WO2013099010A1 - タンク及びその製造方法 - Google Patents
タンク及びその製造方法 Download PDFInfo
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- WO2013099010A1 WO2013099010A1 PCT/JP2011/080467 JP2011080467W WO2013099010A1 WO 2013099010 A1 WO2013099010 A1 WO 2013099010A1 JP 2011080467 W JP2011080467 W JP 2011080467W WO 2013099010 A1 WO2013099010 A1 WO 2013099010A1
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- fiber
- layer
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- winding
- fibers
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D22/00—Producing hollow articles
- B29D22/003—Containers for packaging, storing or transporting, e.g. bottles, jars, cans, barrels, tanks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/56—Winding and joining, e.g. winding spirally
- B29C53/58—Winding and joining, e.g. winding spirally helically
- B29C53/60—Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels
- B29C53/602—Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels for tubular articles having closed or nearly closed ends, e.g. vessels, tanks, containers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/56—Winding and joining, e.g. winding spirally
- B29C53/58—Winding and joining, e.g. winding spirally helically
- B29C53/60—Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels
- B29C53/62—Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels rotatable about the winding axis
- B29C53/66—Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels rotatable about the winding axis with axially movable winding feed member, e.g. lathe type winding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/32—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core on a rotating mould, former or core
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
- F17C1/02—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge involving reinforcing arrangements
- F17C1/04—Protecting sheathings
- F17C1/06—Protecting sheathings built-up from wound-on bands or filamentary material, e.g. wires
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/56—Winding and joining, e.g. winding spirally
- B29C53/58—Winding and joining, e.g. winding spirally helically
- B29C53/581—Winding and joining, e.g. winding spirally helically using sheets or strips consisting principally of plastics material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
- B29L2031/7172—Fuel tanks, jerry cans
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0602—Wall structures; Special features thereof
- F17C2203/0604—Liners
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0602—Wall structures; Special features thereof
- F17C2203/0612—Wall structures
- F17C2203/0614—Single wall
- F17C2203/0619—Single wall with two layers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0634—Materials for walls or layers thereof
- F17C2203/0658—Synthetics
- F17C2203/0663—Synthetics in form of fibers or filaments
- F17C2203/067—Synthetics in form of fibers or filaments helically wound
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2209/00—Vessel construction, in particular methods of manufacturing
- F17C2209/21—Shaping processes
- F17C2209/2154—Winding
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/012—Hydrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0107—Single phase
- F17C2223/0123—Single phase gaseous, e.g. CNG, GNC
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/036—Very high pressure (>80 bar)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0165—Applications for fluid transport or storage on the road
- F17C2270/0168—Applications for fluid transport or storage on the road by vehicles
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0165—Applications for fluid transport or storage on the road
- F17C2270/0184—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Definitions
- the present invention relates to a tank having a reinforcing fiber layer and a manufacturing method thereof.
- a high-pressure hydrogen tank is used as a fuel gas supply source.
- This high-pressure hydrogen tank is generally manufactured using a filament winding method. Specifically, a fiber impregnated with a thermosetting resin is wound around the outer peripheral surface of a liner (inner container) by a filament winding method, and then the resin of the wound fiber is thermally cured. Thereby, the reinforcing fiber layer is formed on the outer peripheral surface of the liner, and the strength of the high-pressure hydrogen tank is secured.
- the filament winding method generally uses a fiber impregnated with a low-viscosity resin
- the end of the fiber which is the end of the fiber that is the end of winding
- the viscosity of the resin is further reduced by heat, so that the fiber ends are easily loosened. For this reason, at the end of winding, after an operator cuts the fiber, the end of the fiber is firmly tied to the winding surface and fixed.
- a method described in Patent Document 1 below is also known as a fiber terminal treatment method different from such a binding and fixing method.
- a double-sided tape is attached to the inner surface of the fiber end of the prepreg, and the fiber end is attached to the winding surface at the end of winding.
- the tank manufacturing method described in Patent Document 2 below includes a winding step of winding a predetermined amount of fiber impregnated with resin, and curing for forming a reinforcing fiber layer by thermosetting the resin impregnated in the wound fiber. And a process. In this winding step, the end of the fiber is put inside the already wound fiber using a jig.
- the fiber end is formed by crossing the fibers forming the outermost wound layer so that the fiber end is sandwiched between the outermost layer of the already wound fiber and the inner layer of the outermost layer.
- the fiber end is pressed down by a plurality of already wound fibers.
- Patent Document 1 or Patent Document 2 has a problem to be solved, in addition to the fact that the work by a human hand is indispensable and the surface is uneven.
- the present invention has been made in view of such problems, and the object thereof is to improve the smoothness of the tank surface after completion, and to improve workability during production for mass production. It is an object of the present invention to provide a method for manufacturing a tank capable of performing the above and a tank with a higher level of smoothness of the surface thereof.
- a method for manufacturing a tank according to the present invention is a method for manufacturing a tank having a reinforcing fiber layer, in which a fiber-impregnated fiber is wound for a predetermined amount, and the wound fiber is impregnated. And a curing step of forming a reinforcing fiber layer by thermally curing the resin. In the winding step, the end of the fiber that is the end of winding is pushed into the already wound inner fiber layer, so that at least part of the fixed region that is part of the end is between the fibers that form the outermost layer. The ends are fixed to the inner fiber layer.
- the fiber end is inserted so as to cross the already wound fiber, and the fiber end is pressed down by a plurality of already wound fibers. I thought that it might be the cause of the unevenness of the tank surface later. If the fiber end is inserted across the fibers forming the outermost wound layer so that the fiber end is sandwiched between the outermost layer of the already wound fiber and the layer inside the outermost layer, the fiber ends. The already wound fiber is lifted by the part where the end enters. In other words, the already wound fiber rapidly rises as compared with other portions so as to get over the end of the fiber that has entered.
- the fibers forming the inner fiber layer that has already been wound are in a state in which a plurality of fibers are adjacent to each other. Therefore, by pushing the end portion into the inner fiber layer, a minute gap existing between adjacent fibers is utilized as much as possible to form a space into which a fixed region that is a part of the end portion enters. By forming a space into which the fixed region enters in this way, local swell of the inner fiber layer is reduced. Furthermore, in the present invention, the termination process can be performed only by pushing the end portion, so that the workability is remarkably improved.
- a part of the fixed region is sandwiched between the fibers forming the outermost layer by pushing the end portion, while the remaining portion of the fixed region is located on the back side of the outermost layer. It is also preferable to arrange in the inner fiber layer.
- a part of the fixing region is sandwiched between the fibers forming the outermost layer, a part of the fixing region can be held while relaxing local bulging of the outermost layer. Furthermore, since the remaining part of the fixing region is disposed in the inner fiber layer on the inner side of the outermost layer, the remaining part of the fixing region can be more reliably held. Therefore, it is possible to more reliably hold the entire fixing region in the outermost layer and the inner fiber layer on the back side while avoiding the bulge of the outermost layer.
- the remaining portion of the fixed region is formed closer to the end of the end portion than to a part of the fixed region.
- the fixing region may be bent along the direction intersecting the surface including the outermost layer, and the remaining portion of the fixing region may be disposed on the inner fiber layer on the inner side of the outermost layer. preferable.
- the fixing region is bent in the direction intersecting the surface including the outermost layer and arranged on the inner fiber layer, so that the remaining portion and the inner side of the fixing region against the external force acting in the direction of pulling out the fixing region. It can counter by the frictional force with a fiber layer, and can fix the edge part of a fiber more reliably.
- the end portion in the winding process, is processed using a termination processing jig, and the termination processing jig is inserted into the inner fiber layer so as to be adjacent to each other. It is also preferable to have a first part that widens the interval between them and a second part that pushes the end into the part where the gap is widened.
- the first portion of the termination processing jig since the first portion of the termination processing jig temporarily widens the distance between the fibers, it becomes easier to arrange the fixing region in the widened distance, and between the adjacent fibers. An existing minute space can be used effectively. Furthermore, since the second portion pushes the end portion where the interval between the adjacent fibers of the first portion is widened, a fixed region that is a fraction of the end portion can be easily arranged in the inner fiber layer. .
- a tank according to the present invention is a tank having a reinforcing fiber layer obtained by winding a resin-impregnated fiber and then thermosetting the resin, and the reinforcing fiber layer is the end of winding. And an inner fiber layer wound before the end portion, and at least a part of the fixing region that is a part of the end portion forms the outermost layer of the inner fiber layer. The end part is fixed to the inner fiber layer by being sandwiched between the fibers.
- the fixing region which is a part of the end is sandwiched between fibers forming the outermost layer, and the end is fixed to the inner fiber layer.
- the end portion By treating the end portion in this way, local bulging of the inner fiber layer into which the end portion enters is alleviated.
- the fibers forming the inner fiber layer that has already been wound are in a state in which a plurality of fibers are adjacent to each other. Therefore, a space in which a fixed region that is a part of the end portion enters is formed in the inner fiber layer by utilizing a minute gap existing between adjacent fibers as much as possible. By forming a space into which the fixed region enters in this way, local swell of the inner fiber layer is reduced.
- a part of the fixed region is sandwiched between the fibers forming the outermost layer, while the remaining part of the fixed region is disposed on the inner fiber layer on the inner side of the outermost layer. Is also preferable.
- a part of the fixing region is sandwiched between the fibers forming the outermost layer, a part of the fixing region can be held while relaxing local bulging of the outermost layer. Furthermore, since the remaining part of the fixing region is disposed in the inner fiber layer on the inner side of the outermost layer, the remaining part of the fixing region can be more reliably held. Therefore, it is possible to more reliably hold the entire fixing region in the outermost layer and the inner fiber layer on the back side while avoiding the bulge of the outermost layer.
- the remaining portion of the fixed region is formed closer to the end of the end portion than a part of the fixed region.
- the fixing region is bent along a direction intersecting the surface including the outermost layer, and the remaining portion of the fixing region is disposed on the inner fiber layer on the inner side of the outermost layer.
- the fixing region is bent in the direction intersecting the surface including the outermost layer and arranged on the inner fiber layer, so that the remaining portion and the inner side of the fixing region against the external force acting in the direction of pulling out the fixing region. It can counter by the frictional force with a fiber layer, and can fix the edge part of a fiber more reliably.
- the present invention it is possible to provide a tank manufacturing method capable of further improving the smoothness of the tank surface after completion and improving workability, and a tank having a higher level of surface smoothness. Can do.
- FIG. 1 is a diagram showing a fuel cell vehicle equipped with a high-pressure tank according to the present embodiment.
- the fuel cell vehicle 100 has, for example, three high-pressure tanks 1 mounted on the rear part of the vehicle body.
- Each high-pressure tank 1 constitutes a part of the fuel cell system 101 and supplies fuel gas to the fuel cell 104 through the gas supply line 102.
- the fuel gas stored in the high-pressure tank 1 is a combustible high-pressure gas, for example, a compressed natural gas of 20 MPa, or a hydrogen gas of, for example, 35 MPa or 70 MPa.
- the high-pressure tank 1 can be applied not only to a fuel cell vehicle but also to various moving bodies (for example, ships, airplanes, robots, etc.) and stationary types.
- FIG. 2 is a diagram showing an outline of a manufacturing facility for the high-pressure tank 1, and is a diagram showing a part of the high-pressure tank 1 in cross section.
- the high-pressure tank 1 has a liner 3 formed in a hollow shape so that a storage space 2 is defined therein, and a reinforcing fiber layer 4 that covers the outer surface of the liner 3. Yes.
- Fuel gas is supplied / discharged between the storage space 2 and the gas supply line 102 through an opening (not shown) formed at one end or both ends of the high-pressure tank 1 in the axial direction.
- the liner 3 is a portion corresponding to the inner shell or the inner container of the high-pressure tank 1.
- the liner 3 has gas barrier properties and suppresses permeation of stored gas to the outside.
- the material of the liner 3 is not particularly limited, and examples thereof include polyethylene, polypropylene resin, and other hard resins in addition to metals.
- the reinforcing fiber layer 4 is a portion corresponding to the outer shell or outer container of the high-pressure tank 1 and plays a role of reinforcing the high-pressure tank 1.
- the reinforcing fiber layer 4 is formed by winding a fiber 12 impregnated with a matrix resin 11 (hereinafter simply referred to as “resin 11”) around the outer surface of the liner 3 and then curing the resin.
- Resin 11 is, for example, an epoxy resin, a modified epoxy resin, an unsaturated polyester resin, etc., and here, a thermosetting epoxy resin is used.
- the fibers 12 are, for example, metal fibers, glass fibers, carbon fibers, alumina fibers, aramid fibers, natural organic fibers, and the like. Among these, carbon fibers and aramid fibers are particularly preferable, and here, carbon fibers are used. Therefore, the reinforcing fiber layer 4 of the present embodiment is CFRP in which the epoxy resin 11 is reinforced with the carbon fibers 12.
- the fiber 12 is drawn out from the bobbin 14, and after the tension is adjusted by the tension adjusting unit 15, the fiber 12 is immersed in the resin tank 16 to impregnate the liquid resin 11.
- the fiber 12 impregnated with the resin 11 is wound around the liner 3 with a predetermined tension. This winding is performed by attaching the liner 3 to the shaft 17, rotating the liner 3 around the shaft together with the shaft 17, and supplying the fibers 12 from the supply unit 18 to the rotating liner 3.
- the fiber 12 supplied from the supply unit 18 to the liner 3 may be in a prepreg state.
- terminus of the fiber 12 is provided.
- the winding method examples include a filament winding method and a tape winding method.
- the filament winding method (FW method) is used, and the fiber 12 is hoop-wound and helically wound around the liner 3.
- the fiber 12 is configured as a plurality of fiber bundles.
- hoop winding refers to winding the fiber 12 around the body 3a of the liner 3 in the circumferential direction.
- the hoop winding is performed, for example, by reciprocating the supply unit 18 in the axial direction of the liner 3 while rotating the liner 3 and supplying the fibers 12 from the supply unit 18.
- the hoop layer formed by the hoop winding ensures the circumferential strength of the body portion 3a.
- helical winding means winding the fiber 12 around the body 3a and the dome 3b, 3b of the liner 3 in a spiral shape.
- This helical winding is performed, for example, by reciprocating the supply unit 18 in the axial direction and the radial direction of the liner 3 while supplying the fiber 12 from the supply unit 18 while rotating the liner 3.
- the longitudinal strength of the high-pressure tank 1 is ensured by the helical layer wound helically.
- the reinforcing fiber layer 4 is formed by performing such hoop winding and helical winding a plurality of times, and actually includes a plurality of layers.
- the number of the layers is arbitrary, but is 10 or 30, for example. Further, the order of the hoop winding and the helical winding is arbitrary, and the design can be changed as appropriate.
- “winding the fiber 12” means that the fiber 12 is wound by any one of hoop winding, helical winding, and other winding methods unless otherwise specified.
- a manufacturing method of the high-pressure tank 1, particularly a process of forming the reinforcing fiber layer 4 will be described.
- a winding step in which the fiber 12 impregnated with the resin 11 is wound around the liner 3 by a predetermined amount by the FW method and a curing step in which the resin 11 impregnated in the wound fiber 12 is thermally cured are performed.
- the fiber 12 is wound around the outer peripheral surface of the liner 3 rotated about the axis to a predetermined thickness.
- “winding a predetermined amount” in the winding step includes winding the fiber 12 by an amount necessary to form the entire reinforcing fiber layer 4.
- FIG. 4 is a diagram showing the treatment of the end of the fiber when the winding process is completed, and is an enlarged side view of the high-pressure tank in a state where several turns of the fiber are left.
- FIG. 5 is a view showing the treatment of the fiber end when the winding process is finished, and (A) is an enlarged view of portion A as seen from the direction B of FIG. 4 and shows a state where a jig is set. , (B) shows a state where the end of the fiber is treated using a jig.
- the end treatment jig 20 is used to treat the end of the fiber 12 that is the end of winding, that is, the fixed region 12a when the fiber 12 is wound around the liner 3. As shown in FIG. 5A, the fiber 12 is cut along the cut line CL, leaving the fixed region 12a at the end of winding. The fixed region 12a is treated using the termination processing jig 20.
- An inner fiber layer 42 is formed inside the outer fiber layer 40 including the fixed region 12a.
- the fibers 12 are laminated over several layers.
- a plurality of the inner fiber layers 42 are arranged so that the fibers 12 are along each other.
- the termination processing jig 20 pushes the fixed region 12a of the fiber 12 at the end of winding along the extending direction of the fiber 12b that forms the outermost layer of the fiber 12 that forms the inner fiber layer 42 that has already been wound. . Since a plurality of single fibers are twisted together in the fixed region 12 a, at least a part of the single fibers 121 is pushed into the inner fiber layer 42. As a result, at least a part of the single fibers of the termination region 12a is arranged inside the fiber 12b in a state where the extension direction of the termination region 12a and the extension direction of the fibers 12b forming the outermost layer are aligned. 5B illustrates a state in which the three single fibers 121 are pushed in, all the single fibers constituting the terminal region 12a may be pushed into the inner fiber layer 42. It is preferable.
- the remaining portion 121a on the distal end side of the fixed region 12a enters deeper than the fiber 12b that forms the outermost layer of the inner fiber layer 42, and the fixed region 12a (single fiber 121).
- the portion 12b on the side of the fiber 12 already wound around the remaining portion 121a is sandwiched between the fibers 12b forming the outermost layer of the inner fiber layer 42.
- the fixing region 12a is bent along a direction intersecting with the surface including the outermost layer (layer formed by the fibers 12b) of the inner fiber layer 42, and extends into the inner fiber layer 42.
- the bending mode of the fixed region 12a is not limited to this.
- a bending mode in which the fixing region 12a is bent so as to form an angle of about 90 degrees and enters vertically toward the axis of the tank is also preferable.
- FIGS. 6 (A) to (F) are schematic views showing a state in which the extending direction of the fiber 12 is seen through the paper surface.
- FIG. 6A shows that the fixed region 12a of the fiber 12 is located outside the fiber 12b forming the outermost layer.
- the termination processing jig 20 is inserted from the state shown in FIG.
- the termination processing jig 20 is inserted from the fixed region 12a side to the fiber 12b side.
- the termination processing jig 20 includes a first portion 201 and a second portion 202.
- the first portion 201 is a portion having a pointed tip shape, and is a portion that forms the tip portion of the termination processing jig 20.
- the first portion 201 is inserted between the fibers 12b forming the outermost layer of the inner fiber layer 42, thereby widening the interval between the adjacent fibers 12b.
- the second portion 202 constitutes a portion closer to the base of the termination processing jig 20 than the first portion 201 and has a shape protruding in a key shape.
- the second portion 202 is a portion that pushes the fixed region 12a into a portion where the interval between the first portions 201 is widened.
- the termination processing jig 20 when the termination processing jig 20 is inserted, the second portion 202 of the termination processing jig 20 hooks some of the single fibers constituting the fixed region 12a. Then, the termination processing jig 20 is pushed in the traveling direction. As the termination processing jig 20 is further pushed, a part of the fixed region 12a hooked by the second portion 202 enters between the fibers 12b as shown in FIG. 6D.
- the second portion 202 being configured to be able to hook the fixed region 12a only when moving in the direction in which the first portion 201 of the termination processing jig 20 is inserted. Accordingly, the shape of the second portion 202 is not limited to that shown in FIGS.
- the jig 30 includes a ring 32 and an operation unit 34.
- the ring 32 and the operation unit 34 are integrally formed, and the operation unit 34 is connected to a part of the ring 32 and extends linearly.
- the operation unit 34 is operated by a worker or a working robot on the part opposite to the ring 32. By operating the operation unit 34, the position of the ring 32 relative to the high-pressure tank 1 can be moved together with the operation unit 34.
- the ring 32 is configured to be able to insert the fibers 12 as a fiber bundle, and is configured to be able to engage with the fibers 12 on the inner peripheral surface thereof.
- the ring 32 may be a whole ring-like shape, but here, a notch 36 is formed in a part thereof.
- the jig 30 is set horizontally on the outer surface (winding surface) of the fiber 12 that has already been wound.
- the operation portion 34 of the jig 30 is located above both the outer fiber layer 40 that becomes the surface layer of the reinforcing fiber layer 4 and the inner fiber layer 42 around which the remaining several turns of fibers 12 are wound. Will be left over.
- the remaining several turns of the fiber 12 (impregnated with the resin 11) is wound around the inner fiber layer 42 from above the portion 34a of the operation portion 34. Then, the fiber 12 is guided from the notch 36 into the ring 32, the fiber 12 is passed through the ring 32, and the fiber 12 is cut. By this cutting, a termination region 12a is formed at the portion that has passed through the ring 32. Thereafter, the operation is performed so that the portion 34 b of the operation portion 34 on the outer fiber layer 40 is pulled in the direction of the arrow 60 so that the base side of the termination region 12 a is hooked by the inner peripheral surface of the ring 32.
- the terminal region 12a is drawn into the inside of the fiber 12 wound first. Specifically, the termination region 12a is drawn into at least a part of the remaining several turns of the fiber group 12c wound in FIG. 7B. As a result, the termination region 12a is covered with the fiber group 12c. Thereafter, by continuing the operation of the operation unit 34, the ring 32 is automatically removed from the terminal region 12a and pulled out to the outside of the fiber group 12c, and finally the entire jig 30 is removed outside the high-pressure tank 1. .
- the method for manufacturing a tank according to this embodiment is a method for manufacturing a tank having a reinforcing fiber layer, in which a fiber 12 impregnated with a resin is wound by a predetermined amount, and the wound fiber 12 is impregnated.
- the fixing region 12a including the end of the fiber 12 that is the end of winding is pushed in along the extending direction of the fiber 12b that forms the already wound inner fiber layer 42, and the fixing region 12a extends.
- the fixing region 12a is arranged on the inner side of the fiber 12b in a state where the direction and the extending direction of the fiber 12b are along.
- the end of the fiber is inserted so as to cross the already wound fiber, so that a plurality of already wound wires are wound.
- the fact that the fiber ends were pressed down by the produced fiber itself was thought to be the cause of irregularities on the tank surface after production. If the fiber end is inserted so as to cross the already wound fiber, the already wound fiber is lifted by the portion where the fiber end enters. In other words, the already wound fiber rapidly rises as compared with other portions so as to get over the end of the fiber that has entered.
- the fixing region 12a including the end portion of the fiber 12 that is the end of winding is pushed between the fibers 12b that form the outermost layer of the inner fiber layer 42 that has already been wound, and at least a part of the fixing region 12a. Is held by being sandwiched between the fibers 12b forming the outermost layer, and the local swell of the inner fiber layer 42 into which the fixing region 12a enters is reduced.
- the outermost layer of the inner fiber layer 42 that has already been wound is in a state where a plurality of fibers 12b are adjacent to each other. Therefore, by pushing in the fixing region 12a, a minute gap existing between the adjacent fibers 12b is utilized as much as possible to form a space into which the fixing region 12a enters (FIGS. 6A to 6F and its) See description). By forming a space in which the fixed region 12a enters in this way, local swell of the inner fiber layer 42 is reduced.
- the part corresponding portion 121b of the fixing region 12a is sandwiched between the fibers 12b forming the outermost layer, while the remaining portion corresponding portion 121a of the fixing region 1a is sandwiched between the outermost layers. It arrange
- the whole fixed region 12a can be more reliably held in the outermost layer and the inner fiber layer on the back side while avoiding the bulge of the outermost layer.
- the remaining portion 121a of the fixed region 12a is formed closer to the end of the end portion than the partial corresponding portion 121b of the fixed region 12a.
- the fixing region 12 is bent along the direction intersecting the surface including the outermost layer, and the remaining portion 121a of the fixing region 12 is disposed on the inner fiber layer 42 on the inner side of the outermost layer. Yes.
- the fixing region 12a is bent in the direction intersecting with the surface including the outermost layer and disposed on the inner fiber layer 42, so that the fixing region 12a is subjected to an external force acting in the direction of pulling out the fixing region 12a. This can be countered by the frictional force between the remaining portion 121a and the inner fiber layer 42, and the end portion of the fiber can be more reliably fixed.
- the fixing region 12a is processed using the termination processing jig 20, and the termination processing jig 20 is inserted into the inner fiber layer 42 so that the interval between the adjacent fibers 12b is increased.
- the first portion 201 of the termination processing jig 20 temporarily widens the interval between the fibers 12b, it becomes easier to arrange the fixing region 12a in the widened interval, and between the adjacent fibers 12b. It is possible to effectively use the minute space existing in the. Furthermore, since the 2nd part 202 pushes in the fixed area
- the high-pressure tank 1 manufactured by the manufacturing method described in the present embodiment is a tank having a reinforcing fiber layer formed by winding the fiber 12 impregnated with the resin 11 and then thermosetting the resin 11.
- the reinforcing fiber layer has a fixed region 12a including an end portion of the fiber 12 that is the end of winding, and a fiber 12b that forms an inner fiber layer 42 that is wound before the fixed region 12a.
- the fixing region 12a which is a part of the end is sandwiched between the fibers 12b forming the outermost layer, and the end is fixed to the inner fiber layer 42.
- the fibers 12b forming the already wound inner fiber layer 42 are in a state where a plurality of fibers are adjacent to each other. Therefore, a space in which the fixed region 12a, which is a part of the end, enters is formed in the inner fiber layer 42 by utilizing a minute gap existing between the adjacent fibers 12b as much as possible. By forming a space in which the fixed region 12a enters in this way, local swell of the inner fiber layer 42 is reduced.
Abstract
Description
2:貯留空間
3:ライナー
3a:胴部
3b:ドーム部
4:補強繊維層
11:樹脂
12:繊維
12a:固定領域
12b:繊維
12c:繊維群
14:ボビン
15 張力調整部
16:樹脂槽
17:シャフト
18:供給ユニット
20:終端処理治具
30:治具
32:リング
34:操作部
34a:部分
34b:部分
40:外側繊維層
42:内側繊維層
60:矢印
100:燃料電池自動車
101:燃料電池システム
102:ガス供給ライン
104:燃料電池
121:単繊維
201:第1部分
202:第2部分
Claims (9)
- 補強繊維層を有するタンクの製造方法であって、
樹脂を含浸した繊維を所定分巻き付ける巻き付け工程と、
巻き付けた繊維に含浸している樹脂を熱硬化することで、前記補強繊維層を形成する硬化工程と、を備え、
前記巻き付け工程では、
巻き終わりとなる繊維の端部を、既に巻き付けられている内側繊維層に押し込むことで、前記端部の一部である固定領域の少なくとも一部を、前記最外層を形成する繊維間に挟み、
前記端部を前記内側繊維層に対して固定することを特徴とするタンクの製造方法。 - 前記巻き付け工程では、
前記端部の押し込みによって、前記固定領域の一部を前記最外層を形成する繊維間に挟む一方で、前記固定領域の残部を前記最外層よりも奥側の前記内側繊維層に配置することを特徴とする請求項1に記載のタンクの製造方法。 - 前記固定領域の残部を、前記固定領域の一部よりも前記端部の末端に近い方に形成してなることを特徴とする請求項2に記載のタンクの製造方法。
- 前記固定領域を前記最外層を含む面と交差する方向に沿わせて屈曲させ、前記固定領域の残部を前記最外層よりも奥側の前記内側繊維層に配置することを特徴とする請求項3に記載のタンクの製造方法。
- 前記巻き付け工程では、終端処理治具を用いて前記端部を処理するものであって、
前記終端処理治具は、前記内側繊維層に差し込まれることで互いに隣接する繊維同士の間隔を広げる第1部分と、その間隔を広げた部分に前記端部を押し込む第2部分とを有することを特徴とする請求項1に記載のタンクの製造方法。 - 樹脂を含浸した繊維を巻き付けた後でその樹脂を熱硬化させてなる補強繊維層を有するタンクであって、
前記補強繊維層は、巻き終わりとなる繊維の端部と、前記端部よりも先に巻き付けられてなる内側繊維層とを有し、
前記端部の一部である固定領域の少なくとも一部が、前記内側繊維層の最外層を形成する繊維間に挟み込まれることで、前記端部が前記内側繊維層に対して固定されていることを特徴とするタンク。 - 前記固定領域の一部が前記最外層を形成する繊維間に挟まれている一方で、前記固定領域の残部が前記最外層よりも奥側の前記内側繊維層に配置されていることを特徴とする請求項6に記載のタンク。
- 前記固定領域の残部が、前記固定領域の一部よりも前記端部の末端に近い方に形成されてなることを特徴とする請求項7に記載のタンク。
- 前記固定領域が前記最外層を含む面と交差する方向に沿わせて屈曲され、前記固定領域の残部が前記最外層よりも奥側の前記内側繊維層に配置されてなることを特徴とする請求項8に記載のタンク。
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EP11879137.5A EP2799214B1 (en) | 2011-12-28 | 2011-12-28 | Manufacturing method for a tank |
US14/368,571 US9381710B2 (en) | 2011-12-28 | 2011-12-28 | Tank and method of manufacturing the same |
JP2013551143A JP5757343B2 (ja) | 2011-12-28 | 2011-12-28 | タンクの製造方法 |
PCT/JP2011/080467 WO2013099010A1 (ja) | 2011-12-28 | 2011-12-28 | タンク及びその製造方法 |
CN201180076078.6A CN104023950B (zh) | 2011-12-28 | 2011-12-28 | 罐及其制造方法 |
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PCT/JP2011/080467 WO2013099010A1 (ja) | 2011-12-28 | 2011-12-28 | タンク及びその製造方法 |
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JP2020142388A (ja) * | 2019-03-04 | 2020-09-10 | トヨタ自動車株式会社 | 高圧タンクの製造方法 |
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DE102014016023B3 (de) * | 2014-10-29 | 2016-03-24 | Daimler Ag | Druckgasbehälter |
JPWO2018181290A1 (ja) * | 2017-03-29 | 2020-01-23 | 三井化学株式会社 | 積層体及びその製造方法 |
EP3385598A1 (de) | 2017-04-03 | 2018-10-10 | Enrichment Technology Company Ltd. | Faserverstärkter druckbehälter |
JP6614225B2 (ja) * | 2017-10-31 | 2019-12-04 | トヨタ自動車株式会社 | タンクの製造方法およびタンク |
JP6927139B2 (ja) * | 2018-05-10 | 2021-08-25 | トヨタ自動車株式会社 | フィラメントワインディング装置、フィラメントワインディングの設計方法およびタンクの製造方法 |
JP7287369B2 (ja) * | 2020-09-11 | 2023-06-06 | トヨタ自動車株式会社 | タンクおよびタンクの製造方法 |
US20230140626A1 (en) * | 2021-11-04 | 2023-05-04 | Supercool Metals LLC | Bulk metallic glass structures for hydrogen applications |
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