WO2013054867A1 - カバーテープ - Google Patents
カバーテープ Download PDFInfo
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- WO2013054867A1 WO2013054867A1 PCT/JP2012/076402 JP2012076402W WO2013054867A1 WO 2013054867 A1 WO2013054867 A1 WO 2013054867A1 JP 2012076402 W JP2012076402 W JP 2012076402W WO 2013054867 A1 WO2013054867 A1 WO 2013054867A1
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- WIPO (PCT)
- Prior art keywords
- resin
- wax
- layer
- cover tape
- antistatic
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/017—Antistatic agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L21/6836—Wafer tapes, e.g. grinding or dicing support tapes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2405/00—Adhesive articles, e.g. adhesive tapes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/006—Presence of polyolefin in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2477/00—Presence of polyamide
- C09J2477/006—Presence of polyamide in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2491/00—Presence of oils, fats or waxes
- C09J2491/006—Presence of oils, fats or waxes in the substrate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2221/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof covered by H01L21/00
- H01L2221/67—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere
- H01L2221/683—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/68313—Auxiliary support including a cavity for storing a finished device, e.g. IC package, or a partly finished device, e.g. die, during manufacturing or mounting
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
Definitions
- the present invention relates to a cover tape used for a package of electronic parts.
- Such a chip-type surface-mount electronic component is stored in a carrier tape in which storage pockets thermoformed according to the shape of the electronic component are continuously formed.
- the cover tape is stacked on the upper surface of the carrier tape as a cover material, and both ends of the cover tape are continuously heat-sealed in the length direction with a heated sealing trowel to form a package of electronic parts.
- the cover tape is set to the cover tape feeding portion of the taping machine as a roll that is cut into a width matched to the carrier tape to be heat-sealed and continuously rolled up. If the front and back of the cover tape stick to each other and become a state generally called blocking, the cover tape will not be stably fed out, which causes the parts to be stably loaded into the carrier tape storage pocket. The problem arises that the component loading line is not stopped. That is, when the cover tape is transported or stored as a roll-shaped roll, it is exposed to a high temperature or high temperature and high humidity environment so that the base layer on the front side or the antistatic layer on the front side and the adhesive layer on the back side adhere to each other.
- the blocking phenomenon occurs, and once this blocking occurs, it cannot be expected to be eliminated even if the roll-shaped scroll is stored in a place where the temperature and humidity are controlled within an appropriate range. Also, depending on the type of resin that constitutes the adhesive layer, not only the above-mentioned parts loading line is stopped, but also the antistatic layer laminated on the base layer of the cover tape is transferred to the adhesive layer, resulting in a decrease in antistatic performance. It may be accompanied by a defective phenomenon.
- antistatic agents include low molecular weight and high molecular weight antistatic agents such as surfactants that exert their effects by adsorbing moisture in the air. It is difficult to obtain sufficient antistatic performance to control the adhesion of dust and dust, and the problem is that it adversely affects performance because it moves to the surface opposite to the coated surface during tape winding ( Patent Document 6). Further, even with a polymer type antistatic agent, it is easily affected by ambient moisture and moisture, and the antistatic performance is lowered in a low humidity environment (23 ° C. ⁇ 20% RH atmosphere or less) (Patent Document 7, It was difficult to maintain sufficient antistatic performance such as 8).
- the main subject of this invention is providing the cover tape which can eliminate the above-mentioned problem at least partially.
- another object of the present invention is a process in which blocking does not occur even when exposed to a high temperature or high temperature and humidity environment, stable antistatic performance is maintained even in a low humidity environment, and an electronic component is stored in a carrier tape. It is to provide a cover tape that is free from harmful effects.
- an antistatic layer is provided on the surface of the base material layer opposite to the adhesive layer.
- the antistatic layer contains at least an inorganic antistatic agent and a wax having an average particle size of 0.2 to 3.0 ⁇ m, and the inorganic antistatic agent is added to all the components constituting the antistatic layer.
- the content is 40 to 80% by mass
- the content of wax is 10 to 50% by mass, 23 ° C. ⁇ 30% R.D. H.
- a cover tape characterized in that the surface resistivity on the base material layer side in an atmosphere is 10 13 ⁇ / ⁇ or less.
- the surface resistivity on the substrate layer side is the surface resistivity on the surface of the substrate layer on the antistatic layer side.
- the cover tape has an intermediate layer or the like between the base material layer and the adhesive layer as long as the antistatic layer is provided on the surface side of the base material layer to form the surface layer of the cover tape. This layer may be interposed, and other layers such as an intermediate layer are preferably interposed from the viewpoint of improving the strength.
- the inorganic antistatic agent is magnesium silicate or smectite, such as montmorillonite, beidellite, nontronite, hectorite, sabonite, or a combination thereof, and in other preferred embodiments,
- the wax is any of plant-derived carnauba wax, rice wax, candelilla wax, petroleum-derived paraffin wax, microcrystalline wax, synthetic wax olefin wax, ester wax, ketone wax, amide wax or These are combinations.
- the antistatic layer comprises, as a binder component, polyurethane resin, acrylic resin, polyvinyl chloride resin, ethylene-vinyl acetate resin, polyester resin, butadiene resin, styrene resin.
- thermoplastic resin selected from the group consisting of a resin, an acrylic-modified polyester resin, and combinations thereof
- the adhesive layer is a polyurethane-based resin that can be heat-sealed to a resin carrier tape, an acrylic resin A resin, a polyvinyl chloride resin, an ethylene-vinyl acetate resin, a polyester resin, a butadiene resin, a styrene resin including a hydrogenated system, a polyolefin resin, or a combination thereof, and further preferable.
- the substrate layer comprises polyester, polyolefin Or any of the resin films of nylon is obtained by laminating a more or at a plurality of layers.
- an antistatic layer or a conductive layer may be provided on the surface side of the adhesive layer that can be heat sealed to the carrier tape, and the antistatic layer on the adhesive layer side is the surface of the base material layer.
- the composition may be the same as or different from that of the antistatic layer provided on the substrate.
- an antistatic layer containing an inorganic antistatic agent and a wax is formed on the surface of the base material layer, so that no blocking occurs even when exposed to a high temperature or high temperature and humidity environment, and even in a low humidity environment. It is possible to obtain a cover tape that maintains stable antistatic performance and has no harmful effects in the process of storing electronic components in a carrier tape.
- a cover tape 10 includes a base material layer 11, an intermediate layer 12 laminated on the back side of the base material layer 11, and a laminate on the back side of the intermediate layer 12.
- the adhesive layer 13 and the antistatic layer 14 laminated on the surface on the front side opposite to the intermediate layer 12 (or the adhesive layer 13) of the base material layer 11 are included.
- the base material layer 11 is formed by laminating any one or a plurality of resin films made of polyester, polyolefin, or nylon. Particularly preferable materials for the base material layer 11 are biaxially stretched polyethylene terephthalate (PET), biaxially stretched polyethylene naphthalate (PEN), polypropylene, polyethylene, biaxially stretched 6,6-nylon, 6-nylon, and the like.
- PET polyethylene terephthalate
- PEN biaxially stretched polyethylene naphthalate
- polypropylene polyethylene
- polyethylene biaxially stretched 6,6-nylon, 6-nylon, and the like.
- a thickness of 9 to 35 ⁇ m is preferable.
- Examples of the resin constituting the intermediate layer 12 include low density polyethylene, linear low density polyethylene, very low density polyethylene, ethylene-propylene copolymer, ethylene-1-butene copolymer, and ethylene-1-pentene copolymer. , Ethylene-1-hexene copolymer, ethylene-1-octene copolymer, ethylene-vinyl acetate copolymer, ethylene-acrylic acid ester copolymer, polyurethane, and these may be used alone or as a mixture of two or more. Can also be used together.
- the thickness is preferably 10 to 50 ⁇ m, and if it is less than 10 ⁇ m, the tear strength is inferior.
- the adhesive layer 13 is formed of an adhesive thermoplastic resin, and examples of the thermoplastic resin include polyurethane resins, acrylic resins, polyvinyl chloride resins, ethylene-vinyl acetate resins, polyester resins, and butadiene resins. Any of a resin, a styrene resin including a hydrogenation system, a polyolefin resin, or a combination thereof is preferably used.
- the thickness of the adhesive layer 13 is not particularly limited as long as it can be appropriately sealed with the carrier tape, and is, for example, 5 to 40 ⁇ m.
- the antistatic layer 14 contains an inorganic antistatic agent and a wax.
- the inorganic antistatic agent magnesium silicate or smectite, for example, montmorillonite, beidellite, nontronite, hectorite, sabonite or a combination thereof is preferably used.
- the content of the inorganic antistatic agent with respect to the entire components constituting the antistatic layer is preferably 40 to 80% by mass. When the amount is less than 40% by mass, the antistatic performance is hardly exhibited.
- the wax contained in the antistatic layer 14 includes plant-derived carnauba wax, rice wax, candelilla wax, petroleum-derived paraffin wax, microcrystalline wax, synthetic wax olefin wax, ester wax, and ketone wax. Any one of the amide waxes or a combination thereof is preferably used.
- the content of wax with respect to the total components constituting the antistatic layer is preferably 10 to 50% by mass, more preferably 10 to 30% by mass, or 15 to 25% by mass. If it is less than 10% by mass, it is difficult to sufficiently suppress blocking, and if it exceeds 50% by mass, the antistatic performance may be impaired.
- the wax is uniformly dispersed in the antistatic layer 14 in the form of fine particles, and the average particle size thereof is 0.2 to 3.0 ⁇ m, preferably 0.5 to 3.0 ⁇ m. If it is less than 0.2 ⁇ m, it is difficult to obtain sufficient anti-blocking performance, and if it exceeds 3.0 ⁇ m, the antistatic performance may be impaired.
- the antistatic layer 14 is formed by preparing a coating solution containing an antistatic agent and a wax and coating the surface of the base material layer 11.
- the average particle diameter is the average particle diameter of the wax particles in the wax dispersion contained in the coating liquid, strictly speaking, the weight average particle diameter, and can be measured by, for example, the Coulter counter method or the Microtrac method.
- the antistatic layer 14 may further contain a thermoplastic resin as a binder component.
- a thermoplastic resin as a binder component.
- thermoplastic resins polyurethane resins, acrylic resins, polyvinyl chloride resins, ethylene-vinyl acetate resins, polyester resins, butadiene resins, styrene resins, and acrylic modified polyester resins are preferably used. it can.
- the thickness of the antistatic layer 14 is 0.02 to 0.5 ⁇ m, preferably 0.05 to 0.3 ⁇ m, and more preferably 0.05 to 0.2 ⁇ m. If the thickness of the antistatic layer is less than 0.02 ⁇ m, sufficient antistatic performance may not be exhibited. On the other hand, if the thickness of the antistatic layer exceeds 0.5 ⁇ m, the antistatic layer is caused by cohesive failure of the antistatic layer. It may desorb itself and cause a problem as a foreign object. As will be described later, the antistatic layer is usually applied by applying a solution in which various components constituting the antistatic layer are dissolved or dispersed, or by applying an emulsion of various components constituting the antistatic layer. Although formed, when formed by a coating method, the thickness here is the thickness after drying.
- FIG. 2 shows the structure of a cover tape according to another embodiment of the present invention, and the same reference numerals as those in FIG. 1 are given to the parts having the same structure as the cover tape 10 shown in FIG. The description is omitted.
- a further antistatic layer or conductive layer 15 is formed on the surface of the adhesive layer 13.
- the antistatic agent of the antistatic layer 15 can be any of cationic, anionic, nonionic, amphoteric, and polymeric antistatic agents.
- the conductive agent may be, for example, conductive fine particles obtained by providing conductivity to sulfides such as zinc sulfide, copper sulfide, cadmium sulfide, nickel sulfide, palladium sulfide, barium sulfate, or oxidation.
- sulfides such as zinc sulfide, copper sulfide, cadmium sulfide, nickel sulfide, palladium sulfide, barium sulfate, or oxidation.
- Metal oxides such as tin, zinc oxide, indium oxide, and titanium oxide, conductive carbon fine particles, silicon-containing organic compounds, or surface metal plating fine particles can be used.
- these additional antistatic layers or conductive layers 15 include polyurethane resins, acrylic resins, polyvinyl chloride resins, ethylene-vinyl acetate resins, polyester resins, butadiene resins, styrene containing hydrogenated systems.
- a thermoplastic resin serving as a binder component composed of a base resin, an acrylic-modified polyester resin, and a combination thereof can be contained, and the further antistatic layer or the conductive layer 15 itself may have heat sealability.
- FIG. 3 shows the structure of a cover tape according to still another embodiment of the present invention. Compared with the structure of the cover tape 10 shown in FIG. 1, the intermediate layer 12 is omitted in the cover tape 10 of FIG. The only difference is.
- the total thickness is preferably in the range of 40 to 75 ⁇ m. If it is less than 40 ⁇ m, it is easy to cut when the cover tape is peeled off at a high speed, and if it exceeds 75 ⁇ m, not only the heat transfer becomes worse when the cover tape is heat-sealed to the carrier tape, but the sealing state becomes unstable, This is because the variation in peel strength when peeling the cover tape from the carrier tape increases.
- cover tape 10 which concerns on the said embodiment, it does not specifically limit as a peeling form at the time of peeling the cover tape 10 from a carrier tape,
- the adhesive layer 13 in the case of FIG. 1, 3) of a carrier tape and the cover tape 10, or
- any form of interfacial delamination peeled off at the interface of the further antistatic layer or conductive layer 15 in the case of FIG. 2, cohesive failure inside the structure of the cover tape 10 or cohesive delamination due to peeling at the interface, or delamination There may be.
- the cover tape 10 is 23 ° C. ⁇ 30% R.D. on the antistatic layer 14 side.
- the surface resistivity in the atmosphere has an antistatic performance of 10 13 ⁇ / ⁇ or less, preferably 10 12 ⁇ / ⁇ or less. If the surface resistivity exceeds 10 13 ⁇ / ⁇ , dust may adhere to the antistatic layer 14 side. When storing the component or mounting the component with the cover tape 10 peeled off from the carrier tape, Dust may adhere and the original function may not be exhibited.
- the method for producing the cover tape is not particularly limited, and a conventionally used method can be used.
- the laminate including the intermediate layer 12 is manufactured by dry lamination or extrusion lamination.
- the antistatic layer 14 is applied to the surface of the laminate on the side of the base material layer 11 using, for example, a gravure coater, reverse coater, kiss coater, air knife coater, Mayer bar coater, dip coater or the like.
- an antistatic agent, a wax, and other thermoplastic resins are contained, and in particular, as described above, a dispersion liquid in which fine wax having an average particle diameter of a predetermined range is uniformly dispersed is prepared as a coating liquid. This is applied to the laminate.
- a similar coating method can also be used when a further antistatic layer or conductive layer 15 is provided on the adhesive layer 13 side.
- an adhesive may be applied to the contact surface of each layer when producing a laminated structure.
- the wettability of the coating agent may be improved by applying corona treatment or ozone treatment to the surface of the layer to be applied before coating, and in particular, corona treatment. Is preferred.
- Blocking resistance A method for evaluating the blocking resistance of a cover tape will be described with reference to FIG. After slitting a plastic core 20 having a diameter of 93 mm with a width of 5.5 mm and a length of 500 m and winding the cover tape so that the antistatic layer side of the surface of the base material layer faces outward, a 60 ° C. dry environment and 40 ° C x 90% R.D. H. Each is put into the environment for 24 hours. After removal from each environment, 23 ° C. ⁇ 50% R.D. H. In an environment of 1 hour, and also at 23 ° C. ⁇ 50% R.D. H.
- the cover tape is cut leaving 20 m of the core portion.
- the position of the jig “0” in FIG.
- the cover tape is drawn out 20 cm in a state of standing at 3 o'clock), and a 1 g load 23 is attached to the tip (FIG. 4 (a)).
- the feeding portion is rotated 180 ° clockwise so as to come to “6” on the jig (in FIG. 4, the direction is specified by the clock board at the 9 o'clock position) (FIG. 4B).
- the position at which the feeding portion stops after the feeding portion is naturally peeled off and moved from the wound cover tape by the 1 g load 23 is read (for example, as shown in FIG. 4C).
- the evaluation score “0” to “6” on the jig 21 indicated by the load 23 indicates the degree of blocking. That is, when the evaluation score is “6”, it is in a blocking state, and as the evaluation score becomes smaller, it means that the blocking resistance is excellent, and when the evaluation score is “0”, it indicates that there is no blocking. It becomes. Since this method is very strict as an evaluation of blocking resistance, if the evaluation score is “3” or less, it can be determined that the cover tape has blocking resistance.
- Chemipearl W500 (manufactured by Mitsui Chemicals, olefin wax aqueous dispersion, solid content: 40%, average particle size: 2.5 ⁇ m (Coulter counter method))
- Chemipearl W900 (manufactured by Mitsui Chemicals, olefin wax aqueous dispersion, solid content: 40%, average particle size: 0.6 ⁇ m (Microtrac method))
- Chemipearl W100 (manufactured by Mitsui Chemicals, olefin wax aqueous dispersion, solid content: 40%, average particle size: 3.0 ⁇ m (Coulter counter method))
- Chemipearl W400 (manufactured by Mitsui Chemicals, olefin-based wax aqueous dispersion, solid content: 40%, average particle size: 4.0 ⁇ m (Coulter counter method)) MYE-35G (manufact
- Example 1 Styrene-butadiene block copolymer “Clearen” (manufactured by Denki Kagaku Kogyo Co., Ltd.) 42.5% by mass, styrene-butadiene block copolymer “TR-2000” (manufactured by JSR) 22.5% by mass, ethylene- ⁇ -olefin random copolymer “Tuffmer A” (Mitsui Chemicals) 25% by mass and high impact polystyrene: Toyostyrene “E640N” (Toyo Styrene Co., Ltd.) 10% by mass were pre-blended using a tumbler.
- a single screw extruder having a diameter of 40 mm kneading was performed at 210 ° C. to obtain a resin composition constituting the adhesive layer (13 in FIG. 2) at a line speed of 20 m / min.
- a film was formed using an inflation extruder to obtain a 15 ⁇ m thick film constituting the adhesive layer.
- a two-component curable polyurethane anchor coating agent is applied to a biaxially stretched polyethylene terephthalate film (thickness: 12 ⁇ m) constituting the base material layer (11 in FIG.
- a laminated film (laminated body 11 to 13 in FIG. 2) was obtained by an extrusion laminating method. After corona treatment on both surfaces of the base material layer and the adhesive layer of the laminated film, the base material layer surface is diluted with water in advance as an antistatic layer 1 (14 in FIG. 2) to obtain a solid content concentration of 3.5%.
- Inorganic antistatic agent aqueous solution “Laponite S482” manufactured by Rockwood Additives
- 60% by mass 60% by mass
- 25% by mass of “Chemical Pearl W500” manufactured by Mitsui Chemicals
- polyester resin “KA3556” An antistatic layer 2 (in FIG. 2) formed by applying a dispersion mixed with 15% by mass (manufactured by Unitika Co., Ltd.) with a gravure coater so that the coating thickness after drying is 0.1 ⁇ m.
- Bondip PM manufactured by Konishi Co., Ltd.
- NK polymer MK-100EC-242 manufactured by Shin-Nakamura Chemical Co., Ltd.
- AERODISP W630 manufactured by Nippon Aerosil Co., Ltd.
- Examples 2 to 9 Comparative Examples 1 to 9>
- the cover tapes according to Examples 2 to 3 of the present invention and the comparison were made in the same manner as Example 1 except that the antistatic layer (14 in FIG. 2) was formed at the composition ratio described in Tables 1 and 2.
- Cover tapes according to Examples 1 and 3 to 9 were prepared. Further, the antistatic layer was formed with the composition ratio described in Tables 1 and 2, and the adhesive layer (13 in FIG. 2) was formed of acrylic resin “EC-242” (manufactured by Shin-Nakamura Chemical Co., Ltd.). Except for the above, cover tapes according to Examples 4 to 9 and a cover tape according to Comparative Example 2 were produced in the same manner as Example 1.
- the cover tape provided by the present invention eliminates troubles such as production stoppage in the production process of storing electronic components on a carrier tape by a taping machine and inability to inspect the stored components. Specifically, the cover tape is blocked. By suppressing it, the feeding stability is realized, and the antistatic performance that is stable even at low humidity is provided, so that the storage efficiency of electronic components can be increased.
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Abstract
Description
上記問題の対策として、カバーテープの最表面に帯電防止剤を塗布することがなされている。
また、本発明の他の課題は、高温又は高温多湿環境下に曝されてもブロッキングの発生がなく、低湿度環境下でも安定した帯電防止性能を維持し、電子部品をキャリアテープに収納する工程で弊害の無いカバーテープを提供することにある。
図1に示すように、本発明の一実施形態に係るカバーテープ10は、基材層11と、該基材層11の裏側に積層される中間層12と、該中間層12の裏側に積層される接着層13と、基材層11の中間層12(又は接着層13)とは反対側の表側の面に積層される帯電防止層14とを含む構造を有する。
尚、後述するように、帯電防止層14は、帯電防止剤やワックスを含有する塗工液を調製し、基材層11の表面にこれを塗工することによって形成されるが、ワックスの上記平均粒径は、塗工液に含まれるワックス分散液中におけるワックス粒子の平均粒径、厳密には重量平均粒径であり、例えばコールターカウンター法又はマイクロトラック法等により測定することができる。
本実施形態においては、接着層13の表面に、更なる帯電防止層もしくは導電層15が形成される。更なる帯電防止層15には、基材層11の表面に設けられる帯電防止層14と同一の成分を用いてもよいが、別の成分を用いてもよい。一実施形態では、帯電防止層15の帯電防止剤は、カチオン性、アニオン性、ノニオン性、両性、高分子型のいずれの帯電防止剤でも用いることができる。また、導電層15が形成される場合、導電剤としては、例えば硫化亜鉛、硫化銅、硫化カドミウム、硫化ニッケル、硫化パラジウム等の硫化物に導電性をもたせた導電性微粒子、硫酸バリウム、または酸化錫、酸化亜鉛、酸化インジウム、酸化チタン等の金属酸化物、導電性カーボン微粒子、ケイ素含有有機化合物、もしくは表面金属メッキ微粒子などが使用できる。更に、これら更なる帯電防止層又は導電層15には、ポリウレタン系樹脂、アクリル系樹脂、ポリ塩化ビニル系樹脂、エチレン-酢酸ビニル系樹脂、ポリエステル系樹脂、ブタジエン系樹脂、水素添加系を含むスチレン系樹脂、アクリル変性ポリエステル樹脂及びこれらの組合せからなるバインダー成分となる熱可塑性樹脂を含有させることができ、該更なる帯電防止層又は導電層15自体がヒートシール性を有していてもよい。
図4を参照しながら、カバーテープの耐ブロッキング性評価方法を説明する。
直径93mmのプラスチックコア20に幅5.5mm×長さ500mでスリット加工してカバーテープの基材層表面の帯電防止層側が外方となるようレコード状に巻いた後に、60℃ドライ環境および40℃×90%R.H.環境にそれぞれ24時間投入する。各環境下から取り出した後、23℃×50%R.H.の環境下に1時間放置し、同じく23℃×50%R.H.の雰囲気下で巻芯部の残りが20m程度になるまで繰り出した状態で、巻芯部の20mを残してカバーテープを切断する。図4に示す治具21に巻芯部のスリット品22を時計回りの向きでテープを繰り出せるように取り付けた後、冶具の「0」の位置(図4中、時計盤で方向を特定して3時の位置)で静置した状態でカバーテープを20cm繰り出し、その先端部に1gの荷重23を取り付ける(図4(a))。ついで、繰り出し部が冶具上の「6」(図4中、時計盤で方向を特定して9時の位置)に来るように時計回りに180°回転させる(図4(b))。回転直後に1gの荷重23により巻取状態のカバーテープから自然に繰り出し部が剥離されて移動した後に繰り出し部が停止する位置を読み取る(例えば図4(c)に示すようになる)。
耐ブロッキング性評価と同じ環境下にスリット加工品を投入し、同様に巻芯部を用いて三菱化学社のハイレスタUP MCP-HT450を使用し、JIS K 6911の方法にて、23℃×50%R.H.雰囲気下、印加電圧500Vで基材層表面の帯電防止層側の表面抵抗率を測定する。
上記(2)と同じ測定器を用いて23℃×30%R.H.雰囲気下に24時間放置した後に同一雰囲気下にて、印加電圧500Vで基材層表面の帯電防止層側の表面抵抗率を測定する。
(基材層11の原料)
・ 二軸延伸ポリエチレンテレフタレートフィルム(東洋紡社製)、厚み12μm
(中間層12の原料)
・ m-LLDPE:ハーモレックスNH745N(日本ポリエチレン社製)
(接着層13の樹脂)
・ スチレン-ブタジエンブロック共重合体1:クリアレン(電気化学工業社製、ピカット軟化温度:76℃、スチレン比:83質量%)
・ スチレン-ブタジエンブロック共重合体2:TR-2000(JSR社製、ピカット軟化温度:45℃、スチレン比:40質量%)
・ ハイインパクトポリスチレン:トーヨースチロールE640N(東洋スチレン社製、ピカット軟化温度:99℃)
・ エチレン-α-オレフィンランダム共重合体:タフマーA(三井化学社製)
・ アクリル系樹脂:EC-242(新中村化学工業社製、Tg=60℃)
・ ワックス成分:
ケミパールW500(三井化学社製、オレフィン系ワックス水分散体、固形分:40%、平均粒径:2.5μm(コールターカウンター法))
ケミパールW900(三井化学社製、オレフィン系ワックス水分散体、固形分:40%、平均粒径:0.6μm(マイクロトラック法))
ケミパールW100(三井化学社製、オレフィン系ワックス水分散体、固形分:40%、平均粒径:3.0μm(コールターカウンター法))
ケミパールW400(三井化学社製、オレフィン系ワックス水分散体、固形分:40%、平均粒径:4.0μm(コールターカウンター法))
MYE-35G(丸芳化学社製、オレフィン系ワックス水分散体、固形分:35%、平均粒径:0.2μm)
AQACER498(BYK社製、パラフィンワックス水分散体、固形分:50%、平均粒径:0.1μm(へグマンゲージ法))
・ バインダー樹脂:
エリーテルKA3556(ユニチカ社製、ポリエステル樹脂、ガラス転移温度:80℃)
・ 無機系帯電防止剤:
ラポナイトS482(Rockwood Additives社製、ケイ酸マグネシウム、燐片状(短辺:1nm、長辺:25nm)
(帯電防止層15)
・ 帯電防止剤:
ボンディップPM(コニシ社製、四級アンモニウムアクリレートエチル硫酸塩)
・ バインダー樹脂:
NKポリマーMK-100EC-242(新中村化学工業社製、ガラス転移温度:55℃、メタクリル酸メチル-アクリル酸ブチルのランダム共重合体のエマルジョン溶液)
・ アンチブロッキング材:
AERODISP W630(日本アエロジル社製、球状アルミナ、平均粒径:0.12μm)
スチレン-ブタジエンブロック共重合体「クリアレン」(電気化学工業社製)42.5質量%と、スチレン-ブタジエンブロック共重合体「TR-2000」(JSR社製)22.5質量%と、エチレン-α-オレフィンランダム共重合体「タフマーA」(三井化学社製)25質量%と、ハイインパクトポリスチレン:トーヨースチロール「E640N」(東洋スチレン社製)10質量%を、タンブラーを用いてプリブレンドし、径40mmの単軸押出機を用いて210℃で混練し、毎分20mのライン速度で接着層(図2中、13)を構成する樹脂組成物を得た。この接着層の樹脂組成物を用いて、インフレーション押出機を用いて製膜を行い、接着層を構成する15μm厚のフィルムを得た。更に、基材層(図2中、11)を構成する二軸延伸ポリエチレンテレフタレートフィルム(厚み12μm)に二液硬化型ポリウレタン型アンカーコート剤を、ロールコーターを用いて塗布しておき、当該塗布面と上述した接着層のフィルムとの間に、中間層(図2中、12)を構成する溶融したm-LLDPE「ハーモレックスNH745N」(日本ポリエチレン社製)を25μmの厚みになるように押出し、押出ラミネート法によって積層フィルム(図2中、11~13の積層体)を得た。積層フィルムの基材層と接着層の両表面にコロナ処理した後、基材層表面に帯電防止層1(図2中、14)として予め水で希釈して固形分濃度が3.5%となるように作製しておいた無機系帯電防止剤水溶液「ラポナイトS482」(Rockwood Additives社製)60質量%とワックス成分となる「ケミパールW500」(三井化学社製)25質量%及びポリエステル樹脂「KA3556」(ユニチカ社製)15質量%を混合した分散液をグラビアコーターにより乾燥後の塗工厚みが0.1μmになるように塗布し、次いで接着層表面に形成させる帯電防止層2(図2中、15)として予め作製しておいたボンディップPM(コニシ社製)31質量%、NKポリマーMK-100EC-242(新中村化学工業社製)25質量%とAERODISP W630(日本アエロジル社製)44質量%を混合した分散液を、グラビアコーターを用いて、乾燥後の塗工厚みが0.3μmになるように塗布したカバーテープを得た。
帯電防止層(図2中、14)を、表1及び表2に記載した組成比率にて形成した以外は、実施例1と同様にして本発明の実施例2~3に係るカバーテープ及び比較例1、3~9に係るカバーテープを作製した。また、帯電防止層を表1及び表2に記載した組成比率にて形成し、接着層(図2中、13)をアクリル系樹脂「EC-242」(新中村化学工業社製)によって形成した以外は、実施例1と同様にして本発明の実施例4~9に係るカバーテープ及び比較例2に係るカバーテープを作製した。
11 基材層
12 中間層
13 接着層
14 帯電防止層
15 帯電防止層又は導電層
20 プラスチックコア
21 耐ブロッキング性評価用治具
22 巻芯部のスリット品
23 荷重
1~6 耐ブロッキング性のスコア
Claims (6)
- 基材層と樹脂製キャリアテープにヒートシールされる接着層とを少なくとも有するカバーテープにおいて、基材層の接着層とは反対側の面に帯電防止層を有し、該帯電防止層が少なくとも無機系帯電防止剤と平均粒径が0.2~3.0μmのワックスを含有し、帯電防止層を構成する成分全体に対し、無機系帯電防止剤が40~80質量%、ワックスの含有量が10~50質量%であり、23℃×30%R.H.雰囲気下での基材層側の表面抵抗率が1013Ω/□以下であることを特徴とするカバーテープ。
- 無機系帯電防止剤が、ケイ酸マグネシウム又はスメクタイトのいずれかあるいは双方であることを特徴とする請求項1に記載のカバーテープ。
- ワックスが、植物由来のカルナバワックス、ライスワックス、キャンデリラワックス、石油由来のパラフィンワックス、マイクロクリスタリンワックス、合成ワックスであるオレフィン系ワックス、エステル系ワックス、ケトン系ワックス、アミド系ワックスのいずれか又はこれらの組み合わせであることを特徴とする請求項1又は2に記載のカバーテープ。
- 上記帯電防止層が、バインダー成分として、ポリウレタン系樹脂、アクリル系樹脂、ポリ塩化ビニル系樹脂、エチレン-酢酸ビニル系樹脂、ポリエステル系樹脂、ブタジエン系樹脂、スチレン系樹脂、アクリル変性ポリエステル樹脂及びこれらの組合せからなる群から選択される熱可塑性樹脂を含有することを特徴とする請求項1から3のいずれか一項に記載のカバーテープ。
- 上記接着層が、樹脂製キャリアテープにヒートシール可能なポリウレタン系樹脂、アクリル系樹脂、ポリ塩化ビニル系樹脂、エチレン-酢酸ビニル系樹脂、ポリエステル系樹脂、ブタジエン系樹脂、水素添加系を含むスチレン系樹脂、ポリオレフィン系樹脂のいずれか又はこれらの組み合わせを含有することを特徴とする請求項1から4のいずれか一項に記載のカバーテープ。
- 上記基材層が、ポリエステル、ポリオレフィン又はナイロンからなる樹脂製フィルムのいずれか一層か又はその複数層の積層体であることを特徴とする請求項1から5のいずれか一項に記載のカバーテープ。
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- 2012-10-12 US US14/351,329 patent/US9453146B2/en active Active
- 2012-10-12 CN CN201210387293.4A patent/CN103043302B/zh active Active
- 2012-10-12 CN CN2012205219558U patent/CN202953309U/zh not_active Expired - Lifetime
- 2012-10-12 SG SG11201401462QA patent/SG11201401462QA/en unknown
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JPWO2016120705A1 (ja) * | 2015-01-27 | 2018-01-18 | 王子ホールディングス株式会社 | 積層体及び加飾成形体 |
JP2017007739A (ja) * | 2015-06-17 | 2017-01-12 | 浙江潔美電子科技股▲ふん▼有限公司 | 電子部品の収納用キャリアテープのカバーテープ及びその調製方法 |
JP2017013801A (ja) * | 2015-06-29 | 2017-01-19 | 住友ベークライト株式会社 | 電子部品包装用カバーテープ |
JP2020121727A (ja) * | 2019-01-29 | 2020-08-13 | 住友ベークライト株式会社 | 電子部品包装用のカバーテープおよび電子部品包装体 |
JP7192532B2 (ja) | 2019-01-29 | 2022-12-20 | 住友ベークライト株式会社 | 電子部品包装用のカバーテープおよび電子部品包装体 |
JP2021116121A (ja) * | 2020-01-29 | 2021-08-10 | 住友ベークライト株式会社 | 電子部品包装用のカバーテープおよび電子部品包装体 |
JP7547734B2 (ja) | 2020-01-29 | 2024-09-10 | 住友ベークライト株式会社 | 電子部品包装用のカバーテープおよび電子部品包装体 |
Also Published As
Publication number | Publication date |
---|---|
US9453146B2 (en) | 2016-09-27 |
JPWO2013054867A1 (ja) | 2015-03-30 |
TWI568650B (zh) | 2017-02-01 |
CN202953309U (zh) | 2013-05-29 |
US20140248487A1 (en) | 2014-09-04 |
SG10201602865TA (en) | 2016-05-30 |
CN103043302B (zh) | 2016-06-01 |
TW201336747A (zh) | 2013-09-16 |
JP6113073B2 (ja) | 2017-04-12 |
KR101955745B1 (ko) | 2019-03-07 |
KR20140107183A (ko) | 2014-09-04 |
SG11201401462QA (en) | 2014-09-26 |
CN103043302A (zh) | 2013-04-17 |
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