WO2012085150A4 - Titano-silico-alumo-phosphat - Google Patents
Titano-silico-alumo-phosphat Download PDFInfo
- Publication number
- WO2012085150A4 WO2012085150A4 PCT/EP2011/073686 EP2011073686W WO2012085150A4 WO 2012085150 A4 WO2012085150 A4 WO 2012085150A4 EP 2011073686 W EP2011073686 W EP 2011073686W WO 2012085150 A4 WO2012085150 A4 WO 2012085150A4
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- WO
- WIPO (PCT)
- Prior art keywords
- silico
- titano
- tapso
- phosphate
- aluminophosphate
- Prior art date
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- 229910019142 PO4 Inorganic materials 0.000 title claims abstract 12
- 239000010452 phosphate Substances 0.000 title claims abstract 12
- 239000010936 titanium Substances 0.000 claims abstract 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 8
- 229910052719 titanium Inorganic materials 0.000 claims abstract 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 2
- 230000015572 biosynthetic process Effects 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims abstract 2
- 229910052710 silicon Inorganic materials 0.000 claims abstract 2
- 239000010703 silicon Substances 0.000 claims abstract 2
- 238000003786 synthesis reaction Methods 0.000 claims abstract 2
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- RZQXOGQSPBYUKH-UHFFFAOYSA-N 3-[[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound OCC(CO)(CO)NCC(O)CS(O)(=O)=O RZQXOGQSPBYUKH-UHFFFAOYSA-N 0.000 claims 1
- 108700016232 Arg(2)-Sar(4)- dermorphin (1-4) Proteins 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 1
- 238000002329 infrared spectrum Methods 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 229910052762 osmium Inorganic materials 0.000 claims 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052701 rubidium Inorganic materials 0.000 claims 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 229910052706 scandium Inorganic materials 0.000 claims 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 238000001027 hydrothermal synthesis Methods 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0292—Phosphates of compounds other than those provided for in B01J20/048
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
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- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
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- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Abstract
Die vorliegende Erfindung betrifft ein Titano-Silico-Alumo-Phosphat, das tetraedrisch koordiniertes Titan in der Gerüststruktur enthält, das eine freie Koordinationsstelle für CO aufweist, das mittels einer charakteristischen IR-Bande bei 2192 ± 5 cm-1 nachgewiesen werden kann. Das Titano-Silico-Alumo-Phosphat zeigt aussergewöhnlich hohe hydrothermale Stabilität und weist eine gute Adsorptionskapazität auch bei höheren Temperaturen auf. Aufgrund der hohen hydrothermalen Stabilität kann es durch ein Hydrothermalverfahren ausgehend von einer Synthesegelmischung aus einer Aluminium-, Phosphor-, Silizium- und einer Titanquelle, sowie entsprechenden Templaten erhalten werden.
Claims
1. Titano-Silico-Alumo-Phosphat mit tetraedrisch
koordiniertem Titan, das eine freie Koordinationsstelle für CO aufweist.
2. Titano-Silico-Alumo-Phosphat nach Anspruch 1, dadurch gekennzeichnet, dass das tetraedrisch koordinierte Titan im IR-Spektrum eine Ti-CO-Bande bei 2192 ± 5 cm-1 aufweist .
3. Titano-Silico-Alumo-Phosphat nach Anspruch 2, dadurch gekennzeichnet, dass die Ti-CO-IR-Bande eine Intensität von 0,005 bis 0,025 aufweist.
4. Titano-Silico-Alumo-Phosphat nach Anspruch 3, dadurch gekennzeichnet, dass das Titano-Silico-Alumo-Phosphat 0 , 06 bis 5 Gew.-% Titan im Gerüst enthält.
5. Titano-Silico-Alumo-Phosphat nach Anspruch 4, dadurch gekennzeichnet, dass das Titano-Silico-Alumo-Phosphat ein Ti/Si/ (Al+P) -Verhältnis von 0,01 : 0 , 01 : 1 bis 0,2 : 0,2 : 1 aufweist.
6. Titano-Silico-Alumo-Phosphat nach Anspruch 5, dadurch gekennzeichnet, dass das Titano-Silico-Alumo-Phosphat ein Si/Al-Verhältnis von 0,05 bis 3 aufweist.
7. Titano-Silico-Alumo-Phosphat nach Anspruch 6, dadurch gekennzeichnet, dass das Titano-Silico-Alumo-Phosphat eine hydrothermale Stabilität bis 900 °C aufweist.
8. Titano-Silico-Alumo-Phosphat nach Anspruch 7, dadurch gekennzeichnet, dass es ausgewählt ist aus TAPSO-5, TAPSO-8, TAPSO-11, TAPSO-16, TAPSO-17, TAPSO-18, TAP50- 20, TAPSO-31, TAPSO-34, TAPSQ-35, TAPSO-36, TAPSO-37, TAPSO-40, TAPSO-41, TAPSO-42, TAPSO-44, TAPSO-47, TAPSO- 56.
9. Titano-Silico-Alumo-Phosphat nach Anspruch 8, dadurch gekennzeichnet, dass das Titano-Silico-Alumo-Phosphat mindestens ein weiteres Metall enthält, ausgewählt aus Lithium, Natrium, Kalium, Magnesium, Calcium,
Strontium, Barium, Scandium, Titan, Vanadium, Chrom, Mangan, Eisen, Nickel, Kupfer, Zink, Gallium, Germanium, Kobalt, Bor, Rubidium, Yttrium, Zirkonium, Niob,
Molybdän, Ruthenium, Rhodium, Palladium, Silber,
Cadmium, Indium, Zinn, Lanthan, Hafnium, Tantal,
Wolfram, Rhenium, Osmium, Iridium, Platin, Gold,
und/oder Bismut.
10. Titano-Silico-Alumo-Phosphat nach Anspruch 9, dadurch gekennzeichnet, dass das ein weiteres Metall enthaltende Titano-Silico-Alumo-Phosphat, Metall im Bereich von 1 Gew.-% bis 20 Gew.-% bezogen auf das Gesamtgewicht des Titano-Silico-Alumo-Phosphats enthält .
11. Titano-Silico-Alumo-Phosphat nach einem der vorstehenden Ansprüche, dessen Kristallitgröße zwischen 0,1 μm und 10 μm beträgt.
12. Verfahren zur Herstellung eines Titano-Silico-Alumo- Phosphats umfassend die Schritte des a) Bereitstellens einer wässrigen
Synthesegelmischung, enthaltend, mindestens eine Aluminiumquelle, eine Phosphorquelle, eine Siliziumquelle, ein Templat und eine
Titanquelle,
b) Rührens über mehrere Stunden bei einer
Temperatur im Bereich von 150 bis 350 °C, c) Filtrierens, und Trocknens bei einer Temperatur von 100 ºC,
d) Kalzinierens bei einer Temperatur im Bereich von 400 bis 600 °C,
e) Erhaltens eines titanhaltigen Silico-Alumo-
Phosphats .
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013545384A JP2014501691A (ja) | 2010-12-22 | 2011-12-21 | チタノシリコアルミノホスフェート |
| EP11819094.1A EP2655256A2 (de) | 2010-12-22 | 2011-12-21 | Titano-silico-alumo-phosphat |
| CN201180061797.0A CN103269977B (zh) | 2010-12-22 | 2011-12-21 | 磷酸钛硅铝 |
| US13/996,030 US20130334460A1 (en) | 2010-12-22 | 2011-12-21 | Titano-silico-alumino-phosphate |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010055679A DE102010055679A1 (de) | 2010-12-22 | 2010-12-22 | Titano-Silico-Alumo-Phosphat |
| DE102010055679.3 | 2010-12-22 |
Publications (3)
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| WO2012085150A2 WO2012085150A2 (de) | 2012-06-28 |
| WO2012085150A3 WO2012085150A3 (de) | 2012-09-07 |
| WO2012085150A4 true WO2012085150A4 (de) | 2012-10-26 |
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| PCT/EP2011/073686 WO2012085150A2 (de) | 2010-12-22 | 2011-12-21 | Titano-silico-alumo-phosphat |
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| US (1) | US20130334460A1 (de) |
| EP (1) | EP2655256A2 (de) |
| JP (1) | JP2014501691A (de) |
| CN (1) | CN103269977B (de) |
| DE (1) | DE102010055679A1 (de) |
| WO (1) | WO2012085150A2 (de) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112016029733B8 (pt) * | 2014-06-18 | 2022-09-27 | Basf Corp | Catalisador scr, método para reduzir seletivamente óxidos de nitrogênio (nox) e sistema de tratamento de gás de exaustão |
| US10850265B2 (en) | 2014-06-18 | 2020-12-01 | Basf Corporation | Molecular sieve catalyst compositions, catalytic composites, systems, and methods |
| US9889437B2 (en) * | 2015-04-15 | 2018-02-13 | Basf Corporation | Isomorphously substituted catalyst |
| US9764313B2 (en) | 2014-06-18 | 2017-09-19 | Basf Corporation | Molecular sieve catalyst compositions, catalyst composites, systems, and methods |
| CN105406038A (zh) * | 2015-11-03 | 2016-03-16 | 山东精工电子科技有限公司 | 一种溶胶凝胶法合成高容量高循环纳米级磷酸铁锰锂材料 |
| CN108996515A (zh) * | 2018-07-28 | 2018-12-14 | 瑞声科技（南京）有限公司 | 一种吸音材料及应用该吸音材料的扬声器箱 |
| CN110040744B (zh) * | 2019-04-08 | 2022-07-01 | 福建师范大学 | 一种MeAPSO-34分子筛及其制备方法 |
| CN113120922B (zh) * | 2021-06-02 | 2023-03-10 | 江西省科学院应用化学研究所 | 一种纳米片状形貌的La-SAPO-34分子筛的合成方法及应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4684617A (en) | 1984-04-13 | 1987-08-04 | Union Carbide Corporation | Titanium-aluminum-phosphorus-silicon-oxide molecular sieves |
| US4880520A (en) * | 1984-04-13 | 1989-11-14 | Uop | Hydrocarbon conversion process using titanium-aluminum-phosphorus-silicon-oxide molecular sieves as catalyst |
| US4818739A (en) * | 1984-12-18 | 1989-04-04 | Uop | Hydrocracking catalysts and processes employing non-zeolitic molecular sieves |
| CN1011691B (zh) * | 1985-04-27 | 1991-02-20 | 联合碳化公司 | 钛-铝-磷-硅-氧化物分子筛的制备方法 |
| TWI234556B (en) * | 1997-07-23 | 2005-06-21 | Mitsubishi Gas Chemical Co | Catalysts for methanol conversion reactions |
| JP2001038216A (ja) * | 1999-08-04 | 2001-02-13 | Mitsubishi Gas Chem Co Inc | 触媒寿命の改善方法 |
| JP4596116B2 (ja) * | 2002-05-24 | 2010-12-08 | 三菱瓦斯化学株式会社 | ８酸素員環細孔を持つ結晶質シリコアルミノリン酸塩モレキュラーシーブ及びその製造方法、並びにそれを触媒とするメチルアミン類の製造方法 |
| EP2022565A1 (de) | 2007-07-06 | 2009-02-11 | Casale Chemicals S.A. | Verfahren zur Herstellung molekularer Silicoaluminophosphat-Molekularsiebe, Katalysatoren mit besagten Sieben und katalytische Dehydrierungsprozesse mit besagten Katalysatoren |
| DE102009034850A1 (de) | 2009-07-27 | 2011-02-10 | Süd-Chemie AG | Verfahren zur Herstellung eines Silico-Alumo-Phosphats |
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2010
- 2010-12-22 DE DE102010055679A patent/DE102010055679A1/de not_active Ceased
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2011
- 2011-12-21 WO PCT/EP2011/073686 patent/WO2012085150A2/de active Application Filing
- 2011-12-21 US US13/996,030 patent/US20130334460A1/en not_active Abandoned
- 2011-12-21 CN CN201180061797.0A patent/CN103269977B/zh not_active Expired - Fee Related
- 2011-12-21 JP JP2013545384A patent/JP2014501691A/ja active Pending
- 2011-12-21 EP EP11819094.1A patent/EP2655256A2/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| CN103269977B (zh) | 2015-04-15 |
| DE102010055679A1 (de) | 2012-06-28 |
| JP2014501691A (ja) | 2014-01-23 |
| CN103269977A (zh) | 2013-08-28 |
| WO2012085150A2 (de) | 2012-06-28 |
| EP2655256A2 (de) | 2013-10-30 |
| WO2012085150A3 (de) | 2012-09-07 |
| US20130334460A1 (en) | 2013-12-19 |
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