrical insulating properties or flexibility. Filled with transparent insulator. In other words, the LED chip is disposed in a through hole provided in the transparent insulator.
- the electrical connection between the electrode of the LED chip and the conductive circuit layer in the transparent light-emitting device described above is, for example, the first transparent insulating substrate, the transparent insulating resin sheet in which the LED chip is disposed in the through hole, and the second transparent In many cases, this is performed by thermocompression bonding of a laminate with an insulating substrate. In this case, by making the thickness of the transparent insulating resin sheet after thermocompression bonding (thickness of the transparent insulator) thinner than the thickness of the LED chip, the conductive circuit layer may be pressed against and contacted with the electrode of the LED chip. is there. The electrode of the LED chip and the conductive circuit layer may be bonded with a conductive adhesive.
- the hot melt adhesive sheet with the LED chip fixed is sandwiched between the upper and lower insulating substrates having the conductive circuit layer and thermocompression bonded, and the LED chip is embedded in the adhesive sheet, whereby the adhesion between the upper and lower insulating substrates and the LED It has also been proposed to simultaneously perform electrical connection between the chip electrode and the conductive circuit layer.
- a light-transmitting flexible light-emitting device in which a light-emitting diode is embedded, a light-emitting device that handles the problem that a short circuit occurs between a conductive circuit layer and an LED chip when bent, and a method for manufacturing the same I will provide a.
- a light-emitting device includes a first translucent support base including a first translucent insulator and a conductive circuit layer provided on a surface of the first translucent insulator, Two light-transmitting insulators, and a predetermined gap is provided between the second light-transmitting insulator and the first light-transmitting support base so that the surface of the second light-transmitting insulator faces the conductive circuit layer.
- a light emitting diode disposed in a gap between the first translucent support base and the second translucent support base, the first translucent support base and the second And a third translucent insulator embedded in a space between the translucent support base.
- FIG. 1 is a schematic cross-sectional view illustrating a schematic configuration of a light emitting device 1 according to an embodiment.
- 2 is an enlarged cross-sectional view of a part of the light emitting device 1 shown in FIG.
- the light emitting device 1 generally includes a translucent support base 2, a translucent support base 3, a light emitting diode 22, and a translucent insulator 13.
- the translucent support base 2 includes a translucent insulator 4 and a conductive circuit layer 5 provided on the surface of the translucent insulator 4.
- the conductive circuit layer 5 is provided only on the surface of the translucent insulator 4 constituting the translucent support base 2.
- the translucent support base 3 includes a translucent insulator 6 and is disposed so that the surface of the translucent insulator 6 faces the conductive circuit layer 5 with a predetermined gap. That is, the translucent support base 3 itself does not have a conductive circuit layer.
- the light emitting diode 22 is formed by forming a semiconductor layer on an insulating substrate or a semiconductor substrate.
- the light emitting diode 22 is provided on the light emitting diode body 27 and one surface of the light emitting diode body 27 and is electrically connected to the conductive circuit layer 5.
- Electrodes 28 and 29 are provided, and are arranged between the translucent support base 2 and the translucent support base 3.
- a plurality of light emitting diode bodies 27 are arranged with a predetermined interval.
- the minimum distance d between the light emitting diode bodies 27 is not particularly limited, but is particularly effective when mounting at a high density so that the minimum distance d is 1500 ⁇ m or less. Further, the number of the light emitting diode bodies 27 to be arranged can be determined as appropriate according to the specifications (for example, outer dimensions, light emitting area, etc.) of the light emitting device 1.
- the light-emitting diode 22 includes an N-type semiconductor layer (for example, an n-GaN layer) 24 and an active layer (for example, an InGaN layer) sequentially formed on an insulating substrate 23 such as a transparent sapphire substrate. 25 and a light emitting diode body 27 having a P-type semiconductor layer (for example, a p-GaN layer) 26.
- the arrangement positions of the N-type semiconductor layer and the P-type semiconductor layer may be reversed.
- a single-sided electrode structure in which electrodes 28 and 29 are provided on the light emitting surface side of the light emitting diode body 27 is applied.
- a single-sided electrode structure can also be applied to a light emitting diode in which a semiconductor layer is formed on a semiconductor substrate.
- the electrodes 28 and 29 of the light emitting diode 22 are electrically connected to the conductive circuit layer 5 of the translucent support base 2.
- the electrodes 28 and 29 are pad electrodes made of an alloy containing Au (gold).
- the electrode 28 is electrically connected to the conductive circuit layer 5 by contacting the conductive circuit layer 5 via the conductive bump 30.
- the electrode 29 is electrically connected to the conductive circuit layer 5 by contacting the conductive circuit layer 5 via the conductive bump 30.
- the conductive bump 30 may be gold, AuSn alloy, alloy with silver, copper, nickel or other metals, a mixture, eutectic, amorphous material, solder, eutectic solder, a mixture of metal fine particles and resin, different materials.
- An isotropic conductive film may be used.
- wire bumps using wire bonders, electrolytic plating, electroless plating, inks containing metal fine particles were baked by ink jet printing, pastes containing metal fine particles were formed, applied ball mounts, pellet mounts, vapor deposition sputtering, etc.
- a bump may be used.
- the melting point of the conductive bump 30 is preferably 180 ° C. or higher, more preferably 200 ° C. or higher.
- An upper limit is 1100 degrees C or less as a practical range. If the melting point of the conductive bump 30 is lower than 180 ° C., the conductive bump 30 is greatly deformed in the vacuum heat pressing process in the manufacturing process of the light emitting device, and the sufficient thickness cannot be maintained, or the conductive bump 30 protrudes from the electrode. Inconveniences such as lowering the luminous intensity of the LED occur.
- the melting point of the conductive bump 30 is, for example, a melting point value measured using a sample of about 10 mg at a heating rate of 5 ° C./min using a DSC-60 differential scanning calorimeter manufactured by Shimadzu Corporation. When the line temperature and the liquidus temperature are different, the value is the solidus temperature.
- the dynamic hardness DHV of the conductive bump 30 is 3 or more and 150 or less, preferably 5 or more and 100 or less, more preferably 5 or more and 50 or less.
- the dynamic hardness DHV of the conductive bump 30 is less than 3, the conductive bump 30 is greatly deformed in the vacuum hot pressing process in the manufacturing process of the light emitting device, and a sufficient thickness cannot be maintained.
- the conductive bump 30 protrudes from the electrode, causing problems such as a decrease in the luminous intensity of the LED.
- the dynamic hardness DHV of the conductive bump 30 exceeds 150, the conductive bump 30 deforms the translucent support base 2 in the vacuum hot press process in the manufacturing process of the light emitting device, thereby causing poor appearance and poor connection. It is not preferable because it is generated.
- the dynamic hardness DHV of the conductive bump 30 is obtained, for example, by a test using a Shimadzu dynamic ultrafine hardness meter DUH-W201S manufactured by Shimadzu Corporation at 20 ° C.
- a diamond regular pyramid indenter (Vickers indenter) having a facing angle of 136 ° is pushed into the conductive bump 30 at a load speed of 0.0948 mN / sec.
- the test force (P / mN) when the indenter indentation depth (D / ⁇ m) reaches 0.5 ⁇ m is substituted into the following equation.
- the height of the conductive bump 30 is preferably 5 ⁇ m or more and 50 ⁇ m or less, and more preferably 10 ⁇ m or more and 30 ⁇ m or less. If the height of the conductive bump 30 is less than 5 ⁇ m, the effect of preventing a short circuit between the conductive circuit layer and the P-type semiconductor layer or between the conductive circuit layer and the N-type semiconductor layer is not preferable. On the other hand, if the thickness exceeds 50 ⁇ m, it is not preferable because the conductive bump 30 deforms the translucent support base 2 in the vacuum hot pressing process in the manufacturing process of the light emitting device, thereby causing poor appearance and poor connection.
- the contact area of the electrode and the conductive bump 30 of the light emitting diode body 27 is preferably 100 [mu] m 2 or more 15,000 2 or less, more preferably 400 [mu] m 2 or more 8,000Myuemu 2 or less. Each of these dimensions is a value measured in a stable environment where the room temperature and the temperature of the object to be measured are 20 ° C. ⁇ 2 ° C.
- the electrodes 28 and 29 of the light emitting diode body 27 and the conductive circuit layer 5 of the translucent support base 2 are connected to each other by vacuum hot pressing using the conductive bumps 30. Accordingly, at the time of vacuum hot pressing, at least a part of the conductive bump 30 is electrically connected to the electrode of the light emitting diode 22 in a state where it is not melted. Therefore, the contact angle between the electrode surface of the light emitting diode body 27 and the conductive bump 30 is preferably, for example, 135 degrees or less.
- the light emitting diode 22 is lit by a DC voltage applied via the electrodes 28 and 29.
- the conductive circuit layer 5 of the light emitting device 1 forms a 7 series 2 parallel circuit. By connecting in series, the flowing current becomes the same in all the light emitting diode bodies 27.
- the translucent insulator 13 is embedded between the translucent support base 2 and the translucent support base 3.
- the translucent insulator 4 and the translucent insulator 6 have, for example, insulation, translucency, and flexibility so that the translucent support base 2 and the translucent support base 3 can be bent.
- a sheet-like resin material is used.
- the resin material include polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polycarbonate (PC), polyethylene succinate (PES), cyclic olefin resin (for example, Arton (trade name) manufactured by JSR), acrylic resin, and the like. Can be mentioned.
- the total light transmittance of the translucent insulators 4 and 6 is preferably 90% or more, and more preferably 95% or more.
- the total light transmittance is defined by, for example, JIS K7105.
- the thickness of the translucent insulator 4 and translucent insulator 6 is preferably in the range of 50 to 300 ⁇ m, for example.
- the thickness of the translucent insulator 4 and the translucent insulator 6 is greater than 300 ⁇ m, it becomes difficult to impart good flexibility to the translucent support base 2 and the translucent support base 3, This is because the light property may also be lowered.
- the thickness of the translucent insulator 4 and the translucent insulator 6 is less than 50 ⁇ m, the translucent insulator 4 and the translucent insulator 6 are deformed around the light emitting diode 22 during vacuum thermocompression bonding. This is not preferable.
- a transparent conductive material such as indium tin oxide (ITO), fluorine-doped tin oxide (FTO), zinc oxide, indium zinc oxide (IZO) or the like is used.
- the conductive circuit layer 5 can be formed by, for example, forming a thin film by applying a sputtering method, an electron beam evaporation method, or the like, and patterning the obtained thin film by laser processing, etching processing, or the like.
- the conductive circuit layer 5 is formed by applying a mixture of fine particles of a transparent conductive material having an average particle diameter of 10 to 300 nm and a transparent resin binder in a circuit shape by screen printing or the like, or a coating film of the above mixture.
- a circuit may be formed by performing patterning processing by laser processing or photolithography.
- the conductive circuit layer 5 is not limited to one made of a transparent conductive material, and may be one in which fine particles of an opaque conductive material such as gold or silver are attached in a mesh shape. For example, after applying a photosensitive compound of an opaque conductive material such as silver halide, exposure / development processing is performed to form the mesh-shaped conductive circuit layer 5. Alternatively, the conductive circuit layer 5 may be formed by applying slurry containing opaque conductive material fine particles in a mesh shape by screen printing or the like.
- the conductive circuit layer 5 may be any layer as long as it shows translucency when formed on the surface of the translucent insulator 4 and the translucent support base 2 can be obtained.
- the conductive circuit layer 5 has translucency such that the total light transmittance (JIS K7105) of the translucent support base 2 is 10% or more, and the total light transmittance of the light emitting device 1 as a whole is 1% or more. It is preferable. If the total light transmittance of the entire light emitting device 1 is less than 1%, the light emitting point is not recognized as a bright point.
- the translucency of the conductive circuit layer 5 itself varies depending on its configuration, but the total light transmittance is preferably in the range of 10 to 85%.
- a translucent insulator 13 is embedded in a space between the translucent support base 2 and the translucent support base 3, that is, a space excluding a portion where the plurality of light emitting diodes 22 are arranged.
- the translucent insulator 13 is preferably made of a material containing an elastomer as a main component, and may contain other resin components as necessary.
- elastomers include acrylic elastomers, olefin elastomers, styrene elastomers, ester elastomers, urethane elastomers, and the like.
- acrylic elastomers that satisfy the above-mentioned characteristics are excellent in fluidity at the time of softening, adhesiveness after curing, weather resistance, etc. in addition to translucency, electrical insulation, flexibility, etc. It is suitable as a constituent material of the translucent insulator 13.
- the translucent insulator 13 is preferably composed of a translucent insulating resin, particularly an elastomer, that satisfies characteristics such as a predetermined Vicat softening temperature, tensile storage modulus, glass transition temperature, melting temperature, and the like.
- a predetermined Vicat softening temperature is preferably in the range of 80 to 160 ° C.
- the tensile storage modulus between 0 ° C. and 100 ° C. is preferably in the range of 0.01 to 10 GPa.
- it is preferable that the translucent insulator 13 is not melted at the Vicat softening temperature and the tensile storage modulus at the Vicat softening temperature is 0.1 MPa or more.
- the translucent insulator 13 preferably has a melting temperature of 180 ° C. or higher, or a melting temperature that is 40 ° C. higher than the Vicat softening temperature.
- the translucent insulator 13 preferably has a glass transition temperature of ⁇ 20 ° C. or lower.
- the Vicat softening temperature is a value obtained under A50 conditions described in JIS K7206 (ISO K306: 2004) under the conditions of a test load of 10 N and a heating rate of 50 ° C./hour.
- the glass transition temperature and the melting temperature are values obtained by heat flux differential scanning calorimetry using a differential scanning calorimeter at a rate of temperature increase of 5 ° C./min by a method according to JIS K7121 (ISO 3146). .
- the tensile storage modulus was raised at a constant rate of 1 ° C./min from ⁇ 100 ° C. to 200 ° C. using a dynamic viscoelasticity automatic measuring instrument according to JlS K7244-1 (ISO 6721), and a frequency of 10 Hz. This is the value obtained in.
- the translucent insulator 13 can be disposed around the electrodes 28 and 29. That is, when each of the electrodes 28 and 29 has an area smaller than an electrode formation surface (for example, a light emission surface) of the light emitting diode body 27 and a shape protruding from the electrode formation surface, the electrodes 28 and 29 are brought into contact with the conductive circuit layer 5. In this state, a space is created between the surface where the electrodes 28 and 29 are not formed (the surface where the electrodes 28 and 29 are not formed) and the conductive circuit layer 5 in the electrode formation surface. It is preferable to fill the light-transmitting insulator 13 in a minute space between the non-formation surface of the electrodes 28 and 29 and the conductive circuit layer 5.
- an electrode formation surface for example, a light emission surface
- the translucent insulator 13 has a thickness smaller than the height T 1 of the light emitting diode 22 in order to improve the contact between the conductive circuit layer 5 and the electrodes 28 and 29.
- the translucent support base 2 that is in close contact with the translucent insulator 13 has a shape curved inward from the portion where the light emitting diodes 22 are arranged toward the intermediate portion between the adjacent light emitting diodes 22. Yes. Therefore, the translucent support base 2 presses the conductive circuit layer 5 against the electrodes 28 and 29. Thereby, the electrical connectivity between the conductive circuit layer 5 and the electrodes 28 and 29 and the reliability thereof can be improved.
- FIG. 3 shows a connection example between the conductive circuit layer 5 and the light emitting diode 22 in the present embodiment.
- a light emitting diode 22 is connected to the conductive circuit layer 5.
- the conductive circuit layer 5 is, for example, a transparent conductive material, but is not limited to this as described above. Further, the pattern of the conductive circuit layer 5 is not limited to this and can be variously changed.
- the flexible translucent light emitting device in which the light emitting diode is embedded for example, even when the pad electrode side is bent so as to be concave, a sufficient height can be secured by the conductive bumps 30. A short circuit can be prevented.
- ⁇ Manufacturing method> 4A to 4D are views for explaining a method of manufacturing the light emitting device according to this embodiment. A method for manufacturing the light emitting device according to the present embodiment will be described with reference to FIGS. 4A to 4D.
- a light emitting diode 22 having an electrode 28 and an electrode 29 (an anode electrode and a cathode electrode or a cathode electrode and an anode electrode) is prepared.
- conductive bumps 30 are formed on both the electrodes 28 and 29 of the light emitting diode 22.
- a method for forming the conductive bump 30 a method of making gold or gold alloy bump from Au wire or Au alloy wire using a wire bump processing machine can be adopted.
- the wire diameter used is preferably 15 ⁇ m or more and 75 ⁇ m or less.
- a wire bonding apparatus is used to discharge the wire tip and melt the metal to form a ball, and then apply ultrasonic waves to connect to the pad electrode. Then, the wire is separated from the ball with the ball connected to the pad electrode.
- the upper surface of the ball may be rounded by pressing the upper surface of the ball as desired.
- the tamping process may be performed with a press machine through a resin sheet, or the upper surface of the ball may be pressed with a jig tip of a wire bonding apparatus.
- the rounding process is performed by pressing, the curvature of the upper surface of the ball is slightly larger than that of the lower part of the ball.
- FIG. 5 is a schematic diagram of a bump (ball) shape before rounding.
- the wire that was cut off at the time of bump formation remains on the conductive bump 30. This rest is called the tail.
- FIG. 6A to 6C are diagrams for explaining the rounding process using a jig.
- a light emitting diode is arranged on a bump bonding apparatus stage (not shown) (see FIG. 6A).
- a jig which is attached to the bump bonding apparatus and harder than the bump, is pressed onto the upper part of the bump with its lower surface parallel to the electrode (see FIG. 6B).
- the jig is pressed until the height of the bump reaches a desired height B.
- the wire remaining on the upper part when the wire is cut is crushed by the jig (see FIG. 6C), and a continuous surface without protrusions is formed on the bump.
- FIG. 7A to 7C are diagrams for explaining the rounding process by press working using a resin sheet.
- FIG. 8A is a diagram showing an arrangement of light emitting diodes before pressing.
- FIG. 8B is a diagram for explaining the arrangement of the LED chips after pressing.
- a resin sheet 200 thicker than the height of the formed bump height B added to the LED chip thickness is disposed on the press lower plate of the press apparatus, and the LED chip having the bump formed on the resin sheet 200 is disposed, and further formed.
- a resin sheet 100 thicker than the height obtained by adding the LED chip thickness to the bump height B is disposed on the LED chip (see FIG. 7A).
- the resin sheets 100 and 200 for example, PET, fluororesin, TPX, olefin, or the like can be used.
- the bump formation surface of the light emitting diode is as follows. Embedded in the resin sheet 100. Further, the surface opposite to the bump forming surface of the LED chip is embedded in the resin sheet 200.
- the resin sheets 100 and 200 are peeled off.
- the wire remaining on the upper part when the wire is separated at the time of bump formation is crushed by the resin sheet 100 to form a continuous surface on the upper part of the bump (see FIG. 7C).
- the bump height B can be adjusted by adjusting the resin hardness and the pressing pressure.
- the continuous surface formed on the upper part of the bump becomes a curved surface as compared with the rounding method using a jig.
- conductive bumps are formed on the pad electrodes with metal balls.
- electrolytic plating and electroless plating ink jet coating using ink containing metal fine particles, coating and printing of paste containing metal fine particles, ball mounting
- metal such as gold, silver, copper, and nickel, alloys such as gold-tin alloys, eutectic, amorphous, and solder can be used by thermocompression bonding of a pellet mount anisotropic conductive film.
- a translucent support base 2 having a translucent insulator 4 and a conductive circuit layer 5 formed on the surface thereof, and a translucent support base 3 made of only the translucent insulator 6 are prepared.
- the constituent material, forming method, and the like of the conductive circuit layer 5 are as described above.
- a translucent insulating resin sheet 13 ′ having a Vicat softening temperature in the range of 80 to 160 ° C. is prepared.
- the translucent insulating resin sheet 13 ′ has a tensile storage modulus between 0 ° C. and 100 ° C. in the range of 0.01 to 10 GPa and is not melted at the Vicat softening temperature.
- the main component is a resin having a tensile storage modulus at Vicat softening temperature of 0.1 MPa or more, a melting temperature of 180 ° C. or higher, or 40 ° C. higher than Vicat softening temperature, and a glass transition temperature of ⁇ 20 ° C. or lower. Is preferred.
- the translucent insulating resin sheet 13 ' is preferably an elastomer sheet, and more preferably an acrylic elastomer sheet.
- a translucent insulating resin sheet 13 ′ is disposed on the conductive circuit layer 5 of the translucent support base 2 so as to cover the entire conductive circuit layer 5 (see FIG. 4A).
- the translucent insulating resin sheet 13 ' is temporarily attached with an adhesive.
- the translucent insulating resin sheet 13 ′ has a shape capable of covering the entire conductive circuit layer 5 and further the entire translucent insulator 4 including the portion where the light emitting diode 22 is disposed on the conductive circuit layer 5. have.
- a plurality of light emitting diodes 22 are arranged on the translucent insulating resin sheet 13 '(see FIG. 4B).
- the light emitting diode 22 is arranged so that the electrodes 28 and 29 are located on the translucent insulating resin sheet 13 ′ side, in other words, on the conductive circuit layer 5 side.
- the translucent support base 3 is disposed on the light emitting diode 22 (see FIG. 4C).
- the light-emitting diode 22 is placed between the translucent support base 2 and the translucent support base 3 with the electrodes 28 and 29 positioned on the conductive circuit layer 5 side. Placed in.
- the translucent insulating resin sheet 13 ' is translucent generated by disposing the space between the translucent support base 2 and the translucent support base 3, that is, the light emitting diode 22, in the vacuum thermocompression bonding process described below. It is only necessary to have a thickness capable of sufficiently filling the space based on the gap between the support base 2 and the translucent support base 3.
- the thickness of the translucent insulating resin sheet 13 ′ can sufficiently fill the gap between the translucent support base 2 and the translucent support base 3 based on the height of the light emitting diode 22. I just need it.
- the thickness (T) of the translucent insulator 13 is made thinner than the height (H) of the light emitting diode 22, the translucent insulating resin sheet 13 ′ is made to correspond to the difference (HT). What is necessary is just to set thickness.
- a laminated body in which a translucent support base 2, a translucent insulating resin sheet 13 ′, a light emitting diode 22, and a translucent support base 3 are sequentially laminated is placed in a vacuum atmosphere. Pressurize while heating.
- the laminate In the heating / pressurizing step (vacuum thermocompression bonding step) of the laminate in a vacuum atmosphere, the laminate is Mp ⁇ 10 (° C.) ⁇ Vp softening temperature Mp (° C.) of the translucent insulating resin sheet 13 ′. It is preferable to heat and pressurize to a temperature T in the range of T ⁇ Mp + 30 (° C.). A more preferable heating temperature is in the range of Mp ⁇ 10 (° C.) ⁇ T ⁇ Mp + 10 (° C.).
- the translucent support base 2 and the translucent support base are connected to the electrodes 28 and 29 disposed on the conductive circuit layer 5 via the translucent insulating resin sheet 13 ′ while being connected to predetermined positions of the conductive circuit layer 5.
- the light-transmitting insulator 13 can be formed by embedding a light-transmitting insulating resin sheet 13 ′ that has been softened.
- the heating temperature T during vacuum thermocompression bonding of the laminate is less than 10 (° C.) lower than the Vicat softening temperature Mp of the translucent insulating resin sheet 13 ′ (T ⁇ Mp ⁇ 10), the translucent insulating resin The softening of the sheet 13 ′ becomes insufficient, and the adhesion of the light-transmitting insulating resin sheet 13 ′ (and thus the light-transmitting insulator 13) to the light-emitting diode 22 may be reduced. If the heating temperature T exceeds 30 (° C.) higher than the Vicat softening temperature Mp of the translucent insulating resin sheet 13 ′ (Mp + 30 ⁇ T), the translucent insulating resin sheet 13 ′ is too soft and defective in shape or the like. May occur.
- thermocompression bonding step of the laminate in a vacuum atmosphere is preferably performed as follows.
- the above-mentioned laminate is pre-pressurized to bring the constituent members into close contact with each other.
- the laminate is pressurized while being heated to the temperature as described above.
- the light-transmitting insulating resin sheet softened in the space between the light-transmitting support base 2 and the light-transmitting support base 3 by thermocompression bonding the pre-pressurized laminate in a vacuum atmosphere. 13 'can be embedded without a gap.
- the vacuum atmosphere during thermocompression bonding is preferably 5 kPa or less.
- the pre-pressurization step can be omitted, in this case, the pre-pressurization step is preferably performed because misalignment or the like is likely to occur in the laminate.
- thermocompression bonding step of the laminate When the thermocompression bonding step of the laminate is performed in an air atmosphere or under a low vacuum, bubbles tend to remain in the light emitting device 1 after thermocompression bonding, particularly around the light emitting diode 22. Since the air bubbles remaining in the light emitting device 1 are pressurized, the bubbles of the light emitting device 1 after thermocompression bonding and peeling from the translucent support bases 2 and 3 of the light emitting diode 22 are caused. Furthermore, if bubbles or blisters are present inside the light emitting device 1, particularly in the vicinity of the light emitting diode 22, light is scattered unevenly, which causes a problem in the appearance of the light emitting device 1, which is not preferable.
- the electrode 28 , 29 and the conductive circuit layer 5 can be electrically connected to each other, and the translucent insulator 13 can be formed in close contact with the periphery of the light emitting diode 22. Furthermore, a part of the translucent insulator 13 can be satisfactorily filled in the space between the non-formation surface of the electrodes 28 and 29 and the conductive circuit layer 5 in the light emitting surface of the light emitting diode body 27.
- the light emitting device 1 with improved electrical connectivity and reliability between the conductive circuit layer 5 and the electrodes 28 and 29 of the light emitting diode 22 can be manufactured with high reproducibility. .
- FIG. 13 is a view showing the light-emitting diodes 22 constituting the light-emitting device 1, the translucent insulator 13, the conductive circuit layer 5, and the translucent insulating bases 4 and 6 located in the vicinity thereof.
- FIG. 14 is an enlarged view showing the conductive bumps 30 formed on the electrodes 28 and 29 of the light emitting diode 22.
- the contact area of the conductive circuit layer 5 in contact with the conductive bump 30 of the light emitting diode 22 is recessed along the conductive bump 30. Yes. Thereby, the area which the conductive bump 30 and the conductive circuit layer 5 contact can be increased. As a result, the resistance between the conductive bump 30 and the conductive circuit layer 5 can be reduced.
- the translucent insulator 13 is a single-layer sheet.
- the translucent insulator 13 is made of two translucent insulating resin sheets, and the two translucent insulating resins are used.
- the structure shown in FIG. 2 may be obtained by pressurizing the translucent support base 2 and the translucent support base 3 with the light emitting diode sandwiched between the sheets.
- the translucent support base 3 is used as a temporary base, the whole is pressed to obtain electrical connection between the electrodes 28 and 29 and the conductive circuit layer 5, and then the opposite of the electrodes 28 and 29 of the two sheets.
- the translucent resin sheet on the side is peeled off, and the translucent resin sheet having the same thickness as that which has been peeled off again and the final translucent support base 3 may be covered to obtain the configuration shown in FIG. .
- FIG. 9 is a schematic cross-sectional view illustrating a schematic configuration of the light-emitting device 1 according to the embodiment.
- FIG. 10 is an enlarged cross-sectional view of a part of the light emitting device 1 shown in FIG.
- the light emitting device according to the present embodiment is different from the light emitting device according to the first embodiment in that the light emitting diodes constituting the light emitting device have electrodes on both surfaces.
- the light emitting device 1 generally includes a translucent support base 2, a translucent support base 3, a light emitting diode 8, and a translucent insulator 13.
- the translucent support base 2 includes a translucent insulator 4 and a conductive circuit layer 5 formed on the surface thereof.
- the translucent support base 3 includes a translucent insulator 6 and a conductive circuit layer 7 formed on the surface thereof.
- the translucent support base 2 and the translucent support base 3 are arranged with a predetermined gap therebetween so that the conductive circuit layer 5 and the conductive circuit layer 7 face each other.
- a translucent insulator 13 is present in a portion other than the light emitting diode 8, the conductive circuit layer 5, and the conductive circuit layer 7 between the translucent insulator 4 and the translucent insulator 6.
- Single or a plurality of light emitting diodes 8 are arranged between the surface of the translucent support base 2 having the conductive circuit layer 5 and the surface of the translucent support base 3 of the conductive circuit layer 7.
- the light emitting diode 8 has an electrode 9 on the light emitting surface side and an electrode 10 on the opposite surface side.
- the electrode 9 is electrically connected to the conductive circuit layer 5, and the electrode 10 is electrically connected to the conductive circuit layer 7.
- a light emitting diode chip having a PN junction can be used.
- the light emitting diode 8 is not limited to the LED chip, and may be a laser diode (LD) chip or the like.
- LD laser diode
- the light emitting diode 8 for example, a P-type semiconductor layer formed on an N-type semiconductor substrate, an N-type semiconductor layer formed on a P-type semiconductor substrate, or an N-type semiconductor on the semiconductor substrate. A layer and a P-type semiconductor layer are formed, a P-type hetero semiconductor layer and an N-type hetero semiconductor layer are formed on a P-type semiconductor substrate, and an N-type semiconductor substrate is formed on an N-type semiconductor substrate.
- Either a hetero semiconductor layer or a P-type hetero semiconductor layer may be used.
- the LED may be bonded to a metal support substrate such as CuW or a semiconductor support substrate such as Si, Ge or GaAs, and the PN junction may be moved from the first semiconductor substrate to the support substrate.
- the light-emitting diode 8 used in this embodiment includes a P-type semiconductor layer 16 or 17 and a light-emitting layer sandwiched between N-type semiconductor layers 17 or 16 (a PN junction interface or a double heterojunction structure).
- the electrode 9 is electrically connected to the conductive circuit layer 5 by contacting the conductive circuit layer 5 via the conductive bump 20.
- the electrode 10 is electrically connected to the conductive circuit layer 7 by contacting the conductive circuit layer 7.
- the light emitting diode 8 is lit by a DC voltage applied via the electrodes 9 and 10.
- the light emitting diode body 12 may include a light reflection layer, a current diffusion layer, a transparent electrode, or the like. In this case, the light emitting diode body 12 includes a light reflection layer, a current diffusion layer, and a transparent electrode.
- the conductive bump 20 has the same configuration as the conductive bump according to the first embodiment.
- the height of the conductive bump 20 is preferably 5 ⁇ m or more and 50 ⁇ m or less, and more preferably 10 ⁇ m or more and 30 ⁇ m or less. If the height of the conductive bump 20 is less than 5 ⁇ m, the effect of preventing a short circuit between the conductive circuit layer 5 and the semiconductor layer 16 becomes weak, which is not preferable. On the other hand, if the height of the conductive bumps 20 exceeds 50 ⁇ m, the conductive bumps 20 deform the first support base in the vacuum hot pressing process in the manufacturing process of the light emitting device, resulting in poor appearance and poor connection. This is not preferable.
- the vertical distance a from the surface of the LED chip to the tip of the bump, the center position in the planar direction of the bump, and the maximum distance b to the end of the LED chip is preferably 0.120 or more and 0.400 or less in order to ensure the reliability of the light emitting device according to the present invention, and the ratio a / b is more preferably 0.130 or more and 0.380 or less. It is.
- the contact area between the electrode 9 of the LED chip and the conductive bump 20 is preferably 100 ⁇ m 2 or more and 15,000 ⁇ m 2 or less, more preferably 400 ⁇ m 2 or more and 8,000 ⁇ m 2 or less. Each of these dimensions is a value measured in a stable environment where the room temperature and the temperature of the object to be measured are 20 ° C. ⁇ 2 ° C.
- the conductive circuit layer 5 and the conductive circuit layer 7 are formed on the surfaces of the translucent insulating bases 4 and 6, respectively.
- the conductive circuit layer 7 has the same configuration as the conductive circuit layer 5 described in the first embodiment.
- a translucent insulator 13 is embedded in a portion excluding a portion where the plurality of light emitting diodes 8 are disposed between the translucent support base 2 and the translucent support base 3.
- the translucent insulator 13 is preferably not melted at the Vicat softening temperature, and the tensile storage elastic modulus at the Vicat softening temperature is preferably 0.1 MPa or more.
- the translucent insulator 13 preferably has a melting temperature of 180 ° C. or higher, or a melting temperature that is 40 ° C. higher than the Vicat softening temperature.
- the translucent insulator 13 preferably has a glass transition temperature of ⁇ 20 ° C. or lower.
- the elastomer as the constituent material of the translucent insulator 13 is the peel strength of the translucent insulator 13 formed using the elastomer from the conductive circuit layers 5 and 7 (according to the method A of JIS C5061-8.1.6). Is more preferably 0.49 N / mm or more.
- the translucent insulator 13 and the translucent support base 2 and the translucent support base 2 are translucent. It can be embedded between the optical support base 3.
- the contact state between the conductive circuit layer 5 and the electrode 9 (first electrode with bumps; the same applies hereinafter) and the contact state between the conductive circuit layer 7 and the electrode 10 are arranged in close contact with the periphery of the light emitting diode 8. The translucent insulator 13 is maintained.
- the reliability of electrical connection between the conductive circuit layer 5 and the electrode 9 and the conductive circuit layer 7 and the electrode 10 can be improved particularly when the light emitting device 1 is subjected to a bending test, a thermal cycle test (TCT), or the like. it can.
- the Vicat softening temperature of the translucent insulator 13 exceeds 160 ° C., the translucent insulating resin sheet cannot be sufficiently deformed in the process of forming the translucent insulator 13 described later, and thereby the conductive circuit layer 5 and the electrode 9 and the electrical connectivity between the conductive circuit layer 7 and the electrode 10 are deteriorated. If the Vicat softening temperature of the translucent insulator 13 is less than 80 ° C., the holding power of the light emitting diode 8 is insufficient, and the electrical connection reliability between the conductive circuit layer 5 and the electrode 9 and between the conductive circuit layer 7 and the electrode 10 is ensured. Decreases.
- the Vicat softening temperature of the translucent insulator 13 is preferably 100 ° C. or higher.
- the electrical connection reliability between the conductive circuit layer 5 and the electrode 9 and between the conductive circuit layer 7 and the electrode 10 can be further enhanced.
- the Vicat softening temperature of the translucent insulator 13 is preferably 140 ° C. or lower.
- the electrical connectivity between the conductive circuit layer 5 and the electrode 9 and between the conductive circuit layer 7 and the electrode 10 can be improved more effectively.
- the electrodes 9 and electrodes 10 of the plurality of light-emitting diodes 8 can be accurately placed on the conductive circuit layer 5 and the conductive circuit layer 7 at the time of vacuum thermocompression bonding described later.
- the translucent insulating resin sheet 13 ′ needs to maintain a relatively high storage elasticity from room temperature to around the heating temperature in the vacuum thermocompression bonding process.
- the translucent insulator 13 having a tensile storage modulus between 0 ° C. and 100 ° C. of 0.01 GPa or more is applied.
- the translucent insulator 13 having a tensile storage modulus between 0 ° C. and 100 ° C. of 10 GPa or less is applied.
- the tensile storage elastic modulus between 0 ° C. and 100 ° C. of the translucent insulator 13 is preferably 0.1 GPa or more, and preferably 7 GPa or less.
- the electrodes 9 and 10 at the time of vacuum thermocompression bonding The vertical position accuracy with respect to the conductive circuit layer 5 and the conductive circuit layer 7 can be further increased.
- the elastomer constituting the translucent insulator 13 has a melting temperature of 180 ° C. or higher, or 40 ° C. higher than the Vicat softening temperature.
- the tensile storage modulus at the Vicat softening temperature of the elastomer is more preferably 1 MPa or more.
- the melting temperature of the elastomer is more preferably 200 ° C. or higher or 60 ° C. higher than the Vicat softening temperature.
- the translucent insulator 13 is not only for manufacturability of the light emitting device 1 but also for improving the bending resistance and heat cycle characteristics of the light emitting device 1 in a wide temperature range from low temperature to high temperature. And the balance of properties of tensile storage modulus and glass transition temperature is important. By using the elastomer having the above-described tensile storage elastic modulus, it is possible to improve the bending resistance and heat cycle characteristics of the light emitting device 1.
- the glass transition temperature of the elastomer is too high, the bending resistance and heat cycle characteristics of the light emitting device 1 in a low temperature environment may be deteriorated. For this reason, it is preferable to use an elastomer having a glass transition temperature of ⁇ 20 ° C. or lower. Based on such a glass transition temperature and tensile storage elastic modulus, it is possible to improve the bending resistance and heat cycle characteristics of the light emitting device 1 in a wide temperature range from a low temperature to a high temperature.
- the glass transition temperature of the elastomer is more preferably ⁇ 40 ° C. or lower.
- the thickness of the translucent insulator 13 may be equal to the gap between the translucent support base 2 and the translucent support base 3 based on the height of the light-emitting diode 8. In order to improve the contact between the circuit layer 7 and the electrodes 9 and 10, it is preferably thinner than the height of the light emitting diode 8. Further, the thickness (T) of the translucent insulator 13 is more preferably set so that the difference (HT) from the height (H) of the light emitting diode 8 is in the range of 5 to 200 ⁇ m.
- the difference (HT) between the height (H) of the light emitting diode 8 and the thickness (T) of the translucent insulator 13 is less than 1/2 of the height (H) of the light emitting diode 8. It is preferable that
- 11A to 11D are views for explaining a method for manufacturing the light emitting device according to this embodiment. A method for manufacturing the light-emitting device 1 according to the present embodiment will be described with reference to FIGS. 11A to 11D.
- a light emitting diode 8 having an electrode 9 on one side and an electrode 10 (an anode electrode and a cathode electrode or a cathode electrode and an anode electrode) on the other side is prepared.
- conductive bumps 20 are formed on the electrodes 9 (electrode pads) of the LED chip.
- a method for forming the conductive bump 20 a method of making gold or gold alloy bumps from Au wires or Au alloy wires using a wire bump processing machine can be adopted.
- the wire diameter used is preferably 15 ⁇ m or more and 75 ⁇ m or less.
- a wire bonding apparatus is used to discharge the wire tip and melt the metal to form a ball, and then apply ultrasonic waves to connect to the pad electrode. Then, the wire is separated from the ball with the ball connected to the pad electrode.
- the bump 20 is rounded similarly to the bump 30 according to the first embodiment. This rounding process may be performed using a resin sheet. In that case,
- FIG. 12A is a diagram showing an arrangement of light emitting diodes before pressing.
- FIG. 12B is a diagram showing the arrangement of the light emitting diodes after pressing.
- the bump forming surface of the light emitting diode is embedded in the resin sheet 100 as shown in FIG. 12B.
- the surface opposite to the bump forming surface of the light emitting diode is embedded in the resin sheet 200.
- the resin sheets 100 and 200 are peeled off.
- the wire remaining on the upper part when the wire is separated at the time of bump formation is crushed by the resin sheet 100 to form a continuous surface on the upper part of the bump (see FIG. 7C).
- the bump height B can be adjusted by adjusting the resin hardness and the pressing pressure.
- a translucent support base 2 having a translucent insulator 4 and a conductive circuit layer 5 formed on the surface thereof, a translucent insulator 6 and a conductive circuit layer 7 formed on the surface thereof.
- a translucent support base 3 is prepared. The constituent materials, formation methods, and the like of the conductive circuit layer 5 and the conductive circuit layer 7 are as described above.
- a translucent insulating resin sheet 14 having a Vicat softening temperature in the range of 80 to 160 ° C. is prepared.
- the translucent insulating resin sheet 14 has a tensile storage modulus between 0 ° C. and 100 ° C. in the range of 0.01 to 10 GPa and is not melted at the Vicat softening temperature
- the main component is a resin having a tensile storage modulus at Vicat softening temperature of 0.1 MPa or more, a melting temperature of 180 ° C. or higher, or 40 ° C. higher than Vicat softening temperature, and a glass transition temperature of ⁇ 20 ° C. or lower. preferable.
- the translucent insulating resin sheet 14 is preferably an elastomer sheet, and more preferably an acrylic elastomer sheet.
- a translucent insulating resin sheet 14 is disposed on the conductive circuit layer 5 of the translucent support base 2 so as to cover the entire conductive circuit layer 5 (see FIG. 11A).
- the translucent insulating resin sheet 14 has a shape capable of covering the entire conductive circuit layer 5 and the entire translucent insulator 4 including the portion where the light emitting diode 8 is disposed on the conductive circuit layer 5. Have.
- a plurality of light-emitting diodes 8 are arranged on the translucent insulating resin sheet 14 (see FIG. 11B).
- the light emitting diode 8 is disposed so that the electrode 9 on which the conductive bumps 20 are formed is positioned on the translucent insulating resin sheet 14 side, in other words, on the conductive circuit layer 5 side.
- a translucent support base 3 having a conductive circuit layer 7 formed on the translucent insulator surface is disposed on the light emitting diode 8 (see FIG. 11C).
- the light-emitting diode 8 has the electrode 9 positioned on the translucent insulating resin sheet 14 side and the electrode 10 positioned on the translucent support base 3 side. It arrange
- the translucent insulating resin sheet 14 is a translucent support produced by arranging the space between the translucent support base 2 and the translucent support base 3, that is, the light-emitting diodes 8 in a vacuum thermocompression bonding process described below. It is only necessary to have a thickness capable of sufficiently filling the space based on the gap between the base 2 and the translucent support base 3.
- the thickness of the translucent insulating resin sheet 14 can sufficiently fill the gap between the translucent support base 2 and the translucent support base 3 based on the height of the light emitting diode 8 described above. That is good. Further, when the thickness (T) of the translucent insulator 13 is made thinner than the height (H) of the light-emitting diode 8, the translucent insulating resin sheet 14 is made to correspond to these differences (HT). The thickness may be set.
- the laminated body in which the translucent support base 2, the translucent insulating resin sheet 14, the light emitting diode 8, and the translucent support base 2 are sequentially laminated is heated in a vacuum atmosphere. While applying pressure.
- the heating and pressurizing process (vacuum thermocompression bonding process) of the laminate in a vacuum atmosphere is Mp ⁇ 10 (° C.) ⁇ T ⁇ Mp + 30 (° C.) with respect to the Vicat softening temperature Mp (° C.) of the translucent insulating resin sheet 14. It is preferable to apply pressure while heating to a temperature T in the range of A more preferable heating temperature is in the range of Mp ⁇ 10 (° C.) ⁇ T ⁇ Mp + 10 (° C.). By applying such heating conditions, it is possible to pressurize the laminate in a state where the light-transmitting insulating resin sheet 14 is appropriately softened.
- the bumped electrode 9 disposed on the conductive circuit layer 5 is connected to a predetermined position of the conductive circuit layer 5 via the translucent insulating resin sheet 14, and the electrode 10 is connected to the predetermined position of the conductive circuit layer 7.
- the translucent insulating resin sheet 14 softened between the translucent support base 2 and the translucent support base 3 can be embedded to form the translucent insulator 13.
- the heating temperature T at the time of vacuum thermocompression bonding of the laminate is less than 10 (° C.) lower than the Vicat softening temperature Mp of the translucent insulating resin sheet 14 (T ⁇ Mp-10), the translucent insulating resin sheet 14 may be insufficiently softened, and the adhesiveness of the translucent insulating resin sheet 14 (and thus the translucent insulator 13) to the light emitting diode 8 may be reduced.
- the translucent insulating resin sheet 14 (and thus the translucent insulator 13) is satisfactorily provided in the space between the non-formation surface of the electrode 9 and the conductive circuit layer 5 in the light emitting surface of the light emitting diode body 12. There is a possibility that it cannot be filled. If the heating temperature T exceeds 30 (° C.) higher than the Vicat softening temperature Mp of the translucent insulating resin sheet 14 (Mp + 30 ⁇ T), the translucent insulating resin sheet 14 may be excessively softened, resulting in a defective shape or the like. There is.
- connection between the electrode 10 and the conductive circuit layer 7 may be a direct contact, or may be via a conductive adhesive or the like.
- thermocompression bonding step of the laminate in a vacuum atmosphere is preferably performed as follows.
- the above-mentioned laminate is pre-pressurized to bring the constituent members into close contact with each other.
- the laminate is pressurized while being heated to the temperature as described above.
- the light-transmitting insulating resin sheet softened in the space between the light-transmitting support base 2 and the light-transmitting support base 3 by thermocompression bonding the pre-pressurized laminate in a vacuum atmosphere. 14 can be embedded without a gap.
- the vacuum atmosphere during thermocompression bonding is preferably 5 kPa or less.
- the pre-pressurization step can be omitted, in this case, the pre-pressurization step is preferably performed because misalignment or the like is likely to occur in the laminate.
- thermocompression bonding step of the laminate When the thermocompression bonding step of the laminate is performed in an air atmosphere or under a low vacuum, bubbles are likely to remain in the light emitting device 1 after thermocompression bonding, particularly around the light emitting diode 8. Since the air bubbles remaining in the light emitting device 1 are pressurized, they cause swelling of the light emitting device 1 after thermocompression bonding and peeling from the translucent support bases 2 and 3 of the light emitting diode 8. Furthermore, if bubbles or blisters are present inside the light emitting device 1, particularly in the vicinity of the light emitting diode 8, the light is scattered unevenly, which causes a problem in the appearance of the light emitting device 1, which is not preferable.
- generation of bubbles in the light emitting device 1 can be suppressed based on various characteristics of the translucent insulator 13, vacuum thermocompression bonding conditions, and the like. It is preferable that no bubbles having an outer diameter of 500 ⁇ m or more or an outer size of the light emitting diode 8 exist in the light emitting device 1.
- the pressure applied at the time of vacuum thermocompression bonding of the laminate varies depending on the heating temperature, the material and thickness of the translucent insulating resin sheet 14, the final thickness of the translucent insulator 13, and the like. It is preferably in the range of ⁇ 20 MPa, and more preferably in the range of 1 ⁇ 12 MPa.
- the bumped electrode 9 and the conductive circuit are provided.
- a light-transmitting insulator 13 is obtained in which the layer 5 and the electrode 10 are electrically connected to the conductive circuit layer 7 and are in close contact with the periphery of the light-emitting diode 8.
- the space between the non-formation surface of the electrode 9 and the conductive circuit layer 5 in the light emitting surface of the light emitting diode body 12 can be satisfactorily filled with a part of the translucent insulator 13, and bubbles remain. Is suppressed. By these, it becomes possible to obtain the light emitting device 1 that improves the electrical connection reliability between the conductive circuit layers 5 and 7 and the electrodes 9 and 10.
- a light emitting device with improved electrical connectivity and reliability between the conductive circuit layers 5 and 7 and the electrodes 9 and 10 of the light emitting diode 8 is manufactured with high reproducibility. can do.
- the conductive circuit layer 5 is in a state where the contact region in contact with the conductive bump 20 of the light emitting diode 8 is recessed along the conductive bump 20. It has become. Thereby, the area which the conductive bump 20 and the conductive circuit layer 5 contact can be increased. As a result, the resistance between the conductive bump 20 and the conductive circuit layer 5 can be reduced.
- the translucent insulator is a single-layer sheet.
- the translucent insulator is made of two translucent insulating resin sheets, and the two translucent insulating resin sheets are formed.
- the structure shown in FIG. 10 may be obtained by pressurizing the first and second translucent support bases with the light emitting diode sandwiched therebetween.
- LED chips shown in Examples 1 to 7 and Comparative Examples 1 to 7 in Table 1 were prepared.
- the chip thickness was 150 ⁇ m in all cases.
- a bump was formed on the first electrode of the LED chip by a gold wire bonder and rounded to produce a bump having a height shown in Table 1.
- a polyethylene terephthalate sheet having a thickness of 180 ⁇ m was prepared as first and second translucent support bases on which no bumps were formed.
- a conductive circuit layer was produced by forming a silver mesh electrode on the surface of the substrate.
- the Vicat softening temperature is 110 ° C.
- the melting temperature is 220 ° C.
- the glass transition temperature is ⁇ 40 ° C.
- the tensile storage modulus at 0 ° C. is 1.1 GPa
- the tensile storage modulus at 100 ° C. is 0.
- An acrylic elastomer sheet having a tensile storage elastic modulus at 110 ° C. of 3 GPa and a Vicat softening point of 0.2 GPa and a thickness of 60 ⁇ m was prepared as the first and second translucent insulating resin sheets.
- Vicat softening temperature is No. made by Yasuda Seiki Seisakusho.
- the A50 condition described in JIS K7206 (ISO 306) was obtained under the conditions of a test load of 10 N and a heating rate of 50 ° C./hour.
- the glass transition temperature and the melting temperature are in accordance with JIS K7121 (ISO 3146), and a differential heat calorimeter DSC-60 manufactured by Shimadzu Corporation is used for differential heat scanning at a heating rate of 5 ° C./min. It was determined by calorimetry.
- the tensile storage elastic modulus is from -100 ° C to 200 ° C using a DDV-01GP dynamic viscoelasticity automatic measuring instrument manufactured by A & D, in accordance with JIS K7244-4 (ISO 6721-4). It calculated
- a second translucent insulating resin sheet is placed on the conductive circuit layer of the second translucent support base so as to cover the entire conductive circuit layer and translucent insulator, and the second translucent insulating resin
- Six LED chips were arranged at predetermined positions on the sheet. The six LED chips were arranged such that the second electrode was positioned on the second translucent insulating resin sheet side.
- a first translucent insulating resin sheet and a first translucent support base were laminated on six LED chips.
- the first translucent insulating resin sheet was disposed so that the conductive circuit layer of the first translucent support base was positioned on the first translucent insulating resin sheet side.
- the first translucent insulating resin sheet has a shape that covers the entire conductive circuit layer and translucent insulator of the first translucent support base.
- a laminated body in which a second translucent support base, a second translucent insulating resin sheet, an LED chip, a first translucent insulating resin sheet, and a first translucent support base are laminated in order was pre-pressed at a pressure of 0.1 MPa, and the working space was evacuated to 0.1 kPa.
- the laminate was pressed at a pressure of 9.8 MPa while being heated to 120 ° C. in a vacuum atmosphere of 5 kPa. By maintaining this heated / pressurized state for 10 minutes, the first translucent support base and the second translucent support base are electrically connected to each other while electrically connecting the electrode of the LED chip and the conductive circuit layer.
- the first and second translucent insulating resin sheets were embedded between them to form a translucent insulator.
- the characteristics of the light emitting devices of Examples 1 to 7 and Comparative Examples 1 to 9 were evaluated as follows. Six samples were prepared for each of Examples 1 to 7 and Comparative Examples 1 to 9. The six samples in each example were subjected to a bending resistance test described in JIS C5016 (IEC2499-1 and IEC326-2) 8.6 in an energized state. The bending test was performed for all samples in an environment of a temperature of 35 ⁇ 2 ° C., a relative humidity of 60 to 70%, and an atmospheric pressure of 86 to 106 kPa.
- the six samples are bent so that the second conductive circuit layer is inward in the direction orthogonal to the LED chip arrangement direction so that the LED chip row is at the center of the bent portion, and the LED chip arrangement direction
- the minimum bend radius of the sample bent in the direction perpendicular to was examined.
- a plurality of types of measurement cylinders having a uniform radius from 100 mm to 5 mm and having a perfectly circular cross section were prepared.
- the obtained light emitting device was set so that the back surface of the light emitting surface of the LED chip hits the curved surface of the surface of the measuring cylinder.
- the light emitting device was turned on, and in this state, the light emitting device was bent 180 ° along the curved surface of the surface of the measuring cylinder.
- This bending test was performed in order from a measuring cylinder with a large radius to a measuring cylinder with a small radius, and it was measured to which measuring radius of the bending cylinder the lighting state was maintained. The results are shown in Table 1.
- the conductive bump is a wire bump using a wire bonder, electrolytic plating, electroless plating, ink-jet-printed ink containing metal fine particles, printing of paste containing metal fine particles or application ball mounting
- bumps formed by pellet mounting, vapor deposition sputtering, or the like may be used.
- the present invention is not limited thereto, and various forms of conductive bumps such as lift-off bumps can be used.
- the conductive bump can be formed of a mixture of metal fine particles and resin.
- a metal such as silver (Ag) or copper (Cu) or an alloy thereof is mixed with a thermosetting resin to make a paste, and droplets of the paste are sprayed onto the electrode by an ink jet method or a needle dispensing method to form a protrusion.
- the conductive layer bumps may be formed by hardening by heat treatment.
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Abstract
Description
本発明の第1の実施形態に係る発光装置について、図面を参照して説明する。図1は、実施形態に係る発光装置1の概略構成を示す模式断面図である。また、図2は、図1に示す発光装置1の一部を拡大して示す断面図である。
図4A~図4Dは、本実施形態に係る発光装置の製造方法を説明する図である。本実施形態に係る発光装置の製造方法について、図4A~図4Dを参照して説明する。
ボール頂部に残った微小な突起はそのまま残してもよいが、所望によりボール上面を押圧してボール上面の丸め処理を行ってもよい。後者の場合、タンピング処理は、樹脂シートを介してプレス機で行っても良いし、ワイヤボンディング装置の治具先端でボール上面をプレスするようにしても良い。押圧による丸め処理を行った場合は、ボール上面の曲率はボール下部よりやや大きくなる。
積層体の真空雰囲気中での熱圧着工程は、以下のようにして実施することが好ましい。上述した積層体を予備加圧して各構成部材間を密着させる。次いで、予備加圧された積層体が配置された作業空間を真空引きした後、積層体を上記したような温度に加熱しながら加圧する。このように、予備加圧された積層体を真空雰囲気中で熱圧着することによって、透光性支持基体2と透光性支持基体3との間の空間に軟化させた透光性絶縁樹脂シート13’を隙間なく埋め込むことができる。
次に、本発明の第2の実施形態に係る発光装置について、図面を参照して説明する。なお、第1の実施形態に係る発光装置と同等の構成については、説明を省略する。
図11A~図11Dは、本実施形態に係る発光装置の製造方法を説明する図である。本実施形態に係る発光装置1の製造方法について、図11A~図11Dを参照して説明する。
積層体の真空雰囲気中での熱圧着工程は、以下のようにして実施することが好ましい。上述した積層体を予備加圧して各構成部材間を密着させる。次いで、予備加圧された積層体が配置された作業空間を真空引きした後、積層体を上記したような温度に加熱しながら加圧する。このように、予備加圧された積層体を真空雰囲気中で熱圧着することによって、透光性支持基体2と透光性支持基体3との間の空間に軟化させた透光性絶縁樹脂シート14を隙間なく埋め込むことができる。
2 透光性支持基体
3 透光性支持基体
4 透光性絶縁体
5 導電回路層
6 透光性絶縁体
7 導電回路層
8 発光ダイオード
9,10 電極
11 発光層
12 発光ダイオード本体
13 透光性絶縁体
13’,14 透光性絶縁樹脂シート
16,17 半導体層
20 導電性バンプ
22 発光ダイオード
23 絶縁基板
25 活性層
27 発光ダイオード本体
28,29 電極
30 導電性バンプ
100,200 樹脂シート
Claims (17)
- 第1の透光性絶縁体と、前記第1の透光性絶縁体の表面に設けられた導電回路層とを備える第1の透光性支持基体と、
第2の透光性絶縁体を備え、前記第2の透光性絶縁体の表面が前記導電回路層と対向するように、前記第1の透光性支持基体との間に所定の間隙を持って配置された第2の透光性支持基体と、
ダイオード本体と、前記ダイオード本体の一方面に設けられ、前記導電回路層と導電性バンプを介して電気的に接続された第1および第2の電極とを有し、前記第1の透光性支持基体と前記第2の透光性支持基体との間隙に配置された発光ダイオードと、
前記第1の透光性支持基体と前記第2の透光性支持基体との間の空間に埋め込まれた、第3の透光性絶縁体とを具備する発光装置。 - 第1の透光性絶縁体と、前記第1の透光性絶縁体の表面に設けられた第1の導電回路層とを備える第1の透光性支持基体と、
第2の透光性絶縁体と、前記第2の透光性絶縁体の表面に設けられた第2の導電回路層とを備え、前記第2の導電回路層が前記第1の導電回路層と対向するように、前記第1の透光性支持基体との間に所定の間隙を持って配置された第2の透光性支持基体と、
ダイオード本体と、前記ダイオード本体の一方面に設けられ、前記第1の導電回路層と導電性バンプを介して電気的に接続された第1の電極と、前記ダイオード本体の反対面に設けられ、前記第2の導電回路層と電気的に接続された第2の電極とを備え、前記第1の透光性支持基体と前記第2の透光性支持基体との間隙に配置された発光ダイオードと、
前記第1の透光性支持基体と前記第2の透光性支持基体との間の空間に埋め込まれた、第3の透光性絶縁体とを具備する発光装置。 - 前記導電性バンプの形状は、前記発光ダイオードの電極に接している面の直径をA、前記導電性バンプの高さをBとした場合、B/A=0.2~0.7を満たしている請求項1又は2記載の発光装置。
- 前記導電性バンプの高さは、5μm以上50μm以下である請求項1乃至3のいずれか一項に記載の発光装置。
- 前記導電性バンプと前記第1の電極との接触面積および前記導電性バンプと前記第2の電極との接触面積は、それぞれ、100μm2以上15,000μm2以下である請求項1乃至4のいずれか一項に記載の発光装置。
- 前記導電性バンプの材質は、金、銀、銅、ニッケル、又はこれらの合金のいずれかである請求項1乃至5のいずれか一項に記載の発光装置。
- 前記合金は、AuSn合金、ニッケル合金である請求項6記載の発光装置。
- 前記導電性バンプは、金属微粒子と樹脂の混合物である請求項1乃至5のいずれか一項に記載の発光装置。
- 前記導電性バンプの融点は、180℃以上である請求項1乃至8のいずれか一項に記載の発光装置。
- 前記導電性バンプのダイナミック硬さは3以上150以下である請求項1乃至9のいずれか一項に記載の発光装置。
- 前記導電性バンプの上面は、丸め処理を施してある請求項3に記載の発光装置。
- 前記発光ダイオード表面から前記導電性バンプの頂上までの距離と前記導電性バンプの中心から前記発光ダイオードの最遠端部までの距離の比が、0.120以上0.400以下である請求項2記載の発光装置。
- 前記導電回路層は、前記導電性バンプに沿って窪んでいる請求項1乃至12のいずれか一項に記載の発光装置。
- 前記発光ダイオードは、前記第3の透光性絶縁体に埋め込まれている請求項1乃至13のいずれか一項に記載の発光装置。
- 第1の透光性絶縁体と、前記第1の透光性絶縁体上に設けられた導電回路層とを有する第1の透光性支持基体と、
第2の透光性絶縁体を有し、前記第1透光性支持基体と所定の間隙を持って配置された第2の透光性支持基体と、
ダイオード本体と、前記ダイオード本体と前記導電回路層を導電性部材を介して電気的に接続する電極と、を有し、かつ前記第1の透光性支持基体と前記第2の透光性支持基体との間に配置された発光ダイオードと、
前記第1の透光性支持基体と前記第2の透光性支持基体との間隙に設けられた第3の透光性絶縁体とを備え
前記電極と前記導電回路層は直接接触することなく、前記導電性部材が前記導電回路層と直接接触していることを特徴とする発光装置。 - 第1の透光性支持基体と第2の透光性支持基体との間に、発光ダイオードと透光性絶縁体を埋め込んだ発光装置の製造方法であって、
第1の透光性絶縁体と、前記第1の透光性絶縁体の表面に設けられた導電回路層とを備える第1の透光性支持基体を用意する工程と、
ダイオード本体と、前記ダイオード本体の一方面に設けられた第1の電極と第2の電極とを有する発光ダイオードを用意し、前記第1の電極および前記第2の電極上に導電性パンプを形成する工程と、
前記導電回路層上に、透光性絶縁樹脂シートを配置する工程と、
前記透光性絶縁樹脂シート上に、前記第1の電極および第2の電極が前記透光性絶縁樹脂シート側に位置するように前記発光ダイオードを配置する工程と、
前記第1の透光性支持基体、前記透光性絶縁樹脂シート、前記発光ダイオードが順に積層された積層体を、減圧下で加熱しながら加圧し、前記第1の電極と前記導電回路層および前記第2の電極と前記導電回路層とを前記導電性バンプを介して電気的に接続する工程とを具備する発光装置の製造方法。 - 第1の透光性支持基体と第2の透光性支持基体との間に、発光ダイオードと透光性絶縁体を埋め込んだ発光装置の製造方法であって、
第1の透光性絶縁体と、前記第1の透光性絶縁体の表面に設けられた第1の導電回路層とを備える第1の透光性支持基体を用意する工程と、
第2の透光性絶縁体と、前記第2の透光性絶縁体の表面に設けられた第2の導電回路層とを備える第2の透光性支持基体を用意する工程と、
ダイオード本体と、前記ダイオード本体の一方面に設けられた第1の電極と、前記ダイオード本体の反対面に設けられた第2の電極とを備える発光ダイオードを用意し前記第1の電極上に導電性バンプを形成する工程と、
前記第1の透光性支持基体の前記第1の導電回路層上に、透光性絶縁樹脂シートを配置する工程と、
前記透光性絶縁樹脂シートを配置した第1の透光性支持基体と前記第2の透光性支持基体との間に、前記第1の電極が第1の透光性絶縁樹脂シート側に位置するように前記発光ダイオードを配置する工程と、
前記第1の透光性支持基体、前記第1の透光性絶縁樹脂シート、前記発光ダイオード、前記第2の透光性支持基体が積層された積層体を減圧下で加熱しながら加圧し、前記第1の電極を導電性バンプを介して前記第1の導電回路層と、また前記第2の電極と前記第2の導電回路層とを電気的に接続する工程と、
を具備する発光装置の製造方法。
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JP6920375B2 (ja) | 2021-08-18 |
JPWO2015083365A1 (ja) | 2017-03-16 |
EP3079177A4 (en) | 2016-12-28 |
CN109119412A (zh) | 2019-01-01 |
CN105518884B (zh) | 2018-10-26 |
CN105518884A (zh) | 2016-04-20 |
US20160276561A1 (en) | 2016-09-22 |
US10483443B2 (en) | 2019-11-19 |
EP3079177A1 (en) | 2016-10-12 |
US10910539B2 (en) | 2021-02-02 |
EP3079177B1 (en) | 2020-03-25 |
JP6560123B2 (ja) | 2019-08-14 |
JP2019216246A (ja) | 2019-12-19 |
US20200044130A1 (en) | 2020-02-06 |
CN109119412B (zh) | 2022-05-31 |
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