WO2015046559A1 - ニトリル共重合体ゴムおよびその製造方法 - Google Patents
ニトリル共重合体ゴムおよびその製造方法 Download PDFInfo
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- WO2015046559A1 WO2015046559A1 PCT/JP2014/076019 JP2014076019W WO2015046559A1 WO 2015046559 A1 WO2015046559 A1 WO 2015046559A1 JP 2014076019 W JP2014076019 W JP 2014076019W WO 2015046559 A1 WO2015046559 A1 WO 2015046559A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/16—Purification
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/22—Coagulation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
Definitions
- the present invention relates to a nitrile copolymer rubber and a method for producing the same, and more particularly to a nitrile copolymer rubber capable of providing a crosslinked rubber having excellent heat resistance and compression set resistance and a method for producing the same.
- rubber nitrile copolymer rubber containing an ⁇ , ⁇ -ethylenically unsaturated nitrile monomer unit and a conjugated diene monomer unit or an olefin monomer unit is a rubber having excellent oil resistance.
- This vulcanizate is mainly used as a material for rubber products around various oils of automobiles such as fuel hoses, gaskets, packings and oil seals.
- Such a nitrile copolymer rubber is generally produced by emulsion polymerization using an emulsifier.
- emulsion polymerization is performed using sodium dodecylbenzenesulfonate as an emulsifier, paramentane hydroperoxide as a radical initiator, and t-dodecyl mercaptan as a chain transfer agent.
- Copolymer rubber has been obtained.
- the nitrile copolymer rubber obtained by the technique of Patent Document 1 does not necessarily have sufficient compression set resistance in the case of a rubber cross-linked product, and therefore further improvement in compression set resistance is required. It was.
- An object of the present invention is to provide a nitrile copolymer rubber capable of providing a rubber cross-linked product excellent in heat resistance and compression set resistance and a method for producing the same.
- the present inventor has obtained by emulsion polymerization using 2,2,4,6,6-pentamethylheptane-4-thiol as a chain transfer agent, and has a polymer pH of 8
- the present inventors have found that the above object can be achieved by a nitrile copolymer rubber having a molecular weight of .5 or less, and have completed the present invention.
- a coalesced rubber is provided.
- the nitrile copolymer rubber of the present invention preferably has a polymer pH of 8.0 or less.
- the nitrile copolymer rubber is 2, 2, 4, 6 to 100 parts by weight of a monomer mixture containing an ⁇ , ⁇ -ethylenically unsaturated nitrile monomer and a conjugated diene monomer.
- 6-pentamethylheptane-4-thiol is preferably obtained by emulsion polymerization using 0.1 to 1 part by weight as a chain transfer agent.
- the content ratio of ⁇ , ⁇ -ethylenically unsaturated nitrile monomer unit in 10% by weight of all monomer units is 10 to 60% by weight, The content ratio of the monomer unit is preferably 40 to 90% by weight.
- a crosslinkable nitrile copolymer rubber composition obtained by blending a crosslinking agent with the nitrile copolymer rubber, and a rubber obtained by crosslinking the crosslinkable nitrile copolymer rubber composition.
- a cross-linked product is provided.
- a monomer mixture containing an ⁇ , ⁇ -ethylenically unsaturated nitrile monomer and a conjugated diene monomer is used as a chain transfer agent for 2,2,4,6,6.
- -A step of obtaining a latex of a nitrile copolymer rubber by emulsion polymerization using pentamethylheptane-4-thiol, and a mixture obtained by mixing the latex of the nitrile copolymer rubber and a coagulant There is provided a method for producing a nitrile copolymer rubber having a step of obtaining a coagulated crumb by coagulating under a condition that the pH of the liquid is less than 7.0, and a step of drying the coagulated crumb.
- nitrile copolymer rubber capable of providing a rubber cross-linked product excellent in heat resistance and compression set resistance and a method for producing the same.
- Nitrile Copolymer Rubber The nitrile copolymer rubber of the present invention is obtained by emulsion polymerization using 2,2,4,6,6-pentamethylheptane-4-thiol as a chain transfer agent, and the polymer pH is 8. 5 or less.
- the nitrile copolymer rubber of the present invention is obtained by, for example, converting a monomer mixture containing an ⁇ , ⁇ -ethylenically unsaturated nitrile monomer and a conjugated diene monomer into 2,2,4,6,6. It can be obtained by emulsion polymerization using pentamethylheptane-4-thiol as a chain transfer agent.
- the ⁇ , ⁇ -ethylenically unsaturated nitrile monomer is not limited as long as it is an ⁇ , ⁇ -ethylenically unsaturated compound having a nitrile group, and ⁇ - ⁇ such as acrylonitrile; ⁇ -chloroacrylonitrile, ⁇ -bromoacrylonitrile, etc. Halogenoacrylonitrile; ⁇ -alkylacrylonitriles such as methacrylonitrile; and the like. Acrylonitrile and methacrylonitrile are preferred. These ⁇ , ⁇ -ethylenically unsaturated nitrile monomers may be used in combination.
- the content of the ⁇ , ⁇ -ethylenically unsaturated nitrile monomer unit in the nitrile copolymer rubber of the present invention is preferably 10 to 60% by weight, more preferably 100% by weight, based on 100% by weight of all monomer units. Is 15 to 55% by weight, particularly preferably 20 to 50% by weight. If the content of the ⁇ , ⁇ -ethylenically unsaturated nitrile monomer unit is too small, the oil resistance of the resulting rubber cross-linked product may be lowered. Conversely, if it is too much, cold resistance may be lowered. .
- the conjugated diene monomer is preferably a conjugated diene monomer having 4 to 6 carbon atoms such as 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, chloroprene.
- 1,3-butadiene and isoprene are more preferred, and 1,3-butadiene is particularly preferred. Of these, 1,3-butadiene is preferred.
- the content of the conjugated diene monomer unit in the nitrile copolymer rubber of the present invention is preferably 40 to 90% by weight, more preferably 45 to 85% by weight, based on 100% by weight of the total monomer units. Particularly preferred is an amount of 50 to 80% by weight. If the content of the conjugated diene monomer unit is too low, the elasticity of the resulting rubber cross-linked product may be reduced. If it is too high, the rubber cross-linked product will have oil resistance, heat aging resistance, chemical stability, etc. It can be damaged.
- the nitrile copolymer rubber of the present invention is obtained by copolymerizing an ⁇ , ⁇ -ethylenically unsaturated nitrile monomer, a conjugated diene monomer, and another copolymerizable monomer. May be.
- Such other monomers include ethylene, ⁇ -olefin monomers, ⁇ , ⁇ -ethylenically unsaturated carboxylic acid ester monomers, ⁇ , ⁇ -ethylenically unsaturated carboxylic acid monomers, ⁇ , ⁇ -ethylenically unsaturated polyvalent carboxylic acid anhydride monomer, aromatic vinyl monomer, fluorine-containing vinyl monomer, copolymerizable anti-aging agent and the like.
- the ⁇ -olefin monomer preferably has 3 to 12 carbon atoms, and examples thereof include propylene, 1-butene, 4-methyl-1-pentene, 1-hexene and 1-octene.
- Examples of the ⁇ , ⁇ -ethylenically unsaturated carboxylic acid ester monomer include methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, n-dodecyl acrylate, methyl methacrylate, and ethyl methacrylate.
- the hydroxyalkyl group has 1 to 12 carbon atoms; fluorine-substituted benzyl group-containing acrylic ester such as fluorobenzyl acrylate and fluorobenzyl methacrylate; and fluorine-substituted benzyl group-containing methacrylate ester; trifluoroacrylate Fluoroalkyl group-containing acrylic acid ester and fluoroalkyl group-containing methacrylic acid ester such as ethyl and tetrafluoropropyl methacrylate; dimethyl maleate, dimethyl fumarate, dimethyl itaconate, And unsaturated polyvalent carboxylic acid polyalkyl esters such as diethyl itaconate; and amino group-containing ⁇ , ⁇ -ethylenically unsaturated carboxylic acid esters such as dimethylaminomethyl acrylate and diethylaminoethyl acrylate.
- Examples of the ⁇ , ⁇ -ethylenically unsaturated carboxylic acid monomer include ⁇ , ⁇ -ethylenically unsaturated monocarboxylic acids such as acrylic acid and methacrylic acid; ⁇ , ⁇ such as maleic acid, fumaric acid, and itaconic acid.
- -Ethylenically unsaturated polycarboxylic acid monoalkyl maleate such as monomethyl maleate, monoethyl maleate, monopropyl maleate, mono n-butyl maleate, monocyclopentyl maleate, monocyclohexyl maleate, mono maleate
- Maleic acid monocycloalkyl esters such as cycloheptyl, maleic acid monomethylcyclopentyl, maleic acid monoalkylcycloalkyl esters such as monoethylcyclohexyl maleate, monomethyl fumarate, monoethyl fumarate, monopropyl fumarate, mono-fumarate
- Monoalkyl esters of fumarate such as monoalkyl fumarate such as til, monocyclopentyl fumarate, monocyclohexyl fumarate and monocycloheptyl fumarate, monomethylcyclopentyl fumarate and monoethylcyclohexyl fumarate
- Examples of the ⁇ , ⁇ -ethylenically unsaturated polyvalent carboxylic acid anhydride monomer include maleic anhydride.
- Examples of the aromatic vinyl monomer include styrene, ⁇ -methylstyrene, vinyl pyridine and the like.
- fluorine-containing vinyl monomer examples include fluoroethyl vinyl ether, fluoropropyl vinyl ether, o-trifluoromethylstyrene, vinyl pentafluorobenzoate, difluoroethylene, and tetrafluoroethylene.
- copolymerizable anti-aging agents examples include N- (4-anilinophenyl) acrylamide, N- (4-anilinophenyl) methacrylamide, N- (4-anilinophenyl) cinnamamide, N- (4-anilino). Phenyl) crotonamide, N-phenyl-4- (3-vinylbenzyloxy) aniline, N-phenyl-4- (4-vinylbenzyloxy) aniline and the like.
- the content of these other monomer units in the nitrile copolymer rubber of the present invention is preferably 30% by weight or less, more preferably 15% by weight or less, in 100% by weight of all monomer units.
- the amount is particularly preferably 5% by weight or less.
- the nitrile copolymer rubber of the present invention has a polymer pH of 8.5 or less, preferably 8.0 or less.
- the polymer pH is preferably 1 or more, more preferably 2 or more, and still more preferably 5 or more.
- the polymer pH is the pH of the component contained in the dried rubber, and can be determined, for example, by the following method. That is, a rubber solution is obtained by dissolving 6 g of dried rubber in 100 g of a soluble solvent (for example, tetrahydrofuran). And it can obtain
- a nitrile copolymer rubber obtained by emulsion polymerization using 2,2,4,6,6-pentamethylheptane-4-thiol as a chain transfer agent and having a polymer pH of 8.5 or less is used.
- the heat resistance and compression set resistance in the case of a rubber cross-linked product can be improved.
- the polymer pH of the nitrile copolymer rubber exceeds 8.5, the compression set resistance of the resulting rubber cross-linked product is deteriorated.
- the method for controlling the polymer pH of the nitrile copolymer rubber to 8.5 or lower is not particularly limited.
- the rubber latex obtained by polymerization is coagulated, it can be controlled by adjusting the pH during coagulation.
- the nitrile copolymer rubber of the present invention is obtained by emulsion polymerization using 2,2,4,6,6-pentamethylheptane-4-thiol as a chain transfer agent.
- the amount of 2,2,4,6,6-pentamethylheptane-4-thiol used in the emulsion polymerization is not particularly limited. However, since the effect of the present invention becomes more remarkable, ⁇ , ⁇ -ethylenic unsaturation 0.1 to 1 part by weight of 2,2,4,6,6-pentamethylheptane-4-thiol is added to 100 parts by weight of a monomer mixture containing a nitrile monomer and a conjugated diene monomer.
- the Mooney viscosity [ML 1 + 4 (100 ° C.)] of the nitrile copolymer rubber of the present invention is preferably 10 to 200, more preferably 20 to 150, and particularly preferably 20 to 100.
- the Mooney viscosity of the nitrile copolymer rubber can be adjusted by appropriately selecting conditions such as the amount of chain transfer agent, polymerization reaction temperature, and polymerization initiator concentration.
- the method for producing a nitrile copolymer rubber of the present invention comprises a monomer mixture containing an ⁇ , ⁇ -ethylenically unsaturated nitrile monomer and a conjugated diene monomer.
- 2,2,4,6,6-pentamethylheptane-4-thiol can be used as a chain transfer agent, and commonly used polymerization auxiliary materials such as emulsifiers and polymerization initiators can be used.
- the monomer mixture containing the ⁇ , ⁇ -ethylenically unsaturated nitrile monomer and the conjugated diene monomer is the same as described above.
- ⁇ , ⁇ -ethylenically unsaturated nitrile monomer acrylonitrile and methacrylonitrile are preferable.
- conjugated diene monomer 1,3-butadiene and isoprene are preferable, and 1,3-butadiene is more preferable.
- Other monomers that can be copolymerized include ethylene, ⁇ -olefin monomer, ⁇ , ⁇ -ethylenically unsaturated carboxylic acid ester monomer, ⁇ , ⁇ -ethylenically unsaturated carboxylic acid monomer , ⁇ , ⁇ -ethylenically unsaturated polyvalent carboxylic acid anhydride monomer, aromatic vinyl monomer, fluorine-containing vinyl monomer, copolymerizable anti-aging agent, etc. It is the same as what I did.
- the content ratio of the ⁇ , ⁇ -ethylenically unsaturated nitrile monomer in the monomer mixture containing the ⁇ , ⁇ -ethylenically unsaturated nitrile monomer and the conjugated diene monomer The amount is preferably 10 to 60 parts by weight, more preferably 15 to 55 parts by weight, and particularly preferably 20 to 50 parts by weight in 100 parts by weight of the mixture.
- the content of the conjugated diene monomer is preferably 40 to 90 parts by weight, more preferably 45 to 85 parts by weight, and particularly preferably 50 to 80 parts by weight in 100 parts by weight of the total monomer mixture. .
- the content of other copolymerizable monomers is preferably 30 parts by weight or less, more preferably 15 parts by weight or less, and particularly preferably 5 parts by weight or less in 100 parts by weight of the total monomer mixture. is there.
- nonionic emulsifiers such as polyoxyethylene alkyl ether, polyoxyethylene alkyl phenol ether, polyoxyethylene alkyl ester, polyoxyethylene sorbitan alkyl ester; myristic acid, palmitic acid, oleic acid And anionic emulsifiers such as salts of fatty acids such as linolenic acid, alkylbenzene sulfonates such as sodium dodecylbenzene sulfonate, higher alcohol sulfates, and alkyl sulfosuccinates; sulfoesters of ⁇ , ⁇ -unsaturated carboxylic acids, ⁇ , ⁇ -unsaturated carboxylic acid sulfate esters, sulfoalkyl aryl ethers and other copolymerizable emulsifiers.
- the amount of the emulsifier used is preferably 0.1
- the polymerization initiator is not particularly limited as long as it is a radical initiator, but inorganic peroxides such as potassium persulfate, sodium persulfate, ammonium persulfate, potassium perphosphate, hydrogen peroxide; t-butyl peroxide, cumene Hydroperoxide, p-menthane hydroperoxide, di-t-butyl peroxide, t-butylcumyl peroxide, acetyl peroxide, isobutyryl peroxide, octanoyl peroxide, dibenzoyl peroxide, 3, 5, 5 Organic peroxides such as trimethylhexanoyl peroxide and t-butylperoxyisobutyrate; azobisisobutyronitrile, azobis-2,4-dimethylvaleronitrile, azobiscyclohexanecarbonitrile, methyl azobisisobutyrate, etc.
- inorganic peroxides
- polymerization initiators can be used alone or in combination of two or more.
- an inorganic or organic peroxide is preferable.
- a peroxide is used as the polymerization initiator, it can be used as a redox polymerization initiator in combination with a reducing agent such as sodium bisulfite or ferrous sulfate.
- the amount of the polymerization initiator used is preferably 0.01 to 2 parts by weight with respect to 100 parts by weight of all monomers used for the polymerization.
- 2,2,4,6,6-pentamethylheptane-4-thiol is used as the chain transfer agent.
- 2,2,4,6,6-pentamethylheptane-4-thiol and other serial transfer agents may be used in combination, but 2,2 in all chain transfer agents.
- 4,6,6-pentamethylheptane-4-thiol is not less than 50% by weight, preferably not less than 70% by weight, particularly preferably not less than 90% by weight.
- the amount of 2,2,4,6,6-pentamethylheptane-4-thiol used in the emulsion polymerization is not particularly limited, but the effect of the present invention becomes even more remarkable. It is preferable to use 0.1 to 1 part by weight, based on 100 parts by weight of the monomer mixture containing an unsaturated nitrile monomer and a conjugated diene monomer, and 0.2 to 0.6 parts by weight. More preferably, is used.
- Water is usually used as the emulsion polymerization medium.
- the amount of water used is preferably 80 to 500 parts by weight with respect to 100 parts by weight of the total monomers.
- polymerization auxiliary materials such as a stabilizer, a dispersant, a pH adjuster, an oxygen scavenger, and a particle size adjuster can be used as necessary. In using these, neither the kind nor the usage-amount is specifically limited.
- the temperature for emulsion polymerization is preferably 0 to 80 ° C., more preferably 0 to 50 ° C., and particularly preferably 0 to 30 ° C.
- the polymerization conversion rate of emulsion polymerization is preferably 50 to 95%, more preferably 70 to 90%.
- the latex of the nitrile copolymer rubber obtained by emulsion polymerization in order to hydrogenate the carbon-carbon unsaturated bond in the obtained nitrile copolymer rubber A hydrogenation reaction may be performed.
- the type and amount of the hydrogenation catalyst used in the hydrogenation reaction, the hydrogenation temperature, etc. may be determined according to known methods.
- the latex of the nitrile copolymer rubber obtained by emulsion polymerization and the coagulant are mixed to obtain a coagulated crumb.
- the mixing method of the nitrile copolymer rubber latex and the coagulant is not particularly limited.
- the nitrile copolymer Examples include a method of adding a coagulant (preferably an aqueous solution) to rubber latex, and the method (i) above is preferable.
- the pH at the time of coagulation that is, the nitrile
- the pH of the mixture obtained by mixing the latex of the copolymer rubber and the coagulant is adjusted to less than 7.0, preferably 6.0 or less.
- 1.0 or more is preferable, as for the minimum of pH at the time of solidifying, 2.0 or more is more preferable, and 5.0 or more is further more preferable.
- an aqueous solution containing a coagulant for example, when using a method of adding salt of nitrile copolymer rubber to an aqueous solution containing a coagulant and salting out, an aqueous solution containing a coagulant And a method of adjusting the pH to the above range by adding an inorganic acid such as sulfuric acid.
- the coagulant used for coagulation is not particularly limited, and examples include calcium chloride, sodium chloride, calcium hydroxide, aluminum sulfate, and aluminum hydroxide.
- the amount of the coagulant used is preferably 0.5 to 150 parts by weight, more preferably 0.5 to 20 parts by weight with respect to 100 parts by weight of the solid content in the latex of the nitrile copolymer rubber.
- the solidified crumbs thus obtained can be washed with water as necessary and dried to obtain the nitrile copolymer rubber of the present invention. Washing with water and drying can be performed by known methods.
- Crosslinkable nitrile copolymer rubber composition The crosslinkable nitrile copolymer rubber composition of the present invention is obtained by blending a crosslinking agent with the nitrile copolymer rubber of the present invention described above.
- any known rubber crosslinking agent can be used, and examples thereof include a sulfur-based crosslinking agent and an organic peroxide-based crosslinking agent.
- Sulfur-based cross-linking agents include powdered sulfur, sulfur white, precipitated sulfur, colloidal sulfur, surface-treated sulfur, insoluble sulfur, and the like; sulfur chloride, sulfur dichloride, morpholine disulfide, alkylphenol disulfide, dibenzothiazyl disulfide, N, Sulfur-containing compounds such as N′-dithio-bis (hexahydro-2H-azenopine-2), phosphorus-containing polysulfides, polymer polysulfides; tetramethylthiuram disulfide, selenium dimethyldithiocarbamate, 2- (4′-morpholinodithio) And sulfur donating compounds such as benzothiazole;
- organic peroxide crosslinking agents include dicumyl peroxide, cumene hydroperoxide, t-butylcumyl peroxide, paramentane hydroperoxide, di-t-butyl peroxide, 1,3-bis (t-butyl
- crosslinking agents sulfur-based crosslinking agents are preferable, and sulfur is more preferable.
- the blending amount of the crosslinking agent in the crosslinkable nitrile copolymer rubber composition of the present invention is preferably 0.1 to 10 parts by weight, more preferably 0.2 parts per 100 parts by weight of the nitrile copolymer rubber. ⁇ 5 parts by weight.
- the crosslinkable nitrile copolymer rubber composition of the present invention has a reinforcing property such as carbon black, zinc acrylate and zinc methacrylate other than the crosslinking agent, which is usually used in the rubber processing field.
- Fillers Non-reinforcing fillers such as calcium carbonate and clay, antioxidants, light stabilizers, scorch inhibitors such as primary amines, plasticizers, processing aids, lubricants, adhesives, lubricants, flame retardants, An acid agent, an antifungal agent, an antistatic agent, a colorant, a silane coupling agent, a crosslinking accelerator, a crosslinking assistant, a crosslinking retarder, and the like can be blended.
- the compounding amount of these compounding agents an amount corresponding to the compounding purpose can be appropriately adopted.
- the crosslinkable nitrile copolymer rubber composition of the present invention is prepared by mixing the above components, preferably in a non-aqueous system.
- the method for preparing the crosslinkable nitrile copolymer rubber composition of the present invention is not limited, but usually the components excluding the crosslinking agent and the thermally unstable crosslinking aid are used as Banbury mixers, intermixers, kneaders, etc. After first kneading with this mixer, it can be prepared by transferring to a roll or the like and adding a cross-linking agent or a heat-labile cross-linking aid, etc., followed by secondary kneading.
- the Mooney viscosity [ML 1 + 4 (100 ° C.)] (compound Mooney) of the crosslinkable nitrile copolymer rubber composition of the present invention thus obtained is preferably 15 to 150, more preferably 40 to 120.
- Cross-linked rubber The cross-linked rubber of the present invention is obtained by cross-linking the cross-linkable nitrile copolymer rubber composition of the present invention described above.
- the rubber cross-linked product of the present invention uses the cross-linkable nitrile copolymer rubber composition of the present invention and is molded by, for example, a molding machine corresponding to a desired shape, such as an extruder, an injection molding machine, a compressor, or a roll. It can be produced by carrying out a cross-linking reaction by heating and fixing the shape as a cross-linked product. In this case, crosslinking may be performed after molding in advance, or crosslinking may be performed simultaneously with molding.
- the molding temperature is usually 10 to 200 ° C, preferably 25 to 120 ° C.
- the crosslinking temperature is usually 100 to 200 ° C., preferably 130 to 190 ° C.
- the crosslinking time is usually 1 minute to 24 hours, preferably 2 minutes to 6 hours.
- a heating method a general method used for crosslinking of rubber such as press heating, steam heating, oven heating, hot air heating, etc. may be appropriately selected.
- the rubber cross-linked product of the present invention is obtained by using the nitrile copolymer rubber of the present invention described above, it has excellent heat resistance and compression set resistance. Therefore, the rubber cross-linked product of the present invention makes use of its properties and seal members such as packings, gaskets, O-rings and oil seals; hoses such as oil hoses, fuel hoses, inlet hoses, gas hoses, brake hoses, refrigerant hoses; It can be suitably used for diaphragms, accumulator pradas, boots, and the like, but can be particularly suitably used as a seal member.
- seal members such as packings, gaskets, O-rings and oil seals
- hoses such as oil hoses, fuel hoses, inlet hoses, gas hoses, brake hoses, refrigerant hoses
- It can be suitably used for diaphragms, accumulator pradas, boots, and the like, but can be particularly suitably
- composition of Nitrile Copolymer Rubber The content ratio of acrylonitrile units in the nitrile copolymer rubber was calculated by measuring the nitrogen content in the nitrile copolymer rubber by the Kjeldahl method according to JIS K6383.
- Mooney viscosity (Polymer Mooney) The Mooney viscosity (polymer Mooney) of the nitrile copolymer rubber was measured according to JIS K6300 (unit: (ML 1 + 4 , 100 ° C.)).
- the polymer pH of the nitrile copolymer rubber was measured by the following procedure. That is, first, the nitrile copolymer rubber formed into a sheet with a roll was finely cut with scissors, and 6 g ( ⁇ 0.05 g) of the cut nitrile copolymer rubber was weighed. Next, 6 g of the weighed nitrile copolymer rubber was added to an Erlenmeyer flask containing 100 g of tetrahydrofuran, and dissolved in tetrahydrofuran by stirring.
- crosslinkability test The crosslinkable nitrile copolymer rubber composition was subjected to a condition of 160 ° C. in accordance with JIS K6300-2 using a rubber vulcanization tester (trade name “Moving Direometer MDR”, manufactured by Alpha Technologies). A crosslinkability test was conducted. From the results of the obtained crosslinkability test, the minimum torque value ML (unit: dN ⁇ m), the maximum torque value MH (unit: dN ⁇ m), t10 (unit: min.), And t90 (unit: min.) was measured.
- t10 and t90 are the time required for the torque to increase 10% from the minimum torque ML, respectively, and 90% increase when “maximum torque MH ⁇ minimum torque ML” is 100%. It means the time it takes to do.
- a cross-linkable nitrile copolymer rubber composition is placed in a mold having a length of 15 cm, a width of 15 cm, and a depth of 0.2 cm, and press-molded at 160 ° C. for 20 minutes while being pressed at a press pressure of 10 MPa. Got. Next, the obtained sheet-like rubber cross-linked product was punched out with a No. 3 dumbbell to prepare a test piece.
- Heat Aging Test After obtaining the same sheet-like cross-linked product used for the evaluation of the above normal physical properties, it was punched with a JIS No. 3 dumbbell to prepare a test piece. Using the obtained test piece, in accordance with the provisions of JIS K6257 “Aging Test Method for Vulcanized Rubber”, Section 4 “Air Heated Aging Test (Normal Oven Method)”, air was used at 100 ° C. for 70 hours. Heat aging treatment was performed. Test specimens (test specimens after heat aging) subjected to air heating aging treatment are subjected to tensile stress (100% tensile stress, 200% tensile stress) and elongation according to JIS K6251, and durometer hardness test according to JIS K6253.
- the hardness was measured using a machine (type A). From these measurement results, the elongation change rate, tensile stress change rate (100% tensile stress change rate, 200% tensile stress change rate), and hardness change amount were obtained from the following formulas. The smaller the absolute value of the tensile stress change rate, elongation change rate, and hardness change amount, the better the heat aging resistance.
- Tensile stress change rate (%) ⁇ ((tensile stress after thermal aging) ⁇ (tensile stress in normal state)) / (tensile stress in normal state) ⁇ ⁇ 100
- Elongation change rate (%) ⁇ ((Elongation after heat aging) ⁇ (Elongation in normal state)) / (Elongation in normal state) ⁇ ⁇ 100
- Hardness change (Hardness after heat aging)-(Normal hardness)
- the compression-set-rate crosslinkable nitrile copolymer rubber composition was crosslinked by pressing at a temperature of 160 ° C. for 30 minutes to obtain a cylindrical rubber crosslinked product having a diameter of 29 mm and a height of 12.7 mm. Then, using the obtained rubber cross-linked product according to JIS K6262, the rubber cross-linked product was compressed by 25% and placed in an environment of 100 ° C. for 70 hours, and then the compression was released to obtain the compression set rate. It was measured. The smaller the value of the compression set, the better the compression set resistance.
- Synthesis example 1 In a reaction vessel having an internal volume of 10 liters, 2 parts of potassium oleate (emulsifier), 0.1 part of potassium phosphate (stabilizer) and 200 parts of water were charged, and 25 parts of acrylonitrile, and 2,2,2, 0.40 part of 4,6,6-pentamethylheptane-4-thiol (PMHT, chain transfer agent) was added. After replacing the internal gas with nitrogen three times, the reaction vessel was kept at 10 ° C., 75 parts of butadiene, 0.015 part of ferrous sulfate (activator) and p-menthane hydroperoxide (polymerization initiator) 0.05 part was charged and the polymerization reaction was started.
- the resulting nitrile copolymer rubber (A1) had a polymer composition of 28% by weight of acrylonitrile units and 72% by weight of butadiene units, a Mooney viscosity (polymer Mooney) of 51, and a polymer pH of 7.9. .
- the resulting nitrile copolymer rubber (A2) had a polymer composition of 28% by weight of acrylonitrile units and 72% by weight of butadiene units, a Mooney viscosity (polymer Mooney) of 53, and a polymer pH of 7.1. .
- Synthesis example 3 A mixture of the nitrile copolymer rubber latex added to the 0.2% by weight calcium chloride aqueous solution with stirring except that the pH was set to 9 because no sulfuric acid was added.
- a nitrile copolymer rubber (A3) was obtained.
- the resulting nitrile copolymer rubber (A3) had a polymer composition of 28% by weight of acrylonitrile units and 72% by weight of butadiene units, a Mooney viscosity (polymer Mooney) of 52, and a polymer pH of 9.0. .
- Synthesis example 4 As chain transfer agent, instead of 0.40 part of 2,2,4,6,6-pentamethylheptane-4-thiol, t-dodecyl mercaptan (TDM) (trade name “Sulfole 120”, manufactured by Chevron Philips Chemical Co., Ltd. A nitrile copolymer rubber (A4) was obtained in the same manner as in Synthesis Example 1, except that 0.35 part of t-dodecyl mercaptan purity 90 to 100% by weight was used.
- TDM t-dodecyl mercaptan
- the resulting nitrile copolymer rubber (A4) had a polymer composition of 28% by weight of acrylonitrile units and 72% by weight of butadiene units, a Mooney viscosity (polymer Mooney) of 54, and a polymer pH of 7.6. .
- the obtained nitrile copolymer rubber (A5) had a polymer composition of 28% by weight of acrylonitrile units and 72% by weight of butadiene units, a Mooney viscosity (polymer Mooney) of 51, and a polymer pH of 7.0. .
- Synthesis Example 6 A mixture of the nitrile copolymer rubber latex added to the 0.2% by weight calcium chloride aqueous solution with stirring except that the pH was set to 9 because no sulfuric acid was added. In the same manner as in Synthesis Example 4, a nitrile copolymer rubber (A6) was obtained. The resulting nitrile copolymer rubber (A6) had a polymer composition of 28% by weight of acrylonitrile units and 72% by weight of butadiene units, a Mooney viscosity (polymer Mooney) of 53, and a polymer pH of 8.8. .
- Example 1 Using a Banbury mixer, add 100 parts of SRF carbon black, 1 part of stearic acid, 5 parts of zinc oxide and 5 parts of dioctyl phthalate to 100 parts of the nitrile copolymer rubber (A1) obtained in Synthesis Example 1. The mixture is then transferred to a roll and 0.5 parts of powdered sulfur (325 mesh), 1.5 parts of tetramethylthiuram disulfide and 1.5 parts of N-cyclohexyl-2-benzothiazylphenamide are added. By kneading, a crosslinkable nitrile copolymer rubber composition was prepared.
- Example 2 The same procedure as in Example 1 was conducted except that 100 parts of the nitrile copolymer rubber (A2) obtained in Synthesis Example 2 was used instead of 100 parts of the nitrile copolymer rubber (A1) obtained in Synthesis Example 1. Thus, a crosslinkable nitrile copolymer rubber composition was obtained and evaluated in the same manner. The results are shown in Table 1.
- Comparative Example 1 The same procedure as in Example 1 was conducted except that 100 parts of the nitrile copolymer rubber (A3) obtained in Synthesis Example 3 was used instead of 100 parts of the nitrile copolymer rubber (A1) obtained in Synthesis Example 1. Thus, a crosslinkable nitrile copolymer rubber composition was obtained and evaluated in the same manner. The results are shown in Table 1.
- Comparative Example 2 The same procedure as in Example 1 was performed except that 100 parts of the nitrile copolymer rubber (A4) obtained in Synthesis Example 4 was used instead of 100 parts of the nitrile copolymer rubber (A1) obtained in Synthesis Example 1. Thus, a crosslinkable nitrile copolymer rubber composition was obtained and evaluated in the same manner. The results are shown in Table 1.
- Comparative Example 3 The same procedure as in Example 1 was conducted except that 100 parts of the nitrile copolymer rubber (A5) obtained in Synthesis Example 5 was used instead of 100 parts of the nitrile copolymer rubber (A1) obtained in Synthesis Example 1. Thus, a crosslinkable nitrile copolymer rubber composition was obtained and evaluated in the same manner. The results are shown in Table 1.
- Comparative Example 4 The same procedure as in Example 1 was conducted except that 100 parts of the nitrile copolymer rubber (A6) obtained in Synthesis Example 6 was used instead of 100 parts of the nitrile copolymer rubber (A1) obtained in Synthesis Example 1. Thus, a crosslinkable nitrile copolymer rubber composition was obtained and evaluated in the same manner. The results are shown in Table 1.
- a nitrile copolymer obtained by emulsion polymerization using 2,2,4,6,6-pentamethylheptane-4-thiol as a chain transfer agent and having a polymer pH of 8.5 or less The rubber cross-linked product obtained by using rubber is excellent in heat resistance, and also has a low compression set rate and excellent compression set resistance (Example 1, 2).
- a nitrile copolymer rubber having a polymer pH of 9.0 although obtained by emulsion polymerization using 2,2,4,6,6-pentamethylheptane-4-thiol as a chain transfer agent
- the obtained rubber cross-linked product had a high compression set rate and was inferior in compression set resistance
- the resulting rubber cross-linked product is inferior in heat resistance.
- the compression set rate was high and the compression set resistance was inferior (Comparative Examples 2 to 4).
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Abstract
Description
本発明のニトリル共重合体ゴムは、ポリマーpHが8.0以下であることが好ましい。
そして、上記ニトリル共重合体ゴムが、α,β-エチレン性不飽和ニトリル単量体および共役ジエン単量体を含有してなる単量体混合物100重量部に対し、2,2,4,6,6-ペンタメチルヘプタン-4-チオール0.1~1重量部を連鎖移動剤として用いた乳化重合で得られたものであることが好ましい。
本発明のニトリル共重合体ゴムにおいては、全単量体単位100重量%中における、α,β-エチレン性不飽和ニトリル単量体単位の含有割合が10~60重量%であり、共役ジエン単量体単位の含有割合が40~90重量%であることが好ましい。
本発明のニトリル共重合体ゴムは、2,2,4,6,6-ペンタメチルヘプタン-4-チオールを連鎖移動剤として用いた乳化重合で得られ、ポリマーpHが8.5以下である。
芳香族ビニル単量体としては、スチレン、α-メチルスチレン、ビニルピリジンなどが挙げられる。
本発明において、ポリマーpHとは、乾燥したゴムに含まれる成分のpHであり、たとえば、次の方法により求めることができる。すなわち、乾燥したゴム6gを、これを可溶な溶媒(たとえば、テトラヒドロフラン)100gに溶解させることで、ゴム溶液を得る。そして、得られたゴム溶液に2.0mlの蒸留水を添加、混合し、撹拌することにより得られた溶液のpHを測定することにより求めることができる。
乳化重合における2,2,4,6,6-ペンタメチルヘプタン-4-チオールの使用量は特に限定されないが、本発明の効果がより一層顕著になることから、α,β-エチレン性不飽和ニトリル単量体および共役ジエン単量体を含有してなる単量体混合物100重量部に対し、2,2,4,6,6-ペンタメチルヘプタン-4-チオール0.1~1重量部を連鎖移動剤として用いた乳化重合で得られたものであることが好ましく、0.2~0.6重量部を連鎖移動剤として用いた乳化重合で得られたものであることがより好ましい。
なお、2,2,4,6,6-ペンタメチルヘプタン-4-チオールを連鎖移動剤として使用した場合には、2,2,4,6,6-ペンタメチルヘプタン-4-チオールは、その一部が、本発明のニトリル共重合体ゴムの重合体鎖に結合した状態であってもよい。
本発明のニトリル共重合体ゴムの製造方法は、α,β-エチレン性不飽和ニトリル単量体および共役ジエン単量体を含有してなる単量体混合物を、連鎖移動剤として2,2,4,6,6-ペンタメチルヘプタン-4-チオール用いて乳化重合させることで、ニトリル共重合体ゴムのラテックスを得る工程と、得られたニトリル共重合体ゴムのラテックスと、凝固剤とを混合することにより得られる混合液のpHが7.0未満の条件で凝固を行うことで、凝固クラムを得る工程と、得られた凝固クラムを乾燥する工程と、を有する。
α,β-エチレン性不飽和ニトリル単量体としては、アクリロニトリルおよびメタクリロニトリルが好ましい。
また、共役ジエン単量体としては、1,3-ブタジエンおよびイソプレンが好ましく、1,3-ブタジエンがより好ましい。
また、共重合可能なその他の単量体としては、エチレン、α-オレフィン単量体、α,β-エチレン性不飽和カルボン酸エステル単量体、α,β-エチレン性不飽和カルボン酸単量体、α,β-エチレン性不飽和多価カルボン酸無水物単量体、芳香族ビニル単量体、フッ素含有ビニル単量体、共重合性老化防止剤などが例示され、その具体例も上述したものと同様である。
また、共役ジエン単量体の含有割合は、全単量体混合物100重量部中に、好ましくは40~90重量部、より好ましくは45~85重量部、特に好ましくは50~80重量部である。
なお、共重合可能なその他の単量体の含有割合は、全単量体混合物100重量部中に、好ましくは30重量部以下、より好ましくは15重量部以下、特に好ましくは5重量部以下である。
なお、連鎖移動剤として、2,2,4,6,6-ペンタメチルヘプタン-4-チオールと、他の連載移動剤を併用して用いても良いが、全連鎖移動剤中の2,2,4,6,6-ペンタメチルヘプタン-4-チオールの含有割合は、50重量%以上、好ましくは70重量%以上、特に好ましくは90重量%以上である。
また、乳化重合における2,2,4,6,6-ペンタメチルヘプタン-4-チオールの使用量は特に限定されないが、本発明の効果がより一層顕著になることから、α,β-エチレン性不飽和ニトリル単量体および共役ジエン単量体を含有してなる単量体混合物100重量部に対し、0.1~1重量部を使用することが好ましく、0.2~0.6重量部を使用することがより好ましい。
また、乳化重合の重合転化率は、好ましくは50~95%、より好ましくは70~90%である。
なお、本発明においては、得られるニトリル共重合体ゴム(凝固、乾燥後のニトリル共重合体ゴム)のポリマーpHを8.5以下に制御するために、凝固を行う際のpH、すなわち、ニトリル共重合体ゴムのラテックスと、凝固剤とを混合することで得られる混合液のpHを、7.0未満、好ましくは6.0以下に調整する。なお、凝固を行う際のpHの下限は、1.0以上が好ましく、2.0以上がより好ましく、5.0以上がさらに好ましい。
凝固を行う際のpHを上記のように制御することにより、得られるニトリル共重合体ゴムのポリマーpHを適切に制御することができる。なお、凝固を行う際のpHを調整する方法としては、たとえば、凝固剤を含む水溶液に、ニトリル共重合体ゴムのラテックスを添加して塩析させる方法を用いる場合には、凝固剤を含む水溶液のpHを、硫酸などの無機酸を添加して上記範囲に調整する方法などが挙げられる。
本発明の架橋性ニトリル共重合体ゴム組成物は、上記した本発明のニトリル共重合体ゴムに、架橋剤を配合してなるものである。
有機過酸化物架橋剤としては、ジクミルペルオキシド、クメンヒドロペルオキシド、t-ブチルクミルペルオキシド、パラメンタンヒドロペルオキシド、ジ-t-ブチルペルオキシド、1,3-ビス(t-ブチルペルオキシイソプロピル)ベンゼン、1,4-ビス(t-ブチルペルオキシイソプロピル)ベンゼン、1,1-ジ-t-ブチルペルオキシ-3,3-トリメチルシクロヘキサン、4,4-ビス-(t-ブチル-ペルオキシ)-n-ブチルバレレート、2,5-ジメチル-2,5-ジ-t-ブチルペルオキシヘキサン、2,5-ジメチル-2,5-ジ-t-ブチルペルオキシヘキシン-3、1,1-ジ-t-ブチルペルオキシ-3,5,5-トリメチルシクロヘキサン、p-クロロベンゾイルペルオキシド、t-ブチルペルオキシイソプロピルカーボネート、t-ブチルペルオキシベンゾエート等が挙げられる。
本発明のゴム架橋物は、上述した本発明の架橋性ニトリル共重合体ゴム組成物を架橋してなるものである。
本発明のゴム架橋物は、本発明の架橋性ニトリル共重合体ゴム組成物を用い、たとえば、所望の形状に対応した成形機、例えば押出機、射出成形機、圧縮機、ロールなどにより成形を行い、加熱することにより架橋反応を行い、架橋物として形状を固定化することにより製造することができる。この場合においては、予め成形した後に架橋しても、成形と同時に架橋を行ってもよい。成形温度は、通常、10~200℃、好ましくは25~120℃である。架橋温度は、通常、100~200℃、好ましくは130~190℃であり、架橋時間は、通常、1分~24時間、好ましくは2分~6時間である。
ニトリル共重合体ゴム中のアクリロニトリル単位の含有割合を、JIS K6383に従い、ケルダール法により、ニトリル共重合体ゴム中の窒素含量を測定することにより算出した。
ニトリル共重合体ゴムのムーニー粘度(ポリマームーニー)をJIS K6300に従って測定した(単位は(ML1+4、100℃))。
ニトリル共重合体ゴムのポリマーpHは、次の手順で測定した。すなわち、まず、ロールでシート状にしたニトリル共重合体ゴムを、ハサミで細かく裁断し、裁断したニトリル共重合体ゴムを、6g(±0.05g)秤量した。次いで、秤量したニトリル共重合体ゴム6gを、テトラヒドロフラン100gを入れた三角フラスコ中に添加し、撹拌することで、テトラヒドロフランに溶解させた。次いで、蒸留水2.0ml(±0.1ml)を注射器にて採取し、該蒸留水2.0mlを、三角フラスコ中に、溶液を撹拌させた状態にて少量ずつ滴下した。次いで、蒸留水を添加した後、蒸留水の滴下により生成した凝集物が完全に溶解するまで撹拌を継続した。そして、凝集物が完全に溶解したことを確認し、三角フラスコ中に、pH電極を入れてpHの測定を行い、測定開始1分後のpH値を、ポリマーpHとした。
架橋性ニトリル共重合体ゴム組成物について、ゴム加硫試験機(商品名「ムービングダイレオメータMDR」、アルファテクノロジーズ社製)を用い、JIS K6300-2に準拠して、160℃の条件で架橋性試験を行った。そして、得られた架橋性試験の結果から、トルクの最小値ML(単位は、dN・m)、トルクの最大値MH(単位は、dN・m)、t10(単位は、min.)、およびt90(単位は、min.)を測定した。なお、t10、t90は、「トルクの最大値MH-トルクの最小値ML」を100%としたときに、トルクが最小トルクMLから、それぞれ、10%上昇するのに要する時間、および90%上昇するのに要する時間を意味する。t10およびt90が小さいほど架橋速度が速く、トルクの最大値MHが大きいほど、強固に架橋していることを意味する。
架橋性ニトリル共重合体ゴム組成物を、縦15cm、横15cm、深さ0.2cmの金型に入れ、プレス圧10MPaで加圧しながら160℃で20分間プレス成形してシート状のゴム架橋物を得た。次いで、得られたシート状のゴム架橋物を3号形ダンベルで打ち抜いて試験片を作製した。そして、得られたこの試験片を用いて、JIS K6251に従い、架橋物の引張強度、引張応力(100%引張応力、200%引張応力)および伸びを、また、JIS K6253に従い、デュロメータ硬さ試験機(タイプA)を用いて架橋物の硬さを、それぞれ測定した。
上記常態物性の評価に用いたシート状の架橋物と同様のものを得た後、JIS3号形ダンベルで打ち抜き、試験片を作製した。得られた試験片を用いて、JIS K6257「加硫ゴムの老化試験方法」の4項「空気加熱老化試験(ノーマルオーブン法)」の規定に準拠して、100℃、70時間の条件で空気加熱老化処理を行った。空気加熱老化処理を行った試験片(熱老化後の試験片)について、JIS K6251に従い、引張応力(100%引張応力、200%引張応力)および伸びを、また、JIS K6253に従い、デュロメータ硬さ試験機(タイプA)を用いて硬さを、それぞれ測定した。これらの測定結果から、下記式より、伸び変化率、引張応力変化率(100%引張応力変化率、200%引張応力変化率)、および硬さ変化量を求めた。引張応力変化率、伸び変化率および硬さ変化量の絶対値が小さいほど、耐熱老化性に優れる。
引張応力変化率(%)={((熱老化後の引張応力)-(常態での引張応力))/(常態での引張応力)}×100
伸び変化率(%)={((熱老化後の伸び)-(常態での伸び))/(常態での伸び)}×100
硬さ変化量=(熱老化後の硬さ)-(常態での硬さ)
架橋性ニトリル共重合体ゴム組成物を、温度160℃、30分間プレスすることにより架橋することで、直径29mm、高さ12.7mmの円柱型のゴム架橋物を得た。そして、得られたゴム架橋物を用いて、JIS K6262に従い、ゴム架橋物を25%圧縮させた状態で、100℃の環境下に70時間置いた後、圧縮を解放して圧縮永久歪み率を測定した。圧縮永久歪み率の値が小さいほど、耐圧縮永久歪み性に優れる。
内容積10リットルの反応容器中に、オレイン酸カリウム(乳化剤)2部、リン酸カリウム(安定剤)0.1部、および水200部を仕込み、ここに、アクリロニトリル25部、および2,2,4,6,6-ペンタメチルヘプタン-4-チオール(PMHT、連鎖移動剤)0.40部を加えた。そして、内部の気体を窒素で3回置換した後、反応容器を10℃に保ち、ブタジエン75部、硫酸第一鉄(活性剤)0.015部およびp-メンタンハイドロパーオキサイド(重合開始剤)0.05部を仕込み、重合反応を開始した。そして、重合転化率が80%に達した時点で、ヒドロキシルアミン硫酸塩(重合停止剤)0.2部を加えて重合反応を停止した後、70℃に加温し、減圧下、70℃にて水蒸気蒸留により残留単量体を回収し、アルキル化フェノール(老化防止剤)2部を添加することで、ニトリル共重合体ゴムのラテックスを得た。
そして、得られた凝固クラムを取り出し、水洗した後、50℃にて、8時間減圧乾燥することで、ニトリル共重合体ゴム(A1)を得た。得られたニトリル共重合体ゴム(A1)は、重合体組成が、アクリロニトリル単位28重量%、ブタジエン単位72重量%であり、ムーニー粘度(ポリマームーニー)は51、ポリマーpHは7.9であった。
ニトリル共重合体ゴムのラテックスを、濃度0.2重量%の塩化カルシウム水溶液に、攪拌しながら添加して混合する際の混合液を、硫酸を添加することによりpH=3に調整した以外は、合成例1と同様にして、ニトリル共重合体ゴム(A2)を得た。得られたニトリル共重合体ゴム(A2)は、重合体組成が、アクリロニトリル単位28重量%、ブタジエン単位72重量%であり、ムーニー粘度(ポリマームーニー)は53、ポリマーpHは7.1であった。
ニトリル共重合体ゴムのラテックスを、濃度0.2重量%の塩化カルシウム水溶液に、攪拌しながら添加して混合する際の混合液を、硫酸を添加しなかったことによりpH=9にした以外は、合成例1と同様にして、ニトリル共重合体ゴム(A3)を得た。得られたニトリル共重合体ゴム(A3)は、重合体組成が、アクリロニトリル単位28重量%、ブタジエン単位72重量%であり、ムーニー粘度(ポリマームーニー)は52、ポリマーpHは9.0であった。
連鎖移動剤として、2,2,4,6,6-ペンタメチルヘプタン-4-チオール0.40部の代わりに、t-ドデシルメルカプタン(TDM)(商品名「Sulfole 120」、シェブロンフィリップス化学社製、t-ドデシルメルカプタン純度90~100重量%)0.35部を使用した以外は、合成例1と同様にして、ニトリル共重合体ゴム(A4)を得た。得られたニトリル共重合体ゴム(A4)は、重合体組成が、アクリロニトリル単位28重量%、ブタジエン単位72重量%であり、ムーニー粘度(ポリマームーニー)は54、ポリマーpHは7.6であった。
ニトリル共重合体ゴムのラテックスを、濃度0.2重量%の塩化カルシウム水溶液に、攪拌しながら添加して混合する際の混合液を、硫酸を添加することによりpH=3に調整した以外は、合成例4と同様にして、ニトリル共重合体ゴム(A5)を得た。得られたニトリル共重合体ゴム(A5)は、重合体組成が、アクリロニトリル単位28重量%、ブタジエン単位72重量%であり、ムーニー粘度(ポリマームーニー)は51、ポリマーpHは7.0であった。
ニトリル共重合体ゴムのラテックスを、濃度0.2重量%の塩化カルシウム水溶液に、攪拌しながら添加して混合する際の混合液を、硫酸を添加しなかったことによりpH=9にした以外は、合成例4と同様にして、ニトリル共重合体ゴム(A6)を得た。得られたニトリル共重合体ゴム(A6)は、重合体組成が、アクリロニトリル単位28重量%、ブタジエン単位72重量%であり、ムーニー粘度(ポリマームーニー)は53、ポリマーpHは8.8であった。
バンバリーミキサを用いて、合成例1で得られたニトリル共重合体ゴム(A1)100部に、SRFカーボンブラック60部、ステアリン酸1部、酸化亜鉛5部、ジオクチルフタレート5部を添加して混練し、次いで、混合物をロールに移して、粉末硫黄(325メッシュ)0.5部、テトラメチルチウラムジサルファイド1.5部、N-シクロヘキシル-2-ベンゾチアジルフェンアミド1.5部を添加して混練することで、架橋性ニトリル共重合体ゴム組成物を調製した。
合成例1で得られたニトリル共重合体ゴム(A1)100部の代わりに、合成例2で得られたニトリル共重合体ゴム(A2)100部を使用した以外は、実施例1と同様にして、架橋性ニトリル共重合体ゴム組成物を得て、同様に評価を行った。結果を表1に示す。
合成例1で得られたニトリル共重合体ゴム(A1)100部の代わりに、合成例3で得られたニトリル共重合体ゴム(A3)100部を使用した以外は、実施例1と同様にして、架橋性ニトリル共重合体ゴム組成物を得て、同様に評価を行った。結果を表1に示す。
合成例1で得られたニトリル共重合体ゴム(A1)100部の代わりに、合成例4で得られたニトリル共重合体ゴム(A4)100部を使用した以外は、実施例1と同様にして、架橋性ニトリル共重合体ゴム組成物を得て、同様に評価を行った。結果を表1に示す。
合成例1で得られたニトリル共重合体ゴム(A1)100部の代わりに、合成例5で得られたニトリル共重合体ゴム(A5)100部を使用した以外は、実施例1と同様にして、架橋性ニトリル共重合体ゴム組成物を得て、同様に評価を行った。結果を表1に示す。
合成例1で得られたニトリル共重合体ゴム(A1)100部の代わりに、合成例6で得られたニトリル共重合体ゴム(A6)100部を使用した以外は、実施例1と同様にして、架橋性ニトリル共重合体ゴム組成物を得て、同様に評価を行った。結果を表1に示す。
さらに、乳化重合時に連鎖移動剤として、t-ドデシルメルカプタンを使用して得られたニトリル共重合体ゴムを用いた場合には、得られるゴム架橋物は、耐熱性に劣るものであり、さらに、圧縮永久歪み率が高く、耐圧縮永久歪み性にも劣るものであった(比較例2~4)。
Claims (7)
- 2,2,4,6,6-ペンタメチルヘプタン-4-チオールを連鎖移動剤として用いた乳化重合で得られ、ポリマーpHが8.5以下であるニトリル共重合体ゴム。
- ポリマーpHが8.0以下である請求項1に記載のニトリル共重合体ゴム。
- 前記ニトリル共重合体ゴムが、α,β-エチレン性不飽和ニトリル単量体および共役ジエン単量体を含有してなる単量体混合物100重量部に対し、2,2,4,6,6-ペンタメチルヘプタン-4-チオール0.1~1重量部を連鎖移動剤として用いた乳化重合で得られたものである請求項1または2に記載のニトリル共重合体ゴム。
- 全単量体単位100重量%中における、α,β-エチレン性不飽和ニトリル単量体単位の含有割合が10~60重量%であり、共役ジエン単量体単位の含有割合が40~90重量%である請求項3に記載のニトリル共重合体ゴム。
- 請求項1~4のいずれか1項に記載のニトリル共重合体ゴムに、架橋剤を配合してなる架橋性ニトリル共重合体ゴム組成物。
- 請求項5に記載の架橋性ニトリル共重合体ゴム組成物を架橋してなるゴム架橋物。
- α,β-エチレン性不飽和ニトリル単量体および共役ジエン単量体を含有してなる単量体混合物を、連鎖移動剤として2,2,4,6,6-ペンタメチルヘプタン-4-チオールを用いて乳化重合させることで、ニトリル共重合体ゴムのラテックスを得る工程と、
前記ニトリル共重合体ゴムのラテックスと、凝固剤とを混合することにより得られる混合液のpHが7.0未満の条件で凝固を行うことで、凝固クラムを得る工程と、
前記凝固クラムを乾燥する工程と、を有するニトリル共重合体ゴムの製造方法。
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WO2018207940A1 (ja) | 2017-05-12 | 2018-11-15 | デンカ株式会社 | クロロプレン単量体単位と不飽和ニトリル単量体単位とを含む統計的共重合体の製造方法、統計的共重合体、ラテックス及びその用途 |
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CN105555809B (zh) | 2018-01-23 |
CN105555809A (zh) | 2016-05-04 |
JPWO2015046559A1 (ja) | 2017-03-09 |
US20160185890A1 (en) | 2016-06-30 |
MX2016003369A (es) | 2016-08-12 |
JP6414068B2 (ja) | 2018-10-31 |
KR20210075226A (ko) | 2021-06-22 |
KR102394281B1 (ko) | 2022-05-03 |
KR20160065810A (ko) | 2016-06-09 |
EP3026067A4 (en) | 2016-12-28 |
EP3026067A1 (en) | 2016-06-01 |
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