WO2014157564A1 - Composition de coiffage - Google Patents

Composition de coiffage Download PDF

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Publication number
WO2014157564A1
WO2014157564A1 PCT/JP2014/058986 JP2014058986W WO2014157564A1 WO 2014157564 A1 WO2014157564 A1 WO 2014157564A1 JP 2014058986 W JP2014058986 W JP 2014058986W WO 2014157564 A1 WO2014157564 A1 WO 2014157564A1
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WIPO (PCT)
Prior art keywords
component
group
mass
hair styling
hair
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PCT/JP2014/058986
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English (en)
Japanese (ja)
Inventor
範子 藤井
将典 岡本
一樹 乃田
Original Assignee
株式会社マンダム
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Application filed by 株式会社マンダム filed Critical 株式会社マンダム
Priority to JP2015508724A priority Critical patent/JP6013587B2/ja
Priority to CN201480011124.8A priority patent/CN105007887B/zh
Priority to KR1020157020879A priority patent/KR101789397B1/ko
Publication of WO2014157564A1 publication Critical patent/WO2014157564A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/24—Phosphorous; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present invention relates to a hair styling composition that is suitably used for a hair styling agent for preparing hair.
  • various hair conditioner compositions such as liquid, gel, cream and solid are used.
  • a film-forming polymer is often used for imparting hair-styling power, which is a main function, to a hair-styling composition.
  • the initial hair styling power immediately after hair styling is increased, while the hair styling composition composition on the hair becomes unsuitable and unfit, and stickiness occurs.
  • a film is formed on the surface of the hair after hair styling, derived from the film-forming polymer. For this reason, it is difficult to prepare the hair in a natural state, and when the hair is stimulated with hands or a comb after hair styling, the film peels off from the surface of the hair (so-called flaking occurs), Hair styling power is easily reduced.
  • Patent Document 1 discusses the use of silicones as a plasticizer in a hairdressing composition containing a film-forming polymer.
  • Patent Document 2 discloses a hair cosmetic (hairdressing composition) containing 0.1 to 10% by mass of a fine particle powder having a specific surface area of 50 m 2 / g or more.
  • a hair cosmetic hairdressing composition
  • Patent Document 2 by using the specific fine particle powder at a specific content, a good feel can be obtained, an excellent hair styling power can be obtained, and a good feel can be maintained for a long time, and an excellent It describes that hair styling properties can be obtained.
  • the flexibility of the film formed from the film-forming polymer is increased to some extent.
  • the usability of the hairdressing composition is improved to some extent.
  • the flexibility of the film is improved, there is a problem in that the function of maintaining the hair-styled state for a long time is lowered. That is, when the hair is formulated using the hair styling composition described in Patent Document 1, the hair styling holding power may not be sufficiently high.
  • the hair styling holding power may not be sufficiently high.
  • An object of the present invention is to provide a hair styling composition that is excellent in hair styling retention, applicability, and storage stability.
  • the hairdressing composition according to the present invention includes the following component (A), the following component (B), the component (C) that is a polymer selected from the group consisting of the following component (C1) and the following component (C2). And a content of the component (A) is 0.1% by mass or more and 10% by mass or less.
  • Component (A) Particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide
  • Component (B) Clay mineral Component (C1): Polymer obtained using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as the essential monomer component (C2): As an essential monomer component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether, and Mono selected from the group consisting of vinyl neodecanoate Polymers obtained by using the chromatography
  • the total amount of the component (B) and the component (C) is preferably 0.2% by mass or more and 10% by mass or less.
  • the mass ratio of the content of the component (B) and the content of the component (C) is preferably 0.1: 1 to 30: 1.
  • the hairdressing composition according to the present invention preferably further contains the following component (D).
  • component (D) Compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester
  • the hairdressing composition according to the present invention preferably further contains the following component (E).
  • the hairdressing composition according to the present invention contains specific components (A), (B), and (C), and the content of the component (A) is within a specific range. Is good, and exhibits excellent hair holding ability after hair styling. Furthermore, it exhibits excellent storage stability.
  • the first polymer is a polymer obtained using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as an essential monomer component.
  • the hairdressing composition according to the present invention was selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. Particles, clay minerals, and a polymer selected from the group consisting of the first polymer and the second polymer.
  • the above-mentioned “particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide” May be referred to as “component (A)”. Further, the “clay mineral” may be referred to as “component (B)”. Furthermore, in the present specification, the “polymer selected from the group consisting of the first polymer and the second polymer” may be referred to as “component (C)”. The “first polymer” may be referred to as “component (C1)”, and the “second polymer” may be referred to as “component (C2)”. “(Meth) acrylic acid” means one or both of acrylic acid and methacrylic acid.
  • the hair styling composition according to the present invention preferably further contains a compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester.
  • component (D) the “compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester” may be referred to as “component (D)”. Further, the “polyoxyalkylene alkyl glucoside” may be referred to as “component (D1)”, and the “polyoxyalkylene glycerin fatty acid ester” may be referred to as “component (D2)”.
  • the hairdressing composition according to the present invention preferably further contains polyethylene glycol.
  • polyethylene glycol may be referred to as “component (E)”.
  • the hairdressing composition according to the present invention includes at least a component (A), a component (B), and a component (C).
  • the hairdressing composition according to the present invention preferably further comprises a component (at least one component) selected from the group consisting of component (D) and component (E).
  • the hairdressing composition which concerns on this invention contains all of a component (A), a component (B), a component (C), a component (D), and a component (E).
  • the hairdressing composition according to the present invention may further contain other components. Only one kind of each of the above components, for example, the component (A), the component (B), the component (C), the component (D), the component (E), and the other component may be used. More than species may be used.
  • the component (C) is a polymer (at least one polymer) selected from the group consisting of the component (C1) and the component (C2).
  • the component (D) is a compound (at least one compound) selected from the group consisting of the component (D1) and the component (D2).
  • said component (C1), a component (C2), a component (D1), and a component (D2) only 1 type may respectively be used and 2 or more types may be used.
  • the component (A) is a particle selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. .
  • the component (A) mainly has a role of suppressing stickiness and increasing initial hair styling power and hair styling holding power (particularly hair styling holding power). Further, by using the component (A), it is possible to facilitate hair styling again after hair styling once and to improve re-hair styling, as compared with the case where a film-forming polymer is used.
  • said component (A) from a viewpoint which makes hairdressing performance favorable especially, from the group which consists of a silica, a hydroxyapatite, a titanium oxide, a zinc oxide, a calcium silicate, a magnesium silicate, an aluminum silicate, and magnesium hydroxide. Selected particles (at least one particle) are preferred, and particles (at least one particle) selected from the group consisting of silica and magnesium hydroxide are more preferred. As for the said component (A), only 1 type may be used and 2 or more types may be used.
  • silica known and commonly used silica (anhydrous silicic acid) can be used.
  • the silica may be silicic anhydride (hydrophilic silica) that has not been hydrophobized or may be hydrophobized silicic anhydride.
  • the silica may be silica that has been surface-treated with an amino acid, an ester, lecithin, or the like.
  • the silica may be so-called easily disintegrating silica particles.
  • 1 type may be used and 2 or more types may be used.
  • the hydrophobized silicic anhydride is a substance obtained by hydrophobizing silicic anhydride (for example, untreated silicic anhydride).
  • the treating agent used for the hydrophobizing treatment include organic silyl compounds and silicone compounds.
  • the organic silyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyldialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyltrichlorosilane, long Examples include chain alkyltrichlorosilane, ethyltrialkoxysilane, propyltrialkoxysilane, hexyltrialkoxysilane, long chain alkyltrialkoxysilane, methacryl silane, fluoroalky
  • silicone compound examples include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane, and amino-modified silicone.
  • a publicly known method can be adopted as a method of the above-mentioned hydrophobic treatment.
  • the hydrophobic treatment method include a liquid phase method, a gas phase method, and an autoclave method.
  • hydrophobic silicic anhydride examples include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicone oil treated silicic anhydride and methacrylsiloxylated silicic anhydride. Etc.
  • the above easily disintegratable silica particles are particles formed by aggregating a plurality of silica primary particles. Although it does not specifically limit as said silica primary particle, For example, a spherical silica particle, a scaly silica particle, an amorphous silica particle, etc. are mentioned.
  • the average particle diameter of the silica primary particles is not particularly limited.
  • the easily disintegratable silica particles may contain components other than silica.
  • the component other than the silica (hereinafter may be referred to as “encapsulated component”) is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Examples include antioxidants, plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Of these, amino acids, silicone oils, and vitamins are preferable. Although it does not specifically limit as said amino acids, Dilauroyl glutamate ricin Na (For example, the product name "Perisea" by Asahi Kasei Chemicals Corporation), a trimethylglycine, glutamic acid, etc.
  • the easily disintegratable silica particles encapsulate the inclusion component
  • the inclusion component is released when the easily disintegratable silica particles are disintegrated during hair styling, and an effect corresponding to the type of the inclusion component is exhibited.
  • the easily disintegratable silica particles encapsulate amino acids, thereby exhibiting a hair damage care function.
  • the method for producing the easily disintegratable silica particles is not particularly limited, and a known method can be used.
  • the silica oil absorption is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, still more preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / 100 g or less, more preferably 700 mL / 100 g or less.
  • the oil absorption amount of the silica is not less than the above lower limit and not more than the above upper limit, the initial hair styling power, the hair styling holding power, and the re-hair styling property are further improved.
  • the oil absorption is measured according to the method described in JIS K5101.
  • silica silicic acid manufactured by Fuji Silysia Chemical Co., Ltd., trade name “Silysia 320”, trade name “Silisia 310P”, trade name “Silicia 250”, trade name “Silicia 250N”, product.
  • the said calcium carbonate is represented by the INCI name "CALCIUM CARBONATE", for example.
  • the said calcium carbonate only 1 type may be used and 2 or more types may be used.
  • Sakai Chemical Industry make brand name "Karumaru SCS M5"; Shiraishi calcium company make, brand name "Fuwakaru” etc. are mentioned, for example.
  • the magnesium carbonate is represented by, for example, the INCI name “MAGNESIUM CARBONATE”. As for the said magnesium carbonate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium carbonate, the Toda Pharmaceutical company make, brand name "light magnesium carbonate” etc. are mentioned, for example.
  • hydroxyapatite is represented by, for example, the INCI name “HYDROXYAPATITE”. As for the said hydroxyapatite, only 1 type may be used and 2 or more types may be used.
  • the hydroxyapatite is not particularly limited, and examples thereof include spherical hydroxyapatite, plate-like hydroxyapatite, and amorphous hydroxyapatite. Among these, spherical hydroxyapatite is preferable from the viewpoint of exhibiting high hair styling performance.
  • examples of commercially available hydroxyapatite include, for example, trade name “Plate HAP”, trade name “Spherical HAP”, trade name “HAP-100”, trade name “HAP-200”, and trade name, manufactured by Taihei Chemical Industry Co., Ltd. Examples thereof include “HAP-300”.
  • the titanium oxide is represented by, for example, the INCI name “TITANIUM DIOXIDE”.
  • the titanium oxide is not particularly limited, and may be fine particle titanium oxide or pigment titanium, for example. As for the said titanium oxide, only 1 type may be used and 2 or more types may be used. Examples of commercially available titanium oxide include trade name “TTO-55 (A)” and trade name “CR-50” manufactured by Ishihara Sangyo Co., Ltd.
  • the zinc oxide is represented by, for example, the INCI name “ZINC OXIDE”. As for the said zinc oxide, only 1 type may be used and 2 or more types may be used. Examples of commercially available zinc oxide include trade name “FINEX-30S-LP2” manufactured by Sakai Chemical Industry Co., Ltd.
  • the calcium silicate is represented, for example, by the INCI name “CALCIUM SILICATE”. As for the said calcium silicate, only 1 type may be used and 2 or more types may be used. Examples of commercially available products of calcium silicate include Tomita Pharmaceutical Co., Ltd., trade name “FLORITE R”; Nippon Insulation Co., Ltd., trade name “Zonotolite Powder XJ”, and trade name “Tobermorite Powder TK”. .
  • the magnesium silicate is represented by, for example, the INCI name “MAGNESIUM SILICATE”. As for the said magnesium silicate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium silicate, the Tomita Pharmaceutical company make, brand name "magnesium silicate (light)" etc. are mentioned, for example.
  • the aluminum silicate is represented by, for example, the INCI name “ALUMINUM SILICATE”. As for the said aluminum silicate, only 1 type may be used and 2 or more types may be used. Although it does not specifically limit as an aluminum silicate, A synthetic aluminum silicate is preferable. Examples of the synthesis method include, for example, a method of adding Na 2 SiO 3 to alum and drying the generated precipitate, a method of producing a silicate sol by electrodialysis, thereby producing a gel, and an aluminum salt in water glass. The method of adding the aqueous solution of this is mentioned. As a commercial item of the said aluminum silicate, the Tomita Pharmaceutical company make, brand name "synthetic aluminum silicate (heavy)" etc. are mentioned, for example.
  • the magnesium hydroxide is represented by, for example, the INCI name “MAGNESIUM HYDROXIDE”. As for the said magnesium hydroxide, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium hydroxide, the Tomita Pharmaceutical company make, brand name "magnesium hydroxide (heavy)" etc. are mentioned, for example.
  • the content of the component (A) is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass. Hereinafter, it is preferably 7% by mass or less, more preferably 5% by mass or less.
  • the content of the component (A) is equal to or higher than the lower limit, the hair styling retention power can be further increased, and stickiness can be further suppressed.
  • content of the said component (A) is below the said upper limit, storage stability (stability at the time of long-term storage) can be improved further. In addition, the touch after styling becomes even better.
  • the content of the component (A) is the total content of all the components (A) in the hairdressing composition according to the present invention. Further, in 100% by mass of the hairdressing composition according to the present invention, the content of silica, and calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and
  • the content (total content) of the particles selected from the group consisting of magnesium hydroxide is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass, respectively. % Or less, preferably 7% by mass or less, more preferably 5% by mass or less.
  • the component (B) is a clay mineral.
  • the hairdressing composition is appropriately thickened, so that the dispersibility of the component (A) is further increased. It becomes much better and the storage stability becomes much better. In addition, the applicability during hair styling is improved.
  • the said component (B) only 1 type may be used and 2 or more types may be used.
  • the component (B) may be a natural product or a synthetic product. Although it does not specifically limit as said component (B), For example, kaolin group clay mineral, antigolite group clay mineral, pyrophyllite group clay mineral, mica group clay mineral, smectite group clay mineral, vermiculite group clay mineral, green mud Examples include stone group clay minerals and organically modified clay minerals.
  • Examples of the kaolin group clay mineral include kaolin, nacrite, dickite, and halosite.
  • examples of the antigolite group clay mineral include antigolite, amesite, and cronstedite.
  • examples of the pyrophyllite clay mineral include pyrophyllite and talc (talc).
  • examples of the mica group clay minerals include illite, sea chlorite, ceradonite, sericite, mica (mica), muscovite, chromium muscovite and biotite.
  • Examples of the smectite clay mineral include bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite, and lucentite. Vermiculite etc.
  • vermiculite group clay mineral examples include chlorite.
  • examples of the organic modified clay mineral include an organic modified clay mineral obtained by organically modifying a smectite group clay mineral or a vermiculite group clay mineral.
  • a quaternary ammonium salt type cationic surfactant is preferably used for the organic modification treatment.
  • examples of the quaternary ammonium salt type cationic surfactant include the above alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.
  • the component (B) is preferably a clay mineral selected from the group consisting of synthetic silicates and derivatives thereof.
  • the above-mentioned synthetic silicate and its derivative are not a silicate mineral mainly composed of magnesium silicate or silicic acid (sodium / magnesium) derived from nature, which contains impurities, but silicic acid obtained by synthesis. Refers to salts and silicate derivatives.
  • Examples of the synthetic silicate and derivatives thereof include, for example, an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 3076): SODIUM MAGNESIUM SILICATE Acid (sodium / magnesium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 1793): MAGNESIUM FLUOROSILICATE Magnesium Fluorosilicate, INCI name Cosmetic gradient Dictary and Handbook, 14th edition, Volume 2, CTFA, 2012, p.
  • SODIUM MAGNESIUM FLUOROSILICATE fluorosilicic acid (sodium / magnesium), INCI name (International CosmicHindoticIndigo 14th Edition, Volume 2, CTFA, 2012, p. 1799): MAGNESIUM POTASSIUM FLUOROSILIC Fluorosilicate (magnesium / potassium), INCI name (International Cosmetic Ingredient Dictionary and Han book, 14th edition, volume 2, CTFA, 2012, p. 1800): MAGNESIUM SODIUM FLUOROSILICATE, fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary, Handbook 14th edition) Volume 1, CTFA, 2012, p. 156): ALUMINUM, synthetic aluminum silicate represented by SILICATE.
  • a clay mineral at least one selected from the group consisting of synthetic silicic acid (sodium / magnesium), fluorosilicic acid (sodium / magnesium), and fluorosilicic acid (sodium / magnesium) is used. Clay minerals are particularly preferred.
  • the content of the component (B) is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and further preferably 0.5% by mass. As mentioned above, Preferably it is 10 mass% or less, More preferably, it is 5 mass% or less, More preferably, it is 3 mass% or less.
  • the content of the component (B) is at least the above lower limit, the storage stability and coatability of the hairdressing composition are further improved. In addition, the hair styling property is further improved.
  • the content of the component (B) is not more than the above upper limit, the applicability of the hairdressing agent composition is further improved.
  • the content of the component (B) is the total content of all the components (B) in the hairdressing composition according to the present invention.
  • the component (C) is at least one polymer selected from the group consisting of the component (C1) and the component (C2).
  • the hair styling retention property is further improved.
  • the hairdressing composition is difficult to separate, and the storage stability is further improved.
  • the hairdressing composition is appropriately thickened, so that the dispersibility of the component (A) is further improved and storage stability is improved. Becomes even better.
  • the said component (C) only 1 type may be used and 2 or more types may be used.
  • only 1 type may be used for said component (C1) and said component (C2), respectively, and 2 or more types may be used.
  • component (C) only one of the component (C1) and the component (C2) may be used, or the component (C1) and the component (C2) may be used in combination. .
  • the monomer component used to obtain the polymer of the component (C1) includes at least two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters. That is, the component (C1) is a polymer including at least two or more structural units selected from the group consisting of structural units derived from (meth) acrylic acid and structural units derived from (meth) acrylic acid alkyl esters. . In this specification, the polymer that can correspond to both the component (C1) and the component (C2) is not the component (C1) but the component (C2).
  • C1 examples include Dow Chemical Co., Ltd., trade name “Aculin 33” and trade name “Aculin 33A”; SEPPIC, trade name “SepiMAX ZEN”, and the like.
  • the component (C1) is not particularly limited, but it is preferably neutralized with a basic substance or neutralized with a basic substance.
  • the basic substance include alkanolamines such as triethanolamine and monoethanolamine; inorganic basic compounds such as ammonia, sodium hydroxide and potassium hydroxide; basic amino acids such as arginine.
  • the basic substance is added in an amount sufficient to neutralize the component (C1) or an amount sufficient to neutralize the component (C1).
  • the type of the basic substance and the amount of the component (C1) used may be appropriately blended.
  • the monomer component used to obtain the polymer of the component (C2) is at least one monomer component (c2a) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, and (meth) And at least one monomer component (c2b) selected from the group consisting of polyoxyethylene alkyl ethers of acrylic acid, polyoxyethylene alkyl ethers of itaconate and vinyl neodecanoate. That is, the component (C2) is a polymer including at least a structural unit derived from the monomer component (c2a) and a structural unit derived from the monomer component (c2b). As for the said monomer component (c2a) and the said monomer component (c2b), only 1 type may respectively be used and 2 or more types may be used.
  • C2 International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p.66-67
  • ACRYLATES / STERETTH-20TETHACLAY POLYMERS (Acrylates / Stearless Methacrylic Acid-20) Copolymer)
  • CIRYLATES under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p.
  • ACRYLATES / BEHENETH-25 METHACRYLATE COPOLYMER ((Acrylates / Beheneth-25 Methacrylate Copolymer)); INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, 20th edition, CT, 14th edition) 68-69) "ACRYLATES / VIN L NEODENONOATE CROSSPOLYMER ((Acrylates / vinyl neodecanoate) crosspolymer) ”; INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p.
  • ACRYLATES / STEARETH-20 ITACONATE COPOLYMER ((Acrylates / Itaconic Acid Steareth-20) Copolymer) ”; INCI name (International Cosmetic Ingredient Dictionary and Handbook, Vol. 14, 20th edition, CT, 1st edition .60) “ACRYL A compound represented by “ATES / CETETH-20, ITACONATE COPOLYMER ((Acrelates / Ceteth-20 itaconate) copolymer)” is preferable.
  • the component (C2) is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance.
  • Examples of the basic substance in this case include the basic substances described above.
  • the basic substance is added in an amount sufficient to neutralize the component (C2), or an amount sufficient to neutralize the component (C2). ) And the type of the basic substance and the amount of the component (C2) used may be appropriately blended.
  • the content of the component (C) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and preferably 5% by mass or less. Preferably it is 2 mass% or less.
  • the content of the component (C) is at least the above lower limit, the storage stability and coatability of the hairdressing composition are further improved.
  • the content of the component (C) is not more than the above upper limit, applicability is further improved and the feel of the hair is further improved.
  • Content of the said component (C) is a total amount of content of all the components (C) in the hairdressing composition which concerns on this invention.
  • the total content of the component (B) and the content of the component (C) is the applicability of the hairdressing composition. From the viewpoint of further improvement, preferably 0.2% by mass or more, more preferably 0.4% by mass or more, still more preferably 0.6% by mass or more, preferably 10% by mass or less, more preferably 8% by mass or less. More preferably, it is 5% by mass or less.
  • the total content of the component (B) and the component (C) is not less than the lower limit, the stagnation due to the component (A) at the time of application of the hairdressing composition is further suppressed, and the applicability is further improved. improves.
  • the viscosity is low at the time of application, and even better applicability is exhibited. After application, the viscosity is increased, so that the hairdressing retention is further improved.
  • the total content of the component (B) and the component (C) is not more than the above upper limit, the storage stability of the hairdressing composition is further improved.
  • the mass ratio of the component (B) to the component (C) is preferably 0.1: 1 to 30: 1. 0.2: 1 to 20: 1 is more preferable, and 0.5: 1 to 10: 1 is still more preferable.
  • the component (D) is at least one compound selected from the group consisting of the component (D1) and the component (D2).
  • flaking can be further suppressed, washing off after hair styling is improved, and good hair feel can be imparted to the hair after styling while maintaining high initial hair styling power.
  • the sense of discomfort to which the hair-styling composition is attached is suppressed, and hair can be styled in a natural state.
  • the said component (D) only 1 type may be used and 2 or more types may be used.
  • only 1 type may be used for said component (D1) and said component (D2), respectively, and 2 or more types may be used.
  • component (D) only one of the component (D1) and the component (D2) may be used, and the component (D1) and the component (D2) may be used in combination. .
  • the component (D1) is a polyoxyalkylene alkyl glucoside.
  • the oxyalkylene group in the component (D1) include an oxyethylene group and an oxypropylene group.
  • the average addition mole number of the oxyalkylene group in the component (D1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less.
  • the number of carbon atoms of the alkyl group in the component (D1) is preferably 1 to 4, more preferably 1 to 3.
  • the alkyl group in the component (D1) is preferably a methyl group or an ethyl group.
  • the component (D1) is not particularly limited, and examples thereof include polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside, and polyoxypropylene ethyl glucoside.
  • the component (D1) is preferably polyoxyethylene methyl glucoside.
  • the component (D2) is a polyoxyalkylene glycerin fatty acid ester.
  • the number of carbon atoms of the fatty acid in the component (D2) is preferably 8 or more, and preferably 22 or less.
  • Examples of the oxyalkylene group in the component (D2) include an oxyethylene group and an oxypropylene group.
  • the average added mole number of the oxyalkylene group in the component (D2) is preferably 5 or more, and preferably 40 or less.
  • the fatty acid in the component (D2) is preferably a branched fatty acid, and the component (D2) is a polyoxyalkylene. It is preferably a glycerin branched fatty acid ester.
  • the number of carbon atoms of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, and preferably 16 or less.
  • Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid, and isostearic acid.
  • the polyoxyalkylene glycerin branched fatty acid ester is particularly preferably polyoxyethylene glyceryl isostearate.
  • the content of the component (D) is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 20% by mass or less, more preferably. It is 10 mass% or less.
  • the content of the component (D) is not less than the above lower limit, flaking is further suppressed, washing off after hair styling is further improved, and better touch is imparted to the hair after hair styling.
  • The is not more than the above upper limit, stickiness is further reduced.
  • Content of the said component (D) is a total amount of content of all the components (D) in the hairdressing agent composition which concerns on this invention.
  • the mass ratio of the content of the component (A) to the content of the component (D) is 1 : 0.2 to 1:20 is preferable, and 1: 1 to 1:10 is more preferable.
  • content of the component (A) is relatively increased, the hair styling power is further improved.
  • content of the said component (D) becomes relatively large, the touch of hair and the wash-off property at the time of the hair-washing of a hairdressing agent will become still better.
  • the mass ratio of the content (total content) of the particles selected from the group consisting of magnesium oxide and the content of the component (D) is 1: 0.2 to 1:20, respectively.
  • the ratio is preferably 1: 1 to 1:10.
  • the component (E) is polyethylene glycol. By using the component (E), it is possible to impart a good touch to the hair after styling while maintaining high hair styling properties. As for the said component (E), only 1 type may be used and 2 or more types may be used.
  • the number average molecular weight of the component (E) is preferably 800 or more, more preferably 900 or more, preferably 2000 or less, more preferably 1700 or less. is there.
  • the content of the component (E) is 0.3% by mass or more, preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably mass. It is 15% or less, more preferably 10% by mass or less.
  • content of the component (E) is not less than the above lower limit, the effect of imparting a good touch to the hair is further improved. Hair content improves further because content of the said component (E) is below the said upper limit.
  • Content of the said component (E) is a total amount of content of all the components (E) in the hairdressing composition which concerns on this invention.
  • the hairdressing composition according to the present invention is not particularly limited, but preferably contains water. Although the said water will not be specifically limited if it is the water used for cosmetics, Purified water is preferable. In 100% by mass of the hairdressing composition according to the present invention, the content of water is preferably 30% by mass or more, more preferably 40% by mass or more, preferably 95% by mass or less, more preferably 90% by mass or less. .
  • the hairdressing composition according to the present invention is not particularly limited, but preferably contains a lower alcohol having 2 to 5 carbon atoms (particularly ethanol).
  • the content of the lower alcohol (particularly ethanol) is preferably 2% by mass or more, more preferably 5% by mass or more, preferably 50% by mass or less, more preferably. 30% by mass or less.
  • the hairdressing composition according to the present invention may be used within the range not inhibiting the effects of the present invention, for example, surfactants such as nonionic surfactants, cationic surfactants and amphoteric surfactants; glycerin, 1,3-butylene glycol Polyhydric alcohols such as propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol; lauryl alcohol, myristyl alcohol, C12-18 higher alcohols such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; sugar alcohols such as sorbitol, maltitol and trehalose; polysaccharides such as xanthan gum, carrageenan, guar gum and gellan gum Compounds; silicone oil; sequestrants, antioxidants, plant extracts
  • the property of the hairdressing composition according to the present invention is not particularly limited, and examples thereof include liquid, gel, cream, and solid.
  • the hair styling composition is preferably liquid or gel.
  • the viscosity at 25 ° C. of the hairdressing composition is preferably 1000 mPa ⁇ s or more, more preferably 2000 mPa ⁇ s or more, preferably 100,000 mPa ⁇ s or less, more preferably 50000 mPa ⁇ s or less.
  • the viscosity is not less than the above lower limit and not more than the above upper limit, applicability is further enhanced, flaking and stickiness are further suppressed, and initial hair styling power and hair styling holding power are further enhanced.
  • the viscosity is not more than the above upper limit and the fluidity is high, the occurrence of flaking and stickiness can be suppressed, and the initial hair styling power and hair styling holding power can be increased.
  • the above viscosity is No. using a viscometer. It is measured under the conditions of a rotation speed of 12 rpm and a rotation time of 1 minute using a 4-rotor.
  • a viscometer a TV-22 viscometer manufactured by Toki Sangyo Co., Ltd. can be used.
  • the method for producing the hairdressing composition according to the present invention is not particularly limited, and a known method for producing a hairdressing composition can be used as the method for producing the hairdressing composition according to the present invention. Although it does not specifically limit as a manufacturing method of the hairdressing agent composition which concerns on this invention, For example, after stirring a component (A), a component (C), and water with a disper mixer, changing to a paddle mixer, other The method of mix
  • the hairdressing composition according to the present invention includes at least a component (A), a component (B), and a component (C).
  • the hairdressing composition according to the present invention exhibits excellent hair holding ability. Furthermore, only the component (A) solves the problem that the applied hair is stagnated and improves applicability. Furthermore, it is presumed that the combined use of component (B) and component (C) results in the formation of a crosslinked structure of component (B) and component (C), but the hairdressing composition is moderately thickened. . In addition, the hairdressing composition exhibits thixotropic properties, and the viscosity decreases under shear stress.
  • a component (A) becomes difficult to settle or aggregate, and the storage stability when a hairdressing composition is stored for a long period of time improves.
  • applicability is improved.
  • the said effect is further improved by making the compounding ratio of a component (B) and a component (C) into a specific preferable range.
  • the combined use of the component (B) and the component (C) causes the component (C) to exhibit an effect of retaining water, but separation of the hairdressing composition (liquid component separation) And storage stability is further improved.
  • the hair styling power and flaking suppression effect are further improved, and further, the effect of giving gloss to the hair after hair styling and the wash-off property are improved.
  • the hair styling composition according to the present invention preferably further contains a component (E).
  • a component (E) By using the component (E), it is possible to impart a good touch to the hair after styling while maintaining high hair styling properties. In addition, stickiness arises only with a component (E), but the said effect can be exhibited, suppressing stickiness, by using a component (A) and a component (E) together.
  • the hairdressing composition according to the present invention is used, not only hair can be properly dressed, but the state of hairstyling can be favorably sustained for a long period of time. Furthermore, the hairdressing composition of the present invention is excellent in storage stability.
  • the hair styling composition according to the present invention is not particularly limited, but can be used, for example, in a form filled in a container.
  • Examples of the container include a bottle container, a jar container, and a tube container.
  • the container is preferably a bottle container or a tube container.
  • Component (D) Product name "Neugen GIS-125": Polyoxyethylene glyceryl isostearate, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.
  • Examples 1 to 42 and Comparative Examples 1 to 9 Blending ingredients shown in the following Tables 1 to 6 were blended (blending unit is mass%) to prepare hairdressing composition.
  • the properties of the hairdressing composition obtained in Examples 1 to 42 were all gel-like.
  • surface was shown by the actual compounding quantity (composition quantity of goods).
  • the obtained hairdressing composition was filled in a plastic container.
  • Test Example 3 Evaluation of hair holding ability
  • Twenty professional panels observed the hair of the wig subjected to hair styling after 6 hours after the test example 2 (applicability evaluation), and answered the presence or absence of hair styling retention power. In addition, it was determined that the hair having the hair shape of Test Example 2 in which the shape of the hair was kept is held. Based on the above answers, hair holding ability was evaluated according to the following criteria.
  • Example 1 The hair styling compositions obtained in Example 1, Example 20, Example 22, and Example 41 were also evaluated for the following flaking and washing-off.
  • Test Example 4 Evaluation of flaking
  • Twenty expert panels combed the hair of the wig from the root of the hair to the tip of the hair with the fingertips five times after the above Test Example 3 (evaluation of hair holding ability), and answered the presence or absence of flaking.
  • Test Example 3 evaluation of hair holding ability
  • flaking was evaluated according to the following criteria.
  • the hairdressing composition obtained in Example 1 and Example 22 had an evaluation result of “ ⁇ (pretty good)” for both flaking and washing-off.
  • the hairdressing composition obtained in Example 20 and Example 41 had an evaluation result of “ ⁇ (good)” for both flaking and washing-off.

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Abstract

La composition de coiffage ci-décrite contient : 0,1-10 % en poids, limites incluses, de particules (composant A) choisies dans le groupe constitué par la silice, le carbonate de calcium, le carbonate de magnésium, l'hydroxy- apatite, l'oxyde de titane, l'oxyde de zinc, le silicate de calcium, le silicate de magnésium, le silicate d'aluminium, et l'hydroxyde de magnésium ; et des minéraux argileux (composant B). La composition de coiffage contient également un polymère (composant C) choisi dans le groupe constitué par : un polymère (composant C1) obtenu à l'aide de deux monomères ou plus choisis dans le groupe constitué par l'acide (méth)acrylique, et un ester d'alkyle d'acide (méth)acrylique ; et un polymère (composant C2) obtenu à l'aide d'un monomère choisi dans le groupe constitué par l'acide (méth)acrylique, et un ester d'alkyle d'acide (méth)acrylique, et d'un monomère choisi dans le groupe constitué par un éther polyoxyéthylène alkylique d'acide (méth)acrylique, un éther polyoxyéthylène alkylique d'acide itaconique, et le néodécanoate de vinyle.
PCT/JP2014/058986 2013-03-29 2014-03-27 Composition de coiffage WO2014157564A1 (fr)

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JP2017109934A (ja) * 2015-12-15 2017-06-22 株式会社ミルボン 毛髪用処理剤、毛髪処理方法
JP2017160166A (ja) * 2016-03-10 2017-09-14 ジャパンコーティングレジン株式会社 整髪剤用アクリル系樹脂エマルションおよびその製造方法、並びに整髪剤およびその製造方法
JP2017206478A (ja) * 2016-05-20 2017-11-24 株式会社マンダム 整髪剤組成物
WO2018198563A1 (fr) * 2017-04-27 2018-11-01 株式会社マンダム Composition d'agent de coiffage
JP2019142824A (ja) * 2018-02-23 2019-08-29 ホーユー株式会社 整髪剤組成物
JP7169879B2 (ja) 2016-11-08 2022-11-11 株式会社 資生堂 整髪料組成物

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JP6192502B2 (ja) * 2013-11-19 2017-09-06 株式会社マンダム 乳化整髪剤組成物
WO2015174130A1 (fr) * 2014-05-16 2015-11-19 株式会社マンダム Composition de coiffure
JP6628487B2 (ja) * 2015-03-31 2020-01-08 株式会社マンダム 整髪剤組成物
JP6723772B2 (ja) * 2016-03-10 2020-07-15 ジャパンコーティングレジン株式会社 整髪剤組成物
JP6679169B2 (ja) * 2016-05-20 2020-04-15 株式会社マンダム 整髪剤組成物

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WO2015145822A1 (fr) * 2014-03-28 2015-10-01 株式会社マンダム Composition de produit de coiffure pour les cheveux
JP2017109934A (ja) * 2015-12-15 2017-06-22 株式会社ミルボン 毛髪用処理剤、毛髪処理方法
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JP2017160166A (ja) * 2016-03-10 2017-09-14 ジャパンコーティングレジン株式会社 整髪剤用アクリル系樹脂エマルションおよびその製造方法、並びに整髪剤およびその製造方法
JP2017206478A (ja) * 2016-05-20 2017-11-24 株式会社マンダム 整髪剤組成物
JP7169879B2 (ja) 2016-11-08 2022-11-11 株式会社 資生堂 整髪料組成物
WO2018198563A1 (fr) * 2017-04-27 2018-11-01 株式会社マンダム Composition d'agent de coiffage
JP2019142824A (ja) * 2018-02-23 2019-08-29 ホーユー株式会社 整髪剤組成物
JP7178684B2 (ja) 2018-02-23 2022-11-28 ホーユー株式会社 整髪剤組成物

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WO2014157563A1 (fr) 2014-10-02
CN105025867B (zh) 2017-08-04
KR101789397B1 (ko) 2017-10-23
JP6013587B2 (ja) 2016-10-25
KR20150103237A (ko) 2015-09-09
KR101763501B1 (ko) 2017-07-31
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CN105007887B (zh) 2018-08-31
JP6092365B2 (ja) 2017-03-08

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