WO2015041037A1 - 触媒式蓄熱燃焼装置 - Google Patents

触媒式蓄熱燃焼装置 Download PDF

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Publication number
WO2015041037A1
WO2015041037A1 PCT/JP2014/072971 JP2014072971W WO2015041037A1 WO 2015041037 A1 WO2015041037 A1 WO 2015041037A1 JP 2014072971 W JP2014072971 W JP 2014072971W WO 2015041037 A1 WO2015041037 A1 WO 2015041037A1
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Prior art keywords
heat storage
exhaust gas
catalyst
temperature
combustion apparatus
Prior art date
Application number
PCT/JP2014/072971
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English (en)
French (fr)
Japanese (ja)
Inventor
伸介 飯島
市川　秀樹
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新東工業株式会社
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Application filed by 新東工業株式会社 filed Critical 新東工業株式会社
Priority to CN201480043808.6A priority Critical patent/CN105452770B/zh
Priority to JP2015537627A priority patent/JP6341466B2/ja
Publication of WO2015041037A1 publication Critical patent/WO2015041037A1/ja

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/07—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/061—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
    • F23G7/065—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel
    • F23G7/066—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel preheating the waste gas by the heat of the combustion, e.g. recuperation type incinerator
    • F23G7/068—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel preheating the waste gas by the heat of the combustion, e.g. recuperation type incinerator using regenerative heat recovery means

Definitions

  • the present invention generally relates to a catalytic regenerative combustion apparatus, and more specifically, recovers the heat of treated exhaust gas while detoxifying combustible harmful components contained in the exhaust gas by treatment by catalytic combustion.
  • the present invention relates to a catalytic heat storage combustion apparatus used for preheating treatment exhaust gas.
  • Exhaust gas exhausted from various production facilities and treatment facilities and containing combustible harmful components such as harmful components or volatile organic compounds cannot be directly released into the atmosphere from the viewpoint of pollution prevention. For this reason, such exhaust gas is detoxified by the exhaust gas treatment device and then released into the atmosphere.
  • a heat storage chamber containing a heat storage material is connected to the combustion chamber, the heat storage material is heated with a high-temperature treated gas in which combustible harmful components are burned, and untreated exhaust gas is discharged into the combustion chamber.
  • a heat storage combustion apparatus that reduces the running cost by preheating with a heat storage material that has been heated before being introduced into the battery (for example, Patent Document 1).
  • Patent Document 2 a catalytic heat storage combustion apparatus in which a heating unit is installed between a catalyst for decomposing flammable harmful components and a heat storage body has also been proposed (for example, Patent Document 2).
  • Patent Document 2 a catalytic heat storage combustion apparatus in which a heating unit is installed between a catalyst for decomposing flammable harmful components and a heat storage body has also been proposed.
  • a combustion apparatus for example, Patent Document 3 in which a second heat storage layer is installed on the heating chamber side of the catalyst or a hot air generator is provided outside, and the hot air generator and the heating chamber are provided.
  • a catalyst is connected by a hot air supply duct to prevent overheating of the catalyst due to radiant heat from the heating means (for example, Patent Document 4).
  • Patent Document 3 in the combustion device in which the second heat storage layer is installed on the heating chamber side of the catalyst, the pressure loss increases due to the resistance in the second heat storage layer, and the power consumption of the blower and the like increases. There is a problem that the running cost increases. Moreover, it is necessary to remove the second heat storage layer every time the catalyst is replaced, and there is a problem that maintenance is not easy. Further, if the space for taking out the catalyst is provided between the catalyst and the second heat storage layer in order to facilitate maintenance, there is a problem that the combustion apparatus becomes large.
  • Patent Document 4 a separate hot air generator is provided, and in the combustion device in which the hot air generator and the heating chamber are connected by a duct, a high-temperature gas duct and a damper for connecting both of them are additionally required.
  • the combustion apparatus of patent document 4 is a system which heats exhaust gas indirectly with a hot air, the gas flow volume in a thermal storage combustion apparatus increases with the hot air for a heating, the pressure loss of an apparatus increases, There is a problem that the running cost increases, and there is a problem that the apparatus must be enlarged in order to keep the pressure loss low.
  • the present invention has been made in view of these points, and an object of the present invention is to provide a catalytic regenerative combustion apparatus in which a catalyst is not overheated, maintenance work is easy, and operation is possible at a low running cost. .
  • a catalytic thermal storage combustion device that purifies exhaust gas by burning flammable harmful components in the exhaust gas, A plurality of heat storage and purification chambers in which a heat storage body through which exhaust gas can pass and a catalyst that burns the combustible harmful components are sequentially arranged and disposed inside, A heating chamber that heats the exhaust gas, the heating chamber connected to each of the plurality of heat storage purification chambers on the side where the catalyst of each of the heat storage purification chambers is disposed; Gas flow switching means for switching the flow of the exhaust gas so as to selectively supply the exhaust gas to one of the plurality of heat storage purification chambers, which is connected to the side where the heat storage body is disposed of the plurality of heat storage purification chambers. And comprising The heating unit is disposed at a position where radiation from the heating unit does not reach the catalyst.
  • a catalytic heat storage combustion apparatus is provided.
  • the combustible harmful component contained in the exhaust gas refers to, for example, a combustible harmful component such as toluene or ethyl acetate or a volatile organic compound.
  • the catalyst is arranged at a position where the radiation from the heating part of the heating chamber does not reach the catalyst, so that it is not overheated by the radiant heat from the heating part. For this reason, the life of the catalyst is extended, the number of replacements is reduced, and the running cost can be reduced.
  • the heating chamber is disposed offset from the catalyst in the arrangement direction of the heat storage body and the catalyst.
  • the catalyst can be disposed at a position where it can be reliably shielded from the radiation of the heating unit, and the combustion apparatus can be miniaturized.
  • a first temperature measuring means is provided between the catalyst and the heating chamber, The operation of the heating unit is controlled based on the detection result of the first temperature measuring means.
  • the temperature control of the heating chamber can be accurately performed. Furthermore, since excessive heating in the heating chamber can be prevented, the running cost can be suppressed.
  • a second temperature measuring means is provided between the catalyst and the heat storage body, The gas flow switching means is activated based on the measurement result of the second temperature measuring means.
  • the gas flow switching means is configured such that the temperature measured by the second temperature measuring means provided in the heat storage and purification chamber to which the exhaust gas is supplied is combusted by the catalyst with combustible harmful components contained in the exhaust gas. When the temperature drops to a temperature higher than the starting combustion start temperature, the flow direction of the exhaust gas is switched.
  • a catalytic regenerative combustion apparatus in which the catalyst is not overheated, maintenance work is easy, and operation is possible at a low running cost.
  • FIG. 2 is a cross-sectional view of the catalytic heat storage combustion device of FIG. 1
  • (A) is a longitudinal cross-sectional view of the catalytic heat storage combustion device
  • (B) is a vertical cross-sectional view of the left-right direction. It is drawing for demonstrating switching of the gas flow direction of waste gas in the catalyst type thermal storage combustion apparatus of FIG. It is a time chart for demonstrating operation
  • (A) is a longitudinal cross-sectional view of the left-right direction of one modification
  • (B) is the left-right direction of another modification
  • (C) is sectional drawing of another modification. It is a longitudinal cross-section of the front-back direction of the catalytic thermal storage combustion apparatus of the other embodiment of the catalytic thermal storage combustion apparatus of this invention. It is drawing of the catalyst type thermal storage combustion apparatus of another embodiment of the catalytic type thermal storage combustion apparatus of this invention, (A) is a typical perspective view of the catalytic type thermal storage combustion apparatus of another embodiment, (B) is a schematic longitudinal cross-sectional view of the left-right direction.
  • (A) is a typical perspective view of the catalytic-type thermal storage combustion apparatus of another embodiment.
  • (B) is a schematic longitudinal sectional view in the left-right direction.
  • the catalytic thermal storage combustion apparatus 1 is a so-called catalytic thermal storage combustion apparatus that purifies exhaust gas by burning combustible harmful components in the exhaust gas.
  • exhaust gas refers to a gas that is exhausted from various production facilities and processing facilities and contains a combustible harmful component such as a harmful component or a volatile organic compound.
  • the combustible harmful component contained in the exhaust gas refers to a combustible harmful component such as toluene or ethyl acetate or a volatile organic compound.
  • FIG. 1 is a schematic perspective view of a catalytic heat storage combustion apparatus 1 according to a preferred embodiment of the present invention.
  • FIG. 2 is a schematic longitudinal sectional view showing the internal structure of the catalytic heat storage combustion apparatus 1.
  • the catalytic heat storage combustion apparatus 1 includes two heat storage purification chambers 10 and 20 for purifying the exhaust gas by burning combustible harmful components contained in the exhaust gas, and the exhaust gas. And a heating chamber 30 for heating the.
  • the two heat storage purification chambers 10 and 20 are integrally formed in a parallel arrangement state, and are divided into individual heat storage purification chambers 10 and 20 by a partition wall 10a disposed in the center. Note that the heat storage and purification chambers 10 and 20 may be separated from each other.
  • heat storage bodies 11, 21 and catalyst layers 12, 22 are arranged in each heat storage purification chamber 10, 20, heat storage bodies 11, 21 and catalyst layers 12, 22 are arranged.
  • the heat storage bodies 11 and 21 are arranged in a lower region of the heat storage purification chambers 10 and 20 while being spaced apart from the bottom surfaces of the heat storage purification chambers 10 and 20 by a predetermined distance. That is, a space is formed below the heat storage bodies 11 and 21.
  • a heat storage material having a sufficient heat exchange capacity under the operating temperature condition is used. Specifically, various materials such as sand, ceramics, and metal are used as the heat storage material.
  • the shape of the heat storage material is also a shape capable of circulating exhaust gas such as a porous material, a honeycomb shape, and a granular material.
  • the heat storage materials 11 and 21 are the above-described heat storage materials that are accommodated in a container in a state in which exhaust gas can flow inside.
  • the catalyst layers 12, 22 are spaced apart from the heat storage bodies 11, 21 by a predetermined distance and have a predetermined distance downward from the ceiling portion of the heat storage purification chambers 10, 20. They are arranged at positions separated by an interval. That is, in the catalytic heat storage combustion apparatus 1 of the present embodiment, between the heat storage bodies 11 and 21 and the catalyst layers 12 and 22 and between the catalyst layers 12 and 22 and the ceiling portion of the heat storage purification chambers 10 and 20. Each has a space. And in the catalyst type thermal storage combustion apparatus 1 of this embodiment, the thermal storage bodies 11 and 21 and the catalyst layers 12 and 22 are arrange
  • the catalyst layers 12 and 22 are arranged as catalyst layers 12 and 22 in which a catalyst capable of burning and decomposing combustible harmful components contained in exhaust gas is held in a container.
  • the catalyst held in the catalyst layers 12 and 22 is capable of decomposing flammable harmful components contained in the untreated exhaust gas, and known catalysts made of noble metals, base metal oxides, and the like are used.
  • the catalyst has a shape that allows exhaust gas such as porous, honeycomb, and granular materials to flow through the inside of the catalyst layer, and the catalyst layers 12 and 22 have a structure that allows the exhaust gas to pass through the inside. Yes.
  • Connection ducts 13 and 23 for introducing and discharging exhaust gas into the heat storage and purification chambers 10 and 20 are connected to the lower portions of the heat storage and purification chambers 10 and 20. As shown in FIG. 1, the connection ducts 13 and 23 are disposed so as to communicate with the heat storage purification chambers 10 and 20 below the heat storage bodies 11 and 21 (that is, the side on which the heat storage body is disposed). ing. Therefore, the connection ducts 13 and 23 introduce exhaust gas into the space below the heat storage bodies 11 and 21, and discharge the treated exhaust gas from the space below the heat storage bodies 11 and 21.
  • each of the connection ducts 13 and 23 is connected to two connection portions of a four-way valve 40 (gas flow switching means).
  • a gas supply duct 41 that supplies untreated exhaust gas to the catalytic thermal storage combustion apparatus 1 and an exhaust duct 42 that exhausts from the catalytic thermal storage combustion apparatus 1 are connected to other connection parts of the four-way valve 40, respectively. ing.
  • the four-way valve 40 is used as the gas flow switching means, the flow of the exhaust gas can be switched by one switching valve, and the structure of the catalytic heat storage combustion apparatus 1 can be simplified.
  • the gas flow switching means other valves such as a butterfly type on / off valve, a poppet type on / off valve, and a three-way valve can also be used.
  • an air cylinder method using compressed air is adopted as a driving method of the gas flow switching means, but a driving method using a hydraulic cylinder, an electric cylinder, or the like can also be adopted.
  • the heat storage purification chambers 10 and 20 are connected to the heating chamber 30 so that the space above the catalyst layers 12 and 22 communicates with the inside of the heating chamber 30 through the connection ports 14 and 24.
  • the heating chamber 30 is disposed adjacent to the back side of each of the heat storage and purification chambers 10 and 20. Therefore, in the catalytic heat storage combustion apparatus 1 of the present embodiment, the heating chamber 30 does not overlap the heat storage bodies 11 and 21 and the catalyst layers 12 and 22 arranged in the vertical direction in a plan view (side). It is arranged in an offset state. That is, in the catalytic heat storage combustion apparatus 1 of the present embodiment, the heating chamber 30 is in a positional relationship offset from the catalyst layers 12 and 22 in the arrangement direction of the heat storage bodies 11 and 21 and the catalyst layers 12 and 22, that is, in the vertical direction. It is arranged with.
  • the heating chamber 30 has a height substantially equal to that of the heat storage purification chambers 10 and 20, and is divided into an upper region 30b and a lower region 30c by a horizontal partition wall 30a disposed above. ing. Further, the upper region 30b is divided into upper sections 30e and 30e corresponding to the respective heat storage and purification chambers 10 and 20 by a vertical partition wall 30d.
  • an electric heater 31 as a heating unit is arranged in the heating chamber 30, an electric heater 31 as a heating unit is arranged.
  • the electric heater 31 is a heating device for heating the introduced exhaust gas to a temperature at which the combustible and harmful components can be combusted in the catalyst layers 12 and 22, and is inserted into the heating chamber 30 from the ceiling to the heating chamber 30. 30 is attached.
  • Each electric heater 31 includes three elongate heater elements h having a distal end portion disposed in the pipe member 30f.
  • the tip side portion disposed in the pipe member 30f of the heater element h is a heat generating portion (heating portion) 31 'that generates radiant heat. Therefore, in the catalytic thermal storage combustion apparatus 1 of the present embodiment, the heat generating portion 31 ′ that generates radiant heat is disposed in the pipe member 30 f. With such a configuration, radiation from the heat generating portion 31 ′ does not reach the catalyst in the heat storage purification chamber 10, 20.
  • the heating chamber 30 is configured such that the exhaust gas contacts the electric heater 31 at a predetermined flow rate that is faster than the flow rate in the heat storage and purification chambers 10 and 20.
  • the predetermined flow rate is a flow rate that prevents local heating of the exhaust gas and enables uniform heating.
  • the flow rate of the exhaust gas is increased by the flow path portion 32 which is an elongated space between the elongated heat generating portion 31 ′ of the electric heater 31 and the pipe portion 30 f disposed around the elongated heating portion 31 ′, and the predetermined flow rate is increased. Have achieved.
  • first temperature measurement means 15, 25 are provided in spaces between the catalyst layers 12, 22 and the ceiling of the heat storage purification chamber 10, 20, respectively.
  • the first temperature measuring means 15 and 25 are composed of a thermocouple or the like, and between the catalyst layers 12 and 22 and the ceiling of the heat storage and purification chambers 10 and 20 in order to control the operation of the electric heater 31 of the heating chamber 30. Measure the temperature in the space.
  • second temperature measurement means 16 and 26 are provided in spaces between the heat storage bodies 11 and 21 and the catalyst layers 12 and 22, respectively.
  • the second temperature measuring means 16 and 26 are also composed of thermocouples or the like, and the heat storage bodies 11 and 21 and the catalyst layers 12 and 22 are used to perform switching control of the flow direction of the exhaust gas in the respective heat storage and purification chambers by the gas flow switching means. Measure the temperature in the space between.
  • the catalytic heat storage combustion apparatus 1 includes a control device (not shown) including a personal computer.
  • This control device controls the overall operation of the catalytic regenerative combustion apparatus 1, for example, the control of the electric heater 31 in the heating chamber 30 based on the temperature detected by the first temperature measuring means 15, 25, and the second temperature measuring means 16, 26. Control of switching the flow direction of exhaust gas based on the detected temperature is performed.
  • the target temperature in the heating chamber 30 is required to heat the exhaust gas in the heating chamber up to a temperature at which the flammable harmful components are completely burned in the catalyst layers 12 and 22.
  • a certain heating target temperature T1 a gas flow switching temperature T2 at which the gas flow direction is switched by the four-way valve 40, and a combustion start temperature T3 at which the combustible harmful components start to burn by the catalyst in the catalyst layers 12 and 22 are set. .
  • the catalytic heat storage combustion apparatus 1 When the catalytic heat storage combustion apparatus 1 is started, first, a blower (not shown) for introducing exhaust gas into the heat storage purification chambers 10 and 20 is started, and the four-way valve 40 is stored in the atmosphere or untreated exhaust gas on one side. The direction is set in the direction of introduction into the purification chamber 10. Next, the electric heater 31 in the heating chamber 30 is activated. In the catalytic thermal storage combustion apparatus 1, the four-way valve 40 is set until the start-up is completed, that is, until it is determined that the inside of the heating chamber 30 has reached the heating target temperature T1 based on the temperature detected by the first temperature measurement means 15 It switches every time and the heat storage bodies 11 and 21 are heated.
  • the exhaust gas treatment process performed after the start-up is completed will be described along the time chart of FIG.
  • the time ts point is set as the start point of the exhaust gas treatment process.
  • the four-way valve 40 is operated, and as shown in FIG. 3A, untreated exhaust gas containing combustible harmful components supplied from an unillustrated exhaust gas emission source is connected from an untreated gas supply duct 41 to a connection duct. 13 is introduced into the space below the one heat storage purification chamber 10 (the space below the heat storage body 11).
  • the untreated exhaust gas introduced into the lower space of the heat storage purification chamber 10 passes through the heat storage body 11 and the catalyst layer 12 and is supplied to the heating chamber 30. Since the heat storage body 11 is heated to a predetermined temperature, the untreated exhaust gas is heated by the heat storage body 11 when passing through the heat storage body 11. For this reason, when exhaust gas passes the catalyst layer 12, at least a part of combustible harmful component is burned.
  • the temperature of the heat storage body 11 decreases due to heat exchange with the exhaust gas.
  • the exhaust gas temperature T2a detected by the second temperature measuring means 16 disposed between the heat storage body 11 and the catalyst layer 12 is the gas flow. While the temperature is equal to or higher than the switching temperature T2 (for example, 200 ° C.), the exhaust gas is introduced into the space below the heat storage purification chamber 10 and passes through the heat storage body 11 and the catalyst layer 12, and thus passes through the catalyst layer 12. At this time, since the catalyst layer 12 is maintained at a temperature higher than the combustion start temperature T3, at least a part of the combustible harmful component in the exhaust gas is combusted.
  • the exhaust gas that has passed through the catalyst layer 12 is introduced into the upper section 30e of the heating chamber 30 corresponding to the heat storage purification chamber 10.
  • the exhaust gas introduced into the upper section 30e first contacts the heat generating section 31 'disposed in the flow path section 32 at a predetermined flow rate in the flow path section 32 formed below the upper section 30e. , Flowing downwards. Then, it flows into the lower region 30 c of the heating chamber 30.
  • the exhaust gas that has flowed into the lower region 30c is then disposed in the flow channel portion 32 at a predetermined flow rate at the flow channel portion 32 formed below the upper section 30e of the heating chamber 30 corresponding to the other heat storage purification chamber 20. It flows upward while in contact with the generated heat generating portion 31 ′ and flows into the upper section 30 e of the heating chamber 30 corresponding to the heat storage purification chamber 20. While the exhaust gas flows through the flow path portion 32, the heat generation portion 31 ′ is heated to a temperature at which the combustible harmful components are completely decomposed in the catalyst layer 22.
  • the flow rate of the exhaust gas in the flow path part 32 is set so as to prevent local heating of the exhaust gas, uniformly heat the exhaust gas, and not to increase the pressure loss.
  • it is set to about 5 to 30 m / s.
  • the exhaust gas passes through the vicinity of the surface of the heat generating portion 31 ′ of the electric heater 31 at a relatively high speed, so that the surface temperature of the heat generating portion 31 ′ does not rise significantly from the set temperature, and the electric heater 31 is long. It can be a lifetime.
  • the output of the electric heater 31 is controlled so that the temperature T1b detected by the first temperature measuring means 25 on the downstream side of the heating chamber 30 becomes the heating target temperature T1.
  • the high-temperature exhaust gas in which combustible harmful components are decomposed (combusted) in the catalyst layer 22 passes through the heat storage body 21. At this time, heat exchange is performed between the heat storage body 21 and the high-temperature exhaust gas, and the heat storage body 21 is heated.
  • the treated exhaust gas that has passed through the heat accumulator 21 is exhausted from the connection duct 23 via the four-way valve 40 and the exhaust duct 42.
  • the temperature of the heat storage body 11 decreases due to heat exchange with the exhaust gas, and the untreated exhaust gas cannot be sufficiently heated. For this reason, the flow direction of the exhaust gas is switched in order to effectively use the waste heat stored in the heat storage bodies 11 and 21.
  • the gas flow direction switching timing is determined based on the exhaust gas temperature detected by the second temperature measuring means 16 on the upstream side of the heating chamber 30. That is, in the regenerative exhaust gas purification apparatus 1 of the present embodiment, when the control device (not shown) determines that the exhaust gas temperature T2a detected by the second temperature measuring means 16 is lower than the gas flow switching temperature T2, the four-way valve As shown in FIG. 3B, the flow direction of the exhaust gas is adjusted so that the untreated exhaust gas is supplied to the heat storage purification chamber 20 and the treated exhaust gas is exhausted from the heat storage purification chamber 10. Switch.
  • untreated exhaust gas is sent into the heat storage purification chamber 20, preheated by the high-temperature heat storage body 21 in the heat storage purification chamber 20, then passed through the catalyst layer 22 and sent into the heating chamber 30. Further heating.
  • the preheated exhaust gas passes through the catalyst layer 22, and at least a part of the combustible harmful components is combusted.
  • the electric heater 31 is controlled such that the temperature T1a detected by the first temperature measuring means 15 on the downstream side of the heating chamber 30 becomes the heating target temperature T1.
  • the exhaust gas further heated is sent to the heat storage purification chamber 10 where the flammable harmful substances are decomposed in the catalyst layer 12.
  • the treated exhaust gas in which the flammable harmful components are decomposed in the catalyst layer 12 passes through the heat storage body 11. At this time, heat exchange is performed between the heat storage body 11 and the treated exhaust gas, and the heat storage body 11 is heated.
  • the treated exhaust gas that has passed through the heat storage body 11 is exhausted from the connection duct 13 via the four-way valve 40 and the exhaust duct 42 to the outside of the system.
  • the gas flow direction switching timing is determined based on the exhaust gas temperature detected by the second temperature measuring means 26 on the upstream side of the heating chamber 30.
  • the control device determines that the exhaust gas temperature T2b detected by the second temperature measuring means 26 is lower than the gas flow switching temperature T2, the control device operates the four-way valve 40, The gas flow direction is switched to the state shown in FIG.
  • the untreated exhaust gas is alternately flowed into the heat storage purification chambers 10 and 20, and the heat stored in the heat storage bodies 11 and 21 is used for preheating the untreated exhaust gas. While being used, the flammable harmful components are decomposed.
  • the output control of the electric heater 31 is detected by the first temperature measuring means 15, 25 located on the downstream side of the heating chamber 30 in the exhaust gas flow direction among the first temperature measuring means 15, 25. Performed based on exhaust gas temperature. According to such a configuration, the output of the electric heater 31 is reduced by the amount by which the exhaust gas is heated by the combustion heat of the combustible harmful component in the catalyst layer located on the upstream side of the heating chamber 30 in the exhaust gas flow direction. Running costs can be reduced. Moreover, even if the concentration of the flammable harmful component contained in the untreated exhaust gas varies, the flow direction of the exhaust gas can be controlled at an appropriate timing without being greatly affected.
  • the exhaust gas is preheated by the combustion heat of combustible harmful components in the catalyst layers 12 and 22 located on the upstream side of the heating chamber 30, and the first temperature measuring means 15 on the upstream side of the heating chamber 30.
  • the output of the electric heater 31 is controlled to zero immediately, thereby preventing excessive heating by the electric heater 31 and running cost. Can be reduced.
  • the heat generating portion 31 ′ of the heating chamber 30 is disposed at a position where the catalyst layers 12 and 22 are not heated by radiation. 22 is not overheated. Thereby, the catalyst life is extended, the replacement frequency is lowered, and the running cost of the catalytic heat storage combustion apparatus can be reduced. Further, since the heating unit is not disposed above the catalyst layer, the catalyst layers 12 and 22 can be easily exchanged, and the maintenance of the catalytic heat storage combustion apparatus is simplified.
  • the heating chamber 30 is arrange
  • the heat storage purification chambers 10 and 20 are connected in a direction substantially orthogonal to the direction.
  • the catalyst layers 12 and 22 can be arrange
  • combustible harmful components of the exhaust gas in the catalyst layers 12 and 22 are based on the exhaust gas temperatures T1a and T1b detected by the first temperature measuring means 15 and 25. Since the output control of the electric heater 31 can be performed so as to reach the heating target temperature T1, which is the target temperature for heating the exhaust gas to a temperature at which it can be completely combusted, the electric power in the electric heater 31 is excessively consumed. It is suppressed.
  • the gas flow switching temperature T2 which is set higher than the combustion start temperature T3 at which the combustible harmful components start to be burned by the catalyst in the catalyst layers 12 and 22, and the second temperature measuring means 16 and 26. Based on the detected exhaust gas temperatures T2a and T2b, the four-way valve 40 is operated to switch the gas flow direction.
  • the untreated exhaust gas is caused to flow into the one heat storage body 11 through the connection duct 13 by the operation of the four-way valve 40, the heat of the heat storage body 11 is deprived by the untreated exhaust gas and the heat storage body 11
  • the exhaust gas temperature T2a in the space between the catalyst layers 12 decreases.
  • the four-way valve 40 is switched so that untreated exhaust gas flows into the other heat storage body 12.
  • the one heat accumulator 11 and the catalyst layer 12 into which the untreated gas has flown until now become the downstream side of the heating chamber 30, and the space between the heat accumulator 11 and the catalyst layer 12 has a high temperature after catalytic combustion.
  • the exhaust gas temperature T2a in this region rises from the gas switching temperature T2, and is always maintained at the switching temperature T2 or higher.
  • the exhaust gas temperature T2a of the space temperature between the heat storage body and the catalyst layer is always maintained at a temperature equal to or higher than the combustion start temperature of the flammable harmful component by switching the four-way valve 40 as described above. It is possible to suppress the operation of the heater disposed in the heating chamber 30 and reduce energy consumption.
  • the regenerative exhaust gas purification apparatus 1 of the above embodiment when the temperature of the untreated exhaust gas passes through the regenerators 11 and 21 located upstream of the heating chamber in the exhaust gas flow direction, Since it is heated to the combustion start temperature T3 or higher, at least a part of the combustible harmful components can be combusted even when passing through the catalyst layers 12 and 22 on the upstream side of the heating chamber 30. Thereafter, the exhaust gas in which at least a part of the combustible harmful component is burned is further heated in the heating chamber 30, so that the combustible harmful component can be burned by the downstream catalyst and completely decomposed.
  • the electric heater 31 is used as a heating unit, a fuel pipe, a blower for combustion air, and the like are unnecessary, and thus a simple structure can be achieved.
  • the heating chamber may employ other various structures in which the electric heater is disposed at a position where the catalyst layer cannot be heated by radiation from the heat generating portion.
  • the number of electric heaters and the arrangement position in the heating chamber can be arbitrarily set.
  • an electric heater is used as the heating unit of the heating chamber 30, but other heating means such as a burner may be employed.
  • two pipes are used to form the flow path portion 32 in the heating chamber 30, but other structures may be used as long as the exhaust gas flow rate can be set to a predetermined flow rate.
  • FIG. 5 (A) which is a longitudinal cross-sectional view of the left-right direction of other embodiment of the heating chamber 30 may be sufficient.
  • the lower ends of the left and right hanging portions corresponding to the pipe portion 30f in the above embodiment and extending downward are connected to form a U-shaped region below the heating chamber 30, and this U-shaped lower region
  • the inner space is used as a flow path part.
  • the heat generating portion (heating portion) 31 ′ is disposed only in the drooping portion on the left side of the U-shaped lower region.
  • the electric heater 31 is disposed only on the right-side hanging portion or a configuration in which the electric heater 31 is provided on the left and right hanging portions may be employed. Also in these configurations, the heat generating part (heating part) 31 ′ of the heating chamber 30 is arranged at a position where the catalyst layers 12 and 22 are not heated by radiation.
  • FIG. 5B which is a vertical cross-sectional view in the left-right direction of another embodiment of the heating chamber 30, it is possible to adopt a configuration in which the flow path portion 32 is partitioned by a horizontal partition wall 33.
  • the partition wall 33 is a component corresponding to the horizontal partition wall 30a of the embodiment of FIG.
  • the upper section 30e and the lower region 30c of the heating chamber 30 are communicated with each other by the openings formed on the left and right tip sides of the horizontal partition wall 33.
  • a heating part (heating part) 31 ′ is inserted into the lower area 30 c (flow path part 32) from the side surface of the heating chamber 30 in the inner space of the lower area 30 c partitioned by the horizontal partition wall 33. Is the flow path portion 32. Also in this configuration, the heat generating part (heating part) 31 ′ of the heating chamber 30 is arranged at a position where the catalyst layers 12 and 22 are not heated by radiation.
  • FIG. 5C which is a vertical cross-sectional view of another embodiment of the heating chamber 30, the insertion direction of the heat generating portion (heating portion) 31 ′ may be changed.
  • the heat generating part (heating part) 31 ′ is inserted into the lower region 30 c (flow path part 32) from the bottom surface of the heating chamber 30.
  • the heat generating part (heating part) 31 ′ of the heating chamber 30 is arranged at a position where the catalyst layers 12 and 22 are not heated by radiation.
  • the heating chamber is not separated from the heat storage purification chambers 10 and 20 by a partition wall, but is disposed apart from the heat storage purification chambers 10 and 20 as shown in FIG.
  • the structure connected with each of the thermal storage purification chambers 10 and 20 may be sufficient.
  • FIG. 7 a configuration in which the heating chamber 30 is arranged via the partition wall 17 between the heat storage purification chamber 10 and the heat storage purification chamber 20 may be adopted.
  • a minimum switching time t1 and a maximum switching time t2 are set, and the four-way valve 40 is controlled by combining these t1 and t2 with the exhaust gas temperature detected by the second temperature measuring means 16 and 26.
  • the structure to do may be sufficient.
  • the minimum switching time t1 is a time during which the four-way valve 40 is not operated until the minimum switching time t1 is exceeded even if the exhaust gas temperature detected by the second temperature measuring means 16, 26 falls below the gas flow switching temperature T2.
  • the maximum switching time t2 is for operating the four-way valve 40 when the exhaust gas temperature detected by the second temperature measuring means 16 and 26 exceeds the maximum switching time t2 even if it does not fall below the gas flow switching temperature T2. It's time.
  • the above t1 and t2 are used when the amount of untreated gas to be processed fluctuates or when the amount of combustible harmful components contained in the untreated gas fluctuates.
  • the amount of untreated exhaust gas flowing into the apparatus decreases (for example, becomes half of the rated treatment amount)
  • the heat storage body 11 on the side to which the untreated exhaust gas is supplied and the catalyst layer 12 The rate of decrease in the exhaust gas temperature T2a in the space becomes lower. For this reason, the time required for the exhaust gas temperature T2a in the space between the heat storage body 11 and the catalyst layer 12 to fall to the switching temperature T2 becomes longer.
  • the temperature of the treated exhaust gas exhausted from the opposite (exhaust side) heat storage body increases with the passage of time.
  • the four-way valve is forcibly operated with the maximum switching time t2 as an upper limit to switch the inflow direction of the exhaust gas.
  • the exhaust gas temperature T2a in the space between the heat storage body and the catalyst layer on the downstream side of the heating chamber rises, and then the untreated gas is supplied. Since the time required for the exhaust gas temperature T2a in this portion to decrease to the switching temperature T2 becomes longer, the same processing is performed.
  • the number of times the four-way valve is activated during a predetermined time (for example, 1 hour) is reduced.
  • a predetermined time for example, 1 hour
  • the untreated inside the heat storage body upstream of the heating chamber, the lower space of the heat storage body, the duct connecting the lower space of the heat storage body and the switching valve The exhaust gas may flow back to the duct that discharges the treated gas to the atmosphere by switching the four-way valve, and may be discharged into the atmosphere without being treated.
  • the untreated exhaust gas supply duct and the duct that releases the treated gas to the atmosphere are communicated via the four-way valve, and the exhaust gas supply duct is connected. Untreated exhaust gas may be released to the atmosphere through a discharge duct. Therefore, if the four-way valve is actuated many times in a predetermined time, the removal rate of combustible harmful components is reduced, and the desired removal performance cannot be obtained. For this reason, the minimum switching time t2 is set as a lower limit, the number of operations of the four-way valve per predetermined time is limited, and the reduction in the removal rate of combustible harmful components is suppressed.
  • the catalytic heat storage combustion apparatus 1 of the said embodiment is the structure provided with the two heat storage purification chambers 10 and 20, this invention can also be set as the structure provided with the 3 or more heat storage purification chambers.
  • the structure further provided with the heat storage chamber 30 of the structure similar to the heat storage purification chambers 10 and 20 may be sufficient.
  • 31 is a heat storage body
  • 32 is a catalyst layer
  • 33 is a connection duct
  • 35 is a first temperature measuring means
  • 36 is a second temperature measuring means.
  • three gas flow switching means 40 are provided in order to purify the exhaust gas by sequentially switching two heat storage chambers among the three heat storage chambers.
  • FIG. 8B shows a state in which untreated exhaust gas is supplied to the heat storage chamber 10 and the treated exhaust gas is discharged from the heat storage chamber 20.
  • Control of the electric heater 31 in the heating chamber 30 and switching of the gas flow direction are based on the exhaust gas temperature detected by the first temperature measuring means and the second temperature measuring means, as in the case of two heat storage chambers. Do it.
  • untreated exhaust gas is supplied to the heat storage chamber 20
  • the flow of exhaust gas is switched to a state where the treated exhaust gas is discharged from the heat storage chamber 30, and then the heat storage Untreated exhaust gas is supplied to the chamber 30, and the state is switched to a state in which the treated exhaust gas is discharged from the heat storage chamber 10. Thereafter, the state is returned to the state shown in FIG. 8B, and thereafter the same switching is performed.

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Incineration Of Waste (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
PCT/JP2014/072971 2013-09-19 2014-09-02 触媒式蓄熱燃焼装置 WO2015041037A1 (ja)

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JP2017020752A (ja) * 2015-07-14 2017-01-26 株式会社大気社 多塔式の蓄熱式脱臭装置における切換機構、多塔式の蓄熱式脱臭装置、及び、３塔式の蓄熱式脱臭装置の運転方法
CN110410807A (zh) * 2019-06-21 2019-11-05 山东皓隆环境科技有限公司 催化燃烧一体机
CN113019116A (zh) * 2020-03-06 2021-06-25 株式会社岛川制作所 有害成分加热净化装置

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CN107152691A (zh) * 2017-06-22 2017-09-12 南京艾尔普特环保科技有限公司 基于RTO的低NOx补燃及VOC高效去除方法及系统
TWI686579B (zh) * 2018-11-15 2020-03-01 財團法人金屬工業研究發展中心 蓄熱艙熱流體處理之流路切換裝置
CN113483344A (zh) * 2021-07-09 2021-10-08 陕西青朗万城环保科技有限公司 一种微波增强蓄热燃烧废气处理方法及其装置
CN114307894A (zh) * 2021-10-08 2022-04-12 河北天龙环保科技有限公司 一种基于催化剂的高温蓄热催化氧化系统

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JP2017020752A (ja) * 2015-07-14 2017-01-26 株式会社大気社 多塔式の蓄熱式脱臭装置における切換機構、多塔式の蓄熱式脱臭装置、及び、３塔式の蓄熱式脱臭装置の運転方法
CN110410807A (zh) * 2019-06-21 2019-11-05 山东皓隆环境科技有限公司 催化燃烧一体机
CN113019116A (zh) * 2020-03-06 2021-06-25 株式会社岛川制作所 有害成分加热净化装置

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TWI626404B (zh) 2018-06-11
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JP6341466B2 (ja) 2018-06-13
JPWO2015041037A1 (ja) 2017-03-02

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