WO2013047612A1 - Boisson emballée - Google Patents

Boisson emballée Download PDF

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Publication number
WO2013047612A1
WO2013047612A1 PCT/JP2012/074774 JP2012074774W WO2013047612A1 WO 2013047612 A1 WO2013047612 A1 WO 2013047612A1 JP 2012074774 W JP2012074774 W JP 2012074774W WO 2013047612 A1 WO2013047612 A1 WO 2013047612A1
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Prior art keywords
mass
less
isoquercitrin
component
still
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PCT/JP2012/074774
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English (en)
Japanese (ja)
Inventor
俊 迫田
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花王株式会社
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Publication of WO2013047612A1 publication Critical patent/WO2013047612A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52—Adding ingredients
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52—Adding ingredients
    • A23L2/60—Sweeteners
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/40—Colouring or decolouring of foods
    • A23L5/41—Retaining or modifying natural colour by use of additives, e.g. optical brighteners

Definitions

  • the present invention relates to a packaged beverage.
  • Isoquercitrin is a flavonol glycoside in which one glucose is ⁇ -bonded at the 3-position of quercetin. Isoquercitrin has a strong antioxidant activity and is known to prevent discoloration of the pigment (Patent Document 1), and is also expected to act on the living body such as anti-arteriosclerosis and blood flow improvement. ing.
  • isoquercitrin is poorly soluble in water and thus works effectively in vitro, but is not sufficiently effective in vivo and has limited use as a water-based composition for beverages and the like. Therefore, in order to improve the solubility in water, “enzyme-treated isoquercitrin” obtained by allowing glycosyltransferase to act on isoquercitrin in the presence of starch is proposed (Patent Document 2). “Enzyme-treated isoquercitrin” is a mixture of isoquercitrin and ⁇ -glucosylisoquercitrin in which one or more glucoses are further added to the glucose residue of isoquercitrin with an ⁇ -1,4 bond.
  • Non-patent Document 3 a quercetin glycoside composition in which the composition of ⁇ -glucosyl isoquercitrin contained in enzyme-treated isoquercitrin is changed by fractionation to further enhance oral absorbability. Recently, it has been found that isoquercitrin has an action to reduce body fat of obese people, and it is reported that it is effective when ingested in the form of a beverage (Non-patent Document 1).
  • the present invention includes the following components (A) and (B): (A) Isoquercitrin and its sugar adduct 0.03-0.25% by mass, (B) Alcohols
  • the present invention provides a packaged beverage containing 0.0004 mass% or more and less than 1 mass% and having a pH of 2-5.
  • the present invention is a method for suppressing color change of a container-packed beverage containing isoquercitrin and its sugar adduct, wherein the following components (A) and (B) are: (A) Isoquercitrin and its sugar adduct 0.03-0.25% by mass, (B) Alcohols
  • the present invention provides a method for suppressing a change in color tone, which is formulated so as to be 0.0004% by mass or more and less than 1% by mass, and the pH is adjusted to 2 to 5.
  • the present invention is to provide a container-packed beverage containing isoquercitrin and a sugar adduct thereof that hardly change in color tone even when stored for a long period of time. Moreover, this invention is providing the color tone change suppression method of the container-packed drink containing an isoquercitrin and its sugar adduct.
  • the inventor of the present invention contains alcohols together with isoquercitrin and its sugar adduct, and further adjusts the pH within a specific range, so that the color tone hardly changes even when stored for a long period of time, and the appearance is improved. It has been found that a retained beverage is obtained.
  • the present invention it is possible to provide a packaged beverage containing isoquercitrin and a sugar adduct thereof that hardly change in color tone even when stored for a long period of time. Moreover, according to this invention, the color tone change suppression method of the container-packed drink containing isoquercitrin and its sugar adduct can be provided.
  • the container-packed beverage of the present invention contains 0.03 to 0.25% by mass of (A) isoquercitrin and its sugar adduct (hereinafter also referred to as “isoquercitrin sugar adduct etc.”).
  • the content of the component (A) is preferably 0.15% by mass or less, more preferably 0.12% by mass or less, and further preferably 0.1% by mass or less from the viewpoint of suppressing color change.
  • content of a component (A) is 0.04 mass% or more from a viewpoint of a physiological effect, Furthermore, 0.05 mass% or more, Furthermore, 0.06 mass% or more is preferable.
  • the range of the content of component (A) is 0.04 to 0.15% by mass, further 0.05 to 0.12% by mass, further 0.06 to 0.12% by mass, and further 0.06 to 0%. .1% by mass is preferable.
  • Isoquercitrin is obtained by ⁇ -bonding one glucose at the 3-position of quercetin (quercetincet3-O- ⁇ -D-glucopyranoside).
  • the isoquercitrin sugar adduct can be obtained, for example, by allowing glycosyltransferase to act on isoquercitrin in the presence of a sugar donor (glucose source), and adding one or more glucose to the glucose residue of isoquercitrin.
  • ⁇ -Glucosylisoquercitrin further added with ⁇ -1,4 bond (FFI Journal, Vol.209, No.7, 2004, p.622-628; Food Hygiene Journal, Vol.41, No. .1, p.54-60).
  • the component (A) includes isoquercitrin in which the number of glucose residues (n) is 0 in the following formula (1) and an integer in which the number of glucose residues (n) is 1 or more (preferably A mixture with an isoquercitrin sugar adduct which is an integer of 1 to 15, more preferably an integer of 1 to 10, and still more preferably an integer of 1 to 8.
  • Glc represents a glucose residue
  • n represents 0 or an integer of 1 or more.
  • the mass ratio of isoquercitrin sugar adduct / isoquercitrin in component (A) is preferably 1 or more, more preferably 2 or more, and particularly preferably 4 or more, from the viewpoint of water solubility.
  • the mass ratio is preferably 1000 or less, further 500 or less, further 100 or less, further 50 or less, further 25 or less, and further 10 or less from the viewpoint of production efficiency.
  • the range of the mass ratio is preferably 1 to 1000, further 1 to 500, further 1 to 100, further 1 to 50, further 1 to 25, further 1 to 10, further 2 to 10, and further 4 to 10.
  • Such (A) isoquercitrin sugar adducts and the like are commercially available.
  • Sanmerin AO-1007, Sanmerin Powder C-10 and the like (manufactured by Saneigen FFI Co., Ltd.) Can be mentioned.
  • glycosyltransferases used for glycosylation of isoquercitrin include glucosidases such as ⁇ -amylase (EC 3.2.1.1) and ⁇ -glucosidase (EC 3.2.1.20), and cyclodextrin glucanotransferase (EC). And transglucosidase such as 2.4.1.19).
  • glycosyltransferases are all commercially available, and examples thereof include contizyme (manufactured by Amano Enzyme).
  • the amount of glycosyltransferase used is not uniform depending on the type of enzyme and the desired composition.
  • cyclodextrin glucanotransferase [enzyme specific activity of about 100 units ( ⁇ -cyclodextrin from soluble starch per 1 minute per minute)
  • the amount of enzyme produced is defined as 1 unit)] is usually 0.001 to 20 parts by weight, preferably 0.005 to 10 parts by weight, more preferably 0.01 to 10 parts by weight per 1 part by weight of isoquercitrin. 5 parts by mass.
  • the sugar donor (glucose source) used for glycosylation is not particularly limited as long as one or more molecules of the glucose residue can be transferred to one molecule of isoquercitrin.
  • the amount of glucose used is usually 0.1 to 20 parts by weight, preferably 0.5 to 15 parts by weight, and more preferably 1 to 10 parts by weight with respect to 1 part by weight of isoquercitrin.
  • composition of the resulting (A) isoquercitrin sugar adduct is not uniform depending on the reaction conditions.
  • the temperature is 80 ° C. or less, preferably 20 to 80 ° C., more preferably 40 to 75 ° C., pH 3 to 11
  • various compositions can be obtained by allowing glycosyltransferase to act on isoquercitrin in the presence of a sugar donor (glucose source), preferably under conditions of pH 4-8.
  • the analysis method of (A) isoquercitrin sugar adduct and the like shall follow the method described in the examples described later.
  • the above reaction can be performed while standing or stirring or shaking.
  • the head space of the reaction system may be replaced with an inert gas such as nitrogen, and an antioxidant such as ascorbic acid may be added to the reaction system.
  • Isoquercitrin sugar adducts and the like can be prepared starting from rutin as well as using isoquercitrin as a raw material as described above. For example, ⁇ -1,6-rhamnosidase (EC 3.2.1.40) is allowed to act on rutin to convert it to isoquercitrin, and then (A) an isoquercitrin sugar adduct is prepared according to the above-mentioned method. it can.
  • ⁇ -1,6-rhamnosidase is commercially available, and examples thereof include hesperidinase, naringinase (manufactured by Tanabe Seiyaku Co., Ltd.), and cellulase A “Amano” 3 (manufactured by Amano Enzyme).
  • isoquercitrin sugar adducts where n is 0 and isoquercitrin sugar adducts where n is 4 or more are reduced by fractionation and rich in isoquercitrin sugar adducts where n is 3
  • the fraction contained in may be collected and used.
  • the container-packed beverage of the present invention preferably contains (A) an isoquercitrin sugar adduct or the like so as to be 0.01 to 0.1% by mass in terms of quercetin from the viewpoint of suppressing color change, and further 0 0.06% by mass or less, more preferably 0.05% by mass or less, and further preferably 0.04% by mass or less, and from the viewpoint of physiological effects, 0.016% by mass or more, further 0.021% by mass or more, and further 0.025 mass% or more is preferable.
  • the content range of the component (A) is preferably 0.016 to 0.06% by mass, more preferably 0.021 to 0.05% by mass, and further preferably 0.025 to 0.04% by mass in terms of quercetin.
  • the container-packed drink of this invention contains (B) alcohol in order to suppress a color tone change.
  • alcohol is a general term for compounds in which a hydrogen atom of a chain hydrocarbon is substituted with a hydroxyl group, a monohydric alcohol having one hydroxyl group and a polyvalent alcohol having two or more hydroxyl groups. It is a concept that includes alcohol.
  • polyhydric alcohol as used herein does not include sugar alcohol.
  • the alcohol used in the present invention is preferably an aliphatic alcohol having 1 to 7 carbon atoms from the viewpoint of color tone stability.
  • propanols such as methanol, ethanol, 1-propanol and isopropanol
  • butanols such as 1-butanol, 2-butanol and isobutanol
  • amyl alcohol isoamyl alcohol
  • 2-pentanol and 3-pen Pentanols such as butanol, 2-methyl-1-butanol
  • hexanols such as 1-hexanol, 2-hexanol and 3-hexanol
  • Monohydric alcohols such as heptanols such as 4-heptanol
  • polyhydric alcohols such as ethylene glycol, propylene glycol, 1,3-butanediol, neopentyl glycol, glycerin, diglycerin, propylene glycol It can be mentioned.
  • the content of the alcohol (B) in the packaged beverage of the present invention is 0.0004% by mass or more and less than 1% by mass, preferably 0.9% by mass or less from the viewpoint of further suppressing color change. More preferably, it is 0.8 mass% or less, More preferably, it is 0.7 mass% or less, Most preferably, it is 0.6 mass or less, and Preferably it is 0.001 mass% or more, More preferably, it is 0.005 mass% or more. More preferably, it is 0.01% by weight or more, more preferably 0.02% by weight or more, more preferably 0.03% by weight or more, further preferably 0.05% by weight or more, and particularly preferably 0.1% by weight. That's it.
  • the content range of the component (B) is 0.001 to less than 1% by mass, further 0.001 to 0.9% by mass, further 0.005 to 0.9% by mass, and further 0.01 to 0.9% by mass, further 0.02-0.8% by mass, further 0.03-0.8% by mass, further 0.05-0.7% by mass, further 0.1-0.7% by mass, Furthermore, 0.1 to 0.6% by mass is preferable.
  • the packaged beverage of the present invention can be a so-called non-alcoholic beverage.
  • “non-alcohol” is a concept that includes not only ethanol content of 0% by mass but also ethanol content that does not correspond to alcoholic beverages stipulated in applicable regulations (the liquor tax law in Japan). .
  • the mass ratio [(B) / (A)] of the component (A) and the component (B) in the packaged beverage of the present invention is preferably 30 or less, more preferably from the viewpoint of color change suppression and flavor. Is 25 or less, more preferably 20 or less, more preferably 15 or less, further preferably 10 or less, and preferably 0.05 or more, more preferably 0.1 or more, still more preferably 0.3 or more, and still more preferably. 0.5 or more, more preferably 1 or more.
  • the range of the mass ratio [(B) / (A)] is 0.05 to 30, further 0.1 to 25, further 0.3 to 20, further 0.5 to 15, and particularly 1 to 10. Preferably there is.
  • the container-packed beverage of the present invention can contain a sweetener.
  • sweeteners include, for example, monosaccharides such as fructose, glucose, tagatose, and arabinose, disaccharides such as lactose, trehalose, maltose, and sucrose; Oligosaccharides, non-crystalline saccharides such as syrup, and honey and the like in which sugars such as glucose and fructose account for about 70%.
  • These sweeteners can be used alone or in combination of two or more.
  • the content of the sweetener in the packaged beverage of the present invention can be appropriately determined, but is 0.02 to 1% by mass, further 0.05 to 0.8% by mass, and further 0.05 to 0. 0%. 6% by mass is preferable from the viewpoint of suppressing color change.
  • the content is preferably 1% by mass or less, more preferably 0.1 to 0.9% by mass, and still more preferably 0.2 to 0.8% by mass. %, More preferably 0.3 to 0.7% by mass.
  • a measuring method of a carbon dioxide gas it can measure with a gas volume meter and can convert into gas amount.
  • the gas volume refers to the ratio of the gas volume at 20 ° C. of the carbon dioxide dissolved in the beverage to the beverage volume.
  • the container-packed drink of this invention can contain a potassium ion.
  • the refreshing feeling is not diluted even during long-term storage, and the refreshing feeling in the mouth is maintained. Therefore, it is suitable not only for drinking in daily life, but also as a drink that is drunk particularly in sports.
  • Potassium ions as potassium salts such as potassium chloride, potassium carbonate, potassium sulfate, potassium acetate, potassium bicarbonate, potassium citrate, potassium phosphate, potassium hydrogen phosphate, potassium tartrate, potassium sorbate etc. or mixtures thereof Can be blended.
  • the potassium ions include those derived from raw materials.
  • the content of potassium ions in the packaged beverage of the present invention is preferably 0.001% by mass or more, more preferably 0.002% by mass or more, still more preferably 0.003% by mass or more, and further preferably 0.005.
  • % By mass or more, particularly preferably 0.01% by mass or more, and preferably 0.2% by mass or less, more preferably 0.1% by mass or less, still more preferably 0.09% by mass or less, still more preferably 0%. 0.08% by mass or less, particularly preferably 0.07% by mass or less.
  • the range of the potassium ion content is preferably 0.001 to 0.2% by mass, more preferably 0.002 to 0.1% by mass, further 0.003 to 0.09%, and further 0.005 to 0.08. % By mass, especially 0.01 to 0.07% by mass is preferred.
  • acidulant such as preservatives, seasonings, fruit juice extracts, malt extracts, vegetable extracts, nectar extracts, and quality stabilizers can be used alone or in combination of two or more.
  • content of an additive can be suitably selected within the range which does not prevent the objective of this invention.
  • the pH (20 ° C.) of the packaged beverage of the present invention is 2 to 5, but 3 to 4 is preferable from the viewpoint of further suppressing color tone change.
  • the container-packed beverage of the present invention preferably has a low viscosity in a container-packed state.
  • it is preferably not a high-viscosity food having shape-retaining properties such as jelly, but a viscosity that allows it to flow and be drunk only by tilting the container.
  • the specific viscosity is preferably 0.01 to 500 mPa ⁇ s, more preferably 0.01 to 400 mPa ⁇ s, and particularly preferably 0.01 to 200 mPa ⁇ s when measured at 20 ° C. with a vibration viscometer. .
  • the container-packed drink of this invention is the value which reduced the b * value of the container-packed drink immediately after manufacture from the b * value of the container-packed drink after preserve
  • ⁇ b * ) is preferably 2 or less, more preferably 1.9 or less, further 1.8 or less, further 1.7 or less, further 1.6 or less, and further 1.5 or less.
  • the “b * value” is one of coordinate values representing hue and saturation when the color is expressed in the L * a * b * color system, and is a coordinate indicating the saturation in the yellow direction. Value.
  • the L * a * b * color system includes L * indicating lightness and a * which is a coordinate value indicating saturation in the red direction, but in the present invention, it is most easily manifested when the color tone changes. It prescribes about b * .
  • the b * value is measured according to the method described in the examples below.
  • the container-packed beverage of the present invention can be produced by, for example, blending the component (A) and the component (B) and adjusting the concentration and pH of each component.
  • a container which can be used for the container-packed beverage of the present invention a molded container mainly composed of polyethylene terephthalate (so-called PET bottle), a metal can, a paper container combined with a metal foil or a plastic film, a bottle or the like is used.
  • PET bottle polyethylene terephthalate
  • a packaging container is mentioned.
  • heat sterilization such as a metal can can be performed, it can be sterilized under the conditions stipulated in the applicable regulations (the Food Sanitation Law in Japan).
  • those that cannot be sterilized by retort such as PET bottles and paper containers, are preliminarily sterilized at a high temperature and short time using a plate heat exchanger, for example, and then cooled to a certain temperature and filled into containers. Etc. can be adopted. Moreover, you may mix
  • the structure similar to the above is employable also in the color tone change suppression method of the container-packed drink containing isoquercitrin and its sugar adduct.
  • this invention discloses the following container drinks or the color tone change suppression method further.
  • the content of the component (A) is preferably 0.04% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.06% by mass or more, preferably 0.15% by mass or less, More preferably, it is 0.12% by mass or less, and still more preferably 0.1% by mass or less, in the above-mentioned [1-1].
  • the content of component (A) is preferably 0.04 to 0.15% by mass, more preferably 0.05 to 0.12% by mass, still more preferably 0.06 to 0.12% by mass, still more preferably The packaged beverage according to [1-1], which is 0.06 to 0.1% by mass.
  • the mass ratio of isoquercitrin sugar adduct / isoquercitrin is preferably 1 or more, more preferably 2 or more, further preferably 4 or more, preferably 1000 or less, more preferably 500.
  • Component (A) has an isoquercitrin sugar adduct / isoquercitrin mass ratio of preferably 1 to 1000, more preferably 1 to 500, still more preferably 1 to 100, still more preferably 1 to 50, and still more preferably. Is from 1 to 25, more preferably from 1 to 10, more preferably from 2 to 10, and even more preferably from 4 to 10, The packaged beverage according to any one of [1-1] to [1-3] above . [1-6] The content of the component (A) is preferably 0.01 to 0.1% by mass, more preferably 0.016 to 0.06% by mass, still more preferably 0.021 to 0.05% by mass in terms of quercetin.
  • [1-7] The packaged beverage according to any one of [1-1] to [1-6] above, wherein the component (B) is an aliphatic alcohol having 1 to 7 carbon atoms.
  • [1-8] The packaged beverage according to any one of [1-1] to [1-7] above, wherein the component (B) is at least one selected from ethanol, isoamyl alcohol, 1-hexanol, glycerin and propylene glycol. .
  • the content of the component (B) is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, further preferably 0.01% by mass or more, more preferably 0.02% by mass or more, and further preferably. Is 0.03% by mass or more, more preferably 0.05% by mass or more, further preferably 0.1% by mass or more, and less than 1% by mass, 0.9% by mass or less, more preferably 0.8% by mass. % Or less, more preferably 0.7% by mass or less, and still more preferably 0.6% by mass or less, according to any one of [1-1] to [1-8] above.
  • the content of the component (B) is preferably 0.001% by mass or more and less than 1% by mass, more preferably 0.001 to 0.9% by mass, still more preferably 0.005 to 0.9% by mass, and still more preferably. Is 0.01 to 0.9% by mass, more preferably 0.02 to 0.8% by mass, more preferably 0.03 to 0.8% by mass, still more preferably 0.05 to 0.7% by mass, More preferably 0.1 to 0.7% by mass, and still more preferably 0.1 to 0.6% by mass, the packaged beverage according to any one of [1-1] to [1-8] above .
  • the mass ratio [(B) / (A)] of the component (A) and the component (B) is preferably 0.05 or more, more preferably 0.1 or more, still more preferably 0.3 or more, Preferably, it is 0.5 or more, more preferably 1 or more, preferably 30 or less, more preferably 25 or less, further preferably 20 or less, still more preferably 15 or less, still more preferably 10 or less. -1] to [1-10] The packaged beverage according to any one of [1-10]. [1-12] The mass ratio [(B) / (A)] of the component (A) and the component (B) is preferably 0.05 to 30, more preferably 0.1 to 25, still more preferably 0.3 to 20.
  • a sweetener is contained, and the content of the sweetener is preferably 0.02 to 1% by mass, more preferably 0.05 to 0.8% by mass, and still more preferably 0.05 to 0.6% by mass.
  • carbon dioxide is contained, and the content of carbon dioxide is preferably 1% by mass or less, more preferably 0.1 to 0.9% by mass, still more preferably 0.2 to 0.8% by mass, and still more preferably.
  • the packaged beverage contains potassium ions, and the content of potassium ions is preferably 0.001% by mass or more, more preferably 0.002% by mass or more, still more preferably 0.003% by mass or more, and further preferably 0. 0.005% by mass or more, more preferably 0.01% by mass or more, preferably 0.2% by mass or less, more preferably 0.1% by mass or less, still more preferably 0.09% by mass or less, still more preferably.
  • the packaged beverage contains potassium ions, and the content of potassium ions is preferably 0.001 to 0.2% by mass, more preferably 0.002 to 0.1% by mass, and still more preferably 0.003 to 0%. 0.09 mass, more preferably 0.005 to 0.08 mass%, and still more preferably 0.01 to 0.07 mass%, as described in any one of the above [1-1] to [1-14] Bottled beverage.
  • the value ( ⁇ b * ) obtained by subtracting the b * value of the packaged beverage immediately after production from the b * value of the packaged beverage after storage at 55 ° C.
  • a method for suppressing color change of a packaged beverage containing isoquercitrin and its sugar adduct comprising the following components (A) and (B): (A) Isoquercitrin and its sugar adduct 0.03-0.25% by mass, (B) Alcohols A method for suppressing change in color tone, comprising blending so as to be 0.0004 mass% or more and less than 1 mass% and adjusting the pH to 2 to 5.
  • the component (A) is preferably 0.04% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.06% by mass or more, preferably 0.15% by mass or less, more preferably The method for suppressing a change in color tone according to [2-1], wherein the blending is performed so that the content is 0.12% by mass or less, more preferably 0.1% by mass or less.
  • the component (A) is preferably 0.04 to 0.15% by mass, more preferably 0.05 to 0.12% by mass, still more preferably 0.06 to 0.12% by mass, and still more preferably 0.06.
  • the method for suppressing a change in color tone according to the above [2-1] which is blended in an amount of 0.1 to 0.1% by mass.
  • [2-4] The method for suppressing a change in color tone according to any one of [2-1] to [2-3] above, wherein an aliphatic alcohol having 1 to 7 carbon atoms is used as the component (B).
  • [2-5] The change in color tone according to any one of [2-1] to [2-4] above, wherein at least one selected from ethanol, isoamyl alcohol, 1-hexanol, glycerin and propylene glycol is used as the component (B). Suppression method.
  • the component (B) is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, still more preferably 0.01% by mass or more, still more preferably 0.02% by mass or more, and still more preferably 0.001% by mass or more.
  • the component (B) is preferably 0.001% or more and less than 1% by weight, more preferably 0.001 to 0.9% by weight, still more preferably 0.005 to 0.9% by weight, and still more preferably 0.001% by weight.
  • the mass ratio [(B) / (A)] of the component (A) and the component (B) is preferably 0.05 or more, more preferably 0.1 or more, still more preferably 0.3 or more, Preferably 0.5 or more, more preferably 1 or more, preferably 30 or less, more preferably 25 or less, still more preferably 20 or less, still more preferably 15 or less, still more preferably 10 or less.
  • the mass ratio [(B) / (A)] of component (A) and component (B) is preferably 0.05 to 30, more preferably 0.1 to 25, and still more preferably 0.3 to 20.
  • the value ( ⁇ b * ) obtained by subtracting the b * value of the packaged beverage immediately after production from the b * value of the packaged beverage after storage at 55 ° C. for 7 days is preferably 2.0 or less, more preferably 1.
  • a sample for analysis was prepared by the following procedure. 1 g of a sample was weighed, 1 mL of methanol was added, and a mixed solution of methanol and water (1: 1) was further added to make a constant volume of 10 mL to obtain a sample solution. The prepared sample solution was subjected to high performance liquid chromatographic analysis.
  • quercetin equivalent amount of isoquercitrin sugar adducts and the like in the sample was calculated by calculating the content of the aglycone part from the respective molar concentrations of isoquercitrin and each sugar adduct.
  • a sample for analysis was prepared by the following procedure. A sample (5 g) was weighed, and water was added thereto to make a constant volume of 25 mL. The solution was subjected to disk filtration to obtain a sample solution. The prepared sample solution was subjected to gas chromatographic analysis.
  • a sample for analysis was prepared by the following procedure.
  • a sample (5 g) was weighed and tetrahydrofuran was added thereto to make a constant volume of 25 mL.
  • the solution was subjected to disk filtration to obtain a sample solution.
  • the prepared sample solution was subjected to gas chromatographic analysis.
  • a sample for analysis was prepared by the following procedure. A sample (5 g) was weighed, and 20 mg of internal standard (trimethylene glycol) and methanol were added thereto to make a constant volume of 10 mL. This was used as a sample solution for gas chromatographic analysis.
  • internal standard trimethylene glycol
  • Examples 1 to 12 Comparative Examples 1 to 3 Prepared with the composition shown in Table 1, then sterilized at 85 ° C. for 2 minutes, and filled in a 200 mL PET bottle with 160 mL to prepare a packaged beverage.
  • Table 1 shows the component analysis and evaluation results of each packaged beverage.
  • Example 13 In the formulation of Example 1, ion-exchanged water was blended so as to give a 4-fold concentrated solution, the concentrated solution was sterilized at 85 ° C. for 2 minutes, and then diluted 4-fold, the carbon dioxide volume was 2.5. In this way, carbonated water cooled to 5 ° C. was blended, filled into a pressure-resistant PET bottle and wound, and then sterilized at 65 ° C. for 20 minutes to prepare a packaged beverage. When this “packed beverage” was evaluated for “color tone change” and “kokumi”, the same results as in Example 1 were obtained.
  • Example 14 In the formulation of Example 1, a container-packed beverage was prepared in the same manner as in Example 1 except that 0.02% by mass of potassium chloride (0.0105% by mass as potassium ions) was further added. When this “packed beverage” was evaluated for “color tone change” and “kokumi”, the same results as in Example 1 were obtained.

Abstract

L'invention porte sur une boisson emballée, qui contient de l'isoquercitrine et un composé d'addition de sucre de celle-ci, laquelle boisson ne change pas facilement de couleur même si elle est stockée pendant une longue période. Cette boisson emballée contient les composants (A) et (B) suivants : (A) de 0,03 à 0,25 % en masse d'isoquercitrine et d'un composé d'addition de sucre de celle-ci; et (B) de 0,0004 % en masse à moins de 1 % en masse d'alcool de sucre. La boisson emballée a un pH de 2 à 5.
PCT/JP2012/074774 2011-09-27 2012-09-26 Boisson emballée WO2013047612A1 (fr)

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JP2015142562A (ja) * 2013-12-27 2015-08-06 花王株式会社 容器詰飲料
JP2017029024A (ja) * 2015-07-30 2017-02-09 サントリー食品インターナショナル株式会社 酵素処理イソクエルシトリン含有容器詰飲料
JP2017042109A (ja) * 2015-08-27 2017-03-02 サントリー食品インターナショナル株式会社 酵素処理イソクエルシトリン含有飲料

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JP6375128B2 (ja) * 2014-04-01 2018-08-15 花王株式会社 ビアテイスト飲料
JP5890565B2 (ja) * 2014-06-25 2016-03-22 花王株式会社 容器詰飲料
JP6745246B2 (ja) * 2017-06-22 2020-08-26 花王株式会社 ポリフェノール含有飲料
US11446319B2 (en) 2018-06-01 2022-09-20 Taiyo Kagaku Co., Ltd. Composition containing flavonoid-cyclodextrin clathrate compound

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JPH09266767A (ja) * 1996-03-29 1997-10-14 Meiji Seika Kaisha Ltd サンザシ抽出物入り持久力向上飲食品
JP2005087147A (ja) * 2003-09-19 2005-04-07 Sanei Gen Ffi Inc 退色抑制剤
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JP2011093842A (ja) * 2009-10-09 2011-05-12 Tokiwa Shokubutsu Kagaku Kenkyusho:Kk 抗ストレス剤
JP2012085568A (ja) * 2010-10-18 2012-05-10 Kao Corp ゼリー状食品

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JP4712746B2 (ja) 2006-09-15 2011-06-29 キユーピー株式会社 酸性飲料
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JPH09266767A (ja) * 1996-03-29 1997-10-14 Meiji Seika Kaisha Ltd サンザシ抽出物入り持久力向上飲食品
JP2005087147A (ja) * 2003-09-19 2005-04-07 Sanei Gen Ffi Inc 退色抑制剤
WO2010110328A1 (fr) * 2009-03-25 2010-09-30 三栄源エフ・エフ・アイ株式会社 Composition à base d'isoquercitrine facilement hydrosoluble
JP2011093842A (ja) * 2009-10-09 2011-05-12 Tokiwa Shokubutsu Kagaku Kenkyusho:Kk 抗ストレス剤
JP2012085568A (ja) * 2010-10-18 2012-05-10 Kao Corp ゼリー状食品

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JP2015142562A (ja) * 2013-12-27 2015-08-06 花王株式会社 容器詰飲料
JP2017029024A (ja) * 2015-07-30 2017-02-09 サントリー食品インターナショナル株式会社 酵素処理イソクエルシトリン含有容器詰飲料
JP2017042109A (ja) * 2015-08-27 2017-03-02 サントリー食品インターナショナル株式会社 酵素処理イソクエルシトリン含有飲料

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