WO2012124242A1 - Matière active de cathode pour une batterie secondaire à électrolyte non-aqueux, son procédé de fabrication et batterie secondaire à électrolyte non-aqueux l'utilisant - Google Patents

Matière active de cathode pour une batterie secondaire à électrolyte non-aqueux, son procédé de fabrication et batterie secondaire à électrolyte non-aqueux l'utilisant Download PDF

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Publication number
WO2012124242A1
WO2012124242A1 PCT/JP2012/000084 JP2012000084W WO2012124242A1 WO 2012124242 A1 WO2012124242 A1 WO 2012124242A1 JP 2012000084 W JP2012000084 W JP 2012000084W WO 2012124242 A1 WO2012124242 A1 WO 2012124242A1
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WO
WIPO (PCT)
Prior art keywords
nickel
lithium
active material
positive electrode
raw material
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PCT/JP2012/000084
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English (en)
Japanese (ja)
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祐樹 杉本
直人 安田
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株式会社豊田自動織機
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Publication of WO2012124242A1 publication Critical patent/WO2012124242A1/fr

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/125—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type[MnO3]n-, e.g. Li2MnO3, Li2[MxMn1-xO3], (La,Sr)MnO3
    • C01G45/1257—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type[MnO3]n-, e.g. Li2MnO3, Li2[MxMn1-xO3], (La,Sr)MnO3 containing lithium, e.g. Li2MnO3, Li2[MxMn1-xO3
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/20—Two-dimensional structures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

L'invention concerne : une matière active de cathode destinée à une batterie secondaire à électrolyte non-aqueux dotée de caractéristiques de batterie supérieures ; un procédé de fabrication de la matière active de cathode ; une batterie secondaire à électrolyte non-aqueux utilisant la matière active de cathode ; et un véhicule. La matière active de cathode destinée à une batterie secondaire à électrolyte non-aqueux comprend un oxyde de nickel et un oxyde complexe de lithium-nickel ayant une structure cristalline classée en tant que structure de sel gemme stratifiée et contenant au moins l'élément lithium (Li) et l'élément nickel (Ni). L'oxyde de nickel constitue une partie des matières premières pour produire l'oxyde complexe de lithium-nickel ou un sous-produit généré par les matières premières.
PCT/JP2012/000084 2011-03-14 2012-01-10 Matière active de cathode pour une batterie secondaire à électrolyte non-aqueux, son procédé de fabrication et batterie secondaire à électrolyte non-aqueux l'utilisant WO2012124242A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011055672 2011-03-14
JP2011-055672 2011-03-14

Publications (1)

Publication Number Publication Date
WO2012124242A1 true WO2012124242A1 (fr) 2012-09-20

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WO (1) WO2012124242A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102730765A (zh) * 2012-07-11 2012-10-17 中国第一汽车股份有限公司 一种碳酸盐沉淀式熔盐法制备的高容量正极材料
WO2015050176A1 (fr) * 2013-10-04 2015-04-09 Semiconductor Energy Laboratory Co., Ltd. Oxyde composite au lithium-manganèse, batterie secondaire, dispositif électronique et procédé pour former une couche
US10367188B2 (en) 2015-01-09 2019-07-30 Semiconductor Energy Laboratory Co., Ltd. Storage battery electrode, manufacturing method thereof, storage battery, and electronic device
US10741828B2 (en) 2016-07-05 2020-08-11 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material including lithium cobaltate coated with lithium titanate and magnesium oxide
US11094927B2 (en) 2016-10-12 2021-08-17 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material particle and manufacturing method of positive electrode active material particle
US11133501B2 (en) 2015-10-30 2021-09-28 Samsung Sdi Co., Ltd. Composite positive active material, method of preparing the same, and lithium secondary battery including positive electrode including the same
US11444274B2 (en) 2017-05-12 2022-09-13 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material particle
US11670770B2 (en) 2017-06-26 2023-06-06 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing positive electrode active material, and secondary battery
US11799080B2 (en) 2017-05-19 2023-10-24 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material, method for manufacturing positive electrode active material, and secondary battery

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1059725A (ja) * 1996-08-16 1998-03-03 Sakai Chem Ind Co Ltd 粒子状組成物及びその製造方法並びにリチウムイオン二次電池
JP2000133263A (ja) * 1998-10-23 2000-05-12 Hitachi Ltd リチウム二次電池
JP2003168428A (ja) * 2001-11-29 2003-06-13 Sumitomo Metal Mining Co Ltd 非水系電解質二次電池用正極活物質およびその製造方法
JP2004107095A (ja) * 2001-10-11 2004-04-08 Mitsubishi Chemicals Corp リチウム遷移金属複合酸化物の製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1059725A (ja) * 1996-08-16 1998-03-03 Sakai Chem Ind Co Ltd 粒子状組成物及びその製造方法並びにリチウムイオン二次電池
JP2000133263A (ja) * 1998-10-23 2000-05-12 Hitachi Ltd リチウム二次電池
JP2004107095A (ja) * 2001-10-11 2004-04-08 Mitsubishi Chemicals Corp リチウム遷移金属複合酸化物の製造方法
JP2003168428A (ja) * 2001-11-29 2003-06-13 Sumitomo Metal Mining Co Ltd 非水系電解質二次電池用正極活物質およびその製造方法

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102730765A (zh) * 2012-07-11 2012-10-17 中国第一汽车股份有限公司 一种碳酸盐沉淀式熔盐法制备的高容量正极材料
WO2015050176A1 (fr) * 2013-10-04 2015-04-09 Semiconductor Energy Laboratory Co., Ltd. Oxyde composite au lithium-manganèse, batterie secondaire, dispositif électronique et procédé pour former une couche
US10454102B2 (en) 2013-10-04 2019-10-22 Semiconductor Energy Laboratory Co., Ltd. Lithium manganese composite oxide, secondary battery, electronic device, and method for forming layer
US10367188B2 (en) 2015-01-09 2019-07-30 Semiconductor Energy Laboratory Co., Ltd. Storage battery electrode, manufacturing method thereof, storage battery, and electronic device
US11881578B2 (en) 2015-01-09 2024-01-23 Semiconductor Energy Laboratory Co., Ltd. Storage battery electrode, manufacturing method thereof, storage battery, and electronic device
US10923706B2 (en) 2015-01-09 2021-02-16 Semiconductor Energy Laboratory Co., Ltd. Storage battery electrode, manufacturing method thereof, storage battery, and electronic device
US11545655B2 (en) 2015-01-09 2023-01-03 Semiconductor Energy Laboratory Co., Ltd. Storage battery electrode, manufacturing method thereof, storage battery, and electronic device
US11133501B2 (en) 2015-10-30 2021-09-28 Samsung Sdi Co., Ltd. Composite positive active material, method of preparing the same, and lithium secondary battery including positive electrode including the same
US11043660B2 (en) 2016-07-05 2021-06-22 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material including lithium cobaltate coated with lithium titanate and magnesium oxide
US10741828B2 (en) 2016-07-05 2020-08-11 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material including lithium cobaltate coated with lithium titanate and magnesium oxide
US11094927B2 (en) 2016-10-12 2021-08-17 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material particle and manufacturing method of positive electrode active material particle
US11444274B2 (en) 2017-05-12 2022-09-13 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material particle
US11489151B2 (en) 2017-05-12 2022-11-01 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material particle
US11799080B2 (en) 2017-05-19 2023-10-24 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material, method for manufacturing positive electrode active material, and secondary battery
US11670770B2 (en) 2017-06-26 2023-06-06 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing positive electrode active material, and secondary battery

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