WO2014132393A1 - スピーカ用振動板 - Google Patents
スピーカ用振動板 Download PDFInfo
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- WO2014132393A1 WO2014132393A1 PCT/JP2013/055409 JP2013055409W WO2014132393A1 WO 2014132393 A1 WO2014132393 A1 WO 2014132393A1 JP 2013055409 W JP2013055409 W JP 2013055409W WO 2014132393 A1 WO2014132393 A1 WO 2014132393A1
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- diaphragm
- liquid
- layer
- speaker
- diaphragm layer
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R7/00—Diaphragms for electromechanical transducers; Cones
- H04R7/02—Diaphragms for electromechanical transducers; Cones characterised by the construction
- H04R7/12—Non-planar diaphragms or cones
- H04R7/122—Non-planar diaphragms or cones comprising a plurality of sections or layers
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R7/00—Diaphragms for electromechanical transducers; Cones
- H04R7/02—Diaphragms for electromechanical transducers; Cones characterised by the construction
- H04R7/12—Non-planar diaphragms or cones
- H04R7/122—Non-planar diaphragms or cones comprising a plurality of sections or layers
- H04R7/125—Non-planar diaphragms or cones comprising a plurality of sections or layers comprising a plurality of superposed layers in contact
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R31/00—Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor
- H04R31/003—Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor for diaphragms or their outer suspension
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R2231/00—Details of apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor covered by H04R31/00, not provided for in its subgroups
- H04R2231/001—Moulding aspects of diaphragm or surround
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R2307/00—Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
- H04R2307/021—Diaphragms comprising cellulose-like materials, e.g. wood, paper, linen
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R2307/00—Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
- H04R2307/023—Diaphragms comprising ceramic-like materials, e.g. pure ceramic, glass, boride, nitride, carbide, mica and carbon materials
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R2307/00—Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
- H04R2307/025—Diaphragms comprising polymeric materials
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R2307/00—Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
- H04R2307/027—Diaphragms comprising metallic materials
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04R—LOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
- H04R2307/00—Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
- H04R2307/029—Diaphragms comprising fibres
Definitions
- the present invention relates to a speaker diaphragm.
- the speaker diaphragm has a multilayer structure in which a plurality of diaphragm layers having different physical properties are stacked for the purpose of improving sound quality (see, for example, Patent Document 1).
- a diaphragm for a speaker having a multi-layer structure is made by making different materials separately, for example, by making a paper between a semi-dried inner cone paper and an outer cone paper, and making a semi-dried inner-layer cone paper. Is manufactured by laminating and sandwiching and heating and pressing, or by adhering an adhesive fiber to the material constituting one layer and bonding it to the other layer.
- the loudspeaker diaphragm manufactured by the above-described method is formed by dewatering the layers made in advance and then stacking them. Therefore, the bonding between the cone papers (each layer) becomes relatively weak, and there is a problem such as delamination.
- An example of a problem is a point that may occur.
- an increase in manufacturing cost due to the use of adhesive fibers is an example of a problem.
- an object of the present invention is to provide an inexpensive speaker diaphragm that can suppress delamination.
- the invention described in claim 1 is a speaker diaphragm comprising a plurality of laminated papermaking bodies, and two papermaking bodies adjacent to each other are integrated. is there.
- FIG. 4B is a cross-sectional view for explaining the speaker diaphragm shown in FIG. 4A
- FIG. 3C is an enlarged cross-sectional view of the speaker diaphragm shown in FIG. .
- FIG. 3C It is a figure for demonstrating the manufacturing apparatus of the diaphragm for speakers, and a figure for demonstrating an example of the 1st diaphragm layer formation process of the manufacturing method of the diaphragm for speakers.
- the speaker diaphragm according to an embodiment of the present invention includes a plurality of laminated paper products, and two paper products adjacent to each other are integrated. Moreover, the boundary part of two papermaking bodies adjacent to each other may be integrated. Since it did in this way, the integrity between each papermaking body can be improved without using adhesive fiber etc., and interlayer isolation
- This unity includes connectivity. Specific examples of having the integrity include having a predetermined adhesion, a predetermined adhesion, a predetermined peeling strength, a predetermined bonding force, and a predetermined binding force.
- the papermaking body may be made of a material, and an entangled portion where the materials of the two papermaking bodies are entangled may be formed at a boundary portion between the two papermaking bodies.
- the thickness of the entangled portion may be smaller than the thickness of one of the two papermaking bodies.
- the peel strength may be between two papermaking bodies adjacent to each other. By doing in this way, the integrity between each layer can be improved and the isolation between papermaking bodies can be suppressed.
- the density of one of the two papermaking bodies may be larger than the density of the other papermaking body.
- one papermaking body of two papermaking bodies adjacent to each other may be a surface layer of the plurality of papermaking bodies, and this one papermaking body may have a uniform thickness throughout.
- the other papermaking body adjacent to one papermaking body of two papermaking bodies adjacent to each other may have a uniform thickness throughout.
- FIG. 1 is a view for explaining a speaker diaphragm according to an embodiment of the present invention.
- FIG. 1A is a half sectional view for explaining a speaker device employing a speaker diaphragm according to an embodiment of the present invention.
- FIG. 1B is a cross-sectional view for explaining the speaker diaphragm shown in FIG.
- FIG. 1C is an enlarged cross-sectional view of the speaker diaphragm shown in FIG.
- a speaker device 10 employing a speaker diaphragm according to an embodiment of the present invention includes a magnetic circuit 1 formed by a magnet 1A, a plate 1B, and a yoke 1C, and a magnetic circuit 1 as shown in FIG.
- the voice coil 3 wound around the voice coil support portion 2 and the speaker diaphragm 4 whose center portion is fixed to the voice coil support portion 2 are disposed in the magnetic gap.
- the outer peripheral edge of the speaker diaphragm 4 is fixed to the frame 7 via an edge 5 and a gasket 6.
- the voice coil support 2 is fixed to the frame 7 by a damper 8, and the opening of the voice coil support 2 is covered with a center cap 9.
- the speaker diaphragm 4 has a multilayer structure in which a plurality of diaphragm layers are stacked. As shown in FIGS. 1B and 1C, the speaker diaphragm 4 includes a first diaphragm layer 4a and a second diaphragm layer 4b made of a papermaking body formed by papermaking.
- the speaker diaphragm 4 is an example of a laminated body and an example of a multilayer papermaking body.
- Each of the first diaphragm layer 4a and the second diaphragm layer 4b corresponds to an example of a papermaking body.
- the speaker diaphragm 4 having a two-layer structure will be described here, the present invention is not limited to this form, and the speaker diaphragm 4 may have a multilayer structure of three or more layers.
- the configuration of the speaker diaphragm which will be described later, may be diverted to a speaker edge, a speaker diaphragm in which the speaker diaphragm and the speaker edge are integrally formed, or a center cap.
- the speaker edge has a multilayer structure in which a plurality of edge layers are stacked
- the speaker vibration body has a multilayer structure in which a plurality of vibration layers are stacked
- the center cap has a plurality of center cap layers stacked. It will have a multilayer structure.
- the outermost layer on the side where the center cap 9 is provided corresponds to an example of the surface layer.
- the first diaphragm layer 4a corresponds to an example of the other layer
- the second diaphragm layer 4b corresponds to an example of one layer and the surface layer.
- Each diaphragm layer of the speaker diaphragm 4 is made of a material.
- Materials include, for example, wood pulp fibers, non-wood pulp fibers, chemical fibers, synthetic fibers, animal fibers, plant fibers, organic fibers, inorganic fibers, glass fibers, carbon fibers, ceramic fibers and other fibrous materials, mica powder, graphite And particulate materials such as carbon-based materials, metal materials, ceramic materials, and resins.
- the “material” includes, for example, the aforementioned powder, hollow particles, fibers, and the like.
- the material 4a1 of the first diaphragm layer 4a and the material 4b1 of the second diaphragm layer 4b may be different types of materials or the same type of materials.
- the diaphragm layers of the speaker diaphragm 4 are separated by a liquid layer that does not include the material of each diaphragm layer, and a plurality of suspension liquids that include the material of the diaphragm layer are sequentially formed.
- the diaphragm layers are laminated so that the diaphragm layers are integrated.
- the materials of two adjacent diaphragm layers are bonded to each other by a chemical bond (the chemical bond includes van der Waals force, hydrogen bond, metal bond, etc.).
- the material is natural fiber, they are bonded by hydrogen bonding.
- the suspension corresponds to an example of the first liquid and the second liquid.
- the speaker diaphragm 4 having this structure has a relatively large coupling force between the diaphragm layers, so that problems such as delamination can be prevented.
- the speaker diaphragm 4 having a structure laminated by papermaking has an entangled portion 4z in which fibrous materials (particularly, fibers) of each diaphragm layer are intertwined at a boundary portion between each diaphragm layer. .
- this entangled portion 4z the diaphragm layers are integrally formed, and the integral force (including the coupling force) between the diaphragm layers is increased, and problems such as delamination can be suppressed.
- the thickness of the entangled portion 4z formed at the boundary portion between the first diaphragm layer 4a and the second diaphragm layer 4b of the speaker diaphragm 4 is such that the first diaphragm layer 4a and the second diaphragm layer 4b are the same.
- the thickness is preferably smaller than the thickness of the first diaphragm layer 4a or the thickness of the second diaphragm layer 4b so as to have a predetermined thickness.
- FIG. 2 is a diagram for explaining a speaker diaphragm manufacturing apparatus, and a diagram for explaining an example of a first diaphragm layer forming step of the speaker diaphragm manufacturing method.
- FIG. 3 is a diagram for explaining an example of a liquid layer injection step of the method for manufacturing the speaker diaphragm.
- FIG. 4 is a diagram for explaining an example of a second diaphragm layer forming step of the method for manufacturing the speaker diaphragm.
- FIG. 5 is a diagram for explaining an example of a state of deposition after injection of the suspension liquid containing the material of the second diaphragm layer.
- FIG. 6 is a diagram for explaining an example of a molding process of the speaker diaphragm manufacturing method.
- FIG. 7 is a diagram for explaining an example of another molding process of the speaker diaphragm manufacturing method.
- the loudspeaker diaphragm manufacturing apparatus 20 sequentially injects a suspension liquid containing the diaphragm layer material into a common tank for papermaking, with a liquid layer not including the diaphragm layer material interposed therebetween. Then, the suspension liquid is sequentially made to laminate a plurality of diaphragm layers.
- the speaker diaphragm manufacturing apparatus 20 corresponds to an example of a laminate manufacturing apparatus.
- the speaker diaphragm manufacturing apparatus 20 includes a tank 30, a dehydrating apparatus 61, a liquid injection apparatus 62, and a control apparatus 70 as shown in FIG. 2.
- the tank 30 includes a tank body 31, a papermaking unit 40, and a liquid injection unit 50.
- the tank body 31 is formed in a cylindrical shape (cylindrical shape in the illustrated example) using a light-transmitting material such as acrylic, for example, and a suspension containing a liquid such as water or a material of a diaphragm inside the tank body 31. Liquid such as liquid is injected. That is, the tank body 31 stores the liquid.
- the tank main body 31 corresponds to an example of a wall portion of the tank (in the illustrated example, the wall portion is formed in a cylindrical shape).
- the papermaking section 40 includes an attachment section 41, a mold 42, a net 43, and an inclined surface section 44.
- the attachment portion 41 is formed in a concave shape, and the mold 42, the net 43, and the inclined surface portion 44 are disposed in the attachment portion 41.
- a connecting port 41B as an example of a dehydrating port to which a dehydrating device 61 described later is connected is provided at the center of the bottom of the attachment unit 41, and a valve is provided in the connecting port 41B.
- the mold 42 includes a plurality of suction ports 42 ⁇ / b> A and a support surface 42 ⁇ / b> B to which the plurality of suction ports 42 ⁇ / b> A are attached and support the net 43.
- the plurality of suction ports 42 ⁇ / b> A are connected to the dehydrator 61.
- the support surface 42B is formed in a concave shape, and a net 43 is disposed on the support surface 42B.
- An inclined surface portion 44 is connected to the outer peripheral portion 43 a of the net 43.
- the net 43 is formed in a predetermined shape according to the shape of the speaker diaphragm, for example, and is formed in a cone shape in this configuration example.
- the net 43 is formed with, for example, a plurality of holes, and deposits the material on the net 43 out of the suspension liquid containing the material of the diaphragm layer, and allows the liquid to pass through the holes.
- a metal net or a punching metal can be employed.
- the inclined surface portion 44 is a cylindrical member (substantially cylindrical shape in the illustrated example) formed in an inclined surface shape (tapered surface shape) in which the inner diameter gradually decreases from the upper end 44a to the lower end 44b. is there.
- the edge part of the lower end 44b of the inclined surface part 44 is connected with the outer peripheral part 43a of the net
- the edge part of the upper end 44a of the inclined surface part 44 is supported by the attaching part 41 over the perimeter.
- a step portion 41C formed at the edge on the upper end side of the attachment portion 41 is detachably fitted to the lower end of the tank body 31.
- the tank body 31, the mounting portion 41, the mold 42, and the net 43 are arranged so that their axis centers overlap the axis L.
- the liquid injection unit 50 includes a liquid injection port 51 and a conduit 52.
- the liquid inlet 51 is opened in a slit shape (that is, in an annular shape) over the entire circumference of the inner peripheral surface 31 a of the tank body 31 at the lower portion of the tank body 31 (that is, the lower portion of the tank 30). Thereby, the liquid can be injected from the liquid injection port 51 over the entire circumferential direction of the tank body 31.
- the liquid inlet 51 only needs to be provided at least in the lower part of the tank 30. In the present configuration example, as an example, the liquid inlet 51 is provided in the lower part of the tank 30 and the papermaking unit 40 (specifically, the inclined portion). It is arranged above the upper end 44a) of the face 44.
- the conduit 52 is connected to the liquid injection port 51, and is configured to guide the liquid supplied from the liquid injection device 62 to the liquid injection port 51.
- the dehydrator 61 includes, for example, a suction pump and is connected to each suction port 42A of the mold 42.
- the dehydrating device 61 sucks liquid in the liquid stored in the tank body 31 through the net 43 provided at the lower part of the tank 30.
- the dehydrating device 61 is connected to the control device 70 and operates in response to a control signal from the control device 70.
- the liquid injection device 62 includes a storage tank that stores liquid to be injected into the tank 30, and a pump (not shown) that sends the liquid stored in each storage tank to a conduit 52 connected to the tank 30.
- a storage tank that stores liquid to be injected into the tank 30, and a pump (not shown) that sends the liquid stored in each storage tank to a conduit 52 connected to the tank 30.
- One or a plurality of storage tanks may be provided, and the liquid may be stored in the storage tank for each different type of liquid.
- the liquid injection device 62 is connected to the control device 70 and operates in response to a control signal from the control device 70.
- the control device 70 is configured to include, for example, a microcomputer, and implements the function according to the present invention by comprehensively controlling the entire manufacturing device 20.
- the control device 70 controls operations of the dehydrating device 61, the liquid injection device 62, and the like. At this time, the control device 70 performs the above control based on the detection result of the sensor 32 provided in the tank 30, as shown in FIG.
- the sensor 32 detects characteristics relating to the liquid and material in the tank 30 such as the liquid level, the degree of dispersion of the material in the liquid, and the degree of flow of the liquid, and outputs a signal indicating the detection result to the control device 70. To do.
- the tank 30 is provided with a tank body 31 so that a suspension liquid containing the diaphragm layer material can be sequentially injected across the liquid layer not including the diaphragm layer material. It is preferable that the length is not less than a predetermined length.
- the speaker diaphragm manufacturing method includes (1) a diaphragm layer forming step and (2) a molding step.
- the diaphragm layer forming step includes (1-a) first diaphragm layer forming step, (1-b) liquid layer injecting step, and (1-c) second diaphragm layer forming step as sub-steps. .
- the first suspension liquid K1 and the second suspension liquid K2 containing the material for forming each diaphragm layer are sequentially injected into the tank 30, The liquid is dehydrated.
- the first suspension liquid K1 corresponds to an example of a first liquid
- the second suspension liquid K2 corresponds to an example of a second liquid.
- the first suspension K1 containing the material 4a1 of the first diaphragm layer 4a is poured into the tank 30.
- the control device 70 controls the liquid injection device 62 to inject from the liquid injection port 51 the first suspension K1 prepared in advance by including the material 4a1 in the water.
- the material 4 a 1 may be injected (injected) into the tank 30 while injecting a liquid such as water into the tank 30 from the upper end opening of the tank 30.
- the method of injecting the first suspension K1 that is initially injected into the tank 30 is arbitrary.
- a first suspension liquid layer R51 in which the material 4a1 is dispersed in water is formed.
- the liquid that is, water
- the controller 70 may control the dehydrator 61 to forcibly suck the liquid to perform dehydration, or may perform dehydration by natural fall without forcibly sucking.
- the injection speed of the first suspension liquid K1, the liquid dehydration speed, and the like are appropriately adjusted so that the liquid level in the tank 30 does not become lower than the liquid injection port 51.
- the thickness of the liquid layer R52 (the length along the vertical direction of the tank 30) can be determined according to various conditions such as the specific gravity of the material of each diaphragm layer, the falling speed of the material in the liquid, and the like. preferable.
- the controller 70 may control the dehydrator 61 to forcibly suck the liquid for dehydration, or the liquid may be dehydrated by natural fall without forcibly sucking.
- the liquid W injection speed, the liquid dehydration speed, and the like are adjusted as appropriate so that the water level in the tank 30 does not fall below the liquid injection port 51.
- the liquid that is, water
- the material 4b1 of the second diaphragm layer 4b is deposited so as to overlap the material 4a1 of the first diaphragm layer 4a deposited on the mesh 43.
- the liquid may be forcibly sucked and dehydrated by the dehydrating device 61, or the liquid may be dehydrated by natural fall without forced suction.
- the control device 70 controls the liquid injection device 62 to inject a predetermined amount of liquid W from the liquid injection port 51,
- the liquid layer R54 that does not include the material of the diaphragm layer may be formed.
- the liquid component (water) in the tank 30 is dehydrated, and a multilayer paper-making body in which the material 4a1 of the first diaphragm layer 4a and the material 4b1 of the second diaphragm layer 4 are laminated on the net 43 is obtained.
- the liquid layer injection process is sandwiched between the first diaphragm layer forming process and the second diaphragm layer forming process. That is, a predetermined period between the end of the injection of the first suspension K1 performed in the first diaphragm layer forming step and the start of the injection of the second suspension K2 performed in the second diaphragm layer forming step. In this predetermined period, the liquid W that does not contain the material of each diaphragm layer is injected into the liquid in the tank 30.
- the material 4a1 is deposited after the first suspension K1 is injected and deposited on the net 43, and the material of the diaphragm layer is not included even if the liquid W is not injected. If the liquid layer R52 is formed, the liquid layer injection step of injecting the water W during the predetermined period may be omitted.
- the controller 70 determines the first suspension liquid layer R51, the liquid layer R52 and the second suspension liquid layer R53 according to the state of the first suspension liquid layer R53, the second suspension liquid layer R53, and the deposition (lamination) state on the net.
- the injection timing, injection rate, or dehydration rate of the suspension liquid K1, the second suspension liquid K2, and the water W are adjusted.
- the operator may manually operate the dehydration device 61 and the liquid injection device 62 while visually confirming the state in the tank 30 and the like.
- the paper making section 40 (specifically, the net 43) is provided in the lower part of the tank 30 in the diaphragm layer forming step, dehydration starts when the liquid is injected into the tank 30. Thereafter, the operation is continued until the liquid in the tank 30 is exhausted.
- the diaphragm layer forming step The start time and duration of dehydration in are arbitrary.
- the dehydration start timing and duration can be arbitrarily changed.
- dehydration may be performed continuously from the end of the injection of the first suspension K1 (including immediately after the end of injection and after a while has passed since the end of the injection) until after the end of the injection of the second suspension.
- the dehydration may be started at the latest before the start of the injection of the second suspension.
- a multilayer paper-making body in which the material 4a1 of the first diaphragm layer 4a and the material 4b1 of the second diaphragm layer 4 are formed on the mesh 43 (that is, The speaker diaphragm 4) is molded by a molding method such as a hot press method, a wet press method, or an oven method, and the speaker diaphragm 4 as shown in FIGS. Is made.
- the multilayer paper-making body is taken out from the net 43 and, for example, as shown in FIG. 6, a female die 81 provided with a heating unit 811 and a male die 82 provided with a heating unit 821 are provided.
- the speaker diaphragm 4 having a predetermined shape is manufactured by heating and pressurizing with a mold 80 having the same.
- the multi-layer paper body is taken out from the net 43 and, for example, the multi-layer paper body is placed in a mold 83 having a hollow portion 831 disposed in a drying pot 800 as shown in FIG. While being suctioned by the vacuum pump 832, drying is performed by a heating device 84 such as a gas stove disposed above the mold 83. In this method, the speaker diaphragm 4 is produced only by drying without applying pressure.
- wood pulp fiber NBKP softwood bleached kraft pulp
- NBKP of this wood pulp fiber is beaten, set to a beating degree of about 20 ° SR (Shopper Liegler) and dispersed in water, and a suspension having a concentration of about 1.0 g / L (first suspension) K1) is prepared.
- the first suspension liquid K ⁇ b> 1 is injected into the tank 30 from the liquid injection port 51.
- the material 4a1 starts to settle after its injection due to its own weight.
- the material 4a1 starts to be sucked from the suction port 42A of the mold 42 by the dehydrator 61 and dehydrated, the material 4a1 is placed on the net 43 having a predetermined shape. To deposit. After the first suspension K1 is injected, water W is continuously injected into the liquid in the tank 30 from the liquid injection port 51 to form a liquid layer R52 that does not include the material of the diaphragm layer as shown in FIG. To do. During this time, dehydration continues.
- NBKP coniferous bleached kraft pulp
- the material 4b1 of the surface layer (second diaphragm layer 4b) is adopted as the material 4b1 of the surface layer (second diaphragm layer 4b), and the NBKP is adjusted to a beating degree of about 20 ° SR.
- a suspension (second suspension K2) of about 1.0 g / L is prepared in advance. After the liquid W is injected, the second suspension K2 is injected from the liquid injection port 51 in the liquid in the tank 30 as shown in FIG. At this time, the suction by the dehydrator 61 is continuously performed, and the material 4 b 1 is deposited on the net 43. In this case, the strength of the suction needs to be balanced with the amount of water supplied.
- the dehydrating apparatus 61 can adjust the vacuum pressure to about 0 to 500 mmHg (0 to 66660 Pa).
- the tank body 31 is removed from the papermaking unit 40, and the net 43 is placed on the mold 80 having the same shape and sucked, whereby the deposited material is transferred onto the mold 80 as shown in FIG.
- the mold 80 is heated to a temperature of about 160 ° C. and dried by pressing at a pressure of about 2 kg / cm 2 (196 kPa) for about 40 seconds.
- the first diaphragm layer 4a and the second diaphragm layer 4b may be dyed in different colors.
- the loudspeaker diaphragm 4 of the present embodiment includes the first diaphragm layer 4a and the second diaphragm layer 4b, which are each composed of a papermaking material of the materials 4a1 and 4b1, and are laminated with each other.
- the 1st diaphragm layer 4a and the 2nd diaphragm layer 4b are integrated in those boundary parts. Since it did in this way, the coupling
- an adhesive fiber such as a polyvinyl alcohol fiber, a polyvinyl alcohol fiber containing boron, or a heat fusion fiber may be used.
- an entangled portion 4z in which materials contained in the first diaphragm layer 4a and the second diaphragm layer 4b are entangled with each other is formed.
- the first diaphragm layer 4a and the second diaphragm layer 4b can be integrated by the entangled portion at the boundary portion thereof, so that the integrity between the layers can be improved and the interlayer separation can be suppressed.
- the first diaphragm layer 4a and the second diaphragm layer 4b can be integrated to increase the first Separation of the diaphragm layer 4a and the second diaphragm layer 4b can be suppressed. Further, the first diaphragm layer 4a and the second diaphragm layer 4b can be integrated with each other while maintaining the predetermined thickness of the first diaphragm layer 4a and the second diaphragm layer 4b. Isolation of 4a and the 2nd diaphragm layer 4b can be suppressed. Further, since the predetermined thickness of the first diaphragm layer 4a and the second diaphragm layer 4b can be maintained, the acoustic characteristics of the speaker device using the speaker diaphragm according to the present invention can be improved.
- the second diaphragm layer 4b when the second diaphragm layer 4b is a surface layer, the second diaphragm layer 4b has a uniform thickness throughout. When the thickness of the second diaphragm layer 4b is not uniform and there is almost no thickness at a predetermined position, the desired physical properties of the speaker diaphragm 4 cannot be obtained. For this reason, the acoustic characteristics of the speaker device are reduced. However, since the second diaphragm layer 4b of the speaker diaphragm 4 according to the present invention has a uniform thickness, desired physical properties of the speaker diaphragm 4 can be obtained, and the acoustic characteristics of the speaker device can be improved. The acoustic characteristics to be obtained can be obtained.
- the first diaphragm layer 4a adjacent to the second diaphragm layer 4b has a uniform thickness throughout.
- desired physical properties of the speaker diaphragm 4 cannot be obtained.
- the acoustic characteristics of the speaker device are reduced.
- the first diaphragm layer 4a of the speaker diaphragm 4 according to the present invention has a uniform thickness, desired physical properties of the speaker diaphragm 4 can be obtained, and the acoustic characteristics of the speaker device can be improved. The acoustic characteristics to be obtained can be obtained.
- the first diaphragm layer 4a may be a surface layer.
- the speaker diaphragm 4 may have a multilayer structure of three or more layers.
- at least the third diaphragm layer 4c is provided.
- the third diaphragm layer 4c the first diaphragm layer 4a and the second diaphragm layer 4b have uniform thickness, so that desired physical properties of the speaker diaphragm 4 can be obtained, and the acoustic characteristics of the speaker device are obtained. And desired acoustic characteristics can be obtained.
- the method for manufacturing the speaker diaphragm described above is a method for manufacturing the speaker diaphragm 4 having a two-layer structure, but is not limited thereto.
- a method of manufacturing a speaker diaphragm 4A having a multilayer structure of three or more layers shown in FIGS. 8A and 8B may be used.
- the speaker diaphragm 4A has a three-layer structure in which a first diaphragm layer 4d, a second diaphragm layer 4e, and a third diaphragm layer 4f are sequentially laminated.
- a foam layer is formed as the second diaphragm layer 4e which is an intermediate layer. This foam layer is produced by making a fine hollow body (a foam material having a hollow particle shape) that expands by heating, and then compressing it by heating.
- a method for manufacturing the speaker diaphragm 4A having the three-layer structure will be briefly described.
- a suspension (first suspension) containing the material of the first diaphragm layer 4 d is injected into the tank 30.
- Water (liquid) that does not contain the diaphragm material is injected from the liquid injection port 51 in the liquid in the tank 30. At this time, a liquid layer made of water is formed on the suspension liquid layer made of the first suspension.
- a suspension liquid layer composed of the second suspension liquid is formed on the liquid layer.
- Water (liquid) that does not contain the material of the diaphragm in the liquid in the tank 30 is injected from the liquid inlet 51. At this time, a liquid layer made of water is formed on the suspension liquid layer made of the second suspension.
- a suspension (third suspension) containing the material of the third diaphragm layer 4f is injected into the liquid in the tank 30. At this time, a suspension liquid layer made of the third suspension liquid is formed on the liquid layer.
- the liquid in the tank 30 is discharged by dehydration performed in parallel with the liquid injection, and the first diaphragm layer 4d, the second diaphragm layer 4e, and the third diaphragm layer 4f are formed on the net 43.
- a laminated multilayer paper product is obtained.
- the multilayer papermaking body is heated and pressurized with a mold 80 in substantially the same manner as in the above-described embodiment, thereby producing a speaker diaphragm 4 ⁇ / b> A having a three-layer structure as shown in FIG. 8.
- a pulp fiber prepared to NBKP 20 ° SR is used as in the first embodiment, and a cationic sizing agent is used to further increase the waterproof property of the pulp material. Add about 5%.
- a material for the intermediate layer (second diaphragm layer 4e) for example, a fine hollow body having an average particle diameter of about 20 ⁇ m and a property of expanding by heating is dispersed in water (liquid) at a concentration of about 1.0 g / L. A turbid liquid (second turbid liquid) is prepared.
- a raw material obtained by mixing mica powder at a ratio of 10% with respect to the same pulp raw material (90%) as the base material layer (first diaphragm layer 4d) is 1.
- a concentration of about 0 g / L is prepared, and about 5% of a sizing agent is similarly added to prepare a turbid liquid (third turbid liquid).
- the material of the base material layer and water are injected into the tank 30 to obtain a turbid liquid (first turbid liquid). Then, water is injected from the liquid inlet 51 in the liquid in the tank 30, and then the second turbid liquid is injected from the liquid inlet 51 in the liquid in the tank 30. Further, after injecting water from the liquid inlet 51 in the liquid in the tank 30, the third turbid liquid is injected from the liquid inlet 51 in the liquid in the tank 30.
- the liquid in the tank 30 is dehydrated in parallel with the injection of each liquid, and a multilayer comprising the first diaphragm layer 4d, the second diaphragm layer 4e, and the third diaphragm layer 4f on the net 43.
- a papermaking product is obtained. And this multilayer papermaking body is press-dried similarly to 1st Embodiment with the metal mold
- the material of the first diaphragm layer 4d and the material of the second diaphragm layer 4e are intertwined with the boundary portion between the first diaphragm layer 4d and the second diaphragm layer 4e.
- a first entangled portion 4x is formed.
- a second entangled portion 4y formed by the material of the second diaphragm layer 4e and the material of the third diaphragm layer 4f entangled with the boundary portion between the second diaphragm layer 4e and the third diaphragm layer 4f. Is formed.
- the thickness of the first entangled portion 4x is smaller than the thickness of the first diaphragm layer 4d, the second diaphragm layer 4e, or the third diaphragm layer 4f.
- the thickness of the second entangled portion 4y is smaller than the thickness of the first diaphragm layer 4d, the second diaphragm layer 4e, or the third diaphragm layer 4f.
- the first diaphragm layer 4d, the second diaphragm layer 4e, or the third diaphragm layer 4f are integrated with each other, and the first diaphragm layer 4d and the second diaphragm layer 4e. Or, it had a high peel strength to the extent that it was difficult to peel the third diaphragm layer 4f.
- the liquid inlet 51 is disposed below the tank 30 and above the papermaking section 40 (specifically, the upper end 44a of the inclined surface section 44).
- a liquid injection port 51 ⁇ / b> A configured to be disposed on the inner peripheral surface of the tank body 31 in the circumferential direction and open downward may be used.
- the conduit 52 may extend to the central portion of the tank body 31, and the front end opening of the conduit 52 may be a liquid inlet 51 ⁇ / b> B so that the conduit 52 is oriented horizontally, vertically, upward, or the like. Good.
- the opening direction of the liquid inlet 51 is not limited to the horizontal direction, the downward direction, and the upward direction as long as the liquid can be injected in the liquid in the tank 30. is there.
- the first suspension K1 corresponds to an example of the first liquid
- the second suspension K2 corresponds to an example of the second liquid
- the first liquid and the second liquid indicate that the first liquid is injected first and the second liquid is injected after the first liquid, that is, “first” and “second”. Is merely a relative ordering relationship and not an absolute ordering relationship. That is, it does not mean that the first liquid is injected first among all the liquids and the second liquid is injected second among all the liquids.
- the former corresponds to an example of the first liquid and the latter corresponds to an example of the second liquid.
- the former corresponds to an example of the first liquid and the latter corresponds to an example of the second liquid.
- Example 1 The speaker diaphragm of Example 1 is manufactured using the speaker diaphragm manufacturing method described above, and has the same beating degree as the first diaphragm layer made of NBKP of wood pulp fiber having a beating degree of 20 ° SR. And a second diaphragm layer made of NBKP made of 20 ° SR wood pulp fiber. The density of the first diaphragm layer is higher than the density of the second diaphragm layer. The first diaphragm layer and the second diaphragm layer are integrated at the boundary portion.
- Example 2 The speaker diaphragm of Example 2 is manufactured using the above-described speaker diaphragm manufacturing method, and includes a first diaphragm layer made of NBKP of wood pulp fiber having a beating degree of 20 ° SR, and a beating degree of 20 A second diaphragm layer made of NBKP of wood pulp fibers at SR, and a fabric disposed between the first diaphragm layer and the second diaphragm layer. This fabric is made of polypropylene fibers. The first diaphragm layer and the woven fabric, and the second diaphragm layer and the woven fabric are integrated at a boundary portion thereof.
- Comparative Example 1 The speaker diaphragm of Comparative Example 1 is configured to have a single diaphragm layer composed of NBKP of wood pulp fibers having a beating degree of 20 ° SR.
- Table 1 shows the measurement results of the physical properties of the speaker diaphragms of Examples 1 and 2 and Comparative Example 1.
- the Young's modulus of the speaker diaphragm of Examples 1 and 2 is larger than the Young's modulus of the speaker diaphragm of Comparative Example 1. Further, the propagation speed of the speaker diaphragm of Examples 1 and 2 is larger than the propagation speed of the speaker diaphragm of Comparative Example 1. Further, the internal loss of the speaker diaphragm of Examples 1 and 2 is slightly smaller than or equivalent to the internal loss of the speaker diaphragm of Comparative Example 1.
- the Young's modulus and internal loss of a speaker diaphragm are inversely proportional, and when one of Young's modulus and internal loss is large, the other is small.
- the first diaphragm and the second diaphragm are integrated directly or through a fabric, so that the material of the first diaphragm and the second diaphragm are integrated. It is thought that internal loss is improved by friction of the material. In addition, it is considered that the internal loss is improved because there is an entangled portion at the boundary between the first diaphragm and the second diaphragm, so that friction is more easily generated.
- the density of the speaker diaphragm of Examples 1 and 2 is higher than the density of the speaker diaphragm of Comparative Example 1, it is considered that the Young's modulus of the speaker diaphragm is improved.
- the reason why the density of the speaker diaphragms in Examples 1 and 2 is large is considered that the dehydration time is relatively long, and therefore the material is attracted to the net and the voids in the diaphragm layer are relatively small.
- the density of the first diaphragm layer is large, the material of the second diaphragm layer is difficult to enter the first diaphragm layer, so that the first diaphragm layer has a predetermined thickness or a uniform thickness. It is thought that the 2nd diaphragm layer which has various thickness can be formed.
- the first diaphragm layer and the second diaphragm layer are integrated, and it is difficult to peel off the first diaphragm and the second diaphragm. And had high peel strength.
- the boundary between the first diaphragm layer and the second diaphragm has an entangled portion.
- the fibers of the first diaphragm layer and the fibers of the second diaphragm layer are entangled.
- the fibers in the entangled portion are made in the order of the first diaphragm layer and the second diaphragm layer, the fibers penetrate from the first diaphragm layer toward the second diaphragm layer, and the second diaphragm layer
- the paper is made in the order of the first diaphragm layer, it may penetrate from the second diaphragm layer toward the first diaphragm layer.
- the fibers in the layers other than the entangled portion are deposited along the front surface, the back surface, or the boundary of the speaker diaphragm. Therefore, the direction in which the fibers are deposited in the entangled portion may be different from the direction in which the fibers are deposited in other than the entangled portion. Further, the entangled portion may be formed over the entire boundary between the first diaphragm layer and the second diaphragm, or may be formed only at a predetermined position on the boundary.
- Differences between the speaker diaphragms of the first and second embodiments and the comparative example include that there is a boundary portion, that there is an entangled portion, that the fiber deposition direction in the entangled portion is different,
- the density of the first diaphragm layer is greater than the density of the second diaphragm layer, or the second diaphragm layer and the first diaphragm layer
- the density of the second diaphragm layer may be larger than the density of the first diaphragm layer.
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Abstract
Description
以下、スピーカ用振動板について、図1を参照して説明する。
以下、本発明の一実施例に係るスピーカ用振動板の製造に用いられる製造装置及び製造方法の一例について、図2~図7を参照して説明する。
振動板層形成工程では、各振動板層を形成する材料を含む第1縣濁液K1及び第2縣濁液K2をタンク30内に順次注入し、タンク30内の液の脱水を行う。第1縣濁液K1は、第1液体の一例に相当し、第2縣濁液K2は、第2液体の一例に相当する。
まず、図2に示すように、第1振動板層4aの材料4a1を含ませた第1懸濁液K1をタンク30内に注入する。この際、制御装置70により液体注入装置62を制御して、水に材料4a1を含ませて予め作成した第1縣濁液K1を液体注入口51から注入する。または、タンク30の上端開口から、水などの液をタンク30内に注入しながら、タンク30内に材料4a1を注入(投入)してもよい。最初にタンク30内に注入する第1縣濁液K1の注入方法は任意である。タンク30内では、水に材料4a1が分散した第1縣濁液層R51が形成される。規定形状の網43では液(即ち、水)が通過して脱水され、網43上に材料4a1が堆積する。この際、制御装置70により脱水装置61を制御して強制的に液を吸引して脱水してもよく、または、強制吸引せずに自然落下により脱水してもよい。第1振動板層形成工程において、タンク30内の液体の水位が液体注入口51より低い位置にならないように、第1縣濁液K1の注入速度や液の脱水速度等を適宜調整する。
第1振動板層4aの材料4a1をタンク30内に注入した後、図3に示すように、制御装置70により液体注入装置62を制御して、予め規定した量の液W(水)を液体注入口51から注入する。この際、タンク30内の液体の水位が、液体注入口51より高い位置にある状態において、タンク30内の液体中で液Wを注入する。また、タンク30内の液体の液面に乱れ(波打ち)が生じない程度の速度で液Wを注入することが好ましい。タンク30内では、振動板層の材料を含まない液体層R52が形成される。この液体層R52の厚さ(タンク30の上下方向に沿った長さ)は、各振動板層の材料の比重、液体中での材料の落下速度、等の各種条件に応じて決定することが好ましい。この際、制御装置70により脱水装置61を制御して強制的に液を吸引して脱水してもよく、または、強制吸引せずに自然落下により液を脱水してもよい。液体層注入工程においても、タンク30内の水位が液体注入口51より低い位置にならないように、液Wの注入速度や液の脱水速度等を適宜調整する。
液Wをタンク30内に注入した後、図4に示すように、水に材料4b1を含ませて予め作成した第2懸濁液K2を液体注入口51からタンク30内に注入する。この際、タンク30内の水位が、液体注入口51より高い位置にある状態において、タンク30内の液体中で第2縣濁液K2を注入する。また、タンク30内の液体の液面に乱れ(波打ち)が生じない程度の速度で第2縣濁液K2を注入することが好ましい。タンク30内では、水に材料4b1が分散した第2縣濁液層R53が形成される。網43では液(即ち、水)が通過して脱水され、網43上に堆積した第1振動板層4aの材料4a1の上に重なるように、第2振動板層4bの材料4b1が堆積する。この際、脱水装置61により強制的に液を吸引して脱水してもよく、または、強制吸引せずに自然落下により液を脱水してもよい。
上述した振動板層形成工程において、網43上に形成された、第1振動板層4aの材料4a1及び第2振動板層の材料4b1が積層された多層の抄造体(即ち、スピーカ用振動板4の前駆体)を、ホットプレス法、ウェットプレス法、オーブン法、等の成形法により成形して、図1(b)、(c)に示すようなスピーカ用振動板4を作製する。具体的には、網43上から上記多層の抄造体を取り出して、例えば図6に示すように、加熱部811を備えた雌金型81と、加熱部821を備えた雄金型82とを有する金型80にて、加熱及び加圧して、所定形状のスピーカ用振動板4を作製する。
スピーカ用振動板について、以下に示す実施例1、2及び比較例1のスピーカ用振動板を作成して、それぞれについて物性値を測定し比較を行った。
実施例1のスピーカ用振動板は、上述したスピーカ用振動板の製造方法を用いて製造され、叩解度20°SRの木材パルプ繊維のNBKPで構成される第1振動板層と、同じ叩解度20°SRの木材パルプ繊維のNBKPで構成される第2振動板層と、を有して構成されている。第1振動板層の密度は、第2振動板層の密度より高くなっている。これら第1振動板層及び第2振動板層は、その境界部分において一体化している。
実施例2のスピーカ用振動板は、上述したスピーカ用振動板の製造方法を用いて製造され、叩解度20°SRの木材パルプ繊維のNBKPで構成される第1振動板層と、叩解度20°SRの木材パルプ繊維のNBKPで構成される第2振動板層と、第1振動板層及び第2振動板層の間に配置された織物と、を有して構成されている。この織物はポリプロピレン系の繊維で構成されている。これら、第1振動板層及び織物、並びに、第2振動板層及び織物は、それらの境界部分において一体化している。
比較例1のスピーカ用振動板は、叩解度20°SRの木材パルプ繊維のNBKPで構成される単一の振動板層を有して構成されている。
4a1、4b1 材料(材料の一例)
4a、4d 第1振動板層(抄造体の一例)
4b、4e 第2振動板層(抄造体の一例)
4f 第3振動板層(抄造体の一例)
4x 第1交絡部分
4y 第2交絡部分
4z 交絡部分
10 スピーカ装置
20 スピーカ用振動板の製造装置
30 タンク
31 タンク本体
32 センサ
40 抄造部
41 取り付け部
41B 接続口(脱水口の一例)
42 金型
43 網
44 傾斜面部
50 液体注入部
51、51A、51B 液体注入口
52 導管
61 脱水装置
62 液体注入装置
70 制御装置
K1 第1縣濁液
K2 第2縣濁液
Claims (9)
- 積層された複数の抄造体を備え、
互いに隣接する2つの抄造体が一体化していることを特徴とするスピーカ用振動板。 - 前記互いに隣接する2つの抄造体の境界部分が一体化していることを特徴とする請求項1に記載のスピーカ用振動板。
- 前記抄造体は材料で構成され、
前記2つの抄造体の境界部分には、当該2つの抄造体の材料が交絡した交絡部分が形成されていることを特徴とする請求項2に記載のスピーカ用振動板。 - 前記交絡部分の厚みが、前記2つの抄造体のうち一方の抄造体の厚さに対して小さいことを特徴とする請求項3に記載のスピーカ用振動板。
- 前記2つの抄造体の間で剥離強力を有することを特徴とする請求項2に記載のスピーカ用振動板。
- 前記2つの抄造体のうち、一方の抄造体の密度は他方の抄造体の密度に対して大きいことを特徴とする請求項5に記載のスピーカ用振動板。
- 前記一方の抄造体のヤング率は、前記他方の抄造体のヤング率に対して大きいことを特徴とする請求項6に記載のスピーカ用振動板。
- 前記2つの抄造体の一方の抄造体が前記複数の抄造体のうちの表層であり、
前記一方の抄造体が、全体にわたって均一な厚みを有することを特徴とする請求項6に記載のスピーカ用振動板。 - 前記2つの抄造体の前記一方の抄造体に隣接する他方の抄造体が、全体にわたって均一な厚みを有することを特徴とする請求項8に記載のスピーカ用振動板。
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PCT/JP2013/055409 WO2014132393A1 (ja) | 2013-02-28 | 2013-02-28 | スピーカ用振動板 |
JP2015502656A JPWO2014132393A1 (ja) | 2013-02-28 | 2013-02-28 | スピーカ用振動板 |
US14/771,104 US20160014520A1 (en) | 2013-02-28 | 2013-02-28 | Speaker diaphragm |
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CN106149478A (zh) * | 2015-04-02 | 2016-11-23 | 赖宗伸 | 模塑产品之制造方法及成品 |
WO2018008347A1 (ja) * | 2016-07-04 | 2018-01-11 | パナソニックIpマネジメント株式会社 | ラウドスピーカ用振動部品と、それを含むラウドスピーカ、およびそのラウドスピーカを搭載した移動体装置 |
JP2021080619A (ja) * | 2019-11-18 | 2021-05-27 | 王子ホールディングス株式会社 | パルプモールド成形体 |
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JP2019054309A (ja) * | 2016-01-28 | 2019-04-04 | パナソニックIpマネジメント株式会社 | スピーカ用振動板、スピーカ、および、スピーカ用振動板の製造方法 |
JP6257815B1 (ja) * | 2017-01-31 | 2018-01-10 | アルパイン株式会社 | 音響装置 |
CN112383865B (zh) * | 2020-12-11 | 2022-06-14 | 苏州索迩电子技术有限公司 | 一种骨传导发声装置的使用方法 |
CN112367596A (zh) * | 2020-12-11 | 2021-02-12 | 苏州索迩电子技术有限公司 | 一种骨传导发声装置 |
CN115119087B (zh) * | 2022-04-29 | 2024-04-05 | 苏州索迩电子技术有限公司 | 一种骨传导发声单元及可穿戴设备 |
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- 2013-02-28 JP JP2015502656A patent/JPWO2014132393A1/ja active Pending
- 2013-02-28 US US14/771,104 patent/US20160014520A1/en not_active Abandoned
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WO2018008347A1 (ja) * | 2016-07-04 | 2018-01-11 | パナソニックIpマネジメント株式会社 | ラウドスピーカ用振動部品と、それを含むラウドスピーカ、およびそのラウドスピーカを搭載した移動体装置 |
JP2021080619A (ja) * | 2019-11-18 | 2021-05-27 | 王子ホールディングス株式会社 | パルプモールド成形体 |
JP7435276B2 (ja) | 2019-11-18 | 2024-02-21 | 王子ホールディングス株式会社 | パルプモールド成形体 |
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