WO2013168543A1 - 冷感に優れた異型断面繊維 - Google Patents

冷感に優れた異型断面繊維 Download PDF

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Publication number
WO2013168543A1
WO2013168543A1 PCT/JP2013/061641 JP2013061641W WO2013168543A1 WO 2013168543 A1 WO2013168543 A1 WO 2013168543A1 JP 2013061641 W JP2013061641 W JP 2013061641W WO 2013168543 A1 WO2013168543 A1 WO 2013168543A1
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Prior art keywords
section
cross
fiber
axis
flat
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PCT/JP2013/061641
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English (en)
French (fr)
Japanese (ja)
Inventor
森島　一博
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帝人株式会社
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Application filed by 帝人株式会社 filed Critical 帝人株式会社
Priority to CN201380023228.6A priority Critical patent/CN104271819A/zh
Publication of WO2013168543A1 publication Critical patent/WO2013168543A1/ja

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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins

Definitions

  • the present invention relates to a modified cross-section fiber excellent in cooling feeling. More specifically, the present invention relates to an atypical cross-section fiber excellent in cooling feeling that can be suitably used for apparel use, which is excellent in comfort and texture when worn in summer.
  • Patent Document 1 those using a hygroscopic polymer as a polymer constituting the fiber (Patent Document 1), those using a thermoplastic elastomer (Patent Document 2), and inorganic particles having excellent thermal conductivity are kneaded. Something has been proposed.
  • hygroscopic polymers cause stickiness during sweating and cause discomfort
  • elastomers have inferior processing characteristics such as low dyeing fastness in addition to their own tackiness.
  • Patent Document 5 a mixed yarn having water absorption and hygroscopicity using a fiber having a flat cross section as a sheath yarn has been proposed (Patent Document 5).
  • the mixed yarn is intended to reduce the feeling of stickiness by reducing the chance that the core that retains the moisture transferred through the gap between the fibers of the flat cross section reduces contact with the skin. This method is not different from the method using the hygroscopic polymer in that processing is employed.
  • the object of the present invention is made in the background of the above-mentioned conventional technology, and the object is to provide an atypical cross-section fiber that exhibits excellent cold contact feeling and texture when made into a fabric and is excellent in workability. .
  • the present inventors have found that the above object can be achieved by specifying a polymer that forms a fiber in a modified cross-section fiber, and have reached the present invention.
  • a fiber having polyethylene as a main component the cross-section perpendicular to the fiber axis of the fiber is a flat shape, and the width A of the long axis of the flat cross-section and a short width perpendicular thereto.
  • An atypical cross-section fiber excellent in cooling sensation characterized in that the ratio A / B1 of the maximum shaft width B1 is 2 to 10.
  • an atypical cross-section fiber excellent in processability which can express an excellent cooling feeling and texture when used as a fabric.
  • A represents the width of the long axis in the fiber cross section
  • B1 represents the maximum width of the short axis perpendicular to it.
  • A represents the width of the long axis in the fiber cross section
  • B1 represents the maximum width of the short axis perpendicular to it
  • B2 represents the minimum width of the short axis corresponding to the constricted portion.
  • the atypical cross-section fiber of the present invention needs to have polyethylene as a main constituent.
  • the polyethylene is large and is classified into high-density polyethylene, linear low-density polyethylene, and low-density polyethylene, and among these, high-density polyethylene is preferable because it has good yarn production and high thermal conductivity.
  • the polyethylene is preferably composed of a single component, but a C3 to C12 higher alkene may be contained as a copolymer in a proportion of less than 5% by weight.
  • the polymer used for the fiber of the present invention may contain conventionally known antioxidants, light-proofing agents, flame retardants, pigments and the like as long as the object of the present invention is not impaired.
  • the atypical cross-section fiber of the present invention has a flat cross-sectional shape so that the contact area with the skin can be effectively increased and a cool feeling of contact can be sufficiently felt when the cloth for clothing is used. It is necessary.
  • the ratio A / B1 between the width A of the major axis of the flat shape and the maximum width B1 of the minor axis perpendicular to the major axis needs to be 2 to 10. If the ratio A / B1 of the width A of the major axis and the maximum width B1 of the minor axis perpendicular to it is less than 2, it becomes close to a round cross section and the effect of the flat shape is reduced, while if it exceeds 10, the effect of the flatness is reduced. In addition to the above, the process stability during yarn production may be reduced. A particularly preferred range is 3-8.
  • the cross-sectional shape of the modified cross-section fiber of the present invention is a shape in which round cross-section single yarns are linearly connected in the major axis direction of the cross section, and a shape having 2 to 5 constricted portions is more preferable.
  • the circular cross-section single yarns are linearly connected and the overall flat cross-sectional shape reduces the space between the single yarns compared to the case where the single round cross-section yarns exist alone, effectively expressing the cooling effect.
  • the bending properties of the fibers are improved, and the fabric is rich in flexibility.
  • the cross-sectional shape of the fiber is not a mere flat shape, but has a constricted portion, for example, without excessively relying on the reflection of inorganic compound particles, thereby improving the irregular reflection on the fiber surface and the light refraction effect, thereby preventing permeation. It is possible to impart a certain degree of property. If the number of constricted portions is less than 2, the above effect is difficult to obtain, and conversely if the number of constricted portions exceeds 5, it is not preferable in terms of process stability.
  • the ratio A / B1 between the long axis width A of the flat cross section and the maximum width B1 of the short axis perpendicular thereto is 2-6.
  • the flatness ratio is less than 2, the effect of the flat cross section is difficult to obtain, and in the case of a fabric such as a woven or knitted fabric, the long axis is difficult to be arranged parallel to the fabric surface, and the heat shielding property may be lowered.
  • the flatness ratio exceeds 6, the spinning stability is lowered, so a more preferable range is 3-5.
  • the ratio B1 / B2 between the shortest maximum width B1 of the flat cross section and the shortest axis minimum width B2 corresponding to the constricted portion is 1.05 or more and 1 .6 or less is preferable.
  • B1 / B2 is less than 1.05, the effect of connecting the above-described round cross sections may be reduced, and when B1 / B2 exceeds 1.6, the thickness of the connecting portion (constriction portion) becomes thin, The cooling effect may be reduced.
  • a preferred range is 1.1 to 1.4.
  • the single yarn fineness of the modified cross-section fiber of the present invention is preferably 1 to 10 dtex.
  • the single yarn fineness is less than 0.1 dtex, the spinning stability is lowered, and the fine voids between the fibers are increased, the heat insulation between the fibers is increased, and the cooling effect may be reduced.
  • the single yarn fineness exceeds 10 dtex, when the knitted fabric is used, the inter-fiber distance is increased, the contact area is decreased, the contact cooling effect is lowered, and the texture may be hardened.
  • the single yarn fineness is more preferably 0.5 to 8 dtex.
  • the strength of the modified cross-section fiber of the present invention is preferably 1.5 cN / dt or more. If the strength is less than 1.5 cN / dt, the durability is poor.
  • a known method may be used, but the melt spinning method is preferable in terms of cost.
  • the stretching method known hot roll stretching or warm water stretching can be used.
  • a known antistatic agent, fiber finishing agent, or the like can be used as necessary in the process of spinning and stretching the fiber.
  • the modified cross-section fiber of the present invention when used as a fabric, it may be used for all fabrics or partially.
  • the structure is not particularly limited, and may be a woven fabric, a knitted fabric, or a non-woven fabric.
  • Reference examples 1-2 In Examples 1 and 2, similar fibers were obtained using polyethylene terephthalate (inherent viscosity 0.63). Tube knitting was made in the same manner as in Examples 1 and 2 and used as a criterion for evaluation of cooling feeling.
  • the temperature difference in the evaluation of cooling sensation is the temperature difference from the maximum drop temperature of Reference Example 1 for Examples 1 and 3 and Comparative Example 1, and the maximum drop of Reference Example 2 for Examples 2 and 4 to 5. Indicates the temperature difference from the temperature.
  • Example 1 High-density polyethylene (melt flow rate according to JIS K-7210; 19) is melted with an extruder set at 230 ° C., and discharged at a temperature of 240 ° C. from a die having 12 discharge holes having the cross-sectional shape shown in FIG. And wound at a spinning speed of 1500 m / min.
  • the wound undrawn yarn was drawn under the conditions of a preheating temperature of 90 ° C., a heat setting temperature of 120 ° C., and a draw ratio of 4.0 times to obtain a polyethylene flat cross-section fiber of 84 dtex / 12 filaments.
  • Example 2 84 dtex / 36 filaments of a polyethylene flat cross-section fiber was obtained in the same manner as in Example 1 except that a nozzle having 36 discharge holes and having a cross-sectional shape shown in FIG. 2 was used. Table 1 shows the physical properties of the obtained fibers and the evaluation results of the tubular knitting made using the fibers.
  • Example 1 In Example 1, it implemented like Example 1 except having changed the cross-sectional shape of the fiber. Table 1 shows the physical properties and evaluation results of the obtained fibers.
  • Example 2 it implemented like Example 2 except having changed the cross-sectional shape of the fiber.
  • Table 1 shows the physical properties and evaluation results of the obtained fibers.
  • Examples 1 and 2 which are within the scope of the present invention, have good spinning properties and physical properties and excellent cooling feeling when used as a fabric.
  • a plain woven fabric was woven without twisting at a weaving density of 110 / 2.54 cm to create a shirt and evaluated for wearing, it was excellent in a refreshing feeling.
  • the comparative example 1 whose ridge cross-sectional shape is a round cross-section became inferior in cool feeling. Further, in Comparative Example 2 where the flatness ratio was larger than the range of the present invention, although a cooling sensation was obtained, the spinning performance was poor and the process stability was poor.
  • Example 3 with a high number of constrictions and high flatness results in slightly inferior process stability and physical properties at the time of spinning, and in Example 4 in which the thickness of the constricted portion is thinned, the cooling sensation is slightly reduced. It became.
  • the atypical cross-section fiber of the present invention has an excellent cooling feeling and a good texture, has a refreshing feeling when used as a fabric, and can be used for many applications such as sports and outer clothing and industrial materials.
  • the industrial value is extremely large.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
PCT/JP2013/061641 2012-05-07 2013-04-19 冷感に優れた異型断面繊維 WO2013168543A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201380023228.6A CN104271819A (zh) 2012-05-07 2013-04-19 凉感优异的异型截面纤维

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012106017 2012-05-07
JP2012-106017 2012-05-07

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WO2013168543A1 true WO2013168543A1 (ja) 2013-11-14

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CN (1) CN104271819A (zh)
TW (1) TW201402891A (zh)
WO (1) WO2013168543A1 (zh)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013234407A (ja) * 2012-05-09 2013-11-21 Teijin Ltd 冷感に優れた複合繊維
JP2015175075A (ja) * 2014-03-14 2015-10-05 株式会社クラレ 耐光性に優れた溶融異方性芳香族ポリエステル繊維
WO2019017432A1 (ja) * 2017-07-20 2019-01-24 東洋紡株式会社 マルチフィラメントおよびそれを構成するモノフィラメント
KR20200036171A (ko) * 2018-09-28 2020-04-07 코오롱인더스트리 주식회사 폴리에틸렌 원사, 그 제조방법, 및 이를 포함하는 냉감성 원단
WO2021132768A1 (ko) * 2019-12-27 2021-07-01 코오롱인더스트리 주식회사 폴리에틸렌 원사, 그 제조방법, 및 이를 포함하는 냉감성 원단
WO2023106799A1 (ko) * 2021-12-08 2023-06-15 코오롱인더스트리 주식회사 치수안정성이 향상된 폴리에틸렌 원사 및 이를 포함하는 기능성 원단
WO2023106796A1 (ko) * 2021-12-08 2023-06-15 코오롱인더스트리 주식회사 원착 폴리에틸렌 원사 및 이를 포함하는 기능성 원단
WO2023121164A1 (ko) * 2021-12-20 2023-06-29 코오롱인더스트리 주식회사 이형단면 폴리에틸렌 원사 및 이를 포함하는 기능성 원단

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111235735A (zh) * 2020-03-11 2020-06-05 赖裕文 一种瞬间凉感面料

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JP2004107809A (ja) * 2002-09-17 2004-04-08 Toray Ind Inc ポリアミドマルチフィラメントおよびストッキングおよびインナーウエアー
JP2006070397A (ja) * 2004-09-03 2006-03-16 Teijin Fibers Ltd 扁平断面繊維およびそれからなる織物、スポーツ衣料
JP2007146334A (ja) * 2005-11-29 2007-06-14 Nippon Ester Co Ltd ポリエステル繊維
JP2010236130A (ja) * 2009-03-31 2010-10-21 Toyobo Co Ltd 快適性布帛
JP3175126U (ja) * 2012-02-10 2012-04-19 株式会社成願 冷感タオル地
JP2012112056A (ja) * 2010-11-22 2012-06-14 Teijin Fibers Ltd 遮熱性ポリエステル繊維

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JPS6052613A (ja) * 1983-08-30 1985-03-25 Toyobo Co Ltd 高強力、高弾性率ポリエチレン繊維
JPH0214011A (ja) * 1988-06-27 1990-01-18 Mitsubishi Rayon Co Ltd 多孔質ポリエチレン繊維
JP3843297B2 (ja) * 2000-04-03 2006-11-08 東洲貿易株式会社 速乾性編地及び速乾性編物製品
CN100368611C (zh) * 2006-01-27 2008-02-13 范伟杰 珍珠复合纤维及其制造方法
JP5462619B2 (ja) * 2009-12-25 2014-04-02 三菱レイヨン・テキスタイル株式会社 織編物及びそれを用いた衣類

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004107809A (ja) * 2002-09-17 2004-04-08 Toray Ind Inc ポリアミドマルチフィラメントおよびストッキングおよびインナーウエアー
JP2006070397A (ja) * 2004-09-03 2006-03-16 Teijin Fibers Ltd 扁平断面繊維およびそれからなる織物、スポーツ衣料
JP2007146334A (ja) * 2005-11-29 2007-06-14 Nippon Ester Co Ltd ポリエステル繊維
JP2010236130A (ja) * 2009-03-31 2010-10-21 Toyobo Co Ltd 快適性布帛
JP2012112056A (ja) * 2010-11-22 2012-06-14 Teijin Fibers Ltd 遮熱性ポリエステル繊維
JP3175126U (ja) * 2012-02-10 2012-04-19 株式会社成願 冷感タオル地

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013234407A (ja) * 2012-05-09 2013-11-21 Teijin Ltd 冷感に優れた複合繊維
JP2015175075A (ja) * 2014-03-14 2015-10-05 株式会社クラレ 耐光性に優れた溶融異方性芳香族ポリエステル繊維
WO2019017432A1 (ja) * 2017-07-20 2019-01-24 東洋紡株式会社 マルチフィラメントおよびそれを構成するモノフィラメント
JPWO2019017432A1 (ja) * 2017-07-20 2020-05-28 東洋紡株式会社 マルチフィラメントおよびそれを構成するモノフィラメント
TWI752250B (zh) * 2017-07-20 2022-01-11 日商東洋紡股份有限公司 複絲以及構成複絲之單絲
JP7176517B2 (ja) 2017-07-20 2022-11-22 東洋紡株式会社 マルチフィラメントおよびそれを構成するモノフィラメント
KR20200036171A (ko) * 2018-09-28 2020-04-07 코오롱인더스트리 주식회사 폴리에틸렌 원사, 그 제조방법, 및 이를 포함하는 냉감성 원단
KR102167737B1 (ko) 2018-09-28 2020-10-19 코오롱인더스트리 주식회사 폴리에틸렌 원사, 그 제조방법, 및 이를 포함하는 냉감성 원단
WO2021132768A1 (ko) * 2019-12-27 2021-07-01 코오롱인더스트리 주식회사 폴리에틸렌 원사, 그 제조방법, 및 이를 포함하는 냉감성 원단
WO2023106799A1 (ko) * 2021-12-08 2023-06-15 코오롱인더스트리 주식회사 치수안정성이 향상된 폴리에틸렌 원사 및 이를 포함하는 기능성 원단
WO2023106796A1 (ko) * 2021-12-08 2023-06-15 코오롱인더스트리 주식회사 원착 폴리에틸렌 원사 및 이를 포함하는 기능성 원단
WO2023121164A1 (ko) * 2021-12-20 2023-06-29 코오롱인더스트리 주식회사 이형단면 폴리에틸렌 원사 및 이를 포함하는 기능성 원단

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JPWO2013168543A1 (ja) 2016-01-07
CN104271819A (zh) 2015-01-07
TW201402891A (zh) 2014-01-16

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