WO2015004757A1 - Unité de gazéification d'échantillon et chromatographe à gaz - Google Patents

Unité de gazéification d'échantillon et chromatographe à gaz Download PDF

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Publication number
WO2015004757A1
WO2015004757A1 PCT/JP2013/068905 JP2013068905W WO2015004757A1 WO 2015004757 A1 WO2015004757 A1 WO 2015004757A1 JP 2013068905 W JP2013068905 W JP 2013068905W WO 2015004757 A1 WO2015004757 A1 WO 2015004757A1
Authority
WO
WIPO (PCT)
Prior art keywords
sample
seal cap
protrusion
housing
internal space
Prior art date
Application number
PCT/JP2013/068905
Other languages
English (en)
Japanese (ja)
Inventor
出　由彦
肇 武本
省司 井出
優 小櫻
亮 武知
Original Assignee
株式会社島津製作所
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社島津製作所 filed Critical 株式会社島津製作所
Priority to JP2015526067A priority Critical patent/JP6090446B2/ja
Priority to PCT/JP2013/068905 priority patent/WO2015004757A1/fr
Publication of WO2015004757A1 publication Critical patent/WO2015004757A1/fr

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/04—Preparation or injection of sample to be analysed
    • G01N30/06—Preparation
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/04—Preparation or injection of sample to be analysed
    • G01N30/06—Preparation
    • G01N30/12—Preparation by evaporation
    • G01N2030/126—Preparation by evaporation evaporating sample
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/26—Conditioning of the fluid carrier; Flow patterns
    • G01N30/28—Control of physical parameters of the fluid carrier
    • G01N30/30—Control of physical parameters of the fluid carrier of temperature

Definitions

  • the present invention relates to a sample vaporization unit that has a sample vaporization chamber for vaporizing a sample injected by a sampler and sends the sample vaporized in the sample vaporization chamber to an analysis column, and a gas chromatograph including the sample vaporization unit.
  • a gas chromatograph is provided with a sample vaporizing unit for vaporizing a sample and feeding it to an analysis column.
  • the sample vaporizing unit has a housing, and there is a space serving as a sample vaporizing chamber inside the housing, and a sample for injecting a sample into the sample vaporizing chamber at the top of the housing.
  • An inlet is provided.
  • the lower part of the sample vaporization chamber is connected to the analysis column, and the carrier gas is introduced from the upper part of the sample vaporization chamber.
  • the sample vaporization chamber is heated to a high temperature, and the liquid sample injected into the sample vaporization chamber is vaporized by heat and sent to the analysis column by the carrier gas.
  • the sample vaporization chamber inside the housing accommodates a cylindrical insert made of glass or quartz, and the sample injected from the sample injection port is vaporized inside the insert. Since the sample is vaporized inside the insert, the sample gas can be introduced into the analysis column without contacting the metal inner wall of the sample vaporization chamber.
  • the insert Since the insert is in direct contact with the sample, it is a component that tends to become dirty due to adhesion of vaporization residue, etc. of the sample. Therefore, the insert is housed in the sample vaporizing chamber in a detachable state so that the insert can be periodically replaced and cleaned (see Patent Documents 1 and 2).
  • an opening leading to the sample vaporizing chamber is provided on the upper surface of the housing, and the opening is sealed with a seal cap.
  • the sample injection port is provided in the seal cap, and the seal cap is fixed to the housing with a septum and a seal ring sandwiched between the insert.
  • an object of the present invention is to make it possible to easily attach and detach the seal cap while maintaining high airtightness of the sample vaporizing chamber.
  • a sample vaporizing unit has an internal space that forms a sample vaporizing chamber, a housing having an opening on the top surface that leads to the internal space, and a top surface of the internal space that is detachably attached to the top of the housing.
  • a seal cap having a sample injection part for inserting a needle for sample injection into the internal space from above, a column connection part provided at the lower part of the housing for connecting an analysis column, and an upper end inside A cylindrical insert arranged in the internal space so that the lower end is connected to the analytical column, a carrier gas supply unit connected to the internal space and supplying the carrier gas to the internal space, and a seal cap And a seal cap fixing mechanism that is pressed against the housing side.
  • the seal cap fixing mechanism is a protrusion that is fixed to the housing and protrudes in the horizontal direction, is connected to the seal cap by a connecting shaft arranged in the horizontal direction, and is a rotation lever that rotates in the vertical plane around the connecting shaft, And the pivot lever is not engaged with the projection when the pivot lever is in a predetermined position, and the projection is arranged below the projection by rotating the pivot lever in one direction from the predetermined position. And a guide rail that moves along the protrusion as the lever rotates in one direction.
  • the guide rail in the sample vaporization unit of the present invention is preferably formed in a shape in which the distance between the connecting shaft and the portion in contact with the protrusion is shortened as the rotation angle of the rotation lever in one direction increases. If it does so, the distance of a projection part and a connection axis
  • the guide rail is preferably configured to be elastically deformed by a stress received from the protrusion when the rotating lever rotates in one direction from a predetermined position. By doing so, the sealing cap can be pressed against the housing side by the elastic force of the material of the rotating lever, so that the sealing performance between the sealing cap and the housing is improved.
  • An example of a structure in which the guide rail is elastically deformed is a spring structure in which the guide rail is supported by the rotating lever only at both ends in one direction, and the portions other than both ends are not fixed to the rotating lever.
  • the edge of the opening leading to the internal space of the housing may protrude in a ring shape upward from the top surface of the housing, and the protrusion may protrude in the horizontal direction from the side surface of the edge.
  • the seal cap and the seal cap fixing mechanism can be downsized.
  • the seal cap may have a seal portion that seals the upper end of the insert disposed in the vicinity of the opening, and an elastic ring-shaped seal member may be disposed between the seal cap and the upper end of the insert. Since the vaporization of the sample occurs inside the insert, it is possible to improve the airtightness inside the insert by crushing the seal member with a seal cap and sealing the upper end of the insert.
  • a gas chromatograph includes a sample vaporization unit according to the present invention, an analysis column connected to a column connection portion of the sample vaporization unit and separating a sample injected into the sample vaporization unit, and a sample separated by the analysis column And a detector for detecting.
  • the sample vaporizing unit of the present invention includes a rotation lever as a seal cap fixing mechanism, and when the rotation lever is in a predetermined position, the rotation lever is not engaged with the protrusion on the housing side.
  • a guide rail that is arranged below the protrusion, engages with the protrusion, and moves along the protrusion when it rotates in one direction from the position. Cap can be fixed and released. Accordingly, the seal cap can be easily attached and detached without using a special tool, and the work efficiency of the insert replacement is improved.
  • the gas chromatograph of the present invention is equipped with the sample vaporization unit of the present invention, it is easy to attach and detach the insert of the sample vaporization unit, and the efficiency of the maintenance work is improved.
  • the gas chromatograph includes a sample vaporization unit 2, an analysis column 8, a detector 10, and a column oven 12.
  • One end of the analysis column 8 is connected to the column connection 18 at the lower end of the sample vaporizing unit 2, and the other end is connected to the detector 10.
  • the analysis column 8 is accommodated in the column oven 12, and the sample vaporizing unit 2 and the detector 10 are attached to the upper part of the column oven 12.
  • the sample vaporizing unit 2 is provided with a cylindrical sample vaporizing chamber 6 a inside the housing 6.
  • a heater 16 is provided around the sample vaporizing chamber 6a.
  • the inner surface of the sample vaporizing chamber 6a is made of metal, and the inside of the sample vaporizing chamber 6a is heated to a high temperature by the heat of the heater 16.
  • An opening 7 leading to the sample vaporizing chamber 6 a is provided on the upper surface of the housing 6, and the opening 7 is sealed with a seal cap 4.
  • the seal cap 4 includes a sample injection port 22 for inserting a sample injection needle into the upper surface.
  • a pipe 14 for supplying a carrier gas for feeding the sample gas vaporized in the sample vaporizing chamber 6 to the analysis column 8 is connected to the side surface of the seal cap 4.
  • the sample is injected from the needle inserted into the sample vaporizing chamber 6a through the sample injection port 22.
  • the liquid sample injected into the sample vaporizing chamber 6a through the seal cap 4 is vaporized in the sample vaporizing chamber 6a heated to a high temperature, and the vaporized sample gas is introduced into the analysis column 8 by the carrier gas.
  • the sample gas is separated by the analysis column 8 and detected by the detector 10 for each separated component.
  • FIG. 2 is a perspective view of the sample vaporizing unit 2.
  • the casing 6 of the sample vaporizing unit 2 is a member having a prismatic shape, and a sample vaporizing chamber 6a is provided inside.
  • An oven fixing portion 20 that protrudes in the horizontal direction is provided on the side surface of the housing 6, and the housing 6 is fixed to the wall surface of the column oven 12 with bolts and nuts.
  • a portion below the oven fixing part 20 of the housing 6 is accommodated in the column oven 12, and a column connection part 18 for connecting one end of the analytical column 8 is provided at the lower end thereof.
  • the shape of the housing 6 is not limited to a prismatic shape, and may be a cylindrical shape or other shapes.
  • the sample vaporizing chamber 6a is provided as a hole having a circular cross section that extends from the upper surface of the housing 6 to the column connecting portion 18 at the lower end, and a cylindrical insert 40 made of quartz glass or the like is accommodated in the sample vaporizing chamber 6a. Yes. An opening 7 on the upper surface of the housing 6 communicating with the sample vaporizing chamber 6 a is sealed with a seal cap 4.
  • the seal cap 4 includes a seal cap body 4a, a sample injection portion 4b, and a rotation lever 4c.
  • the seal cap body 4a is a member having a circular planar shape.
  • a sample injection part 4b is attached to the upper part of the seal cap body 4a, and a sample injection port 22 through which a sample injection needle is inserted vertically downward into the sample vaporization chamber 6a on the upper surface of the sample injection part 4b.
  • the sample injection port 22 is provided as a hole for guiding the needle to the upper end portion of the insert 40, but the middle of the hole is closed by a septum made of an elastic material such as natural rubber or silicone rubber. The septum allows the sample injection needle to pass through while maintaining airtightness, and after pulling out the needle, the through hole by the needle is closed by the elasticity of the needle so as to maintain the airtightness in the sample vaporizing chamber 6a.
  • the piping 14 is connected to the side surface of the seal cap body 4a.
  • a pipe connection part 15 is provided at the tip of the pipe 14, and a pipe for supplying carrier gas is connected to the pipe connection part 15.
  • Inside the seal cap body 4a there is provided a flow path for guiding the carrier gas supplied through the pipe 14 to the sample vaporizing chamber 6a.
  • Rotating lever 4c has portions facing each other so as to sandwich the side surface of seal cap body 4a from both sides, and holes 30 are provided in these portions.
  • Two connecting shafts 29 extending in opposite directions are provided on the side surface of the seal cap body 4a.
  • the connecting shafts 29 are fitted in the holes 30 of the rotating lever 4 c, respectively, and the rotating lever 4 c is pivotally supported by the connecting shaft 29.
  • the rotation lever 4c is attached to the seal cap body 4a so that the rotation lever 4c rotates in the vertical plane around the connecting shaft 29.
  • the edge 7a of the opening 7 protrudes upward from the upper surface of the housing 6 into a cylinder, and the opening 7 is sealed by covering the edge 7a with the seal cap 4.
  • the seal ring 37 which is a ring-shaped elastic member, is disposed so as to contact the upper end of the insert 40 in the opening 7.
  • a seal portion 24 that is in contact with a seal ring 37 disposed in the opening 7 is provided at a lower portion of the seal cap body 4a.
  • columnar protrusions 36 extending in the horizontal direction are provided at two positions located on opposite sides.
  • the protrusion 36 protrudes outward from the side surface of the seal cap body 4a.
  • the seal cap body 4 a is provided with a recess 25 that opens downwardly below the connecting shaft 29. When the protrusion 36 enters the recess 25, the seal cap 4 is positioned with respect to the housing 6 in the rotational direction.
  • the protrusion 36 forms part of a seal cap fixing mechanism for fixing the seal cap 4 to the housing 6.
  • the rotation lever 4c of the seal cap 4 is provided with a guide rail 27 (see FIG. 5) for engaging with the protrusion 36. By engaging the guide rail 27 with the protrusion 36, the seal cap 4 is engaged. Is fixed to the housing 6.
  • the turning lever 4c is in the vertically upward state (the state shown in FIGS. 3 and 4)
  • the position of the rotating lever 4c at this time is defined as a “release position”.
  • the rotation lever 4 is rotated from the release position and tilted while the seal cap 4 is put on the edge 7 a of the opening 7, the guide rail 27 engages with the protrusion 36 and the seal cap 4 is moved to the housing 6. Fixed to.
  • FIGS. 5, 6A and 6B A seal cap fixing mechanism for fixing the seal cap 4 to the housing 6 will be described with reference to FIGS. 5, 6A and 6B.
  • 5 is an exploded perspective view of the seal cap 4
  • FIG. 6A is a conceptual diagram showing a state of the seal cap fixing mechanism that releases the fixation of the seal cap 4
  • FIG. 6B is a seal cap fixing mechanism that fixes the seal cap 4. It is a conceptual diagram which shows the state of.
  • the rotation lever 4 c includes two rotation portions 26 provided so as to be sandwiched between both sides of the seal cap body 4 a and a connecting bar 28 that connects the two rotation portions 26. It is configured. Both the rotating part 26 and the connecting bar 28 are made of metal such as stainless steel. A hole 30 into which one end of the connecting shaft 29 is fitted is provided in the two rotating portions 26, and the rotating portion 26 rotates in a vertical plane around the axis of the connecting shaft 29.
  • the protrusion 36 (see FIGS. 3 and 4) provided on the edge 7a of the opening 7 protrudes toward the rotating part 26 through the recess 25 of the seal cap body 4a.
  • a guide rail 27 provided on the inner side of the rotating portion 26 (on the side surface side of the seal cap body 4a) and engaged with the protruding portion 36 is curved so that the connecting shaft 29 side has a concave shape.
  • the guide rail 27 is provided with a surface on which the protrusion 36 is slid with the rotation of the rotation lever 4c.
  • the guide rail 27 has a portion P1 that is in contact with the protrusion 36 when the rotation portion 26 (the rotation lever 4c) is slightly rotated from the released state, and the rotation portion 26 is If the portion that contacts the protrusion 36 when it is completely turned and turned is P2, the distance between the connecting shafts 29 and P2 is greater than the distance L1 between the connecting shafts 29 and P1. It is formed in a curved shape so that the distance L2 is shorter. As a result, the distance between the projection 36 that slides along the guide rail 27 and the connecting shaft 29 varies depending on the position (rotation angle) of the rotation lever 4c.
  • the position (height) of the connecting shaft 29 changes according to the rotation of the rotation lever 4c. Since the connecting shaft 29 is connected to the seal cap body 4a, the seal cap body 4a is displaced as the connecting shaft 29 is displaced. As shown in FIG. 6A, when the rotating lever 4c is in the released state, the lower seal portion 24 of the seal cap body 4a is only in contact with the seal ring 37 on the insert 40. As shown in FIG. 6B, when the rotation lever 4c is tilted, the seal cap body 4a is lowered, and the seal portion 24 presses the seal ring 37 so that the space between the seal cap body 4a and the insert 40 is strong. Seal.
  • an opening 32 along the shape of the guide rail 27 is provided immediately above the guide rail 27 of the rotating portion 26, and a strong stress is applied to the guide rail 27.
  • the guide rail 27 is slightly elastically deformed.
  • the portion of the rotation portion 26 where the guide rail 27 is formed is slightly elastically deformed, and the elastic force
  • the connecting shaft 29 is biased downward.
  • the sample vaporizing unit 2 introduces only a part of the sample supplied into the sample vaporizing chamber 6a into the analysis column 8 by the carrier gas supplied through the pipe 14, You may provide the split exit for exhausting the remainder to the exterior with carrier gas. Further, a purge outlet may be provided for discharging a substance that adversely affects the analysis in the sample vaporizing chamber 6a to the outside.

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

La présente invention concerne un mécanisme de fixation de bouchon de fermeture hermétique qui fixe un bouchon de fermeture hermétique à un boîtier dans le but d'étanchéifier l'ouverture assurant une interconnexion avec une chambre de gazéification d'échantillon du boîtier. Le mécanisme de fixation de bouchon de fermeture hermétique est doté d'un levier pivotant qui est couplé au bouchon de fermeture hermétique au moyen d'une tige de couplage disposée horizontalement et qui pivote dans des plans vertical et horizontal centrés sur la tige de couplage. Le levier pivotant est doté d'un rail de guidage qui, lorsque le levier pivotant se trouve dans une position prédéfinie, ne coopère pas avec une saillie ménagée du côté boîtier et qui, lorsque le levier pivotant est pivoté dans un premier sens par rapport à la position prédéfinie, est disposé au-dessous de la saillie, coopère avec la saillie et se déplace le long de la saillie.
PCT/JP2013/068905 2013-07-10 2013-07-10 Unité de gazéification d'échantillon et chromatographe à gaz WO2015004757A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2015526067A JP6090446B2 (ja) 2013-07-10 2013-07-10 試料気化ユニット及びガスクロマトグラフ
PCT/JP2013/068905 WO2015004757A1 (fr) 2013-07-10 2013-07-10 Unité de gazéification d'échantillon et chromatographe à gaz

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2013/068905 WO2015004757A1 (fr) 2013-07-10 2013-07-10 Unité de gazéification d'échantillon et chromatographe à gaz

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WO2015004757A1 true WO2015004757A1 (fr) 2015-01-15

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WO (1) WO2015004757A1 (fr)

Cited By (8)

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CN105004816A (zh) * 2015-08-12 2015-10-28 苏州优谱德精密仪器科技有限公司 一种液化石油气成分快速检测方法
WO2016132439A1 (fr) * 2015-02-16 2016-08-25 株式会社島津製作所 Unité de vaporisation d'échantillon et chromatographe en phase gazeuse
JP2017125808A (ja) * 2016-01-15 2017-07-20 株式会社島津製作所 ガスクロマトグラフ
JP2017125784A (ja) * 2016-01-15 2017-07-20 株式会社島津製作所 部材連結機構
WO2017149583A1 (fr) * 2016-02-29 2017-09-08 株式会社島津製作所 Mécanisme et procédé de liaison d'éléments
CN108369215A (zh) * 2015-12-07 2018-08-03 株式会社岛津制作所 开口密封结构体、试样气化单元以及气相色谱仪
CN113316718A (zh) * 2018-11-14 2021-08-27 安捷伦科技有限公司 用于流体连接件的配件组件
CN113777208A (zh) * 2021-09-16 2021-12-10 王飞龙 一种化工检测用杂质分析仪器

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JP3129007U (ja) * 2006-11-15 2007-02-01 株式会社島津製作所 ガスクロマトグラフ
JP2009092672A (ja) * 2008-12-24 2009-04-30 Shimadzu Corp ガスクロマトグラフ

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JP3129007B2 (ja) * 1992-12-11 2001-01-29 株式会社日立製作所 ホトマスク及び半導体装置の製造方法

Patent Citations (3)

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JP2006105992A (ja) * 2004-09-30 2006-04-20 Agilent Technol Inc 改良されたインレットシール機構を備えているガスクロマトグラフシステム
JP3129007U (ja) * 2006-11-15 2007-02-01 株式会社島津製作所 ガスクロマトグラフ
JP2009092672A (ja) * 2008-12-24 2009-04-30 Shimadzu Corp ガスクロマトグラフ

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US10551359B2 (en) 2015-02-16 2020-02-04 Shimadzu Corporation Sample vaporization unit and gas chromatograph
EP3260857A4 (fr) * 2015-02-16 2019-01-16 Shimadzu Corporation Unité de vaporisation d'échantillon et chromatographe en phase gazeuse
WO2016132439A1 (fr) * 2015-02-16 2016-08-25 株式会社島津製作所 Unité de vaporisation d'échantillon et chromatographe en phase gazeuse
CN113484451B (zh) * 2015-02-16 2023-10-13 株式会社岛津制作所 试样气化单元及气相色谱仪
JPWO2016132439A1 (ja) * 2015-02-16 2017-11-30 株式会社島津製作所 試料気化ユニット及びガスクロマトグラフ
CN107533037A (zh) * 2015-02-16 2018-01-02 株式会社岛津制作所 试样气化单元及气相色谱仪
CN113484451A (zh) * 2015-02-16 2021-10-08 株式会社岛津制作所 试样气化单元及气相色谱仪
CN105004816A (zh) * 2015-08-12 2015-10-28 苏州优谱德精密仪器科技有限公司 一种液化石油气成分快速检测方法
US11092578B2 (en) 2015-12-07 2021-08-17 Shimadzu Corporation Opening sealing structure, sample vaporization unit, and gas chromatograph
CN108369215B (zh) * 2015-12-07 2023-09-12 株式会社岛津制作所 开口密封结构体、试样气化单元以及气相色谱仪
CN113820412A (zh) * 2015-12-07 2021-12-21 株式会社岛津制作所 开口密封结构体、试样气化单元以及气相色谱仪
JPWO2017098565A1 (ja) * 2015-12-07 2018-09-13 株式会社島津製作所 開口封止構造体、試料気化ユニット及びガスクロマトグラフ
CN108369215A (zh) * 2015-12-07 2018-08-03 株式会社岛津制作所 开口密封结构体、试样气化单元以及气相色谱仪
JP2017125808A (ja) * 2016-01-15 2017-07-20 株式会社島津製作所 ガスクロマトグラフ
JP2017125784A (ja) * 2016-01-15 2017-07-20 株式会社島津製作所 部材連結機構
WO2017149583A1 (fr) * 2016-02-29 2017-09-08 株式会社島津製作所 Mécanisme et procédé de liaison d'éléments
JPWO2017149583A1 (ja) * 2016-02-29 2018-11-01 株式会社島津製作所 部材連結機構及び部材連結方法
CN108700559B (zh) * 2016-02-29 2022-02-08 株式会社岛津制作所 构件连结机构和构件连结方法
CN108700559A (zh) * 2016-02-29 2018-10-23 株式会社岛津制作所 构件连结机构和构件连结方法
US10883645B2 (en) 2016-02-29 2021-01-05 Shimadzu Corporation Member linking mechanism and member linking method
CN113316718A (zh) * 2018-11-14 2021-08-27 安捷伦科技有限公司 用于流体连接件的配件组件
CN113316718B (zh) * 2018-11-14 2024-05-24 安捷伦科技有限公司 用于流体连接件的配件组件
US12000810B2 (en) 2018-11-14 2024-06-04 Agilent Technologies, Inc. Fitting assemblies for fluidic connections
CN113777208A (zh) * 2021-09-16 2021-12-10 王飞龙 一种化工检测用杂质分析仪器
CN113777208B (zh) * 2021-09-16 2023-07-04 海南哈勃新能源技术合伙企业(有限合伙) 一种化工检测用杂质分析仪器

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